experiment 10 group 6 ken caceres christian daroya rubycor duran jomari galecio jessa pilorin...
TRANSCRIPT
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Experiment 10
Group 6Ken CaceresChristian DaroyaRubycor DuranJomari GalecioJessa Pilorin
SOLUBILITY
BSBIO1A
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Objectives:
1. To define solubility2. To identify the factors affecting
it3. To use the solubility class
diagram competently
GO TO TEST COMPOUNDS
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SolubilityIt describes the amount of one
substance (solute) that will dissolve in a specified amount of another substance (solvent) under stated conditions
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Solute - A minor component of a solution.
Solution - A homogeneous mixture.
Solvent - The major component of a solution.
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Soluble – that can be dissolvedEx. Ethanol and waterInsoluble – cannot be dissolvedSlightly soluble - A very small
amount will dissolve and the solution will be transparent
ex. Pentane and water
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SolubilityPhenomenon: Like dissolves likePolar solute dissolves polar solvent Ex. NaCl is soluble in waterNonpolar solute dissolves nonpolar
solventEx. Pentane and benzeneFactors1. Van der Waals forces2. Dipole forces between polar molecules3. Hydrogen bonding4. Branching in some compounds5. Functional groups
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1. Van der Waals Forces (VWF)
These are forces between 2 nonpolar compounds
Non-polar liquids dissolve to each other because of VWF
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Ion-induced dipole attraction
a type of VWF which is a weak attraction that results when the approach of an ion induces a dipole in an atom or in a nonpolar molecule by disturbing the arrangement of electrons in the nonpolar species.
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2. Dipole – dipole interaction
Forces between 2 polar compounds
Cause of polar liquid’s solubility to each other
Positive and negative ends attract each other
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3. H Bondingthese occur
between polar covalent molecules that possess a hydrogen bonded to an extremely electronegative element, specifically - N, O, and F
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Lower alcohols (low MW) are soluble in water because the attraction between the OH (hydroxyl group) of water and alcohol are similar to those between individual water / alcohol molecules
= Hydrogen bond
= Oxygen= Hydrogen
Legend:
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Increase in carbon chain length, in high- molecular weight alcohols, decreased water solubility
This is because the strength of VWF increases with the increasing chain length
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Branching in some compounds favors solubility in waterBecause branched carbon chains
will not allow close approach of the branched molecules
Thus leading to a decreased VWF and an increased H bonding
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Functional groupsSolubility in water indicates the
presence of OH groupSolubility in a basic solvent
(NaHCO3) indicates the presence of an acidic functional group
Ex. Solubility of benzoic acid in NaHCO3 with –COOH (carboxyl group) as functional group.
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Solubility Class of Organic Compounds
= determines the possible functional
group classes to which the
unknown may belong
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SOLUBILITY TEST ANALYSIS:
S1 S2
These are very polar compounds which consist of salts of carboxylic acids or amines.
It is also possible the compound is of low molecular weight and has many polar functional groups such as a carbohydrate.
Low mol. Wt. (MW) amines
These compounds are low molecular weight (generally less than 5 carbons) with a polar functional group such as carboxylic acid, amine, alcohol, aldehyde, or ketone.
Low MW carboxylic acids
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SOLUBILITY TEST ANALYSIS:
A1 A2
Higher molecular weight carboxylic acids fall into this class.
Strong acids
Phenols show this kind of solubility.
Weak acids
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SOLUBILITY TEST ANALYSIS:
B1 N1
Primary, secondary and tertiary amines fall into this class.
However, if there are two or more phenyl groups on the nitrogen, the amine will probably not be basic enough to form the salt and will, then, be insoluble.
These are higher molecular weight compounds (generally more than 9 carbons) containing an oxygen atom.
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N2 INERT
These are medium size molecules (generally containing from 5 to 9 carbons) containing an oxygen atom.
These are neutral compounds. Alkyl halides and alkanes fall into this class.
SOLUBILITY TEST ANALYSIS:
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Test Compounds
N-propyl alcohol
Naphthalene
Urea
Aniline
Benzoic Acid
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Urea
Molecular Formula
Structural Formula
Commonname
Properties
CO(NH2)2
Carbamide resin
Isourea
MW: 60.06g/mol
Appears as a white solid
MP:133-135°C
NH2
CNH2
O
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Urea Distilled H2O soluble
Ether Insoluble
NaOH Soluble
NaHCO3 Soluble
HCl Soluble
H2SO4 Soluble
H3PO4 soluble
Solubility Class S2
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Benzoic acid
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IUPAC Name
CommonName
Molecular Formula
Structural Formula
Benzoic acid
Benzene-carboxylic acid
C7H6O2
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Benzoic acid and distilled water
Insoluble to cold water but can be soluble to hot water
Water-solubility of carboxylic acids decrease as the number of carbons increase. In case of benzoic acid, the molecule contains seven carbons and six of them form a benzene ring.
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Benzoic acid and Ether
SolubleBenzoic acid
is soluble in ether due to the low polarity of its molecules and weak intermolecular forces.
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Benzoic acid and NaOHSolubleNaOH helps
deprotonate benzoic acid
organic acids (such as carboxylic acids) react with bases to form water soluble salts
Either strong/weak acid
R-COOH + Na+ + OH- + H2O → R-COO- Na+ + OH- + H3O+
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Benzoic Acid and NaHCO3solubleNaHCO3 is a weak
base that reacts with organic acids to form water soluble salts
Solubility to NaHCO3 makes it a strong acid or Class A1
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Benzoic Acid and HClInsolubleHCl cannot
dissolve benzoic acid because it is a nonpolar compound.
Benzoic acid can’t loose a proton (H+) just like HCl
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Benzoic Acid and H2SO4InsolubleH2SO4 cannot
dissolve benzoic acid because it is a nonpolar compound.
Benzoic acid can’t loose a proton (H+) just like H2SO4.
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Benzoic Acid and H3PO4InsolubleH3PO4 cannot
dissolve benzoic acid because it is a nonpolar compound.
Benzoic acid can’t loose a proton (H+) just like H3PO4
Back to Test Compounds
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