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Hazardous Waste Policies and

Procedures Manual

Prepared by California State Polytechnic University, PomonaEnvironmental Health & Safety Department

3801 West temple AvenuePomona, California 91768

Phone: (909) 869-3695Fax: (909) 869-4698

http://www.cpp.edu/~ehs

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http://www.cpp.edu/~ehs

Revision: March 14, 2013Filename: HazWasteManual.doc

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Table of Contents

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1.0 Policy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

2.0 Purpose. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

3.0 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

.

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4.0 Responsibilities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

.

2

5.0 Specific

Procedures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

5

6.0 Employee

Training. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

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7.0 Recordkeeping and Labeling. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

8.0 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

Appendix A - Hazardous Waste Tracking Form. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

Appendix B - Satellite Accumulation Inspection

Checklist . . . . . . . . . . . . . . . . . . . . . . . . . .

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Appendix C – Acutely & California Extremely Hazardous Chemical

Listing . . . . . . . . . . . . .

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Appendix D – Requirements for Incompatible

Waste . . . . . . . . . . . .. . . . . . . . . . . . . . . . . .

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Appendix E – Hazardous Waste List (Appendix X, CCR

66261.126) . . . . . . . . . . . . . . . . .

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Appendix F – Common Flammable

Liquids. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

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Appendix G – Toxicity Characteristics and Tables I, II and II. . . . . . . . . . . . . . . . . . . . . . . 74

Appendix H – Universal Hazardous Waste. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78

Appendix I – Management of Treated Wood Waste. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

Appendix J - Hazardous Waste Tank System Daily Inspection

Log. . . . . . . . . . . . . . . . . . .

96

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1.0 Policy

1.1 It is the policy of California State Polytechnic University - Pomona to manage hazardous waste generated on campus in compliance with applicable federal, state, and local regulations.

1.2 Wherever possible, hazardous waste generated at California State Polytechnic University – Pomona will be managed in a manner that minimizes short and long term liability associated with such waste. Environmental Health & Safety has primary authority in determining management options to achieve this objective.

1.3 It is the policy of California State Polytechnic University – Pomona to make every effort to reduce the volume and toxicity of hazardous waste generated to the degree determined to be economically practicable (waste minimization).

2.0 Purpose2.1 To ensure that California State Polytechnic University – Pomona is in

compliance with applicable federal, state, and local regulations affecting the handling, storage, and disposal of hazardous waste.

3.0 Definitions

3.1 Waste

Any solid, liquid, semi-solid, or contained gaseous, discarded material that has been relinquished, recycled, disposed of, burned or incinerated, accumulated, stored, or treated in lieu of being relinquished for disposal. A material is a waste if it poses a threat to public health or the environment and meets either, or both, of the following conditions: It is mislabeled or not adequately labeled, unless the material is correctly labeled or adequately labeled within 10 days after the materials discovered to be mislabeled or inadequately labeled. It is packaged in deteriorated or damaged containers, unless the material(s) are contained in sound or undamaged containers within 96 hours after the containers are discovered to be deteriorated or damaged (HSC 25124).

3.2 Hazardous Waste

A waste, or combination of wastes, which because of its quantity, concentration, or physical characteristics may either cause or significantly contribute to an increase in mortality or an increase in serious irreversible, or incapacitating illness, pose a substantial present or potential hazard to human health or the environment when improperly treated, stored, transported, disposed of, or otherwise managed (HSC 25117).

3.3 Acutely Hazardous Waste

Waste materials identified as acutely hazardous by the Federal Environmental Protection Agency. Examples are formulations containing tri-, tetra-, or pentachlorophenol, chloroacetaldehyde, Dieldrin, n-nitrosodimethylamine, and other compounds and mixtures specified in 40 CFR 261.

3.4 Extremely Hazardous Waste

Waste materials identified as extremely hazardous by the California Environmental Protection Agency (Department of Toxic Substances Control). Examples are arsenic compounds, bromine, dinitrobenzenes (o,m,p), hydrazine,

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hydrochloric acid, and other compounds and mixtures specified in 22 CCR 66261.

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3.5 Satellite Accumulation Area

A collection area for hazardous waste at or near the point that the waste is generated. Satellite accumulation collection containers can be no more than 210 Liters (55 gallons) for non-acute hazardous waste nor more than 946 milliliters (1-quart) for acutely hazardous waste. Waste must be removed from satellite accumulation areas within one year from the date that waste was first put in to the container. EH&S has developed a hazardous waste pick-up cycle of every ninety days, this means hazardous waste is shipped off Campus every ninety days. Which, ensures hazardous waste does not accumulate and create other substantial hazards?

3.6 Treatment

Any method, technique, or process which changes or is designed to change the physical, chemical, or biological character or composition of any hazardous waste or any material contained therein, or removes or reduces its harmful properties or characteristics for any purpose. ‘Treatment’ does not include the removal of residues from manufacturing process equipment for the purposes of cleaning that equipment (HSC 25123.5 ).

Treatment of hazardous waste may only be performed with an appropriate hazardous waste treatment permit issued by the Department of Toxic Substances Control. Treatment is highly regulated and requires extensive reporting and public notification requirements; examples of treatment include distillation, neutralization, oxidation or reduction, precipitation, rinsing empty containers, and dilution. The only exceptions to treatment without a permit are laboratory experiments performed by students.

3.7 Principal Investigators (PIs)

A PI shall be a faculty or non-faculty member who is responsible for a particular laboratory, research area and /or process that generates hazardous waste.

4.0 Responsibilities

4.1 Environmental Health & Safety Department

a. Develop, implement and maintain the Hazardous Waste Management Policy and Procedures, as directed by the Vice President for Administrative Affairs. Continuously evaluate new and existing regulations for applicability to the various Colleges that make up CSPUP operations.

b. Inspect satellite accumulation areas on a routine basis to ensure compliance with applicable regulations.

c. Arrange for transportation and disposal of all hazardous waste generated at California State Polytechnic University - Pomona. This includes development and management of hazardous waste contracts with off site vendors. Preparation of bid documents, review disposal facility permits, review insurance certificates and Department of Transportation registrations, schedule transportation and ensure vendor compliance with DOT pre-transport requirements, and approve invoices. (DOT regulations available in EH&S)

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d. Prepare State Board of Equalization Tax Returns (generator fees, manifest fees, hazardous waste permits and storage fees) and regulatory agency reports (EPA Biennial Hazardous Waste Reports, Waste Minimization Reports).

e. Make hazardous waste determinations (i.e. identify which materials at CSPUP meet the criteria for being a hazardous waste).

f. Prepare Department of Toxic Substances Control treatment permit applications.

g. Attend inspections with regulatory agency personnel, verify corrections to citations are made and prepare formal responses.

h. Maintain a database of established waste streams at CSPUP and collect information necessary from individuals responsible for generating waste.

i. Provide initial and annual hazardous waste generator training.

4.1.1 Procurement and Support Services

a. Monitor all hazardous waste contractors' required registrations, insurance policies, and bonds

b. Immediately notify EH&S, upon cancellation or any required registration’s, insurance policies, and bonds.

4.2 Deans, Directors, Department Heads, Supervisors (HEERA Managers and Supervisors)

a. Ensure that hazardous waste is properly identified, stored, handled and disposed of by department personnel. (See Appendices A, B, C, D, E and F)

b. Ensure that individuals under their supervision understand and adhere to adopted procedures outlined in this document (section 5.0).

c. Make sure that personnel handling hazardous waste receive the necessary education and training as specified in Section 6.0.

4.3 Department Chairs and Leads

a. Ensure that individuals under their supervision understand and adhere to adopted procedures outlined in this document (section 5.0)

b. Notify Environmental Health & Safety prior to commencing with activities that may generate a new hazardous waste, extension 4697. It is important that hazardous waste is collected in Department of Transportation approved containers and drums to prevent unnecessary recontainerization of hazardous waste. EH&S will not accept hazardous waste in unauthorized containers or without an attached Hazardous Waste Tracking Form (EH&S F-366-07 Rev. 4/96), for each container of hazardous waste

c. Make sure that personnel handling hazardous waste receive the necessary education and training from Environmental Health & Safety.

d. Contact /Environmental Health & Safety prior to generating a new hazardous waste, extension 4697.

e. Notify EH&S regarding the location of all satellite accumulation areas.f. Notification should be made 24 hours in advance to schedule a

hazardous waste pick-up, unless the waste being generated is a weekly scheduled pick-up. (i.e., Art, Communications)

g. Provide information on waste being generated; including constituents and weight percentages, date of generation, (month/day/ year) special hazards, etc.

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h. Make every effort to minimize the volume and toxicity of wastes being generated.

4.4 Principal Investigators (PIs)

a. Ensure that individuals under their supervision understand and adhere to adopted procedures outlined in this document (section 5.0).

b. Notify Environmental Health & Safety prior to commencing with activities that may generate a new hazardous waste, extension 4697. It is important that hazardous waste is collected in Department of Transportation approved containers and drums to prevent unnecessary recontainerization of hazardous waste. EH&S will not accept hazardous waste in unauthorized containers or without an attached Hazardous Waste Tracking Form (EH&S F-366-07 Rev. 4/96), for each container of hazardous waste.

c. Make sure that personnel handling hazardous waste receive the necessary education and training as specified in Section 6.0

d. Contact /Environmental Health & Safety prior to generating a new hazardous waste, extension 4697.

e. Notify EH&S regarding the location of all satellite accumulation areas.f. Notification should be made 24 hours in advance to schedule a

hazardous waste pick-up, unless the waste being generated is a weekly scheduled pick-up. (I.e., Art, Communications

g. Provide information on waste being generated; including constituents and weight percentages, date of generation, (month/day/ year) special hazards, etc.

h. Make every effort to minimize the volume and toxicity of wastes being generated.

4.5 Employees (Faculty and Staff)

a. Notify your Department Chair, Lead, or PI prior to commencing with operations that may generate a new hazardous waste. Also, notify Environmental Health and Safety prior to commencing with activities that may generate a new hazardous waste, extension 4697. It is important that hazardous waste is collected in Department of Transportation approved containers and drums to prevent unnecessary re-containerization of hazardous waste.

b. Report hazardous materials spills, leaking containers, or other releases to Environmental Health & Safety, extension 4697. For Emergency Releases contact University Police, extension 911.

c. Read and comply with procedures and guidelines provided by Environmental Health & Safety.

d. Ensure that your individual hazardous waste training is up to date.e. Ensure each container of hazardous waste has a Hazardous Waste

Tracking Form attached and Environmental Health and Safety is contacted to schedule a waste pick – up. (Hazardous waste pick-ups are usually done on Friday, except when the 4-10 working schedule is effective, then pick–ups will be on Thursdays.

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5.0 Specific Procedures

5.1 Hazardous Waste Identification

a. Generally, hazardous wastes are any of those that meet the definition of hazardous waste in Section 3.0 of this document. However, this definition is not comprehensive, and the determination of a waste as hazardous may involve careful evaluation and/or laboratory analysis. Any questions regarding the status of a particular waste should be directed to Environmental Health & Safety, extension 4697.

5.1.1. Generating a Waste

a. To determine how your experiments, class projects, and activities (i.e., ASME, CapSet, Rose Float, etc.) and normal operations will be regulated by State Hazardous Waste Laws, you must determine if you generate a hazardous waste.

b. Generators are responsible for determining if they generate waste and if that waste is hazardous.

c. Any questions regarding the status of a particular waste should be directed to Environmental Health and Safety, extension 4697.

5.1.2 What Does It Mean to Generate A Waste?

a. Section 3.1 of this document defines waste as:1. Any material for which there is no use or reuse intended and

which is to be discarded; 2. Any material that poses a threat to public health or the

environment, and which meets either or both of the following conditions:a) Is mislabeled or not adequately labeled or b) Is packaged in a deteriorated of damaged container.

b. Simply, it is necessary to understand the definition of waste in the regulations and how materials may inadvertently become waste, thorough mismanagement. So a through review of your operations should be conducted to identify your wastes that are being generated.

5.1.3 Special Rules

a. Certain recyclable materials have special rules regarding their handling. The following is a listing of these materials:1. Used lubricating oil; 2. Spent lead acid storage batteries; 3. Recyclable materials used in Agriculture; 4. Waste elemental Mercury; 5. Contaminated containers; 6. Waste oil filters.

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5.1.4 Waste Stream Classification

a. Once you identify your waste streams and classify them according to the following categories, the next step is answering the question whether the waste generated, are hazardous waste.

WASTE STREAM ANALYSIS CLASSIFICATIONObvious non-hazardous wastes

(paper, wood products, food waste, etc.).

Non-hazardous waste

Industrial wastewater as discharged, radioactive wastes, spent sulfuric acid

being recycled.

Not a waste subject to hazardous waste regulations.

Animal carcasses, empty containers from hazardous materials and

pesticides used in households, waste chemicals still in process, samples,

scrap metals.

Non-hazardous or exempt from coverage of the hazardous waste

regulations

Recyclable materials used to make products by the generator as

"excluded recyclable materials."

Not subject to the hazardous waste regulations.

*All other wastes generated must be characterized to determine whether they are hazardous

5.1.5 Strict Liability and Listed Hazardous Wastes

a. In order for waste to be subject to the Hazardous Waste Handling Requirements, the waste generated must be hazardous.

b. A waste disposed of as "non-hazardous" even though it turns out to be an innocent error, in fact, to be hazardous; the University can and/or will be held responsible by the enforcement agency. This is called "Strict Liability" and is one of the fundamental concepts of the hazardous waste laws.

c. Waste, are determined to be hazardous by definition, listing or meeting certain criteria. These rules have been adopted from federal regulations under RCRA. Both the University and the enforcement agency must use the following lists to determine whether wastes generated are hazardous and are subject to the Hazardous Waste Regulations, under both the federal and state requirements.1. Hazardous wastes from non-specific sources (40 Code of Federal

Regulations (CFR) 261.31) incorporated by reference as 22 California Code of Regulations (CCR) 66261.131. This list describes the wastes generated from industrial and commercial processing which are deemed to be hazardous wastes.

2. Hazardous wastes from specific sources (40 CFR 261.132) incorporated by reference as 22 CCR 66261.32. This list describes wastes, which result from certain types of industrial or commercial processing, which are deemed to be hazardous wastes.

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3. Discarded commercial chemical products, off-specification species, container residues, and spill residues thereof (40 CFR 261.33) incorporated by reference as 22 CCR 66261.33. This list is composed of two alphabetical lists of chemicals that are wastes or otherwise discarded from any industrial or commercial activity, off-specification products, residues in soil, water or debris, etc. Chemicals on the first list are acutely hazardous wastes, based on toxicity and/or reactivity. The second lists wastes are from similar sources, deemed to be federal and state hazardous wastes.

4. California List State list of chemical names and common names for hazardous wastes and hazardous materials (Appendix X of 22 CCR 66261.126).

5.1.6 Characteristics for Identifying Hazardous Waste

a. The four hazardous characteristics are ignitable, corrosive, reactive, and toxic. CCR Title 22 regulations have merged the persistence criteria into the toxicity characteristic similar to federal EPA Regulations. Waste material not excluded or exempted from consideration as hazardous waste, nor listed on any of the lists described above must be "Characterized" to determine by virtue of its properties whether it is hazardous. Remember if you generate the waste you have to be certain the waste is not hazardous by virtue of these criteria or the University may face a violation of the hazardous waste regulations governing handling, transportation and disposal.1. Ignitability (22 CCR 66261.21) A waste is ignitable if it is easily

combustible or flammable or, if ignited, burns so vigorously that it creates a hazard. This category includes:a) A liquid (other than an aqueous solution containing less

than 24 percent alcohol by volume) with a flashpoint equal to or less than 140° F (60° C).

b) A non-liquid, capable under standard temperature and pressure of causing fire by means of friction, absorption of moisture, or spontaneous chemical changes and which, when ignited, burns so vigorously and persistently that it creates a hazard.

c) A flammable, compressed gas. d) An oxidizer. e) Examples of ignitable wastes are: paint wastes, certain

degreasers, thinners and solvents (petroleum distillates), stripping agents, epoxy resins, adhesives, rubber cements and glues, and some waste inks.

2. Corrosivity (22 CCR 66261.22) A waste is corrosive if it dissolves metals and other materials, or burns the skin or eyes on contact. This category includes wastes having any of the following characteristics:a) It is aqueous and has a pH equal to or less than 2, or

equal to or greater than 12.5 or by mixture with an equivalent weight of water it produces a solution with those pH characteristics.

b) It is a liquid (or when mixed with an equivalent weight of water it produces a liquid) and corrodes steel at a rate greater than 0.250 inch (6.35 millimeters) per year.

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c) Examples of corrosive wastes are: Alkaline degreasers, spent metal treating and plating solutions, corrosive cleaning solutions, rust removers, waste acids, and bleach compounds (peroxides and chlorine compounds).

3. Reactivity (22 CCR 66261.23) A waste is reactive if it is unstable or undergoes rapid or violent chemical reactions, such as catching fire, exploding, or giving off fumes, when exposed to or mixed with water, air or other materials. This category includes any waste which: a. Is normally unstable and readily undergoes violent change

without detonating. b. Reacts violently with water. c. Forms potentially explosive mixture with water. d. Generates toxic gases, vapors or fumes when mixed with

water. e. Is a cyanide- or sulfide bearing waste which, when

exposed to pH conditions between 2 and 12.5 can generate toxic gases, vapors or fumes.

f. Is capable of detonation, explosive reaction or explosive decomposition.

g. Examples of reactive wastes are chromic acids used in plating, copper striping and aluminum anodizing; cyanide compounds from electroplating and metal treating and ore leaching processes; permanganate and manganese wastes from dry cell battery, paint, inks, and dye manufacturing; bleaches and hypochlorites from water treatment processes and swimming pool and sanitizing operations.

4. Toxicity (22 CCR 66261.24) A waste is hazardous by virtue of the toxicity characteristic if it exceeds specified concentrations of certain metals and organic compounds as listed by reference in the regulations. a) Identification of hazardous waste by toxicity criteria is one

of the most complex processes in environmental regulatory compliance.

b) Innocuous – appearing waste material with unknown ingredients or properties must be submitted for laboratory analysis or biological testing.

c) Keep in mind that if a complete battery of tests are necessary, the costs may be excessive.

d) To minimize these costs a better understanding of the chemical content of the waste is required for any waste generated here at Cal Poly.

5.1.7 Summary of Determining Whether Your Wastes are Hazardousa. You should always consider it necessary to study information available

on raw materials, have tests performed on your waste or take other steps to accurately classify your wastes. The following information is provided to help you in making these classifications.1. If you know the chemical composition of your wastes, check to

see if they are listed as hazardous wastes(see section 5.1.5); or 2. Use information contained on MSDS’s to identify the hazardous

substances, the operations uses, and which may be contained in its wastes.

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3. Determine whether your waste exhibits one of the characteristics (see section 5.1.6) described above which would qualify if as a hazardous waste. May be done by testing according to the methods outlined in the appropriate regulations.

4. Check for typical waste streams and presume that the waste are hazardous if they fall into these categories. To illustrate: a college is likely to generate hazardous wastes if it handles the following types of materials and these materials are not entirely consumed by your operation or experiment.a.) oils or other petroleum products; b.) dyes, paints, printing inks, thinners, solvents, or cleaning

fluids; c) pesticides or other related chemicals; d) materials that dissolve metals, wood paper, or clothing

(acids and bases); e) flammable materials; f) materials that burn or itch upon contact with the skin; g) materials that bubble or fume upon contact with water; h) products accompanied by shipping papers or labels or an

MSDS (Material Safety Data Sheet) indicating that the product is hazardous; or

i) any substance listed as a hazardous waste in the list of common names (Appendix X to 22 CCR 66261.126).

NOTE: Equipment and other articles that contain or have been contaminated by hazardous wastes also are considered hazardous waste, unless certified as clean, for example: piping, tanks, concrete sumps, and even concrete floors.

