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PLASTiCE International Launch Conference Europe for sustainable plastics Bologna, Italy, October 24-25 2011 This project is implemented through the CENTRAL EUROPE Programme co- financed by the ERDF MAMbo Museo d'Arte Moderna di Bologna Via Don Giovanni Minzoni, 14—Bologna

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Page 1: Europe for sustainable plastics - conference eBrochure

PLASTiCE International Launch

Conference

Europe for

sustainable

plastics

Bologna, Italy, October 24-25 2011

This project is implemented through the

CENTRAL EUROPE Programme co-

financed by the ERDF

MAMbo

Museo d'Arte Moderna di Bologna

Via Don Giovanni Minzoni, 14—Bologna

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Foreword

Dear Friends and Colleagues,

On behalf of the PLASTiCE project partnership it is my sincere pleasure to wel-come you at the PLASTiCE Launch Conference “Europe for Sustainable Plastics”.

The conference will address the issue of plastics sustainability by giving an over-view of ongoing activities in this field, particularly those funded from European sources.

Sustainability is of course a loosely defined subject but very much parallel to the general objective we are all working for – to reduce the environmental burdens resulting from the great success of plastic materials that has lead to an apparently ever-increasing use of these materials. But there are many ways to follow this goal and only future will show how successful and determined we will be.

In addition to rational use and optimal reuse of plastics a long-term approach to improved sustainability is to make plastics that are integrated with natural cycles. This approach is allowed by bioplastics incorporating the use of renewable re-sources and ultimate biodegradability.

Our conference should highlight cutting edge developments in this area and will hopefully provide some answers to open issues. In particular it should provide sup-port for a stronger push in this direction in Central Europe. Central Europe is at a crossroads: it has great knowledge and potential in the field, but the potential re-mains unrealized. It is in our interest to support a decisive shift in the region toward higher sustainability by joining scientific and industrial development.

Our conference is also a contribution to the celebration of the international year of chemistry and it is almost symbolic of our dependence on the continuous develop-ment of knowledge that it is organized in the beautiful city of Bologna, which is the proud home to the first and oldest continuously operating University in the world.

Finally I would like to thank all participants and presenters for their contributions and I wish that we may achieve our common goals.

Andrej Kržan

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Conference Agenda

October 24th 2011

9:00 Welcome coffee and registration of participants

10:00-10:30 Opening of the Conference,

Antonella LIBERATORE, Emilia-Romagna Region, Territorial Coorperation office

Giuseppe CONTI - Head of Research Office, University of Bologna

Andrej KRŽAN - PLASTiCE Coordinator, National Institute of Chemistry, Ljubljana, Slovenia

10:30-11:00 Introduction to sustainable plastics

Past EU Activities Re Sustainable Plastics - Gerhard BRAUNEGG (Graz University of Technology, AT)

11:00-11:20 Coffee Break

11:20-13:00 Session One

11:20-11:40 Turning polysaccharides into plastics. Some European Polysaccharide Network of

Excellence (EPNOE) results - Patrick NAVARD (Armines-Mines Paris Tech-CNRS, FR)

11:40-12:00 SURFUNCELL: Surface functionalization of cellulose matrices using cellulose

embedded nano-particles - Volker RIBITSCH (Graz University, AT)

12:00-12:20 BIOMASA: Utilization of Biomass for the preparation of environmentally friendly

polymer materials - Andrzej OKRUSZEK (Technical University of Lodz, PL)

12:20-12:40 WHEYLAYER: The "Whey" forward for the plastics industry - Robert CARROLL (Pimec, ES)

12:40-13:00 MARGEN: New generation of the polymeric packaging materials susceptible to organic recycling- Marek KOWALCZUK (Polish Academy of Science Centre of Polymer and Carbon Materials,PL)

13:00-14:00 Lunch

14:00-15:40 Session one continues

14:00-14:20 ANIMPOL: From Animal waste to PHA-Bioplasics - Martin KOLLER (Graz University of Technology, AT)

14:20-14:40 BIOPOL: Technology of biodegradable polyesters production from renewable resources - Andrzej DUDA (Polish academy of Sciences, PL)

14:40-15:00 ECOSHELL: Bio-materials for structural use in car application - Alain de LARMINAT, Kambiz KAYVANTASH (Citi Technologies, FR)

15:00-15:40 Recent developments in Bioplastics in the frame of AIMPLAS FP6 and FP7 Projects:

PICUS, NATEX, BUGWORKERS, HYDRUS, PLA4Food - Liliana CHAMUDIS (AIMPLAS, ES)

15:40-16:00 Coffee break

16:00-17:40 Session two

16:00-16:20 ECOPACK: Improvement of green labels for packaging and mulching plastics based on application of innovative (eco)toxicological tests for the safe recovery of material

wastes - Daniel RIBERA (BioTox, FR)

16:20-16:40 REBIOFOAM: Development of a flexible and energy-efficient pressurised microwave heating process to produce 3D-shaped Renewable BIO-Polymer FOAMs for novel

generation of transportation packaging - Federica MASTROIANNI (Novamont, IT)

16:40-17:00 HORTIBIOPACK: Development of innovative bidegradable packaging system to improve shelf life, quality and safety of high-value sensitive horticultural fresh produce - Demetres BRIASSOULIS (Agricultural University of Athens, GR)

17:00-17:20 Construction and outfitting of Center of Bioimmobilisation and innovative Packaging materials - Artur BARTKOWIAK (Center of Bioimmobilisation and Innovative Packaging Materials, PL)

17:20-17:40 ECOBIOCAP: ECOefficient BIOdegradable Composite Advanced Packaging - Natalie GONTARD (Joitn Research Agro-Polymers Engineering and Emerging Technologies , FR)

19:30 Dinner

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Conference Agenda

October 25th 2011

09:20-11:00 Session three

09:20-09:40 Development of Biobased/Biodegradable/Compostable Nanocomposite Mulching Films - Erhan PISKIN (Ahcettepe University and Biyomedtek,TR)

09:40-10:00 The new assortment of biodegradable products for agriculture developed in a frame of the realisation of BIOGRATEX project -Technologies and Properties - Izabella KRUCINSKA (Technical University Lodz, PL)

10:00-10:20 BIOAGROTEX: Development of new agrotextiles from renewable resources and with a

tailored biodegradability - Stijn MONSAERT (Centrexbel, BE)

10:20-10:40 BIOMASS WASTE - A source of raw materials and energy - Matjaž KUNAVER (PoliMaT, SI)

10:40-11:00 FORBIOPLAST: Bio-composites based on forest derived materials and biodegradable

polymers - Andrea LAZZERI (University of Pisa, IT)

11:00-11:20 Coffee break

11:20-13:00 Session four

11:20-11:40 MARINECLEAN: Marine debris removal and preventing further litter entry - Janez NAVODNIK (PoliEko, SI)

11:40-12:00 BIOCHEM: Eco-IP Partnership for Driving Innovation in the Sector of Bio-based Products - Maria Grazia ZUCCHINI (Aster, IT)

12:00-12:20 NOVAMONT - Federica MASTROIANNI (Novamont, IT)

12:20-12:40 MIREL - Stanislaw HAFTKA (Telles, NL)

12:40-13:00 ASSOBIOPLASTICHE - David NEWMAN (Assobioplastiche, IT)

13:00-14:00 Lunch

14:00-15:00 Session five

14:00-14:20 ECOCORTEC - Ivana RADIC BORSIC (Ecocortec, HR)

14:20-14:40 ECOZEMA - Armido MARANA (Ecozema, IT)

14:40-16:00 Round table - Conclusions, Recommendations, Follow up

16:00-17:00 Giuded tour of the Museum

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About the Conference

Europe for Sustainable Plastics is an international conference organized as the

Launch Conference of the PLASTiCE (Innovative Value Chain Development

for Sustainable Plastics in Central Europe) project, which started in April 2011

within the Central Europe programme.

In Central Europe, Europe and beyond there are currently a number of ongoing

projects dealing with the broader issue of sustainable plastics. In addition there are

also numerous activities carried out by companies and associations working to pro-

mote the wider use of sustainable plastics. These activities range from basic sci-

ence to the development of marketable applications. The Europe for sustainable

plastics conference was planned to join these actors in one focused event and give

them an opportunity to present their work and forward views.

By this we hope to provide a much needed snapshot of the current situation and a

de facto overview of the developing trends in bioplastics and other modern, sustain-

able plastic materials and solutions. The conference should help in realizing im-

portant synergies but also to point out the unresolved challenges still waiting

ahead. The results of the conference will be widely distributed after the event is

finished thus reaching an audience much greater than that present in Bologna.

The program of the conference consists of more than 25 presentations of the cur-

rent state-of-the-art by:

national and international R&D project coordinators/representatives giving

their views on the topic from the scientific/academic and potential application

development viewpoint;

industry representatives presenting their current successes and future goals

as well as their view of future trends (environmental view, market view);

NGO representatives working within the environmental sector to promote

the use of sustainable plastics.

The contributions cover the development of novel materials for various applications

such as packaging, agriculture, textiles etc. indicating the expected wider ac-

ceptance of these materials in the future. We expect that the conference will be an

opportunity to identify new synergies between projects and institutions that may

ease the process of making solid advances. In addition the aggregate view will al-

low us to identify the trends, and more importantly the barriers that still exist and

limit the wider use of new sustainable plastics and that we should overcome in the

future.

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About PLASTiCE

The international project PLASTiCE - Innovative value chain development for

sustainable plastics in Central EuropeInnovative value chain development

for sustainable plastics in Central Europe started in April 2011 within the Cen-

tral Europe Programme. It brings together 13 partners from 4 countries (Italy, Slo-

vakia, Slovenia and Poland) that represent the entire value chain from production

to waste management and enjoys a strong support from institutions of knowledge.

The PLASTiCE project has as its objective to promote new environmentally

friendly and sustainable solutions, particularly biodegradable plastics, in the pack-

aging and end-user industry. This will be achieved through information dissemina-

tion and by identifying and removing barriers to the faster and more widespread

use of sustainable types of plastic, particularly biodegradable plastics and plastics

based on renewable resources, in Central Europe.

Among the most important project objectives are:

raising awareness among target groups including general public on the issue

of biodegradable plastics

improving technology transfer and knowledge exchange mechanisms with end

-user industries

improving access to scientific knowledge and the use of already existing

knowledge as well as adapting it to the requirements of biodegradable poly-

mer and plastics producers

intensifying application-oriented cooperation between research and industry.

The project is following these objectives by dissemination of information through

National Information Points that will be established in all participating countries,

as well as through targeted events. We are conducting an analysis of market ex-

pectations and case studies of the value chain that will be the basis for the devel-

opment a Transnational Advisory Scheme and proposing a Roadmap for Joint

R&D Scheme, which will to intensify application-oriented cooperation between

research and industry.

These actions are tailored, but not limited, to the particular needs of Central Eu-

rope with its specific situation The region possesses relatively strong centres of

knowledge on biodegradable materials but lags in the application of such materi-

als as well as production and commercial activity linked to them. By joining and

combining the R&D potential from different countries this project has a well-

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About PLASTiCE

rounded scientific support that is being applied to addressing these shortcom-

ings.

Through the combined effect of information, regulatory support and by involving

the complete value chain contribution (research, producer, converter, end user)

the project will contribute to overcoming current obstacles to the wider use of

sustainable plastics use in Central Europe and through the lessons learnt else-

where as well.

(www.plastice.org)

PROJECT PARTNERS

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About CENTRAL EUROPE

CENTRAL EUROPE is an EU programme that encourages transnational cooper-

ation among the countries of Central Europe to improve innovation, accessibility

and the environment and to enhance the competitiveness and attractiveness of

cities and regions.

The CENTRAL EUROPE programme invests € 231 million to provide funding to

projects carried out in partnership involving national, regional and local institu-

tions from Austria, the Czech Republic, Germany, Hungary, Italy, Poland, the

Slovak Republic and Slovenia.

The CENTRAL EUROPE programme area covers about 1,050,000 square kilo-

metres, an area that is approximately a fifth of the EU landmass. About 148 mil-

lion citizens or 28 percent of the EU population live in this area. CENTRAL EU-

ROPE is financed by the Euro-

pean Regional Development

Fund and runs from 2007 to

2013.

The programme area is char-

acterised by a high population

density as well as a high de-

gree of urbanisation, with 73

percent of the population living

in cities or urban areas. Its

economy shows high dispari-

ties with regard to income and

living standards: Besides en-

compassing some of Europe’s

richest regions, CENTRAL

EUROPE also includes some

of Europe’s poorest ones.

CENTRAL EUROPE aims to contribute to reducing these differences through

cooperation between regions, working towards joint solutions to common prob-

lems and actions that harness the regions’ potential. The programme should

also help to strengthen the overall competitiveness by stimulating innovation and

promoting excellence throughout Central Europe.

