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Santa Ana River Basin Section Santa Ana River Basin Section CALIFORNIA WATER ENVIRONMENT ASSOCIATION Air, Water & Energy Sustainability for Wastewater Treatment Plants FOG: Grease to Energy FOG: Grease to Energy Robert A. Gillette, P.E., BCEE June 11, 2009 rc1104mrwpca.ppt

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Santa Ana River Basin SectionSanta Ana River Basin SectionCALIFORNIA WATER ENVIRONMENT ASSOCIATION

Air, Water & Energy Sustainability for , gy yWastewater Treatment Plants

FOG: Grease to EnergyFOG: Grease to Energy

Robert A. Gillette, P.E., BCEEJune 11, 2009

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Overview

1. The FOG Sewer Problem

2. Research

3. Design Considerations

4 Installations4. Installations

5. Questions?Q

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Two-Phase Di ti

Two-Phase Di ti

FOG Sewer Problem

FOG Sewer ProblemDigestion OverviewDigestion Overview

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FOG Problem

State and Fede al p sh to eliminate 1. State and Federal push to eliminate sanitary sewer overflows

2 Grease plugging causes overflows2. Grease plugging causes overflows3. Grease cleaning costs us all

R it f th 4. Remove it from the sewers

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Two-Phase Di ti

Two-Phase Di ti

How to get FOG Out of your Sewers

How to get FOG Out of your Sewers

Digestion OverviewDigestion Overview

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The FOG Problem - Education

Fl e s1. Flyers2. Restaurant Training and

Maintenance SheetsMaintenance Sheets3. Best Management Practices

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Volatile Solids Loading Rate

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Help Your Restaurantswith BMP’s and Charts

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FOG Problem – Education Alone is not Enoughis not Enough

Implement an O dinance1. Implement an Ordinance2. Provide them with Design

Standards for Grease TrapsStandards for Grease Traps3. Require documentation of

compliancecompliance4. Develop a Data Base

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Two-Phase Di ti

Two-Phase Di ti ResearchResearchDigestion OverviewDigestion Overview

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Recent Research Objectives

1 Establish the feasibility of increasing the 1. Establish the feasibility of increasing the amount of dewatered FOG quantities added to the digesters

2. Quantify the degree of mesophilic anaerobic biodegradation and methane generation from SCBWRF sludge when co-digested with an increasing amount of FOGFOG

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Approach

1.Perform parallel laboratory-scale batch e o pa a e abo ato y sca e batcdigestion of sludge without FOG and with increasing amounts of FOG

Ph 1 E i ti G T h i bi l d a. Phase 1 – Existing Ga. Tech microbial seed culture not acclimated to FOG

b. Phase 2 – Using seed culture acclimated to gFOG during phase 1

2.Perform parallel semi-continuous feed laboratory scale digestion of sludge with laboratory-scale digestion of sludge with and without FOGa. Phase 3 – Using seed culture acclimated to

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gFOG during phase 2

Reactor VS LoadingSample

VS Loading, % of Total Total VS Load, kg/m3

(% FOG VS)PS Mix TWAS Cake FOGP FOGL

1. Seed Blank − − − − − −

2. PS 100% − − − − 3.0

3. TWAS − 100% − − − 3.0

4. Cake − − 100% − − 3.0

5 FOG 100% 2 395. FOGP − − − 100% − 2.39

6. FOGL − − − − 100% 3.0

7. PS + TWAS 39% 61% − − − 3.0

8. PS + TWAS + C 28% 44% 29% − − 3.0

9. PS + TWAS + FOGP 28% 53% − 14% − 3.48 (14%)

10. PS + TWAS + FOGL 31% 49% − − 20% 3.75 (20%)

11. PS+ TWAS+ 0.5 FOGP+ 0.5 FOGL 32% 51% − 7% 10% 3.62 (17%)

12 PS + TWAS + FOG + FOG 27% 43% 11% 18% 4 23 (29%)12. PS + TWAS + FOGP + FOGL 27% 43% − 11% 18% 4.23 (29%)

13. PS + TWAS + C + FOGP 24% 38% 25% 14% − 3.48 (14%)

14. PS + TWAS + C + FOGL 22% 35% 23% − 20% 3.75 (20%)

15. PS+WAS+C +0.5FOGP +0.5FOGL 23% 36% 24% 7% 10% 3.62 (17%)

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16. PS + TWAS + C + FOGP + FOGL 20% 31% 20% 11% 18% 4.23 (29%)

1 kg/m3 = 0.0625 lb/ft3

Biogas and Methane Generation Curves Generated for ReactorsCurves Generated for Reactors