5.2 Hazardous Waste Generation

a. Prior to generating a new hazardous waste, CSPUP personnel will contact Environmental Health & Safety to obtain or supply information on the waste being generated, manufacturer material safety data sheets, recommended disposal method, labeling information and a Hazardous Waste Tracking Form(s).

b. Department personnel generating hazardous waste will maintain labels with the following information: The University’s Name, address, EPA generator I.D, number, the wording "Hazardous Waste", accumulation start date (the date waste was first put in to the container (month/day/year)), chemical constituents (proper IUPAC or common name only, no empirical formulas; e.g. 1,2-dichlorohexane or benzene), approximate weight percentages (range not to exceed 20 percentage points; e.g. 10-30%), generating department, and EH&S recommends including the room number where waste is accumulated. A complete Hazardous Waste Release Form also complies with this paragraph.

c. All efforts should be made to keep hazardous waste containers in good condition and free from exterior contamination. It will be the department’s responsibility to properly repackage any containers unsuitable for disposal.

d. Waste materials must be collected in compatible containers. e. Ensure hazardous waste container lids are kept on the hazardous waste

containers at all times.

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f. Ensure that each satellite accumulation collection container meets the requirements set forth on the inspection form in Appendix B.

g. Hazardous waste collection areas and satellite accumulation areas will not be located near storm drains.

h. Sufficient spill response equipment and supplies shall be readily available.

i. Unobstructed aisle space of at least 3 feet shall be maintained to allow for emergency response and the inspection of containers.

5.3 Satellite Accumulation Exemption

a. The hazardous waste must be accumulated in containers b. The hazardous waste must be accumulated at the initial accumulation

point, which must be at or near the area where the waste is generated. The term "at or near" means that the process generating the waste and the "satellite" accumulation point must be in the same or adjacent room or work area. The term "initial accumulation point" means that there cannot be any interim accumulation of the waste prior to its being accumulated at the "satellite" accumulation point. However, certain generating activities (for example, equipment maintenance) may necessitate the temporary interim accumulation of the waste during the process of performing such activities. Such temporary interim storage will not disallow "satellite" accumulation of the waste, if the interim accumulation is necessary to the generating activity and if the waste is placed in the "satellite" accumulation area prior to the end of the work shift of the person generating the waste.

c. Residuals from the treatment of onsite waste may not be accumulated under the "satellite" exemption.

d. The initial accumulation point "must be" under the control of the operator of the process generating the waste. The term "operator of the process" means the "hands-on" operator(s) of the machinery or activity that generates the waste not the overall operator of the generator site or facility as a whole. The term "under the control" means that the accumulation container must be in the line of sight of the operator(s) or in a locked compartment to which the operator(s) control(s) access. The purpose of this requirement is to ensure that the operator(s) control(s) all access to and management of the accumulated waste so as to prevent incompatible mixing of wastes and other unsafe management practices. In the event that this application of this requirement is unworkable for a particular activity, and alternative control procedure may be allowed. Such alternative control procedures must ensure that access to, and management of, the accumulation containers and their contents is at all times controlled by designated operators, all of whom must have day-to-day, hands-on knowledge of all wastes going into the containers (and the processes generating those wastes), so as to ensure that proper management practices are followed at all times.

e. The "satellite" accumulation point must be operated so as to ensure that the single 55-gallon accumulation limit for hazardous waste or 1-quart accumulation limit for acutely or extremely hazardous waste are not exceeded. There are two exceptions to the single limit:1. If not all of the waste streams generated by a single process or

group of processes located within the same physical area are compatible, a separate 55-gallon (or one-quart) limit applies to each group of waste streams that are compatible.

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2. If the generator determines that using only one 55-gallon (or one-quart) container to initially accumulate specific compatible waste streams is not practical (e.g., prevents recycling or requires unreasonable accumulation procedures) or is not safe from an environmental protection or worker safety standpoint, the generator may apply a separate 55-gallon (or one-quart) limit to those specific compatible waste streams.

f. The containers holding the waste must be maintained in good condition (e.g., no rust or structural defects). If a container begins to leak the contents will be transferred to another container in good condition.

g. Hazardous waste will be collected in a container that is compatible to prevent damage to the container and leakage of the hazardous waste.

h. Hazardous waste containers will be closed except when waste is being added.

i. The initial date of hazardous waste accumulation must be clearly marked on all containers used for satellite accumulation. Additionally, each container must be labeled with the words "Hazardous Waste", composition of the waste, physical state of the wastes, a statement that calls attention to the particular hazardous properties of the waste, generator name and address of the generator.

j. No treatment of hazardous waste is allowed while being accumulated under the satellite accumulation exemption.

k. Within three days after the 55-gallon (or one-quart) accumulation limit is reached, the generator must label the container with the date the accumulation limit was reached and move the container to the Campus’s Hazardous Materials Storage Facility.

l. Hazardous waste collected under the satellite accumulation must be moved to a licensed treatment storage or disposal facility within one year from the initial accumulation date or within 90 days from when the 55-gallon (or one-quart) limit is reached, whichever occurs first.

m. Satellite accumulation areas must be inspected on a weekly basis to insure that the containers are properly stored, not leaking, and that the area is in compliance with this section.

5.4 Tanks

a. Tanks shall be reviewed and certified as not leaking and adequate by an independent qualified, professional engineer, whom is registered in California.

b. If a tank is found to be leaking or inadequate it will be removed from service and the following actions taken:1. Cessation of use, prevention of the flow or addition of hazardous

waste;2. Inspect the tank to determine the cause of the leak or problem;3. Remove the hazardous waste from the tank within 24 hours or if

not possible, at the earliest possible time. 4. A visual inspection of any leak shall be conducted immediately

and the following action taken:a) Prevent further migration to soils or surface waters;b) Remove and dispose of any visible contamination;c) Notify Environmental Health and Safety immediately;d) Environmental Health and Safety will be responsible for

the notification of the regulatory agencies.5. If the tank can be repaired it shall be reviewed and recertified

before reuse.Page 12

6. If the tank cannot be repaired it will be closed as per applicable regulations.

c. Ignitable or reactive hazardous waste will be protected in such a manner as to prevent ignition, reaction, and damage to the tank.

d. Incompatible wastes shall not be placed in the same tank.e. All hazardous waste tanks shall have appropriate secondary

containment and leak detection systems.f. No material should be placed in the tank that could result in damage to

the tank.g. The tank shall be operated in such a manner to prevent any spills or

overflows. At a minimum this includes spill prevention controls, and overflow prevention controls.

h. Uncovered tanks will not be used for hazardous waste.i. The following items must be inspected on a daily basis:

1. Overfill / spill control equipment;2. Above ground portions of tanks and associated piping for

corrosion or leaks;3. Documentation of data from monitoring and leak detection

equipment.j. The proper operation of the cathode protection system will be inspected

within 6 months of installation and annually there after. All sources of impressed current shall be inspected every other month.

k. If the hazardous waste tank is an underground tank design operation must comply with 23 CCR 2610 et. Seq.

5.5 Hazardous Waste Disposal

a. Use only containers approved by EH&S to prevent unnecessary waste transfers and container contamination.

b. Fill out EH&S provided hazardous waste tracking forms, for each container, completely to ensure proper handling. Accurate composition information is critical because much of CSPUP’s hazardous waste is consolidated (mixed) prior to disposal.

c. Most University waste is collected in "Satellite Accumulation" containers. These containers should be located in areas at or near the point that the waste is generated. Satellite accumulation collection containers can be no more than 210 Liters (55 gallons) for non-acute hazardous waste or more than 946 milliliters (1-quart) for acutely hazardous waste.

d. Waste must be removed from satellite accumulation areas within one year from the date that waste was first put in to the container. CSPUP is on a collection cycle of every ninety days, this means it is recommended that you collect the waste containers, ensure a waste tracking form is attached, and call EH &S for a Pick-up, before the ninety day cycle. This ninety-day cycle just ensures that stockpiles of hazardous waste do not accumulate and create other substantial hazards.

e. Contact EH&S when you need hazardous waste containers removed from your area. Routine waste pick-ups occur every Friday, except when the 4-10 workweek is effective, then routine waste pick-ups will occur on Thursdays. E-mail [email protected] or call, x4697.

f. Environmental Health & Safety will remove approved waste streams within three days of notification by the generating department. Routine pickups occur once per week. All Pick-ups will try to be scheduled for the weekly pick-up day.

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5.6 Hazardous Waste Minimization

a. Every effort shall be made by CSPUP personnel to minimize the volume and toxicity of hazardous waste generated at CSPUP.

b. All new process that produce a new hazardous waste stream must be reported to EH&S, along with documentation of that process.

5.7 Hazardous Waste or Hazardous Material Releases

a. In the event that a small quantity of a low toxicity hazardous material is released, it may be cleaned up provided that all of the necessary safety precautions have been taken. This includes assessing the potential for exposure, wearing the appropriate personal protective equipment, and collecting the material in the proper containers. Never attempt to clean up or contain a hazardous material if it has the potential to cause adverse health effects due to the quantity and/or toxicity. See CSPUP Hazardous Substance Contingency Plan, Part I, Section 4.2 for Definition of Hazardous Materials Emergency.

b. In the event of an emergency release, notify nearby personnel, instruct individuals to evacuate the immediate area and Contact University Police and the Environmental Health and Safety Office and provide the following information: 1. Location of spill / area evacuated2. What was spilled / is there a fire3. How much was spilled / is spill heading for or going into a storm

drain4. Any injuries / is the area safe5. Provide your name and extension or phone number.6. Stay on site to provide additional information to emergency

responders.See the Emergency Procedures Pamphlet

5.8 Equipment and Materials

a. See CSPUP’s Hazardous Substance Contingency Plan, Appendix C for emergency response equipment listings. The following is the Directory listing of Tables:Table 1: EPA Protection Level ChartTable 2: Emergency Response Vehicle Equipment ListTable 3: Hazardous Waste Accumulation Facility EquipmentTable 4: Emergency Response Team Member Gear Bag And Equipment

ListTable 5: EH&S Office Store room Equipment ListTable 6: Industrial Hygiene Equipment ListTable 7: Radiation Safety Monitoring Equipment ListTable 8: College/Department Emergency Equipment List

5.9 Pre-Transportation Authorization for Faculty and Staff

a. Before any Hazardous Material may be removed/shipped from University Properties, including University Properties that are not part of the Main Campus in Pomona, California, the person responsible/requesting the movement/shipment of these hazardous materials must comply with the following:

Page 14

1. Contact EH &S (3) weeks before the requested removal, movement, and/or shipment.

2. Obtain the Dean’s or the Department Manager’s approval in writing for the shipment and have on file with EH &S.

3. Submit a listing of the hazardous materials and written procedures for the use of the hazardous materials off site

4. Submit information on the manner in which the hazardous materials will be shipped. (air, land, sea,) List any known restrictions.

5. Provide the name of the Company, Vendor, or Airline transporting or shipping the hazardous materials, along with a phone number of their Hazardous Materials Coordinator/Contact you spoke to about your request to transport/ship your hazardous materials.

6. Material Safety Data Sheets and labeling requirements7. Written plan for the return of all/any unused hazardous materials.8. Written plan for the disposal of the waste these hazardous

materials may create.

5.10 Pre-Transportation Procedures for EH&S Staff

a. Packaging, Labeling, and Marking Requirements. Before transporting University hazardous waste off-site or arranging transportation with vendors under contract, Environmental Health & Safety staff will ensure that each hazardous waste container of 110 gallons or less is packaged and labeled, and transportation vehicles appropriately marked in accordance with applicable Department of Transportation packaging regulations under 49 CFR Parts 172, 173, 178, and 179. The basic procedure follows:1. Identify hazardous waste to be transported off-site in the DOT

Hazardous Materials Table (49 CFR 172.101).2. Reference appropriate packaging, labeling, marking, and carriage

information found in the DOT Hazardous Materials Table (49 CFR 172.101)

6.0 Employee Training

6.1 Unless otherwise specified, employees handling or generating hazardous waste must receive the following training at the specified intervals:

a. Employees (Faculty, Staff, Student Assistants, etc.) will receive hazardous waste generator training, within 6 months of assignment and annual refresher training;

b. Students will be trained by, their Instructor or Principal Investigator;

c. All training will be documented, with copies forwarded to Environmental Health and Safety

d. The safety training documentation, "Employee Training Sign-up sheet (EH&S Form 2556) may be used to document Employees and/or Student Training.

e. EH&S and Departments will maintain records of all training.f. Student Training Records shall be maintained by Departments for

one year.

Page 15

g. Environmental Health and Safety shall maintain all training records for at least the duration of employment or enrollment, plus 30 years.

Page 16

7.0 Recordkeeping and Labeling

a. Departments are responsible for maintaining legible labels on all of the hazardous waste containers in their area and ensuring that each container of Hazardous Waste is scheduled for pick-up or otherwise transported to the Universities Hazardous Waste Storage Area, behind building 3, has a completed hazardous waste tracking form.

b. All California State Polytechnic University – Pomona hazardous waste manifests will be signed by the Environmental Specialist, or other Designee within the EH&S Office. Some exceptions have made for automotive fluids recycling manifests. Hazardous Waste contracts are developed and managed by EH&S and include general hazardous waste, medical waste, and spill response.

c. The EH&S Specialist also assists with the development of contracts initiated by other campus departments where hazardous waste may potentially be generated.

d. The EH&S Specialist signs all hazardous waste manifests resulting from such properly administered contracts, and the EH&S office will maintain copies of all hazardous waste manifests.

e. Records of all hazardous waste manifests will be kept on site for a minimum of five years from the TSDF returned copy date. Manifests beyond this date may be stored on site or stored in archives for a minimum of thirty years to serve as an accurate accounting of material shipped to potential CERCLA (Superfund) Sites.

f. Land Disposal Restriction (LDR’s) notices, Hazardous Waste Profile Sheets, and Exception Reports will be kept with the associated manifest. Note that LDR’s are to be attached to the manifest, whereas profiles are kept in a single section of the same calendar year manifest binder. All of these documents are to be kept with the manifest for the time period indicated herein.

g. Biennial Reports will be kept for a minimum of five years from the established submittal date. Biennial Reports will be kept with manifest archives for the established time period [thirty (30) years].

h. Waste analysis and laboratory analytical reports will be kept with the hazardous waste manifests for the established time period [five (5) years on site, thirty (30) years archived]. Note that laboratory analytical reports may be kept with hazardous waste profiles, in contract files, permitting files, or in individually designated files depending on the nature of the contract and/or waste materials.

i. Note that the periods of retention referred to in this procedure are automatically extended during the course of any unresolved enforcement action regarding the regulated activity or as requested by the US EPA Administrator or by Cal-EPA [per 22 CCR 66262.40(d)].

8.0 References

Copies of the below listed references can be obtained from EH&S, Building 98, Room 1 – 33.

Code of Federal Regulations, Title 40.Code of Federal Regulations, Title 49.California Code of Regulations, Title 22. California Health & Safety Code, Division 20.

Page 17

Appendix A

Hazardous Waste Tracking Form

Page 18

Appendix B

Page 19

Appendix C

ACUTELY & CALIFORNIA EXTREMELY HAZARDOUS CHEMICAL LISTING

Acutely and California Extremely Hazardous Chemical Listing

Chemical Acutely Hazardous

California Extremely Hazardous

Acetaldehyde, chloro YesAcetamide, N-fluoren-2-yl YesAcetic acid, fluoro-, sodium salt YesAcetone Cyanohydrin Yes YesAcetone Thisemicarbazide Yes Acetyl chloride YesAcrolein Yes YesAcrylamide Yes YesAcrylonitrile Yes YesAcrylyl Chloride Yes Actidione YesAdiponitrile Yes YesADP, 4- YesAFL 1082 YesAldicarb Yes YesAldrin Yes YesAldrin, mixture dry more than 65% YesAldrin, mixtrue liquid less than 60%` YesAlkyl Aluminum Chloride YesAllyl Alcohol Yes Allyl Trichlorosilane YesAllylamine Yes Aluminum chloride YesAluminum phosphide Yes YesAminobiphenyl, 4- YesAminopterin Yes Amiton Yes Amiton oxalate Yes Ammonia Yes Ammonium arsenate Yes

Page 20

Appendix C





Ammonium bifluoride YesAmmonium hydrogen fluoride, solid YesAmmonium Trichlorosilane (& isomers) YesAmphetamine Yes Aniline Yes Aniline, 2, 3, 6-trimethyl Yes Aninopyridine, 2- YesAnisoyl chloride YesAntimony pentachloride YesAntimony pentafluoride Yes YesAntimycin A Yes ANTU Yes Aroclor YesArsenic YesArsenic and salts YesArsenic chloride YesArsenic compounds (inorganic) YesArsenic pentachloride YesArsenic pentafluoride YesArsenic pentaselenide YesArsenic pentoxide Yes YesArsenic sulfide YesArsenic tribromide YesArsenic tribromide, arsenic iodide YesArsenic trioxide, arsenious oxide YesArsenious acid and salts YesArsenous oxide Yes Arsenous trichloride Yes Arsine Yes Yes

Page 21

Appendix C





Askarel YesAzinphos-ethyl Yes Azinphos-methyl Yes Aziridine YesAzodrin YesBaldafum YesBanol YesBarium cyanide YesBAYER 25634 YesBenzyl chloride Yes Benzenamine, 3-(trifluoromethyl)- Yes Benzene hexachloride YesBenzene, 1-(chloromethyl)-4-nitro Yes Benzenearsonic acid Yes Benznephosphorous dichloride YesBenzidine (and its salts) YesBenzimindazole, 4,5-dichloro-2- (trifluoromethyl)- Yes Benzoquinone, 1,4- YesBenzotrichloride Yes Benzotrifluoride YesBenzoyl chloride YesBenzyl chloride Yes Benzyl chlorocarbonate (Benzyl chloroformate YesBenzyl cyanide Yes Beryllium YesBeryllium compounds YesBeryllium copper YesBeryllium fluoride Yes

Page 22

Appendix C





Beryllium hydride YesBeryllium hydroxide YesBeryllium oxide Yes BHC, gamma- YesBicyc [2.2.1] heptane-2-carbonitrile, 5-chloro-6-((((Meth Yes Bidrin. Docrptp[jps. 3-(dimethylamine) - 1-methyl- 3-oxo -propenyl diemthyl Yes

Biphenyl YesBis (chloromethyl) ketone Yes Bitoscanate Yes Bladafum YesBomyl, dimethyl 3-hydroxygluaconate 2, methyl phosphate YesBoranes YesBordeaux arsenites YesBoron tribromide YesBoron trichloride Yes YesBoron trifluoride Yes YesBoron trifluoride compound with methyl ether Yes BPL YesBromadiolone Yes Bromine Yes YesBromine pentafluoride YesBromine trifluoride YesBromomethane YesBrucine YesButenal, 2- YesButyl trichlorosilane YesButyl-5-mehyl-4,6-dinitrophenyl acetate, 2-tert YesButyllithium (and isomers), n- Yes

Page 23

Appendix C





Cacodylic acid YesCadmium (powder) YesCadmium compounds YesCadmium cyanide YesCadmium oxide Yes Cadmium stearate Yes Calcium YesCalcium arsenate Yes Calcium arsenate, PENSAL YesCalcium arsenite YesCalcium carbide YesCalcium hydride YesCalcium hypochlorite YesCalcium oxychloride (dry) YesCalcium phosphide YesCamphechlor Yes Cantharidin Yes Carbachol chloride Yes Carbamic acid, methyl-, (o-((2,4-dimethyl-1,2- dithiol Yes Carbanolate Yes Carbofuran YesCarbofuran; 2,3-dihydro-2,2-dimethyl-y- benzofuranyl methylcarbanate Yes

Carbomethoxy-1-methyvinyl dimethyl phosphate YesCarbon disulfide Yes Carbonphenothion Yes YesCarbonyl chloride YesCeresan liquid YesCEREWET Yes

Page 24

Appendix C





Chemflorm YesChlordan: 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetrahydroi Yes

Chlordane Yes Chlordecone (kepone) YesChlorfenvinfos Yes Chlorine Yes YesChlorine dioxide (not hydrate YesChlorine dioxide hydrate, frozen YesChlorine pentafluoride YesChlorine trifluoride YesChlormephos Yes Chlormequat chloride Yes Chloro-1-(2,4-dichlorophenyl) vinyl diethyl phosphate, 2- YesChloro-4-dimethylamino-6-methyl pyrimidine, 2- YesChloro-endo-6-cyano-2-norbornanone-O-( methylcarbamoyll)oxime, exo-3- Yes

Chloroacetic acid Yes Chloroacetophenone, alpha- YesChloroacetyl chloride Yeschlorobenylidene malonitrile, ortho- YesChlorochromic anhydride YesChloroethanol Yes Chloroethyl chloroformate Yes Chloroform Yes Chloromethyl ether Yes (Chloromethyl) Ether, Dichloromethyl ether, bis YesChloromethyl methyl ether (technical grade Yes Chloropacinone Yes

