energy and exergy analysis of a once through multi stage flash desalination...
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133 THE INTERNATIONAL JOURNAL OF ENGINEERING AND INFORMATION TECHNOLOGY (IJEIT), VOL.6, NO.2,2020
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
Energy and Exergy Analysis of a Once
Through Multi Stage Flash Desalination Unit
at Variable Operational Temperatures
Jamal S. Yassin
University of Misurata/Mechanical Engineering Department, Misurata, Libya [email protected]
Abstract— This paper is to investigate the exergy and energy
analysis of the once through multi stage flash (OT-MSF)
desalination unit at variable operational temperatures. Here
the study is carried out theoretically by developing a
computer package using visual basic 6 as a tool to encode
the program. This program contains input and output pages
where many variables can be studied such as feed water,
final stage and heating steam temperatures as well as
heating steam and distillate mass flow rates with other
variables to study the exergy and energy analysis for each
stage of the unit and for the whole system as a single unit.
The performance parameters considered here are the
performance ratio (PR), the exergetic efficiency and the
specific heat transfer area (sA). The results obtained have
shown a clear influence of the feed water and last stage
temperatures, in which the performance ratio and the
exergetic efficiencies are increased by increasing feed water
temperature and decreased by increasing last stage
temperature. At feed water temperature 30 oC the
performance ratio obtained is 15 and the exergetic efficiency
is 52 % for the OT-MSF unit.
Index Terms: once through, temperatures, specific area,
exergetic efficiency, performance ratio.
I. INTRODUCTION
ater is the life, and there is no life without water,
which is unfortunately decreasing rapidly in many
places due to extensive consumption , rising of
population, increasing standards of living,
industrialization, and in some instances, wasteful water
use and management policies. Nowadays, around 1.7
billion people have shortage for accessing to water,
particularly in the developing countries, especially in
Middle East, South Asia and Africa. The shortage in the
drinking water contributes in 70-80% of diseases in
around 90 developing countries[1].
So the decreasing of water resources and steadily rising
water demand drive us towards new approaches for safe
and reliable water supply for the municipal, agricultural
and industrial sectors. One solution for fresh water
provision is sea water desalination using any
conventional or renewable source of energy.The
continual research and development of desalination
processes have resulted in a variety of commercial
desalination methods. These processes are classified into
major desalination processes that include multi stage
flash, multi effect, vapor compression and reverse
osmosis desalination; while the minor processes include
solar humidification, freezing and electrodialysis
desalination [1].The primary desalination methods used
are multi-stage flash distillation (MSF) that
constitutes44% of the installed world capacity and
reverse osmosis (RO) that constitutes 42%. Therefore,
these two methods constitute about 86% of the total
world capacity. The remaining 14% is made up of
electrodialysis (6%), vapor compression VC (4%) and
multiple effect distillation ME(4%) [2]. These
desalination technologies are energy consuming , and a
comparison of the idealized and actual processes shows
that the actual energy cost of desalination is much higher
than the cost under ideal operation. This corresponds to a
second law efficiency of under 20% and points out that
there are tremendous opportunities in both the MSF and
RO plants for improvements. The first step in any
improvement or enhancement project is diagnostics, and
the most powerful diagnostics tool in thermodynamics is
second law analysis [3].
The second law of thermodynamics (exergy analysis)
becomes further appreciated to measure the performance
of the desalination systems. Exergy analysis interprets for
the obtainable forms of energy in the system streams and
energy supply with a reference environment and
recognizes the major losses of energy/exergy destruction.
This helps in evolving an effective desalination processes
by reducing the hidden losses [4]. However, many
investigations have been conducted in this topic for
processes improvements.
W
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Received 9 Mar, 2020; revised 1 May, 2020; accepted 2 May, 2020.
Available online 3 May, 2020.
Jamal S. Yassin/ Energy and Exergy Analysis of a Once Through Multi Stage Flash Desalination Unit at Variable Operational Temperatures 134
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
Veera Gnaneswar Gude investigated the exergy
analysis of the desalination processes to evaluate the
thermodynamic efficiency of major components and
process streams and identifies suitable operating
conditions to minimize exergy destruction. Well-
established MSF, MED, MED-TVC, RO, solar
distillation, and membrane distillation technologies were
discussed with case studies to illustrate the exergy
performances [5].