500

600

350

400

450

300

400

l Gas

(mL)

200

250

300

350

hane

(mL)

100

200Tota

50

100

150Met

h

00 10 20 30 40 50 60 70 80 90 100 110 120

Time (Days)

00 10 20 30 40 50 60 70 80 90 100 110 120

Time (Days)

Seed DP Reference PSSeed DP Reference PS

TWAS Cake FOGPFOGL PS+TWAS PS+TWAS+Cake

PS+TWAS+FOGP PS+TWAS+FOGL PS+TWAS+0.5FOGP+0.5FOGLPS+TWAS+FOGP+FOGL PS+TWAS+Cake+FOGP PS+TWAS+Cake+FOGL

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PS+TWAS+FOGP+FOGL PS+TWAS+Cake+FOGP PS+TWAS+Cake+FOGL

PS+TWAS+Cake+0.5FOGP+0.5FOGL PS+TWAS+Cake+FOGP+FOGL

Assumed complete degradation of components within 120 days

The Methane Production of the Components Was CalculatedComponents Was Calculated

SampleReactor

Seed PS TWAS Cake FOGP FOGL

Biogas produced, mL @ 35oC 68.0 342.3 164.0 198.0 490.0 539.5

Methane produced, mL @ 35oC 45.9 237.0 118.6 146.4 367.6 402.4

Methane, % 67.5 69.2 72.3 73.9 75.0 74.6

Biogas produced, L @ STP/kg component VS addedd 680 248 335 1,324 1,177

Methane, L @ STP/kg component VS addedd 470 179 247 993 878

Normalized methane, L @ STP/kg component VS addedd 2.6 1.00 1.4 5.5 4.9

Methane L @ STP/kg component VS destroyedd 830 767 928 1 404 1 121Methane, L @ STP/kg component VS destroyedd 830 767 928 1,404 1,121

Normalized methane, L @ STP/kg component VS destroyedd 1.1 1.00 1.2 1.8 1.5

Biogas produced, L @ STP/kg component TS addedd 536 163 217 1,278 897

Methane L @ STP/kg component TS addedd 370 118 160 958 669Methane, L @ STP/kg component TS added 370 118 160 958 669

Normalized methane, L @ STP/kg component TS addedd 3.1 1.0 1.4 8.1 5.7

Methane yield for FOG samples compared to the TWAS sample was

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Methane yield for FOG samples compared to the TWAS sample was about 5 times higher on a VS basis and was about 8 times higher on

a TS basis for FOGP

FOG and Sludge Destruction

0.9

1.0

0.7

0.8

D D

estro

yed

PSTWAS

0 4

0.5

0.6

grad

able

CO TWAS

CakeFOGPFOGLk = 0.20 1/d

0.2

0.3

0.4

actio

n of

Deg k = 0.15 1/d

k = 0.10 1/dk = 0.05 1/dk = 0.04 1/dk = 0.03 1/d

0.0

0.1

0 10 20 30 40 50 60 70 80 90 100 110 120

Fra

k = 0.02 1/d

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Time (Days)

Detention Time

Total VFATotal VFA

3000 3500 4000

VFA (m

Control

FOG

VFA

m

10001500 2000 2500 (

gCOD/L)

FOGmg

COD

0 500

1000

0 5 10 15 20 25 30

D

/

l

0 5 10 15 20 25 30Time (days)

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FOG Research General Findings

1. Rates of Destruction: FOGL ~ FOGP ~ PS > TWAS

2. Following an initial period of 3 to 5 days, FOG degradation followed approximately first-order degradation followed approximately first-order kinetics with a rate constant in the range of 0.10 to 0.1590% FOG d t ti h d ithi 18 d 3. 90% FOG destruction reached within ~ 18 days batch digestion

4. TWAS: The first 25% destruction was fast (~ S e st 5% dest uct o as ast (0.10 1/d), then very slow (~ 0.02 1/d), indicating a very large refractory fraction (significant aerobic digestion occurs during high-SRT aeration

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aerobic digestion occurs during high SRT aeration at high mixed liquor temperature)

Two-Phase Di ti

Two-Phase Di ti

Design Considerations

Design Considerations

Digestion OverviewDigestion Overview

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Design Considerations

1 Volume of grease per day1. Volume of grease per daya. Grease holding tank sizeb. VS loading of digesterg g

2. Percent grease/water in truck load

3 Grease conversion to digester gas3. Grease conversion to digester gasa. Cubic-feet (cf) per pound (lb) VS feedb. BTU content of gasb. BTU content of gas