Page 25

Appendix C





Chlorophenyl) thio. methyl O,O-diethyl phosphorodithioate, S-(4- YesChlorophenyl-2,4,5-tri-chlorophenyl sulfide, S-para- YesChloropicrin Yes Chloropicrin mixture YesChlorosulfonic acid YesChlorotetrafluoroethane YesChlorovinyldichloroarsine, beta- YesChloroxuron Yes Chlorthiophos Yes Chromic Chloride YesChromium oxychloride YesChromyl chloride YesCMME YesCobalt Carbonyl Yes Cobalt ((2,2'-(1,2-Ethanediyibis(nitrilomethylidyne)) Bi Yes Colchicine Yes Compoind 1080 YesCopper Acetoarsenite YesCopper arsenate YesCopper arsenite YesCopper cyanide YesCoroxon; ortho, ortho-dimethyl-ortho-(3-chloro -4- methylcoumarin-7-yl) Yes

Coumafuryl YesCoumaphos Yes Coumatetralyl Yes YesCresol, o- Yes Crimidine Yes Yes

Page 26

Appendix C





Crotonaldehyde Yes Crotonaldehyde, (E) Yes Crotonaldehyde, 2-butenal YesCupric arsenate YesCyanide or cyanide mixture, dry YesCyanide solution, N.O.S. YesCyanogen YesCyanogen bromide Yes Cyanogen iodide Yes Cyanophenphos YesCyanophenyl-O-ethyl phenyl phosphonothioate, O-para- YesCyanophos Yes Cyanuric fluoride Yes Cyclohexenyltrichlorosilane YesCycloheximide Yes YesCyclohexylamine Yes Cyclohexyltrichlorosilane YesCyolan YesD, 2,4- YesDCB YesDDVP YesDecaborane (14) Yes YesDechlorane YesDELNAV; S,S-1,4-dioxane-2,3-diyl bis(o,o-diethyl phosphorodithioate Yes

Demeton Yes Demeton, Systox YesDemeton-S-methyl Yes Dialifor Yes Yes

Page 27

Appendix C





Diamine, anhydrous YesDiborane Yes YesDiboron Hexahydride YesDibromo-3-chloropropane, 1,2- YesDichlorobenzidine, 3,3'- YesDichlorodimethylsilane YesDichloroethyl ether Yes YesDichloroethylarsine YesDichloromethyphenylsilane YesDichlorophenoxyacetic acid, 2,4- YesDichlorvos Yes YesDicrotophos Yes Dieldrin: 1,2,3,4,10,10-Hexachloro-6,76-epoxy-1,4,4a,5,6,7,8,8a-octahyd Yes

Diepoxybutane Yes Diethoxyphosphinylimino)-1,3-dithiolane YesDiethyl chlorophosphate Yes Diethyl Chlorovinyl phosphate YesDiethyl S-(N-ethoxycabonyl n-methyl-carbamoyl-methyl phosphorodithioa Yes

Diethyl Zinc, zinc ethyl YesDiethyl-O,4-(methylsulfinyl) phenyl, phosphorothioate, O,O- YesDiethyl-O-para-nitrophenyl phosphorothioate, O,O- YesDiethyl-S-(isoprpylthiomethyl phosphorodithioate, O,O- YesDiethylaluminum chloride YesDiethylcarbamazine citrate Yes Diethyldichlorosilane YesDifluorophosphoric acid YesDigitoxin Yes Diglycidyl ether Yes Yes

Page 28

Appendix C





Digoxin Yes Dihydroxybenzene, p- (hydroquinone) Yes YesDiiphenyldichlorosilane YesDIMECRON YesDimefox Yes Dimefox, tetramethylphosphorodiamidic fluoride YesDimethoate Yes Dimethoxystrychnine YesDimethyl 3-hydroxyglutaconate dimethyl phosphate YesDimethyl phosphorochloridothioate Yes Dimethyl phosphorothinoate, O,O- YesDimethyl sulfate Yes YesDimethyl sulfide Yes Dimethyl sulfide, methylsulfide YesDimethyl-p-phenylenediamine Yes Dimethylamino)-1-methyl-3-oxo-1-propenyl dimethyl phosphate, 3- Yes

Dimethylaminoazobenzene YesDimethylhydrazine Yes Dimethylhydrazine, 1,1- YesDimethylnitrosamine Yes YesDimetilan Yes Dinitro-6-sec-butylphenol, 2,4- YesDinitro-ortho-cresol, 4,6- YesDinitrobenzene (ortho, meta, para) YesDinitrobenzene solid or dinitrobenzol, solid YesDinitrocresol Yes Dinitrophenol YesDinitrophenol, 2,4- Yes

Page 29

Appendix C





Dinoseb Yes YesDinotrerb Yes Dioxathion Yes YesDiphacinone Yes Diphenyl YesDiphenylamine chloroarsine, phenarsazine chloride YesDiphosgene (phosgene) YesDithiobiuret Yes Dithione YesDNPC YesDodecyltrichlorosilane YesDOWCO-139, ZECTRAN, Mexacarbate, 4-(dimethylamine)-3,5- dimethylphenyl m Yes

DOWIDICE I YesDyfonate YesEGETON 30 YesEI YesEmetine, dihydrochloride Yes Endosulfan Yes YesEndosulfan & mixture liquid YesEndothall YesEndothion Yes Endothion, exothion, s-(methosy-4-oxo-4H- pyran-2- yl-methyl)O,O-dim Yes

Endrin Yes Endrin;1,2,3,6,10,10-hexachloro-6,7-epoxy-1,4,4,4a,5,6,8,8 a-octahydro Yes

Epichlorohydrin Yes EPN; O-ethyl O-para-nitrophenyl phenylphosphonothioate Yes YesEpoxypropyl) ether, bis(2,3- Yes

Page 30

Appendix C





Ergocalciferol Yes Ergotamine tartrate Yes Ethanesulfonyl chloride, 2-chloro- Yes Ethanethiol YesEthanol, 1,2-dichloro-, acetate Yes Ethino & mixture dry YesEthion Yes YesEthoprophos Yes Ethyl chlorocarbonate YesEthyl eichloroarsine YesEthyl mercaptan YesEthyl O-para-nitrophenyl phenylphosphonothioate, O- YesEthyl phenyl dichlorosilane YesEthyl-S, S-dipropyl phosphorodithioate, O YesEthylbis (2-chloroethyl) amine Yes Ethyldichlorosilane YesEthylene cyanohydrin YesEthylene fluorohydrin Yes Ethylene oxide Yes Ethylenediamine Yes Ethyleneimine Yes Ethylsulfonyl) ethyl, O,O-dimethyl phosphorothinaote, s-,2( YesEthylthiocyanate Yes Ethyltrichloro silane YesExothion YesFAC;O,O-diethyl-S-carboethoxyethyl phosphorodithioate YesFenamiphos Yes Fenitrothion Yes

Page 31

Appendix C





Fensulfothion Yes YesFerric arsenate, solid YesFerric arsenite, solid YesFerrous arsenate, solid YesFlouric acid YesFluenetil Yes Fluoboric acid YesFluorine Yes YesFluoroacetamide Yes Fluoracetanilide YesGluoroacetic acid Yes Fluoroacetyl chloride Yes Fluoroboric acid YesFluorosulfonic acid (fizzies) YesFluorouracil Yes Fonofos Yes YesFormaldehyde Yes Formaldehyde cyanohydrin Yes Formetanate hydrochloride Yes Formothion Yes Formparanate Yes Fosthietan Yes Fostion YesFuberidazole Yes Fumarin YesFuradan YesFuran Yes Furanyl)-3-oxobutyl 1.1-4-hydroxy-2H-1-benzopyran-2-one, 3-,1-(2- Yes

Page 32

Appendix C





Gallium trichloride Yes GB YesGuthion; O,O-dimethyl-S-4- oxo-1,2,3-benzotriazin -3(4H)-ylmethyl phospho Yes

Hanane YesHeptachlor; 1,4,5,6,7,8,8-heptachlor-3a,4,7,7a- tetrahydro-4,7-methanoin Yes

Hexachlorocyclopentadiene Yes Hexadecyltrichlorosilane YesHexamethylenediamine, N.N'-dibutyl- Yes Hexyltrichlorosilane YesHydrazine Yes YesHydriodic acid YesHydrobromic acid, -49% strength YesHydrobromic acid, +49% strength YesHydrochloric acid YesHydrochlorite compounds YesHydrochlorite solution YesHydrocyanic acid Yes YesHydrogen bromide YesHydrogen chloride (gas only) Yes Hydrogen fluoride Yes Hydrogen peroxide (concentration>52% Yes Hydrogen phosphide YesHydrogen selenide Yes YesHydrogen sulfide Yes YesHydroquinone Yes Hydroxy-N-cis-crotonamide, 3- YesHydroxypropioniotrile, beta- YesInerteen Yes

Page 33

Appendix C





Iron arsentate YesIron, pentacarbonyl- Yes Isobenzan Yes YesIsobutyronitrile Yes Isocyanic acid, 3,4-dichlorophenyl ester Yes Isodrin Yes Isofluorphate Yes Isophorone diisocyanate Yes Isoproplymethylpyrazolyl dimethlcarbamate Yes Isopropyl Chloroformate Yes Isopropyl Formate Yes Isoprpylphenyl-N-methylcarbamate, meta- YesKepone YesLactonitrile Yes LAH YesLannate YesLead arsenate, solid YesLead cyanide YesLead orthoarsenate YesLeptophos Yes Lindane Yes Lithium YesLithium aluminum hydride YesLithium amide YesLithium amide, powdered YesLithium ferrosilicon YesLithium hydride Yes Lithium hypochlorite Yes

Page 34

Appendix C





Lithium hypochlorite compound, dry YesLithium peroxide YesLithium silicon YesLondon purple YesLondon purple, solid YesMagnesium YesMagnesium arsenate YesMagnesium arsenite YesMalathion YesMaleic anhydride YesMalonoitrile Yes Manganese arsenate YesManganese, tricarbonyl methycyclopentadienyl Yes Marlate YesMecarbam YesMechlorethamine Yes Medinoterb acetate YesMephosfolan Yes Mercuric acetate Yes Mercuric chloride Yes YesMercuric oxide Yes Mercury YesMercury chloride YesMercury compound N.O.S. YesMercury, metallic YesMetaisosystox-sulfon YesMetal hydrides YesMethacrolein diacetate Yes

Page 35

Appendix C





Methacrylic anhydride Yes Methacrylonitrile Yes Methacryloyl chloride Yes Methacryloyloxyethyl isocyanate Yes Methamidophos Yes Methanesulfonyl fluoride Yes Methidathion Yes Methiocarb Yes Methomyl Yes YesMethoxy-2-oxo-1,24-thiadiazol-3 (2H)-yl) methy, -O,O-dimethyl phosphoro Yes

Methoxy-4-oxo-4H-pyran-2-yl)-methyl.O-O-dimethyl phosphorothioate, S-, Yes

Methoxychlor YesMethoxyethylmercuric acetate Yes Methoxyethylmercuric chloride YesMethyl 2-chloroacrylate Yes Methyl bromide Yes methyl chlorocarbonate YesMethyl chloroformate Yes YesMethyl chloromethyl ether Yes Methyl disulfide Yes Methyl hydrazine Yes Methyl isocyanate Yes YesMethyl mercaptan Yes Methyl parathion YesMethyl parathion, liquid YesMethyl phenkapton Yes Methyl phosphonic dichloride Yes Methyl sulfate Yes

Page 36

Appendix C





Methyl sulfide YesMethyl thiocyanate Yers Methyl vinyl ketone Yes Methyl yellow YesMethyl-2-(methylthio) propionaldehyde-O-(methylcarbomyl) oxime, 2- Yes

Methylaluminum sesquibromide YesMethylaluminum sesquichloride YesMethylaziridine (propyleneimine), 2- YesMethyldichloroarsine YesMethyldichlorosilane YesMethylhydrazine YesMethylmagnesium bromide YesMethylmagnesium chloride YesMethylmagnesium iodide YesMethylmercuric dicyanamide Yes Methyltrichlorosilane Yes YesMetolcarb Yes Mevinphos Yes YesMexacarbate Yes Mintacol YesMitomycin C Yes Mixture of arsenic trioxide, aniline, lime and ferrus oxide YesMMH YesMOCAP, O-ethyl-S,S-dipropyl phosphorodithioate YesMonocrotophos Yes Monomethyl hydrazine YesMuscimol Yes Mustard gas Yes

Page 37

Appendix C





NA, 1- YesNaphthylamine, 1- YesNaphthlyamine, 2-NA YesNaphthlamine, alpha YesNBP, 4- YesNemagon YesNIA 10, 242 YesNickel antimonide YesNickel carbonyl Yes Nickel carbonyl, nickel tetracarbonyl YesNickel cyanide YesNickelous arsenate YesNickel tetracarbonyl YesNicotine Yes Nicotine sulfate Yes Nitric acid Yes Nitric oxide Yes Nitrobenzene Yes YesNitrobiphenyl, 4-NBP, 4- YesNitrocyclohexane Yes Nitrogen dioxide Yes Nitrophenol YesNitrophenol (ortho, meta, para) YesNonyltrichlorosilane YesNorbormide YesOCMB YesOctadecyltrichlorosilane YesOctyltrichlorosilane Yes

Page 38

Appendix C





Oleum (fuming sulfuric acid) YesOMPA YesOrganorhodium Complex (PMN-82-147) Yes YesOrthozenol YesOuabain Yes Oxabicyclo[2.2.1] heptane-2,3-dicarboxylic acid, 7- YesOxamyl Yes Oxetane,3,3-bis (chloromethyl Yes Oxydisulfoton Yes Oxygen difluoride YesOzone YesPara-(5-amino-3-phenyl-1H-1,2,4-triazol-1-yl) - N,N,N',N-tetrametnyl ph Yes

Para-oxon YesParaquat Yes Paraquat methosulfate Yes Paration Yes YesParathion mixture, dry YesParathion-methyl Yes Paris green Yes PCP YesPensal YesPentaborane Yes YesPentachlorophenol YesPentadecylamine Yes Perecetic acid Yes Perchloromethylmercaptan Yes YesPesticides not specifically listed YesPextox 14 Yes

Page 39

Appendix C





Phenarsazine chlorine YesPhenol Yes Phenol, 2,2'-thiobis(4,6-dichlororo- Yes Phenol, 2,2'-thiobis(4-chloro-6-methyl)- Yes Phenol, 3- (1-methylethyl)-, methlycarbamate Yes Phenoxarsine, 10,10'-oxydi- Yes Phenyl chloromethyl ketone Yes YesPhenylbenzene YesPhenylhydrazine hydrochloride Yes Phenylmercury acetate Yes Phenylphenol YesPhenylsilatrane Yes Phenylthiourea Yes Phenyltrichlorosilane Yes YesPhorate Yes Phorate, thimet, O,O-diethyl-S-[(ethylthio)methyl] phosphorodithioate Yes

Phosacetim Yes Phosdrin YesPhosfolan Yes Phosfolan, Cyolan, 2-(Diethoxyphosphinylimono) 1,3-dithiolane YesPhosgene Yes Phosgene, Carbonyl Chloride YesPhosmet Yes Phosphamidon Yes Phosphamidon, Dimecorn, 2-Chloro-2-diethylcarbamoyl- 1-methylvinyl dime Yes

Phoshpine Yes YesPhosphonothioic Acid, Methyl-,o-(4Nitrophenyl) O-phen Yes Phosphonothioic Acid, Methyl-,o-Ehtyl o-(4-(Methylthio Yes

Page 40

Appendix C





Phosphonothioic Acid, Mehtyl-,s-(2(Bis(1-Methylethyl) A Yes Phosphoric Acid, Dimethyl-4-(Methylthio)Phenyl Ester Yes Phosphoric Chloride YesPhosphorous Yes Phosphorus Oxychloride Yes YesPhosphorus Pentachloride Yes Phosphorus Pentasulfide YesPhosphorus Pentoxide Yes Phosphorus Sesquisulfide, Tetraphosphorus Trisulfide YesPhosphorus Tribromide YesPhosphorus Trichloride Yes YesPhosphorus Trisulfide YesPhosphorus, White or Yellow, Dry YesPhosphoryl Bromide YesPhostoxin YesPhysostigmine Yes Physostigmine, Salicylate (1:1) Yes Picrotoxin Yes Piperidine Yes Piprotal Yes Pirimifos-Ethyl Yes Platinum Compounds YesPolychlorinated Biphenyls (PCBs) YesPolychlorocamphene YesPotassium Acid Fluoride YesPotassium Arsenate YesPotassium Arsenite Yes YesPotassium Bifluoride YesPotassium Cyanide Yes Yes

Page 41

Appendix C





Potassium Cyanide Solution YesPotassium Cyanide Solid YesPotassium Hydride YesPotassium Silver Cyanide Yes Potassium (Metal or Metallic) YesPromecarb Yes Propanenitrile, 3-chloro Yes Propargyl Bromide Yes YesPropiolactone, Beta- Yes YesPropionitrile Yes Propiophenone, 4-Amino- Yes Propyl Chloroformate Yes Propylene Oxide Yes Propyleneimine Yes YesPropyltrichlorosilane YesProthoate Yes YesPyranol YesPyrene Yes Pyridine, 2-Methyl-5-Vinyl Yes Pyridine, 4-Amino- Yes Pyridine, 4-Nitro-, 1-Oxide Yes Pyriminil Yes Pyrophoric YesQuinone YesRacumin 57 YesRatox YesS,,(4-Chlorophenyl) thio.methyl.O,O-diethyl Phosphorodithioate YesS-,2-(ethyl-sulfonyl)ethyl.O,O-dimethyl Phosphorothioate YesSalcomine Yes

Page 42

Appendix C





Sarin Yes Schradan YesSelenious Acid Yes Selenium YesSelenium Compounds YesSelenium Flouride YesSelenium Oxychloride Yes Selenous Acid and Salts YesSemicarbazide Hydrochloride Yes Silane, (4-Aminobutyl) Diethoxymethyl Yes Silicochloroform YesSilicon Chloride YesSilicon Tetrachloride YesSilver Acetylide YesSilver Cyanide YesSinox YesSodium Alumionum Hydride YesSodium Amide YesSodium Arsenate Yes YesSodium Arsenite Yes Sodium Azide (Na(N3)) Yes Sodium Bifluoride YesSodium Cacodylate Yes YesSodium Cyanide Yes YesSodium Cyanide, Solid YesSodium Dimethylarsenate YesSodium Fluoroacetate Yes Sodium Hydride YesSodium Hypochloride Yes

Page 43

Appendix C





Sodium Methylate YesSodium Pentachlorophenate Yes Sodium Peroxide YesSodium Potassium Alloy YesSodium Selenate Yes YesSodium Selenite Yes Sodium Tellurite Yes Sodium, Metal Dispersion in Organic Solvent YesSodium, Metal or Metallic YesStannane, Acetoxytriphenyl Yes Strontium Arsenate YesStrychnine Yes YesStrychnine, Sulfate Yes Sulfonyl Chloride YesSulfotep Yes Sulfoxide, 3-Chloropropyl Octyl Yes Sulfur Chloride YesSulfur Dioxide Yes Sulfur Mustard YesSulfur Oxychloride YesSulfur Pentafluoride YesSulfur Tetrafluoride Yes Sulfur Trioxide Yes Sulfuric Acid Yes Sulfuric Anhydride YesSulfuryl Chloride YesSulfuryl Fluoride, Sulfonyl Fluoride YesSupracide Yes

Page 44

Appendix C





Surecide, Cyanophenphos, o-para-Cyanophenyl-O-ethyl Phenyl Phosphonoth Yes

Systox YesTabun Yes TDI YesTEDP YesTel (and other organic lead) YesTellurium Yes Tellurium Hexafluoride Yes YesTelodrin, Isobenzan YesTemik YesTEPA YesTEPP Yes YesTerbufos Yes Tetrachlorodibenzo-p-dioxin (TCDD), 2,3,7,8- YesTetrachlorodibenzo-para-dioxin, 2,3,7,8- YesTetraethyl Eithionopyrophosphate YesTetraethyl Lead (Export Shipment by Water) YesTetraethyl Pyrophosphate YesTetraethyl Pyrophosphate mixture, dry YesTetraethyl Pyrophosphate, liquid YesTetraethyl Lead Yes Tetraethyltin Yes YesTetramethylphosphorodiamidic Fluoride YesTetranitromethane Yes YesTetraphosphorus Trisulfide YesTetrasul YesThallium YesThallium compounds Yes