Isa, et al., studied the exergy analysis of an optimized
MSF distillation plant based on the latest published
thermodynamics properties of water and seawater
software of the Massachusetts Institute of Technology by
using design and optimized plant operation data. Exergy
flow rates are evaluated throughout the plant and the
exergy flow diagram is prepared in both cases. The rates
of exergy destruction and their percentages are indicated
on the diagram so that the locations of each exergy
destruction can easily be identified. The study concludes
that as a result of an optimization, making the MSFD unit
once-through cooling system to recirculating type by
using cooling tower system, the unit's exergy destruction
pattern changes meaningfully [6].
A.M.K. El-Ghonemy studied the performance of the
seawater multi-stage flash (MSF) desalination plant that
is currently under operation in Al-Khafji operations plant
located in Saudi Arabia (KSA). The objective is to
present field results of this MSF plant operation in order
to measure and evaluate the performance at 70% and
100% capacity during summer (case-1) and winter (case-
2) operation. The results showed that, for the same plant
output, the main cooling water flow rates is decreased
from 47.1% to 20.1% for case-1 and case-2 respectively,
which in turns directly reduces the pumping power by the
same ratio. Consequently, running the large scale thermal
desalination MSF plant in cold regions is more economic
than hot regions for pumping power energy saving
considerations[7].
Nafey et al., presented the design and thermoeconomic
analysis of a proposed multi stage flash-thermal vapor
compression MSF-TVC system. The proposed MSF-
TVC system is analyzed and investigated under different
operating conditions by using the thermoeconomic
methodology. The comparison between the proposed
MSF-TVC system and the conventional MSF system
showed that the gain ratio of the MSF-TVC system is
96% higher than that of the conventional MSF brine
circulation plant. The heat transfer area of the MSF-TVC
is 52 % higher than the conventional MSF. The exergetic
efficiency of the MSF-TVC system is 46 % higher than
that of the MSF system. The unit product cost of the
MSF-TVC system is 19 % lower than that of the
conventional brine circulation multi stage flash (MSF-
BR) system[8].
Adel K. El-Feky in his study focused on the analysis of
the energy and exergy of MSF and MVC units. The
exergy losses due to irreversibility for the subsystems of
the units are evaluated, the specific exergy losses of the
MSF unit is at the range of 63 kJ/kg. The exergy
destruction in heat recovery and heat rejection sections,
brine heater and all the other systems are calculated, these
values are 61, 17, 10, and 12% respectively. The study
showed that, the second law efficiencies of the MSF unit
is around 4 % and for the MVC is around 7%, so these
law efficiencies clarify that there are many ways to
improve the plant performance by reducing the highest
exergy destruction through these systems [1].
Ezzeghni, et al. carried out the exergy analysis of a
brine mixing once through multi stage flash MSF-BM
desalination plant to identify the component that has the
largest exergy destruction. The MSF-BM desalination
plant is located at 30 km north-west of Tripoli the capital
of Libya. Exergy flow rates are estimated all over the
plant and exergy flow diagram is prepared. The results of
the exergy analysis show that the multi-stage flash unit,
pumps and motors are the major sites of highest exergy
destruction, where 61.48 % of the entire input exergy
took place in the MSF unit, and 19.8 % happens in the
pumps and motors [4].
However, this study is conducted to investigate the
exergy analysis of the MSF desalination plant at different
hypothetical operational parameters such as feed water
temperature, steam temperature and brine temperature
with some other variables. In this case a computer
software using visual basic language has been developed
to perform the analysis through the stages of the MSF
desalination unit.
II. ENERGY ANALYSIS OF THE MSF
UNIT
The MSF unit is one of the thermal technologies which
depends on evaporation and condensation techniques in
each stage and it operates at progressively lower
pressures, as water boils at lower temperatures, Figure 1.
For this technique, the feed water is heated under
sufficiently high pressure to prevent boiling, until it
reaches the first “flash chamber.” In the first flash
chamber (stage), the pressure is released and sudden
evaporation or “flashing” takes place. This flashing of a
small portion of the feed continues in each successive
stage, because the pressure in each is lower.