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Abstracts and Posters

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Presentations in alphabetic order of speakers

CONSTRUCTION AND OUTFITTING OF CENTER OF BIOIMMOBILISATION AND INNOVATIVE

PACKAGING MATERIALS; BARTKOWIAK, Artur (Center of Bioimmobilisation and Innovative Packaging

Materials, Poland)

HORTIBIOPACK- DEVELOPMENT OF INNOVATIVE BIDEGRADABLE PACKAGING SYSTEM TO

IMPROVE SHELF LIFE, QUALITY AND SAFETY OF HIGH-VALUE SENSITIVE HORTICULTURAL

FRESH PRODUCE; BRIASSOULIS, Demetres (Agricultural University of Athens Department of Natural

Resources and Agricultural Engineering, Greece)

Abstract, Poster

WHEYLAYER - THE »WHEY« TO SUSTAINABLE PACKAGING; CARROLL, ROBERT, Pimec (The SME

association of Catalunya, Spain)

Abstract, Poster

RECENT DEVELOPMENTS IN BIOPLASTICS IN THE FRAME OF AIMPLAS FP6 AND FP7

PROJECTS; CHAMUDIS, Liliana (AIMPLAS, Spain)

Abstract, Poster1, Poster2, Poster3, Poster4, Poster5

BIOPOL- TECHNOLOGY OF BIODEGRADABLE POLYESTERS PRODUCTION FROM RENEWABLE

RESOURCES; DUDA, Andrzej (Centre of Molecular and Macromolecular Studies, Polish Academy of Science,

Poland)

Abstract

ECOBIOCAP- ECOEFFICIENT BIODEGRADABLE COMPOSITE ADVANCED PACKAGING;

GONTARD, Natalie (Joint Research Unit Agro-polymers Engineering and Emerging Technologies, France)

Abstract

ANIMPOL - FROM ANIMAL WASTE TO PHA-BIOPLASTICS ; KOLLER, Martin (Graz University of

Technology, Austria)

Abstract, Poster

MARGEN-NEW GENERATION OF THE POLYMERIC PACKAGING MATERIALS SUSCEPTIBLE TO

ORGANIC RECYCLING; KOWALCZUK, Marek (Polish Academy of Science Centre of Polymer and Carbon

Materials, Poland)

Abstract, Poster

THE NEW ASSORTMENT OF BIODEGRADABLE PRODUCTS FOR AGRICULTURE DEVELOPED IN

A FRAME OF TEH REALISATION OF BIOGRATEX PROJECT -TECHNOLOGIES AND PROPERTIES;

KRUCINSKA, Izabella (Technical University of Lodz, Department of Material and Commodity Sciences and Textile

Metrology, Poland)

Abstract

BIOMASS WASTE – A SOURCE OF RAW MATERIALS AND ENERGY; KUNAVER, Matjaž (Center of

Excellence PoliMaT, Slovenia)

Abstract

ECOSHELL- BIO-MATERIALS FOR STRUCTURAL USE IN CAR APPLICATION; de LARMINAT, Alain

(CITI Technologies, France)

Abstract, Poster

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FORBIOPLAST– BIO-COMPOSITES BASED ON FOREST DERIVED MATERIALS AND

BIODEGRADABLE POLYMERS; LAZZERI, Andrea (University of Pisa, Department of Chemical Engineering,

Italy)

Abstract

REBIOFOAM -DEVELOPMENT OF A FLEXIBLE AND ENERGY-EFFICIENT PRESSURISED

MICROWAVE HEATING PROCESS TO PRODUCE 3D-SHAPED RENEWABLE BIO-POLYMER

FOAMS FOR NOVEL GENERATION OF TRASPORTATION PACKAGING; MASTROIANNI, Federica

(Novamont SpA, Italy)

Abstract

BIOAGROTEX- DEVELOPMENT OF NEW AGROTEXTILES FROM RENEWABLE RESOURCES AND

WITH A TAILORED BIODEGRADABILITY; MONSAERT, Stijn (Centrexbel, Belgium)

Abstract

TURNING POLYSACCHARIDES INTO PLASTICS. SOME EUROPEAN POLYSACCHARIDE

NETWORK OF EXCELLENCE (EPNOE) RESULTS; NAVARD, Patrick (Armines-Mines ParisTech -CNRS,

France)

Abstract, Poster

MARINECLEAN- MARINE DEBRIS REMOVAL AND PREVENTING FURTHER LITTER ENTRY;

NAVODNIK, Janez* and Pogač, Vladimir** (*Technology center PoliEko,**Turna, Slovenia)

Abstract

BIOMASA- UTILIZATION OF BIOMASS FOR THE PREPARATION OF ENVIRONMENTALLY

FRIENDLY POLYMER MATERIALS; OKRUSZEK, Andrzej (Technical University of Lodz, Poland)

Abstract

DEVELOPMENT OF BIOBASED/BIODEGRADABLE/COMPOSTABLE NANOCOMPOSITE

MULCHING FILMS; PIŞKIN, Erhan (Hacettepe University and Biyomedtek, Ankara, Turkey)

Abstract

ECOPACK- IMPROVEMENT OF GREEN LABELS FOR PACKAGING AND MULCHING PLASTICS

BASED ON APPLICATION OF INNOVATIVE (ECO)TOXICOLOGICAL TESTS FOR THE SAFE

RECOVERY OF MATERIAL WASTES; RIBERA, Daniel (BIO-TOX, France)

Abstract

SURFUNCELL- SURFACE FUNCTIONALISATION OF CELLULOSE MATRICES USING CELLULOSE

EMBEDDED NANO-PARTICLES; RIBITSCH, Volker (Universitaet Graz, Austria)

Abstract

BIOCHEM – ECO-IP PARTNERSHIP FOR DRIVING INNOVATION IN THE SECTOR OF BIO-BASED

PRODUCTS; ZUCCHINI, Maria Grazia (Aster, IT)

Abstract, Poster1, Poster2

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Development of innovative biodegradable packaging system to improve shelf life, quality and safety

of high-value sensitive horticultural fresh produce

Demetres Briassoulis

Agricultural University of Athens

[email protected]

Background

Equilibrium Modified Atmosphere Packaging (EMAP)

of Fresh Produce is increasingly used to extend shelf-life

of fresh produce. Increased EMAP usage coupled with

negative environmental views associated with

nondegradable synthetic packaging materials creates a

societal demand and a need of SMEs for

biodegradable films.

aims at developing innovative and safe biodegradable

Equilibrium Modified Atmosphere Packaging film sys-

tems based mainly on the use of environmental friendly

bio-based, biodegradable raw materials aiming at the

improvement of the shelf life, quality and safety of spe-

cific high value sensitive horticultural fresh produce.

Several research works are in progress worldwide aiming

at developing biodegradable packaging materials for var-

ious applications, including food packaging. A limited

portion of this research effort is dedicated to EMAP

packaging systems. The development of biodegradable

films that are based on renewable raw materials and de-

signed for EMAP systems for fresh produce, meeting the

design criteria of gas transport properties, ensuring safety

of the produce while maintaining its original quality,

firmness and colour is still at the very early stages of

research and development.

Objectives of HortiBioPack

Design biodegradable Equilibrium Modified

Atmosphere Packaging film systems to offer

optimal gas transport properties tailored to

achieve Equilibrium Modified Atmosphere Pack-

aging (EMAP) of high value fresh horticultural

produce through the development of new and

existing technologies.

Develop active and intelligent packaging sys-

tems which regulate the modified atmosphere

and actively interact to prevent spoilage through

modified nano-fillers against microbial action.

Develop compostable packaging systems,

mainly based on renewable raw materials,

CEN 13432 certified.

Optimise EMAP systems in terms of design

and low-cost, with enhanced mechanical and

physical behaviour through optimisation of the

processing parameters of low thickness film,

depending on the application

Two specific sensitive high value horticultural fresh pro-

duce representing fruits (peach) and vegetables (cherry

tomato) are considered.

Progress

During the first period of the project, the design require-

ments of two representative horticultural products

(cherry tomatoes and peaches) were studied with respect

to shelf lifetime, quality, and safety to consumers. The

optimal EMAP conditions for the two horticultural prod-

ucts (cherry tomatoes and peaches), selected as typical

examples, were determined by extensive full scale stor-

age experiments. All crucial parameters defining the op-

timal EMAP conditions were identified and quantified.

The mechanical, physical and chemical properties of

existing biodegradable materials were critically re-

viewed. Moreover, the European legal framework regu-

lating food packaging materials was critically reviewed.

After a systematic literature review and testing of exist-

ing biodegradable, bio-based films and taking into ac-

count the above results, PLA was selected as the packag-

ing material to be used for developing the new EMAP

system for cherry tomatoes and peaches.

Based on the design requirements already established for

cherry tomatoes and peaches, a new PLA based EMAP

with micro-perforations system was designed that meets

the corresponding requirements. Combined experimental

work and numerical simulations were used to design the

new system. In parallel the introduction of nano-particles

with antimicrobial action is under investigation with re-

spect to both the biological effect of such additives and

their compatibility to the matrix material.

Full scale experiments are in progress (peach for the

summer and early autumn period; cherry tomatoes for

late autumn period) for validating and optimising the

new EMAP system for cherry tomatoes and peaches.

Results already presented in the scientific community

and dissemination activities may be found in the web

page of the project: http://www.hortibiopack.aua.gr/

Expected final results

1. Design requirements for developing biodegradable

EMAP and selection of biobased biodegradable mate-

rials.

2. Design of micro-perforation in combination with

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membrane permeability characteristics to meet

EMAP requirements

3. Innovative biobased biodegradable film processing

technology

4. Novel nanotechnology systems for biodegradable

EMAP film

5. Prototypes: biodegradable EMAP solutions for peach

and cherry tomatoes; extension of the design to straw-

berries and arugula (or rucola).

The introduction of novel environmentally friendly pack-

aging materials in EMAP for fresh produce will boost

several high technology SMEs working in this field, and

reduce the negative environmental impact of the exten-

sive use of plastics in such applications.

Partnership

The project objectives are achieved by bringing together

research teams of high scientific quality with complimen-

tary expertise and experiences in the field, along with a

group of SMEs with complementarity in business inter-

ests and/or regional characteristics and applications all of

them targeting the development of innovative biode-

gradable packaging for fresh horticultural produce:

AUA - Agricultural University of Athens (EL)

Mach S.R.L. (I)

Advanced & NanoMaterials Research s.r.l. (I)

Irmatech (F)

Pacsystem AB Svenskt (S)

Ingino raffaele s.r.l. (I)

Alfa Beta Roto S.A. (EL)

CNR - National Research Council of Italy (I):

Institute of Polymer Chemistry and Technology

(ICTP-CNR)

Sassari Unit of Institute of Sciences of Food

Production (ISPA-SS)

Institute of Food Science (ISA)

UBS - University of South Brittany (F)

SIK - The Swedish Institute for Food and Biotechnol-

ogy (S)

Project Coordinator

Prof. Demetres Briassoulis

AGRICULTURAL UNIVERSITY OF ATHENS,

Department of Natural Resources & Agricultural Engi-

neering

75, Iera Odos Str., 11855 Athens, Greece

Tel.: +30.210.5294011, FAX: +30.210.5294023

E-mail address: [email protected]

Typical simulation of a laser micro-perforated film with

small WVTR

Experiments with peach packed in EMAP prototype bags

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Wheylayer: the whey to sustainable packaging

Robert Carroll

PIMEC: the SME association of Cataluyna

The whey forward to sustainable packaging

The WHEYLAYER Project is a 3 year industry driven

research and development project that is being funded

by the European Commission’s Seventh Framework

Programme under “Research for SME- Associations”.

The aim of the this cooperative research project was to

replace currently used synthetic oxygen-barrier layers

with whey protein coatings. Preliminary tests on the

oxygen permeation properties of whey-protein-coated

plastic films carried out to date have revealed that Whey

protein isolate (WPI) or concentrate (WPC) coating

solutions displayed excellent oxygen barrier properties

at low to intermediate Relative Humidity, comparable to

synthetic oxygen barriers and have showed great

promise in the potential of whey protein coatings for

replacing existing expensive synthetic oxygen barrier

polymers.

This present research project has built upon exiting

research in order to arrive at a commercially feasible

technique for developing whey coated plastic films,

without jeopardising the oxygen or moisture barrier

performance of conventional plastic films, while

increasing the recyclability of these plastics.

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Recent developments in Bioplastics in the frame of AIMPLAS FP6 and FP7 Projects

Presenter: Liliana Chamudis

AIMPLAS

[email protected]

This communication reports some of the current achieve-

ments in the field of bioplastics developed by AIMPLAS

in collaboration with industrial and research organisa-

tions in the frame of EU projects. The goals, research

areas addressed and results obtained are presented for

FP6 Project PICUS and FP7 Projects NATEX, HY-

DRUS, BUGWORKERS and PLA4FOOD. The research

is focused to improve characteristics and processing of

bioplastics (thermoplastic starch, PLA, or PHA/PHB) for

application in diverse industrial sectors such as packag-

ing, agriculture, electrical/electronic, white goods or

structural composites.