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Appendix C





Thallium Sulfate Yes Thallium (1) Acetate YesThallium (1) Carbonate YesThallous Carbonate Yes Thallous Chloride Yes Thallous Malonate Yes Thallous Sulfate Yes Thimet YesThiocarbazide Yes Thiocarbonylchloride YesThionazin Yes YesThionyl Chloride YesThiophenol Yes Thiophosgene YesThiophosphoryl Chloride YesThiosemicarbazide Yes Thiotanox Yes Thiourea, (2-Chlorophenyl)- Yes Thiourea, (2-Methylphenyl)- Yes Titanic Chloride YesTitanium Tetrachloride Yes YesToluene Diisocynate YesToluene-2,4-Diisocyanate Yes YesToluene-2,6-Diisocyanate Yes Toxaphene (Polychlorinated Camphenes) YesTranid Yes Trans-1,4-Dichlorobutene Yes Triamiphos Yes YesTriazofos Yes

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Appendix C





Trichloro (Chloromethyl) Silane Yes Trichloro (Dichlorophenyl) Silane Yes Trichloroacetyl Chloride Yes Trichloroborane YesTrichlorethylsilane Yes Trichloromethanesulfenyl Chloride YesTrichloronate Yes Trichloronitromethane YesTrichlorophenoxyacetic Acid, 2,4,5-T, YesTrichlorosilane YesTriethoxysilane Yes Triethylenephosphoramide YesTrifluoromethylbenzene YesTrimethylchlorosilane Yes Trimethylolpropane Phosphite Yes Trimethyltin Chloride Yes Triphenyltin Chloride Yes Tris (2-Chloroethyl) Amine Yes Tris- (1-Axiridinyl) Phosphine Oxide YesTrithion YesUDMH YesUltracide YesValinomycin Yes Vanadic Acid Anhydride YesVanadium Pentoxide Yes YesVapona YesVinyl Acetate Monomer Yes Vinyl Chloride Yes

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Appendix C





Vinyl Trichlorosilane YesWarfarin Yes Warfarin Sodium Yes Water Reactive Compounds YesWepsyn 155 YesWP 155 YesXylylene Dichloride Yes Zectranh YesZinc Arsenate YesZinc Cyanide YesZinc Phosphide Yes YesZinc, Dichloro(4,4-Dimethyl-5((((Methylamino )Carbonyl) O Yes Zinophos, O,O-Tetramethylthiuram Monosulfide YesZinconium Tetrachloride Yes

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Appendix D

Requirements for Incompatible WastesA. Incompatible wastes shall not be placed in the same container in order to prevent the

occurrence of the following reactions:

1. generate extreme heat or pressure, fire or explosions, or violent reactions;2. produce uncontrolled toxic mists, fumes, dusts, or gases in sufficient quantities

to threaten human health or the environment;3. produce uncontrolled flammable fumes or gases in sufficient quantities to pose

a risk of fire or explosions;4. damage the structural integrity of the device or facility;5. through other like means threaten human health or the environment.

B. Hazardous waste shall not be placed in an unwashed container that previously held an incompatible waste or material.

C. A container holding a hazardous waste that is incompatible with any waste or other materials transferred or stored nearby in other containers, piles, open tanks, or surface impoundment’s shall be separated from the other material or protected from them by means of a dike, berm, wall, or other device. 22 CCR 66264.177.

Examples of Potentially Incompatible Waste

Many hazardous wastes, when mixed with other waste or materials can produce effects which are harmful to human health and the environment, such as (1) heat or pressure, (2) fire or explosion, (3) violent reaction, (4) toxic dusts, mists, fumes, or gases, or (5) flammable fumes or gases. Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences, which result from mixing materials in one group with materials in another group. The list is intended as a guide to indicate the need for special precautions when managing these potentially incompatible waste materials or components.

This list is not intended to be exhaustive. Faculty, Staff and EH&S shall, as regulations require, adequately analyze all wastes so as to avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not. Any questions or concerns should be addressed to EH&S at extension 4697.

In the lists below, the mixing of a Group A material with a Group B material may have the potential consequence as noted.

Group 1 – A Group 1 - BAcetylene Sludge Acid sludgeAlkaline caustic liquids Acid and waterAlkaline cleaner Battery acid Alkaline corrosive liquids Chemical cleanersAlkaline corrosive battery fluid Electrolyte, acidCaustic wastewater Etching acid liquid or solventLime sludge and other corrosive alkaliesLime wastewater Pickling liquor and other

corrosive acidsLime and water Spent acidSpent caustic Spent mixed acid

Spent sulfuric acid

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Potential consequences: Heat generation;violent reaction.

Group 2 – A Group 2 - BAluminum Any waste in Group

1 - A or 1 - BBerylliumCalciumLithiumMagnesiumPotassiumSodiumZinc powderOther reactive metals and metal hydridesPotential consequences: Fire or explosion; Generation of

flammable hydrogen gas.

Group 3 – A Group 3 - BAlcohols Any concentrated waste in

Groups 1 - A or 1 - B.Water Calcium

LithiumMetal hydridesPotassium SO2Cl2, SOCl2, PCl3, CH3SiCl3Other water - reactive waste

Potential consequences: Fire, explosion, or heat generation; generation of Flammable or toxic gases.

Group 4 – A Group 4 - BAlcohols Concentrated Group 1 - A or 1 - B

wastes Aldehydes Group 2 - A wastesHalogenated hydrocarbonsNitrated hydrocarbonsUnsaturated hydrocarbonsOther reactive organic compounds and solventsPotential consequences: Fire, explosion, or violent reaction.

Group 5 – A Group 5 - BSpent cyanide and sulfide solutions Group 1 - B wastesPotential consequences: Generation of toxic hydrogen cyanide

or hydrogen sulfide gas.

Group 6 – A Group 6 - BChlorates Acetic acid and other organic acidsChlorine Concentrated mineral acidsChlorites Group 2 - A wastesChromic acid Group 4 - A wastesHypochlorite Other flammable and combustible wastes

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NitratesNitric acid, fumingPerchloratePermanganatesPeroxidesOther strong oxidizersPotential consequences: Fire, explosion, or violent reaction.

Partial List of Incompatible Chemicals

The following list of chemicals in the left hand column should be transported, stored, used, and disposed of in such a manner that they do not accidentally come in contact with the corresponding chemicals in the right hand column. These chemicals could react violently if allowed to come in accidental contact with each other, resulting in an explosion, or may produce highly toxic and/or flammable gases or vapors. However, it should be remembered that this list is not in any way complete, but is to serve only as a guide for the more commonly used chemicals.

Acetic acid Chromic acid, Ethylene glycol, Hydroxyl-containing compounds, Nitric acid, Perchloric acid, Permanganates, Peroxides, Carbon tetrachloride, and other hydrocarbons.

Acetone Bromine, Chlorine, Nitric acid, Sulfuric acid, Chloroform, and Alumina.

Acetylene Bromine, Chlorine, Copper (tubing), Fluorine, Silver, Mercury or their compounds.

Alkaline and alkaline earth metals such as Calcium, Cesium, Lithium, Powdered Aluminum, Magnesium, Potassium, and Sodium.

Carbon dioxide, Chlorinated hydrocarbons, Fluorine, Iodine, and Water.

Aluminum and its alloys

(particularly powders)Acid or alkaline solutions, Ammonium persulphate and water, Chlorates, Chlorinated compounds, Nitrates, and Organic compounds in nitrate/nitrite salt baths.

Ammonia (anhydrous) Bromine, Calcium, Hyprchlorite, Chlorine, Halogens, Hydrogen fluoride, Hydrofluoric (anhydrous), Iodine, Mercury (in manometers, for example), and Silver.

Ammonium perchlorate, Permanganate, or Persulfate

Combustible materials: Oxidizing materials such as acids, Chlorates, and Nitrates.

Ammonium nitrate Acid, Chlorates, Chlorides, Lead, Metallic nitrates, Metal powders, finely divided Organics or Combustibles, Sulfur, Zinc, Flammable fluids.

Aniline Hydrogen peroxide, Nitric acid, or other strong oxidizing agents

Arsenical materials Any reducing agentAzides AcidsBarium peroxide Combustible Organics, Oxidizable

materials, and water.Barium rhodanide Sodium NitrateBismuth and its alloys Perchloric acidBromine Acetone, Acetylene, Ammonia, Benzene,

Butadiene, Butane and other Petroleum gases, Hydrogen, finely divided Metals,

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Sodium Carbide, and Turpentine.Calcium or Sodium Carbide Moisture (in air) or water.Calcium Hypochlorite (Activated) Ammonia or Carbon.Calcium Oxide WaterCarbon (activated) Calcium hypochlorite, all Oxidizing agentsCarbon tetrachloride SodiumCarbon tetrachloride SodiumChlorates or Perchlorates Acids, Aluminum, Ammonium salts,

Carbon, Cyanides, Phosphorus, Metal powders, Oxidizable Organics or other Combustibles, Sugar, Sulfides, and Sulfur.

Chlorine Acetone, Acetylene, Ammonia, Benzene, Butadiene, Butane, and other Petroleum gases, finely divided Metals, Hydrogen, Metal powders, Methane, Propane (or other petroleum gases), sodium carbide, and Turpentine.

Chlorine dioxide Ammonia, Hydrogen Sulfide, Methane, and Phosphine.

Chromic acid and Chromium trioxide Acetic acid (glacial), Acetic anhydride, Alcohol’s, Camphor, Combustible materials, Flammable liquids, Glycerine, Naphthalene, Nitric acid, Sulfur, and Turpentine.

Copper Acetylene, Hydrogen peroxideCumene hydroperoxide Acids (mineral or organic)Cyanides Acids or alkaliesFlammable Liquids Ammonium nitrate, Chromic acid, Hydrogen

peroxide, Nitric acid, sodium peroxide, Halogens.

Fluorine Most mineralsHydrocarbons such as Benzene, Butane, Gasoline, Propane, Turpentine, etc.

Bromine, Chlorine, Chromic acid, Fluorine, Hydrogen peroxide, and Sodium peroxide.

Hydrofluoric acid or Anhydrous hydrogen fluoride

Ammonia (anhydrous or aqueous)

Hydrocyanic acid or Hydrogen cyanide Alkalies and Nitric acidHydrogen peroxide 3% Copper, Chromium, Iron, most metals or

their salts, Alcohols, Acetone, Organic materials, Aniline, Nitro-methane, Combustible materials.

Hydrogen peroxide 30% or 90% Same as 3% Hydrogen peroxide plus Aniline, any Flammable Liquids, Combustible materials, Nitro-methane, and all other Organic matter.

Hydrogen sulfide Fuming Nitric acid or Oxidizing gasesHypochlorites Acids, Activated CarbonIodine Acids, moisture in air, and Water.Lithium aluminum hydride Air, Chlorinated hydrocarbons, Carbon

dioxide, Ethyl acetate, and Water.Magnesium (particularly powder) Carbonates, Chlorates, Heavy metal

oxalates or oxides, Nitrates, Perchlorates, Peroxides, Phosphates, and Sulfates.

Mercuric oxide SulfurMercury Acetylene, Alkali metals, Ammonia,

Fulminic acid, Hydrogen, Nitric acid with ethanol and oxalic acid.

Nitrates Combustible materials, Esters, Phosphorous, Sodium acetate, Stannous chloride, Sulfuric acid, Water, and Zinc Powder.

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Nitric acid (conc) Acetic acid, Aniline, Chromic acid, Flammable gases and liquids, Hydrocyanic acid, Hydrogen sulfide, and Nitratable substances, Copper Brass, and heavy Metals.

Nitric acid Alcohols and other oxidizable organic material, Hydriodic acid (Hydrogen Iodide), Magnesium or other metals, Phosphorous, Thiophene and Carbon.

Nitrites Acids, Potassium or Sodium cyanideNitro paraffins Inorganic alkalies, Bases, Amines.Oxalic acid Mercury or Silver.Oxygen (liquid or enriched air) Flammable gases, Liquids or solids such as

Acetone, acetylene, Grease, Hydrogen, Oils, and Phosphorous.

Perchloric acid Acetic anhydride, Alcohols, Bismuth and its alloys, Paper, Wood, Grease, Oils or any organic materials, and Reducing agents.

Peroxides (organic) Acids (mineral or organic), Avoid friction, Store cold.

Phosphorous Chlorates and perchlorates, Nitrates and Nitric acid.

Phosphorous pentoxide Organic compounds or Water.Phosphorous (Red) Oxidizing materialsPhosphorous (White) Air (oxygen) or other oxidizing materials,

Alkalies, Reducing agents.Picric acid Ammonia heated with oxides or salts of

heavy metals and friction with oxidizing agents.

Potassium Air (moisture and/or oxygen), or Water, Carbon dioxide, Carbon tetrachloride.

Potassium chlorate or perchlorate Acids or their vapors, Combustible materials, especially organic solvents, Phosphorous, and Sulfur.

Potassium permanganate Benzaldehyde ethylene glycol, Glycerin, Glycerol, Sulfuric acid, and Reducing agents.

Selenides Reducing agents.Silver Acetylene, Ammonium compounds, Nitric

acid with ethanol, Oxalic acid, Tartaric acid and Fulminic acid.

Sodium Carbon tetrachloride, Carbon dioxide, Water.

Sodium amide Air (moisture and oxygen) or Water.Sodium chlorate Acids, Ammonium salts, Oxidizable

materials, and Sulfur.Sodium hydrosulfite Air (moisture and oxygen) or Water.Sodium nitrite Ammonia compounds, Ammonium nitrate,

or other Ammonium salts.Sodium peroxide Acetic acid (glacial) acetic anhydride,

Alcohols, Penzaldehyde carbon disulfide ethyl acetate, Ethylene glycol furfural, Glycerine, Methanol, Methyl acetate, and other oxidizable substances.

Sulfides AcidsSulfur Any oxidizing materialsSulfuric acid Potassium chlorate, Potassium perchlorate,

Potassium permanganate (similar compounds of light metals, such as

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Sodium, Lithium) and Water.Tellurides Reducing agentsWater Acetyl chloride, Alkaline and Alkaline Earth

Metals, their Hydrides and Oxides barium peroxide carbides, Chromic acid, Phosphorous oxychloride, Phosphorous pentachloride, Phosphorous pentoxide, Sulfuric acid and Sulfur trioxide, etc.

Zinc chlorate Acids or organic materialsZinc (particularly powder) Acids of waterZirconium (particularly in powder form) Carbon tetrachloride and other Halogenated

Hydrocarbons, Peroxides, Sodium bicarbonate, and Water.

This partial listing of incompatible chemicals was located on Humboldt’s Web Site (www.humboldt.edu/ehs/chemical.html) and applies to CSPUP. The CSPUP Environmental Health & Safety Department wishes to thank the EH&S Department at Humboldt for having this on their web site for all to use.

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http://www.humboldt.edu/ehs/chemical.html

Appendix E

Hazardous Waste List

(California Code of Regulations, Title 22 Section 66261.126)

Appendix X - List of Chemical Names and Common Names for Hazardous Wastes and Hazardous Materials

(a) This subdivision sets forth a list of chemicals, which create a presumption that a waste is a hazardous waste. If a waste consists of or contains a chemical listed in this subdivision, the waste is presumed to be a hazardous waste Environmental Regulations of CALIFORNIA unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristics, which serve as a basis for listing the chemicals, are indicated in the list as follows:

(X) toxic (C) corrosive (I) ignitable (R) reactive * =Extremely Hazardous

A chemical denoted with an asterisk is presumed to be an extremely hazardous waste unless it does not exhibit any of the criteria set forth in section66261.110 and section 66261.113. Trademark chemical names are indicated by all capital letters.

1. Acetaldehyde (X,I) 2. Acetic acid (X,C,I)

3. Acetone, Propanone (I) 4. *Acetone cyanohydrin (X)

5. Acetonitrile (X,I) 6. *2-Acetylaminofluorene, 2-AAF (X)

7. Acetyl benzoyl peroxide (X,I,R) 8. *Acetyl chloride (X,C,R)

9. Acetyl peroxide (X,I,R) 10. Acridine (X)

11. *Acrolein, Aqualin (X,I) 12. *Acrylonitrile (X,I)

13. *Adiponitrile (X) 14. *Aldrin;1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4,5,8-endo-exodimethanonaphthlene(X)

15. *Alkyl aluminum chloride (C,I,R) 16. *Alkyl aluminum compounds (C,I,R)

17. Allyl alcohol, 2-Propen-l-ol (X,I) 18. Allyl bromide, 3-Bromopropene (X,I)

19. Allyl chloride, 3-Chloropropene (X,I) 20. Allyl chlorocarbonate, Allyl chloroformate (X,I)

21. *Allyl trichlorosilane (X,C,I,R) 22. Aluminum (powder) (I)

23A. Aluminum chloride (X,C) 23B. *Aluminum chloride (X,C,I)

24. Aluminum fluoride (X,C) 25. Aluminum nitrate (X,I)

26. *Aluminum phosphide, PHOSTOXIN (X,I,R)

27. *4-Aminodiphenyl, 4-ADP (X)

28. *2-Aminopyridine (X) 29. *Ammonium arsenate (X)

30. *Ammonium bifluoride (X,C) 31. Ammonium chromate (X,I)

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32. Ammonium dichromate, Ammonium bichromate (X,C,I)

33. Ammonium fluoride (X,C)

34. Ammonium hydroxide (X,C) 35. Ammonium molybdate (X)

36. Ammonium nitrate (I,R) 37. Ammonium perchlorate (I,R)

38. Ammonium permanganate (X,I,R) 39. Ammonium persulfate (I,R)

40. Ammonium picrate (I,R) 41. Ammonium sulfide (X,C,I,R)

42. n-Amyl acetate, 1-Acetoxypentane (and isomers) (X,I)

43. n-Amylamine, 1-Aminopentane (and isomers) (X,I)

44. n-Amyl chloride, 1-Chloropentane (and isomers) (X,I)

45. n-Amylene, 1-Pentene (and isomers) (X,I)

46. n-Amyl mercaptan, 1-Pentanethiol (and isomers) (X,I)

47. n-Amyl nitrite, n-Pentyl nitrite (and isomers) (X,I)

48. *Amyl trichlorosilane (and isomers) (X,C,R)

49. Aniline, Aminobenzene (X)

50. Anisoyl chloride (X,C) 51. Anthracene (X)

52. Antimony (X)

53. Antimony compounds (X) 54. *Antimony pentachloride (X,C,R)

55. *Antimony pentafluoride (X,C,R) 56. Antimony pentasulfide (X,I)

57. Antimony potassium tartrate (X) 58. Antimony sulfate, Antimony trisulfate (X,I)

59. Antimony trichloride, Antimony chloride (X,C)

60. Antimony trifluoride, Antimony fluoride (X,C)

61. Antimony trioxide, Antimony oxide (X) 62. Antimony trisulfide, Antimony sulfide (X,I,R)

63. *Arsenic (X) 64. *Arsenic acid and salts (X)

65. *Arsenic compounds (X) 66. *Arsenic pentaselenide (X)

67. *Arsenic pentoxide, Arsenic oxide (X) 68. *Arsenic sulfide, Arsenic disulfide (X)

69. *Arsenic tribromide, Arsenic bromide (X)

70. *Arsenic trichloride, Arsenic chloride (X)

71. *Arsenic triiodide, Arsenic iodide (X) 72. *Arsenic trioxide, Arsenious oxide (X)

73. *Arsenious acid and salts (X) 74. *Arsines (X)

75. Asbestos (including chrysotile, amosite, crocidolite, tremolite,anthophyllite, and actinolite) (X)

76. *AZODRIN, 3-Hydroxy-N-cis-crotonamide (X)

77. Barium (X,I) 78. Barium azide (I,R)

79. Barium bromide (X) 80. Barium carbonate (X)

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81. Barium chlorate (X,C,I,R) 82. Barium chloride (X)