Figure 1. Multi Stage Flash Desalination Unit [10]
Thus, this design offers the benefit of heat recovery.
That is, the feed water passing through the heat
exchanger in the upper section of the flash chamber gains
heat as it condenses the vapor to distillate. Two distinct
sections of each stage are the flashing chamber (where
the vapors are produced) and the condensing section
(where the vapors are condensed) [9].
An essential step in MSF distillation is to maintain the
flashing process for a longer period of time without the
addition of any external heat. Therefore, for this reason,
the temperature and pressure of every stage are stabilized
135 THE INTERNATIONAL JOURNAL OF ENGINEERING AND INFORMATION TECHNOLOGY (IJEIT), VOL.6, NO.2,2020
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
at a lower value than during the previous stage. In the
final stage, the temperature of brine and condensate is
same as the inlet temperature [10].
There are two main layouts for the MSF process. The
first is the once-through (MSF-OT) system and the
second is the brine circulation system.
A. Assumptions of the energy analysis
The assumptions used to develop the energy analysis
of the MSF-OT process include the following:
Steady state operation, which is the industry
standard. Although, system operation may
experience seasonal temperature variations of
the intake seawater, but, such variations are slow
and the system parameters are adjusted
accordingly. Another factor that may change the
system characteristics is the tube fouling, which
results in the increase of the thermal resistance
for heat transfer. This problem is encountered
through the use of on-line ball cleaning system
or tube acid cleaning, which restores conditions
to near clean operation.
Heat losses to the surroundings are negligible.
This assumption is valid, since, the surface to
volume ratio of the MSF plants is very small.
Also, the temperature of the low temperature
stage is very close to the ambient temperature,
which reduces the rate of heat transfer to the
surroundings.
Equal heat transfer area in each flashing stage in
the heat recovery section.
Equal heat transfer area in each flashing stage in
the heat rejection section.
The heat capacities for feed seawater, brine, and
distillate product depend on temperature and
composition.
The overall heat transfer coefficients in the
evaporators depends on the following
parameters:
Flow rate of the condensing vapor.
Flow rate of the brine inside the condenser
tubes.
Temperatures of the condensing vapor and the
brine.
Physical properties of the condensing vapor
and the brine, which includes thermal
conductivity, viscosity, density, and specific
heat.
The tube material, diameter, and wall
thickness.
The fouling resistance.
The percentage of the non-condensable gases.
The overall heat transfer coefficient is the sum
of the thermal resistances expressed in terms of
the inside and outside heat transfer coefficient,
the fouling resistance, and the thermal resistance
of the condenser tube.
The latent heat of formed/condensed vapor
depends on temperature.
Thermodynamic losses include the boiling point
elevation (BPE), the non-equilibrium allowance
(NEA), and demister losses (Tp).
The distillate product is salt free [11].
B. Elements of the energy analysis
The energy analysis of the MSF-OT process is
based on the following elements:
- Overall material balance.
- Stages and condensers temperature profiles.
- Stage material and salt balance.
- Condensers and brine heater heat transfer area.
- Stage dimensions.
- Performance parameters [12].
Figure 2. OT-MSF Flashing Stage Variables [12]
C. Mathematical modeling of the energy analysis
According to Figure. 2 the overall material balance
equations is given by
(1)
Where M is the mass flow rate and the subscript b, d,
and defines the brine, distillate, and feed.The overall salt
balance is given by
(2)
Where X is the salt concentration.
The temperature distribution in the MSF-OT system is
defined in terms of four temperatures; these are the
temperatures of the steam, Ts, the brine leaving the
preheater (top brine temperature), To, the brine leaving
the last stage, Tn, and the feed seawater, Tf. A linear
profile for the temperature is assumed for the flashing
brine and the seawater flowing inside the condenser
tubes.