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Design Considerations

1 Digester mixing requirements – fear of 1. Digester mixing requirements fear of grease collection at top of digester

2. Grease holding tank mixing (chopper G ease o d g ta g (c oppepump)

3. Heating may not be requiredg y q4. FOG metering into digester5. Odor5. Odor

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Design Considerations

1 Capital cost1. Capital cost2. How to get it built3 Intake screen or grinder3. Intake screen or grinder4. Two access manways5 Liquid decanting?5. Liquid decanting?6. Hauler rinse system7 Overfill alarms7. Overfill alarms

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Two-Phase Di ti

Two-Phase Di ti

InstallationsInstallationsDigestion OverviewDigestion Overview

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Pinellas County FLPinellas County FLPinellas County, FLPinellas County, FL

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Pinellas - Polymer FOG Dewatering

FOG is Received and FOG is Received and Dewatered at the County Solids Waste FOGFacility Using Polymer Addition and Overnight

FOG Dewatering

ScreenContainers

and Overnight Gravity Drainage

Dewatered FOGDewatered FOG Transportation

Container

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Pinellas - FOGp - Dewatering

FOG is Dewatered from 2 to 4 Percent Solids to 30 to 40 Percent SolidsSolids to 30 to 40 Percent Solids

FOG As Received FOG As Received From HaulersFrom Haulers Dewatered FOGDewatered FOG

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Pinellas - FOGp – Polymer Dewatering

FOGFOG Dewatering

ScreenContainers

Dewatered FOGDewatered FOG Transportation

Container

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Pinellas - FOGp – Polymer Dewatering

FOGFOG Dewatering

ScreenContainers

Dewatered FOGDewatered FOG Transportation

Container

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Pinellas - FOGp Receiving System1. Desire to reduce NG purchase for dryer2. Need to get rid of FOG

FOGFOG Dewatering

ScreenContainers

Dewatered FOGDewatered FOG Transportation

Container

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Pinellas - FOGp Receiving

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Pinellas - FOGp - Off Loading

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Pinellas - FOGp - Unloading

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Pinellas - FOGp - Tank

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Pinellas - FOGp- Pumps & Piping

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Pinellas - FOGp - Feed Pump

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Pinellas - FOGp- Needed Heater

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Pinellas - FOGp - Heat Tracing

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Pinellas - FOGp - Odor Control

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Pinellas - FOGp - Level Measurement

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Pinellas - FOGp - Gas Metering

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Pinellas - FOGp - Tank & Controls

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Pinellas – FOGL - Dewatering

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Pinellas - FOGL - Dewatering

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Pinellas - FOGL - Cake

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Pinellas - FOGL - Cake

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Watsonville CAWatsonville CAWatsonville, CAWatsonville, CA

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Watsonville, CA

Project Purpose:j p1. Increase digester

gas production2. Accept grease

hauler truck loads –restaurant grease traps and other sourcessources

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Watsonville - Unloading

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Watsonville - Receiving Tank

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Watsonville – Cost Savings

Grease Natural Gas Total Year

Grease Revenue

Natural Gas Savings

Total Savings

2002 $0 $0 $0

2003 $34,000 $61,000 $95,000$ , $ , $ ,

2004 $69,000 $118,000 $187,000

2006 $85,000 $145,000 $230,000

2006 $59,000 $129,000 $188,000

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Totals $247,000 $453,000 $700,000

Millbrae CAMillbrae CAMillbrae, CAMillbrae, CA

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Millbrae, CA

1 City decided 1. City decided to work with Chevron

2. Total Energy recoverya. Receivingb. Digestion

C ic. Cogeneration

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Milbrae, CA -Millbrae – Off Site Unloading

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Milbrae, CA -Millbrae – Rock Trap

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Milbrae, CA -Millbrae - Grinder

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Milbrae, CA -Millbrae - Odor Control

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Volatile Solids Loading RateMillbrae – Level Measurement

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Milbrae, CA -Millbrae – Gas System y

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Millbrae –Turbine

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F CAF CAFresno, CAFresno, CA

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Fresno - FOG - Receiving

1 Plan for large loadings – 3 – 15,000 tanks1. Plan for large loadings 3 15,000 tanks2. Off load from both sides simultaneously ,

up to 3 trucks at a time.up to 3 t uc s at a t e3. Mix with primary sludge in tanks so they

can continue with current sludge feed gsystem

4. Pump mixing

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Fresno - FOG - Receiving

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Fresno - FOG - Receiving

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Fresno - FOG - Receiving

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QUESTIONS?Bob Gillette

[email protected] 565 4888

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