for the proactive corrosion inhibitor management of ... · for the proactive management of pipeline...

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FOR THE PROACTIVE MANAGEMENT OF PIPELINE CORROSION CoMic™ detects micelles and so provides information on optimal corrosion inhibitor dosage; it provides increased risk assurance Applications Regular testing as part of an improved corrosion management system Time saving lab chemical screening tool Field inhibitor dose optimisation Troubleshoot production issues onsite Consumables e.g. LUX Marker™ Data analysis Instrument For onshore and offshore use A micelle is a nanoscale aggregate of corrosion inhibitor that forms when a system has reached saturation i.e. corrosion inhibitor has adhered to every available surface (pipe, solid, interface) Optimally-dosed Corrosion inhibitor working at its maximum effectiveness Over-dosed Surplus chemical used; increased risk of emulsions and separation issues Corrosion inhibitor Micelle Cross-section of micelle Under-dosed Increased risk of corrosive attack and loss of integrity CoMic™ helps to optimise corrosion inhibitor use by measuring for the presence and amount of corrosion inhibitor micelles*. There is a strong link between the optimum functional dose for organic film-forming corrosion inhibitors and the concentration at which micelles form in a system i.e. its critical micelle concentration (CMC). * Patent pending

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FOR THE PROACTIVE MANAGEMENT OF PIPELINE CORROSIONCoMic™ detects micelles and so provides information on optimal corrosion inhibitor dosage; it provides increased risk assurance

ApplicationsRegular

testing as partof an improved

corrosion management

system

Time savinglab chemical

screening tool

Fieldinhibitor dose optimisation

Troubleshoot production

issues onsite

Consumables e.g. LUX Marker™

Data analysisInstrument

For onshore and o� shore use

A micelle is a nanoscale aggregate of corrosion inhibitor that forms when a system has reached saturation i.e. corrosion inhibitor has adhered to every available surface (pipe, solid, interface)

Optimally-dosedCorrosion inhibitor working at its maximum eff ectiveness

Over-dosedSurplus chemical used; increased risk of emulsions and separation issues

Corrosion inhibitor

Micelle Cross-section of micelle

Under-dosedIncreased risk of corrosive attack and loss of integrity

CoMic™ helps to optimise corrosion inhibitor use by measuring for the presence and amount of corrosion inhibitor micelles*. There is a strong link between the optimum functional dose for organic fi lm-forming corrosion inhibitors and the concentration at which micelles form in a system i.e. its critical micelle concentration (CMC).

* Patent pending

Details on use• For onsite use; so avoiding sample

degradation associated with transit time to central lab and subsequent inaccurate results

• Samples are tested (i.e. it is not an online instrument)

• Simple to perform (mix sample and marker, place in instrument, read signal)

• Quick to perform (minutes)

• Data analysis (micelle interpretation) conducted by LUX personnel for robustness

• All chemicals and consumables are provided

Typical data• Fluids from an inter-platform pipeline were tested for the

presence of corrosion inhibitor micelles

• CoMic™ materials were taken to the asset and fresh samples were provided by asset staff

• Testing of samples in the off shore laboratory with CoMic™ only took a few minutes

• Data from testing the ‘input’ fl uid indicated the presence of micelles but these were not apparent in the fl uid reaching the destination platform (‘output’)

• The analysis provided information to the operator, beyond that already available from probes and residual monitoring, to better understand the corrosion risks that existed in the pipeline

Typical CoMic™ data

CoMic™ provides information not off ered by other monitoring approaches; it is a complementary tool

CoMic™ Simple residual analyses e.g. methyl orange

Complex residual analysis e.g. LC-MS

Corrosion rate testing e.g. coupons, probes

Suitable for fi eld use? ✔ ✔ ✘ ✔ (not all)

Reliable & accurate? ✔ ✘ ✔ ✔ (not all)

Robust to interferences(e.g. oil, scale inhibitors)?

✔ ✘ ✘ ✘ (not all)

Indicates if dosage is optimal? ✔ ✘ ✘ ✔

Indicates overdosing? ✔ ✘ ✘/✔ ✘

Provides concentration info? ✘ ✔ ✔ ✘

“ The CMC should be used as the treatment rate in the fi eld since maximum inhibition is achieved at this concentration.”K. Tsui, J. E. Wong and N. Park,Corrosion 2010 Paper 10326

Mic

elle

-Lik

e P

arti

cles

20000

18000

16000

14000

12000

10000

8000

6000

4000

2000

0Input Output

For More Information Contact:

Dr Cameron [email protected]

T+44 131 516 7290

LUX Assure Ltd, Unit 5.3, Research Avenue SouthHeriot Watt Research Park, Edinburgh EH14 4AP, UK

www.luxassure.com

CoMic™ current status - trialled, deployed and commercially available CoMic™ is unique. No other company can provide our corrosion inhibitor micelle detection tool.

LUX Assure: By applying Life Science concepts LUX aims to become the world leader in providing new technology to monitor diffi cult to detect chemicals used by the oil industry. LUX’s other analysis technologies cover areas such as Methanol and MEG, Chemical Tracers and Oil in Water.

The CoMic™ instrument