83. Barium chromate (X) 84. Barium citrate (X)

85. Barium compounds (soluble) (X) 86. *Barium cyanide (X)

87. Barium fluoride (X) 88. Barium fluosilicate (X)

89. Barium hydroxide (X) 90. Barium iodide (X)

91. Barium manganate (X) 92. Barium nitrate (X,I)

93. Barium oxide, Barium monoxide (X) 94. Barium perchlorate (X,I,R)

95. Barium permanganate (X,I,R) 96. Barium peroxide (X,I,R)

97. Barium phosphate (X) 98. Barium stearate (X)

99. Barium sulfide (X) 100. Barium sulfite (X)

101. Benzene (X,I) 102. *Benzene hexachloride, BHC; 1,2,3,4,5,6-Hexachlorocyclohexane (X)

103. *Benzenephosphorous dichloride (I,R)

104. Benzenesulfonic acid (X)

105. *Benzidine and salts (X) 106. *Benzotrifluoride, Trifluoromethylbenzene (X,I)

107. *Benzoyl chloride (X,C,R) 108. Benzoyl peroxide, Dibenzoyl peroxide (X,I,R)

109. Benzyl bromide, alpha-Bromotoluene (X,C)

110. Benzyl chloride, alpha-Chlorotoluene (X)

111. *Benzyl chlorocarbonate, Benzyl chloroformate (X,C,R)

112. *Beryllium (X,I)

113. *Beryllium chloride (X) 114. *Beryllium compounds (X)

115. *Beryllium copper (X) 116. *Beryllium fluoride (X)

117. *Beryllium hydride (X,C,I,R) 118. *Beryllium hydroxide (X)

119. *Beryllium oxide (X) 120. *BIDRIN, Dicrotophos, 3-(Dimethylamino)-1-methyl-3-oxo-1-propenyldimethylphosphate (X)

121. *bis (Chloromethyl) ether, Dichloromethylether, BCME (X)

122. Bismuth (X,I)

123. *bis (Methylmercuric) sulfate, CEREWET, Ceresan liquid (X)

124. Bismuth chromate (X)

125. *BOMYL, Dimethyl 3-hydroxyglutaconate dimethyl phosphate (X)

126. *Boranes (X,I,R)

127. *Bordeaux arsenites (X) 128. *Boron trichloride, Trichloroborane (X,C,R)

129. *Boron trifluoride (X,C,R) 130. Bromic acid (X)

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131. *Bromine (X,C,I) 132. *Bromine pentafluoride (X,C,I,R)

133. *Bromine trifluoride (X,C,I,R) 134. *Brucine, Dimethoxystrychnine (X)

135. 1,2,4-Butanetriol trinitrate (R) 136. n-Butyl acetate, 1-Acetoxybutane (and isomers) (X)

137. n-Butyl alcohol, 1-Butanol (and isomers) (X)

138. n-Butyl amine, 1-Aminobutane (and isomers) (X)

139. n-Butyl formate (and isomers) (X) 140. tert-Butyl hydroperoxide (and isomers) (X,I)

141. *n-Butyllithium (and isomers) (X,C,I,R)

142. n-Butyl mercaptan, 1-Butanethiol (and isomers) (X,I)

143. tert-Butyl peroxyacetate, tert-Butyl peracetate (I,R)

144. tert-Butyl peroxybenzoate, tert-Butyl perbenzoate (I,R)

145. tert-Butyl peroxypivalate (I,R) 146. *n-Butyltrichlorosilane (C,I,R)

147. para-tert-Butyl toluene (X) 148. n-Butyraldehyde, n-Butanal (and isomers) (X,I)

149. *Cacodylic acid, Dimethylarsinic acid (X)

150. *Cadmium (powder) (X,I)

151. Cadmium chloride (X) 152. *Cadmium compounds (X)

153. *Cadmium cyanide (X) 154. Cadmium fluoride (X)

155. Cadmium nitrate (X,I,R) 156. Cadmium oxide (X)

157. Cadmium phosphate (X) 158. Cadmium sulfate (X)

159. *Calcium (I,R) 160. *Calcium arsenate, PENSAL (X)

161. *Calcium arsenite (X) 162. *Calcium carbide (C,I,R)

163. Calcium chlorate (I,R) 164. Calcium chlorite (I)

165. Calcium fluoride (X) 166. *Calcium hydride (C,I,R)

171. Calcium oxide, Lime (C) 172. Calcium permanganate (X,I)

173. Calcium peroxide, Calcium dioxide (C,I)

174. *Calcium phosphide (X,I,R)

175. Calcium resinate (I) 176. Caprylyl peroxide, Octyl peroxide (I)

177. *Carbanolate, BANOL, 2-Chloro-4,5-dimethylphenyl methylcarbamate (X)

178. Carbon disulfide, Carbon bisulfide (X,I)

179. Carbon tetrachloride, Tetrachloromethane (X)

180. *Carbophenothion, TRITHION, S[[(4-Chlorophenyl) thio]methyl] O,O-diethylphosphorodithioate (X)

181. Chloral hydrate, Trichloroacetaldehyde (hydrated) (X)

182. *Chlordane; 1,2,4,5,6,7,8,8-

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Octachloro-4,7-methano-3a,4,7,7a-tetra-hydro- indane; (X)

183. *Chlorfenvinphos, Compound 4072, 2-Chloro-1-(2,4-dichloro-phenyl) vinyldiethyl phosphate (X)

184. *Chlorine (X,C,I,R)

185. *Chlorine dioxide (X,C,I,R) 186. *Chlorine pentafluoride (X,C,I,R)

187. *Chlorine trifluoride (X,C,I,R) 188. *Chloroacetaldehyde (X,C)

189. *alpha-Chloroacetophenone, Phenyl chloromethyl ketone (X)

190. *Chloroacetyl chloride (X,C,R)

191. Chlorobenzene (X,I) 192. para-Chlorobenzoyl peroxide (I,R)

193. *ortho-Chlorobenzylidene malonitrile, OCMB (X)

194. Chloroform, Trichloromethane (X)

195. *Chloropicrin, Chlorpicrin, Trichloronitromethane (X)

196. *Chlorosulfonic acid (X,C,I,R)

197. Chloro-ortho-toluidine, 2-Amino-4-chlorotoluene (X)

198. Chromic acid, Chromium trioxide, Chromic anhydride (X,C,I)

199. Chromic chloride, Chromium trichloride (X)

200. Chromic fluoride, Chromium trifluoride (X)

201. Chromic hydroxide, Chromium hydroxide (X)

202. Chromic oxide, Chromium oxide (X)

203. Chromic sulfate, Chromium sulfate (X)

204. Chromium compounds (X,C,I)

205. *Chromyl chloride, Chlorochromic anhydride (X,C,I,R)

206. Cobalt (powder) (X,I)

207. Cobalt compounds (X) 208. Cobaltous bromide, Cobalt bromide (X)

209. Cobaltous chloride, Cobalt chloride (X)

210. Cobaltous nitrate, Cobalt nitrate (X,I)

211. Cobaltous resinate, Cobalt resinate (X,I)

212. Cobaltous sulfate, Cobalt sulfate (X)

213. Cocculus, Fishberry, Picrotoxin (X) 215. *Copper acetoarsenite, Paris green (X)

216. Copper acetylide (I,R) 217. *Copper arsenate, Cupric arsenate (X)

218. *Copper arsenite, Cupric arsenite (X)

219. Copper chloride, Cupric chloride (X)

220. Copper chlorotetrazole (I,R) 221. Copper compounds (X)

222. *Copper cyanide, cupric cyanide (X) 223. Copper nitrate, Cupric nitrate (X,I,R)

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224. Copper sulfate, Cupric sulfate, Blue vitriol (X)

225. *Coroxon ortho, ortho-diethyl-ortho-(3-Chloro-4-methycou-marin-7-yl)

phosphate (X) 226. *Coumafuryl, FUMARIN, 3-[1-(2-Furanyl)-3-oxobutyl]1-4-hydroxy-

2H-1-benzopyran-2-one (X) 227. *Coumatetralyl, BAYER 25634, RACUMIN 57, 4-Hydroxy -3- (1,2,3,4- tetrahydro-1-naphthalenyl) -2H-1-benzopyran-2-one (X)

228. *Crimidine, CASTRIX, 2-Chloro-4-dimethylamino-6-methyl-pyrimidine (X)

229. *Crotonaldehyde, 2-Butenal (X)

230. Cumene, Isopropyl benzene (X,I)@ 231. Cumene hydroperoxide; alpha,alpha-Dimethylbenzyl hydro-peroxide (X,I)

232. Cupriethylene diamine (X) 233. *Cyanide salts (X)

234. Cyanoacetic acid, Malonic nitrile (X) 235. *Cyanogen (X,I,R)

236. Cyanogen bromide, Bromine cyanide (X)

237. Cyanuric triazide (I,R)

238. Cycloheptane (X,I) 239. Cyclohexane (X,I)

240. Cyclohexanone peroxide (I) 241. *Cyclohexenyltrichlorosilane (X,C,R)

242. *Cycloheximide, ACTIDIONE (X) 243. *Cyclohexyltrichlorosilane (X,C,R)

244. Cyclopentane (X,I) 245. Cyclopentanol (I)

246. Cyclopentene (X,I) 247. DDT; 1,1,1-Trichloro-2,2-bis(chlorophenyl) ethane (X)

248. *DDVP, Dichlorvos, VAPONA, Dimethyl dichlorovinyl phosphate (X)

249. *Decaborane (X,I,R)

250. DECALIN, Decahydronaphthalene (X)

251. *Demeton, SYSTOX (X)

252. *Demeton-S-methyl sulfone, METAISOSYSTOX-SULFON, S-[2- (ethyl -sulfonyl)ethyl] O,O-dimethyl phosphorothioate (X)

253. Diazodinitrophenol, DDNP, 2-Diazo-4,6-dinitrobenzene-1-oxide (I,R)

254. *Diborane, Diboron hexahydride (I,R)

255. *1,2-Dibromo-3-chloropropane, DBCP, Fumazone, nemagon (X)

256. n-Dibutyl ether, Butyl ether (and isomers) (X,I)

257. Dichlorobenzene (ortho, meta, para) (X)

258. *3,3-Dichlorobenzidine and salts, DCB (X)

259. 1,2-Dichloroethylene; 1,2-Dichloroethene (X,I)

260. Dichloroethyl ether, Dichloroether (X,I)

Page 60

261. Dichloroisocyanuric acid, Dichloro-S-triazine-2,4,6-tri-one (X,I)

262. Dichloromethane, Methylene chloride (X)

263. *2,4-Dichlorophenoxyacetic acid; 2,4-D (X)

264. 1,2-Dichloropropane, Propylene dichloride (X,I)

265. 1,3-Dichloropropylene; 1,3-Dichloropropene (X,I)

266. Dicumyl peroxide (I,X)

267. *Dieldrin;1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4 a,5,6,7,8,8a-octahydro-1,4-endo,exo-5,8-dimethanonaphthalene (X)

268. *Diethylaluminum chloride, Aluminum diethyl monochloride, DEAC (I,R)

269. Diethylamine (X,I) 270. *Diethyl chlorovinyl phosphate, Compound 1836 (X)

271. *Diethyldichlorosilane (X,C,I,R) 272. Diethylene glycol dinitrate (I,R)

273. Diethylene triamine (X) 274. *O,O-Diethyl-S-(isopropylthiomethyl) phosphorodithioate (X)

275. *Diethylzinc, Zinc ethyl (C,I,R) 276. *Difluorophosphoric acid (X,C,R)

277. *Diglycidyl ether, bis(2,3-Epoxypropyl) ether (X)

278. Diisopropylbenzene hydroperoxide (X,I)

279. Diisopropyl peroxydicarbonate, Isopropyl percarbonate(X,C,I,R)

280. *Dimefox, Hanane, Pextox 14, Tetramethylphosphorodiamidic fluoride (X)

281. Dimethylamine, DMA (X,I) 282. *Dimethylaminoazobenzene, Methyl yellow (X)

283. *Dimethyldichlorosilane, Dichlorodimethylsilane (X,C,I,R)

284. 2,5-Dimethylhexane-2,5-Dihydroperoxide (I)

285. *1,1-Dimethylhydrazine, UDMH (X,I) 286. *Dimethyl sulfate, Methyl sulfate (X)

287. *Dimethyl sulfide, Methyl sulfide (X,I,R)

288. 2,4-Dinitroaniline (X)

289. *Dinitrobenzene (ortho, meta, para) (I,R)

290. Dinitrochlorobenzene, 1-Chloro-2,4-dinitrobenzene (I,R)

291. *4,6-Dinitro-ortho-cresol, DNPC, SINOX, EGETOL 30 (X)

292. *Dinitrophenol(2,3-;2,4-;2,6-isomers) (I,R)

293. 2,4-Dinitrophenylhydrazine (X,I,R) 294. Dinitrotoluene (2,4-;3,4-;3,5-isomers) (X,I,R)

295. *DINOSEB; 2,4-Dinitro-6-sec-butylphenol (X)

296. 1,4-Dioxane; 1,4-Diethylene dioxide (X,I,R)

297. *Dioxathion, DELNAV; S,S-1,4-dioxane-2,3-diyl bis (O,O-diethyl phosphorodithioate) (X)

298. Dipentaerythritol hexanitrate (R)

299. *Diphenyl, Biphenyl, Phenylbenzene (X)

300. Diphenylamine, DPA, N-Phenylaniline (X)

Page 61

301. *Diphenylamine chloroarsine, Phenarsazine chloride (X)

302. *Diphenyldichlorosilane (X,C,R)

303. Dipicrylamine, Hexanitrodiphenyl amine (I,R)

304. Dipropyl ether (X,I)

305. *Disulfoton, DI-SYSTON; O,O-Diethyl S-[2-(ethylthio) ethyl]phosphoro dithioate (X)

306. *Dodecyltrichlorosilane (X,C,R)

307. *DOWCO-139, ZECTRAM, Mexacarbate, 4-(Dimethylamino)-3,5 -dimethylphenylmethylcarbamate (X)

309. *DYFONATE, Fonofos, O-Ethyl-S-phenylethyl phosphonodithio-ate (X)

310. *Endosulfan, THIODAN; 6,7,8,9, 10, 10-Hexachlor-1, 5,5a, 6,9,9a-hexa-hydro-6,9-methano-2,4,3-benzo-dioxathiepin- 3-oxide (X)

311. *Endothal, 7-Oxabicyclo [2.2.1]heptane-2,3-dicarboxylic acid (X)

312. *Endothion, EXOTHION, S- [ (5-Methoxy-4-oxo-4H-pyran-2-yl). methyl)0,0-dimethyl phosphorothioate (X)

313. *Endrin; 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a- octahydro-1,4-endo-endo-5,8-dimethanonaphthalene (X)

314. Epichlorohydrin, Chloropropylene oxide (X,I)

315. *EPN; O-Ethyl O-para-nitrophenyl phenylphosphonothioate (X)

316. *Ethion, NIALATE; O,O,O',O'-Tetraethyl-S,S-methylene diphos -phorodithioate(X)

317. Ethyl acetate (X,I)

318. Ethyl alcohol, Ethanol (X,I) 319. Ethylamine, Aminoethane (X,I)

320. Ethylbenzene, Phenylethane (X,I) 321. Ethyl butyrate, Ethyl butanoate (I)

322. Ethyl chloride, Chloroethane (X,I) 323. *Ethyl chloroformate, Ethyl chlorocarbonate (X,C,I,R)

324. *Ethyldichloroarsine, Dichloroethylarsine (I,R)

325. *Ethyldichlorosilane (X,C,I,R)

326. *Ethylene cyanohydrin, beta-Hydroxypropionitrile (I,R)

327. Ethylene diamine (X)

328. Ethylene dibromide; 1,2-Dibromoethane (X)

329. Ethylene dichloride; 1,2-Dichloroethane (X,I)

330. *Ethyleneimine, Aziridine, EI (X,I,R) 331. Ethylene oxide, Epoxyethane (X,I,R)

332. Ethyl ether, Diethyl ether (I,R) 333. Ethyl formate (X,I)

334. *Ethyl mercaptan, Ethanethiol (X,I,R)

335. Ethyl nitrate (I,R)

336. Ethyl nitrite (I,R) 337. *Ethylphenyldichlorosilane (X,C,R)

338. Ethyl propionate (I) 339. *Ethyltrichlorosilane (I,R)

340. *Fensulfothion, BAYER 25141, 341. *Ferric arsenate (X)

Page 62

DASANIT,O,O-Diethyl-O-[4- (methyl-sulfinyl)phenyl] phosphorothioate (X)

342. Ferric chloride, Iron (III) chloride (X,C)

343. *Ferrous arsenate, Iron arsenate (X)

344. *Fluoboric acid, Fluoroboric acid (X,C)

345. Fluoride salts (X)

346. *Fluorine (X,C,R) 347. *Fluoroacetanilide, AFL 1082 (X)

348. *Fluoroacetic acid and salts, Compound 1080 (X)

349. *Fluorosulfonic acid, Fluosulfonic acid (X,C,R)

350. Formaldehyde, Methanal (X,I) 351. Formic acid, Methanoic acid (X,C)

352. Fulminate of mercury, Mercuric cyanate (I,R)

353. *FURADAN, NIA 10,242, Carbofuran;2,3-Dihydro-2,2-dimethyl-7- benzofuranylmethylcarbamate (X)

354. Furan, Furfuran (X,I,R) 355. Gasoline (I)

356. *GB, O-Isopropyl methyl phosphoryl fluoride (X)

357. Glutaraldehyde (X)

358. Glycerolmonolactate trinitrate (R) 359. Glycol dinitrate, Ethylene glycol dinitrate (R)

360. Gold fulminate, Gold cyanate (R) 361. Guanidine nitrate (I,R)

362. Guanyl nitrosaminoguanylidene hydrazine (R)

363. *Guthion; O,O-Dimethyl-S-4-oxo-1,2,3-benzotriazin-3(4H)

- ylmethylphosphorodithioate (X) 364. Hafnium (I,X,R)

365. *Heptachlor;1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetra-hydro- 4,7-methanoindene (X)

366. n-Heptane (and isomers) (X,I) 367. 1-Heptene (and isomers) (X,I)

368. *Hexadecyltrichlorosilane (X,C,R) 369. Hexaethyl tetraphosphate, HETP (X)

370. Hexafluorophosphoric acid (X,C) 371. Hexamethylenediamine; 1,6-Diaminohexane (X)

372. n-Hexane (and isomers) (X,I) 373. 1-Hexene (and isomers) (X,I)

374. n-Hexylamine, 1-Aminohexane (and isomers) (X,I)

375. *Hexyltrichlorosilane (X,C,R)

376. *Hydrazine, Diamine (X,I) 377. Hydrazine azide (I,R)

378. Hydrazoic acid, Hydrogen azide (I,R)

379. *Hydriodic acid, Hydrogen iodide (X,C,R)

380. *Hydrobromic acid, Hydrogen bromide (X,C,R)

381. *Hydrochloric acid, Hydrogen chloride, Muriatic Acid (X,C,R)

382. *Hydrocyanic acid, Hydrogen cyanide (X,I,R)

383. *Hydrofluoric acid, Hydrogen fluoride (X,C,R)

Page 63

384. Hydrofluosilicic acid, Fluosilicic acid (X,C)

385. Hydrogen peroxide (X,C,I,R)

386. *Hydrogen selenide (X,I) 387. *Hydrogen sulfide (X,I)

388. *Hypochlorite compounds (X,C,I,R) 389. Indium (X)

390. Indium compounds (X) 391. Iodine monochloride (X,C,R)

392. Isooctane; 2,2,4-Trimethylpentane (X,I)

393. Isooctene (mixture of isomers) (I)

394. Isopentane, 2-Methylbutane (I) 395. Isoprene, 2-Methyl-1,3-butadiene (X,I,R)

396. Isopropanol, Isopropyl alcohol, 2-Propanol (X,I)

397. Isopropyl acetate (X,I)

399. Isopropylamine, 2-Aminopropane (X,I)

400. Isopropyl chloride, 2-Chloropropane (I)

401. Isopropyl ether, Diisopropyl ether (I,R)

402. Isopropyl mercaptan, 2-Propanethiol (X,I)

404. *meta-Isopropylphenyl-N-methylcarbamate, Ac 5,727 (X)

405A. *Kepone; 1,1a,3,3a,4,5,5,5a,5b,6-Decachlorooctahydro- 1,2,4-metheno-2H-cyclobuta (cd) pentalen-2-one, Chlorecone (X)

405B. Lauroyl peroxide, Di-n-dodecyl peroxide (X,C,I,R)

406. Lead compounds (X)

407. Lead acetate (X) 408. *Lead arsenate, Lead orthoarsenate (X)

409. *Lead arsenite (X) 410. Lead azide (I,R)

