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1
PRACTICE USING
THE 2016 ERG (Emergency Response Guidebook)
AND OTHER
RESOURCES
© 2017 Lee Silvi
To use this training aid as a PowerPoint-style
presentation see the instructions in Slide #5
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2
Some images obtained from Miscellaneous WWW
Sites and unknown published sources.
WARNING: Read Slide #3 and Slide #4
completely before using!
New materials and slide program
concept / design is © 2017 Lee Silvi
LAKELAND COMMUNITY COLLEGE
Home of a Classroom Based and
an OnLine Fire Science Degree Program
and an OnLine Emergency Management
(aka Disaster Planning / Homeland Security) Degree
Both are Internationally Accredited by IFSAC
7700 Clocktower Drive
Kirtland, Ohio 44094
(440) 525-7252
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3
Limit of Liability / Disclaimer of Warranty
The college and the author make no representations or warranties with
respect to the accuracy or completeness of the contents of this work and
specifically disclaim all warranties, including without limitation warranties of
fitness for a particular purpose. No Warranty may be created or extended
by use. The advice and strategies contained herein may not be suitable for
every situation. This work is provided with the understanding neither the
college nor the author is engaged in rendering legal or other professional
services. If professional assistance is required, the services of a
competent professional person should be sought. Neither the college nor
the author shall be liable for damages arising herefrom. The fact that an
organization or website is referred to in this work as a citation and/or a
potential source of further information does not mean that the author or the
publisher endorses the information the organization or website may provide
or recommendations it may make. Further, users should be aware that
internet websites listed in this work may have changed or disappeared
between when this work was written and when it is read or utilized.
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CONSENT TO USE
Permission is granted for unaltered non-commercial use of these slides provided the
user agrees with the terms herein, the “Limit of Liability / Disclaimer of Warranty”
found in slide #3, the inclusion of all copyright slides, and agreement to those
terms found within these slides. Use or duplication of these slides
requires the inclusion of all copyright slides. Any use that violates
these terms immediately and unconditionally voids this Consent to Use.
© 2017 Lee Silvi
LAKELAND COMMUNITY COLLEGE
Home of Classroom Based and OnLine
Fire Science Courses and Degrees
http://www.lakelandcc.edu/firesafety
and an OnLine Emergency Management (aka Disaster Planning / Homeland Security) Degree
http://www.lakelandcc.edu/emergencymgmt
7700 Clocktower Drive
Kirtland, Ohio 44094
(440) 525-7252
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5
INSTRUCTIONS:
• To used this training aid in a “PowerPoint-style” slide mode
click on “View” then “Full Screen Mode”. You can then
use your up/down or arrow keys to advance the slides.
This is also compatible with most remote control devices.
• This presentation mostly consists of alternating pairs of slides.
• In most cases the first slide will present you with questions.
The second slide in each pair provides you with suggested
answers.
• For each slide you should also consider / review the information
found on the orange pages such as the general hazard found at the
top of the page, and other information found in the pairs of orange
pages. In some cases you will first go to the green pages. WHY?
• DISCLAIMER: These are practice samples only and perfect accuracy
is NOT GUARANTEED. Report any errors to [email protected]
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6
Please note – Other Identification Systems
exist. These slides primarily review:
• UN / DOT Placards and Labels.
• NFPA 704® System
• HMIS-1®, HMIS-2® , and HMIS-3®
• The newer “Globally Harmonized System”
• The European / South American System
• Pipeline identification in the United States
• The HFR System®
• Selected proprietary labeling systems
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• Given the placard or
symbol at the left what is
the name of the material?
?
• What type of material is it?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Propane (et. Al.)
• What type of material is it?
Flammable gas • What is the correct guide
number?
115
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is
it?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Methanol (and ?) • What type of material is
it?
Flammable liquid • What is the correct guide
number?
131
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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• Given the placard or symbol
at the left what is the name
of the material?
Hydrochloric Acid+ • What type of material is it?
Corrosive / Toxic? • What is the correct guide
number?
157
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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• Given the placard or symbol
at the left what is the name
of the material?
Unknown • What type of material is it?
Infectious
Substances • What is the correct guide
number?
158
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• Given the placards or
symbols at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
-or-
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• Given the placards or
symbols at the left what is
the name of the material?
Unknown • What type of material is it?
Gases, Toxic
and/or Corrosive • What is the correct guide
number?