Projects:

Development of a 100 % Biodegradable

Plastic fiber to manufacture twines to

stake creeping plants and nets for pack-

aging agricultural products.

Project Type: EC FP6 Co-operative Research Project

(CRAFT). Horizontal Research Activities involving

SMEs

PICUS aimed to develop 100% biodegradable plastic

fibres to be used in two specific applications: a) Twines

used for staking and propping crops in greenhouses, and

b) nets for packaging low-weight (up to 5 kg) agricultur-

al, marine and non food products. PICUS objectives

were:

•To develop a fibre that fulfils the mechanical and ther-

mal demands of a traditional staking twine and packag-

ing net during the useful life span, but undergoing com-

plete biodegradation after harvest on composting condi-

tions (twines) and without their disposal problems (nets).

•To find an environmentally friendly solution for the

management of the plastic waste generated by plastic

twines and net.

•To contribute in overcoming the lack of technical expe-

rience that exists about flexible fibre manufacture with

biodegradable polymers.

The new plastic fibres obtained in PICUS fulfilled the

following criteria: 100% biodegradable (“on-farm com-

posted” or treated in composting plants (Municipal Solid

Waste System) after its useful life), hydrophobic, easy

cutting, easy processing, and low plastodeformation.

Figure 1. PICUS Twisted Staking Twines (left &PICUS Net in

tubular form (right).

Natural aligned fibres and textiles for

use in structural composite applica-

tions

Project Type: EC FP7 Collaborative Project (NMP)

targeted to SMEs

NATEX develops aligned textiles from natural fibres

suitable for use as high strength reinforcing fabrics to

produce structural composite parts using bio-based ther-

moplastics (PLA) and thermoset resins. NATEX main

objectives are:

•Development of aligned textiles from natural fibres that

are suitable to be used as high-strength reinforcing fab-

rics for the production of structural biocomposite materi-

als and components.

•To promote the use of natural fibres in structural appli-

cations where traditional materials are currently used; for

this purpose hemp and flax natural fibres are used.

•To make the shift from resource to knowledge intensive

industry through the development of advanced technical

textiles.

•To bring innovative developments in various areas: fibre

preparation, yarns manufacturing, fabric architecture,

polymer selection and modification, processing, joining

and finishing technologies, design of parts using CAD/

CAE tools, etc.

NATEX proves that natural fibres and textiles are a via-

ble solution and can be available for our society in the

near future. The new products – based on natural re-

sources – will offer competitive alternatives in structural

composite parts where nowadays materials from non-

renewable resources are used.

In the project, case studies are developed in four industri-

al sectors: transport systems (motor-cover and grit con-

tainer), energy systems (housing for solar and thermal

panels), agricultural systems (tractor floor) and ship-

building (boat access door).

Development of crosslinked flexi-

ble bio-based and biodegradable

pipe and drippers for micro-

irrigation applications.

Project Type: EC FP7 Capacities Research for the bene-

fit of SMEs (R4SME)

HYDRUS aims to develop plastic pipes and drips for

Figure 2:Microscopy

images of composite

plate made of PLA

reinforced with flax

fibre

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micro-irrigation systems produced

with bio-based and biodegradable

material which will maintain the

functional properties during their

lifespan and at the same time biode-

grade after use in composting con-

ditions. The developed pipes and drips fulfil the follow-

ing requirements:

•Mechanical properties ~ current PE pipes (reactive ex-

trusion, structural changes).

•Traditional plastic processing methods & conventional

agricultural machinery

•Completely biodegradable and not harmful afterwards

(soil/compost)

•Thermally, mechanically and chemically resistant and

inert

•Mechanically recyclable product

•Economically viable

The main results achieved in HYDRUS are:

•new biodegradable pipe/drip fulfilling micro-irrigation

systems requirements including biodegradability stand-

ards.

•Compound formulations, including the necessary addi-

tives and polymer blends, to ensure that the properties of

the final products are met.

•The understanding on reactive extrusion and structural

changes.

New Tailor-made PHB-based

nanocomposites for high per-

formance applications pro-

duced from environmentlly friendly production

routes

Project Type: EC FP7 Collaborative Project (NMP)

targeted to SMEs

BUGWORKERS project aims to develop a new cost-

competitive and environmentally friendly bionanocom-

posite material based on the combination of a polyhy-

droxybutyrate (PHB) matrix produced by new fermenta-

tion culture technology with two types of nanofibres,

cellulose whiskers and lignin-based, in order to have a

true alternative to engineering materials in two main sec-

tors: household appliances, computers and telecommuni-

cations. The project objectives are:

• to increase the PHB yield by high density fermentation

cultures and hydrolyzing sugars from agricultural waste

as the main feed stocks

• to develop 2 grades of PHB (homo- and co-polymer);

one with high crystallinity and high thermal and chemical

resistance, the other a co-polymer with improved flexibil-

ity and impact resistance

• to develop functionalised lignin-based nanofibres and

cellulose-whiskers obtained through enzymatic treat-

ments from renewable resources

• To develop compounding and processing technologies

with the aim of reducing material needs and improving

the end product properties

Figure 3. PHB synthesized by bacteria – final product

Active Multilayer Packaging based on Optimized

PLA formulations for Minimally Processed Vegeta-

bles and Fruits

Project Type: EC FP7 Capacities

R4SME

PLA4FOOD project is focused to the

development of innovative active and biodegradable

packaging for fresh-cut food products

based on renewable resources thermo-

plastic materials (PLA-polylactic acid)

functionalised with the synergic addition

of additives from natural sources

(antioxidants, antibacterial and antifun-

gal) in order to increase the shelf-life of

packed products. Different encapsulation

routes will be tested to protect active

additives from processing conditions and

to have controlled migration

rates. PLA4FOOD main objectives are:

to minimize PLA current limitations in flexibility,

water barrier properties and processability using dif-

ferent additives: bio-based lactic-acid plasticizers,

inorganic nanofillers and organic nucleants.

to develop co-extrusion techniques to achieve the best

cost/benefit ratio and optimal performance of the ac-

tive packaging by controlling the thickness and crys-

tallinity of each layer.

to produce new active and biodegradable packages

from renewable sources that will provide minimally

processed fresh-cut products adequate protection

against environmental agents, will improve product

properties (quality, shelf-life, microbiological safety

and nutritional values), and moreover, will degrade in

composting conditions according to the standard

UNE-EN 13432.AR

Partnerships:

These projects are coordinated by AIMPLAS in Spain

and carried out with the collaboration of industrial enter-

prises and research organisations round Europe..

Acknowledgements: The research leading to these re-

sults has received funding from the European Union

Sixth & Seventh Framework Programme (FP6/2002-

2006; FP7/2007-2013) under grant agreement numbers

17684 (PICUS), 214467 (NATEX), 246449

(BUGWORKERS) 262557 (PLA4FOOD), 231975

(HYDRUS)

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Technology of Biodegradable Polyesters Production from Renewable Resources - BIOPOL

Andrzej Duda and Stanislaw Slomkowski

Center of Molecular and Macromolecular Studies, Polish Academy of Sciences

Sienkiewicza 112, PL-90-363 Lodz, Poland

[email protected]

Project objective

The general objective of Biopol project is to carry out

strategic research and development of innovative techno-

logical solutions employing the renewable materials base

followed by creating new products assortment from the

resulting biodegradable polymers.

Biopol project aims also to meet the needs connected

with the necessity to use biodegradable materials in Po-

land. This is due to a common awareness of the im-

portance of the environment in a human life. Thus, ef-

forts are made to enable a development of environmen-

tally friendly polymeric high-tonnage products based on

new “clean technologies”. It is also possible to use biode-

gradable polyesters in the biomedical area, for example

in controlled drug delivery systems or as bioresorbable

implants.

Specific objectives

To develop production technologies of polylactide (PLA)

in the model research installation (PLA installation).

To develop production technologies of biodegradable

aliphatic-aromatic polyester (BPE) in the model re-

search installation (IBPE installation).

To implement the results of chemical modification of

PLA, IBPE, and PLA-IBPE blends and copolymers

To implement the results of processing of PLA, IBPE,

and PLA-IBPE.

To develop the projects of PLA, IBPE, and PLA-IBPE

based industrial goods.

Partners of the project

Center of Molecular and Macromolecular Studies of

the Polish Academy of Sciences in Lodz - the Project

coordinator

Research carried out at the Center encompasses funda-

mental problems of organic, bioorganic, and macromo-

lecular chemistry and physics. These studies include also

methods of designing modern, high-tech materials. The

earlier research led to development of the methods for

the synthesis of the biodegradable polyesters. Parallel

studies were performed allowing correlation of the poly-

esters microstructure with their performance behavior.

The Center is also currently participating in the imple-

mentation of complementary BIOMASA, BIOGRA-

TEX, and MARGEN projects, which together with BIO-

POL, shall lead to the elaboration of new technology:

beginning with renewable raw materials and finishing

with specialized products made from biodegradable poly-

esters.

Institute of Biopolymers and Chemical Fibers in Lodz

The Institute conducts research and carries out develop-

ment tasks leading to the implementation of the new so-

lutions in the area of synthesis, processing modification,

and use of biopolymers. Techniques and technologies for

production, processing and use of chemical fibers are

also being developed. The Institute is working on the

technology of one of the biodegradable polymers covered

by the BIOPOL project, as well as upon the implementa-

tion of tasks related to the BIOGRATEX and BIOMASA

projects.

Faculty of Chemistry, Warsaw University of Technol-

ogy

The Faculty belongs to the largest polytechnic faculties

of chemistry in Poland. Over 850 students at the under-

graduate level and nearly 110 Ph.D. students are educat-

ed. The main directions of research at the Faculty con-

cern fundamental problems of chemistry and are correlat-

ed with the needs of the economy of the country and of

the region in the widely understood area of the chemical

technology. Department of Chemistry and Technology of

Polymers is involved in the implementation of the BIO-

POL and MARGEN projects. The main activities of the

Laboratory of Technological Processes are to design, and

then to participate in the construction of experimental

installation of biodegradable polyesters.

Realization period

1st January 2009. – 31st December 2013

Project manager

Prof. Dr. Stanisław Slomkowski – Director of Center of

Molecular and Macromolecular Studies, Polish Academy

of Sciences in Lodz.

The Project is realized upon Contract Number

POIG.01.01.02-10-025/09 and co-financed by European

Union in the frame of the Operational Program – Inno-

vative Economy financed from the European Regional

Development Fund.

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EcoBioCAP

Ecoefficient Biodegradable Composite Advanced Packaging

Natalie Gontard

Joint Research Unit Agro-polymers Engineering and Emerging Technologies, France

Call: FP7-KBBE-2010-4

WP Topic addressed: KBBE.2010.2.3-01:

Development of biodegradable food packaging

Type of funding scheme: Collaborative project (small/

medium-scale research project)

Name of coordinating person: Prof. Nathalie Gontard

EcoBioCAP will provide the EU food industry with

customizable, ecoefficient, biodegradable packaging

solutions with direct benefits both for the environment

and EU consumers in terms of food quality and safety.

This next-generation packaging will be developed using

advanced composite structures based on constituents

(biopolyesters, fibres, proteins, polyphenolic compounds,

bioadhesives and high-performance bio-additives)

derived from food industry (oil, dairy, cereal and beer)

by-products only and by applying innovative processing

strategies (blends and multilayers at different scales) to

enable customisation of the packaging’s properties to fit

the functional, cost, safety and environmental impact

requirements of the targeted fresh perishable food (fruit

and vegetables, cheese and ready-to-eat meals).

Demonstration activities with SMEs and industrial

partners will enable the EcoBioCAP technology to be

optimised in terms stability, safety, environmental impact

and cost- effectiveness before full exploitation. The

development of a decision support system for use by the

whole packaging chain will make the EcoBioCAP

technology accessible to all stakeholders. Extensive

outreach activities will not only disseminate the project

results to the scientific community but also ensure that

consumers and end-users are informed of the usage

conditions and benefits of such bio-degradable packaging

and how it should be disposed of.

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Major Objectives

The project ANIMPOL (»Biotechnological conversion of

carbon containing wastes for eco-efficient production of

high added value products«) utilises waste streams from

slaughterhouses, the animal rendering industry and waste

fractions from conventional biodiesel manufacture for the

production of improved biodiesel (fatty acid esters, FAE)

and high-value biodegradable polymeric materials

(polyhydroxyalkanoates, PHA).

Significance of the Project: The Raw Materials

The entire amounts of animal lipids from the

slaughtering process in Europe can be quantified with

more than 500.000 t per year. According to the European

Biodiesel Board, the available saturated biodiesel

fraction from this waste amounts to annually 50.000 t.

