environmental protection agency · absolute pressure of stack gas, p s volume of water vapour...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279

Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Exova Catalyst Ireland, Unit 18 Tallaght Business Centre, Whitestown Business Park, Tallaght, Dublin 24T: +353 86 853 8247

E: [email protected] Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

WaterfordCork Road Industrial Park

Honeywell International Technologies Ltd

Ireland


A2-1 Abrasive Extraction

DELETE & COVER ME

Dates of the Monitoring Campaign

Version

Team Leader

Team Leader

TE1 TE2 TE3 TE4MM 08 922

MCERTS Level 2

Patrick O'Brien

Report Approved by

Stack Emissions Testing Report Commissioned by

8th December 2015

Job Reference Number

CDU-0559

Installation Name & Address

Report Written by

Patrick O'Brien

5th January 2016Report Date

TE1 TE2 TE3 TE4

Stack Reference

Irish EPA IPPC Licence: P0698-01

Signature of Report Approver

Version 1

MM 08 922MCERTS Level 2

CAT-RT (Version BJ)

CDU-0559 Honeywell Int Technology A2-1 (POST)

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TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Summary of Method Deviations

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

The testing performed fully meets the technical requirements in Irish EPA

Guidance Note, AG2.

Opinions and interpretations expressed herein are outside the scope of

Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the written

approval of Exova Catalyst Ireland.

2

9

3

5

6

8

7

CONTENTS

4

7

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Job Number: CDU-0559, Version 1

Sample Date/s: 8th December 2015


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Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Exova Catalyst Ireland were commissioned by Honeywell International Technologies Ltd

to carry out stack emissions testing on the A2-1 Abrasive Extraction at Unit 328.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the

Site's Licence.

There were no special requirements.

Antimony, Lead, Total VOCs (as Carbon)

MONITORING OBJECTIVES

Executive Summary(Page 1 of 7)

Honeywell International Technologies Ltd, Unit 328


8th December 2015

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EPA Export 14-04-2016:01:16:51

where MU = Measurement Uncertainty associated with the Result

Parameter

Antimony ¹ < <

Lead ¹ < <

Total VOCs (as Carbon) ¹ - -

Water Vapour

Stack Gas Temperature

Stack Gas Velocity

¹

- -

NOTE: VOLUMETRIC FLOW RATE DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.

-

-

-

0.0004

0.00046 0.000 - g/hr


8th December 2015

+/-

Units Result

Concentration

MULimit

+/-

0.0003

0.0013

0.0012

Units

mg/m³

-

Result LimitMU


0.00048mg/m³ g/hr

-

0.000

Executive Summary

Mass Emission

-

MONITORING RESULTS

- g/hr

2.9

1.07

m³/hr

0.46

1.3

2692 239

% v/v

m/s

0.1

24.0

mg/m³

263

1.24

0.22

2967

m³/hrVolumetric Flow Rate (REF)

°C

Volumetric Flow Rate (ACTUAL)

0.40

(Page 2 of 7)

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Parameter

R1 < <

R1 < <

R1 - -

R1

All results are expressed at the respective reference conditions.

Date(s)

Mass Emission

Antimony

g/hrLead

08/12/2015 12:50 - 12:55Velocity & Volumetric Flow Rate

mg/m³

0.0013

14:05 - 15:0508/12/2015

mg/m³ 14:05 - 15:05

0.0012

g/hr


Duration

Executive Summary

Sampling

Times

Units

(Page 3 of 7)

MONITORING DATE(S) & TIMES


8th December 2015

Units Concentration Sampling

g/hr

60

60

mg/m³ 0.00046

mins

08/12/20150.00048

Total VOCs (as Carbon) 0.4 08/12/2015 3014:05 - 14:351.07

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Standard Operating Conditions

Process Status


Value

Continuous or Batch Process

Plume Appearance

Bag Filter


8th December 2015

(Page 4 of 7)

Executive Summary

PROCESS DETAILS

Parameter

On

Continuous

Not Visible

Normal Operation

Abatement System

Abatement System Running Status

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EPA Export 14-04-2016:01:16:51

M31

M31

17025 Analysis

0.1 % v/vGravimetricCAT-TP-05

Yes

CAT

Yes

Pitot Tube and Thermocouple

YesCAT

All

CAT-TP-06

Yes 1.2 m/s

ISO 17025 Accreditation Number: 0605

CAT

EN 12619:2013

Yes

ICP-MSCAT Yes Yes

Procedure

LOD

0.16 mg/m³CAT-TP-20

CAT YesWater Vapour

ISOParameter

0 mg/m³

Antimony

EN 16911-1 (MID)

EN 14385 CAT-TP-06 Yes

Lab

Monitoring Analysis

0 mg/m³

Procedure

Analytical

Technique

AnalyticalTechnical

CAT-TP-05 YesEN 14790

(Average)

ISO

Flame Ionisation Detection by Sick 3006 FID


Standard

Lab

Yes

MCERTS

17025

Testing

EN 14385

ICP-MS

Run

SUMMARY OF SAMPLING DEVIATIONS

Parameter

Yes RPS

CAT Yes RPS

Total VOCs (as Carbon)

Testing

(Page 5 of 7)

Testing Analysis

Lead

(with short name reference as appears in the table above)

RPS Laboratories Ltd (RPS)

ANALYSIS LABORATORIES

All There are no deviations associated with the sampling employed.

Velocity & Vol. Flow Rate

Deviation

CAT-TP-41

MONITORING & ANALYTICAL METHODS

Executive Summary


8th December 2015

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Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259

6.9

Safe Access Available

-

-

-

-

There is no requirement to perform a BS EN 15259 Homogeneity Test on this Stack.

-

--m/s

Maximum Angle of Swirl

Executive Summary

cm

Yes

General Platform Information

Units

-

On Roof

-

-

Mean Velocity

Outside

Criteria in EN 15259 -

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type

-

0.60

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Yes

-

-

-

m²

m

All platforms should be designed in accordance with the requirements in the Environment Agency's Technical Guidance Note M1

and EN 15259.

Permanent / Temporary Platform

Inside / Outside

Yes

Units

1.02

°

-

--

(Page 6 of 7)

Width

Compliant

0

SUITABILITY OF SAMPLING LOCATION

Vertical

Yes

Parameter

There are no obstructions present which hamper insertion of sampling equipment

Sample Port Size

Circular

Value

> 5 Pa Yes

-

Yes

Yes

m

Lowest Gas Velocity

m/s

Yes

-

2.89

-

-

Required

-

0.28

-

-

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Pa

-

Port Depth

-

Yes

Traverse 1

m/s

Easy Access Available

-

-2.91

Value

Depth

2.95Highest Gas Velocity

Area

0.00 0.00

Hole

-

Lowest Differential Pressure

Value

-

No Local Negative Flow

Platform has vertical base boards (approx. 0.25m high)

-

-

Yes

< 15°

Yes

-

-

< 3 : 1

-

5

0.00Ratio of Above : 1

-

-

0.00

-

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Photo 4

PLANT PHOTOS

(Page 7 of 7)

Photo 1

SAMPLE POINTS

Executive Summary

Photo 2

Photo 3

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point

Line A

Line B

A1

A2

B1

B2

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APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS

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EPA Export 14-04-2016:01:16:51

Bioaerosols Temperature Logger -

Electronic Refrigerator -


Eco Physics CLD 822Mh

MM 08 922 TE1 TE2 TE3 TE4

Heated Probe (2)

-

-

CAT 3.59

SELECT FTIR

SELECT Horiba Model (2)

Digital Temperature MeterServomex 4900

-

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

Gasmet Sampling System-

MCERTS Number

Equipment Type Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

-

-

SELECT Gas Conditioning

CAT 13.27

Equipment Type

Technical Endorsements

Team Leader Patrick O'Brien MCERTS Level 2

Technician James Magann MCERTS Level 1 MM 15 1330 None

1m Heated Line (1)

-

Technical ProcedureStandard

Heated Probe (1)

Barometer

Digital Manometer (2)

Umbilical (1)

Box Thermocouples (2)


CAT 11.61

SELECT Logger 2 -

Dual Channel Heater Controller CAT 3.81Kg Check Weight CAT 17.24

Last Impinger Arm CAT 4.404

Callipers

- 20m Heated Line (1)

-

METHODS & TECHNICAL PROCEDURES USED

Tubes Kit Thermocouple CAT 4.439

5m Heated Line (1)

Bernath 3006 FID CAT 8.15

Water Vapour


CAT 5.52 1m Heated Line (2)

EN 14790

-

EN 14385

EN 14385

Mass Flow Controller (1)

Single Channel Heater Controller

S-Pitot (2) -

Heated Probe (3) -

CAT 6.44

-

SELECT Logger 1

CAT 20.62

500g Check Weight

SELECT Heated Head 1m Heated Line (3)

CAT 21.S42

EN 16911-1 (MID) CAT-TP-41

Mass Flow Controller (2) CAT 6.45

Mass View (1) -

20m Heated Line (2)

Parameter

Tape Measure CAT 16.35

-

-

Umbilical (2) Servomex 5200MP

Oven Box (1)

-

CAT 4.467

Mass View (2)

-

Laboratory Balance CAT 1.18 / 1.18a

Stack Thermocouple (3)


-

-

CAT 12.53

CAT 3.59

-

Control Box DGM (1)

CAT 3.73-

-


CAT 23.26

Instrumental Analysers

Stopwatch

CAT-TP-06

CAT-TP-06

CAT-TP-20

CAT-TP-05

EN 12619:2013

CAT 20.71

15m Heated Line (1)

CAT 17.24

CAT 7.23

Equipment I.D.

-

Position

Equipment I.D.

Digital Manometer (1)SELECT Horiba Model (1)

Oven Box (2)

-

CAT 14.53

Name

Control Box DGM (2)

-

ABB AO2020-URAS26

-

S-Pitot (1)

L-Pitot

-

CAT 3.73

Equipment Type

-

Antimony

Lead

Miscellaneous Items

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EPA Export 14-04-2016:01:16:51

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

Stack Diameter / Depth, D

Gas Volumetric Flowrate (from Traverse)

Gas Volumetric Flowrate (STP, Dry)

°C

Average Stack Static Pressure, Pstatic

m²

-

Units

PRELIMINARY STACK SURVEY: CALCULATIONS

Volume

7.0

Molar Conc

0.28Stack Area, A

APPENDIX 2

mStack Width, W

24.0

Average Barometric Pressure, Pb

m

Stack Details (from Traverse)

kPa

kPa

0.84

Value

0.60

100.0

Average Stack Gas Temperature, Ta

0.005

-

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc

1.31

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

1.31

79.14

Fraction

Density

Dry

0.011

20.80 32.00

Actual

kg/m³

kPa

0.0131

20.53

Wet Density (STP), P STW

-

101.3

Temperature

N₂

0.06

Mass

Component

m³/hr

Result

°C

kg/m³

0.7914 28.01

1.31

kg/m³ 1.28

Duct gas flow conditions

2692

2967

1.17

0.989

1.29

kg/m³

Gas Volumetric Flowrate (STP, Wet)

Moisture

Conc

0.001

Pa

0.06

24.0

100.0

% v/v

Units

-

1.25

44.01

2657

Gas Volumetric Flowrate REF ¹

%

0.80

p pi

78.10

Dry Density (STP), P STD

18.02

Determinand

0.0006

2692

Result

1.96

-

-

0.2080

m³/hr

REF ¹

1.16

Dry Density (Actual), P Actual

m³/hr

-

1.43 0.297-

Units

Gas Volumetric Flowrate (Actual)

0.0

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EPA Export 14-04-2016:01:16:51

Parameter Parameter

Date of Survey Initial Pitot Leak Check

Time of Survey Final Pitot Leak Check

Atmospheric Pressure Orientation of Duct

Average Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines Available

Are Water Droplets Present? Number of Lines Used

Device Used

Wet Density

Pa 0.84

S-Type Pitot with KIMO MP 200 (500Pa)

Units

5 -

Pass

-

-

-

4.02.91

2.91

-

12:50 - 12:55

Sampling Line A

STATIC (Units: Pa)

Value

∆P -

-

-

100.0

2

0.56

Temp

-

-Swirl

No

kPa

-

-

-

-

Vertical

Pass

1

08/12/2015

Value

-

Depth

-

Velocity

Units

APPENDIX 2

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

-

(1 of 1)

1

-

4

-

24.0

7.0

5.0

1.162

m/sPa

Traverse

m

0.041

1.162

24.00.45

--

4.0

°

6.9

-°C

5.0

7.2

3

2.95

kg/m³Point

1.162

Pass

- - --

-

- -

-

2.91

- -

24.0

- -

24.0

7.0

7.0 -

1.162

-Mean

-

-

0.15

-

-

-

-

4.0

-

-

-

-

-

-

-

- -

-

-

-

-

-

- - -

-

--

-

-

-

-

-

-

-

- -

-

-

1.162

2.89

24.0

-

-

---

-

-

-

-

-

-

--

-

-

-

-

-

-

-

-

-

-

-

-

-

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EPA Export 14-04-2016:01:16:51

- u(qV,w)

Standard uncertainty associated with the volume flow rate (95% Confidence), relative

-

u(φO₂,d)

u(φCO₂,w)

- u²(a)/a²

- u²(qV,w)/q²V,w

-

u(res)

- u²(qV,w)

20.527

0.059

0.637

0.002

263.5 m³/hr

Pa

APPENDIX 2

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

u(φCO₂,d) 0.002

u(cal) 0.005

u(drift) 0.083

u(fit) 0.047

u(Cf) 0.137

u(M) 0.00003

1.066

0.00087

K

u(pc) 175.695 Pa

u(patm) 175.692

- φCO₂,w

- Oxygen, dry

- Carbon Dioxide, dry

- Water Vapour

- Oxygen, wet

- Carbon Dioxide, wet

-

-

1.066

u(ρ) 0.00627 -

u(vi) 0.223 Pa

u(v) 0.114 m/s

Uc(v) 0.223 m/s

Uc,rel(v) 7.64

u(φH₂O) 0.067

u(φO₂,w) 0.629

u(Tc) 1.515

Standard uncertainty associated with the mean velocity (95% Confidence)

Standard uncertainty associated with the mean velocity (95% Confidence), relative

Standard uncertainty associated with the volume flow rate (95% Confidence)

%

Uc(qV,w)

0.00205

- 18072

- 134.4

UnitsValueUncertainty

0.00053

-

Standard Uncertainty on the coefficient of the Pitot Tube

Standard Uncertainty associated with the mean local dynamic pressures

- Resolution

- Calibration

- Drift

- Lack of Fit

- Overall corrections to dynamic measurements

Standard uncertainty associated with the molar mass of the gas

- φO₂,w

u(pstat)

Uc,rel(qV,w) 8.88 %

u(k) 0.005 -

u(∆pi)

Standard uncertainty associated with the stack temperature

Standard uncertainty associated with the absolute pressure in the duct

- Atmospheric Pressure

- Static Pressure

Standard uncertainty associated with the density in the duct

Standard uncertainty associated with the local velocities

Standard uncertainty associated with the mean velocity

Performance characteristics (Uncertainty Components)

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EPA Export 14-04-2016:01:16:51

Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.

0.0001Uncertainty ±mg/m³

MaximumUnits Blank 1

A1, A2, A3 & A4

Parameter

Number of Sampling Lines Used 1 / 1

Number of Sampling Points Used 4 / 4


Parameter

0.0001

Sample Point I.D.'s

ANTIMONY: RESULTS SUMMARY

Units Run 1 Mean

Concentration mg/m³ 0.0005 0.0005

Titanium

Filter Housing Material Borosilicate Glass

0.0

Uncertainty ±g/hr 0.0

APPENDIX 2

Impinger Material

Mass Emission g/hr 0.0

Borosilicate Glass

Absorption Solution Nitric Peroxide

Positioning of Filter

1.31

Uncertainty ±% v/v 0.07

Date of Sample Analysis 17/12/2015

Out Stack

0.0005

Parameter Value

Probe Material

0.0

NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.

Parameter Units Run 1 Mean

Water Vapour % v/v 1.31


0.07

Concentration mg/m³ 0.0005

Name of Analytical Laboratory RPS

Analytical Laboratory's Procedure M31

ISO 17025 Accredited Analysis?