123 (See pages 8 & 9)
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
-or-
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• Given the placard or symbol
at the left what is the name
of the material?
Unknown • What type of material is it?
Substances, Toxic
and/or Corrosive • What is the correct guide
number?
153 (See pages 8 & 9)
-or-
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19
Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
?
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Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
See Pages 20-25
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Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
? -or-
-or-
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Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
See “Note”
on Page 21
(Also: See page 123
in the 2016 Guidebook)
-or-
-or-
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23
Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
?
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24
Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
Pages 20-25
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Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
?
25
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26
Given the placard
or symbol at the left,
to what page in your
ERG might you turn
for initial guidance?
Pages 20-25
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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28
• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What type of material is it?
Water Reactive +
Flammable/Toxic Gases • What is the correct guide
number?
139 (see the 2016
ERG, page 9)
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• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
111 (See the 2016
ERG, page 8)
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• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
111 (See the 2016
ERG, pages 8 and 9)
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3,5-DICHLORO-2,4,6-
TRIFLUOROPYRIDINE (Shipping Paper)
• UN Number ?
• Guide Number ?
• Hazard?
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3,5-DICHLORO-2,4,6-
TRIFLUOROPYRIDINE (Shipping Paper)
• UN Number = 9264
• Guide Number = Use Guide 151
or the Green Pages whichever
is applicable. (See ERG page 20 or 90 for details on when each applies)
• Hazard = Toxic Substance
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• Given the highway trailer
at the left what is the
name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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36
• Given the highway trailer
at the left what is the
name of the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
131 (See the 2016
ERG, pages 12 & 13)
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it ?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Pesticide, n.o.s. (“n.o.s.” Stands for not
otherwise specified.)
• What type of material is it ?
Toxic
• What is the correct guide
number?
151
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• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What type of material is it?
Flammable Gas • What is the correct guide
number?
118 (See pages 8 & 9)
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• Given the placard or symbol
at the left what is the name
of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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• Given the placard or symbol
at the left what is the name
of the material?
Hydrogen Chloride • What type of material is it?
Toxic and/or Corrosive • What is the correct guide
number? As applicable:
Use Guide 125 or the
Green Pages!
Note: This is an Orange Panel that
might be found next to a US Placard.
It is not quite the same as the European
or South American ADR System.
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43
• Given the code at left,
what is this material?
? • What is it’s major hazard?
? • What is the correct guide
number?
? • What ID system is this?
?
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44
• Given the code at left, what is this material?
Sulfur Chlorides
• What is it’s major hazard?
It is a Corrosive / Water Reactive Substance
• What is the correct guide number? As applicable:
Use either Guide 137 or the Green Pages! • What ID system is this?
European / S. American
But it has been found on
IM shipments in the US
(See 2016 E.R.G., page 16)
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• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
134
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DRIVE SAFELY PLACARD (But you have unusual smoke / fire conditions)
• UN Number?
• Guide
Number?
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DRIVE SAFELY PLACARD (But you have unusual smoke / fire conditions)
• UN Number =
Unknown
• Guide
Number =
111
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• Given the placard or
symbol at the left what is
the hazardous material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what
is the hazardous material?
Organic Peroxide
(a “newer” style placard)
• What is the UN Number?
?
• What is the correct guide
number?
148
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• Given the placard or
symbol at the left what
is the hazard?
• What is the UN Number?
• What is the correct guide
number?
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• Given the placard or symbol
at the left what is the hazard?
This is an “Environmentally
Hazardous Substance Mark”
• What is the UN Number?
? • What is the correct guide number?
171
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• Given the code at left, what
is this material?
? • What are it’s major hazards?
? • What is the correct guide
number?
? • What ID system is this?
?
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• Given the code at left,
what is this material?
Acetyl Chloride
• What are it’s major
hazards?
Water reactive, highly
flammable, & corrosive!
• What is the correct
guide number? As
applicable: Use Guide
155 or the Green Pages!
• What ID system is this?
European / S. American
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55
• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
171
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TOLUENE (Shipping Paper)
• UN Number?
• Guide Number?
• Hazard?
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TOLUENE (Shipping Paper)
• UN Number = 1294
• Guide Number = 130
• Hazard = Noxious
Flammable Liquid
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• Given the highway trailer
at the left what is the
name of the material?
? • What type of material?
? • What is the correct guide
number?
?
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60
• Given the highway trailer
at the left what is the
name of the material?
Unknown • What type of material?
A Corrosive • What is the correct guide
number?