This saturated FAE cause problems when used as fuel

due to its elevated cold filter plugging point which is

limiting in blends that exceed 20 vol.-% FAE. From the

saturated FAE, the amount of PHA biopolyesters that can

theoretically be produced amounts to about 35.000 t

annually, if calculated with a conversion yield of 0.7 g/g.

The surplus glycerol phase (CGP) from the biodiesel

production is estimated for Europe with annually

265.000 metric tons. If applied for production of

catalytically active biomass capable to produce PHA, one

can expect about 0.4 g biomass per g of glycerol.

Scientific Approach

PHA are produced from saturated FAE that can have a

negative effect on the properties of biodiesel when used

as engine fuel. Various techniques including

microbiology, genetics, biotechnology, mathematical

modelling of the bioprocesses, chemical engineering,

polymer chemistry- and processing are used to produce

these high-value biopolymers. These studies are

supported by process development, life cycle analysis

and feasibility studies covering the use of and the

marketing of the final products. Involving close

cooperation between academic and industrial partners,

the project aims to solve local waste disposal problems

affecting the entire EU. Fig. 1 illustrates the principles of

the project.

Status of development

Within the first half of the project, the focus of the

ANIMPOL activities was especially directed to the

allocation of raw materials by industrial project partners

and their characterization, and to the application of these

raw materials as carbon sources for the cultivation of

different microbial strains able to accumulate

polyhydroxyalkanoate (PHA) biopolyesters. Also

elaboarated was the optimization of the biotechnological

production of PHA from the respective raw materials by

selected strains, the enhanced downstream processing for

separation of biomass and product isolation, and the

characterization of the produced biomaterials. Based on

the obtained data, the process flow sheet for the

designing of an envisaged pilot scale plant for production

of PHA from the applied waste streams has been adapted

and enhanced; this adaptation is an evolutionary process

that still will go on until the end of the project. Based on

this process flow sheet, calculations are already available

underlining the economic viability of the process to be

developed and designed.

Considerable progress was achieved concerning the

production of fatty acid esters from animal waste lipids.

Here, several animal organs that constitute clearly

surplus materials without interfering with food and feed

purposes were investigated in detail concerning their

fatty acid profiles and converted towards different FAEs.

A lot of attention was devoted to such organs containing

special fatty acids acting as precursors for special PHA

building blocks. Here, also hydrolysis experiments were

carried out for the generation of precursors for special

PHA building blocks from different animal fractions.

The obtained esters were applied successfully as carbon

sources for microbial cultivation, aiming on the

production of PHA.

Fermentation protocols on laboratory bioreactor scale

have been developed for those production strains that,

according to the tests on laboratory scale, appeared to be

most promising during the first project period. Here, data

are available for the production of PHA homo- and co-

polyesters starting from the animal-waste derived carbon

sources glycerol and FAE together with the application

of special precursors for incorporation of desired co-

monomers into the PHA chains. In addition, a broad

The ANIMPOL Project: From Animal Waste to PHA-Bioplastics

Martin Koller, Anna Salerno, Alexander Muhr, Angelika Reiterer, Heidemarie Malli, Karin Malli, Gerhart

Braunegg

Institute of Biotechnology and Biochemical Engineering

Graz University of Technology, Austria

[email protected]

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number of kinetic analyses for discontinuous and

continuous PHA production processes were carried out

by mathematical modeling of the experimental data,

providing new insights in this complex topic.

Novel strategies were successfully tested to separate cells

from the liquid supernatant and to isolate the

biopolyesters from the surrounding cell mass. This was

done by applying biomasses and fermentation broths

containing high densities of PHA-rich cells. Here, the

minimizing of energy and solvent input was the target of

the conducted experiments.

A considerable quantity of work was already

accomplished in the characterization of the properties of

the produced biopolymers. Short chain length as well as

medium chain length PHA were produced by the groups

that are active in microbiology and biotechnology. The

PHA were analyzed by the responsible partners regarding

their material properties. The required feedback of these

data arrived promptly at the biotechnologists to adapt

their fermentation strategies.

Biodegradation tests in various environments were

carried out, accompanied by the assessment of the

ecological and toxicological impact of the materials.

In addition, a broad PHA-based composites were

successfully produced using novel, biobased filler

materials. To a certain extend they even constitute agro-

industrial waste streams which are now upgraded to the

role of value-added raw materials for novel plastic items.

Also the processing of large amounts of allocated PHA

was already started by the responsible industrial partners

in order to get novel insights in the melting and

processing behavior of these biomaterials.

Dissemination of the results as a central item of

ANIMPOL was done by a huge number of written and

oral publications in research journals, industrial journals

and books as well as at diverse conferences. In addition,

the concepts of ANIMPOL were already presented by a

radio station and in the Austrian television.

Expected Impacts:

The impacts of the project activities can be considered

from three aspects. Assuming the technological

activities, the project is expected to have a significant

impact in solving local waste problems affecting the

entire EU. Production of biodiesel and polymers will

have to compete with alternative treatments such as

composting, anaerobic digestion and extraction of other

added-value products. The actual impact will thus depend

on the relative investment required and the economic

value of the products. The production of biodiesel is not

so different to existing systems using recovered waste

fats and oil. Hence, actual impact will depend on the

development of the polymeric materials, which in turn

depends on success in manufacturing PHA at a

reasonable, competitive price; this will be followed by

manufacturing PHA-based products and establishing

new markets where they may be distributed. Due to

uncertainties at several levels the overall impact on

European animal waste processing is not ascertained.

Nevertheless, the project is expected to generate

interesting results leading to various commercial

opportunities, possibly favouring especially the

development of niche markets.

Expected Results

The project should result in cost-efficient and sound

alternative products for the polymer industry based on an

integrated industrial process that will also produce

biodiesel of improved quality. A biotechnological

fermentation process will be developed to convert

saturated FAE to PHA, followed by an environmentally

safe and efficient downstream process resulting in

various forms of PHA. They will be characterized in

terms of their chemical, biological, physical and

mechanical properties. The use of these materials in

preparation of blends and composites with selected

conventional polymeric materials as well as inorganic

and/or organic fillers will result in novel environmentally

favourable benign biodegradable plastics. Results from

feasibility and marketing studies will suggest specific

uses for these products. http://www.animpol.tugraz.at

Fig. 1: Process Diagramm of the ANIMPOL project

Unsaturated

fraction

ANIMAL

Rendering Industry Slaughterhouses

Meat-and-Bone-Meal (MBM) Surplus Lipids

Degreasing

Degreased MBM

Hydrolyzed

MBM

Hydrolysis

BIOTECHNOLOGICAL

PRODUCTION OF

PHAs

Saturated

fraction

Crude Glycerol

Phase (CGP)

Carbon source for

microbial growth and/or

low molecular mass

PHAs

Margaric Acid: Precursor for

production of odd-numbered

PHA building blocks

Industry with Waste Problem to

be Solved

Industry Searching for

Alternative Industrial Process

Polymer Industry

Processed Waste Materials to be Utilized

for Biotechnological PHA Production

Waste Materials Causing

Disposal Problem for Industry

PRODUCTS

Lipids

Transesterification for Fatty Acid

Alkyl Ester Production

(Biodiesel Industry)

Fatty Acid

Alkyl Esters

(Biodiesel)

Carbon source

for PHA

accumulation

HIGH QUALITY

BIODIESEL

EXPLANATION:

Carbon and

Nitrogen

source for

microbial

growth

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New generation of the polymeric packaging materials susceptible to organic recycling

Marek Kowalczuk

Polish Academy of Sciences Centre of Polymer and Carbon Materials, Zabrze

[email protected]

Acronym: MARGEN

http://margen.cmpw-pan.edu.pl/

Project is co-financed by Structural Funds as a part of

Operational Program INNOVATIVE ECONOMY for

the years of 2007-2013.

Proportional funds participation: EU Structural Funds

85%, National Public Funds 15%

Strategic aim of the project

The implementation of new technological solutions ena-

bling progressive replacement of the typical plastic

packages into packages degradable under industrial

composting conditions, safe for the human health and

environmental friendly according to Ecological State

Policy.

Research & Development aims of the project:

1. Technological process study on manufacture of bio-

degradable polymer materials suitable for preparation of

packages degradable under industrial composting condi-

tions.

2. Processing of the biodegradable films for the direct

use, as well as new generation of thermo-formed biode-

gradable packaging especially for food industry.

Additional aim of the project

Determine the processing properties of biodegradable

packaging materials and study of their resistance to ther-

mal degradation under processing conditions including:

• impact of the shearing force

• impact of high temperatures

• impact of manufacturing conditions on industrial

biodegradation process

• optimization of the processing parameters in

order to obtain the best application properties of the

product.

General information

Polymeric materials currently play a major role in eve-

ryday life. The advantages that plastics have compared

to “traditional materials” (performance, durability,

weight, environmental aspects) enable them to penetrate

society and industry to an even larger extent in the com-

ing years. Innovation in plastics will thus make a valua-

ble contribution to increasing economic growth and

quality of life in Europe. At present, there is also a tre-

mendous increase on the potential use of biodegradable

polymers in many different areas such as: medicine,

pharmacy, cosmetic industry, agrochemistry etc. This

novel and promising scientific area relates directly to

the most crucial present health and social problems, at

global as well as European level.

The MARGEN project makes it possible to utilize inter-

disciplinary investigations of biodegradable polymers to

work out the basis of modern polymeric technologies

for advanced packaging (bio)materials. The aim of the

project, carried out as the top priority of the Operating

Program Innovative Economy entitled »The Investiga-

tion and Development of Modem Technologies« is to

introduce new, safe and environmentally friendly tech-

nologies enabling a gradual replacement of packaging

from classical plastics by new generation packaging

susceptible to organic recycling. The project should

work out the foundations of a technological process for

the production of polymeric materials such as polymers,

blends and also nanocomposites, biodegradable under

industrial composting conditions, as well as the founda-

tions of technological processes for the production of

films from the new materials both for the direct use and

the production of new generation of rigid packaging for

food, using the thermoforming method. Development

studies are carried out in order to describe processing

properties of the new generation of biodegradable pack-

aging materials such as their resistance to degradation

under processing conditions, including shearing forces

and high temperatures in the processing machines, and

to investigate the influence of the conditions of pro-

cessing on the biodegradation under industrial compost-

ing conditions with the view of optimizing processing

parameters of the materials and obtaining the best func-

tional quality of the product.

The structure of the project comprises 2 institutes of the

Polish Academy of Sciences, 2 universities as well as 2

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recognized R&D centres investigating polymeric materi-

als. The project is coordinated by the Centre of Polymer

and Carbon Materials, Polish Academy of Sciences in

Zabrze and is implemented with the main partners: Fac-

ulty of Chemistry of Warsaw University of Technology

and Institute for Engineering of Polymer Materials and

Dyes in Toruń as well as the remaining partners: the

Centre of Molecular and Macromolecular Studies of the

Polish Academy of Sciences in Łódź, the Wrocław Uni-

versity of Technology - Faculty of Environmental Engi-

neering and the Polish Packaging Research & Develop-

ment Centre (COBRO) in Warsaw. The essential factor

of the scientific value of the project consists in the devel-

opment of created and protected in Poland (as well as

patented in the EU and in Poland) basis for the modifica-

tion of polyesters, including PLA, by preparing polymer-

ic compositions containing e.g. synthetic analogues of

aliphatic biopolyesters.

Synthetic PHA analogues can be obtained with the use of

synthetic gas from b-lactone monomers. Worked out in

the Centre of Polymer and Carbon Materials of the

Polish Academy of Sciences in Zabrze the unique meth-

od of synthesis of aliphatic biopolyesters analogues on

the way of the anionic ring opening polymerization

(ROP) of b-lactone enables the formation of biodegrada-

ble polymeric materials with controlled microstructure,

molecular mass as well as chemical structure of the end

groups.

Production of biodegradable polymers should not be per-

ceived as a threat to traditional plastic market. The

changes are inevitable because of environmental protec-

tion requirements. These changes are an evolution rather

than a revolution. Traditional devices for classical plas-

tics processing can also be used for new biodegradable

polymer processing. Producers should expect and get

ready for these changes. Much more crucial problem is

utilization of compostable packaging material waste.

Polish municipal administration responsible for packag-

ing waste should become prepared for the task of organ-

izing local systems of organic waste collection, which

could be stored along with compostable packaging waste

made of biodegradable polymer materials.

Published Results of Project Implementation and Re-

cent Achievements

The list of recently published results of the project in-

cludes:

1. M.T. Musiol, J. Rydz, W. Sikorska, P.P. Rychter,

M.M. Kowalczuk, A preliminary study of the deg-

radation of selected commercial packaging materi-

als in comopst and aqueous environments Polish

Journal of Chemical Technology, 2011, 13, 55.