The temperature drop per stage, ΔT, is obtained from
the relation
(3)
Where n is the number of stages
Then the general expression for the temperature of
stage j is
(4)
By neglecting heat transfer losses in each stage the
feed water temperature increment stays the same and is
equal to that of the brine temperature drop, thus:
Jamal S. Yassin/ Energy and Exergy Analysis of a Once Through Multi Stage Flash Desalination Unit at Variable Operational Temperatures 136
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
Then
(5)
Stage Material and Salt Balance
The amount of flashing vapor formed in each stage
obtained by conservation of energy within the stage,
where the latent consumed by the flashing vapor is set
equal to the decrease in the brine sensible heat. This is
(6)
Where y is the specific ratio of sensible heat and latent
heat and is given by:
(7)
In this equation λav is the latent heat and is calculated
at average temperature , thus:
(8)
The general form for the total summation of the
distillate formed in all stages, Md is given by
(9)
The flow rate of the brine stream leaving stage (j) is
given by
(10)
The salt concentration in the brine stream leaving stage
jis given by
(11)
The flow rate of the heating steam, Ms is obtained the
energy balance equation for the brine heater, where
(12)
Brine Heater and Condensers Heat Transfer Areas
The brine heater area is given by
(13)
Where LMTD is the log mean temperature difference
of the brine heater and is given by:
(14)
Also Ub is the overall heat transfer coefficient of the
brine heater at steam temperature and is calculated at the
following correlation [12]:
(15)
The heat transfer area for the condenser in each stage is
assumed equal. Therefore, the calculated heat transfer
area for the first stage is used to obtain the total heat
transfer area in the plant. The condenser heat transfer area
in the first stage is obtained from
(16)
Where Uc is the overall heat transfer coefficient of the
condenser and is calculated at the condensing vapor
temperature (Tv) as follows [12]:
(17)
The condensing vapor temperature in the first stage is
given by:
(18)
In the above equations (BPE) is the boiling point
elevation, (NEA) is the non- equilibrium allowance and
( ) is the temperature drop in the demister.Boiling
point elevation (BPE) is function of salt concentration X
and temperature T, and can be obtained from the
following correlation [12]:
(19)
Where
While non-equilibrium allowance (NEA) is given by:
Where NEA10 is obtained from:
Where H is the gate height and Vb is the brine mass
velocity per chamber width. Then the total heat transfer
in the plant is obtained by summing the heat transfer area
for all condensers and the brine heater, thus:
(20)
Stage Dimensions
Calculations of the stage dimensions include the gate
height, the height of the brine pool, the stage width, and
the stage length. The length of all stages is set equal to
the length of the last stage and the width of all stages is
set equal to the width of the first stage. The height of the
brine pool must be higher than the gate height, this is
necessary to prevent bypass of the vapors between
stages(vapor blow through). The gate height (GH) is
obtained in terms of the stage pressure drop (AP), the
brine density (ρbi), the weir friction coefficient (Cd), the
stage width (W), and the feed flow rate (Mf). For stage j
the gate height is:
(21)
137 THE INTERNATIONAL JOURNAL OF ENGINEERING AND INFORMATION TECHNOLOGY (IJEIT), VOL.6, NO.2,2020
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
The brine pool height is set higher than the gate height
by 0.2 m from designers experience [12].
(22)
Where
and
(23)
Where Pj and Pj+1 are the pressures in stages j and
j+1, and Vbis the brine mass velocity per chamber width.
The length of the last stage is determined as a function of
the vapor flow rate, Dn, the vapor density, ρvn., the vapor
allowable velocity, Vvn, and the stage width, W.
(24)
The cross section area for each stage, As is then
calculated
(25)
Performance Parameters The system performance parameters are defined by the
thermal performance ratio, PR and the specific heat
transfer area, sA. The performance ratio is the defined as
the amount of distillate product produced per unit mass of
the heating steam. This is
(26)
The specific heat transfer area is defined as;
(27)
III. EXERGY ANALYSIS OF THE MSF UNIT
The impetus for new tools for a comprehensive and
accurate analysis of industrial and energy utilization
systems comes from the need for sustainable
development that could be impeded by exhausting energy
sources and deteriorating environment. Exergy evaluation
provides insight to achieve highest technological
efficiency at the lowest cost while meeting the social and
legal conditions. Exergy analysis is generally carried
through various stages of process development including
design phase and when evaluating economic feasibility of
a system. It is very critical in estimating the process
economics, natural resource utilization and environmental
impacts of a system because exergy performance depends
on the environmental conditions (temperature and
pressure) [13].