137 (see page 13
of the 2016 ERG)
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61
• Given the placard or symbol
at the left what is the name
of the material?
? • What type of material is
this?
? • What is the correct guide
number?
?
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62
• Given the placard or symbol
at the left what is the name
of the material?
Hydrogen Cyanide • What type of material is this?
Toxic / Corrosive • What is the correct guide
number?
As applicable: Use Guide
152 or the Green Pages!
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63
• Given the code at left,
what is this material?
? • What is it’s major hazard?
? • What is the correct guide
number?
? • What ID system is this?
?
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64
• Given the code at left,
what is this material?
Gasoline, (a.k.a. Petrol,
Gasohol, Motor Spirits)
• What is it’s major hazard?
Highly flammable
• What is the correct guide
number?
128 • What ID system is this?
European / S. American
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65
HYDROGEN (Shipping Paper)
• UN Number?
• Guide Number?
• Hazard?
![Page 66: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/66.jpg)
66
HYDROGEN (Shipping Paper)
• UN Number = 1049
• Guide Number = 115
• Hazard = Flammable Gas
![Page 67: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/67.jpg)
67
NO PLACARD (But you have unusual smoke / fire conditions)
• UN Number?
• Guide
Number?
![Page 68: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/68.jpg)
68
NO PLACARD (But you have unusual smoke / fire conditions)
• UN Number =
Unknown
• Guide Number
111
![Page 69: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/69.jpg)
69
2-METHYLFURAN (Shipping Paper)
• UN Number?
• Guide Number?
• Hazard?
![Page 70: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/70.jpg)
70
2-METHYLFURAN (Shipping Paper)
• UN Number = 2301
• Guide Number = 128
• Hazard = Flammable Liquid
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71
• Given the placard or symbol
at the left what is the name
of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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72
• Given the placard or symbol at
the left what is the name of the
material?
Chlorine • What type of material is it?
“Gas, Toxic and/or
Corrosive - Oxidizing” • What is the correct guide
number?
As applicable: Use Guide 124
or the Green Pages!
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73
LITHIUM ION BATTERIES (including lithium ion polymer batteries)
Shipping Papers
• UN Number ?
• Guide Number ?
![Page 74: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/74.jpg)
74
LITHIUM ION BATTERIES (including lithium ion polymer batteries)
Shipping Papers
• UN Number: 3480
• Guide Number: 147
Note: This is a newer guide found in the
Emergency Response Guidebook. You will not
find this in editions prior to the 2008 ERG.
This is one reason why you should ALWAYS
use the most current edition of the ERG.
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75
n-PENTANE (Shipping Paper)
• UN Number ?
• Guide Number ?
• Hazard ?
![Page 76: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/76.jpg)
76
n-PENTANE (Shipping Paper)
• UN Number = 1265
• Guide Number = 128
• Hazard = Flammable Liquid
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77
• Given the rail car at the
left what is the name of
the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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78
• Given the rail car at the
left what is the name of
the material?
Unknown • What is the UN Number?
Unknown • What is the correct guide
number?
111 (see page 11
in the 2016 ERG)
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79
• Given the code at left,
what is this material?
? • What is it’s major hazard?
? • What is the correct guide
number?
? • What ID system is this?
?
![Page 80: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/80.jpg)
80
• Given the code at left,
what is this material?
Acetal
• What is it’s major
hazard?
Highly Flammable
• What is the correct
guide number?
127
• What ID system is this?
European / S. American
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81
• Given the placard or
symbol at the left what is
the name of the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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82
• Given the placard or symbol
at the left what is the name
of the material?
Arsine or “SA” • What type of material is it?
Toxic and
Flammable! • What is the correct guide
number?
As applicable: Use Guide
119 or the Green Pages!
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83
• Given the symbol at the left
what is the name of the
material?
? • What type of material is it?
? • What is the correct guide
number?
?
![Page 84: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/84.jpg)
84
• Given the symbol at the left
what is the name of the
material?
Radioactive III, n.o.s. • What type of material is it?
Radioactive III,
thus a HIGH Level
Radioactive Material • What is the correct guide
number?
163
![Page 85: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/85.jpg)
85
• Given the placard or symbol
at the left what is the name of
the material?
? • What type of material is it?
? • What is the correct guide
number?
?
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86
• Given the placard or
symbol at the left what is
the name of the material?
Explosives, n.o.s. ! • What type of material is it?