2. W. Sikorska, P. Dacko, B. Kaczmarczyk, H. Janec-

zek, M. Domański, K. Mańczyk, M. Kowalczuk,

Synthesis and physicochemical properties of new

(bio)degradable poly(ester-urethane)s containing

polylactide and poly[(1,4-butylene terephthalate)-co

-(1,4-butylene adipate)] segments, Polymer, 2011,

52, 4676.

3. M. Kawalec, M. Sobota, M. Scandola, M. Kow-

alczuk, P. Kurcok A convenient route to PHB mac-

romonomers via anionically controlled moderate-

temperature degradation of PHB. J. Polym. Sci.,

Part A: Polym. Chem. 2010, 48, 5490.

4. P. Rychter, M. Kawalec, M. Sobota, P. Kurcok, M.

Kowalczuk Study of Aliphatic-Aromatic Copolyes-

ter Degradation in Sandy Soil and Its Ecotoxicolog-

ical Impac, Biomacromolecules 2010, 11, 839.

5. M.M. Kowalczuk Research works on biodegradable

polymers Opakowanie – Special Edition, 2009, I,

22.

6. M.M. Kowalczuk Anionic ring-opening polymeri-

zation for syntheic analogues of aliphatic biopoly-

esters, Polymer Science, ser. A, 2009, 1, 51.

7. G. Adamus Molecular Level Structure of (R,S)-3-

Hydroxybutyrate/(R,S)-3-Hydroxy-4-

ethoxybutyrate Copolyesters with Dissimilar Archi-

tecture, Macromolecules 2009, 42, 4547.

Innovative cast film extrusion line for flat PLA films

with thermoforming of containers, established at Institute

for Engineering of Polymer Materials and Dyes (IMPIB

Torun), won a silver medal at the Technicon –

Innowacje, 6 Industrial Technology, Science and Innova-

tion Fair, Gdansk, Poland in 2010.

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Biodegradable fibrous products – BIOGRATEX

Izabella Krucinska

Technical University of Lodz

Department of Material and Commodity Sciences and Textile Metrology

90-924 Lodz, 166 Zeromskiego St,

[email protected], www.biogratex.pl

The aim of the project.

The aim of the presentation is to show the research goals

and the solutions achieved as a result of a three-year

realisation of a key project, which is entitled

‘Biodegradable fibrous products – BIOGRATEX’,

financed from the structural funds. The originator of the

project is the Polish Technological Platform of the

Textile Industry, which coordinator is the Technical

University of Łódź. Withing the Platform the project

consortium was set up by nine respected scientific-

research entities for the collaborative realisation of this

project.

The project concerns the development of a

manufacturing technology of the fibrous materials from

polymers subject to the biodegradation processes:

polylactide, polyesters and aliphatic copolyesters,

thermoplastic cellulose and modified polypropylene. The

main goal, as it is presented on the scheme (Fig. 1), is to

process particular types of polymers into the fibrous

products intended for applying in medicine, hygienic

products’ industry, agriculture and filtration.

Biodegradable fibrous products developed in a frame

of Biogratex

The subject of current presentation is showing of the

research on new assortments of fibrous products

obtained as a result of realisation of the project with the

use of commercially available fibre-grade polylactides.

The research on obtaining intermediate products, in the

form of nonwovens formed with the spun-bonded, melt-

blown and mechanical stiching methods, used for

production of fully biodegradable filtration half-masks,

together with giving their characteristics, will be

described. The second group of products described in the

presentation refers to the wound dressings. The results of

research on obtaining the particular components of those

products in the form of stitched nonwovens, foils and

foams in the function of technological parameters will be

presented. The direction of research on increasing the

hydrophilicity of surface by using different variants of

chemical and physico-chemical processing will also be

described.

Fig. 1. Diagram of the works performed during

realisation of the project.

Unique laboratories developde in aframe of Biogratex

As a result of realisation of the project two unique

laboratories were also created. One of them is the

specialist biodegradation laboratory (Fig. 2) created

in the Institute of Biopolymers and Chemical Fibres

in Łódź, which is one the the partners of the project.

The laboratory enables to perform research in the range

of assessment of the susceptibility of polymer materials

and of fibrous products to biological decay caused by

microorganisms that can be found in the natural

environment. The biodegradation research are performed

in the oxygen conditions with the use of innovative

methods, among others the respirometric tests, which

cover the measurement of constant amount of emitted

CO2 with the use of modern research-measurement

device MICRO-OXYMAX RESPIROMETER in

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accordance with the international and European norms.

The biodegradation laboratory have the accreditation

certificate NR AB 388.

Fig. 2. The photograph of biodegradation laboratory.

The second laboratory organised in the same Institute

gives the possibility of forming the with the spun-

bonded method in a laboratory scale (Fig. 3). During the

realisation of the project the laboratory technological

line for production of this type of nonwovens was

created.

In the presentation the assortment of cover and litter

products used for intensification of production

of vegetables manufactured with the use of the designed

technological line will be shown.

Fig. 3. The photograph of of spun-bonded

nonwovens' forming line.

Acknowledgement

The present work is performed within the framework

of the project titled „Biodegradable fibrous

products” (Biogratex) - POIG.01.03.01-00-007-/08-00.

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Biomass waste - a source of raw materials and energy

Matjaž Kunaver12, E. Jasiukaitytė12, N. Čuk2, Tine Seljak1, S. Rodman Opresnik3, T. Katrašnik3

1Center of Excellence PoliMaT, Ljubljana, Slovenia,

2National Institute of Chemistry, Ljubljana, Slovenia

3University of Ljubljana, Faculty of Mechanical Engineering, Slovenia

Biomass such as straw, corn stover and wood and

wood wastes such as leftovers from timber cutting, bro-

ken furniture, sawdust, residues from paper mills etc.

contain appreciable quantities of cellulose, hemicellu-

loses and lignin. New applications and methods in con-

verting the biomass into useful industrial products were

developed by our research group and will be presented in

this contribution.

During liquefaction, lignocellulosic components

are depolymerised to low molecular mass compounds

with high reactivity, high hydroxyl group content and can

be used in many useful applications. We have used a

high energy ultrasound as an energy source to speed up

the liquefaction process in our research. The liquefied

biomass was used as a feedstock in the synthesis of poly-

esters, polyurethane foams and adhesives. The properties

of final products are similar and sometimes better than

the commercial ones. Rigid polyurethane foams have

thermal conductivity coefficient 0.0036 W/mK. For bet-

ter dimensional stability polyesters, produced from the

depolymerised (waste) PET were used in formulations.

The incorporation of the biomass components into the

polymeric compositions provides a certain degree of bio-

degradability.

A special attention was given to the utilization of

the liquefied lignocellulosic materials as a new energy

source with high heating value. Most of liquefied prod-

ucts have a heating value higher than 22 KJ/kg, that is in

the range of pure ethanol and higher than brown coal.

Initial tests have indicated that these products could also

be used as a motor fuel. Since the production of such

liquid fuel utilizes a huge variety of lignocellulosic

wastes and takes place under very mild reaction condi-

tions, an overall energy output is high.

Several possible applications in energy production

were identified and explored by our group.

One of the main practical values of our research is

the utilization of the liquefied lignocellulosic materials in

adhesives for the wood particle boards, veneer boards

and plywood boards. We have proven that such adhe-

sives emit 50% less formaldehyde and products have the

same or even better mechanical and physical properties.

The utilization of the renewable resources into the adhe-

sive formulation can reduce the costs up to 20%. Practi-

cal examples will be given with resulting formaldehyde

concentrations and mechanical and physical properties.

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Ecoshell : Bio-materials for structural use in car application

de LARMINAT Alain.

Citi-Technologies

[email protected]

Introdution

(2min) Presentation of Citi-technologies and the partners

of the project Ecoshell, project founded by the european

commission .

(2min) The CITI-zen

Presentation of The vehicule on which ecoshell is

based: The CITI-zen concept, a light electrical urban car

eco friendly.This vehicule aims to be a just mean for a

just need , simple and secure :

the weight sould be lower than 400Kg without

batteries,

it should be safe in frontal and side crash of the

European regulations R94 and R95 and evaluated on the

pedestrian choc.

In order to achieves these objectives, four main

subprojects are proposed :

Eco-body : A body made with flax fibers and

recycled Polypropilen, the density of this material is

close to 1.15.

Eco-shell : We will explain the containt of this

project further.

Eco-Train: An innovative plug and play dynamic

powertrain.

Eco-seat : Eco-frendly and super-light seats for the car.

Project Ecoshell : structure and objectives

(3min) Ecoshell founded by european commission

Ecoshell main objective is to evaluate whether it is

feasibility of implementing a body in white for the

CITI-zen super lightweight EV entirely made of bio

materials, allowing the car to achieve its extreme

objectives of mechanical performence and weight ?

Ecoshell propose to work simultaneously on :

1- The material: what is the best bio-material for this

application?

2- The structure: what kind of structure can be realised

with this material and fitting well to the car ?

3- The car: how may we design this car to implement

such body in white?

Formulated in terms of a global optimization problem,

the various issues encountered and resolved during the

vehicle design are organized around three topics which

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will be studied through »cost cylesc«three sub-projects :

«Manufacturing », «life cycle » and « end of life ».

Focus on the materials investiguated in Ecoshell :

(10min) Natural fibbers and resins used in Ecoshell

The pre-studies which we have realized indicate that it is

difficult to realize a BIW with a material for which the

young modulus is lower than 15 GPa (even if 20Gpa is

more ralistic) and the strengthis lower than 200Mpa.

Considering the rate of production we need for the car,

we concentrate on two processes of production: SMC

and RTM.

The materials we investigate are Bio-composite

made with Natural fibers and bio-resin. For the natural

fibers we are working with Flax and Hemp.

For the resine we are trying:

-A thermoplastique : the Polyamide.

-A classical thermoset :a Bio-epoxy.

- two new thermoset resins: a resin with tannin of

mimosa and a furanique resin.

We propose to describe here the work which has been

conducted so far, the difficulties we have met already at

this early stage, the first result and orientation we have

taken for the material topic.

Conclusion

(3min) A conclusion in 4 points:

1) The result we have today concerning the mechanical

properties .

2) The target of cost for the material

3) Main issues to be solve.

4) Ecoshell is an open project, all contribution and help

are welcome.

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Bio-composites based on forest derived materials and biodegradable polymers

Andrea Lazzeri, Patrizia Cinelli, Thanh Vu Phuong

Department of Industrial Chemistry, Chemical Engineering and Materials Science

University of Pisa, Via Diotisalvi, 2, 56126, Pisa, Italy

[email protected]

Introduction

The EC project FORBIOPLAST (Figure 1), grant agree-

ment no. 212239, started on the 1st July 2008. The re-

search activity in FORBIOPLAST is focused on the use

of by-products from wood as raw materials for the pro-

duction of composites with biodegradable and recycled

polymers as well as for the production of hard and soft

polyurethane foams by innovative sustainable synthetic

processes with reduced energy consumption.

Figure 1. FORBIOPLAST logo.

The materials produced in the project are devoted to

applications in automotive interior parts and in the pack-

aging and agriculture fields

The cooperation of research centers as the Latvian State

Institute of Wood Chemistry and Pisa University

(UNIPI, Italy) with industries Ritols Ltd (Latvia),

PEMU Plastic Processing Co. (Hungary) and FIAT Re-

search Centre (Italy) lead to the production of proto-

types of soft and hard foam. The Budapest University

for Technology and Economics (LPRT-Hungary) is

cooperating in introducing also wood fibres into these

foams. Figure 2 shows some examples of the prototypes

produced.

Figure 2. Examples of prototypes based on hard and soft

PU foams.

Partners Incerplast (INCP-Romania) and PEMU pro-

duced items for agriculture and packaging applications

based on the formulations selected by UNIPI and LPRT

based on biodegradable polymeric matrices and wood

fibres (Figure 3). Wood fibres were used both as raw

material than after being pre-treated by Fundacion

CARTIF (CARTIF-Spain) or modified by enzymes by

University of Almeria.

Figure 3. Materials based on biodegradable polymers

and wood for applications in packaging and agriculture.

The prototypes were tested by University of Bucharest

(Romania) and University of Almeria (Spain) for toxici-

ty, and for agriculture applications. RODAX IMPEX

S.R.L (Romania) and Norconserv A.S. (Norway) tested

properties relevant to packaging, and Organic Waste

System (Belgium) evaluated the degradability, the an-

aerobic digestion and the Life Cycle Assessment of the

most relevant products. The end users Neochimiki and

Cosmetic (COS-Greece) are performing the validation

of the packaging on their products (cosmetics, and

chemicals). Partner Wiedeman (Germany) has evaluated

the best market opportunities for the product portfolio.