Filter Size and Material 47mm Quartz Fibre

Yes

Standard EN 14385

Technical Procedure CAT-TP-06

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EPA Export 14-04-2016:01:16:51

Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentage

Reported Water Vapour, checked with Tables in EN 14790, Rwv

Volume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂ (Estimated)

Molecular weight of stack gas (wet), Ms

Velocity of stack gas, Vs

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

Nozzle diameter, Dn mm 6.99

Nozzle area, An mm² 38.38

Total sampling time, q min 60

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 113.2

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Average square root of velocity heads, √∆P √mmH₂O 2.81

Average stack gas temperature, Ts °C 24.0

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s 9.68

Conversion factor (K/mm.Hg), Cf - 0.3592

Area of stack, As m² 0.28

Qa = (60)(As)(Vs) m³/min 164.3

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 149.0

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 147.1

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol 28.70

Pitot tube velocity constant, Kp - 34.97

Average of velocity heads, ∆Pavg mmH₂O 7.88

Total mass of liquid collected, Vlc

Vwstd = (0.001246)(Vlc)

% v/v 1.31

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

m³ 1.4430

Gas meter correction factor, Yd

28.84

Average pressure drop across orifice, ∆H mmH₂O

Average dry gas meter temperature, Tm °C 20.5

Total mass collected in impingers (silica trap)

APPENDIX 2

ANTIMONY: ISOKINETIC SAMPLING CALCULATIONS

N/A

% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A

% v/v 0.06

% v/v 20.80

1.3736

g 14.5

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - No

% wet oxygen measured in gas stream, ACT%O₂w % v/v

- N/A

53.4

% oxygen reference condition, REF%O₂ % v/v

Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.0131

m³ 0.0180

Volume of gas sample through gas meter, Vm

Ps = (Pb + (Pstatic / 13.6) mmHg 750.0

- 1.0180

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

Stack static pressure, Pstatic mmH₂O 0.5

N/A

1.3556

Total % v/v 20.86

Vmstw = (Vmstd)(100/(100 - Rwv))

21.8

Test

750.0

% v/v 1.31

Units Run 1

g

m³

Barometric pressure, Pb mmHg

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) - N/A

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

Total mass collected in impingers (liquid trap) g -7.3

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

Velocity pressure coefficient, Cp - 0.84

N₂ % v/v 79.14

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EPA Export 14-04-2016:01:16:51

Sample Runs

<

<

Mass in Back Impinger <

<

<

<

Where: ISO stands for Manual Isokinetic Sampling Train

Blank Runs

<

<


<

<

<

µg 0.02

Calculated Concentration mg/m³ 0.0005


Total Mass Collected µg 0.66

Reported Concentration mg/m³ 0.0005

Mass on Filter / in Rinse µg 0.60

Mass in Front Impingers µg 0.04

Parameter Units Blank 1

Blank Dates - 08/12/2015

Average Volume Sampled (REF) m³ 1.3736



µg 0.02

Sampling Times - 14:05 - 15:05

Sampling Dates - 08/12/2015

Sampling Device - ISO

Volume Sampled (REF) m³ 1.3736


APPENDIX 2

ANTIMONY: SAMPLING DETAILS

Parameter Units Run 1


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Sample Runs

Maximum Temperature Recorded °C 10

Maximum Allowable Temperature °C 30

Exit Temperature Acceptable - Yes

Test Conditions Units Run 1

Ambient Temperature Recorded? - Yes

Allowable Isokinetic Range % 95 - 115

Isokineticity Acceptable - Yes

Filter Temperatures Units Run 1

Maximum Filter Temperature °C 160

Impingers Exit Temperature Units Run 1

MU Acceptable % Yes

Silica Gel (Concurrent Water Vapour) Units Run 1

Less than 50% Faded % Yes

Isokinetic Criterion Compliance Units Run 1

Isokinetic Variation % 113.2

Water Droplets Units Run 1

Are Water Droplets Present - No

MU (Concurrent Water Vapour) Units Run 1

Measurement Uncertainty (MU) % 5.2

Allowable MU % 20

Allowable Leak Rate l/min 0.49

Absorption Efficiency Acceptable - Yes

Detection Limit Units Run 1

Detection Limit µg/m³ 0.5

Leak Test Acceptable - Yes

Absorption Efficiency Units Run 1

Absorption Efficiency % 100.0

Allowable Absorption Efficiency % 90

APPENDIX 2

ANTIMONY: QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units Run 1

Mean Sampling Rate l/min 24.48

Pre-Sampling Leak Rate l/min 0.11

Post-Sampling Leak Rate l/min 0.12

Detection Limit Acceptable

Allowable Detection Limit

- Yes

µg/m³ 5

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EPA Export 14-04-2016:01:16:51

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Expected Sampling Rate l/min 20.00

Validity of Blank vs ELV Units Blank 1

Allowable Blank mg/m³ N/A

Blank Acceptable - N/A

Nature of Deviation Run Number

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

There are no deviations associated with the sampling employed.





APPENDIX 2


Leak Test Results Units Blank 1

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Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Laboratory Result





Leak

Laboratory Result

Sampled Volume (STP)

Leak

Laboratory Result


Leak

Laboratory Result

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty





N/A

0.49

ANTIMONY: MEASUREMENT UNCERTAINTY CALCULATIONS

Value Standard uncertainty

Measured Quantities Symbol Run 1

Vm 1.4430

0.0001

L

Hm 0.0

Vm m³ 1.3556

% 0.68

Symbol

Lr 14.00

1.00

L 0.49 uL % -

≤2%

uLr %

0.0000 1.00

No Requirement

uHm % v/v 1.0

0.00

-

Symbol

- N/A

Uncertainty in Result

Lr mg/m³

Units Run 1

Uncertainty as a Percentage

Sensitivity Coefficient

Measured Quantities

Measured Quantities Units Run 1 Requirement of Standard

≤1%

% 2.00

Tm 293.5 uTm

Run 1

Oxygen Correction Part of MU Budget

mg/m³ 0.0000

≤2%

%

%

Uncertainty in Measurement Units

% v/v

uVm m³ 0.0289

N/A

mg/m³

0.0001

%

% N/A

Units Run 1

mg/m³ 0.0000

mg/m³

% 0.50

% 14.00

≤1%

Overall MU For O₂ Measurement

1.00

Run 1

Measured Quantities

ρm 100.0

Run 1

Measured Quantities Units

≤1%


mg/m³ 0.0001

% 27.9

% 27.9

% 27.9

% N/A

mg/m³ 0.0001

mg/m³ N/A

mg/m³ 0.0001

mg/m³ 0.0001

uρm kPa 0.5

Units

APPENDIX 2

K 2.0

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Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






Parameter Value

Titanium


Impinger Material

1.31

Uncertainty ±% v/v 0.07 0.07

Parameter Units Blank 1 Maximum

Borosilicate Glass


Positioning of Filter Out Stack




Sample Point I.D.'s A1, A2, A3 & A4

Uncertainty ±mg/m³ 0.0001 0.0001

Mass Emission g/hr 0.0 0.0

Uncertainty ±g/hr 0.0 0.0


Standard EN 14385


M31

ISO 17025 Accredited Analysis? Yes





Analytical Laboratory's Procedure

Probe Material

APPENDIX 2

LEAD: RESULTS SUMMARY





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Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





N/Am³/min

m³/min N/A

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

147.1

mm²

N₂ % v/v 79.14


2.81

28.70

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

% v/v

% oxygen reference condition, REF%O₂ % v/v N/A

m³/min 149.0

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

Nozzle area, An

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

Average stack gas temperature, Ts

Area of stack, As m²

38.38

Conversion factor (K/mm.Hg), Cf

N/A

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)


Average square root of velocity heads, √∆P √mmH₂O

0.28

N/A

N/A

0.06

Qa = (60)(As)(Vs) m³/min


164.3

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -

% dry oxygen measured in gas stream, ACT%O₂d

g/gmol 28.84

- 0.3592

Vmstw@X%oxygen = (Vmstw) / (O₂REFw)

0.5

750.0


mmH₂O 53.4

Total mass collected in impingers (silica trap) g 21.8

Test Units Run 1

% v/v

Stack static pressure, Pstatic mmH₂O


1.31

750.0

Ps = (Pb + (Pstatic / 13.6) mmHg


7.88


24.0

Velocity pressure coefficient, Cp -

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

N/A

m³

14.5

Vwstd = (0.001246)(Vlc)


1.4430

Gas meter correction factor, Yd - 1.0180

Average dry gas meter temperature, Tm °C

% v/v

0.84

No-

m³ N/A

Average of velocity heads, ∆Pavg mmH₂O

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) -


APPENDIX 2

LEAD: ISOKINETIC SAMPLING CALCULATIONS

% v/v

Total mass of liquid collected, Vlc g

m³ 0.0180

Volume of gas sample through gas meter, Vm m³

20.5

Average pressure drop across orifice, ∆H

20.80

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 1.3556

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³

N/A

1.3736

m³/min

Total % v/v 20.86


% v/v 1.31

°C

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EPA Export 14-04-2016:01:16:51

Sample Runs

<

<


<

<

<


Blank Runs

<

<


<

<

<

µg

µg

Sampling Device -

- 08/12/2015

Reported Concentration mg/m³

Mass in Front Impingers

0.0004

0.56

Parameter

Sampling Dates

ISO

Sampling Times

0.500

Volume Sampled (REF) m³

Total Mass Collected

1.3736

APPENDIX 2

Run 1

µg


0.02

0.627

Average Volume Sampled (REF)

0.029µg

- 14:05 - 15:05

Mass on Filter / in Rinse µg

Blank 1

Total Mass Collected µg

08/12/2015

µg 0.04

m³ 1.3736

LEAD: SAMPLING DETAILS

Parameter Units



Mass on Filter / in Rinse

-

0.50

Blank Dates

Units

mg/m³ 0.0005Reported Concentration

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EPA Export 14-04-2016:01:16:51

Sample Runs

30

113.2

10°C

°C

Maximum Filter Temperature

Maximum Temperature Recorded

90

Post-Sampling Leak Rate l/min

% 100.0

Allowable Isokinetic Range %

Ambient Temperature Recorded?

Yes

Units

°C




Absorption Efficiency

APPENDIX 2

Impingers Exit Temperature

Isokinetic Criterion Compliance

MU (Concurrent Water Vapour) Units

Yes

Units Run 1

Isokineticity Acceptable

%

Are Water Droplets Present

Units Run 1

-

-

Isokinetic Variation

-

LEAD: QUALITY ASSURANCE(PAGE 1 OF 2)


Allowable Leak Rate l/min

MU Acceptable


µg/m³

Run 1

Yes

Silica Gel (Concurrent Water Vapour) Units

Units Run 1


Test Conditions Run 1

160

- Yes

Run 1

Detection Limit 0.4

%

Pre-Sampling Leak Rate

l/min 24.48

Filter Temperatures

Less than 50% Faded

Run 1

Mean Sampling Rate

0.49

µg/m³

Allowable MU

Maximum Allowable Temperature

Water Droplets Units

Leak Test Acceptable

Yes

%

No

Allowable Absorption Efficiency %

l/min 0.11

95 - 115

0.12



%

20

5

- Yes

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EPA Export 14-04-2016:01:16:51

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Yes




Allowable Blank

Leak Test Acceptable -

Units Blank 1



mg/m³ N/A

Blank 1

(PAGE 2 OF 2)

Leak Test Results

0.15



Expected Sampling Rate l/min

Units

APPENDIX 2

Validity of Blank vs ELV

20.00

LEAD: QUALITY ASSURANCE

l/min

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EPA Export 14-04-2016:01:16:51





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













≤2%%

Run 1

13.00

%

mg/m³ 0.0001

1.00Lr mg/m³ 0.0001

Symbol


mg/m³

Run 1

K

Units

≤1%

26.0

uTm

Measured Quantities

Vm

mg/m³

Requirement of Standard

mg/m³ 0.0001

0.0001

293.5

% 0.50

N/A

Run 1

UnitsMeasured Quantities


0.0000

Units



uLr % -

L 0.49

uHm % v/v

Standard uncertainty

APPENDIX 2

m³

1.00


1.0

ρm 100.0

-

Hm 0.0

Units

Vm

0.49

Lr

m³1.4430 uVm

uL %

%

0.0000

uρm

0.00

Units Run 1

Tm

0.0001

%

% 13.00

≤1%

0.0000

≤1%

Run 1

-

% N/A


0.0289

Value

26.0

mg/m³

% 26.0

%

Measured Quantities

0.68

1.3556

Run 1

No Requirement

Parameter


0.0001

mg/m³

Symbol

≤2%% 2.00

kPa 0.5

2.0

LEAD: MEASUREMENT UNCERTAINTY CALCULATIONS


% v/v N/A

mg/m³

L mg/m³

Run 1

1.00%

N/A

mg/m³ N/A

% N/A

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EPA Export 14-04-2016:01:16:51

Sample Runs

- -

- -

- -

- -

- -






Span Gas Type Propane In Synthetic Air (5 Grade)

EN 12619:2013

Technical Procedure

Heated Head Filter Used

Probe Material Stainless Steel

Filtration Type / Size 0.1µm Glass Fibre



Span Gas Expiry Date

1.2

Parameter

0.40

Number of Sampling Lines Used

A1


Uncertainty ±mg/m³ 0.46

N/A

Yes

Synthetic Air (5 Grade)

Mean

Standard

15/07/2020

Uncertainty

Value

Span Gas Reference Number

Sample Point I.D.'s

mg/m³

0.46

Span Gas Uncertainty (%)


80.2

1.1 1.1

Heated Line Temperature

1.0187

Span Gas Start Pressure (bar) 100

Gas Cylinder Concentration (ppm)

g/hr

TOTAL VOCs (as CARBON): RESULTS SUMMARY

0.40

CAT-TP-20

APPENDIX 2

Mass Emission

Concentration

180°C

Span Gas Set Point (ppm) 80.20

1 / 1

1.2±g/hr

Zero Gas Type

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EPA Export 14-04-2016:01:16:51

Graphical Trend of Data

APPENDIX 2

TOTAL VOCs (as CARBON): DATA TREND

COVER ME WITH CHART/S

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

14

:05

14

:06

14

:07

14

:08

14

:09

14

:10

14

:11

14

:12

14

:13

14

:14

14

:15

14

:16

14

:17

14

:18

14

:19

14

:20

14

:21

14

:22

14

:23

14

:24

14

:25

14

:26

14

:27

14

:28

14

:29

14

:30

14

:31

14

:32

14

:33

14

:34

14

:35

Co

nce

ntr

atio

n (

mg/

m³)

Total VOCs At Reference Conditions

- Run 1

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EPA Export 14-04-2016:01:16:51

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -

ppm

CA

L 2

CA

L 1

- Yes

-


Run Ambient Temperature Range 10 - 15

Units Run 1

Zero Down Sampling Line (Pre)

APPENDIX 2C

AL

3

± ppm

Run 1

CA

L 3

Units

4.01Allowable Zero Drift

ppm

Span Down Sampling Line (Post) ppm

ppm

ppm

CA

L 1

08/12/2015

ppm

ppm 79.80

Nature of Deviation

(x = deviation applies to the associated run)

ppm

Test Conditions

-

ppm

Units

ppm

Sampling Times -

ppm

Zero Down Sampling Line (Post) ppm

ppm 0.10

0.10

Allowable Span Drift

Sampling Dates

Units Run 1

Parameter

°C

Run Number

± ppm 4.01

Yes

ppm

Zero Drift


Instrument Range ppm 100

0.00

Zero Down Sampling Line (Post)

Span Down Sampling Line (Pre)


Span Down Sampling Line (Post)

Span Drift Acceptable

ppm 79.90


80.2


Run 1

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

Span Gas Value

CA

L 2

0.10ppm

ppm

Span Drift

14:05 - 14:35

Zero Drift Acceptable


Span Down Sampling Line (Pre) ppm

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EPA Export 14-04-2016:01:16:51

k =

ppm to mg/m³

MCERTS Range [B] 15.0

mg/m³

Combined interference

mg/m³

Volume or pressure flow dependence 0.00 mg/m³

% at ELV

Result of Compliance with Uncertainty Requirement in M2 N/A

Ambient temperature dependence

mg/m³

Cal gas conc. 80.2 ppm

use rep at span

Performance characteristic

RUN 1 Units

Response time 45

15.0 mg/m³

Cal gas conc. 128.8

%

0.40 mg/m³ (STP, dry)

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Result of Compliance with Uncertainty Requirement in M2 N/A -

Lack of fit 0.01

RUN 1 Units

% of Value

Expanded uncertainty (no O₂) - at 95% Confidence N/A % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence N/A

160.6

RUN 1 Units

Standard deviation of repeatability at zero

mg/m³

Lower of [A] or [B]

ppm

Range Used [A]

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

Units

- mg/m³ (REF)

15.0

mg/m³

Performance characteristics

mg/m³

Uncertainty of calibration gas 0.00

Atmospheric pressure dependence 0.01 mg/m³

APPENDIX 2

0.45

% of Value

mg/m³

mg/m³

Losses in the line (leak) 0.00

RUN 1 Units

Measurement uncertainty

0.20

mg/m³

Expanded uncertainty (with O₂) - at 95% Confidence

Result 0.40 mg/m³

Combined uncertainty 0.24

-

Repeatability at zero 2.00

Range Used 100.0

Performance characteristics RUN 1

% of value

Repeatability at span level 0.00 % full scale

Deviation from linearity 0.17 % of value

Zero drift 0.13 % full scale

Span drift

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty

associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

Measured concentration

TGN M2 Allowable MU

Limit value

Expanded uncertainty 1.96 0.47 mg/m³

Uncertainty corrected to std conds. (O₂) 0.47 mg/m³ (REF)

RUN 1 Units

Expanded uncertainty (no O₂) - at 95% Confidence 115.13

% range

Dependence on voltage 0.50 % full scale/10V


mg/m³

Combined interference (from MCERTS Certificate) 0.04

-

N/A

% full scale

Conversion 1.61

mg/m³

Standard deviation of repeatability at span level 0.00

mg/m³

Drift 0.09

30

% of value/kPa

Ambient temperature dependence 1.40

mg/m³

Dependence on voltage 0.06

seconds

Number of readings in measurement

% full scale

Volume or pressure flow dependence 1.60

0.13

% of full scale

Atmospheric pressure dependence 0.30

% full scale/10K

% of value


CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51





8th December 2015


CDU-0559


Report Written by

Patrick O'Brien


TE1 TE2 TE3 TE4

Stack Reference



Version 1


Team Leader

Team Leader


MCERTS Level 2

Patrick O'Brien

Report Approved by


Version





Ireland



DELETE & COVER ME

CAT-RT (Version BJ)


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EPA Export 14-04-2016:01:16:51

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY


Monitoring Results


Process Details



Sampling Location




4

7

7

CONTENTS

2

9

3

5

6

8


Guidance Note, AG2.





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EPA Export 14-04-2016:01:16:51



Target Parameters



8th December 2015

(Page 1 of 7)




Site's Licence.




Executive Summary

CAT-RT (Version BJ)

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Parameter

Antimony ¹ < <

Lead ¹ - -


Water Vapour


Stack Gas Velocity

¹

- -



0.43

(Page 2 of 7)

°C


0.41

372



0.0010mg/m³ g/hr

-

0.00027

Executive Summary

Mass Emission

-

MONITORING RESULTS

- g/hr

3.3

0.15

m³/hr

0.46

1.03% v/v

m/s

0.06

23.0

mg/m³

50

0.16


8th December 2015

+/-

Units Result

Concentration

MULimit

+/-

UnitsResult LimitMU

-

0.00010

0.0010 0.00026 - g/hr 0.00010

0.00033

0.00034mg/m³

-

339 45 -

-

CAT-RT (Version BJ)

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Parameter

R1 < <

R1 - -

R1 - -

R1



08/12/20150.0010

30

30

mg/m³ 0.0010

mins

Executive Summary

Sampling

Times

Units

(Page 3 of 7)



8th December 2015


g/hrmg/m³

08/12/2015 11:40 - 11:45

Date(s)

Mass Emission

Antimony

g/hrLead

Velocity & Volumetric Flow Rate

0.00033

12:40 - 13:1008/12/2015

mg/m³ 12:40 - 13:10

0.00034

g/hr


Duration

CAT-RT (Version BJ)

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Normal Operation

Abatement System


(Page 4 of 7)

Executive Summary

PROCESS DETAILS

On

ContinuousContinuous or Batch Process

Plume Appearance

Bag Filter

Not Visible

ValueParameter

Process Status



8th December 2015

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Executive Summary





Yes RPS

CAT Yes RPS


EN 16911-1 (MID) CAT-TP-41

Run


Parameter


Deviation

8th December 2015

(Page 5 of 7)

Testing Analysis

Lead

(Average)

ISO



Standard

Lab

Yes

MCERTS

17025

Testing

EN 14385

ICP-MS

Testing

CAT-TP-06


Lab

Monitoring Analysis

0.001 mg/m³

Procedure

Analytical

Technique

AnalyticalTechnical ISOParameter

ICP-MSCAT Yes Yes

Procedure

LOD


CAT YesWater Vapour

0.001 mg/m³

Antimony

Yes 1.2 m/s


CAT

All

EN 12619:2013

YesCAT-TP-05 YesEN 14790


YesCAT

GravimetricCAT-TP-05

Yes

0.1 % v/vCAT

Yes

M31

M31

17025 Analysis

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51


Platform Details




Value

0.00 0.00

-

-

0.00

Hole

-

Area

Yes


-3.29

Value

Depth

3.29

-

5

0.00Ratio of Above : 1 Yes

< 15°

< 3 : 1

-

Yes

-

Highest Gas Velocity

Yes

m

Lowest Gas Velocity

m/s

Yes

-

3.29

-

-

Required

-

0.03

-

-

Orientation of Duct


Pa

-

-

-

Yes

Traverse 1

m/s


-

Width

Compliant

Vertical

Yes

Parameter


Sample Port Size

Circular

Value

Yes

(Page 6 of 7)

Port Depth

-


9.0

1.00

°

-

--

0

Yes

Units

-

-

m²

m


and EN 15259.