Exergy analysis identifies pathways to increase energy
efficiency in a system, which benefits the environment by
avoiding excess energy use, associated resource
consumption, and environmental pollution. Improving
energy efficiency increases both economic and
environmental benefits [14].
The difference between energy and exergy in any
system is that the first is conserved while the second is
not conserved unless in reversible processes which is
ideal case. Exergy is that part of energy that can be
transformed into other forms of energy. It is the
maximum theoretical work obtainable from an overall
system consisting of a system and the environment as the
system comes into equilibrium with the environment
(passes to the dead state)[15].
Different forms of energy flows are utilized in
desalination processes which include kinetic, potential,
heat, mechanical, electrical, chemical, and radiation
energies, as shown in Figure. 3 [16]. According to this
figure there are two forms of exergy: physical
(mechanical and thermo-mechanical) and chemical
(reactions and separations).
Figure 3. Types of Exergy
Thermal desalination processes account for the heat
and mass balances thus involving all forms of exergy, but
the dominant is the thermo-mechanical and the others are
very small which can be neglected, and this what is
considered in the current analysis of the MSF unit. In
this unit in each stage there is a phase change process
with evaporation and condensation as shown in Figure. 4
[5].
Figure 4. Concept of Phase Change Desalination
According to the control volume of this process the
general formula of the rate of exergy transfer is given
by: [15].
At steady state, dEcv/dt = dVcv/dt =0, giving the steady-
state exergy rate balance
In the above equations (e) is the specific flow exergy
and is given by
(28)
Jamal S. Yassin/ Energy and Exergy Analysis of a Once Through Multi Stage Flash Desalination Unit at Variable Operational Temperatures 138
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
Where the last two terms are the kinetic energy and
potential energy, which are almost equal in the inlet and
outlet of the stage, thus their differences can be neglected
in the analysis, so the equation becomes:
(29)
Where h0 and s0 are the enthalpy and entropy of the
stream at the dead state (ambient conditions). In the MSF
process, the streams are pure water, seawater, and heating
steam. To find the specific flow exergy of the stream the
correlations suggested by Sharqawy et al. [17] for the
thermo-physical properties of the saline water are used.
For a given set of operating conditions and the
corresponding properties of the working fluid, the rates of
exergy destruction and exergy loss for each component of
the process can be computed from the above equations.
The following measures can now be defined to assess the
thermodynamic performance of the components of a
system and the entire system [18]:
Exergy destruction ratio for component c of the
system, yD,c:
Exergy destruction ratio for complete system,yD:
Exergy loss ratio for the complete system, yL:
Exergetic efficiency, ψ:
(30)
The exergy destruction rate (irreversibility) is related
to the entropy generation rate by the Gouy–Stodola
equation as follows:
yD= T0 × Sgen (31)
IV. RESULTS AND DISCUSSION
The current study about OT-MSF desalination unit is
carried out theoretically by developing a software
program using visual basic 6 with many pages to input
the influential parameters on the performance of this unit
and get output required results. These parameters are the
feed water temperature (Tf), number of stages, last stage
temperature (Tn), total distillate flow rate (Md) and the
heating steam temperature (Ts). The resulted performance
parameters are the performance ratio (PR), the stage and
unit exergetic efficiencies, and the total specific heat
transfer area. Due to change of temperatures during flow
from one stage to another the physical properties of the
saline water such as specific heat, density and salinity
have been considered variable and function of
temperatures, as well as the distillate water. In all cases
two variables, such as feed water temperature (Tf) and
last stage temperature (Tn), are depicted simultaneously
as family curves to infer their influence on the
performance parameters.
Figure. 5 shows the influence of feed water
temperature and the last stage temperature on the
performance ratio which indicates about the thermal
energy used to produce the fresh water. The values of the
both temperatures are selected within the ranges of
operation that could be applied on the unit, which are
helpful in designing the unit. By fixing the value of
temperature at the last stage (Tn) it is noticed that the
performance ratio increases as feed water temperature
increases, while the opposite happened with the
increasing of (Tn). This means that by using preheaters to
raise the temperature of the feed water from any source of
heat such as condensation heat or solar energy will
improve the performance of the OT-MSF desalination
unit. In the other hand this ratio drops with increasing the
heating steam temperature (Ts) at a certain last stage
temperature (Tn) as shown in Figure.6, this due to the
increasing in the heating energy needed to raise the
temperature of the heating steam.