Materials and Methods

Several materials derived by wood processing were

evaluated as components in composites based on biode-

gradable/ecocompatible polymeric matrices. Wood fi-

bres present on the market, such as La.So.Le. (type

200/150E) and Rettenmaier & Söhne (Germany) (type

EFC100) were considered for this investigation. Fibres

were used as received and after chemical and enzymatic

modification carried out by the Partners of FORBIO-

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PLAST. In order to improve water and moisture re-

sistance of wood-fibre composites, a known procedure is

based on the acetylation of wood fibres. The polymers

used in composites with wood fibres were polylactic acid

(PLA) granules from NatureWorks® (grade 2002D), a

mix of L,D isomer (95% L), with a nominal average mo-

lecular weight Mw=199590 Da, melting point of 140-152

°C, glass transition temperature of 56.7-57.9 °C, and den-

sity of 1.24 g/cm3 and a polyhydroxybutyrate (PHB)

powder form BIOMER LoT13 with 60-70% crystallinity.

A poly(butylene adipate-co-terephthalate), Ecoflex®

from Basf Corp., with melting point of 110-120 °C, den-

sity of 1.25-1.27 g/cm3, and MW=131440 Da and poly-

ethylene glycol, PEG 1500 from Fluka, were used as

flexibilising agents. Composites were prepared using a

Thermo Scientific HAAKE MiniLab II Micro Com-

pounder with a sample volume of 7 cm3. The materials

were extruded at 190 °C, 50 rpm and cooled in air at

room temperature. Standard tensile specimens were pro-

duced using a Thermo Scientific HAAKE MiniJet II, at

190 °C, and 600 bar.

Results and Discussion

Figure 4 compares mechanical properties of PLA/Ecoflex

50/50 and PLA/Ecoflex 20/80 matrices with Rettenmaier

(R) fibre at loadings of 15% and 20% by weight and with

acetylated fibres (Ac1, Ac6) at 15% by weight.

Figure 4. Comparison of mechanical properties in com-

posites based on PLA/Ecoflex 50/50, and PLA/Ecoflex

20/80 as continuous matrix.

Acetylated fibres are expected to improve moisture and

water resistance, which is a typical weakness in wood

based composites, but loss in mechanical properties

could result. In the present case there is no loss in me-

chanical properties.

Composites with higher content of Ecoflex (80%) present

higher values of elongation at break than composites with

50% PLA and 50% Ecoflex, and, of course, lower values

for tensile strength and modulus. Thus the biodegradable

matrix can be tuned by the variation of PLA/Ecoflex ra-

tio in dependence of the technical parameters envisaged

by the final planned application.

Samples were prepared with PHB as continuous matrix,

polyethylene glycol and wood fibres. The main mechani-

cal properties are reported in Figure 5.

Figure 5. Comparison of mechanical properties in com-

posites based on PHB, PEG and wood fibres.

Significant improvements can be achieved in mechanical

properties of composites based on PHB when they are

prepared with wood fibres pre-treated with Aquacer 598

(Aq598), that is water based polypropylene emulsion,

and with Hordamer PE 02 that is an emulsion of polyeth-

ylene waxes. Figure 6 shows the improvement in values

of Young’s Modulus derived by the use of fibres treated

with the additives.

Figure 6. Young’s Modulus of composites based on PHB

and wood fibres treated with water based waxes.

Conclusions

Appropriately tuned composites (ratio PLA/Ecoflex, use

of modified fibres) can meet the technical requirements

defined by FORBIOPLAST end users for mechanical

properties of prototypes suitable for applications in pack-

aging and agriculture.

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REBIOFOAM PROJECT : Development of a flexible and energy-efficient pressurised microwave

heating process to produce 3D-shaped REnewable BIO-polymer FOAMs for a novel generation of

transportation packaging

Federica Mastroianni

Novamont S.p.A.

[email protected]

REBIOFOAM at a glance

REBIOFOAM is a Collaborative Project financially

supported by the European Union Seventh Framework

Programme for Research and Development (FP7). As

its title suggests, the Project targets the development of

a new 3D-shaped Renewable BIO-polymer FOAMs to

be applied as protective packaging material.

Bio-based plastics represent an emerging and highly

promising solution for protective transport packaging,

since they contribute to overcome environmental

concerns such as the depletion of non-renewable fossil

resources and, thanks to their biodegradable and

compostable nature, offer an innovative sustainable disposal

option. The novel foam could therefore be alternative to

expanded materials traditionally applied for cushion

transport packaging, but offering the additional buying

driver that is represented by the novel materials being

biodegradable and compostable.

The Project was launched on the 1st

February 2009 and will be running

for 48 months, until the 31st January

2013. It involves 10 Consortium

partners from 8 different countries and is coordinated by

Novamont, the Italian company world leader in the

production of starch-based biodegradable plastics.

S&T Objectives

The Project objective is to develop a flexible, energy-

efficient and environmentally-sustainable manufactur-

ing process enabling the production of biodegradable

foamed 3D-shaped packaging originating from ex-

pandable starchbased polymer pellets materials. In

this new process, expansion of the pellets is driven by

microwave technology and exploits the inner water con-

tent of the material itself to generate vapour.

In particular the focus is on:

the development of a proper formulation of base

materials as well as of an appropriate extrusion

process accordingly;

the evaluation of the effects of microwave fields

thus enabling an efficient design of the micro-

wave oven;

the comparison of dielectric properties of different

mould materials as well as the selection the most

appropriate material for mould coating;

the development of an efficient microwave

moulding system, as well as the development of

an automated pilot plant prototype demonstrat-

ing viability of technologies at a larger semi-

industrial scale that will be used to produce a vari-

ety of foam packaging product prototypes for dif-

ferent applications.

Since the 1st February 2011, the Project entered its third

year. While its main focus so far has been on developing

the enabling material and processing technologies, the

Project has now entered a second phase, aimed at demon-

strating applicability of the developed material and pro-

cesses through the manufacture of protective packaging

demonstrators on the one side, as well as through the

construction of a pilot foaming process on the other side.

The Project partners

REBIOFOAM Project

involves 10 Consortium

partners from 8 different

countries.

Research and Technological

Development is carried out

in its major part by a core group of Research and

Knowledge Intensive industrial partners (Novamont,

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C-Tech Innovation and FEN) in cooperation with a

limited group of excellent Research Centres

(Fraunhofer Institut and Czech Technical University).

Chemtex Italia has been appointed to define the

conceptual design and the high-level production

requirements and specifications guiding the

manufacturing process and to integrate the key

manufacturing steps developed by the other partners into

an automated pilot process line that should demonstrate

viability of the proposed technologies on a semi-

industrial scale. Two packaging producing companies

(Complas Pack and Recticel) belonging to the targeted

transport packaging sector will assess the overall

integrated manufacturing process and the novel bio-

based packaging materials, while ITENE is responsible

of assessing the functionality of the novel bio-based

packaging materials as a major Research Centre for

Packaging, Transport and Logistics. Finally, a Large

Player (Electrolux) has been included in the Consortium

with the role of final packaging user/validator with

respect to the pilot Consumer Markets of household

appliances and consumer electronics.

Get in touch!

To learn more, visit us at www.rebiofoam.eu and

subscribe our Project newsletter (www.rebiofoam.eu/

newsletter).

The REBIOFOAM project has received funding from the

European Union Seventh Framework Programme

(FP7/2007-2013) under Grant Agreement No. 214425

(NMP3-SE-2009-214425).

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BioAgrotex: Development of new agrotextiles from renewable resources and with a tailored biodeg-

radability Stijn Monsaert, Luc Ruys

Centexbel, Technologiepark 7, B-9052 Zwijnaarde, www.centexbel.eu

Increasing oil prices, a growing threat of oil shortage,

Kyoto agreements on greenhouse gases, environmental

effects and climate changes are all elements that contrib-

ute to the concern for the future of our oil-based econo-

my. Not only the research for biofuels, but also for bio-

based polymers and a more extensive use of the natural

resources by upgrading the value of natural fibres and

side products will be needed to cope with these problems.

Techno-economic studies predict an important growth for

the bio-based polymer industry in the coming decennia.

This will only be possible if new high end applications

are developed. Textiles and especially agrotextiles offer a

very attractive end market. Volumes in this market area

are high and fast growing.

At present, products are mainly based on polyolefins (>

200 ktonnes annually in Europe). Bio-based polymers in

combination with natural fibres and side products can

offer a good alternative if biodegradation can be mod-

elled and adapted according to the specific end applica-

tions. Intrinsic positive properties of the bio-based poly-

mers such as low flammability and high light fastness

can boost technological advantages, leading to major

economic and technological benefits in industrial imple-

mentation.

This project envisages the research and development of

100% renewable agrotextiles via combination of natural

fibres, bio-based fibres and bio-based functional addi-

tives through the following phases:

new and optimised extrusion processes into fibre,

yarn, monofilament or tape,

processing into knitted, woven or nonwoven struc-

tures and new finishing process,

tailor-made mechanical and functional characteris-

tics,

a controlled and predictable biodegradation adapted

to the application envisaged, and

a proven performance for a number of test/demonstration

cases.

This type of project can take a large share of the agrotex-

tile market (up to 50%) by creation of alternatives for oil-

based products and new applications.

www.bioagrotex.eu

Bioagrotex is a EU co-funded project, Grant agreement

no.: 213501 within Seventh Framework Programme.

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EPNOE (European Polysaccharide Network of Excellence); presentation of the project

Patrick Navard

Armines – Mines ParisTech - CNRS

[email protected]

What is EPNOE?

EPNOE (European Polysaccharide Network of Excel-

lence) is a network comprising 16 research centres in 9

countries focusing on research in polysaccharide science

and 27 companies from SMEs to multinational corpora-

tions. It is a common Research, Education and Commu-

nication organisation meant for promoting polysaccha-

ride research in Europe and worldwide, and to offer a

collaborative R&D platform to industry.

Main missions

The main missions of EPNOE are to provide its mem-

bers with an area of mutual trust and collaboration, to be

a platform for bringing together companies and research

centres, to perform the best world-class multidiscipli-

nary research, to disseminate knowledge at all levels of

society, and to be a reliable and innovative research

network on polysaccharide science.

Structure

EPNOE is organized in the form of a legal non profit

association called EPNOE Association, comprising the

sixteen academic and research institutions (regular

members) and the industrial members (associate mem-

bers) brought together into the EPNOE Business and

Industry Club (BIC). EPNOE is organised with four

bodies: the General Assembly, the Governing Board,

the Executive Board and the Finance Supervisory

Board.

Activities

EPNOE’s activities are divided into four themes: Man-

agement, Education, Research and Business and Indus-

try Club. Antother satellite activity is the organisation of

the EPNOE International Polysaccharide Conference

that is held every two year. The forthcoming activities

will be the publication of the EPNOE book, the organi-

sation of an industrial conference every two year, and

the building of a new European project.

Achievements

Overview of EPNOE’s main successful activities:

In terms of Research, more than 40 common papers

are published per year, more than 40 common research

projects are on-going, about 20 PhD are shared by two

EPNOE institutions.

In terms of Education, EPNOE participates in a

European university programme (“Renewable Biore-

sources and Biorefineries” and also set up a European

Commission-sponsored education network on Sustaina-

ble Utilization of Renewable Resources (three series of

courses :2009, 2010, 2011)

In terms of Dissemination, EPNOE published its

Research and Education Road Map 2010-2020, created

a set of e-learning lectures available on the website, and

published three market studies.

EPNOE also successfully organised the EPNOE Inter-

national Polysaccharide Conference (EPNOE 2009 in

Åbo/Turku, EPNOE 2011 in Wageningen). The next

one, EPNOE 2013, will be held in Nice.

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MarineClean - Marine debris removal and preventing further litter entry

Janez Navodnik**,Vladimir Pogač*

**Tehnology centre PoliEko, *Turna d.o.o.,

[email protected]; [email protected]

Introduction

MarineClean project is financed under the CIP Eco-

Innovation 2010 programme. Duration of the project is 3

years, starting in November 2011. Project coordinator is

private SME company from Slovenia, TURNA. Project

consortium consists of eight partners. Project will link

together institutions from three countries with access to

sea, Slovenia, Croatia and Lithuania. Slovenian partners

are besides Turna also Drava water management compa-

ny Ptuj, National Institute for Biology – Marine Biology

Station Piran and Technology centre PoliEko. Partners

from Croatia are SME company EcoCortec and Faculty

for Mechanical Engineering and Naval Architecture

from University of Zagreb. Partners from Lithuania are

Klaipeda Science and Technology Park, and Air Pollu-

tion research centre from Klaipeda University.

Objectives

Marine littering is one of the major ecological threats.