411. Lead carbonate (X) 412. Lead chlorite (I,R)

413. *Lead cyanide (X) 414. Lead 2,4-dinitroresorcinate (I,R)

415. Lead mononitroresorcinate (I,R) 416. Lead nitrate (X,I)

417. Lead oxide (X) 418. Lead styphnate, Lead trinitroresorcinate (I,R)

419. *Lewisite, beta-Chlorovinyldichloroarsine (X)

420. *Lithium (C,I,R)

421. *Lithium aluminum hydride, LAH (C,I,R)

422. *Lithium amide (C,I,R)

423. *Lithium ferrosilicon (I,R) 424. *Lithium hydride (C,I,R)

425. *Lithium hypochlorite (X,C,I,R) 426. Lithium peroxide (C,I,R)

427. Lithium silicon (I,R) 428. *London purple, Mixture of arsenic trioxide, aniline, lime, and ferrousoxide (X)

429. *Magnesium (I,R) 430. *Magnesium arsenate (X)

431. *Magnesium arsenite (X) 432. Magnesium chlorate (I,R)

Page 64

433. Magnesium nitrate (I,R) 434. Magnesium perchlorate (X,I,R)

435. Magnesium peroxide, Magnesium dioxide (I)

436. *Maleic anhydride (X)

437. Manganese (powder) (I) 438. Manganese acetate (X)

439. *Manganese arsenate, Manganous arsenate (X)

440. Manganese bromide, Manganous bromide (X)

441. Manganese chloride, Manganous chloride (X)

442. Manganese methylcyclopentadienyl tricarbonyl (X)

443. Manganese nitrate, Manganous nitrate (X,I)

444. Mannitol hexanitrate, Nitromannite (R)

445. *MECARBAM; O,O-Diethyl S-(N-ethoxycarbonyl-N-methylcarbamoyl-methyl)phosphorodithioate (X)

446. *Medinoterb acetate, 2-tert-Butyl-5-methyl-4,6-dinitro-phenyl acetate(X)

447. para-Menthane hydroperoxide, Paramenthane hydroperoxide (I)

448. Mercuric acetate, Mercury acetate (X)

449. Mercuric ammonium chloride, Mercury ammonium chloride (X)

450. Mercuric benzoate, Mercury benzoate (X)

451. Mercuric bromide, Mercury bromide (X)

452. *Mercuric chloride, Mercury chloride (X)

453. *Mercuric cyanide, Mercury cyanide (X)

454. Mercuric iodide, Mercury iodide (X)

455. Mercuric nitrate, Mercury nitrate (X,I)

456. Mercuric oleate, Mercury oleate (X)

457. Mercuric oxide (red and yellow) (X,I) 458. Mercuric oxycyanide (I,R)

459. Mercuric-potassium iodide, Mayer's reagent (X)

460. Mercuric salicylate, Salicylated mercury (X)

461. Mercuric subsulfate, Mercuric dioxysulfate (X)

462. Mercuric sulfate, Mercury sulfate (X)

463. Mercuric thiocyanide, Mercury thiocyanate (X)

464. Mercurol, Mercury nucleate (X)

465. Mercurous bromide (X) 466. Mercurous gluconate (X)

467. Mercurous iodide (X) 468. Mercurous nitrate (I,R)

469. Mercurous oxide (X) 470. Mercurous sulfate, Mercury bisulfate (X)

472. *Mercury (X) 473. *Mercury compounds (X)

474. Metal carbonyls (X) 475. *Metal hydrides (I,R)

476. Metal powders (X,I) 477A. *Methomyl, LANNATE, S-Methyl-N-((methyl-carbamoyl) oxy)

Page 65

thioacetimidate (X) 477B. *Methoxychlor; 1,1,1-Trichloro-2, -bis (p-methoxyphenyl) ethane, CHEMFLORM, MARLATE (X)

478. *Methoxyethylmercuric chloride, AGALLOL, ARETAN (X)

479. Methyl acetate (X,I)

480. Methyl acetone (Mixture of acetone, methyl acetate, and methylalcohol)(X,I)

481. Methyl alcohol, Methanol (X,I)

482. *Methylaluminum sesquibromide (I,R)

483. *Methylaluminum sesquichloride (I,R)

484. Methylamine, Aminomethane (X,I) 485. n-Methylaniline (X)

486. *Methyl bromide, Bromomethane (X) 487. 2-Methyl-1-butene (I)

488. 3-Methyl-1-butene (I) 489. Methyl butyl ether (and isomers)

(X,I)

490. Methyl butyrate (and isomers) (X,I) 491. Methyl chloride, Chloromethane (X,I)

492. *Methyl chloroformate, Methyl chlorocarbonate (X,I,R)

493. *Methyl chloromethyl ether, CMME (X,I)

494. Methylcyclohexane (X,I) 495. *Methyldichloroarsine (X)

496. *Methyldichlorosilane (X,I,R) 497. *4,4-Methylene bis(2-chloroaniline), MOCA (X)

498. Methyl ethyl ether (X,I) 499. Methyl ethyl ketone, 2-Butanone (X,I)

500. Methyl ethyl ketone peroxide (X,I) 501. Methyl formate (X,I)

502. *Methyl hydrazine, Monomethyl hydrazine, MMH (X,I)

503. *Methyl isocyanate (X,I)

504. Methyl isopropenyl ketone, 3-Methyl-3-butene-2-one (X,I)

505. *Methylmagnesium bromide (C,I,R)

506. *Methylmagnesium chloride 507. *Methylmagnesium iodide (C,I,R)

508. Methyl mercaptan, Methanethiol (X,I)

509. Methyl methacrylate (monomer) (X,I)

510. *Methyl parathion; O,O-Dimethyl-O-para-nitrophenylphospho-rothioate (X)

511. Methyl propionate (I)

512. *Methyltrichlorosilane (X,C,I,R) 513. Methyl valerate, Methyl pentanoate (and isomers) (I)

514. Methyl vinyl ketone, 3-Butene-2-one (X,I)

515A. *Mevinphos, PHOSDRIN, 2-Carbomethoxy-1-methylvinyl dimethyl phosphate(X)

515B. *Mirex;1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta(cd) pentalene, Dechlorane (X)

516. *MOCAP, O-Ethyl-S,S-dipropyl phosphorodithioate (X)

517. Molybdenum (powder) (I) 518. Molybdenum trioxide, Molybdenum anhydride (X)

Page 66

519. Molybdic acid and salts (X) 520. Monochloroacetic acid, Chloracetic acid, MCA (X,C)

521. Monochloroacetone, Chloroacetone, 1-Chloro-2-propanone (X)

522. Monofluorophosphoric acid (X,C)

523. Naphtha (of petroleum or coal tar origin), Petroleum ether, Petroleumnaphtha (X,I)

524. Naphthalene (X)

525. *alpha-Naphthylamine, 1-NA (X) 526. *beta-Naphthylamine, 2-NA (X)

527. Neohexane; 2,2-Dimethylbutane (X,I)

528. Nickel (powder) (X,I)

529. Nickel acetate (X) 530. Nickel antimonide (X)

531. *Nickel arsenate, Nickelous arsenate (X)

532. *Nickel carbonyl, Nickel tetracarbonyl (X)

533. Nickel chloride, Nickelous chloride (X)

534. *Nickel cyanide (X)

535. Nickel nitrate, Nickelous nitrate (X,I,R)

536. Nickel selenide (X)

537. Nickel sulfate (X) 538. Nicotine, beta-pyridyl-alpha-N-methyl pyrrolidine (X)

539. Nicotine salts (X) 540. Nitric acid (X,C,I)

541. Nitroaniline, Nitraniline (ortho, meta, para) (I,R)

542. *Nitrobenzol, Nitrobenzene (X)

543. *4-Nitrobiphenyl, 4-NBP (X) 544. Nitro carbo nitrate (I,R)

545. Nitrocellulose, Cellulose nitrate, Guncotton, Pyroxylin, Collodion,Pyroxylin (nitrocellulose) in ether and alcohol (I,R)

546. Nitrochlorobenzene, Chloronitrobenzene (ortho,meta,para) (X)

547. Nitrogen mustard (X,C) 548. Nitrogen tetroxide, Nitrogen dioxide (X,I)

549. Nitroglycerin, Trinitroglycerin (X,I,R) 550. Nitrohydrochloric acid, Aqua regia (X,C,I)

551. *Nitrophenol (ortho, meta, para) (X) 552. *N-Nitrosodimethylamine, Dimethyl nitrosoamine (X)

553. Nitrosoguanidine (R) 554. Nitrostarch, Starch nitrate (I,R)

555. Nitroxylol, Nitroxylene, Dimethylnitrobenzene (2,4-;3,4-; 2,5-isomers)(X)

556. 1-Nonene, 1-Nonylene (and isomers) (X,I)

557. *Nonyltrichlorosilane (I,R) 558. *Octadecyltrichlorosilane (I,R)

559. n-Octane (and isomers) (X,I) 560. 1-Octene, 1-Caprylene (X,I)

Page 67

561. *Octyltrichlorosilane (I,R) 563. *Oleum, Fuming sulfuric acid (X,C,R)

565. Osmium compounds (X) 566. Oxalic acid (X)

567. *Oxygen difluoride (X,C,R) 568. *Para-oxon, MINTACOL; O,O-Diethyl-0-para-nitrophenyl phosphate (X)

569. *Parathion; O,O-Diethyl-0-para-nitrophenyl phosphorothioate (X)

570A. *Pentaborane (X,I,R)

570B. Pentachlorophenol, PCP, DOWICIDE 7 (X)

571. Pentaerythrite tetranitrate, Pentaerythritol tetranitrate (R)

572. n-Pentane (and isomers) (X,I) 573. 2-Pentanone, Methyl propyl ketone (and isomers) (X,I)

574. Peracetic acid, Peroxyacetic acid (X,C,I,R)

575. Perchloric acid (X,C,I,R)

576. Perchloroethylene, Tetrachloroethylene (X)

577. *Perchloromethyl mercaptan, Trichloromethylsulfenyl chloride (X)

578. Perchloryl fluoride (X,C,I) 580. Phenol, Carbolic acid (X,C)

581. *Phenyldichloroarsine (X) 582. Phenylenediamine, Diaminobenzene (ortho,meta,para) (X)

583. Phenylhydrazine hydrochloride (X) 584. *Phenylphenol, Orthozenol, DOWICIDE I (X)

585. *Phenyltrichorosilane (I,R) 586. *Phorate, THIMET; O,O-Diethyl-S-[(Ethylthio)methyl] phosphorodithioate(X)

587. *Phosfolan, CYOLAN, 2-(Diethoxyphosphinylimino)-1, 3-dithio-lane (X)

588. *Phosgene, Carbonyl chloride (I,R)

589. *Phosphamidon, DIMECRON, 2-Chloro-2-diethylcarbamoyl -1-methylvinyldimethyl phosphate (X)

590. *Phosphine, Hydrogen phosphide (X,I)

591. Phosphoric acid (C) 592. Phosphoric anhydride, Phosphorus pentoxide (C,I)

593. Phosphorus (amorphous, red) (X,I,R)

594. *Phosphorus (white or yellow) (X,I,R)

595. *Phosphorus oxybromide, Phosphoryl bromide (X,C,R)

596. *Phosphorus oxychloride, Phosphoryl chloride (X,C,R)

597. *Phosphorus pentachloride, Phosphoric chloride (X,C,I,R)

598. *Phosphorus pentasulfide, Phosphoric sulfide (X,C,I,R)

599. *Phosphorus sesquisulfide, tetraphosphorus trisulfide (X,C,I,R)

600. *Phosphorus tribromide (X,C,R)

601. *Phosphorus trichloride (X,C,R) 602. Picramide, Trinitroaniline (I,R)

603. Picric acid, Trinitrophenol (I,R) 604. Picryl chloride, 2-Chloro-1,3,5-trinitrobenzene

Page 68

(I,R)

605. *Platinum compounds (X) 606. *Polychlorinated biphenyls, PCB, Askarel, aroclor, chlorextol, inerteen,pyranol (X)

607. Polyvinyl nitrate (I,R) 608. Potasan; O,O-Diethyl-o(4 methylumbelliferone) phosphoro-thioate (X)

609. *Potassium (C,I,R) 610. *Potassium arsenate (X)

611. *Potassium arsenite (X) 612. *Potassium bifluoride, Potassium acid fluoride (X,C)

613. Potassium binoxalate, Potassium acid oxalate (X)

614. Potassium bromate (X,I)

615. *Potassium cyanide (X) 616. Potassium dichloroisocyanurate (X,I)

617. Potassium dichromate, Potassium bichromate (X,C,I)

619. Potassium fluoride (X)

620. *Potassium hydride (C,I,R) 621. Potassium hydroxide, Caustic potash (X,C)

622. Potassium nitrate, Saltpeter (I,R) 623. Potassium nitrite (I,R)

624. Potassium oxalate (X) 625. Potassium perchlorate (X,I,R)

626. Potassium permanganate (X,C,I) 627. Potassium peroxide (C,I,R)

628. Potassium sulfide (X,I) 629. *Propargyl bromide, 3-Bromo-1-propyne (X,I)

630. *beta-Propiolactone, BPL (X) 631. Propionaldehyde, Propanal (X,I)

632. Propionic acid, Propanoic acid (X,C,I)

633. n-Propyl acetate (X,I)

634. n-Propyl alcohol, 1-Propanol (X,I) 635. n-Propylamine (and isomers) (X,I)

636. *Propyleneimine, 2-Methylaziridine (X,I)

637. Propylene oxide (X,I)

638. n-Propyl formate (X,I) 639. n-Propyl mercaptan, 1-Propanethiol (X,I)

640. *n-Propyltrichlorosilane (X,C,I,R) 641. *Prothoate, FOSTION, FAC; O,O-Diethyl-S-carboethoxy ethylphosphorodithioate (X)

642. Pyridine (X,I) 643. *Pyrosulfuryl chloride, Disulfuryl chloride (X,C,R)

644. *Quinone; 1,4-Benzoquinone (X) 645. Raney nickel (I)

646. *Schradan, Octamethyl pyrophosphoramide, OMPA (X)

647A. *Selenium (X)

647B. *Selenium compounds (X) 648. *Selenium fluoride (X)

649. *Selenous acid, Selenious acid and salts (X)

650. *Silicon tetrachloride, Silicon chloride (X,C,R)

651. *Silver acetylide (I,R) 652. Silver azide (I,R)

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653. Silver compounds (X) 654. Silver nitrate (X)

655. Silver styphnate, Silver trinitroresorcinate (I,R)

656. Silver tetrazene (I,R)

657. *Sodium (C,I,R) 658. Sodium aluminate (C)

659. *Sodium aluminum hydride (C,I,R) 660. *Sodium amide, Sodamide (C,I,R)

661. *Sodium arsenate (X) 662. *Sodium arsenite (X)

663. Sodium azide (I,R) 664. *Sodium bifluoride, sodium acid fluoride (X,C)

665. Sodium bromate (X,I) 666. *Sodium cacodylate, Sodium dimethylarsenate (X)

667. Sodium carbonate peroxide (I) 668. Sodium chlorate (X,I)

669. Sodium chlorite (X,I) 670. Sodium chromate (X,C)

671. *Sodium cyanide (X) 672. Sodium dichloroisocyanurate (I)

673. Sodium dichromate, Sodium bichromate (X,C,I)

674. Sodium fluoride (X)

675. *Sodium hydride (X,C,I,R)

676. Sodium hydrosulfite, Sodium hyposulfite (I)

677. Sodium hydroxide, Caustic soda, Lye (X,C)

678. *Sodium hypochlorite (X,I,R) 679. *Sodium methylate, Sodium methoxide (C,I,R)

680. Sodium molybdate (X) 681. Sodium nitrate, Soda niter (X,I,R)

682. Sodium nitrite (X,I,R) 683. Sodium oxide, Sodium monoxide (X,C)

684. Sodium perchlorate (X,I,R) 685. Sodium permanganate (X,I)

686. *Sodium peroxide (X,I,R) 687. Sodium picramate (X,I,R)

688. *Sodium potassium alloy, NaK, Nack (C,I,R)

689. *Sodium selenate (X)

690. Sodium sulfide, Sodium hydrosulfide (X,I)

691. Sodium thiocyanate, Sodium sulfocyanate (X)

692. Stannic chloride, Tin tetrachloride (X,C)

693. *Strontium arsenate (X)

694. Strontium nitrate (X,I,R) 695. Strontium peroxide, Strontium dioxide (I,R)

696. *Strychnine and salts (X) 697. Styrene, Vinylbenzene (X,I)

698. Succinic acid peroxide (X,I) 699. Sulfide salts (soluble) (X)

700. *Sulfotepp, DITHIONE, BLACAFUM, Tetraethyl dithiopyrophosphate, TEDP(X)

701. *Sulfur chloride, Sulfur monochloride (X,C,R)

702. *Sulfur mustard (X,C,R) 703. *Sulfur pentafluoride (X,C)

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704. Sulfur trioxide, Sulfuric anhydride (X,C,I)

705. Sulfuric acid, Oil of vitriol, Battery acid (X,C)

706. Sulfurous acid (X,C) 707. *Sulfuryl chloride, Sulfonyl chloride (X,C,R)

708. *Sulfuryl fluoride, Sulfonyl fluoride (X,C,R)

709. *SUPRACIDE, ULTRACIDE, S-[(5-Methoxy-2-oxo-1,3,4-thiadiazol3 (2H)-yl)methyl] -0, 0-dimethyl phosphorodithioate(X)

710. *SURECIDE, Cyanophenphos, O-para-Cyanophenyl-O- ethylphenylphosphonothioate (X)

711. *Tellurium hexafluoride (X,C)

712. *TELODRIN, Isobenzan; 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7 a-hexahydro-4,7-methanoisobenzofuran (X)

713. *TEMIK, Aldicarb, 2-Methyl-2(methylthio)propionaldehyde -O-(methylcarbamoyl) oxime (X)

714. *2,3,7,8-Tetrachlorodibenzo-para-dioxin, TCDD, Dioxin (X)

715. sym-Tetrachloroethane (X)

717. *Tetraethyl lead, TEL (and other organic lead) (X,I)

718. *Tetraethyl pyrophosphate, TEPP (X)

719A. Tetrahydrofuran, THF (X,I) 719B. Tetrahydrophthalic anhydride, Memtetrahydrophthalic anhydride (X)

720. TETRALIN, Tetrahydronaphthalene (X)

721. Tetramethyl lead, TML (X,I)

722. *Tetramethyl succinonitrile (X) 723. *Tetranitromethane (X,I,R)

724. *Tetrasul, ANIMERT V-101, S-para-Chlorophenyl-2,4,5-trichlorophenylsulfide (X)

725. Tetrazene, 4-Amidino-1-(nitrosamino-amidino)-1-tetra-zene (I,R)

726. *Thallium (X) 727. *Thallium compounds (X)

728. *Thallous sulfate, Thallium sulfate, RATOX (X)

729. *Thiocarbonylchloride, Thiopbosgene (X,C,R)

730. *Thionazin, ZINOPHOS; O,O-Tetramethylthiuram monosulfide (X)

731. *Thionyl chloride, Sulfur oxychloride (X,C,R)

732. *Thiophosphoryl chloride (X,C,R) 733. Thorium (powder) (I)

734. Tin compounds (organic) (X) 735. Titanium (powder) (I)

736. Titanium sulfate (X) 737. *Titanium tetrachloride, Titanic chloride (X,C,R)

738. Toluene, Methylbenzene (X,I) 739. *Toluene-2,4-diisocyanate, TDI (I,R)

740A. Toluidine, Aminotoluene (ortho,meta,para) (X)

740B. *Toxaphene, Polychlorocamphene (X)

741. *TRANID, exo-3-Chloro-endo-6-cyano-2-norbornanone -0-(methylcarbamoyl)oxime (X)

743. 1,1,2-Trichloroethane (X)

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744. Trichloroethylene; Trichlorethene (X) 745. Trichloroisocyanuric acid (X,I)

746. *2,4,5-Trichlorophenoxyacetic acid; 2,4,5-T (X)

747. *Trichlorosilane, Silicochloroform (X,C,I,R)

748. Trimethylamine, TMA (X,I) 749. Trinitroanisole; 2,4,6-Trinitrophenyl methyl ether (I,R)

750. 1,3,5-Trinitrobenzene, TNB (I,R) 751. 2,4,6-Trinitrobenzoic acid (I,R)

752. Trinitronaphthalene, Naphtite (I,R) 753. 2,4,6-Trinitroresorcinol, Styphnic acid (I,R)

754. 2,4,6-Trinitrotoluene, TNT (X,I,R) 755. *tris(1-Aziridinyl) phosphine oxide, Triethylenephospho-ramide, TEPA(X)

756. Tungstic acid and salts (X) 757. Turpentine (X,I)

758. Uranyl nitrate, Uranium nitrate (X,I,R)

759. Urea nitrate (X,I,R)

760. n-Valeraldehyde, n-Pentanal (and isomers) (X,I)

761. Vanadic acid salts (X)

762. Vanadium oxytrichloride (X,C) 763. *Vanadium pentoxide, Vanadic acid anhydride (X)

764. Vanadium tetrachloride (X,C) 765. Vanadium tetraoxide (X)

766. Vanadium trioxide, Vanadium sesquioxide (X)

767. Vanadyl sulfate, Vanadium sulfate (X)

768. Vinyl acetate (I,X) 769. *Vinyl chloride (X,I)

770. Vinyl ethyl ether (I) 771. Vinylidene chloride, VC (X,I)

772. Vinyl isopropyl ether (I) 773. *Vinyltrichlorosilane (X,C,I,R)

774. VX, O-Ethyl methyl phosphoryl N,N-diisopropyl thiocholine (X)

775. *WEPSYN 155, WP 155, Triamiphos,para-(5-Amino-3-phenyl-1H-1,2,4- triazol-1-yl)-N,N,N',N'-tetramethyl phosphonicdiamide (X)

776. Xylene, Dimethylbenzene (ortho,meta,para) (XII)

777. Zinc (powder) (I)

778. Zinc ammonium nitrate (X,I) 779. *Zinc arsenate (X)

780. *Zinc arsenite (X) 781. Zinc chloride (X,C)

782. Zinc compounds (X) 783. *Zinc cyanide (X)

784. Zinc nitrate (X,I,R) 785. Zinc permanganate (X,I)

786. Zinc peroxide, zinc dioxide (X,I,R) 787. *Zinc phosphide (X,I,R)

788. Zinc sulfate (X) 789. Zirconium (powder) (I)

790. *Zirconium chloride, Zirconium tetrachloride (X,C,R)

791. Zirconium picramate (I)

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(b) This subdivision sets forth a list of common names of wastes which are presumed to be hazardous wastes unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11.The hazardous characteristics which serve as a basis for listing the commonnames of wastes are indicated in the list as follows:()

(X) toxic (C) corrosive (I)

ignitable (R) reactive.