Figure 5. Performance ratio vs. Feed Water Temperature and Last Stage
Temperature.
Figure 6. Performance Ratio vs. Feed Water Temperature and Heating
Steam Temperature.
The other important parameter is the exergetic
efficiency which determines the causes of losses and how
we can improve the performance of the system. Here in
Figure.7 at a certain number of stages this parameter
increases with Tf and drops with Tn this due to the
decrease of the total exergy destruction of the all stages
with the feed temperature, which improves the stage
exergetic efficiency as shown in Figure. 8. The total
exergy destruction is the summation of all exergy
destructions of the stages, and it is the difference between
the inflow and outflow exergies of the stages. While by
increasing the last stage temperature Tn this efficiency
139 THE INTERNATIONAL JOURNAL OF ENGINEERING AND INFORMATION TECHNOLOGY (IJEIT), VOL.6, NO.2,2020
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
goes down, due to increase in the exergy destruction of
the last stage.
Figure 7. Unit Exergetic Efficiency vs. Feed Water Temperature and
Last Stage Temperature.
Figure 8. Stage Exergetic Efficiency vs. Feed Water Temperature and
Last Stage Temperature.
Also it is noticed that the unit exergetic efficiency goes
down by increasing the number of stages at a certain feed
water temperature as shown in Figure. 9, and by
increasing(Ts) as shown in Fig. 10. This means that there
should be an optimum case to design the unit by selecting
the proper parameters according to the productivity
needed and the operational conditions.
Figure 9. Unit Exergetic Efficiency vs. Stage Number and Feed Water
Temperature.
Figure 10. Unit Exergetic Efficiency vs. Feed Water Temperature and
Heating Steam Temperature.
The total specific heat transfer area is very important
factor in designing the desalination unit, and it is the
summation of the condensation areas of the all stages
with respect to the fresh water productivity. Here we see
that this parameter influences with the operational
temperatures, where it increases with (Tf) and decreases
with (Tn) as shown in Figure. 11 , and with (Ts) as shown
in Figure.12. So in this case we have to choose the
optimum condition suitable to give the higher
productivity at a minimum heating transfer area.
Figure 11. Total Specific Area vs. Feed Water Temperature and Last
Stage Temperature.
Figure 12. Total Specific Area vs. Feed Water Temperature and Heating
Steam Temperature.
V. CONCLUSIONS
From the results obtained in this study about the
exergy and energy analysis of the OT-MSF desalination
unit, which is carried theoretically, one can conclude the
following:
1. The performance ratio (PR) of the unit has been
influenced by the operation temperatures, where
it is increased by increasing the feed water
temperature (Tf), and goes down by increasing
the heating steam temperature (Ts) and last stage
temperature (Tn).This means that the operation
process of the unit should be set at an optimum
case to get the higher productivity.
2. The exergetic efficiency of the stages or of the
unit get improved also by increasing the feed
water temperature (Tf), while get dropped by
increasing the heating steam temperature (Ts)
and the last stage temperature (Tn), which
influences on the value of the performance ratio
as discussed in the previous point. The lower
exergetic efficiency means more exergy
destruction and higher energy losses, which
Jamal S. Yassin/ Energy and Exergy Analysis of a Once Through Multi Stage Flash Desalination Unit at Variable Operational Temperatures 140
www.ijeit.misuratau.edu.ly ISSN 2410-4256 Paper ID: EN114
reflects badly on the economic aspect of the
desalination process.
3. The total specific heat transfer area of the unit
increases with the feed water temperature
sharply at low values of the last stage
temperature, and smoothly at higher
temperatures. Thus due to the difference
between these two temperatures, if it is small
this means that we need more areas, and if it is
large we need less areas. Although the
productivity will be higher at large areas, it is
not preferred unless we make compromise with
other variables such as steam heating
temperature to find the best performance.
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