The amount of plastic floating in oceans is increasing; in

some parts of oceans there are already 6 times more

small plastic parts than plankton. Plastic floating in sea is

great absorber of heavy metals, pesticides, PCBs and

other toxins that accumulate in marine animals and con-

sequently in humans. Toxins are good for some algae,

which are so widespread in some areas that other organ-

isms lack of oxygen. Bio-oxo or UV-degradable plastic

is not a solution, because sea water inhibits degradation

and plastics is stable, maybe up to 100 years.

Share of ship littering is variable throughout the World,

ranging from 35 to 85%. The remaining shares come

from rivers, wind and lost fishing nets. A large percent

of marine litter is from food packaging used on shore

and delivered into the sea with wind and rivers. Another

major contribution to marine littering are so called ghost

nets – lost fishing nets floating on the surface or near the

sea surface.

Other problems are spillages of different oils that cannot

be solved by expensive cleaning with pumping and fil-

tering in tankers or degradation with microorganisms.

Marine litter is very dangerous to different sea animals:

birds, turtles, fishes and sea mammals, because of possi-

ble entanglement and swallowing.

Marine litter is present in all seas, not only in the great-

est. The most known are North and South Pacific Gar-

bage Patches, but in recent years it was proven that simi-

lar garbage patches exist also in North and South Atlan-

tic, Indian Ocean, Mediterranean Sea, Baltic Sea etc.

Proposed solution and summary of work programme

Project MarineClean will deal with preventing natural

environment of Adriatic Sea that is a part of Mediterra-

nean Sea, and of Baltic Sea. Project MarineClean con-

sists of seven work packages in four areas of acting.

The first area covers collection of marine litter. The se-

cond one deals with edible and biodegradable packaging

materials that will help to reduce the quantities of in wa-

How long does it take for marine litter to decompose?

(years)

glass bottle 1 million

fishing line 600

plastic bottle 450

aluminum can 80-200

rubber boot 50-80

plastic cup 50

tin can 50

nylon fabric 30-40

plastic bag 10-20

cigarette filter 1-5

woolen clothes 1-5 y

plywood 1-3

milk carton 3 months

apple core 2 months

newspaper 6 weeks

orange peel 2-5 weeks

paper towel 2-4 weeks

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ter (sea/lake/river) entered plastics, because it is edible

for humans and water animals and thus biodegradable.

The third area is development of fishing gear that can be

easily traced, collected and recycled when lost. The

fourth area of the proposed project is networking of pro-

posed products users and lobbying at national and EU

decision-makers to promote and enlarge eco-friendly

products usage. A solution for collecting marine litter

(WP2) consists of a net strip that floats on the water sur-

face; minor part is above and the rest is below the sur-

face. The strip is made in one piece on roll by co-

extrusion of recycled plastic reinforced with Kevlar. The

upper part of the strip has a hollow tube-like place that is

filled with air to get the variable high of the strip over the

water, depending on waste and wind. The lower part of

the strip under the water has a coextruded magnetic pro-

file, which is heavy, prevents catching of fishes and sea

mammals sensitive to magnetic field and make the col-

lecting easier. Two mentioned strips are joined on one

end where the barrel is placed to gather marine litter (oil

and/or solid parts-beyond the state of the art). The other

ends of the strips are tight to a small ships/boats or one of

two strips can even be in a hands of a person walking

along the coast.

The second area of action in MarineClean project will be

promoting and organizing production of most of all types

of edible and biodegradable packaging for use on ships

(WP3). Edible packaging, can be eaten by humans or,

when entering into a sea/lake/river, by water animals and

is biodegrade in sea water.

The third area of action in this project is development

and production of fishing equipment with integrated

magnetic imparts, that will help to reduce by-catch of sea

turtles, mammals and some sharks (WP4).

The fourth area of action in our project deals with lobby-

ing on national and EU level for stricter legislation about

garbage disposal from ships into the sea, and with net-

working of all interested parties in Europe in the field of

protecting the marine environment and cleaning of the

sea surface (WP5).

Major outputs and results

Edible and biodegradable barrier packaging as a pro-

posed solution for ships, made of multilayer barrier films

with water soluble surface will be the main innovative

output. This packaging can be removed with washing or

during the cooking or eaten. Available materials will be

tested on their sensory and biodegradation properties in

marine environment.

A very cheap net strip for collecting marine litter that

floats on the water surface can quickly and cheap collect

plastic or oil on big area is other innovative output, usa-

ble in many cases.

The fishing net made of bio based polymer and with US

actuator and a magnetic strip above the bottom edge is

the innovative output of WP4 and will help to reduce

portion of ghost nets floating in sea. It leads to a refor-

mation of a net into a ball shape, it is easy to trace and

collect using detectors, removed and recycled or can

slowly sink to the bottom of the sea where it can be over-

grown by algae or corals. Magnetic insert in fishing net

also prevents undesired trapping of sea animals sensible

to magnetic field.

Networking of end-users of marine litter cleaning equip-

ment, edible packaging and of fishing equipment and

lobbying on national and EU level for intensified surveil-

lance in the return of ship waste and for grants and/or

discounts with edible and biodegradable packaging will

be formed.

Proposed solutions will have positive effect on marine

ecology. Indicators will be the decreasing of marine litter

in tested areas, the number of cleaning groups/areas, the

share of edible packaging on tested ships, and the num-

ber of law changing proposals.

Further information is available at Mrs. Urška Kropf,

PhD, project manager at PoliEko:

[email protected]

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Utilization of biomass for the preparation of environmentally friendly polymer materials

Andrzej Okruszek

Institute of Technical Biochemistry, Faculty of Biotechnology and Food Sciences,

Technical University of Lodz. Lodz, Poland

[email protected]

The aim of the project

The aim of the project is utilization of various kinds of

plant biomass and textile waste materials by their trans-

formation with biotechnological methods, involving ei-

ther enzymatic or microbial processes, into fibrous poly-

mer materials. The intermediate products in those trans-

formations are: cellulose nanofibres, tactical polylactide

and aliphatic-aromatic co-polyesters, which all are

known to be important raw-materials for the production

of biodegradable fibrous materials as well as other kinds

of biodegradable polymer composites.

Cellulose nanofibres

For the preparation of cellulose nanofibres, a cellulose-

rich plant biomass is being utilized, including grass and

straw of various cereals as well as waste fibres from tex-

tile industry (cotton, linen). The biomass is first pretreat-

ed with physical and/or chemical methods including boil-

ing, steam-explosion or treatment with certain chemicals.

Multienzyme complex obtained from Aspergillus niger

mould is utilized as the main enzymatic tool. The fibrous

materials and composites prepared within this project on

the basis of abovementioned intermediates will be further

utilized for obtaining new functional textiles and

nonwovens with potential sanitary or technical applica-

tions, such as sweat-absorbing textile inserts, sanitary

textiles, filtration materials, geotextiles and agrotextiles.

Within this project, the processes of ageing and con-

trolled biodegradation of prepared materials will be stud-

ied, as well as the conditions of their recycling and possi-

ble use of degradation products in agriculture.

Tactical polylactide

The synthesis of tactical polylactide is being performed

by chemical polymerization of L,L-lactide, prepared

from L-lactic acid. The latter is obtained by stereoselec-

tive fermentation of plant biomass, after its sacchariza-

tion by appropriate enzymes (Aspergillus niger prepara-

tions). The microorganisms (bacteria), used for the fer-

mentation, were selected by classical microbiology meth-

ods from the environment. In this case patatoes, cereal

grains or beet pulp are employed as starting biomass. The

tactical polylactide will be further utilized for fiber for-

mation and thermoforming.

Co-polyesters

The third path involves utilization of various oil-plant

biomass, which on sequential treatment with lipase prep-

arations obtained from Mucor circinelloides and Mucor

racemosus moulds (structurization, hydrolysis) and ap-

propriate chemical reactions (cycloaddition, hydrogena-

tion) are transformed into oligodiols/polyols with glycer-

ide backbone. These will be co-polymerized with appro-

priate reagents in order to produce new biodegradable

aliphatic-aromatic co-polyesters. The polyesters will be

utilized as fillers for preparation of various fibrous poly-

mers and composites.

Concluding remarks

The project is being realized by nine research groups

from Poland belonging to four different institutions, with

the Technical University of Lodz being the leader.

The methods of preparation of polymer fibrous materials

and composites elaborated within this project will posi-

tively influence development of science-based economy

and will increase the innovativeness of connected areas

of research and production. The main recipients of elabo-

rated methods will be producers of fibers and nonwovens

from thermoplastic materials, sanitary textiles, filtration

materials, geotextiles, agrotextiles and packing materials.

Acknowledgment

The Project (POIG 01.01.02-10-123/09) is partially

financed by the European Union within the European

Regional Development Fund.

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Development of Biobased/Biodegradable/Compostable Nanocomposite Mulching Films

Erhan Pişkin1, Yeşim Ekinci2, Hülya Yavuz Ersan1, Sinan Eğri1,3,

Gökhan Tezcan1, Koroush Salami1, Özlem Eğri1,4, Zakir Rzaev4 ,

Sevda Ismailova1, Farzaneh Moghtader4 1Hacettepe University, Chem.Eng.Dept., and Bioeng.Div., and

Bioeng. R&D Center-Biyomedtek, Ankara, Turkey 2Yeditepe University, Food Eng.Dept., İstanbul, Turkey

3Gaziosmanpaşa University, Bioeng.Dept., Tokat, Turkey 4Hacettepe University, Nanomed.Nanotechnol.Div.. Ankara, Turkey

[email protected]

Industrial product made of fossil fuel based synthetic raw

materials have been produced in very large quanties and

consumed since 1970s which is also the reality today.

Fuels (petroleum, natural gas and coal) are considered as

non-renewable resources. The annual consumption of

fossil fuel feedstock is about about 7.3 Gton, and we are

consuming about 93% of it for energy production. Only

7% is used for polymer and raw chemicals production.

Fossil fuel feedstock will finish as a result of this very

high consumption rates. More than 30% of the polymers

produced are consumed for packaging (including agro-

chemical uses such as mulching films) which has a rela-

tively short life (< 1 year). This means that packaging

waste accumulating in the environment quite rapidly

which may cause very undesirable adverse effects that

we have already facing today. We have to be more en-

vironmentally conscious. Even only because of these

two main concerns one can easily prospect that naturally

derived resources (also called biobased resources) will be

again a major contributor to the production of industrial

and commodity products. There is a great potential mar-

ket of biobased polymers. They are mainly made of re-

newable resources of agricultural origin desirably agroin-

dustrial waste not interfering with food chain. After use

they are disposed of as organic waste, and return to the

earth through processes of biodegradation and compost-

ing -completing a virtuous circle- A very environmen-

tally friendly approach. Here, in this short presentation,

one important biopolymer, i.e. starch, and important bio-

degradable polyester, polylactic acid and its clay nano-

composites are briefly overviewed.

Starch: Polysaccharides, such as starch, cellulose and

chitin are in one of the most important categories of

biobased polymers, as biopolymers. Corn is the primary

source of starch, although considerable amounts of starch

are produced from potato, wheat and rice starch in

Europe. In order to produce thermally processable starch

(thermoplastic starch, TS) several modifications have

been proposed in which the starch -after milling of the

raw material- is destructured and chemically modified

(converting hydroxyl groups to aldehyde groups) to

obtain amorphous (noncrystalline-more stable in aqueous

media, since more hydrophobic). In order to further

improve its processabilities and also final product

properties (mechanical strength, gas permeability, etc.)

TS is compounded with plasticizers (e.g., glycerol) and/

or complexion agents (e.g., vegetable oils). Alternatively,

several more hydrophobic biodegradable and

nondegradable polymers are used to prepare blends that

are more suitable for injection molding and blowing

films. Compatibility is an important issue when these

types of blends and laminates are considered, and

therefore compatibilizers and other additives should be

used as processing aids. The price of starch especially in

US is competitive with petroleum therefore it has been

processed into several compostable products.

Polylactic acid (PLA): Lactic acid is the most widely

occurring carboxylic acid, having a prime position due to

its versatile applications in food, pharmaceutical, textile,

leather, and other chemical industries. Lactic acid is

widely used in the food related applications but recently

it has gained many other industrial applications like

biodegradable plastic production. Lactic acid, is the

monomer for PLA, may easily be produced by

fermentation of carbohydrate feedstock. There is a huge

list of studies for the production of lactic acid from

different resources nicely reviewed recently.

Lactic acid is an a-hydroxy acids, and as being

bifunctional molecules, it can be homopolymerized into

linear polymers by heating with or without using a

catalyst by direct polycondensation reactions (or in other

terms by intermolecular esterification).This technique

produces only low-molecular-weight polymers

(oligomers). In order to produce polyesters with higher

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molecular weights that lactic acid is first converted to the

respective cyclic dimer, i.e. “lactides”. These processes

are usually based on the transformation of lactic acids

into a low molecular weight polymer by heating or also

using a catalyst (e.g., antimony trioxide, zinc chloride),

and then heating the polymer under reduced pressure to

generate the desired cyclic ester. Then, ring-opening

polymerization of cyclic dimers using various catalysts

(e.g., stannous octoate) are being conducted, usually in

bulk or in reactive extruders which is the main approach

for the synthesis of polyesters with high molecular

weights.