Inside / Outside



Units

-

On Roof

-

-

Mean Velocity

Outside

-

-

-

-

--m/s


Executive Summary

cm

Yes

- -



-


Type

-

0.20


Yes

-

-

-


> 5 Pa


CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51

Photo 3

SAMPLE POINTS

Executive Summary

Photo 2

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4

Line A





CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51



APPENDIX CONTENTS

APPENDICES

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51

Name

CAT-TP-06

CAT-TP-06

-

Heated Probe (3) -

CAT 6.44

Control Box DGM (2)

-

ABB AO2020-URAS26

-

S-Pitot (1)

L-Pitot

-

Equipment I.D.

-

Position


Oven Box (2)



Extractive Sampling

LIST OF EQUIPMENT



S-Pitot (2)

CAT-TP-20

CAT-TP-05

EN 12619:2013

CAT 20.71

15m Heated Line (1)

CAT 17.24

-

CAT 14.53

Equipment I.D.



-

-

CAT 12.53

CAT 3.59

-

Miscellaneous Items



-

-


Oven Box (1)

-

CAT 4.467

Mass View (2)

-


Equipment Type


EN 16911-1 (MID) CAT-TP-41


Mass View (1) -

20m Heated Line (2)

Parameter



Water Vapour



EN 14790

-

EN 14385

EN 14385


CAT 23.26

-

Antimony

Lead

CAT 11.61

SELECT Logger 2 -



Callipers


-

Equipment Type

SELECT Logger 1

1m Heated Line (1)

-


Heated Probe (1)

Barometer


Umbilical (1)



Equipment I.D.

-

-


CAT 13.27


Stopwatch

CAT 3.73

Equipment Type

-

Heated Probe (2)

-

-

CAT 3.59

SELECT FTIR



-

5m Heated Line (1) CAT 20.62

500g Check Weight


Control Box DGM (1)

CAT 3.73-

-

CAT 21.S42



CAT 7.23


MCERTS Number


APPENDIX 1





CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:51



CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p







0.0

1.43 0.30-

Units


-

0.2080

m³/hr

REF ¹

1.17


m³/hr

-

336


%

0.80

p pi

78.32


18.02

Determinand

0.0006

339

Result

1.96

-

kg/m³


Moisture

Conc

0.0012

Pa

0.06

23.0

100.2

% v/v

Units

Component

m³/hr

Result

°C

kg/m³

0.7914 28.01

1.03

kg/m³ 1.28


339

372

1.17

0.99

1.29kg/m³

kPa

0.0103

20.59


-

101.3

Temperature

N₂

0.06



Mass

-

1.25

44.01

-

Units


ppm kg/m³


Conc

1.03

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure


1.03

79.14

Fraction

Density

Dry

0.01

20.80 32.00

Actual

Volume

9.0

Molar Conc

0.03Stack Area, A

APPENDIX 2

mStack Width, W

23.0


m


kPa

0.84

Value

0.20

100.2


0.005Average Stack Static Pressure, Pstatic

m²

-

Units


kPa

°C


CAT-RT (Version BJ)

Page 12 of 30


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EPA Export 14-04-2016:01:16:51

Parameter Parameter







Device Used

--

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

---

-

23.0

-

-

- -

-

--

-

-

-

-

-

-

-

-

-

-

-

-

- - -

-

-

-

-

-

-

- -

-

- -

-

Mean

-

-

-

-

9.0 -

1.170

-

- - - -

- --

-

- -

-

kg/m³Point

Pass

-

m/sPa

Traverse

m

0.101

--° -°C

4.5

9.0 3.29

1

-

-

23.0

5.0

1.170

Units

APPENDIX 2


-

(1 of 1)

kPa

-

-

-

-

Vertical

Pass

1

08/12/2015

Value

-

Depth

-

Velocity

STATIC (Units: Pa)

Value

∆P -

-

-

100.2

Temp

-

-

3.29

-

11:40 - 11:45

Sampling Line A

Units

5 -

Pass

-

-

-Swirl

No

Wet Density

Pa 0.84


CAT-RT (Version BJ)

Page 13 of 30


Unit 328





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EPA Export 14-04-2016:01:16:51

Uc,rel(qV,w) 13.39 %

u(k) 0.005 -

u(∆pi)




- Static Pressure






%

Uc(qV,w)

0.00467

- 645

- 25.4


0.00053

-



- Resolution

- Calibration

- Drift

- Lack of Fit



- φO₂,w

u(pstat) 1.061

u(ρ) 0.00631 -

u(vi) 0.211 Pa

u(v) 0.211 m/s

Uc(v) 0.414 m/s

Uc,rel(v) 12.60

u(φH₂O) 0.053

u(φO₂,w) 0.630



K

u(pc) 175.695 Pa

u(patm) 175.692

- φCO₂,w

- Oxygen, dry


- Water Vapour

- Oxygen, wet


-

-

u(φCO₂,d) 0.002

u(cal) 0.008

u(drift) 0.083

u(fit) 0.033

u(Cf)

APPENDIX 2


0.126

u(M) 0.00003

u(Tc) 1.510

1.061

- u²(qV,w)

- u(qV,w)


20.585

- 0.059

u(φO₂,d) 0.637

u(φCO₂,w) 0.002

- u²(a)/a²

- u²(qV,w)/q²V,w

-

49.8 m³/hr

Pa

u(res) 0.00087

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






Yes

Standard EN 14385




0.06

0.0




Sample Point I.D.'s


Name of Analytical Laboratory

APPENDIX 2

Impinger Material


Borosilicate Glass



1.03



Out Stack

0.0010

Parameter Value

Probe Material

Units Run 1 Mean


Titanium


0.0




Parameter

0.00030.0003Uncertainty ±mg/m³


A1

Parameter



RPS



CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





g

m³





N₂ % v/v 79.14

% v/v 1.03

Units Run 1

g/gmol

9.1

Test

750.0

0.6687

Total % v/v 20.86

No






m³ 0.0070



IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) -


- N/A

61.0



N/A

% v/v 0.06

% v/v 20.80

0.6757

g 5.6

- 1.0180




APPENDIX 2





Vwstd = (0.001246)(Vlc)

% v/v 1.03


m³ 0.7051


28.84



Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)


Qa = (60)(As)(Vs) m³/min 19.5













CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

<

<


<

<

<


Blank Runs

<

<


<

<

<mg/m³ 0.0010

APPENDIX 2










µg 0.02









µg 0.02


Reported Concentration

CAT-RT (Version BJ)

Page 17 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

Yes

µg/m³



-

5




APPENDIX 2









Allowable MU % 20







Yes





MU Acceptable % Yes


Less than 50% Faded %









CAT-RT (Version BJ)

Page 18 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2



l/min 0.40






Allowable Leak Rate






CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













APPENDIX 2

K 2.0

uρm kPa 0.5

Units

mg/m³ 0.0003

mg/m³ N/A

mg/m³ 0.0003

mg/m³ 0.0003

% 27.9

% 27.9

% 27.9

% N/A


mg/m³ 0.0001

≤1%


Measured Quantities

ρm 100.0

Run 1

Run 1

N/A

% 14.00

≤1%


Units

% 0.50

1.000.0001

%

% N/A

% v/v

uVm m³ 0.0141

N/A


≤1%

0.00

Tm 290.9 uTm

Run 1


mg/m³ 0.0000



Measured Quantities

Measured Quantities Units Run 1

Symbol

- N/A


Lr mg/m³

Units Run 1

% 2.00 ≤2%

%

mg/m³ 0.0000 1.00

No Requirement

uHm % v/v 1.0

1.00

L 0.33 uL % -

≤2%

Lr 14.00

L

Hm 0.0

Vm m³ 0.6687

% 0.69

Symbol

Run 1

%


uLr % -




Vm 0.7051

mg/m³ 0.0000

mg/m³ 0.0001

0.33

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






APPENDIX 2









Probe Material



Standard EN 14385


M31







1 / 1


Sample Point I.D.'s A1

Borosilicate Glass





Titanium


Impinger Material

1.03



Parameter Value

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





Total % v/v 20.86


% v/v 1.03

°C

m³/min

N/A

0.6757

m³

17.9


20.80


Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³




APPENDIX 2


% v/v


0.7051



% v/v

0.84

No-

m³ N/A



N/A

m³

5.6

Vwstd = (0.001246)(Vlc)

9.00


23.0

Test Units Run 1

% v/v



1.03

750.0



mmH₂O 61.0




0.5

750.0


g

m³ 0.0070


19.5



g/gmol 28.84



0.03

N/A

N/A

0.06

Qa = (60)(As)(Vs)

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) %

N/A

38.49


103.7

m³/min

- 0.3592




Nozzle area, An

% v/v


m³/min 17.7

N₂ % v/v 79.14


3.00

28.73




Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

17.5

mm²

m³/min

m³/min N/A

N/A

CAT-RT (Version BJ)

Page 22 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

<

-


-

-

-


Blank Runs

-

<

Mass in Back Impinger -

-

-

-


Units

-




Parameter Units

m³ 0.6757

08/12/2015

µg 0.04


Blank 1



0.019µg

- 12:40 - 13:10


Run 1

µg

Calculated Concentration mg/m³



0.6757

APPENDIX 2

Sampling Times

0.500

0.0009

0.03

Parameter

Sampling Dates

ISO

0.67

- 08/12/2015



0.0010

0.60

Blank Dates

µg

Sampling Device -

µg

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

Yes-

5



%

20

0.08

95 - 115


l/min 0.11



Yes

%

No

Run 1

Detection Limit 0.8

%


l/min 23.93

Filter Temperatures

Less than 50% Faded

Run 1

Mean Sampling Rate

0.48

µg/m³

Allowable MU


Units Run 1



160

- Yes


MU Acceptable


µg/m³

Run 1

Yes



%


Units Run 1

-

-


-





Yes

Units Run 1


APPENDIX 2




% 100.0



Yes

Units

°C


90




°C

103.7

10°C

30

CAT-RT (Version BJ)

Page 24 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

l/min


20.00

APPENDIX 2



Units


(PAGE 2 OF 2)

Leak Test Results

0.15

mg/m³ N/A



Blank 1


Units Blank 1





Allowable Blank

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













N/A

Run 1

mg/m³ N/A

% N/A

1.00%

L mg/m³


% v/v N/A

mg/m³

2.0



0.0001

mg/m³

25.9

mg/m³

% 25.9

%

Measured Quantities

0.69

0.6687

Run 1

No Requirement

Parameter

0.0003

%

% 13.00

≤1%

0.0000

≤1%

Run 1

-

% N/A


Run 1

Tm

uρm

0.00

Units

0.0141

Value

Symbol

uL %

%

0.0000

≤2%% 2.00

kPa 0.5

0.33

Lr

m³0.7051 uVm


APPENDIX 2

m³


1.0

ρm 100.0

L 0.33

uHm % v/v

-

Hm 0.0

Vm

290.9

% 0.50

N/A

Run 1



0.0000



uLr % -

1.00

Units

Units

≤1%


mg/m³ 0.0003

0.0001

Units

25.9

uTm

Measured Quantities

Vm

mg/m³

1.00Lr mg/m³ 0.0001

%

mg/m³ 0.0003

Symbol

≤2%%

Run 1

13.00


mg/m³

Run 1

K

CAT-RT (Version BJ)

Page 26 of 30


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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

- -

- -

- -

- -






Zero Gas Type

APPENDIX 2

Mass Emission

Concentration

180°C


1 / 1

0.2±g/hr


0.43

CAT-TP-20

Mean

Standard

15/07/2020

Uncertainty

Value


Sample Point I.D.'s

mg/m³

0.46



80.2

0.1 0.1


1.0187



g/hr

A1



N/A

Yes



0.2

Parameter

0.43

Units Run 1



Parameter




EN 12619:2013

Technical Procedure


CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52



APPENDIX 2


0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

12

:40

12

:41

12

:42

12

:43

12

:44

12

:45

12

:46

12

:47

12

:48

12

:49

12

:50

12

:51

12

:52

12

:53

12

:54

12

:55

12

:56

12

:57

12

:58

12

:59

13

:00

13

:01

13

:02

13

:03

13

:04

13

:05

13

:06

13

:07

13

:08

13

:09

13

:10

Co

nce

ntr

atio

n (

mg/

m³)


- Run 1

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -




12:40 - 13:10


Run 1


Span Gas Value

CA

L 2

0.10ppm

ppm

Span Drift

ppm 79.90


ppm

Zero Drift



0.00



80.2

Sampling Dates

Units Run 1

Parameter

°C

Run Number

± ppm 4.01

Yes-

ppm

Units

ppm

Sampling Times -

ppm


ppm 0.10

0.10


CA

L 1

08/12/2015

ppm

ppm 79.80

Nature of Deviation


ppm

Test Conditions

Allowable Zero Drift

ppm


ppm

ppm




APPENDIX 2C

AL

3

± ppm

Run 1



Units Run 1


CA

L 3

Units

4.01

CA

L 2

CA

L 1

- Yes

-

ppm

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

k =

% full scale


0.13

% of full scale


% full scale/10K

% of value


% full scale

Conversion 1.61

mg/m³


mg/m³

Drift 0.09

30

% of value/kPa


mg/m³


seconds


0.50

mg/m³


-

N/A

% full scale

Span drift




TGN M2 Allowable MU

Limit value



RUN 1 Units


% range


Losses in the line (leak)

-


Range Used 100.0


0.45

% of Value

mg/m³

mg/m³


RUN 1 Units


0.20

mg/m³


Result 0.44 mg/m³


mg/m³


mg/m³



% of value



Zero drift 0.13

Units

-

ppm

Range Used [A]


160.6

RUN 1 Units


mg/m³

Lower of [A] or [B]




Lack of fit 0.01

RUN 1 Units

% of Value




mg/m³ (REF)

15.0

APPENDIX 2

% at ELV



mg/m³


use rep at span


RUN 1 Units

Response time 45

mg/m³


mg/m³


15.0 mg/m³

Cal gas conc. 128.8

%

ppm to mg/m³


CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52





8th December 2015


CDU-0559


Report Written by

Patrick O'Brien


TE1 TE2 TE3 TE4

Stack Reference



Version 1


Team Leader

Team Leader


MCERTS Level 2

Patrick O'Brien

Report Approved by


Version





Ireland



DELETE & COVER ME

CAT-RT (Version BJ)


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EPA Export 14-04-2016:01:16:52

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY


Monitoring Results


Process Details



Sampling Location




4

7

7

CONTENTS

2

9

3

5

6

8






Guidance Note, AG2.

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52



Target Parameters



8th December 2015

(Page 1 of 7)


Executive Summary




Site's Licence.



CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52


Parameter

Antimony ¹ < <

Lead ¹ - -


Water Vapour


Stack Gas Velocity

¹

- -



0.46

(Page 2 of 7)

°C


0.27

0.76

464


- g/hr

0.81

0.20

m³/hr

0.46

1.68

424 400

% v/v

m/s

0.09

22.0

mg/m³

0.0007

Units

mg/m³

-

Result LimitMU


0.0010mg/m³ g/hr

-

0.00028

Executive Summary

Mass Emission

-

MONITORING RESULTS

438

-

0.0004

0.0016 0.00042 - g/hr


8th December 2015

+/-

Units Result

Concentration

MULimit

+/-

0.0007

0.0004

-

-

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

Parameter

R1 < <

R1 - -

R1 - -

R1



08/12/20150.0010

32

32

mg/m³ 0.0016

mins

0.0004

12:00 - 12:3008/12/2015

mg/m³ 12:00 - 12:30

0.0007

g/hr


Duration

Executive Summary

Sampling

Times

Units

(Page 3 of 7)



8th December 2015



g/hrmg/m³

08/12/2015 11:50 - 11:55

Date(s)

Mass Emission

Antimony

g/hrLead

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52


Normal Operation

Abatement System



8th December 2015

(Page 4 of 7)

Executive Summary

PROCESS DETAILS

Parameter

On

ContinuousContinuous or Batch Process

Plume Appearance

Bag Filter

Not Visible

Value

Process Status


CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

8th December 2015



Executive Summary





Yes RPS

CAT Yes RPS


EN 16911-1 (MID) CAT-TP-41

Run


Parameter


Deviation

(Page 5 of 7)

Testing Analysis

Lead

(Average)

ISO



Standard

Lab

Yes

MCERTS

17025

Testing

EN 14385

ICP-MS

Testing


Lab

Monitoring Analysis

0.001 mg/m³

Procedure

Analytical

Technique

AnalyticalTechnical ISOParameter

ICP-MSCAT Yes Yes

Procedure

LOD


CAT YesWater Vapour

0.001 mg/m³

Antimony

CAT-TP-06

Yes 1.2 m/s


CAT

All

EN 12619:2013

YesCAT-TP-05 YesEN 14790


YesCAT


Yes

CAT

Yes

0.1 % v/v

M31

M31

17025 Analysis

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52


Platform Details




Hole

-


Value


Area

Yes

0.00 0.00

-

-

0.00

-0.81

Value

Depth

0.92

-

2


< 15°

< 3 : 1

-

No

-

Yes

Yes

m

Lowest Gas Velocity

m/s

Yes

-

0.78

-

-

Required

-

0.16

-

-

Orientation of Duct


Pa

-

-

-

Yes

Traverse 1

m/s


-

Vertical

Yes

Parameter


Sample Port Size

Circular

Value

(Page 6 of 7)

Port Depth

-


0.5

1.18

°

-

--

Width

Compliant

0

Units

-

-

m²

m


and EN 15259.