Acetylene sludge (C) Acid and water (C)

Acid sludge (C) AFU Floc (X)

Alkaline caustic liquids (C) Alkaline cleaner (C)

Alkaline corrosive battery fluid (C) Alkaline corrosive liquids (C)

Asbestos waste (X) Ashes (X,C)

Bag house wastes (X) Battery acid (C)

Beryllium waste (X) Bilge water (X)

Boiler cleaning waste (X,C) Bunker Oil (X,I)

Catalyst (X,I,C) Caustic sludge (C)

Caustic wastewater (C) Cleaning solvents (I)

corrosion inhibitor (X,C) Data processing fluid (I)

Drilling fluids (X,C) Drilling mud (X)

Dyes (X) Etching acid liquid or solvent (C,I)

Fly ash (X,C) Fuel waste (X,I)

Insecticides (X) Laboratory waste (X,C,R,I)

Lime and sulfur sludge (C) Lime and water (C)

Lime sludge (C) Lime wastewater (C)

Liquid cement (I) Mine tailings (X,R)

Obsolete explosives (R) Oil and water (X)

Oil Ash (X,C) Paint (or varnish) remover or stripper (I)

Paint thinner (X,I) Paint waste (or slops) (X,I)

Pickling liquor (C) Pigments (X)

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Plating waste (X,C) Printing Ink (X)

Retrograde explosives (R) Sludge acid (C)

Soda ash (C) Solvents (I)

Spent acid (C) Spent caustic (C)

Spent (or waste) cyanide solutions (X,C) Spent mixed acid (C)

Spent plating solution (X,C) Spent sulfuric acid (C)

Stripping solution (X,I) Sulfonation oil (I)

Tank bottom sediment (X) Tanning sludges (X)

Toxic chemical toilet wastes (X) Unrinsed pesticide containers (X)

Unwanted or waste pesticides - an unusable portion of active ingredient or undiluted formulation (X)

Waste epoxides (X,I)

Waste (or slop) oil (X) Weed Killer (X)

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Appendix F

Common Flammable Liquids

Material Flash Point Boiling Point

Acetone 0 ˚F 134 ˚F

Amyl Acetate 77 ˚F 300 ˚F

Benzene 12 ˚F 176 ˚F

Butyl Alcohol 84 ˚F 243 ˚F

Denatured Alcohol 60 ˚F 175 ˚F

Ethyl Acetate 24 ˚F 171 ˚F

Ethyl Alcohol 55 ˚F 173 ˚F

Ethylamine <0 ˚F 62 ˚F

Ethyl Ether -49 ˚F 95 ˚F

Fuel Oil No. 1 100 ˚F 304 – 574 ˚F

Gasoline -45 ˚F 100 – 400 ˚F

Hexane -7 ˚F 156 ˚F

Isopropyl Alcohol 53 ˚F 181 ˚F

Jet Fuels -10 - -30 ˚F

Kerosene 100 ˚F 304 – 574 ˚F

Methyl Alcohol 52 ˚F 147 ˚F

Methyl Ethyl Ether -35 ˚F 51 ˚F

Methyl Ethyl Kerosene 21 ˚F 176 ˚F

Napatha V. Mop 28 ˚F 212 – 320 ˚F

Pentane <-40 ˚F 97 ˚F

Petroleum Ether <0 ˚F 95 – 140 ˚F

Propanol 15 – 19 ˚F 120 ˚F

Toluol 10 ˚F 321 ˚F

Turpentine 95 ˚F 300 ˚F

Xylene 90 ˚F 292 ˚F

This listing is not all inclusive and is subject to change at any time.

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Appendix G

Toxicity Characteristics and Tables I (using TCLP), II and III (using STLC or TTLC)(Reference: Section 66261.24 Title 22 CCR)

Table I - Maximum Concentration of Contaminants for the Toxicity Characteristic:

A waste exhibits the characteristic of toxicity if representative samples of the waste have any of the following properties:

When using the Toxicity Characteristic Leaching Procedure (TCLP), test Method 1311 in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods," EPA Publication SW-846, third edition and Updates (incorporated by reference in section 66260.11 of this division), the extracts from representative samples of the waste contain any of the contaminants listed in Table I of this section at a concentration equal to or greater than the respective value given in that table unless the waste is excluded from classification as a solid waste or hazardous waste or is exempted from regulation pursuant to 40 CFR section 261.4. Where the waste contains less than 0.5 percent filterable solids, the waste itself, after filtering using the methodology outlined in Method 1311, is considered to be the extract for the purposes of this section;

Table IContaminant Regulator

y Level Mg/l

Arsenic 5.0Barium 100.0Benzene 0.5Cadmium 1.0Carbon Tetrachloride

0.5

Chlordane 0.03Chlorobenzene 100.0Chloroform 6.0Chromium 5.0o-Cresol 200.0 1m-Cresol 200.0 1p-Cresol 200.0 1Cresol 200.0 12,4-D 10.01,4-Dichlorobenzene 7.51,2-Dichloroethane 0.51,1-Dichloroethylene 0.72,4-Dinitrotoluene 0.13Endrin 0.02Heptachlor (and its epoxide)

0.008

Hexachlorobenzene 0.13Hexachlorobutadiene

0.5

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Hexachloroethane 3.0Lead 5.0Lindane 0.4Mercury 0.2Methoxychlor 10.0Methyl ethyl ketone 200.0Nitrobenzene 2.0Pentachlorophenol 100.0Pyridine 5.0 2Selenium 1.0Silver 5.0Tetrachloroethylene 0.7Toxaphene 0.5Trichloroethylene 0.52,4,5-Trichlorophenol

400.0

2,4,6-Trichlorophenol

2.0

2,4,5-TP (Silvex) 1.0Vinyl Chloride 0.2Notes:1. If o-, m-, and p-Cresol concentrations cannot be differentiated, the total cresol (DO26) concentration is used. The regulatory level of total cresol is 200 mg/l.2. Quantitation limit is greater than the calculated regulatory level. The quantitation limit therefore becomes the regulatory level.

Table II and III - List of Inorganic Persistent and Bioaccumulative Toxic Substances and Their Soluble Threshold Limit Concentration:

It contains a substance listed in Table II or Table III at a concentration in milligrams per liter of waste extract, as determined using the Waste Extraction Test (WET) which equals or exceeds its listed soluble threshold limit concentration or at a concentration in milligrams per kilogram in the waste which equals or exceeds its listed TTLC (Total Threshold Limit Concentration);

Table IISubstancea,b STLC

mg/lTTLC Wet-Weight mg/l

Antimony and/or antimony compounds 15 500Arsenic and/or arsenic compounds 5.0 500Asbestos 1.0 (as percent)Barium and/or barium compounds (excluding barium sulfate)

100 10,000 c

Beryllium and/or beryllium compounds 0.75 75Cadmium and/or cadmium compounds 1.0 100Chromium (VI) compounds 5 500Chromium and/or chromium (III) compounds 5 d 2,500Cobalt and/or cobalt compounds 80 8,000Copper and/or copper compounds 25 2,500Fluoride salts 180 18,000Lead and/or lead compounds 5.0 1,000Mercury and/or mercury compounds 0.2 20Molybdenum and/or molybdenum compounds 350 3,500 e

Nickel and/or nickel compounds 20 2,000

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Selenium and/or selenium compounds 1.0 100Silver and/or silver compounds 5 500Thallium and/or thallium compounds 7 700Vanadium and/or vanadium compounds 24 2,400Zinc and/or zinc compounds 250 5,000

Notes:a. STLC and TTLC values are calculated on the concentrations of the elements, not the compounds.b. In the case of asbestos and elemental metals, the specified concentration limits apply only if substances are in a friable, powdered or finely divided state. Asbestos includes chrysotile, amosite, crocidolite, tremolite, anthophyllite, and actinolite.c. Excluding barium sulfate.d. If the soluble chromium, as determined by the TCLP set forth in Appendix I of Chapter 18 of this Division, is less than 5 mg/l, and the soluble chromium, as determined by the procedures set forth in Appendix II of Chapter 11, equals or exceeds 560 mg/l and the waste is not otherwise identified as a RCRA hazardous waste pursuant to section 66261.100, then the waste is a non-RCRA hazardous waste.e. Excluding molybdenum disulfide.

Table IIISubstancea,b STLC

mg/lTTLC Wet-Weight mg/l

Aldrin 0.14 1.4Chlordane 0.25 2.5DDT, DDE, DDD 0.1 1.02,4-Dichlorophenoxyacetic acid 10 100Dieldrin 0.8 8.0Dioxin (2,3,7,8-TCDD) 0.001 0.01Endrin 0.02 0.2Heptachlor 0.47 4.7Kepone 2.1 21Lead compounds, organic - 13Lindane 0.4 4.0Methoxychlor 10 100Mirex 2.1 21Pentachlorophenol 1.7 17Polychlorinated biphenyls (PCBs) 5.0 50Toxaphene 0.5 5Trichloroethylene 204 2,0402,4,5-Trichlorophenoxypropionic acid 1.0 10

Other Toxicity Characteristics

A substance is hazardous if it:

Has an acute oral LD 50 less than 2,500 milligrams per kilogram; Has an acute dermal LD 50 less than 4,300 milligrams per kilogram; Has an acute inhalation LC 50 less than 10,000 parts per million as a gas or vapor; Has an acute aquatic 96-hour LC 50 less than 500 milligrams per liter when measured in

soft water (total hardness 40 to 48 milligrams per liter of calcium carbonate) with fathead

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minnows (Pimephales promelas), rainbow trout (Salmo gairdneri) or golden shiners (Notemigonus crysoleucas) according to procedures described in Part 800 of the "Standard Methods for the Examination of Water and Wastewater (16th Edition)," American Public Health Association, 1985 and "Static Acute Bioassay Procedures for Hazardous Waste Samples," California Department of Fish and Game, Water Pollution Control Laboratory, revised November 1988 (incorporated by reference, see section 66260.11), or by other test methods or test fish approved by the Department, using test samples prepared or meeting the conditions for testing as prescribed in subdivisions (c) and (d) of Appendix II of this chapter, and solubilized, suspended, dispersed or emulsified by the cited procedures or by other methods approved by the Department;

Contains any of the following carcinogenic substances at a single or combined concentration equal to or exceeding 0.001 percent by weight

o 2-Acetylaminofluorene (2-AAF);o Acrylonitrile;o 4-Aminodiphenyl;o Benzidine and its salts;o bis (Chloromethyl) ether (BCME);o Methyl chloromethyl ether;o 1,2-Dibromo-3-chloropropane (DBCP);o 3,3'-Dichlorobenzidine and its salts (DCB);o 4-Dimethylaminoazobenzene (DAB);o Ethyleneimine (EL);o alpha-Naphthylamine (1-NA);o beta-Naphthylamine (2-NA);o 4-Nitrobiphenyl (4-NBP);o N-Nitrosodimethylamine (DMN);o beta-Propiolactone (BPL); oro Vinyl chloride (VCM).

Has been shown through experience or testing to pose a hazard to human health or environment because of its carcinogenicity, acute toxicity, chronic toxicity, bioaccumulative properties or persistence in the environment.

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Appendix H

Universal Hazardous Waste(03/18/2009)

Introduction

New laws adopted since 2000 created California’s “Universal Waste Rule” to try and simplify how we manage many common hazardous wastes. Mercury containing devices (e.g. Mercury containing thermostats, lamps, switches, thermometers, gauges, medical devices, rubber flooring, flashing athletic shoes/jewelry/other devices, novelties, etc), dental amalgam, batteries, sodium vapor lamps, non-empty aerosol cans, consumer electronic devices, cathode ray tubes that are no longer useful, broken, or discarded are some examples of universal wastes. A more detailed list of universal wastes can be found in the following section. It should be noted that as of February 9, 2006, none of these universal wastes can be legally disposed of in the trash.

Definition of Universal Wastes

Universal wastes are hazardous wastes that are more common and pose a lower risk to people and the environment than other hazardous wastes. Federal and State regulations identify universal wastes and provide somewhat simpler rules for handling, recycling, and disposing of them. The regulations, called the “Universal Waste Rule,” can be found in the California Code of Regulations, Title 22, division 4.5, chapter 23. All citations in this fact sheet refer to these regulations, unless otherwise noted. All universal wastes are hazardous wastes and, without the new rules, they would have to be managed under the same stringent standards as other hazardous wastes. Also, universal wastes are generated by a wide variety of people rather than by the industrial businesses that primarily generate other hazardous wastes. Not all waste products of a particular type are universal wastes. For example, waste thermometers that contain mercury are universal wastes but waste thermometers that contain alcohol are not.

The following items are universal wastes when they are no longer useful, broken or are discarded (Note: Working equipment listed below that has value and can be sold as surplus property is not a universal waste unless it is discarded):

Mercury thermostats. These thermostats contain small glass capsules of mercury, a shiny liquid metal, to make electrical contact. Modern electronic thermostats do not contain mercury.

Batteries. Universal waste batteries include rechargeable nickel-cadmium batteries, silver button batteries, mercury batteries, small sealed lead acid batteries (burglar alarm and emergency light batteries), most alkaline batteries, carbonzinc batteries, and any other batteries that exhibit a characteristic of a hazardous waste (§§66261.20 through 66261.24). NOTE: Spent automotive-type lead acid storage batteries are not universal waste.

Lamps. Universal waste lamps include fluorescent tubes, high intensity discharge lamps, sodium vapor lamps, and any other lamps that exhibit a characteristic of a hazardous waste.

Non-empty aerosol cans. The Legislature added non-empty aerosol cans to the list of universal wastes in 2001. Empty aerosol cans are not universal waste or hazardous waste.

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Mercury switches. Two different types of mercury switches are universal wastes:

Motor vehicle light switches that contain mercury. Health and Safety Code section 25214.6 designates motor vehicle light switches (automatic hood and trunk light switches) containing mercury as universal wastes once they are removed from vehicles. Vehicles that contain the switches are to be considered hazardous waste until the mercury light switches are removed.

Non-automotive mercury switches and products that contain them, when they are recycled as scrap metal. These switches include thermostats and tip switches in portable heaters, washing machine out-of-balance switches, silent wall switches, and other mercury-containing switches and products containing them. All discarded products that contain mercury switches are universal wastes.

Mercury thermometers, including fever thermometers.

Pressure or vacuum gauges that contain mercury. This includes U tube manometers, barometers, sphygmomanometers (blood pressure meters) and similar devices.

Dilators and weighted tubing containing mercury. These medical devices contain mercury.

Rubber flooring that contains mercury. Older gymnasium floors that were poured in place to form indoor tracks and gymnastic areas frequently contain mercury.

Novelties that contain mercury or mercury batteries. This includes singing greeting cards, flashing athletic shoes, jewelry, and other devices. All novelties with added mercury are considered hazardous and are universal wastes.

Mercury gas flow regulators. These older gas flow regulators are managed exclusively by natural gas utilities.

Counterweights and dampers containing mercury, including devices that use pouches of mercury to dampen shaking on hunting bows and snow skis or to absorb recoil on shotguns.

Dental amalgam tooth filling materials including waste amalgam, bits and pieces from chair side traps, and spent wastewater filters.

Consumer electronic devices. Electronics that exhibit hazardous characteristics including, but not limited to CRT devices (e.g., computer monitors, televisions, cash registers and oscilloscopes), computers, computer peripherals, telephones, answering machines, radios, stereo equipment, tape players/recorders, phonographs, video cassette players/recorders, CD or DVD disc players/recorders, calculators, and some appliances. This does not include major appliances (e.g. dishwashers, washers, dryers, refrigerators, etc).

Cathode ray tubes. Waste cathode ray tubes (CRTs), such as television picture tubes and non-flat panel computer monitors, are universal wastes and included in consumer electronic devices.

Gauges that contain mercury. Vacuum and pressure gauges that contain mercury, including blood pressure gauges, barometers, and manometers.

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Management of Universal Hazardous Wastes

To properly dispose of Universal Hazardous Waste and other Hazardous Wastes:

1. Prepare a properly labeled container, which is compatible and non-leaking for the collection of the waste by:

Complete a Hazardous Waste Tracking Form (EH&S F-366-07), available from Environmental Health & Safety (Extension 4697), for each container. Make sure the following critical information is completed on the form: Hazardous Material Name, Quantity, California Waste Code, Waste Classification, Safety Handling Precautions and Initial Accumulation Date. The "Universal Waste Table" below contains the Hazardous Material Name, California Waste Code, Waste Classification and Safety Handling Precautions for the Common Names of Universal Hazardous Waste.

Temporarily tape the completed form on the container before adding waste. Instead of taping the entire form to the container, you can remove the last page of the Hazardous Waste Tracking Form, which is the label for the container and tape the label to the container before adding any waste.

2. Place the Hazardous Waste into the labeled container.

3. Liquid mercury or mercury containing paint shall be placed in an airtight container.

4. Universal Waste thermostats, switches, thermometers, gauges, counter weights, dampers, dilators and weight tubing shall be placed in sealed plastic bags and then placed into airtight containers.

5. Intact Cathode Ray Tube Monitors can be stacked in 3 to 4 layers on a pallet and shrink wrapped. Monitors should not be stacked face down.

6. Incompatible Wastes shall be kept segregated and managed appropriately in separate containers.

7. Make sure the lid is closed on the container when you are not adding waste.

8. Handle all waste in a manner that minimizes breakage, prevents fire, explosion, and the unauthorized release of any Universal Waste or component of a Universal Waste to the environment.

9. Immediately clean up and place in a labeled container, as specified above, any waste that is broken or spilled.

10. When the container is either full or 90 days after the initial accumulation date, call the Environmental Health & Safety Department at Extension 4697 and make arrangements to have the waste picked up or transported to the Hazardous Materials Facility within 3 days.

