earth materials minerals: the crystalline state minerals and mineralogy mineral chemistry atomic...
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Earth MaterialsMinerals: The Crystalline
State• Minerals and Mineralogy • Mineral Chemistry• Atomic Structure of Minerals• Minerals as indicators of the
environment of their formation
diamond quartz pyrite amethystasbestos
Plate boundaries and Earthquakes
Supercontinent and Plate Motion
Fig. 2.10
Supercontinent and Plate Motion
56 million years ago
Supercontinent and Plate Motion
120 million years ago
Supercontinent and Plate Motion
200 million years ago
Earth MaterialsMinerals: The Crystalline
State• Minerals and Mineralogy (p. 67-69)• Mineral Chemistry (p. 69-74)• Atomic Structure of Minerals (p. 74-
77)• Minerals as indicators of the
environment of their formation (p. 92)
diamond quartz pyrite amethystasbestos
Definition of a Mineral
• Naturally formed (inorganic)
Definition of a Mineral
• Naturally formed (inorganic)• Solid
Definition of a Mineral
• Naturally formed (inorganic)• Solid • Specific chemical composition
– What chemical elements are present and in what proportions
Definition of a Mineral
• Naturally occurring (inorganic)• Solid • Specific chemical composition• Crystal Structure
– Ordered arrangement of atoms
Definition of a Mineral
• Naturally occurring (inorganic)• Solid • Specific chemical composition• Crystal Structure
Examples: quartz (SiO2), calcite (CaCO3), halite (NaCl)
Rock is an aggregate of one or more minerals
Polished section
~1 cm
Thin Section
Thin section under ordinary light
Magnetite
Mica
Quartz
Feldspar
Thin section under polarized light
What makes each mineral unique?(p.69)• Composition
What chemical elements are present and in what proportions
– Quartz SiO2
– Olivine (Mg,Fe)2SiO3
What makes each mineral unique?(p.69)• Crystal Structure
How are the chemical elements packed together
Halite (NaCl)
Extremely soft
Extremely hardBoth minerals are made of carbon (C)
Atomic Arrangement& Physical Properties
3D framework
Sheet structure
Elements and atoms
• Chemical Elementsmost fundamental substance
separated by chemical means
• Atomssmallest particle of matterretains all properties of an element
Fig. 3.1
Structure of an Atom
• Ion an atom with excess chargecations H+
anions O2-
• Chemical Compoundelectrically neutral comb. of ions
water, H2O H+, H+, O2-
Ions and Compounds ( p. 54-56)
Complex ions
• Combination of ions with a charge
Si4+, O48- (SiO4)4- Silicate Ion
Transferring Electrons between atoms
Fig. 3.2
Ionic Bonding
Fig. 3.4
Covalent Bonds in Watersharing electrons between
atoms
Nature of Bonding and Physical Properties
3D framework
Sheet structure
Fig. 3.3 and 3.5
The Three States of Matter
Solid Liquid Gas
Ice in a glacier is a mineralWater in the oceans is not a mineral
Box B3.1
The Three States of
Water
Controlled by temperature and Pressure
low Temp, High Pressure favors solid state
In Geology, melting is a change of state
high Temp, low Pressure favors gaseous state
General Rule
Crystal Structure of Minerals (p. 74-77)
Two factors that control the arrangement of atoms and ions
Number of neighboring atoms/ions
Size of atom/ion
Galena (PbS) Packing order of
atoms
Packing arrangementPolymorphs
(p. 79)
Diamond
Graphite
Compounds that occur in more than 1 crystal arrangement
Size of ions of some
geologically important
ions
Size is based on Charge
Fig. 3.8
Silicate ion(SiO4)4-
O2-
O2- O2-
O2-
Si4+
Ionic Substitution
Olivine
Ionic Substitution
Olivine
Ions of Similar Size and Charge can substitute for each otherFor example
Ionic Substitution
OlivineMg2
2+(SiO4)4-
Ionic Substitution
OlivineFe2
2+(SiO4)4-
Fe2+-->Mg2+
Natural Olivine: (Mg,Fe)2SiO4
Phase diagram
Fig. 3.31
Minerals as indicators of their environments of their formationp. 92
Pre
ssu
re
Fig. 3.31
geotherm
Diamonds from the Mantle
Fig. 3.31
Fig. B3.1
Snowball