Fragmentation Hazard Explosives
• What is the correct guide
number? 112 (See pages 6, 8, 15, 27,
118, 162 and 163 in the
2016 Emergency
Response Guidebook)
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87
• Given the placard or symbol
at the left what is the name of
the material?
? • What type of material is it?
? • What is the correct guide
number?
?
![Page 88: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/88.jpg)
88
• Given the placard or symbol
at the left what is the name of
the material?
Organophosphorus
Pesticide, solid … • What type of material is it?
Toxic & Combustible • What is the correct guide
number?
152
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89
DRIVE SAFELY PLACARD (But you have unusual smoke / fire conditions)
• UN Number?
• Guide
Number?
![Page 90: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/90.jpg)
90
DRIVE SAFELY PLACARD (But you have unusual smoke / fire conditions)
• UN Number =
Unknown
• Guide Number =
111
![Page 91: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/91.jpg)
91
• Given the placard or symbol
at the left what is the name of
the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
![Page 92: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/92.jpg)
92
• Given the placard or symbol at
the left what is the name of the
material?
Organic Peroxide, n.o.s. • What is the UN Number?
Unknown • What is the correct guide
number?
148
![Page 93: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/93.jpg)
93
• You have encountered an IM
tank on a truck trailer. Both of
these placards are displayed.
What might this material be ?
? • What is the UN Number?
? • What is the Guide Number?
? • What are the potential hazards
of these materials
?
1131
![Page 94: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/94.jpg)
94
• You have encountered an IM tank
on a truck trailer. Both of these
placards are displayed. What
might this material be ?
Carbon Bisulfide or ? • What is the UN Number?
1131 • What is the Guide Number?
131 • What are the potential hazards of
these materials
It is a toxic flammable liquid.
Remember, MANY HazMats
have more than one hazard,
but this is one that should
display both a primary risk
and a subsidiary risk placard.
1131
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95
• Given the rail car above, what is the name of the material?
? • What is the UN Number?
? • What is the correct guide number?
?
![Page 96: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/96.jpg)
96
• Given the rail car above, what is the name of the material?
This car is nicknamed the “Candystriper”.
It’s cargo is normally Hydrocyanic Acid - UN 1051
• What is the correct guide number?
As applicable: Use Guide 117 or the Green Pages!
(See page 26 or 92 for details on when each applies)
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97
NO VISIBLE PLACARD? (But you have unusual smoke / fire conditions)
• UN Number?
• Guide Number?
• Hazard?
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98
NO VISIBLE PLACARD? (But you have unusual smoke / fire conditions)
• UN Number = Not applicable
• Guide Number = 111
• Hazard = Unknown !!!
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99
LITHIUM NITRIDE (Spilled in Water)
• UN Number = ?
• Guide Number = ?
![Page 100: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/100.jpg)
100
LITHIUM NITRIDE (Spilled in Water)
Determining this one,
and many others that
are considered “hazardous
when spilled in water”,
is much more complicated!
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101
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806
The Guide Number is 138
(see page 128 in the 2016 ERG)
BUT ….. (see the next 5 slides)
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102
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806 / Guide 138 (see page 128)
(2) It is a highlighted material, in Water,
so go to the green pages (page 317,
which refers you to page 351).
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103
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806 / Guide 138 (see page 128)
(2) It is a highlighted material, in Water, so go to the
green pages (page 317, which refers you to page 351)
(3) On page 351 you see the TIH is NH3 - Ammonia
![Page 104: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/104.jpg)
104
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806 / Guide 138 (see page 128)
(2) It is a highlighted material, in Water, so go to the
green pages (page 317, which refers you to page 351)
(3) On page 351 you see the TIH is NH3 - Ammonia
(4) Look up Ammonia in the Blue pages = UN 1005
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105
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806 / Guide 138 (see page 128)
(2) It is a highlighted material, in Water, so go to the
green pages (page 317, which refers you to page 351)
(3) On page 351 you see the TIH is NH3 - Ammonia
(4) Look up Ammonia in the Blue pages = UN 1005
(5) Then look up UN 1005 in the green pages
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106
LITHIUM NITRIDE (Spilled in Water)
Determining this one is More Complicated (continued):
(1) Lithium Nitride is UN 2806 / Guide 138 (see page 128)
(2) It is a highlighted material, in Water, so go to the
green pages (page 317, which refers you to page 351)
(3) On page 351 you see the TIH is NH3 - Ammonia
(4) Look up Ammonia in the Blue pages = UN 1005
(5) Then look up UN 1005 in the green pages
(6) Use the protection distances that provide the most
safety for you - the one for UN 2806 or UN 1005
and MOVE there or farther away NOW !