Polymer nanocomposites are prepared by dispersion

of nano-sized materials (nanofillers) into the polymer

matrix usually less than 10%. Layered clays and silicates

(e.g., montmorillonite, hectorite, saponite) are the most

widely used nanofillers. Incorporation of nanofillers, due

to huge interfacial surface area improves polymer

properties (such as mechanical properties; thermal

stability; flame retardance; barrier properties, etc.)

drastically. Dispersion of the layered silicates into dis-

crete monolayers is hindered by the intrinsic incompati-

bility of hydrophilic layered silicates and hydrophobic

(usually) polymer matrices. Therefore they have to be

“intercalated” or even converted into a better form,

“exfoliated” using several organo-modifier, usually or-

ganic onium ions which are then dispersed in the poly-

mer matrix (both in solution or in melt) to prepare the

nanocomposites.

PLA is a very promising material, as also mentioned

above, since it is commercially available with reasonable

prices, exhibit good thermal plasticity and mechanical

properties suitable for many applications including

packaging films. However, some of its properties, like

flexural properties, gas permeability and heat distortion

temperature, are too low for widespread applications.

Therefore, PLA have been one of the most widely studies

bio-based polymers to prepare nanocomposites in order

to improve its properties. Several parameters affect

nanocomposite properties, including both organoclay

type, size/shape and clay content, and also

organomodifier type and content which will be discussed

in this presentation.

References

Bordes P, Pollet E, Avérous L, Nano-biocomposites:

Biodegradable polyester/nanoclay systems. Prog in Polym Sci

34: 125-155, 2009.

Garlotta D. A literature review of poly(lactic acid). J Polym

Environ, 9:63-84, 2001.

John RP, Anisha GS, Nampoothiri KM, Pandey A, Direct lactic

acid fermentation: Focus on simultaneous saccharification and

lactic acid production, Biotechnol Adv 27:145-152,2009.

Lima LT, Aurasb R, Rubino M, Processing technologies for

poly(lactic acid), Prog Polym Sci 33:820-852, 2008.

Yu J, Peter R, Chang PR, Ma X, The preparation and properties

of dialdehyde starch and thermoplasticdialdehyde starch,

Carbohydrate Polym 79:296-300, 2010

Zobel H F (1998). Molecules to granules: A comprehensive

starch review. Starch-Starke, 40:44-50, 1998.

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Improvement of green labels for packaging and mulching plastics based on application

of innovative (eco)toxicological tests for the safe recovery of material wastes (ECOPACK)

Ribera Daniel

Bio-Tox

[email protected] / [email protected]

Objectives

The main markets addressed by the proposed project are

the biodegradable/compostable food contact materials

(FCMs), food-soiled packaging, other man-made

products in contact with food (paper napkins, bio-plastic

forks…) and plastics for agriculture.

Today, because of difficulties in the selective sorting at

source (soiled materials, films...) and in collection of

this waste, an important part is, at the end of the life

cycle, landfilled or incinerated.

Moreover, despite the EU standard EN 13432 for

biodegradable packaging recoverable through

composting and despite the French NF U52-001

standard on mulching films, industrial composters are

still reluctant to consider food-soiled biodegradable

packaging as feedstock for composting, for fear of lack

of safety and quality.

Indeed, packaging are tools for communication and

large quantities of pigments, coatings and inks are used.

Most recently active packaging have been developed to

extend the food shelf-life with chemical agents: organic

acids, antimicrobials, fungicides, ethanol or silver ions.

Even though the main raw constituent is biodegradable,

the impact on the environment of these additional

constituents could be questioned.

The proposed project will explore some eco-innovative

practices using a new testing scheme in order to fully

assess the safety of FCMs for valorization as compost.

This innovative approach to the design and labeling of

biodegradable/compostable products will go further than

the existing scheme EN 13432 or to French NF U52-001

standard by integratingnew dimensions related to the

direct impact on biodiversity and human health.

Proposed solution and work programme

In the first WP, an exhaustive battery of tests is being

run on 3 model materials (paper, soiled cardboard,

bioplastic).

The environmental risks and human safety will be

assesed by mean of chemical analyses (searches for

environmental contaminants and substances issued from

plastics), ecotoxicological test and toxicological assays.

This will allow us the define the level of contamination

and the impacts on several species representative of the

ecosystem (vegetal, worms, algae, bacteria, human

cells) and on different toxicological end-points such as

acute, sub-acute, chronic toxicity, genotoxicity,

metabolism biomarkers and endocrine disrupting

responses.

The bioassays include current standardized European

tests completed with innovative biomarkers that have

been developed and technically demonstrated with

success. The tests required by the EU Standard EN

13432 and the French standard NF U52-001 are applied

in parallel on the same samples for comparisons.

In the second WP, the testing scheme for the new

Ecopack label will be defined by selecting the most

relevant and efficient tests (based on a cost/benefit

analysis) in terms of risk assessment.

In the third WP, the battery will be validated by testing

several materials.

Major outputs and results

The main result of the project will be the “Ecopack

label/certification” that will become a major tool for

packaging manufacturers and food brands to

communicate on a green image and therefore an

additional purchasing influencer for organic-minded

consumers.

It will not replace the reuse/recycling initiatives nor the

EN 13432 standard but will complete the possibilities of

landfill diversion by promoting food packaging residues

and other FCMs soiled by food as valuable feedstock for

composting

Call for interest

We are looking for manufacturers willing to take part in

the project by providing us with material for the

validation phase.

The tests and analyses results will be available. Without

any prior authorization, we commit ourselves not to

communicate any information about the origin of these

materials.

The participation in such an European program will

reinforce the environmental liability of the sponsors.

The results collected on the material will put it in a pole

position for the Ecopack certification.

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Partners & responsibilities

Bio-Tox (France, www.bio-tox.fr), Coordinator. Acute

and chronic ecotoxicity tests (algae, fish, daphnids,

bacteria, plants, worms), innovatives tests on earthworms

(biomarkers and genotoxicity), searhes for endocrine

disrupting substances.

Institut Pasteur de Lille (France, www.pasteur-lille.fr).

Innovatives tests for genotoxicity.

Celabor (Belgium, www.celabor.be). EN 13432

compliance (biodegradability, desintegration, plant

growth) and heavy metals analyses.

ITENE (Spain, www.itene.com). Analyses on specific

packaging and process Contaminants (PAH, Dioxines,

PCBs, BPA, Phthlates, carbamates...)

PENA Environnement (France, www.pena.fr). Defini-

tion of composting processes and industrial scale appli-

cation

Organic Products Cluster (Greece, www.biocluster.gr).

Dissemination of the Ecopack certification.

Steering and User committees

The steering committee is the decision-making body. It

validates each result and go-no-go decision. In

complement of the 6 partners, the steering committee is

composed of the 6 partners plus representative bodies

from Danone, Novamont and Papeterie de Raon.

User commitees will be constituted. They will act as an

advisory group for both the execution of the Project and

its valorization.

Funding

The Ecopack is supported by the Executive Agency for

Competitiveness and Innovation (EACI) of the European

Commission within the Ecoinnovation -

Competitiveness and Innovation Programme

Contact information :

Daniel Ribera – Julie Taberly

Bio-Tox, 18 impasse de la Fauvette, F-33400 Talence,

France. Tél. +33 557 990 169.

E-mail : [email protected] , [email protected]

The Ecopack label website (under construction) :

www.ecopack-label.eu

E-mail : [email protected]

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SURFUNCELL - Surface functionalization of cellulose matrices using cellulose embedded nano-

particles

Volker Ribitsch, University Graz, Austria

Institute of Chemistry, Heinrichstrassse 28, A – 8010 Graz

[email protected]

Introduction

The SURFUNCELL project is a large scale integrating

project under EC FP7 with a duration of four years and a

total budget of eight million euros. Since its start in De-

cember 2008, six industrial and seven academic partners

have been developing new ways of modifying the surfac-

es of cellulosic materials using polysaccharide deriva-

tives and a wide range of functional nano-particles. The

project is coordinated by Volker Ribitsch of the Univer-

sity of Graz, Austria. Among the partners several mem-

bers of the European Polysaccharide Network of Excel-

lence EPNOE are active beneficiaries. The CEMEF

MINES ParisTech-CNRS (FRA), and the Universities of

Hull (GB), of Jena (BRD), of Maribor (SLO), of Utrecht

(NL) have contributed their knowledge to the successful

development of the project. Industrial partners are: CHT

(GER); Mondi AG (AUT), Innovia (GB), Litija (SLO),

NanoMeps (FRA), Norit-X flow (NED), TITK (GER).

Scientific and technological targets

The aim of the work is the creation of functional surface

modifications using polysaccharides and nano-particles,

leading to four different demonstrators in the fields of

pulp and paper, cellulosic yarns, cellulose films and filter

membranes. The project is based on the concept of sur-

face modification of the material instead of using nano-

particles as fillers in the bulk. This approach, implicating

several advantages, is depicted in Figure 1.

Figure 1. Schematic representation of functional modifi-

cation of nanoparticle surface

The projects outcome is a technology platform based on

structured cellulose material surfaces compounded using

different nano-particle moieties. This approach does not

negatively influence the mechanical properties and be-

haviour of the matrix material. The functionalities are

introduced exactly at the place of need, at the com-

pound’s surface. The compounding is not performed by

covalent binding and does not require heavy chemistry.

The surface modifications are achieved via the adsorp-

tion and fixation of functionalized and stabilized nano-

particles at the ready-made material, without changing

industrial production processes to a large extent.

The project's main achievements are:

4 different demonstrators close to industrial products

New high value materials based on the renewable

resource cellulose, its derivatives, and state-of-the-art

nanotechnology

Technology transfer from science to industrial prod-

ucts in a cooperative process

Advanced understanding of interactions between sol-

id cellulose surfaces and metallic, metal oxide and

polymeric nano-particles

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BIOCHEM – Eco-IP Partnership for Driving Innovation in the Sector of Bio-based Products

Maria Grazia Zucchini

ASTER

[email protected]

BIOCHEM is an innovation programme funded by the

European Commission and supported by SusChem - the

European technology platform for sustainable chemistry

– to drive competitiveness within Europe’s chemical

industry. Part of SusChem’s remit is to promote strategic

innovations and support innovation-led SMEs.

BIOCHEM aims at supporting companies entering the

rapidly emerging market for bio-based products, taking

advantage of the joint effort of 17 innovation

organisations across eight European countries,

coordinated by Chemistry Innovation (UK).

The BIOCHEM consortium partners include innovation

agencies, national chemical organisations, venture and

public funding bodies and programme consultancies.

Over a three-year timeline, their mission is to develop a

technical and business support toolbox to help at least

250 companies innovate in the bio-based products

market.

There are several strong drivers for this project,

particularly climate change - with a global target for an

80% reduction in greenhouse gas emissions by 2050 -

and energy security. Bio-based non-food products

typically come from plants, trees and bio waste with

typical end products in the bio-plastics, bio-lubricants,

bio-surfactant, enzyme and pharmaceutical sectors.

The EU currently accounts for about 30% of the global

58 billions Euros bio-based products market – which is

expected to more than treble by 2020.

Specific aims of BIOCHEM are to stimulate demand-

driven, bio-based business in the chemical sector to

improve the innovation capacity of bio-based chemistry

start-ups and SMEs and to complete a comprehensive

assessment of the bio-based products market.

Using the partner network, BIOCHEM has developed a

“toolbox” of methodologies and processes in a business

support service package that includes innovation

management, life cycle methodology, business planning

and access to public and private funding.

Through an “accelerator” process it will assist SMEs to

understand their potential to enter the bio-based market

and to identify their barriers to innovation. Process

examples include identification of technology providers

and sources of funding, providing access to test facilities.

During its first year of operation, BIOCHEM has laid the

groundwork for acceleration of industrial biotechnology

innovation in Europe, introducing the project to at least

100 European operators.

So far, BIOCHEM has completed a comprehensive

assessment of the needs, the barriers and the

opportunities specific to the European bio-based products

market. A partnering platform has also been developed in

order to help SMEs share their ideas and identify

business and research partners ready to follow them in

their new activities.

Moreover a breakthrough for bio-based business ideas

will be provided through the organisation of four

"Accelerator Fora" for bio-based SMEs, during which

entrepreneurs and researchers considering to set up a

business in the bio-based sector will have the opportunity

to promote their project and meet face-to-face with

European biotech investors, venture capitalists and other

industry and research players.

The first Forum will take place on 5-7 October 2011 in

Milan at the LIFE-MED 2011 fair premises. Next fora

will be held in 2012 in Frankfurt, Palma di Maiorca and

in 2013 in London.

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