Inside / Outside

Yes



Units

-

On Roof

-

-

Mean Velocity

Outside


-


Type

-

0.45


Yes

-

-

-

-

-

--m/s


Executive Summary

cm

Yes


-

-

- -



> 5 Pa

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

Photo 2

Photo 3

SAMPLE POINTS

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4





Line A

A1

A4

A3

A2

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52



APPENDIX CONTENTS

APPENDICES

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52

-

S-Pitot (1)

L-Pitot

-

Equipment I.D.

-

Position

Equipment I.D.


Oven Box (2)

-

CAT 14.53

Name

CAT-TP-06

CAT-TP-06

CAT-TP-20

CAT-TP-05

EN 12619:2013

CAT 20.71

15m Heated Line (1)

CAT 17.24

Equipment Type



Extractive Sampling

LIST OF EQUIPMENT



S-Pitot (2) -

Heated Probe (3) -

CAT 6.44

Control Box DGM (2)

-

ABB AO2020-URAS26



-

-

CAT 12.53

CAT 3.59

-

-

-


Oven Box (1)

-

CAT 4.467

Mass View (2)

-



EN 16911-1 (MID) CAT-TP-41


Mass View (1) -

20m Heated Line (2)

Parameter


Water Vapour



EN 14790

-

EN 14385

EN 14385


CAT 23.26

-

Antimony

Lead

CAT 11.61

SELECT Logger 2 -



Callipers


-



Equipment Type

SELECT Logger 1

1m Heated Line (1)

-


Heated Probe (1)

Barometer


Umbilical (1)



Equipment I.D.

-

-


CAT 13.27


Stopwatch

CAT 3.73

Equipment Type

-

Miscellaneous Items

Heated Probe (2)

-

-

CAT 3.59

SELECT FTIR



-


500g Check Weight


Control Box DGM (1)

CAT 3.73-

-

CAT 21.S42



CAT 7.23



MCERTS Number


APPENDIX 1





CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:52



CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p







0.0


Result

1.96

-

-

0.2080

m³/hr

REF ¹

1.17


m³/hr

-

1.43 0.297-

Units

-

1.25

44.01

417


%

0.80

kg/m³


Moisture

Conc

0.0012

Pa

0.06

22.0

100.0

% v/v

Units

p pi

Mass

Component

m³/hr

Result

°C

kg/m³

0.7914 28.01

1.68

kg/m³ 1.28


424

464

1.18

0.989

1.29

77.81


18.02

Determinand

0.0006

424

kg/m³

kPa

0.0168

20.45


-

101.3

Temperature

N₂

-

Units


ppm kg/m³


Conc

1.68

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure


1.68

79.14

Fraction

Density

Dry

0.014

20.80 32.00

Actual

0.06

Volume

0.6

Molar Conc

0.16Stack Area, A

APPENDIX 2

mStack Width, W

22.0


m


kPa

0.84

Value

0.45

100.0


0.000

m²

-

Units


Average Stack Static Pressure, Pstatic kPa

°C




CAT-RT (Version BJ)

Page 12 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Parameter Parameter







Device Used

--

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

---

-

-

- -

-

1.169

0.92

22.0

-

- -

-

--

-

-

-

-

-

-

-

-

-

-

-

- - -

-

-

-

-

-

-

- -

-

-

2.0

-

-Mean

-

-

0.11

-

-

22.0

0.5

0.6 -

0.78

- -

22.0

- -

- --

-

- -

-

Pass

-

1.169

m

0.031

1.169

22.00.34

--

2.0

°

0.7

-°C

0.3

0.5

3

0.78

kg/m³Point -

4

-

22.0

0.5

2.0

1.169

m/sPa

Traverse Depth

-

Velocity

Units

APPENDIX 2


-

(1 of 1)

1

-Swirl

No

kPa

-

-

-

-

Vertical

Pass

STATIC (Units: Pa)

Value

∆P -

-

-

100.0

2

0.42

Temp

-

-

2.00.78

0.81

-

11:50 - 11:55

Sampling Line A

1

08/12/2015

Value

-

Units

0 -

Pass

-

-

Wet Density

Pa 0.84


1.169

CAT-RT (Version BJ)

Page 13 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52


u(k) 0.005 -

u(∆pi)




- Static Pressure








%

Uc(qV,w)

0.23125

- 49878

- 223.3


0.00053

-



- Resolution

- Calibration

- Drift

- Lack of Fit



- φO₂,w

u(pstat) 1.042

u(ρ) 0.00631 -

u(vi) 0.777 Pa

u(v) 0.390 m/s

Uc(v) 0.764 m/s

Uc,rel(v) 94.14

u(φH₂O) 0.086

u(φO₂,w) 0.626

K

u(pc) 175.695 Pa

u(patm) 175.692

- φCO₂,w

- Oxygen, dry


- Water Vapour

- Oxygen, wet


-

-

u(φCO₂,d) 0.002

u(cal) 0.000

u(drift) 0.083

u(fit) 0.002

u(Cf)

APPENDIX 2


0.086

u(M) 0.00003

u(Tc) 1.505

1.042

- u²(qV,w)

- u(qV,w)


20.450

- 0.059

u(φO₂,d) 0.637

u(φCO₂,w) 0.002

- u²(a)/a²

- u²(qV,w)/q²V,w

-

437.7 m³/hr

Pa

u(res) 0.00087

CAT-RT (Version BJ)

Page 14 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






Yes

Standard EN 14385








0.09

0.0




APPENDIX 2

Impinger Material


Borosilicate Glass



1.68



Out Stack

0.0010

Parameter Value

Probe Material

Units Run 1 Mean


Titanium


0.0




Parameter

0.0003

Sample Point I.D.'s

0.0003Uncertainty ±mg/m³


A1, A2, A3 & A4

Parameter



CAT-RT (Version BJ)

Page 15 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





N₂ % v/v 79.14

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

Units Run 1

g

m³





% v/v 1.68


10.4

Test

750.0

N/A

0.6334

Total % v/v 20.86





m³ 0.0108





- N/A

54.0



% v/v 0.06

% v/v 20.80

0.6442

g 8.7

- 1.0180




APPENDIX 2





Vwstd = (0.001246)(Vlc)

% v/v 1.68


m³ 0.6632


28.84




Qa = (60)(As)(Vs) m³/min 23.2













CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

<

<


<

<

<


Blank Runs

<

<


<

<

<Reported Concentration mg/m³ 0.0010

APPENDIX 2










µg 0.02









µg 0.02


CAT-RT (Version BJ)

Page 17 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

YesDetection Limit Acceptable


-

µg/m³ 5




APPENDIX 2









Allowable MU % 20







Yes





MU Acceptable % Yes











CAT-RT (Version BJ)

Page 18 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2



l/min 0.40






Allowable Leak Rate






CAT-RT (Version BJ)

Page 19 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













APPENDIX 2

K 2.0

uρm kPa 0.5

Units

mg/m³ 0.0003

mg/m³ N/A

% 27.9

% 27.9

% 27.9

% N/A


mg/m³ 0.0001

mg/m³ 0.0003

mg/m³ 0.0003

≤1%


Measured Quantities

ρm 100.0

Run 1

Run 1

% 0.50

% 14.00

≤1%


1.000.0001

%

% N/A

Units Run 1

%


% v/v

uVm m³ 0.0133

Tm 288.7 uTm

Run 1


N/A

mg/m³ 0.0000

Symbol

- N/A


Lr mg/m³

Units Run 1



Measured Quantities

Measured Quantities Units Run 1 Requirement of Standard

≤1%

% 2.00 ≤2%

%

mg/m³ 0.0000 1.00

No Requirement

uHm % v/v 1.0

0.00

1.00

L 0.24 uL % -

mg/m³ 0.0000

mg/m³ 0.0001

L

Hm 0.0

Vm m³ 0.6334

% 0.69

Symbol

≤2%

Lr 14.00 uLr % -




Vm 0.6632

N/A

0.24

CAT-RT (Version BJ)

Page 20 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






APPENDIX 2









Probe Material


Standard EN 14385


M31





1 / 1


Sample Point I.D.'s A1, A2, A3 & A4

Borosilicate Glass







Titanium


Impinger Material

1.68



Parameter Value

CAT-RT (Version BJ)

Page 21 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





Total % v/v 20.86


% v/v 1.68

m³/min

N/A

0.6442

°C

% v/v


m³ 0.0108


15.7


20.80






0.6632



% v/v



N/A

m³

8.7

Vwstd = (0.001246)(Vlc)

0.50


22.0

0.84

Test Units Run 1

% v/v



1.68

750.0

APPENDIX 2




mmH₂O 54.0


No

0.0

750.0


-



g/gmol 28.84

m³/min


23.2

- 0.3592


0.16

N/A

N/A

0.06

Qa = (60)(As)(Vs)






153.96


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)



Nozzle area, An


m³/min 21.2


N₂ % v/v 79.14


0.71

28.66


% v/v

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

m³/min

m³/min N/A

20.9

mm²

N/A

CAT-RT (Version BJ)

Page 22 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

-

-


-

-

-


Blank Runs

<

-


-

-

-


Units

0.50

Blank Dates -

Mass in Front Impingers µg


Parameter Units


0.128


m³ 0.6442

08/12/2015

µg 0.19


Blank 1


0.02

1.047


0.019µg

- 12:00 - 12:30

Run 1

µg


0.6442

APPENDIX 2

Sampling Times

0.900



Parameter

Sampling Dates

0.71

ISO

- 08/12/2015



0.0011

µg

Sampling Device -

µg

CAT-RT (Version BJ)

Page 23 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

Yes-

5



%

20

0.05

95 - 115


l/min 0.11

Yes

%

No


µg/m³

Allowable MU


- Yes

Run 1

Detection Limit 0.9

%


l/min 21.10





MU Acceptable


µg/m³

Run 1

Yes


Less than 50% Faded

Run 1

Mean Sampling Rate

0.42



%


Units Run 1

-


Yes

Units Run 1

-




-


APPENDIX 2






160


% 100.0



Yes

Units

°C

90

°C



98.1

10°C

30

CAT-RT (Version BJ)

Page 24 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

l/min


20.00

APPENDIX 2




Units


Blank 1

(PAGE 2 OF 2)

Leak Test Results

0.15

mg/m³ N/A



Units Blank 1





Allowable Blank

CAT-RT (Version BJ)

Page 25 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ N/A

% N/A

N/A

Run 1

1.00%

L mg/m³


% v/v N/A

mg/m³

2.0


Symbol

≤2%% 2.00

kPa 0.5


0.0002

mg/m³

25.9

mg/m³

% 25.9

%

Measured Quantities

0.69

0.6334

Run 1

No Requirement

Parameter

0.0133

Value

0.0004

%

% 13.00

≤1%

0.0000

≤1%

Run 1

Tm

Run 1

-

% N/A

Overall MU For O₂ Measurement %

0.0000

uρm

0.00

Units

0.24

Lr

m³

m³

1.00


1.0

ρm 100.0

-

Hm 0.0

Units

Vm 0.6632 uVm

uL %

uHm % v/v


APPENDIX 2

uLr % -

L 0.24


mg/m³ 0.0004

0.0002

288.7

% 0.50

N/A

Run 1



0.0000

Units




mg/m³

Run 1

K

Units

≤1%

25.9

uTm

Measured Quantities

Vm

mg/m³

1.00Lr mg/m³ 0.0002

%

mg/m³ 0.0004

Symbol

≤2%%

Run 1

13.00

CAT-RT (Version BJ)

Page 26 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sample Runs

- -

- -

- -

- -

- -






Zero Gas Type

APPENDIX 2

Mass Emission

Concentration

180°C


1 / 1

0.3±g/hr


0.46

CAT-TP-20

Mean

Standard

15/07/2020

Uncertainty

Value


Sample Point I.D.'s

mg/m³

0.46



80.2

0.2 0.2


1.0187



A1



N/A

Yes


g/hr


0.3

Parameter

0.46

Units Run 1



Parameter




EN 12619:2013

Technical Procedure


CAT-RT (Version BJ)

Page 27 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52



APPENDIX 2


0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

12

:00

12

:01

12

:02

12

:03

12

:04

12

:05

12

:06

12

:07

12

:08

12

:09

12

:10

12

:11

12

:12

12

:13

12

:14

12

:15

12

:16

12

:17

12

:18

12

:19

12

:20

12

:21

12

:22

12

:23

12

:24

12

:25

12

:26

12

:27

12

:28

12

:29

12

:30

Co

nce

ntr

atio

n (

mg/

m³)


- Run 1

CAT-RT (Version BJ)

Page 28 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -




12:00 - 12:30

80.2


Run 1


Span Gas Value

CA

L 2

ppm 79.90


0.10ppm



ppm

Span Drift


ppm

Zero Drift



0.00



Sampling Dates

Units Run 1

Parameter

°C

Run Number

± ppm 4.01

Yes-

ppm

Units

ppm

Sampling Times -

ppm


ppm 0.10

0.10

CA

L 1

08/12/2015

ppm

ppm 79.80

Nature of Deviation


ppm

Test Conditions

CA

L 3

Units

4.01Allowable Zero Drift

ppm



ppm

ppm

Run 1



Units Run 1


APPENDIX 2C

AL

3

± ppm

CA

L 2

CA

L 1

- Yes

-

ppm

CAT-RT (Version BJ)

Page 29 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52

k =

% of value/kPa


mg/m³


seconds


% full scale


mg/m³


-

N/A

% full scale

Conversion 1.61

mg/m³


mg/m³

Drift 0.09

30

0.13

% of full scale


% full scale/10K




TGN M2 Allowable MU

Limit value



RUN 1 Units


% range


Losses in the line (leak) 0.50 % of value

Uncertainty of calibration gas 2.00 % of value



Zero drift 0.13 % full scale

Span drift

-


Range Used 100.0


0.45

% of Value

mg/m³

mg/m³


RUN 1 Units


0.20

mg/m³


Result 0.47 mg/m³


mg/m³ (REF)

15.0

mg/m³


mg/m³



APPENDIX 2

Units

-

ppm

Range Used [A]


160.6

RUN 1 Units


mg/m³

Lower of [A] or [B]




Lack of fit 0.01

RUN 1 Units

% of Value



%


% at ELV



mg/m³


use rep at span


RUN 1 Units

Response time 45

15.0 mg/m³

Cal gas conc. 128.8

mg/m³


mg/m³


ppm to mg/m³


CAT-RT (Version BJ)

Page 30 of 30


Unit 328





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EPA Export 14-04-2016:01:16:52




Report Written by

Piotr Nadany

23rd November 2015

Report Date

TE1 TE2 TE3 TE4

TE1 TE2 TE3 TE4

MM 07 881

MCERTS Level 2

Piotr Nadany

Report Approved by


29th 30th October 2015


CDU-0559


Stack Reference



Version 1

MM 07 881

MCERTS Level 2

Team Leader

Team Leader


Version

Exova Catalyst Ireland, Unit 18 Tallaght Business Centre, Whitestown Business Park, Tallaght, Dublin 24

T: +353 86 853 8247

E: [email protected]

Your Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

Waterford

Cork Road Industrial Park


Ireland



CAT-RT (Version BJ)

CDU-0559 A2-4 Abrasive Extraction Honeywell International Technlogies (Report)

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EPA Export 14-04-2016:01:16:52

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY


Monitoring Results


Process Details



Sampling Location




4

7

7

CONTENTS

2

9

3

5

6

8



This test report shall not be reproduced, except in full, without the

written approval of Exova Catalyst Ireland.


Guidance Note, AG2.

CAT-RT (Version BJ)

Page 2 of 32


Unit 328



Sample Date/s: 29th 30th October 2015


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EPA Export 14-04-2016:01:16:52



Target Parameters




(Page 1 of 7)

Exova Catalyst Ireland were commissioned by Honeywell International Technologies Ltd to carry out stack emissions testing on the

A2-4 Abrasive Extraction at Unit 328.


Site's Licence.


Total Particulate Matter, Iron, Titanium


Executive Summary

CAT-RT (Version BJ)

Page 3 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52


Parameter

Total Particulate Matter ¹

Iron ¹ - -

Titanium ¹ < <

Water Vapour


Stack Gas Velocity

¹

- -



°C


(Page 2 of 7)

Volumetric Flow Rate (REF)

0.47

9904

m³/hr

m/s

% v/v

9.55

m³/hr

Executive Summary

Mass Emission

-

30.47

MONITORING RESULTS


0.05mg/m³ g/hr

-

31

0.010

Units

mg/m³

mg/m³

-

5.77

Result

0.02 0.004 - g/hr



g/hr 4.60.59

+/-

Units Result

Concentration

MULimit

+/-

Limit

0.1

660

0.46

0.19

0.1

21.1

1.40

9797 653 15000

0.0

MU

-

CAT-RT (Version BJ)

Page 4 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52

Parameter

R1 - -

R1 - -

R1 < <

R1


0.05 29/10/2015

mg/m³

mins

0.02 30

30

mg/m³

10:10 - 11:13

g/hr

09:00 - 10:0229/10/2015

mg/m³ 09:00 - 10:02

0.19

0.46

Units Concentration

29/10/2015

Sampling

5.77




(Page 3 of 7)

0.59Total Particulate Matter

Units


60

Duration

Executive Summary

Sampling

Times

29/10/2015 09:05 - 09:15

Date(s)

Mass Emission

g/hr

g/hrTitanium

Iron


CAT-RT (Version BJ)

Page 5 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52


Capacity (of 100%) and Tonnes / Hour


N/A



Normal Operation

Abatement System


(Page 4 of 7)

PROCESS DETAILS

Parameter

Process Status


N/A

Fuel

Plume Appearance

Bag Filter

Executive Summary

Not Visible

Value

Feedstock (if applicable)

N/A

On

Batch

CAT-RT (Version BJ)

Page 6 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52




Deviation

1 There are no deviations associated with the sampling employed.

Run


Parameter

ANALYSIS LABORATORIES(with short name reference as appears in the table above)

Exova Catalyst (CAT)

Technique

Analytical

Yes

Gravimetric

MCERTS

17025

Testing

0.1 mg/m³

EN 14385

ICP-MS

Yes YesTotal Particulate Matter


CAT

(Average)17025 Analysis

EN 16911-1 (MID) CAT-TP-41

CAT Yes RPS

Yes

Executive Summary

TestingProcedure

LOD


Yes


RPS

EN 13284-1

(Page 5 of 7)

Testing AnalysisISO



CAT-TP-01 Yes

Lab

YesCAT YesICP-MSTitanium

0.004 mg/m³

Procedure

AnalyticalStandard

Lab

Yes

CAT-TP-06

Yes 1.2 m/s



All


CAT 0.1 % v/v

M31

M31


CAT-TP-03

Technical ISOParameter

0.008 mg/m³

Iron

Water Vapour

Monitoring

CAT

Analysis

CAT Yes

CAT

CAT-RT (Version BJ)

Page 7 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52


Platform Details





Value

Hole

-


Area

0.00 0.00

-

-

0.00

-Yes

< 3 : 1

-

Platform has chains / self closing gates at top of ladders

-9.55

Value

Depth

10.12

-

15


< 15°



> 5 Pa Yes

-

N/A

No

m

Lowest Gas Velocity

m/s

Yes

-

8.83

-

-

Required

-

0.29

-

-

Orientation of Duct


Pa

-

-

-

Yes

Traverse 1

m/s


-

- -

-

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

68.6

Rectangular

Value


-

Vertical

Yes

Parameter


(Page 6 of 7)

Port Depth

On Roof

--

1.15

°

- Yes

0


Inside / Outside

Width

Compliant

-

-

m²

m


and EN 15259.