Universal Hazardous Waste with a University Property Number

If the Universal Hazardous Waste in question is a device of piece or equipment which has a University Property Number, the Universal Hazardous Waste should be removed and handled according to the procedures described in this document. The remaining device or equipment shall be handled according to the University’s Property Survey Procedures, established by the University Property Office at Extension 3394.

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If the Universal Hazardous Waste cannot be removed or is an integral part of the device or equipment (e.g. Electronic Device such as a Computer, Computer Monitor, Television), it should be handled according to the Universal Hazardous Waste Procedures described in this document; however, the properly labeled device or equipment should be submitted to the Property Office, according to University Property Survey Procedures. The Property Office will coordinate with the Environmental Health & Safety Department regarding the final management of the waste device or equipment.

Universal Waste Table

Universal Waste

Hazardous Material Name for Labeling

California Waste Code

Waste Classification

Safety/Handling

Batteries Universal Waste-Batteries

792 Corrosive Material Class 8

Avoid Eye & Skin Contact

Avoid Heat & Open Flames

Wear Gloves and Apron

Thermostats Universal Waste- Thermostats




Avoid Prolonged Breathing of Vapors

Lamps Containing Mercury

Universal Waste -Lamps

M003 Corrosive Material Class 8




Eye Protection Required

Sodium Vapor Lamps

Universal Waste -Lamps

M003 Flammable Solid 4.3





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Universal Waste




Safety/Handling

Cathode Ray Tube (CRT) Devices

Includes Televisions and CRT Computer Monitors.

Universal Waste-CRT Devices

181 Poison 6.1 Avoid Eye & Skin Contact




Cathode Ray Tube (CRT) Glass and/or Broken CRTs

Universal Waste-CRT Glass

Broken Leaded Glass from Televisions or Computers

Do not mix with other glass materials





Consumer Electronic Devices

Universal Waste- Electronic Devices

181 Poison 6.1 Eye Protection Required

Non-empty Aerosol Cans

Universal Waste-Aerosol Cans

343 Poison 6.1 and/or Flammable Liquid Class 3


Avoid Heat & Open Flames

Mercury Switches

Universal Waste-Mercury Switches

M001 (For Motor Vehicle Switches)M002 (For Others)

Corrosive Material Class 8




Mercury Thermo-meters

Universal Waste- Mercury Switches/Thermometers





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Universal Waste




Safety/Handling

Dental amalgam

Universal Waste- Dental amalgam






Pressure or Vacuum Gauges

Universal Waste-Mercury Gauges





Mercury Drained from Pressure or Vacuum Gauges

Universal Waste- Drained Mercury






Novelties Universal Waste-Novelties

M004 Corrosive Material Class 8

Counterweights and Dampers

Universal Waste- Counterweights and Dampers






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Universal Waste




Safety/Handling

Dilators and Weighted Tubing

Universal Waste-DilatorsOrUniversal- Weighted Tubing






Rubber Flooring Containing Mercury

Universal Waste- Waste Mercury- Containing Flooring






Gas Flow Regulators.

Universal Waste-Gas Flow Regulator





Remember to comply with the following when handling Universal Hazardous Waste or any Hazardous Waste.

Do not dispose of waste in the trash.

Do not dilute or treat any waste.

All Universal Wastes will be containerized to prevent leakage, spillage and/or damage.

Use containers that are structurally sound, compatible with the waste, prevent leakage, prevent spillage and/or prevent damage.

All containers shall be placed in a location that has sufficient ventilation to avoid formation of an explosive atmosphere, and designed, built, and maintained to withstand pressures reasonably expected during storage and transportation.

Flammable wastes shall be kept at a safe distance from heat and open flames preferably in flammable storage cabinets.

You may remove Universal Waste containing parts from a device. For example, you can remove mercury ampules from thermostats or electrolyte from batteries. However, you cannot treat and/or change the characteristic of the waste.

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Spill Response

Mercury clean up kits or equipment must be available for cleaning up any spills or releases from universal wastes containing liquid mercury (Specifically, thermostats, switches, thermometers, gauges, counter weights, dampers, dilators, weight tubing).

Immediately contain all releases of universal wastes and other residues from universal wastes.

Waste consisting only of residues of leaking, broken, or otherwise damaged universal waste may be managed as universal waste provided that the leaking, broken, or otherwise damaged universal waste is repackaged in labeled containers that are structurally sound, compatible with the waste, prevent leakage, prevent spillage and/or prevent damage (see Section on Collection, Packaging & Short Term Storage above). Liquid mercury or mercury containing paint must be place in an airtight container. Universal waste thermostats, switches, thermometers, gauges, counter weights, dampers, dilators, weight tubing will be placed in sealed plastic bags and then placed into airtight containers.

Employees handling universal wastes will utilize Personnel Protective Equipment as specified in the following table.

Personal Protective Equipment

Conditions Requiring Use

Closed toed shoes During all activities at all times when handling universal wastes.

Long pants During all activities at all times when handling universal wastes.

Cotton or leather work gloves

When handling Cathode Ray Tube Devices (Includes Televisions and CRT Computer Monitors), Consumer Electronic Devices and Lamps.

Chemical Protective Gloves When handling spilled or otherwise non-contained mercury or mercury containing waste.

Safety Glasses During all activities at all times when handling universal wastes.

Respirator When handling spilled or otherwise non-contained mercury in amounts greater than 10 ml.

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Dust Mask Voluntary (The occasional clean up of a broken Cathode Ray Tube Device (Includes Televisions and CRT Computer Monitors), Consumer Electronic Device or Lamp is not expected to expose individuals to unhealthful levels of dust or debris. However, these activities can under some conditions cause discomfort to employees. In recognition of this fact, departments will purchase NIOSH approved N100 dust masks, with exhalation ports and double straps. These masks will be made available to all employees on a voluntary basis. If you choose to utilize dust masks, please read the information regarding respiratory protection titled “Guide to Respiratory Protection at Work” in this document.)

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Guide to Respiratory Protection at Work(Reference: Appendix D to Section 5144 Title 8 California Code of Regulations: (Mandatory) Information for Employees Using Respirators When Not Required Under the Standard)

Respirators are an effective method of protection against designated hazards when properly selected and worn. Respirator use is encouraged even when exposures are below the exposure limit, to provide an additional level of comfort and protection for workers. However, if a respirator is used improperly or not kept clean, the respirator itself can become a hazard to the worker. Sometimes, workers may wear respirators to avoid exposures to hazards, even if the amount of hazardous substance does not exceed the limits set by OSHA standards. If your employer provides respirators for your voluntary use, or if you provide your own respirator, you need to take certain precautions to be sure that the respirator itself does not present a hazard.

You should do the following:

1. Read and heed all instructions provided by the manufacturer on use, maintenance, cleaning and care, and warnings regarding the respirators limitations.

2. Choose respirators certified for use to protect against the contaminant of concern. NIOSH, the National Institute for Occupational Safety and Health of the U.S. Department of Health and Human Services, certifies respirators. A label or statement of certification should appear on the respirator or respirator packaging. It will tell you what the respirator is designed for and how much it will protect you.

3. Do not wear your respirator into atmospheres containing contaminants for which your respirator is not designated to protect against. For example, a respirator designed to filter dust particles will not protect you against gases, vapors or very small solid particles of fumes or smoke.

4. Keep track of your respirator so that you do not mistakenly use someone else's respirator.

This personal protective equipment, except closed toed shoes and long pants, will be purchased by each department and made available to all employees at no cost. All employees are required to utilize this personal protective equipment in compliance with the above table. Supervisors are responsible for coordinating training on this protective equipment. Training videos and web based training on various safety issues are available from Environmental Health & Safety (Extension 4697).

Training

All employees who handle or have responsibility for managing Universal Waste, should be trained initially and annually thereafter on the information in this document.

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Processing of Aerosol Cans (EH&S Only)

Universal waste aerosol cans can be processed to remove and collect the contents provided the following conditions are met: Aerosol cans are processed in a manner and in equipment designed, maintained, and

operated so as to prevent fire, explosion, and the unauthorized release of any universal waste or component of a universal waste to the environment.

The unit used to process the universal waste aerosol cans is placed on or above a non-earthen floor that is free of cracks or gaps and is sufficiently impervious and bermed to contain leaks and spills.

The Unit is located in a well ventilated area. Operations are performed safely by developing and implementing a written operating

procedure detailing the safe processing of aerosol cans. This procedure shall, at a minimum, include all of the following:o The type of equipment to be used to process the aerosol cans safely.o Operation and maintenance of the unit.o Segregation of incompatible wastes.o Proper waste management practices, including ensuring that flammable wastes are

stored away from heat and open flames.o Waste characterization.

A spill cleanup kit is readily available to immediately clean up spills or leaks of the contents of the aerosol cans.

The contents of the waste aerosol can are characterized (to determine if the contents are a hazardous waste), immediately transferred to an appropriate container and managed in compliance with all applicable federal, state, and local requirements.

All individuals processing aerosol cans are trained on the written operating procedures and are thoroughly familiar with the procedure for sorting, processing aerosol cans, proper waste handling and emergency procedures.

Notify the CUPA, if the facility is under the jurisdiction of a CUPA, or other responsible agency prior to the first time aerosol cans are processed. Notification shall be completed, dated, and signed according to the requirements of Section 66270.11 of Title 22 of the California Code of Regulations, and shall include, but not be limited to, all of the following information:o Name, identification number, site address, mailing address, and telephone number of

the person responsible for processing aerosol canso A description of the aerosol can processing activities, including the type and estimated

volumes or quantities of universal waste aerosol cans to be processed monthly, the treatment process or processes, equipment descriptions, and design capacities.

o A description of the characteristics and management of any hazardous treatment residuals.

Notify the CUPA or agency of any change in operation which necessitates modifying any of the required information submitted in the original notification within 30 days. Each amended notification shall be completed, dated, and signed in accordance with the requirements of Section 66270.11 of Title 22 of the California Code of Regulations, as those requirements apply to hazardous waste facilities permit applications.

Shipping Off-Campus (EH&S Only)

Prepare proper shipping papers such as a bill of lading. A Uniform Hazardous Waste Manifest is not necessary for universal waste shipments (§66273.18).

You may transport universal waste in your own vehicle or may use any common carrier allowed by U.S. DOT and California law to transport non-hazardous waste. You are not required to use a registered hazardous waste hauler to transport universal waste (§66273.18).

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Ship the universal waste to another small quantity handler of universal waste, a large quantity handler of universal waste, or a destination facility. When shipping or receiving universal waste, specific rules apply regarding accepting shipments containing hazardous wastes that are not universal wastes and shipments that are rejected (§66273.18).

Keep records of all shipments and receipts of universal waste for three years (§66273.19). When sending universal waste outside the country, comply with regulations addressing

universal waste export (§66273.20).If you have any questions, feel free to call the Environmental Health & Safety Department at 4697.

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Appendix I

Management of Treated Wood Waste(01/12/2007)

Introduction

The Department of Toxic Substances control has established Emergency Regulation effective January 1, 2007 and is proposing new permanent regulations that will regulate Treated Wood Waste as hazardous waste in California, provided the waste is not a RCRA (Resource Conservation and Recovery Act) listed hazardous waste.

These regulations establish “alternative hazardous waste management standards” for Treated Wood Waste. Individuals handling or disposing of Treated Wood Waste in compliance with these regulations are exempt from compliance with some of the usual hazardous waste management requirements. It should be noted that treated wood waste cannot be legally disposed of in the trash.

Definition of Treated Wood Waste

Treated Wood Waste is waste wood that has been treated with a wood preservative that is registered in accordance with the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA).

Management & Handling

General

Treated Wood Waste shall be disposed of as hazardous waste and not discarded in the regular trash or to the land.

Scavenging of Treated Wood Waste shall be prevented. Treated Wood Waste shall not be burned, recycled, reclaimed, or reused, except as indicated in this

document. Treated Wood can only be reused if all the following conditions are met:

Reuse is on campus The wood is reused in compliance with the FIFRA approval for the wood preservative. Prior to reuse the wood is handled in compliance with all the requirements in this document

Treated Wood Waste shall not be stored for more than 90 days on campus. Do not mix, dilute and/or commingled with any other waste prior to disposal. Treated Wood Waste shall not be treated on campus. Treatment can only be done by properly

permitted facilities.

Labeling

Utilize a Hazardous Waste Tracking Form, available form Environmental Health & Safety (EH&S) at Extension 4697, to label all Treated Wood Waste. Use the information in the following table to complete the tracking form. Be sure to use the wording indicated in the table for the hazardous material name.




Safety/Handling

TREATED WOOD WASTE-Do Not Burn or Scavenge


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The Initial Accumulation Date must be indicated on the Hazardous Waste Tracking Form, which is used to label the waste.

All Treated Wood Waste shall be appropriately labeled. Any manufacturer or other identifying labeling shall not be removed.

Collection, Packaging & Short Term Storage

Treated Wood Waste shall be packaged and stored so that it is protected from run-on and run-off water and stored on an impervious surface to prevent contact with or leaching into the soil or water. This can be accomplished by the following methods: Block and Tarp

Treated Wood Waste shall be covered with plastic or other water impenetrable material to protect from precipitation

Treated Wood Waste shall be elevated to prevent contact with the soil and to protect from reasonably foreseeable run-on; and

Stored on an impervious surface. Containerized

Container must be designed, constructed, maintained, filled, its contents so limited, and closed, so that under conditions normally incidental to handling, there will be no identifiable release of the waste or its constituents to the environment; and

Containers must be water-resistant. Storage Building: A structurally sound building with a water-resistant floor designed to prevent

the movement of water into or out of the building Containment Pad

The waste does not contact the soil. The waste is protected from reasonably foreseeable run-on; and The waste is covered with plastic or other water impenetrable material to protect from

precipitation Treated Wood Waste may be accumulated uncovered if the containment surface is designed

and operated to contain all precipitation and the resulting water is managed in accordance with all applicable laws and regulations

Any saw dust generated from using treated wood is consider Treated Wood Waste and shall be clean up, place in a labeled/sealed container and managed as indicated in this document. The container must be designed, constructed, maintained, filled, its contents so limited, and closed, so that under conditions normally incidental to handling, there will be no identifiable release of the waste or its constituents to the environment. A plastic bucket with a water tight lid is recommended to meet these requirements.

Incompatible wastes shall be kept segregated and managed appropriately in separate containers. All wastes will be containerized to prevent leakage, spillage and/or damage. Use containers that are structurally sound, compatible with the waste, prevent leakage, prevent

spillage and/or prevent damage. All containers shall be closed unless material is being added. Do not store waste for more than three days once the container is full. When the container is full

contact Environmental Health & Safety to coordinate prompt removal.

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Spill Response

In the event that treated wood or waste is spilled the following clean up procedures will be followed immediately:

Isolate the area and keep people from walking through the spill. Contact your supervisor. Utilize the Personnel Protective Equipment as specified in the table below. Sweep up all the debris and place in a sealed container. Use only labeled containers that are structurally sound, compatible with the waste, prevent leakage,

prevent spillage and/or prevent damage (see Sections on Labeling and Collection, Packaging & Short Term Storage above).

Store the container in a secure location. Re-open spill area. Contact Environmental Health & Safety to coordinate prompt removal of the container within 3 days. Employee Safety

Employees handling wastes will utilize Personnel Protective Equipment as specified in the following table.



Closed toed shoes During all activities at all times when handling treated wood or waste.

Long pants During all activities at all times when handling treated wood or waste.

Cotton or leather work gloves

During all activities at all times when handling treated wood or waste.

Safety Glasses During all activities were saw dust may be generated or handled.

Dust Mask Voluntary. The occasional clean up or use of treated wood or waste, including saw dust is not expected to expose individuals to unhealthful levels of dust or debris. However, these activities can under some conditions cause discomfort to employees. In recognition of this fact, departments will purchase NIOSH approved N100 dust masks, with exhalation ports and double straps. These masks will be made available to all employees on a voluntary basis. If employees choose to utilize dust masks, They are to read the information regarding respiratory protection titled “Guide to Respiratory Protection at Work” in this table.)

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Guide to Respiratory Protection at Work(Reference: Appendix D to Section 5144 Title 8 California Code of Regulations: (Mandatory) Information for Employees Using Respirators When Not Required Under the Standard)

Respirators are an effective method of protection against designated hazards when properly selected and worn. Respirator use is encouraged even when exposures are below the exposure limit, to provide an additional level of comfort and protection for workers. However, if a respirator is used improperly or not kept clean, the respirator itself can become a hazard to the worker. Sometimes, workers may wear respirators to avoid exposures to hazards, even if the amount of hazardous substance does not exceed the limits set by OSHA standards. If your employer provides respirators for your voluntary use, or if you provide your own respirator, you need to take certain precautions to be sure that the respirator itself does not present a hazard.

You should do the following:

1. Read and heed all instructions provided by the manufacturer on use, maintenance, cleaning and care, and warnings regarding the respirators limitations.

2. Choose respirators certified for use to protect against the contaminant of concern. NIOSH, the National Institute for Occupational Safety and Health of the U.S. Department of Health and Human Services, certifies respirators. A label or statement of certification should appear on the respirator or respirator packaging. It will tell you what the respirator is designed for and how much it will protect you.

3. Do not wear your respirator into atmospheres containing contaminants for which your respirator is not designated to protect against. For example, a respirator designed to filter dust particles will not protect you against gases, vapors or very small solid particles of fumes or smoke.

4. Keep track of your respirator so that you do not mistakenly use someone else's respirator.

This personal protective equipment, except closed toed shoes and long pants, will be purchased by each department and made available to all employees at no cost. All employees are required to utilize this personal protective equipment in compliance with the above table. Supervisors are responsible for coordinating training on this protective equipment. Training videos and web based training on various safety issues are available from Environmental Health & Safety (Extension 4697).

Training

Training all employees who handle or have responsibility for managing treated wood or waste, initially and annually thereafter on the information in this document.

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Shipping Off-Campus and Tracking (EH&S Only)

Treated Wood Waste shall be shipped and/or transported in a manner that prevents unauthorized access; protects the waste from precipitation; and prevents loss, dispersion, and leaching of waste constituents.

Treated Wood Waste will be shipped to a Treated Wood Waste facility or a Treated Wood Waste approved landfill. An exception is provided to allow a generator to ship from a remote site to a consolidation site provided the following conditions are met: The waste is transported by the generator, employees of the generator or by the generator’s

agent. A shipping document containing all of the following information accompanies the waste while in

transport: Quantity of waste Location of the remote site where the waste was initially collected. Date that the generator first began to accumulate the waste at the remote site Date that the shipment left the remote site Date that the shipment arrives at the consolidation site. Name, address, and telephone number of the generator, and, if different, the address and

telephone number of the consolidation site to which the waste is being transported. Name of the individual or individuals who transported the waste from the remote site to the

consolidation site. Retain copies of the shipping document for at least three years from the date the waste leaves

the consolidation site. Keep records of all off-site shipments to Treated Waste Wood facilities or landfills. These records

may take the form of a log, invoice, manifest, bill of lading, shipping document, or receipt from a Treated Waste Wood facility or landfill. The record for each shipment of waste shall include the following information: Name and address of the facility or landfill to which the waste was sent; Weight or estimated weight of the waste. Assumptions required for weight estimates shall be

recorded in the shipment records. Date the shipment of waste left. Retain copies of the shipping documents for at least three years from the date the waste leaves

the site.

Notifications (EH&S Only)

In any calendar year that the University generates more than 10,000 pounds of Treated Wood Waste the handler shall send written notification to the Department of Toxic Substances Control within 30 days of exceeding the 10,000 pound limit. The notification shall include the following: University's name and mailing address; EPA Generator’s Identification Number; Name and business telephone number of the person at the University who should be contacted

regarding waste management activities; address or physical location of the waste management activities; Date the 10,000 pound limit was exceeded; and A statement indicating that the University is generating more than 10,000 pounds of Treated

Wood Waste per calendar year.

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Appendix J

Hazardous Waste Tank System Daily Inspection Log

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Hazardous Waste Tank System Daily Inspection Log(Revised 03/14/2013)

Date (Month.Year): KeyName: Y-Yes

N-NoNA-Not Applicable

Department:Extension:

Day Is overspill/

spill control

equipment functional

?

Is secondary

containment free

of waste and liquid?

Is the system free of

corrosionand

evident damage?

Are pipes, valves and

pumpsfree of

leaks and in good

condition?

Do open tanks have

atleast 2 ft. of

free board

?

Is leak detection program/

equipment working?

Initials Comments

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