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11 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH Austin, Texas • 28th of October 2019Veronika Gronemann, Jason Holland • Global Syngas and Technology Conference
THIS DOCUMENT IS PUBLIC
Synergies in Air Liquide’s Syngas Technologies & Low Carbon Syngas Offer
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22 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Agenda
1. Air Liquide Overview2. Syngas Technology Overview3. Syngas utilization: HP ATR based methanol4. Syngas utilization: OTF Gas Supply5. Conclusion
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33 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
1.Air Liquide Overview
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44 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide - One business, several activitiesThe Air Liquide business is founded on technical and scientific expertise in essential small molecules for life, matter and energy, as well as on recognized operational know-how. Today, around 67,000 employees are working toward the shared goal of the Group’s sustainable development, driven by a true entrepreneurial spirit and the unrelenting desire for innovation that better serves our customers.
Air Liquide’s value creation model works by integrating and sharing our industrial assets.
This efficient industrial system brings Air Liquide closer to its customers so that it can anticipate their needs and offer them innovative solutions. The Group currently serves more than 3 million customers and patients from a wide range of sectors.
Refining/Steel/Chemicals/Energy Refining Steel Chemicals
Materials& Energy
Automotive & Manufacturing
Food & Pharmaceuticals
Professionals& Retail
Technology& Research
Specialtyingredients
Hygiene
Homehealthcare
Medicalgases
Flat panels
Photovoltaic
Semi-conductors
Maritime
Advanced technologies
Energytransition
~67,000
EMPLOYEES (1)
Revenue€ 18.1
BILLION (2)
Net profit€ 1.844
BILLION
More than3 MILLION
CUSTOMERS& PATIENTS
Present in80
COUNTRIES
~67,000
EMPLOYEES (1)
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55 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH 5
Air Liquide climate objectives
A globalapproach
Reduce our carbon intensity in 2025 vs. 2015 by
Act for clean industry by developing low-carbon solutions
Contribute to a new low-carbon society
CUSTOMERS
ASSETS
ECOSYSTEMS
-30%
A
C
E
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66 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
2.Syngas Technology Overview
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77 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide Hydrogen and Syngas Techno Portfolio
CO2
COCold Box
Membrane
H2 Liquifier
& O2
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88 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Superior Syngas Solutions - Track Record
8
Lurgi Steam Reformer
● More than 145 Steam Reformer plants built
Lurgi Autothermal Reforming
● More than 30 Autothermal Reformer built
Lurgi POX Plants
● More than 30 POX plants built with more that 100 reactors (1)
The complete choice
● With GasPOX, Steam Reforming, Autothermal Reforming and combinations thereof we can offer ALL S/C ratios and ALL capacities
Feed
O2/Steam ↓
↓
Sat. HP-Steam
➔
➔
Syngas
Burner
Syngas
Natural Gas
1) Includes Lurgi MPG®, Lurgi Gas POx , Shell licensed references
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99 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
3.Syngas utilization: HP ATR based methanol
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1010 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH 10
Today: Lurgi MegaMethanol™ 10,000 mtpd methanol capacity at the US Gulf Coast
Texas: Natgasoline - October 2018 Louisiana: YCI-M1 - January 2019ASUAir Liquide
Air Liquide: Technology Licensor, Engineering Partner and ASU Investor
ASUAir Liquide
ASUAir Liquide
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1111 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Purification
Steam Reforming
Autothermal Reforming
Methanol Reactors
Methanol Distillation
Air Separation
Natural Gas
Pure Methanol
Air
Oxy
gen
Purge Gas
Process Steam
Purification
Autothermal Reforming
Methanol Reactors
Methanol Distillation
Air Separation
Natural Gas
Pure Methanol
Air
Oxy
gen
Purge Gas
Process Steam
Flue Gas Duct Fired Heaters
PSA PSA
Tomorrow: HP ATR based MegaMethanol Plant 10,000 mtpd methanol capacity in a single train
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1212 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Combined Reforming based MegaMethanol Plant
HP ATR based MegaMethanol Plant
Production MTPD 5 000 5 000
Specific NG ConsumptionGJ/MT (mmBTU/MT) - LHV 30.1 (28.7) 30.1 (28.7)
Number of Reformer Tubes# 288 (1) -
Amount of Oxygen FlowMTPD 2 200 (1) 3 350 (1)
Synthesis Compression DutyMW 29.6 (2 compressors) 8.9 (1 compressor)
Utility concept Self sufficient Self sufficient
CAPEX 100% 90-95%
Comparison of Combined Reforming and HP ATR based MegaMethanol Plant
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1313 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
4.Syngas Utilization:OTF Gas Supply
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1414 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide Global Footprint
14
● Global Owner Operator ○ Air Liquide Group operates more than 90 Hydrogen, Syngas and CO Production Plants
● Markets catered to include,○ Refineries, Chemicals (Isocyanates, acetic acid, oxo-alcohols, polycarbonate, nylons, H2O2, NH3 and
others), Metals, Electronics
Singapore
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1515 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
What outsourcing means...
H2/CO/Syngas/Steam
Feedstock/Utilities Supplied by 3rd party or customers
Feedstock
Utilities
Electricity or O2 / N2
CUSTOMERAIR LIQUIDE
Air Liquide will ● build, own, operate and maintain the plants, and ● sign a long-term contract (15-20 yrs) to supply products to customer through pipelines
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1616 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Avoided CO2 emissions A new driver for Syngas/H2 production costs? “ ”
Steam Reforming
Biogas
Water + Renewable Electricity
Electrolysis
COS*Fossil Feed
Air Liquide is committed to
produce at least 50% of its
Hydrogen for energy
markets without CO2
emissions by 2020. This is
the Group’s “Blue Hydrogen”
initiative.
16
*CO Shift
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1717 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide Low Carbon Offering Cryocap (HYCO Only) Up to a 60% reduction in CO2 emissions
Absorption Systems (Amine)
Retrofit SMRs to SyngasUp to 60% emissions reduction
CO Coldbox (HYCO Only) ~40-90% footprint reduction
Power Purchase Agreement Menard County Wind Farm
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1818 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Carbon Capture on Syngas/H2 Production Unit
PSA
ShiftNatural Gas
H2/SYG/CO
Fuel Gas System ~60% of CO2
emissions
Solution 1: Amine Unit
(aMDEA)
Solution 2: Cryocap™
Solution 3: Amine Unit
(MEA)~100% of CO2 emissions
CO+ H2O-> CO2+H2
Steam Methane Reformer
Shift
~40% of CO2 emissions
18
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1919 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
5.Conclusion
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2020 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH 20
Conclusion
Technology+
Operations
reliableefficient
cost-effective
Solutions
Customer
Low Carbon World
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2121 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Discover more:www.engineering-airliquide.com