Units

No


-

Mean Velocity

Outside


Units

-

No

0.36

-

-


Type

-

0.80


-

-

-

-

--m/s


Executive Summary

cm

Yes

Criteria in EN 15259

-

CAT-RT (Version BJ)

Page 8 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52

Photo 3

Photo 2

SAMPLE POINTS

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4





Line A Line B

A1

A2

B1

B2

B3 A3

CAT-RT (Version BJ)

Page 9 of 32


Unit 328





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EPA Export 14-04-2016:01:16:52



APPENDIX CONTENTS

APPENDICES

CAT-RT (Version BJ)

Page 10 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53

-

S-Pitot (1)

L-Pitot

-

-

CAT 14.53

Name

CAT 25.37

CAT 3.73

Equipment Type


Oven Box (2)

ABB AO2020-URAS26

-

-



Equipment I.D.


APPENDIX 1

Stopwatch

Control Box DGM (2)

-

-

Iron

Miscellaneous Items

CAT 7.23

Equipment I.D.

-

Position

Equipment I.D.

CAT 20.71

15m Heated Line (1)

CAT 17.24

CAT-TP-06

CAT-TP-06

Heated Probe (3)


-

-

EN 14385

EN 14385

-

JCT JCC P1 Cooler

-

Oven Box (1)

-

CAT 4.467

Mass View (1)

CAT 23.26


Equipment Type


Team Leader Piotr Nadany MCERTS Level 2

Extractive Sampling

LIST OF EQUIPMENT



S-Pitot (2) CAT 21P59

-

-


CAT 25.36

20m Heated Line (2)

Bernath 3006 FID -

CAT-TP-05

CAT 13.27


Mass View (2)



-

-

-

-

CAT 3.62

Parameter

Total Particulate Matter

EN 14790

Titanium

Water Vapour


-

Easylogger EN-EL-12 Bit -



Callipers


-



1m Heated Line (3)

EN 16911-1 (MID) CAT-TP-41

Mass Flow Controller (2) -


Control Box DGM (1)

CAT 3.73-

-

-



MCERTS Number

Equipment Type

Hioki 5043 (V)

1m Heated Line (1)

-

EN 13284-1


Heated Probe (1)

CAT-TP-01

Barometer


Umbilical (1)



Heated Probe (2)

-

-

CAT 3.59

SELECT FTIR



-


500g Check Weight

M&C PSS

MM07 881 TE1 TE2 TE3 TE4

Technician Donal O Faogain MCERTS Level 1 MM 13 1259 TE1


-

-

-

-

CAT-RT (Version BJ)

Page 11 of 32


Unit 328





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se.

EPA Export 14-04-2016:01:16:53



CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p







Moisture

-

1.2498

44.01

9659


%

0.8037

0.0

m³/hr

101.3

Temperature

N₂

kPa

-

- 0.0140

kg/m³

kg/m³



Units

1.40

kg/m³ 1.280


9797

9904

1.273


-

1.40

Total Pressure


1.40

79.14

Determinand

0.0006

9797

1.4277 0.29696

Mass

-

0.2080

m³/hr

REF ¹

1.267


m³/hr

Result

°C

20.51

pi

kg/m³

1.9635

0.7914 28.01

Fraction

% v/v p

-

Units

Result

Dry

0.01129

20.80 32.00

Actual

0.06

Volume

Units

ppm kg/m³

Conc Conc

M

Wet

r% v/v

kg/m³

m³/hr

0.98913

1.287

78.03


18.02

Conc

0.001180.06

21.1

107.9

Molar Conc

0.29Stack Area, A

APPENDIX 2

mStack Width, W

21.1


m


kPa

kPa

0.85

Value

0.80

107.7


0.238

-Average Pitot Tube Calibration Coefficient, Cp

Average Stack Gas Pressure mmH₂O

Component


m²

0.36

Density

Units


°C


8.2



CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

Parameter Parameter







Device Used

- -

-

---

- -

-

-

-

-

-

-

-

-

-

-

-

-

9.52

1.266

9.02

21.0

21.1

1.267

15.0

-

12.0

12.0

8.2

-

-

-

-

12.09.2

15.0

-

-

-

--

-

-

-

-

-

--

-

-

-

-

- -

-

-

-

- -

-

- - -

-

--

--

-

-

-

-

-

-

-

0.73

-

1.2678.3

-

9.79

1.267

-

12.0

- -

8.83

8.210.12

-

7.5

-

-

- -

21.1

21.0

7.0

8.2

1.266

21.1

9.0

9.68

Mean

9.56

8.4

0.60

-

8.6

1.26621.11.266

21.0 21.0

1.266

12.0

21.10.47

9.96

9.14

9.56

1.267

21.0

0.20

4

kPa

-

Wet Density

-

Swirl

Vertical

Pass

238.0

∆P

-

Value

-

Units

2

238 -


kg/m³

238.0

14.0

Pass

VelocitySwirl

No

21.1

8.83

1.267

3

6

∆P Temp

Sampling Line B

mmH₂O

-

(1 of 1)

2

m

0.07

Pass

5

21.1

10.12

1

1.266

21.10.33

kg/m³

12.0

°C

14.0

°

8.9

7.3

m/s°C

Depth

-

Velocity

107.7

mmH₂O

Traverse

2

1.267

Temp

-

0.85Pa

1.266

Point °

21.07.0

12.0

1.267

m/s

STATIC (Units: Pa)

--

09:05 - 09:15

Sampling Line A


12.0

9.2

10.01

9.59

Wet Density

29/10/2015

Units

APPENDIX 2

Value

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

0.628




%

Uc(qV,w)

0.00116

u(φO₂,w)

- φCO₂,w

- Oxygen, dry


- Water Vapour

- Oxygen, wet


-

-



- Resolution

- Calibration

- Drift

- Lack of Fit



- φO₂,w

K

u(pc) 175.695 Pa

u(patm) 175.692

u(pstat) 0.959

u(ρ) 0.00678

- 113497

- 336.9

m/s

Uc(v) 0.468 m/s

Uc,rel(v) 4.90

0.00053

-

660.3 m³/hr

Uc,rel(qV,w) 6.67 %

u(k) 0.005 -

u(∆pi)




- Static Pressure




u(φH₂O) 0.072

-

u(vi) 0.796 Pa

u(v) 0.239

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

u(φCO₂,d) 0.002

u(cal) 0.675

u(drift) 0.083

u(fit) 0.082

u(Cf)

1.357 Pa

u(res) 0.00087

0.840

u(M) 0.00003

u(Tc) 1.500

20.508

APPENDIX 2



- u(qV,w)

- 0.059

u(φO₂,d) 0.637

u(φCO₂,w) 0.002

- u²(qV,w)

- u²(a)/a²

- u²(qV,w)/q²V,w

-

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






Number of Sampling Points Used 6/6


Titanium

Filter Housing Material Titanium

Probe Material

Parameter Units


Filter Size and Material

In Stack

Mass Emission


Number of Sampling Lines Used 2/2

Run 1

Water Vapour

Concentration

Parameter Units

Uncertainty ±g/hr


Mean

1.35


Parameter

Concentration

0.07

Units

0.59

Blank 1

±% v/v

Standard

47mm Glass Fibre

0.37

Parameter

EN 13284-1

Sample Point I.D.'s

1.35

g/hr 5.8

0.07

4.6

Uncertainty

A1, A2, A3, B1, B2 & B3

% v/v

Value

Maximum

mg/m³ 0.37

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Mean

4.6

APPENDIX 2

5.8

mg/m³ 0.59

Run 1

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)




g

5.6

APPENDIX 2


Nozzle area, An

1.2457

Velocity pressure coefficient, Cp

% v/v

Average square root of velocity heads, √∆P


% v/v 1.35


%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

m³

Nozzle diameter, Dn

mmH₂O

0.0171



11.6

79.14


√mmH₂O

13.7


% v/v

18.5



TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (liquid trap)

Barometric pressure, Pb

mmH₂O

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

0.9450

1.35

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

% v/v

1.2628

g 2.1

-

0.84

m³/min N/A

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min

Stack static pressure, Pstatic

Run 1

m³/min

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

Total sampling time, q

98.7

m/s

-

m³/min

0.29


Average of velocity heads, ∆Pavg

-

min 60

% v/v

°C

155.7

%

N/A


g/gmol 28.84

mm

39.45

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)


Bwo = Vwstd / (Vmstd + Vwstd) 0.0135


m³

0.3592

Area of stack, As

21.0

8.06

mm²

N₂

- N/A


763.2Ps = (Pb + (Pstatic / 13.6) mmHg

-

% wet oxygen measured in gas stream, ACT%O₂w

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

N/A

% v/v 20.86

20.80

% v/v

Total



1.3950

2.84

mmH₂O

7.09

N/A

Qa = (60)(As)(Vs)

m²

34.97

No

Pitot tube velocity constant, Kp

762.8

0.06

-

g/gmol 28.70

167.0


9.66

Vwstd = (0.001246)(Vlc)

mmHg

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)


N/A

N/A

-

m³

m³

57.3

% v/v

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number


Blank Runs

Filter I.D. Number


g

mg

g

29/10/2015

Balance Uncertainty / LOD

0.00009

3.22563



Sampling Times

APPENDIX 2

-

Total Mass in Probe Rinse

10:10 - 11:13

3.04691

0.74


0.00038

g

Total Mass in Probe Rinse g

-Sampling Dates

End Filter Mass

-

Parameter

End Probe Rinse Mass

Blank 1

Start Filter Mass

Parameter Units

47-28131

1.2628

g

0.00023

-

m³


Calculated Concentration

Units

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

g

0.13982

0.14005

g

g

3.22572

-

-


0.37

Start Probe Rinse Mass

0.00051

Sampling Device

PR-47-28131

Start Filter Mass

0.59

mg/m³

Run 1

g

Total Mass on Filter

29/10/2015


g

47-28136

-

0.14030


-

Blank Dates

End Filter Mass


mg/m³

g

0.10

mg/m³

mg 0.47

0.10


1.2628

ISO

3.04742

g

0.13992

PR-47-28136

mg/m³

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

Sample Runs

MU (Concurrent Water Vapour)

-

Units Run 1


Run 1

Units

Pre-Conditioning Temperature °C

°C

mg/m³ 0.15

Water Droplets

Units Run 1

Test Conditions Units

95 - 115

180

Run 1

Overall Weighing Uncertainty ± mg

20

%

98.7

Weighing Uncertainty Acceptable

Ambient Temperature Recorded? -

Overall Weighing Uncertainty

Less than 50% Faded

Run 1

%

No

Allowable Weighing Uncertainty

Run 1

0.19

°C


Yes


TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

21

No

%


Leak Test Results

Yes


%

Run 1

Yes

APPENDIX 2

MU Acceptable

Allowable Leak Rate

l/min 0.10

Allowable MU

(PAGE 1 OF 2)

5.4

Units

-



Run 1

Post-Sampling Leak Rate


l/min

Post-Conditioning Temperature

Units

Filter Temperatures

0.44

Units

Measurement Uncertainty (MU)


%

Mean Sampling Rate

0.24

l/min 21.97

-

Yes

± mg/m³

Weighing Uncertainty Criteria

160

ELV [Daily ELV for IED] mg/m³ 3.00

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:53

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Expected Sampling Rate


-

Run Number

Units Blank 1

-

Yes

Nature of Deviation

Blank Acceptable

Blank Acceptable

Allowable Blank

mg/l


l/min

2.7

Blank 1

mg/m³

Units

0.6

10

l/min

20.00

0.00


Allowable Leak Rate

l/min


Acetone / Water Rinse Value

0.40

mg/l

(PAGE 2 OF 2)

YesLeak Test Acceptable


Acetone / Water Rinse Blank Units Blank

Allowable Blank

Leak Test Results

APPENDIX 2


- Yes

CAT-RT (Version BJ)

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Leak

Mass of Particulate

Uncollected Mass





Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass













Vm

uHm

0.0279

ρm 101.8

≤2%

291.5

% 79.5

-

Units

≤1%

%

% v/v0.0Hm

0.5

1.3950

Tm uTm K 2.0

m³

0.0015

<5% of ELV

% 79.5


0.47

Measured Quantities

mg

% 3.43

≤1%

≤2%


uVm m³

uρm

1.2457

≤1%

mg/m³ 0.47

% 0.46

mg/m³ 0.2149

1.00

N/A

Run 1

2.00

1.00

0.13

Measured Quantities

uUCM mg -

-

Run 1 Requirement of Standard


mg/m³ N/A

Symbol Units

UCM

%

Parameter

0.79

mg/m³ 0.47

Lr mg

-

Units Run 1

0.74

mg/m³ 0.015

mg/m³

%

0.24

Units

0.47

Symbol

0.69

mg/m³

%

Uncertainty in Measurement Units Sensitivity Coefficient

%

Units Run 1

% N/A

%

% v/v N/A

kPa

L 0.46

m mg

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS



Vm

-uL %

1.0

um

Run 1

UCM

L

Run 1

79.5

mg/m³

N/A

mg/m³

N/A

%

0.47

0.743

0.79

Units

0.27

-

0.49

0.1029

0.002


Measured Quantities

Run 1

mg/m³

Measured Quantities

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






Yes

Standard EN 14385


M31


0.46



Probe Material Titanium


Sample Point I.D.'s A1, A2, A3, B1, B2 & B3






1.43


Parameter

0.0104

Mean


0.0470

0.11



APPENDIX 2

Impinger Material


Borosilicate Glass


0.08

Parameter MaximumUnits Blank 1

Uncertainty ±mg/m³


Out Stack

0.0123

Parameter Value


0.0104

Units Run 1


IRON: RESULTS SUMMARY


CAT-RT (Version BJ)

Page 21 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





0.4

Test Units Run 1

g

m³



g/gmol

762.8


Total % v/v 20.86

% v/v


N₂ % v/v 79.14

20.80


Vwstd = (0.001246)(Vlc)

g 8.0



APPENDIX 2

IRON: ISOKINETIC SAMPLING CALCULATIONS

60.0


m³ 0.0100




% v/v

-

1.43

Total mass collected in impingers (liquid trap) g 7.6

N/A

m³ N/A

N/A

N/A

m³ 0.7880

1.43

% v/v 0.06



0.6867


Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³




0.6967



% v/v

28.84



Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)







Qa = (60)(As)(Vs) m³/min 171.1










CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

-

<


-

-

-


Blank Runs

-

<


-

-

-Reported Concentration mg/m³ 0.0123

APPENDIX 2

IRON: SAMPLING DETAILS




µg 0.24














µg 0.13


CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

YesDetection Limit Acceptable


-

µg/m³ 5

APPENDIX 2

IRON: QUALITY ASSURANCE

(PAGE 1 OF 2)








90










Allowable MU % 20

MU Acceptable % Yes















CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -



APPENDIX 2

IRON: QUALITY ASSURANCE(PAGE 2 OF 2)









l/min 15.00Expected Sampling Rate


CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













0.0104

≤1%

Run 1


Units

mg/m³ 0.0104

mg/m³

uρm kPa 0.5

mg/m³ 0.0104

mg/m³ N/A

APPENDIX 2

K 2.0

% 22.2



≤1%

% 0.49

% N/A

% 22.2

% 22.2


mg/m³ 0.0053


% v/v

Measured Quantities

ρm 101.8

1.00


≤1%

% 11.00

Run 1

% N/A

Units Run 1



Measured Quantities


N/A

mg/m³ 0.0001

N/A

No Requirement

%

Symbol Units Run 1

uHm % v/v 1.0

% 2.00 ≤2%

% 0.67

L 0.40

- N/A


Lr mg/m³ 0.0052

Symbol

mg/m³ 0.0012

uVm m³ 0.0158

Tm 298.8 uTm

IRON: MEASUREMENT UNCERTAINTY CALCULATIONS



uL

Vm m³ 0.6867 0.07

1.00

% -

uLr % -

L

Hm 0.0

Vm 0.7880

Run 1

0.40 ≤2%

Lr 11.00

mg/m³ 0.0001

mg/m³ 0.0052

1.00

%

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






APPENDIX 2

TITANIUM: RESULTS SUMMARY




Run 1 Mean


Probe Material



Borosilicate Glass



Titanium


Impinger Material



0.0044



Maximum

Standard EN 14385


M31








Sample Point I.D.'s A1, A2, A3, B1, B2 & B3

Parameter Value

1.43

0.2


Parameter Units

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:53





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





- 0.9450


% v/v 1.43

°C

g 7.6


% v/v 1.43

m³/min

g

N/A

0.6967

m³ 0.0100

Total % v/v

g/gmol 28.84

%


25.8


0.7880




m³

8.0

No

763.2


% dry oxygen measured in gas stream, ACT%O₂d % v/v

% v/v N/A

% v/v

20.86


0.84

9.90


N/A

8.41

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

23.0


Vwstd = (0.001246)(Vlc)

mmH₂O




762.8

APPENDIX 2

TITANIUM: ISOKINETIC SAMPLING CALCULATIONS

Test Units

5.6

Run 1


20.80

m³/min

Total sampling time, q min


-

mmH₂O 60.0Average pressure drop across orifice, ∆H



N/A

N/A

0.06

Qa = (60)(As)(Vs) 171.1

- 0.3592



0.29

30

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) 107.7

39.18



% v/v 79.14

% v/v


Nozzle area, An


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)



Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)


2.90

28.69



m³/min 158.5

N₂

m³/min

% oxygen reference condition, REF%O₂

mm²

156.2

N/A

m³/min N/AQstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

CAT-RT (Version BJ)

Page 28 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

<

<


<

<

<


Blank Runs

<

<


<

<

<


Blank Dates

Units


-

0.0182

TITANIUM: SAMPLING DETAILS

Parameter Units

10.00

2.613

29/10/2015



µg 2.06

12.71

Run 1

µg


- 09:00 - 10:02

Blank 1


0.65

Sampling Times

10.000

Sampling Dates

0.6967

APPENDIX 2

1.224µg


- 29/10/2015

µg


µg



0.0182

Parameter


µg

m³



13.837

0.6967

CAT-RT (Version BJ)

Page 29 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53

Sample Runs

No



%

0.10

95 - 115


Run 1Test Conditions

20

24.82

-

Run 1

MU Acceptable


Units Run 1



Yes

%

No

l/min

UnitsAbsorption Efficiency

5


Yes

Run 1

Detection Limit 8.4

Units

Yes

µg/m³


Run 1

Leak Test Results

Yes

Run 1


µg/m³



Allowable MU

Run 1

l/min


Mean Sampling Rate

0.50

%

%


Less than 50% Faded



-


-


APPENDIX 2

TITANIUM: QUALITY ASSURANCE

(PAGE 1 OF 2)

-


% 100.0


180


Units Run 1


Units

°C

Yes

90

Filter Temperatures

°C

0.10





-

107.7

15°C

30

CAT-RT (Version BJ)

Page 30 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

15.00

APPENDIX 2


l/min




(PAGE 2 OF 2)

Leak Test Results

mg/m³ N/A


N/A

Blank 1

-

Allowable Blank

0.00

Leak Test Acceptable -

Units



Units



Blank 1

Yes

Blank Acceptable

CAT-RT (Version BJ)

Page 31 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ N/A

% N/A

N/A

TITANIUM: MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³

Run 1

0.0000


% v/v N/A


0.0022

≤2%% 2.00

kPa 0.5

1.00%

mg/m³

mg/m³

% 22.2

%

Measured Quantities

0.67

22.2

No Requirement

0.6867

Run 1

Tm

Units

0.7880

Hm 0.0

Units

0.40

Lr

m³

m³

L 0.40

%

2.0

-

0.0000

%

≤1%

≤1%

Run 1

mg/m³

uρm

0.03

1.00

ρm 101.8

Units



-

% N/A


Parameter

N/A

0.0158

Value

Vm

0.0044

%

% 11.00

Run 1



0.0005



1.0

uL

Run 1

11.00

Symbol

mg/m³ 0.0044

0.0022

298.8

% 0.49

Measured Quantities

Vm

≤2%

mg/m³

uLr % -


L

Units

uHm % v/v

Run 1

K

1.00Lr mg/m³ 0.0022


Symbol

uVm

≤1%

%

mg/m³ 0.0044

22.2

uTm

mg/m³

APPENDIX 2

CAT-RT (Version BJ)

Page 32 of 32


Unit 328





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EPA Export 14-04-2016:01:16:53

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland


Report Written by

Piotr Nadany

23rd November 2015


29th - 30th October 2015


CDU-0559


Stack Reference



Version 1

MM 07 881

MCERTS Level 2

Team Leader

Team Leader


MCERTS Level 2

Piotr Nadany

Report Approved by


Version


T: +353 86 853 8247



Waterford

Cork Road Industrial ParkHoneywell International Technologies Ltd

Ireland


A2-9 Wet Scrubber

Report Date

TE1 TE2 TE3 TE4

CAT-RT (Version BJ)CDU-0559 A2-9 Wet Scrubber Honeywell International Technlogies (Report)

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EPA Export 14-04-2016:01:16:53

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY


Monitoring Results


Process Details



Sampling Location




4

7

7

CONTENTS

2

9

3

5

6

8

The testing performed fully meets the technical requirements in Irish

EPA Guidance Note, AG2.





CAT-RT (Version BJ)Page 2 of 26

Honeywell International Technologies LtdUnit 328A2-9 Wet Scrubber

Job Number: CDU-0559, Version 1Sample Date/s: 29th - 30th October 2015


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EPA Export 14-04-2016:01:16:53



Target Parameters


(Page 1 of 7)

Exova Catalyst Ireland were commissioned by Honeywell International Technologies Ltd to carry out stack emissions testing on

the A2-9 Wet Scrubber at Unit 328.


Site's Licence.


Hydrogen Fluoride, Nitric acid, Sulphuric acid


Executive Summary

A2-9 Wet Scrubber






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Parameter

Hydrogen Fluoride ¹ - -

Nitric acid ¹ - -

Sulphuric acid ¹ - -

Water Vapour


Stack Gas Velocity

¹

- -



Volumetric Flow Rate (REF)

0.74

24771

m³/hr

m/s

0.1

22.4

1.8

22991 2993

(Page 2 of 7)

mg/m³

592.6



+/-

% v/v

6.1

m³/hr

4.4 0.620

3225

°C

Mass Emission

MONITORING RESULTS

g/hr

mg/m³

592.60.00 1.1200.05 0.2

A2-9 Wet Scrubber

mg/m³ 1.03

g/hr0.01

UnitsResult Limit

0.2

MU

0.067 g/hr 5.903.523.73

Units Result

Concentration

MULimit

+/-

Executive Summary

0.19

-


30000





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EPA Export 14-04-2016:01:16:53

Parameter

R1 - -

R1 - -

R1 - -

R1


0.05

4.4Nitric acid

mg/m³

0.19

g/hrHydrogen Fluoride

30

23.73

140

14029/10/2015

g/hr


1.1

29/10/2015

Sulphuric acid

g/hr

mins

09:00 - 09:30mg/m³ 29/10/2015



A2-9 Wet Scrubber


(Page 3 of 7)

Units

10:00 - 12:20

09:00 - 09:30


Duration

Executive Summary

Sampling

Times

29/10/2015 11:00 - 11:20

Date(s)

Mass Emission

mg/m³

1.03





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Normal Operation

Abatement System


N/A

Fuel

Plume Appearance

Bag Filter

N/A

On

Continuous

Parameter

Not Visible

Value

(Page 4 of 7)

Executive Summary

PROCESS DETAILS



N/A

A2-9 Wet Scrubber



Process Status






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Standard

Lab


Yes

Executive Summary

Testing




DeviationRun


Parameter

All

CAT-TP-10

Yes

(Average)

ISO



Lab

CAT IC Yes

(Page 5 of 7)

Testing Analysis

Sulphuric acid

Nitric acid 0.049 mg/m³

Procedure

Analytical

Technique

Analytical

CAT-AP-01

CAT-AP-01

CAT-AP-01

Technical ISO

Yes

Parameter

CAT-TP-31 0.049 mg/m³


CAT

CAT

Yes Yes

A2-9 Wet Scrubber

Water Vapour

Monitoring Analysis

CAT Yes

IC

Procedure

LOD

Yes CAT

Yes

EN 16911-1 (MID) CAT-TP-41

CAT

MCERTS

17025

Testing

Hydrogen Fluoride ISO 15713

EN 14791

CAT

Yes


CAT-TP-05 YesEN 14790 Gravimetric

Yes

1 There are no deviations associated with the sampling employed.

CAT 0.1 % v/v

17025 Analysis

IC

0.019 mg/m³CAT

CAT-TP-05

1.2 m/s


Yes





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EPA Export 14-04-2016:01:16:53


Platform Details




Where NM = Not Measured as no Isokinetic sampling was performed.


Value

4" BSP

-

Yes

0.00

-

NM

0.00

-


Area

< 3 : 1

-


-6.08

Value

Depth

6.17

-

NM

0.00Ratio of Above : 1

> 5 Pa Yes

-

Yes

Yes

m

Lowest Gas Velocity

m/s

Yes

-

5.87

-

-

Required

-

1.13

NM

-

Orientation of Duct


Pa

0.00

28.4

Circular

Value


-

Vertical

No

Parameter


(Page 6 of 7)

The sampling location meets all the requirements specified in Irish EPA Guidance Note AG1 and EN 15259, and therefore there

are no improvement recommendations.

Yes

Traverse 1



Inside / Outside

Width

Compliant

Port Depth

--

-

NM

-

m/s

- -

-

Sample Port Size


1.05

°

-

Yes

25

Yes

NM


-

Criteria in EN 15259

-

-

Yes


-

Mean Velocity

Outside


Units

-

Permanent


m²

m

No

-

-

-


Type

-

1.20


NM

-

-

-

--m/s


Executive Summary

cm

NM

-

Units





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EPA Export 14-04-2016:01:16:53

Photo 3

Photo 2

SAMPLE POINTS

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4

Line A

Line B





A2





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EPA Export 14-04-2016:01:16:53



APPENDIX CONTENTS

APPENDICES





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EPA Export 14-04-2016:01:16:53

-

-

S-Pitot (1)

L-Pitot

-

-

CAT 14.53

Name

-

CAT 3.73

Equipment Type

-

Miscellaneous Items

-

Equipment I.D.

Position

Equipment I.D.


Oven Box (2)

Piotr Nadany MCERTS Level 2

Extractive Sampling

LIST OF EQUIPMENT


15m Heated Line (1)

CAT 17.24

Control Box DGM (2)


Equipment Type


Team Leader

CAT-TP-31

CAT-TP-10

CAT-TP-05

Stopwatch

Sulphuric acid

-

ABB AO2020-URAS26

-


S-Pitot (2) -

EN 1911

Heated Probe (3) -

-

-



Equipment I.D.


APPENDIX 1

-

-

-

JCT JCC P1 Cooler

CAT 13.27


-

-


Oven Box (1)

-

CAT 4.467

ISO 15713Hydrogen Fluoride



-

-

CAT 12.53

-

-

Mass View (2)


Mass View (1) CAT 25.36

20m Heated Line (2)

EN 14791

Parameter

EN 14790

CAT 20.71

Bernath 3006 FID -

CAT-TP-31

Water Vapour


-




Callipers


-



1m Heated Line (3)

Nitric acid

EN 16911-1 (MID) CAT-TP-41

Control Box DGM (1)

CAT 3.73-

-

CAT 21.S42



MCERTS Number

Equipment Type

Hioki 5043 (V)

1m Heated Line (1)

CAT 5.53


Heated Probe (1)

Barometer


Umbilical (1)



Heated Probe (2)

-

-

-

SELECT FTIR



-


500g Check Weight

M&C PSS


Technician Donal O Faogain MCERTS Level 1 MM 13 1259 TE1



- -

- -





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EPA Export 14-04-2016:01:16:53



CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p








0.0

kg/m³

-

1.2498

44.01

22586


%

0.8037

-

101.3

Temperature

kg/m³


Moisture

1.4277 0.29696-

Units

Result

1.9635

-

% v/v

Units

1.76

kg/m³ 1.279


22991

24771

1.195


-

79.14 0.98913

1.287

77.75


18.02

Determinand

0.0006

22991

Conc

0.001180.06

22.4

101.7

-

kg/m³

0.7914 28.01N₂

kPa

Density

Dry

0.01416

20.80 32.00

Actual

0.06

Volume

-

Units


ppm kg/m³

Conc

1.76

0.2080

m³/hr

REF ¹

1.187


m³/hr

Conc

M

Wet

r% v/v



3.1

Molar Conc

1.13Stack Area, A

APPENDIX 2

mStack Width, W

22.4


m


kPa

kPa

0.85

Value

1.20

101.7


0.023

Component

Average Stack Gas Pressure mmH₂O

m²

-

Units


°C



Total Pressure

m³/hr


1.76 0.0176

20.43

p pi

Mass

m³/hr

Result

°C

Fraction

kg/m³





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EPA Export 14-04-2016:01:16:53

Parameter Parameter







Device Used

--

--

-

-

-

-

-

-

-

-

-

- -

-

-

-

-

- -

-

-

6.10

-

-

-

- - -

-

-

3.1

-

--

1.187

6.17

22.3

-

-

-

-

-

--

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

- - -

-

--

1.187

1.188

-

-

-

-

-

- -

1.187

22.4

22.4

3.2

3.1 22.3Mean

6.17

- -

1.187

-

22.4

6.07

0.30

22.4

-

- -

3.1

-

-

3

6.17

3.1


kg/m³Point °

22.4

4

-

22.4

6.07

6.072.9

3.1

-

1.187

1.187

m/smmH₂O

-

Units

22.2

Pass

VelocitySwirl

No

kPa

-

Wet Density

-

Swirl

Vertical

Pass

Traverse

23.0

0.90

kg/m³

-

°C

-

°

3.2

3.2

m/s°C

22.0

Wet Density

2

-

m

0.08

6.07

1

1.187

22.4

Pass

∆P

-

STATIC (Units: Pa)

Value

∆P Temp

Sampling Line B

mmH₂O

-

(1 of 1)

2

Depth

-

Velocity

2

1.187

1.12

Temp

--

11:00 - 11:20

Sampling Line A


-

3.1

5.87

6.07

29/10/2015

101.7

Value

0.85

Units

APPENDIX 2

1.187

23 -Pa





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EPA Export 14-04-2016:01:16:53

- Oxygen, dry


- Water Vapour

- Oxygen, wet


-

-




- Resolution



%

Uc(qV,w)

0.00441

u(φO₂,w) 0.626

K

u(pc) 175.694 Pa

u(patm) 175.692

u(pstat) 0.772

u(ρ) 0.00639

0.00053

-

- 1645.2


u(k) 0.005 -

u(∆pi)




- Static Pressure




u(φH₂O) 0.090

- 2706705

- Calibration

- Drift

- Lack of Fit



- φO₂,w

- φCO₂,w


-

u(vi) 1.068 Pa

u(v) 0.379 m/s

Uc(v) 0.742 m/s

Uc,rel(v) 12.21

APPENDIX 2


u(φCO₂,d) 0.002

u(cal) 0.097

u(drift) 0.083

u(fit) 0.012

u(Cf)

1.092 Pa

u(res) 0.00087

0.193

u(M) 0.00003

u(Tc) 1.507

- u(qV,w)


3224.6 m³/hr

- u²(qV,w)

20.433

- 0.059

u(φO₂,d) 0.637

u(φCO₂,w) 0.002

- u²(a)/a²

- u²(qV,w)/q²V,w

-





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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <







Name of Analytical Laboratory CAT

CAT-AP-01

Parameter Value

Probe Material Monel

Filter Housing Material Monel

±g/hr

0.11

Run 1

2.57Water Vapour % v/v

Impinger Material Polyethylene

Absorption Solution 0.1 mol/l Sodium Hydroxide



Yes




A1

47mm Quartz Fibre

1/1


2.57

0.11

1.03Concentration mg/m³

APPENDIX 2

Mean

Mean

HYDROGEN FLUORIDE: RESULTS SUMMARY


Parameter Units

A2-9 Wet Scrubber

Run 1

0.07

1.03

Number of Sampling Points Used

Parameter Units

Mass Emission

0.01

Blank 1

0.07

CAT-TP-10

Sample Point I.D.'s

Concentration mg/m³

1/1

ISO 15713

Technical Procedure

Parameter Units Maximum

3.5 3.5

23.7

±% v/v

g/hr 23.7

Standard

Uncertainty

Uncertainty

0.01





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EPA Export 14-04-2016:01:16:53

Sample Runs

-

-

-

-

-

-

-

-

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

<

-

<

<Calculated Concentration mg/m³ 0.01




Liquid Trap Start Mass g 2521.8

Liquid Trap End Mass g 2546.6


Silica Trap End Mass g 806.9

Total Mass Of Water Vapour g 25.3

Calculated Water Vapour % v/v 2.57


Laboratory Result for Impingers µg/ml 0.05

Volume in Impingers ml 311.7

Silica Trap Start Mass g 806.4

-

Mass in Back Impinger µg 7.8


Laboratory Result for Front Impingers

Laboratory Result for Back Impinger

Volume in Front Impingers

Volume in Back Impinger

µg/ml

µg/ml

ml

ml

4.12

-

0.05

305.1

155.9

Sampling Device MFC / MV

Sample Flow Rate l/min 8.52

mins 140

m³

Sampling Dates



Volume Sampled (STP, Dry) m³ 1.1937

1.2253


29/10/2015

APPENDIX 2

HYDROGEN FLUORIDE: SAMPLING DETAILS


Volume Sampled (STP, Wet)

Duration





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EPA Export 14-04-2016:01:16:53

Sample Runs

1 0 0 1

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

Blank 1


Blank Acceptable

mg/m³

Yes

Yes

Mean Sampling Rate

Yes

0.00

Units

Allowable Blank




0.0

-

l/min 8.52




-

Units Run 1


- No




APPENDIX 2

HYDROGEN FLUORIDE: QUALITY ASSURANCE


Units Run 1


Allowable MU % 20

MU Acceptable % Yes



Test Conditions



Units Run 1




Silica Gel (Concurrent Water Vapour)





Water Droplets





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EPA Export 14-04-2016:01:16:53


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













- N/A

mg/m³ 0.000

mg/m³

Measured Quantities


1.00

L

Units

1.00

Measured Quantities

APPENDIX 2

% 6.5

0.86

Run 1

6.5



Lr

1.1937

Units Run 1

mg/m³ 0.0000

% 0.00 ≤2%

% 2.65

N/A

% 6.5


Symbol Run 1

mg/m³

mg/m³


0.027


%

mg/m³ 0.07

- N/A

% v/v

% N/A

0.07

mg/m³

Vm

uVm


m³


Parameter

mg/m³ 0.0206

No Requirement

0.0274

Lr

uLr2.65

2.00 ≤2%%


HYDROGEN FLUORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

Symbol Units Run 1

0.03

mg/m³ N/A

% N/A

Measured Quantities Symbol Units Run 1

Vm 1.1937 m³ 0.0239

uL %

mg/m³ 0.07

L 0.00

% -

-





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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <








Sample Point I.D.'s A1

Filter Housing Material Monel

Impinger Material Polyethylene

Absorption Solution 1.0 mol/l Sodium Hydroxide



Parameter Value

Probe Material Monel

Standard


CAT-AP-01


0.09 0.09

Maximum


Water Vapour % v/v 1.36 1.36

Uncertainty ±% v/v


1/1



4.4


CAT


EN 1911



APPENDIX 2

NITRIC ACID: RESULTS SUMMARY


A2-9 Wet Scrubber


0.19



Mean





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EPA Export 14-04-2016:01:16:53

Sample Runs

-

-

-

-

-

<

-

-


Blank Runs

<

-

<

<



Silica Trap Start Mass g 834.1

15.7




g 4.2


0.05

834.2

Total Mass Of Water Vapour


Silica Trap End Mass

g 1205.8


1.36



Calculated Water Vapour % v/v

Duration 140

Volume in Front Impingers ml 252.4

g



mg/m³ 0.19

Laboratory Result for Front Impingers µg/ml 0.27

Laboratory Result for Back Impinger

µg 74.3

0.3857

Units Run 1

Liquid Trap End Mass

Sampling Device

Sampling Dates

Volume in Back Impinger ml 123.9

0.3857

µg/ml 0.05



Volume Sampled (STP, Wet) m³

- 29/10/2015

- MFC / MV

mins

APPENDIX 2

NITRIC ACID: SAMPLING DETAILS

Parameter

µg/ml

Volume in Impingers ml

0.04

Laboratory Result for Impingers

314.9





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EPA Export 14-04-2016:01:16:53

Sample Runs

¹ The concentration in the last absorber was less than 5 times the analytical detection limit. 1 7 11 19

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

0.00

MU Acceptable % Yes

Leak Test Results



l/min 10.00

Blank Acceptable

% 6.5

Less than 50% Faded

l/min 0.20



Mean Sampling Rate


Run 1

-

Validity of Blank vs ELV Units

Yes

Allowable Leak Rate



l/min

Blank 1


Allowable MU % 20


%



2.72

Allowable Absorption Efficiency


- Yes

- Yes

N/A ¹

Absorption Efficiency Acceptable - N/A ¹


APPENDIX 2

NITRIC ACID: QUALITY ASSURANCE

Leak Test Results


l/min




%



Units Blank 1

Yes


Units Run 1

Allowable Blank mg/m³ 2.0





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EPA Export 14-04-2016:01:16:53


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













-

%

% v/v N/A

No Requirement

% 6.5

- N/A

N/A


Measured Quantities

≤2%

%

Run 1

2.65

Units Run 1

%

≤2%

Measured Quantities Symbol

0.0000

1.00L


Measured Quantities

%

0.01

1.00


0.3804

mg/m³

mg/m³ 0.01

%

Lr 2.65

0.0076

L 0.00

Run 1

Vm

mg/m³

Units Run 1

Symbol

mg/m³

mg/m³

0.01

Symbol

uVm m³

Parameter



mg/m³

Overall MU For O₂ Measurement N/A

6.5

- N/A

% N/A

mg/m³

Units

0.01

% 6.5

Units

mg/m³

0.000


Measured Quantities

mg/m³

0.3804

0.00

%uLr

Vm

0.0051

0.0039

APPENDIX 2

NITRIC ACID: MEASUREMENT UNCERTAINTY CALCULATIONS

uL % -

mg/m³

Units

0.51

2.00


0.005

Run 1

Run 1

Lr

m³

Run 1





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EPA Export 14-04-2016:01:16:53

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






CAT


19/11/2015

1.36

APPENDIX 2

Absorption Solution

Mean

mg/m³ 0.05

Polypropylene

1.1

Uncertainty ±g/hr

Parameter

0.2


Value

Water Vapour

Parameter

Concentration

Date of Sample Analysis

CAT-AP-01Analytical Laboratory's Procedure

Parameter

±% v/v

Borosilicate Glass

Impinger Material



47mm Quartz Fibre

% v/v 1.36

Out Stack

Filter Housing Material

Maximum

1 / 1

SULPHURIC ACID: RESULTS SUMMARY

0.00


A2-9 Wet Scrubber

Units

g/hr 1.1

A1

Probe Material


0.04

Mean

Concentration

Run 1

EN 14791

mg/m³ 0.04

Titanium

Parameter

Mass Emission

0.2

0.09Uncertainty

HPLC Grade Water

Units Blank 1


0.09


Standard


Units Run 1

0.05

1 / 1

Sample Point I.D.'s





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EPA Export 14-04-2016:01:16:53

Sample Runs

-

-

-

-

-

<

-

-


Blank Runs

<

-

<

<

µg

mg/m³

SULPHURIC ACID: SAMPLING DETAILS

834.2




1.36

Parameter

Calculated Water Vapour

Silica Trap Start Mass g

Laboratory Result for Back Impinger µg/ml

Liquid Trap End Mass

18.8


% v/v

Blank 1

µg/ml 0.05

MFC / MV

APPENDIX 2

Laboratory Result for Impingers

Units

Silica Trap End Mass g

Sampling Times -

Duration


30

µg/ml 0.05


0.3857

Volume in Front Impingers ml 252.4

0.05

Blank Dates -

g 4.2

834.1

Volume in Back Impinger

29/10/2015

0.04

314.9

0.3857



ml 123.9


g

m³

Volume in Impingers ml

15.7

1205.8

Total Mass Of Water Vapour


Volume Sampled (STP, Wet) m³ 0.3857

Laboratory Result for Front Impingers

Sampling Dates -

Parameter


09:00 - 09:30

Sampling Device

mins

-

29/10/2015

Units Run 1





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EPA Export 14-04-2016:01:16:53

Sample Runs

² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

l/min 0.00

0.00


Blank Acceptable

- Yes

N/A ²


Run 1


Water Droplets

Less than 50% Faded

Allowable Leak Rate

-

mg/m³

0.20

Units


0.25


10.00


- Yes

Test Conditions


0.00

Validity of Blank vs ELV Units

Yes

l/min

Blank 1

Pre-Sampling Leak Rate l/min

2.0



Leak Test Results

Units Run 1


Blank 1

l/min


Allowable Blank


Allowable MU %

% 100.0

Allowable Absorption Efficiency % N/A ²


Units Run 1



MU Acceptable

SULPHURIC ACID: QUALITY ASSURANCE

Leak Test Results Units

Units Run 1

Mean Sampling Rate

APPENDIX 2

20



Absorption Efficiency Acceptable

%

% Yes

l/min 12.68





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EPA Export 14-04-2016:01:16:53


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Run 1







0.0076

Overall MU For O₂ Measurement % N/A

0.13

- N/A

mg/m³ 0.0013

0.00

m³

0.00

Units Run 1


No Requirement

Units Run 1

0.3804

≤2%

% N/A

Symbol Units Run 1

% 2.00

-

≤2%


Measured Quantities

m³

Lr mg/m³ 0.001

0.0010

mg/m³



% 2.70

%

APPENDIX 2

SULPHURIC ACID: MEASUREMENT UNCERTAINTY CALCULATIONS


1.00

0.3804 uVm

uL % -

Lr 2.70

Run 1

0.00

uLr %

Vm

Run 1

Units Run 1

mg/m³

% 6.6

0.0000

- N/A

% v/v

Parameter

L mg/m³ 0.000

mg/m³ 0.00

mg/m³

% 6.6

1.00

% 6.6

mg/m³

Vm

L

mg/m³ N/A

0.00

mg/m³

0.00

N/A





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EPA Export 14-04-2016:01:16:53







CDU-0559


Report Written by

Piotr Nadany

23rd November 2015

Report Date

TE1 TE2 TE3 TE4

Stack Reference



Piotr Nadany

Report Approved by


T: +353 86 853 8247



Waterford

Cork Road Industrial Park


Ireland


A2-11 Chemical storage


Version

Version 1

MM 07 881

MCERTS Level 2

Team Leader

Team Leader

TE1 TE2 TE3 TE4

MM 07 881

MCERTS Level 2

CAT-RT (Version BJ)

CDU-0559 A2-11 Chemical Store Honeywell International Technlogies (POST)

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EPA Export 14-04-2016:01:16:53

TITLE PAGE

CONTENTS

EXECUTIVE SUMMARY


Monitoring Results


Process Details



Sampling Location




8

9

3

5

6





2

7

CONTENTS

4

7


Guidance Note, AG2.

CAT-RT (Version BJ)

Page 2 of 38


Unit 328



Sample Date/s: 29th - 30th October 2015


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EPA Export 14-04-2016:01:16:53



Target Parameters




Total Particulate Matter, Nickel, Iron, Titanium


Executive Summary(Page 1 of 7)

Exova Catalyst Ireland were commissioned by Honeywell International Technologies Ltd to carry out stack emissions testing on the

A2-11 Chemical storage at Unit 328.


Site's Licence.


CAT-RT (Version BJ)

Page 3 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53


Parameter

Total Particulate Matter ¹

Nickel ¹ - -

Iron ¹ - -

Titanium ¹ < <

Water Vapour


Stack Gas Velocity

¹

- -



°C


Executive Summary

mg/m³

Mass Emission

-

51.34

MONITORING RESULTS

0.02 0.21

Limit

+/-

m/s

0.2

23.1

0.43

12180


18.7

m³/hr

1.4

11948 606

% v/v

618

0.97

0.09

1.01

Units

g/hr

mg/m³

0.20

mg/m³

-

6.21

Result LimitMU


0.01mg/m³ g/hr

-

96.5

0.007

g/hr 16.10.52

(Page 2 of 7)

+/-

Units Result

Concentration

MU

21000

-

0.08

0.017 -

0.08

-

0.081 - g/hr



CAT-RT (Version BJ)

Page 4 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53

Parameter

R1 - -

R1 - -

R1 - -

R1 < <

R1


g/hr

30/10/20150.01

300.02

30

30

mg/m³

30/10/2015

0.08

mins

mg/m³

Sampling

0.1

08:50 - 09:2030/10/2015

mg/m³ 08:50 - 09:20

1.0

g/hr


60

Duration

Executive Summary

Sampling

Times

09:30 - 10:35Total Particulate Matter

Units

(Page 3 of 7)

0.52




Units Concentration

30/10/20156.2

0.2

Velocity & Volumetric Flow Rate 30/10/2015 09:00 - 09:10

Date(s)

Mass Emission

g/hr

Nickel

Titanium mg/m³

g/hr

08:50 - 09:20

Iron

CAT-RT (Version BJ)

Page 5 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53


Normal Operation

Abatement System




N/A

(Page 4 of 7)

Executive Summary

PROCESS DETAILS

Parameter



N/A

Plume Appearance

Bag Filter

Not Visible

Value

On

Batch

Process Status


N/A

Fuel


CAT-RT (Version BJ)

Page 6 of 38


Unit 328





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Executive Summary


Deviation

All


1 Lowest differential pressure < 5 Pa.


Run


Parameter

The sample points where negative flow was measured during the preliminary traverse were omitted from the sampling

exercise.


CAT

Testing

ICP-MS

ICP-MS

0.005 mg/m³YesYes CATCAT-TP-06

Yes RPS

CAT Yes RPS

RPS

Nickel

(Page 5 of 7)

Testing


Lab

Monitoring

CAT

Analysis

0.001 mg/m³

Procedure

Analytical

ICP-MSCAT Yes

0.11 mg/m³

EN 14385


CAT-TP-01 Yes

Lab


Analysis

(Average)

ISO


Yes YesEN 13284-1

Yes

EN 14385

Procedure

LOD

Titanium

CAT YesWater Vapour

Technique

Analytical

CAT-TP-03

Technical ISOParameter

0.007 mg/m³

Yes

Yes

Gravimetric

MCERTS

17025

Testing

Iron

Standard


Following the agreement between the client and Environmental Agency the velocity/volumetric flow rate were

measured

upstream of the abetment system as the sampling location didn’t meet the requirements of BS EN 13284.

All 1 The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.

Yes

All

CAT-TP-06

1 Ratio highest to lowest velocities > 5 : 1.

Yes 1.2 m/s



CAT


Pitot Tube and ThermocoupleYes

1


EN 16911-1 (MID) CAT-TP-41



1

0.1 % v/v

All

M31

M31

M31

17025 Analysis

CAT

CAT-RT (Version BJ)

Page 7 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53


Platform Details




-

-

0.00

--

9


< 15°

< 3 : 1

Yes

0.00 0.00

-No Local Negative Flow

-18.69

Value

18.85Highest Gas Velocity

Area

4" BSP

-


-

Yes

°

--

-


-

-

> 5 Pa Yes

-

N/A

No

m

Lowest Gas Velocity

m/s

Yes

-

18.51

-

Vertical

-

Required

-

0.18

-

-

Orientation of Duct


Pa

Sample Port Size


-

299.0

Circular

Value


-

-

Depth

Value

Yes

Traverse 1



Parameter

1.02

No

10


Inside / Outside

Yes

-

Units



Units

-

Permanent

-

-

Mean Velocity

Outside

-

m²

m

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and BS EN 15259.

Width

Compliant

Port Depth


-

-

-

-


-


Type

-

-m/s


Executive Summary

cm

Yes

(Page 6 of 7)

0.48


No

-

-

-

m/s

-

CAT-RT (Version BJ)

Page 8 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53

Photo 2

SAMPLE POINTS

Photo 3

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4





Line A Line B Line C

A1

A3

A2

B1

B3

B2

C1

C3

C2 B4

B5

B6

CAT-RT (Version BJ)

Page 9 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53



APPENDICES

APPENDIX CONTENTS

CAT-RT (Version BJ)

Page 10 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-05

-

15m Heated Line (1)

CAT 17.24

Equipment I.D.


-

CAT 14.53

CAT 23.26

Equipment I.D.

-

Position

CAT 3.73

Equipment Type

-

Nickel

Iron

Miscellaneous Items

CAT 13.27

Equipment Type

Extractive Sampling

LIST OF EQUIPMENT

Control Box DGM (2)


Technician Donal O Faogain MCERTS Level 1

-Oven Box (2)


Stopwatch

-

-


Oven Box (1)

-

CAT 4.467

Mass View (2)

-




-


-

Dual Channel Heater Controller CAT 3.8

-

Heated Probe (3)

EN 16911-1 (MID) CAT-TP-41


Mass View (1) -

20m Heated Line (2)

Parameter


-


Equipment I.D.

1Kg Check Weight CAT 17.24

Last Impinger Arm

Bernath 3006 FID -

Water Vapour


EN 14790

-

EN 14385

EN 14385

EN 14385



S-Pitot (2)

M&C PSS 1m Heated Line (3) -

-

-

CAT 4.404

Callipers


-



Equipment Type

Hioki 5043 (V)

Titanium

1m Heated Line (1)

-

EN 13284-1


Heated Probe (1)

CAT-TP-01

Barometer


Umbilical (1)



Control Box DGM (1)

CAT 3.73-

-

CAT 21.S42



-

ABB AO2020-URAS26

CAT 12.53

CAT 3.59

-

CAT 7.23

S-Pitot (1)

L-Pitot

-

-

-

JCT JCC P1 Cooler

Heated Probe (2)

-

-

CAT 3.59

SELECT FTIR



-

5m Heated Line (1) -

500g Check Weight

MM 13 1259 TE1

MCERTS Number


APPENDIX 1


Team Leader Piotr Nadany MCERTS Level 2

MCERTS AccreditationName


- -

- -


CAT-RT (Version BJ)

Page 11 of 38


Unit 328





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EPA Export 14-04-2016:01:16:53



CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p








0.0

kg/m³

1.256


m³/hr

-

11777

Units

Conc

0.00118

Pa

0.06

23.1

107.8

% v/v

Units

Mass

Component

m³/hr

Result

°C

-

1.2498

44.01

1.4277 0.29696-

kg/m³

kPa

0.0144

kg/m³


Moisture


%

0.8037

p


0.7914

18.02

Determinand

pi


1.44

kg/m³ 1.280


11948

12180

1.263

11948

20.50


-

101.3

Temperature

N₂

Result

1.9635

-

-

0.2080

m³/hr

REF ¹

0.0006

20.80 32.00

78.00 28.01

1.287

-

Units


ppm kg/m³


Conc

1.44

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure


1.44

79.14 0.98913

Dry

0.01154

Actual

0.06

Volume

305.0

Molar Conc

0.18Stack Area, A

APPENDIX 2

mStack Width, W

23.1


m


°C


kPa

0.85

Value

0.48

107.7


0.096

m²

-

Units


Fraction

Density

kPa



CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Parameter Parameter







Device Used

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

- -

-

--

-

-

--

-

--

-

-

-

-

1.256

18.85

23.1

-

- -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

- -

-

-

- -

--- -

-

0.36

-

4.0

-

-

--

1.256

1.256

23.2

0.12

-

-

- -

301.0

305.0

18.57

23.1

-

- -- -

0.031

23.1

310.0

3

18.85

kg/m³Point

4

m/s

23.1

Pass

-

2

0.45 299.0

7.0

1.256

-

Traverse

-°C

96.0

8.0

APPENDIX 2


-

(1 of 1)

1

Mean

-

310.0

Units

107.7

Temp

-

-Swirl

No

kPa

-

-

96 -

STATIC (Units: Pa)

Value

∆P -

-

-

-

Vertical

Pass

9.018.51

18.69

-

09:00 - 09:10

Sampling Line A

1

30/10/2015

Value

-

Pa °m --

Pass

-

-

Depth

-

Velocity

Units

-

Wet Density

Pa 0.85


1.256

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

0.00053

-



0.00067

-

%

u(v) 0.219 m/s

Uc(v) 0.429 m/s

Uc,rel(v)

-

u(vi)

Uc,rel(qV,w) 5.08 %

u(k) 0.005 -

u(∆pi)




- Static Pressure





Standard uncertainty associated with the volume flow rate (95% Confidence) Uc(qV,w)

- φO₂,w

- φCO₂,w

- Oxygen, dry


- Water Vapour

- Oxygen, wet


-

-

u(pstat) 5.044

u(ρ) 0.00673



175.764 Pa

u(patm) 175.692

5.044

u(φO₂,w) 0.628

- 315.4

99475

0.073

2.30

u(φH₂O)

K

0.257 Pa

- Resolution

- Calibration

- Drift

- Lack of Fit


u(pc)


u(φCO₂,d) 0.002

u(cal) 9.686

u(drift) 0.083

u(fit) 14.669

u(Cf)

u(Tc) 1.511

APPENDIX 2


- u²(qV,w)