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107
• What is this material?
?
2810
• What type of material is this?
? • What is the correct guide number?
?
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108
• What is this material? It could be one of numerous HazMats that share the same UN
number. Most are chemical warfare agents. One of these is Sarin.
According to NIOSH: “Sarin (military designation GB), is a nerve
agent that is one of the most toxic of the known chemical warfare
agents. It is generally odorless and tasteless. Exposure to sarin
can cause death in minutes. A fraction of an ounce (1 to 10 mL)
of sarin on the skin can be fatal. Nerve agents are chemically
similar to organophosphate pesticides and exert their effects
by interfering with the normal function of the nervous system”.
2810
• What type of material is this?
Toxic + • What is the correct guide number?
153
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109
• Given the placard or symbol at
the left what is the name of the
material?
? • What type of material is this?
? • What is the correct guide number?
?
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110
• Given the placard or symbol at the
left what is the name of the
material?
It could be one of many that
share the same UN Number. If
safe to obtain, you will need the
shipping papers or MSDS.
• What type of material is this?
Corrosive
• What is the correct guide number?
154
Note: There are many other
HazMats that share UN Numbers.
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111
• Given the placard or symbol at
the left what is the name of the
material?
? • What type of material is this?
? • What is the correct guide number?
?
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112
• Given the placard or symbol at the
left what is the name of the
material?
It could be one of many that
share the same UN Number.
If safe to obtain, you will need
the shipping papers or MSDS.
• What type of material is this?
Flammable Liquid
• What is the correct guide number?
128
Once again, this is one of many other
HazMats that share UN Numbers.
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113
• Given the information below what is the name of the material?
? • What is the UN Number?
?
• What is the correct guide number?
?
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114
• Given the information below what is the name of the material?
Multiple Materials are on board • What is the UN Number?
UN 1789, 1824, and 2372
• What is the correct guide number?
If you’re not sure which is leaking use the
“most restrictive” guide of the three !
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115
ANOTHER EUROPEAN SYSTEM:
This system
has an
“Emergency
Action Code”
within one of
the panels
BUT ....
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116
ANOTHER EUROPEAN SYSTEM:
The
“Emergency
Action Code”
is NOT the
same as the
two digit
European or
S. American
Hazard ID
Numbers!
![Page 117: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/117.jpg)
Regarding a BLEVE, what is the
minimum time to failure for a severe
torch of a 2000 liter container?
117
![Page 118: PRACTICE USING THE 2016 ERG - Lakeland Community College](https://reader031.vdocuments.mx/reader031/viewer/2022013009/61ce5fb89f656474314f21e8/html5/thumbnails/118.jpg)
Regarding a BLEVE, what is the
minimum time to failure for a severe
torch of a 2000 liter container?
For the answer to this you could have
referred to pages 368 and 369 of the
2016 Emergency Response Guidebook
118
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What is the minimum outdoor
evacuation distance for a high
explosive IED pipe bomb?
119
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What is the minimum outdoor
evacuation distance for a high
explosive IED pipe bomb?
For the answer to this you could
have referred to page 374 of the
2016 Emergency Response Guidebook
120
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What is the night time down wind
protection distance for an
agricultural nurse tank of UN1005 if
the winds are greater than 12 MPH?
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What is the night time down wind
protection distance for an
agricultural nurse tank of UN1005 if
the winds are greater than 12 MPH?
For the answer to this you could
have referred to page 355 of the
2016 Emergency Response Guidebook
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What is the night time down wind
protection distance for a
single ton container of UN1052 if
the winds are greater than 12 MPH?
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What is the night time down wind
protection distance for a
single ton container of UN1052 if
the winds are greater than 12 MPH?
For the answer to this you could
have referred to page 357 of the
2016 Emergency Response Guidebook
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Have you checked your
Emergency Response Guidebook
for any needed corrections?
Do you know how to
check for corrections?
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You should periodically visit this web site to check for errata information applicable to your ERG:
https://www.phmsa.dot.gov/hazmat/corrections-to-the-erg
If the above page returns an error message, type the
word “errata” in the search box found on this web page.
https://www.phmsa.dot.gov/
Have you checked your Emergency Response
Guidebook for any needed corrections?