- u(qV,w)


u(φO₂,d) 0.637

u(φCO₂,w) 0.002

20.501

- 0.059

- u²(a)/a²

- u²(qV,w)/q²V,w

-

24.439

u(M) 0.00003

618.2 m³/hr

Pa

u(res) 0.00087

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






CAT-TP-01


Units

0.52



B1, B2, B3, B4, B5 & B6

% v/v

Value

Standard

47mm Glass Fibre

0.22

Parameter

EN 13284-1

Sample Point I.D.'s


Parameter

Concentration

0.16 0.16

16.1

±% v/v

Blank 1

Uncertainty


In Stack


Titanium


Probe Material

Parameter Units

Water Vapour

Parameter Units

Uncertainty ±g/hr

1.68

Technical Procedure

APPENDIX 2

6.2

mg/m³ 0.52

Run 1


TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Mean

16.1

1.68

Run 1

Concentration


Mean

Maximum

mg/m³ 0.22

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)




Velocity pressure coefficient, Cp

Nozzle area, An

Average square root of velocity heads, √∆P

% v/v

11.3

1.1920

√mmH₂O

16.3

mmH₂O

Vwstd = (0.001246)(Vlc)

0.84

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

N/A

No


44.3

0.06


-


mmH₂O

0.0203



15.2

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

1.1

Barometric pressure, Pb

g

Test Units

mmH₂O

Run 1

2.7780

762.8

m³/min



APPENDIX 2

% v/v

Nozzle diameter, Dn





79.14

1.68

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

% v/v

1.2123


763.6Ps = (Pb + (Pstatic / 13.6) mmHg

g


min

-


0.18

% 108.7

m/s

m³/min

N/A


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)



6.60Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

66.9

m³/min

mm

Bwo = Vwstd / (Vmstd + Vwstd) 0.0168

% wet oxygen measured in gas stream, ACT%O₂w


% v/v

-



-

°C

Total

20.8

3.76

1.94

20.86


% v/v 1.68

50.27

N₂


Average of velocity heads, ∆Pavg


mm²

- N/A

0.4590

m³


m³

0.3592

g/gmol 28.84

% v/v

% v/v

20.80

-

g/gmol 28.66

N/A

Qa = (60)(As)(Vs)

34.97

71.6

8.00

60

mmHg



N/A

N/A

-

m³

m³


% v/v

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Sample Runs

Filter I.D. Number



Blank Runs

Filter I.D. Number


30/10/2015


0.00003

mg

gEnd Probe Rinse Mass

g

3.04264

g

g



g

0.13921

0.13961

Sampling Times

APPENDIX 2

-


09:30 - 10:35

Sampling Dates


-

Parameter Units

g

g

47-27863

Start Filter Mass

Blank 1

End Filter Mass

-

Parameter



g


0.00040

-

m³ 1.2123

mg/m³

g

0.11

30/10/2015

-


1.2123

-

Units

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

0.22

Start Filter Mass

0.52

g

Sampling Device

PR-47-27863

mg


0.00023

3.04267


Run 1

3.04864

0.63


0.00024

mg/m³


0.14000



g

47-28183

-

0.27

0.11

-

End Filter Mass

mg/m³

3.04887

g

0.13976

PR-47-28183

mg/m³

Blank Dates

ISO

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Sample Runs


-

°C

(PAGE 1 OF 2)


Run 1

°C

mg/m³ 0.25

Run 1

Overall Weighing Uncertainty ± mg

± mg/m³

Weighing Uncertainty Criteria

Isokineticity Acceptable -

Run 1

Water Droplets

95 - 115

180


Overall Weighing Uncertainty

Units

160

Yes

21


Yes%

108.7

20

°C

Allowable MU

0.24

-

Yes

APPENDIX 2

Run 1

Allowable Leak Rate

0.10


No

%

0.20

Units Run 1

Test Conditions Units

Allowable Weighing Uncertainty

Pre-Conditioning Temperature

%

Units

Run 1

Leak Test Results

Yes


l/min

Filter Temperatures

l/min

Post-Conditioning Temperature

Yes

Units



Weighing Uncertainty Acceptable

%

ELV [Daily ELV for IED] mg/m³ 5.00

Less than 50% Faded

%

Yes

Units Run 1


Units


MU Acceptable

0.43

-



Run 1



9.6

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Blank Runs

Method Deviations

1

x

x

x

x

- - - - -

- - - - -


-

20.00


l/min

Nature of Deviation

Blank 1

l/min

YesBlank Acceptable



Blank Acceptable

Allowable Blank

mg/l

Acetone / Water Rinse Blank Units Blank


2.7mg/l

10

mg/m³

Units Blank 1

-

l/min

Run Number

0.00

Allowable Leak Rate

1.0

Allowable Blank

0.40

APPENDIX 2


Units

0.00

Acetone / Water Rinse Value

l/min

(PAGE 2 OF 2)

Lowest differential pressure < 5 Pa.

The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.

Ratio highest to lowest velocities > 5 : 1.

The sample points where negative flow was measured during the preliminary traverse were omitted from the sampling exercise.

YesLeak Test Acceptable

Leak Test Results

Yes-

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54





Leak

Mass of Particulate

Uncollected Mass





Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass













mg/m³

m³

mg

% 2.14

%

1.1920

1.34

Measured Quantities

mg/m³

294.3Tm

uHm

0.0556

% v/v

uρm 0.5ρm 101.8


0.27

0.0014

<5% of ELV

Measured Quantities

1.00

0.13

≤1%

≤1%

uUCM mg -

0.82Lr mg

Units

Vm

≤2%

Vm

-L 0.47

1.0

≤2%

%

mg/m³ 0.33

%

%

0.17

N/A

% 258.6

2.00

% 0.47

2.7780

-


0.63

0.0

uVm m³

mg/m³

N/A


UCM

258.6

%

mg/m³

% v/v N/A

Symbol Units Run 1

kPa

uL %

m mg

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS



um

Hm

uTm K 2.0

63.9

0.630

0.82

%

Measured Quantities

Units

0.16

-

0.49

mg/m³

Run 1

N/A

Parameter

0.025

mg/m³

0.1286

0.68

%

0.44

- N/A

0.001

Run 1

Run 1

UCM

L

Run 1

≤1%

mg/m³ 1.34

1.00

mg/m³


Units


mg/m³

Symbol Units

-

% N/A

Units

%



Measured Quantities Run 1

0.1072

CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -








Yes

Standard EN 14385




0.15


Borosilicate Glass



1.36



Out Stack

0.0017

Parameter Value

Probe Material

Water Vapour % v/v

0.0017



APPENDIX 2




0.0078


Parameter

0.1

1.36

0.0069

Units Run 1 Mean


Titanium

6/6

Sample Point I.D.'s


Impinger Material

1/3


0.0069


B1, B2, B3, B4, B5 & B6

NICKEL: RESULTS SUMMARY


Parameter

0.1

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)









Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol



g

m³



% v/v 1.36


Test Units Run 1

- 0.4590


20.80

N₂ % v/v 79.14

N/A


Total

0.0


NICKEL: ISOKINETIC SAMPLING CALCULATIONS

22.9

11.3

0.0054



762.8



APPENDIX 2

m³


20.86


- N/A

g 4.3


% v/v 0.06

% v/v

Bwo = Vwstd / (Vmstd + Vwstd)

mmH₂O

0.3953

m³ 0.0136

0.3899Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³


Vwstd = (0.001246)(Vlc)

% v/v 1.36


m³ 0.9280


28.84


% v/v










Qa = (60)(As)(Vs) m³/min 40.3





CAT-RT (Version BJ)

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EPA Export 14-04-2016:01:16:54

Sample Runs

-

<


-

-

-


Blank Runs

-

<


-

-

-Reported Concentration 0.0017

APPENDIX 2

NICKEL: SAMPLING DETAILS









µg 0.02









µg 0.02


mg/m³

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54

Sample Runs

µg/m³ 5Allowable Detection Limit

- YesDetection Limit Acceptable




APPENDIX 2

NICKEL: QUALITY ASSURANCE

(PAGE 1 OF 2)








Allowable MU % 20







Yes





MU Acceptable % Yes











CAT-RT (Version BJ)

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Unit 328





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Blank Runs

Method Deviations

1

x

x

x

x

- - - - -

- - - - -

APPENDIX 2

NICKEL: QUALITY ASSURANCE(PAGE 2 OF 2)






N/A









Allowable Blank mg/m³


CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54





Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Units

% v/v

Measured Quantities

APPENDIX 2

K 2.0

mg/m³ 0.0069

mg/m³ N/A

Run 1

mg/m³

% N/A

mg/m³ 0.0069

Parameter Units

0.0009

mg/m³ 0.0017

% 21.9

% 88.6

% 88.6

≤1%

- N/A


Run 1

Run 1


1.00



%

% N/A

Units Run 1


Symbol Units Run 1

1.00


Lr mg/m³ 0.0008

N/A

mg/m³ 0.0004

Symbol

uVm m³ 0.0186

Tm 300.0

Units Run 1 Requirement of Standard

≤1%

% 0.49

Run 1

%

ρm 101.8 uρm kPa

% 10.00

≤1%

2.00 ≤2%

uTm

0.5

NICKEL: MEASUREMENT UNCERTAINTY CALCULATIONS

uL % -

uLr % -



Hm 0.0

Vm m³ 0.3899

1.00

Lr 10.00

No Requirement

uHm % v/v 1.0

L 0.70

%

N/A

0.70

Vm 0.9280

Measured Quantities

Measured Quantities

≤2%

mg/m³ 0.0008

0.02

% 0.67

%

mg/m³ 0.0000

mg/m³ 0.0000

L

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






Mean


Probe Material

Mean

Standard EN 14385


M31











Sample Point I.D.'s B1, B2, B3, B4, B5 & B6

Borosilicate Glass


Mass Emission g/hr



1.0 1.0

APPENDIX 2

IRON: RESULTS SUMMARY





1.36



Titanium

Parameter Value


Impinger Material

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54





Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





% v/v 1.36


N/A

0.3953


m³ 0.0054

m³/min




Total % v/v 20.86



°C

m³

27.0


20.80


% v/v

% v/v


0.84

1.19


0.3899


No

11.3

0.9280

% v/v 1.36

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)


N/A

21.0

m³

4.3

Test Units Run 1

Barometric pressure, Pb mmHg 762.8

APPENDIX 2

IRON: ISOKINETIC SAMPLING CALCULATIONS

763.6




-

Vwstd = (0.001246)(Vlc)

mmH₂O 22.9



m³


g/gmol 28.84

- 0.3592

N/A

N/A

- 34.97

% v/v 79.14

Nozzle diameter, Dn

m³/min



mm 9.00

mm²


0.18

63.63



Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)



Nozzle area, An


% v/v

m³/min 37.6


1.09

28.69



N₂




0.06

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

Qa = (60)(As)(Vs) 40.3

37.1

m³/min

m³/min N/A

N/A

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54

Sample Runs

-

-

Mass in Back Impinger -

-

-

-


Blank Runs

<

<


<

<

<

Blank Dates

7.00

mg/m³ 0.0849Reported Concentration

-



30/10/2015

µg 0.45

Units

Units




- 08:50 - 09:20


-

IRON: SAMPLING DETAILS

Parameter

4.430

33.545


Blank 1

Sampling Dates

1.115µg


APPENDIX 2

0.15

Run 1

µg

Sampling Times

28.000

0.3953


Parameter

ISO

m³ 0.3953

7.60

Sampling Device

- 30/10/2015



0.0192

µg

µg

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54

Sample Runs

No


%

0.10

%

No

20

5Allowable Detection Limit

-


14.20

%

l/min 0.10

APPENDIX 2

Yes

95 - 115

Mean Sampling Rate

%Allowable MU

Run 1

Yes


Allowable Absorption Efficiency

l/min

µg/m³



- Yes

0.28



Run 1


MU Acceptable


Run 1

Detection Limit 7.0


%

µg/m³



-



(PAGE 1 OF 2)

Less than 50% Faded


Units Run 1


-


-



Yes





180


% 96.7



Yes

Units

°C

90

°C

°C



99.6

14

30

CAT-RT (Version BJ)

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Unit 328





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EPA Export 14-04-2016:01:16:54

Blank Runs

Method Deviations

1

x

x

x

x

- - - - -

- - - - -

l/min

Units


15.00

APPENDIX 2






Blank 1



(PAGE 2 OF 2)

Leak Test Results

0.00


mg/m³ N/A


Units Blank 1





Allowable Blank

CAT-RT (Version BJ)

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Unit 328





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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













N/A

Run 1


mg/m³

Parameter

mg/m³ N/A

% N/A

IRON: MEASUREMENT UNCERTAINTY CALCULATIONS

2.0

% v/v N/A

95.8

% 95.8

%

0.0186

Value

Run 1

uVm

APPENDIX 2

Run 1

Tm

Units

0.0003

≤1%

0.0813

Run 1

0.0093

1.00%

L mg/m³


0.0042mg/m³

0.0003

uρm

0.22

Units


Measured Quantities



Symbol

≤2%%


1.00

-

% 0.67

0.3899

% 11.00

≤1%

Requirement of StandardMeasured Quantities

2.00

kPa 0.5

Vm 0.9280

0.70

uLr %Lr

m³

m³

Units

uL %

uHm % v/v


1.0

L 0.70

ρm 101.8

-

mg/m³ 0.0201

0.0102

300.0

% 0.49

N/A

Run 1


Hm 0.0

Units

mg/m³

Run 1

≤2%%

Run 1

11.00


mg/m³

Run 1

No Requirement

uTm

Measured Quantities

Vm

mg/m³

1.00Lr mg/m³ 0.0093

K

mg/m³ 0.0813

23.6

Symbol

≤1%

%

-

% N/A

Units

CAT-RT (Version BJ)

Page 32 of 38


Unit 328





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Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






1.36

Uncertainty ±% v/v


APPENDIX 2

TITANIUM: RESULTS SUMMARY

0.0166

0.15

Probe Material Titanium


Impinger Material

Value

0.0152



0.15

0.0166






Sample Point I.D.'s B1, B2, B3, B4, B5 & B6

0.0173

0.2

0.0152

Parameter

Borosilicate Glass




Standard EN 14385

Units

0.2


Mean



Mean

Mass Emission g/hr

Maximum

Run 1

Parameter Units

0.2

0.0173

±g/hr


Uncertainty 0.2

Parameter Run 1


Parameter

Units

Blank 1

CAT-RT (Version BJ)

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Unit 328





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Bwo as a percentage





CO₂ (Estimated)

O₂ (Estimated)





m³ 0.0136



N/A

0.3899


1.36

g 0.0

m³


1.19


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

-

m³ 0.3953


-

% oxygen reference condition, REF%O₂

% v/v


% v/v

0.0054



28.69Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

- N/A

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

mmH₂O


% v/v


Bwo = Vwstd / (Vmstd + Vwstd)

% v/v 79.14

11.3

Vwstd = (0.001246)(Vlc) m³

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

% v/v



99.6

1.09√mmH₂OAverage square root of velocity heads, √∆P

m³/min N/A

40.3

min


37.6


0.18

30

Nozzle area, An

m³/min

m³/min

N/A

%

Qa = (60)(As)(Vs)


m³

m³

N/A

N/A


m/s

m³/min

m²

m³/minQstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

Area of stack, As

0.3592

9.00

1.36

% v/v N/A

0.9280


IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) -

3.71


762.8



Units Run 1

4.3

APPENDIX 2

TITANIUM: ISOKINETIC SAMPLING CALCULATIONS

Test

N₂

% v/v 0.06



Nozzle diameter, Dn mm

763.6

mm² 63.63

mmH₂O 22.9

g

0.84

Total % v/v

N/A

20.86

4.3

No


- 34.97


N/A

20.80

g/gmol 28.84

37.1


CAT-RT (Version BJ)

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Unit 328





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Sample Runs

<

<


<

<

<


Blank Runs

<

<


<

<

<

0.3953

APPENDIX 2

3.000µg

2.606Mass in Front Impingers

Parameter

- 30/10/2015

0.3953m³

Blank Dates

Units





mg/m³


µg 0.762

Sampling Times

m³

- 30/10/2015


µg

µg 6.845

Volume Sampled (REF)

1.239

0.0173

Sampling Dates

- ISOSampling Device

- 08:50 - 09:20

Blank 1



µg 3.000

TITANIUM: SAMPLING DETAILS

Parameter

µg



Units Run 1

CAT-RT (Version BJ)

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Unit 328





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Sample Runs

Yes





Units Run 1







Detection Limit Acceptable - No

Yes

-

14


Exit Temperature Acceptable

Allowable MU %

Run 1


Allowable Detection Limit µg/m³ 5


Maximum Temperature Recorded °C


20

MU Acceptable % Yes

Units Run 1






Detection Limit Units






Water Droplets


APPENDIX 2


- Yes

(PAGE 1 OF 2)


CAT-RT (Version BJ)

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Unit 328





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Blank Runs

Method Deviations

1

x

x

x

x

- - - - -

- - - - -





mg/m³ N/A

N/A





Blank Acceptable -



l/min 0.00Post-Sampling Leak Rate

0.00


Allowable Blank

Units Blank 1

(PAGE 2 OF 2)

Leak Test Results

APPENDIX 2

Pre-Sampling Leak Rate l/min

CAT-RT (Version BJ)

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Unit 328





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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Units

-

0.0

% v/v N/A

% N/A

Units

%

Vm


Measured Quantities

0.0001

%

mg/m³



mg/m³

-

Value

≤2%

N/A

Lr mg/m³

0.0021


mg/m³

% 1.00

11.00

1.00

1.00


Symbol

0.49

uρm kPa

TITANIUM: MEASUREMENT UNCERTAINTY CALCULATIONS

Tm 300.0

Run 1

1.0

101.8

L

≤1%

Run 1

Hm


uTm K

0.5

Symbol

uLr


mg/m³

0.70

% N/A

Units

Parameter

mg/m³ 0.0041

≤1%

%

Units Run 1

% N/A

0.0009

Measured Quantities

% 2.00

mg/m³

2.0

L

Measured Quantities

APPENDIX 2

Lr 11.00


ρm

m³ 0.0186

Run 1Measured Quantities Symbol Run 1

uVm

uHm % v/v

0.0019

%

≤2%

% 0.67

Run 1 Run 1

0.0001

Vm 0.9280

95.8

mg/m³ 0.0166

mg/m³ 0.0166

95.8

% 23.6

%

mg/m³ N/A

uL %

m³

No Requirement


% -

Units

0.3899

≤1%

0.0019

0.04

0.70

CAT-RT (Version BJ)

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Unit 328





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environmental protection agency · absolute pressure of stack gas, p s volume of water vapour...

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