Did you know an errata has
been issued for the 2016 ERG ?
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• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
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• Given the placard or
symbol at the left what is
the name of the material?
• What is the UN Number?
• What is the correct guide
number?
All Are Unknown: By itself, the
NFPA 704 System
does not provide
answers to the
above questions!
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The NFPA 704 System
Note: Prior to the 2007 edition of NFPA 704 the standard used
the word “Reactivity”. As of 2007 this has been replaced with
“Instability”. You will likely see both uses for many, many years.
Note: The above guide is NOT the “official” NFPA guide. Also, NFPA 704
(2007) only recognizes the “slash W”, OX, and SA. Although often used,
all other “special hazard” symbols are NOT NFPA 704 compliant.
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The NFPA 704 System
For the following slides you are to determine the risk.
In the second of each slide pair I have added
any Special Hazard information. In real life
Special Hazard Information may not always
be present, even when applicable !
Note: Most hazard ratings in the NFPA 704 system,
and most other systems, assume the material is in
it’s normal state, at room temperature, and not in
contact with other materials that can alter the
hazard characteristics of the rated material.
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
Note: Prior to the 2007 edition of NFPA 704 the standard used
the word “Reactivity”. As of 2007 this has been replaced with
“Instability”. You will likely see both uses for many, many years.
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• Health Hazard= 0
• Flammability = 4
• Instability = 0
• Special Info =
None Noted under
normal conditions.
(Room temperature and
not mixed with any
other materials)
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 4
• Instability = 3
• Special Info =
Oxidizer
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 2
• Flammability = 4
• Instability = 3
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 2
• Flammability = 4
• Instability = 3
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 2
• Instability = 1
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 2
• Flammability = 3
• Instability = 4
• Special Info =
Radioactive
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 4
• Instability = 3
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 1
• Instability = 0
• Special Info =
None Noted under
normal conditions
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 4
• Flammability = 4
• Instability = 4
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 4
• Instability = 3
• Special Info =
Use No Water
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info = ?
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• Health Hazard= ?
• Flammability = ?
• Instability = ?
• Special Info =
Multiple concerns!
Obviously this facility has multiple hazards. Therefore, detailed
pre-emergency planning and obtaining SDS for all products is critical!
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• Given the placard or
symbol at the left what is
the name of the material?
? • What is the UN Number?
? • What is the correct guide
number?
?
Note: As of December 2008 the HMIS still used the word
“Reactivity”. Whereas, as of 2007, NFPA 704 uses the word
“Instability”. You will likely see both uses for many, many years.
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• Given the placard or
symbol at the left what is
the name of the material?
• What is the UN Number? • What is the correct guide
number?
All Are Unknown:
By itself, the HMIS
System does not
provide the answers
to the above
questions?
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• By itself, the HMIS
does not provide the
name of the material,
UN number, or ERG
Guide Number.
• The rating numbers are
similar to the NFPA 704
System, but may not
use the same testing
methods.
• The HMIS label may
include a PPE Code
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• By itself, the HMIS
does not provide the
name of the material,
UN number, or ERG
Guide Number.
• The rating numbers
are similar to the
NFPA 704 System, but
may not use the same
testing methods.
• The HMIS label may
include a PPE Code
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• By itself, the HMIS
does not provide the
name of the material,
UN number, or ERG
Guide Number.
• The rating numbers are
similar to the NFPA 704
System, but may not
use the same testing
methods.
• The HMIS label may
include a PPE Code
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Note: Be careful as
the HMIS System
has been modified
over the years.
You may see labels
compliant with the
HMIS 1 ®
HMIS 2 ®
or the LATEST:
HMIS 3 ® System
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POSTER (Left) & POCKET CARDS FOR
SOME VERSIONS OF HMIS-I and HMIS II
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HMIS III
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HMIS III
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THE HMIS SYSTEM(S)
Additional HMIS information may be found at
http://www.paint.org/hmis/index.cfm
For the following slides you are
to determine the risk.
In the second of each slide pair I have
added any Special Hazard information.
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 3
• Flammability = 4
• Reactivity = 3
• Special Info = Code G (See the pocket card)
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 2
• Flammability = 3
• Reactivity = 0
• Special Info =
Code “H”
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 1
• Flammability = 0
• Reactivity = 0
• Special Info =
No Personal Protection
Letter Code is used, but
note the contents and
potential effects do
appear in the white
space at the bottom.
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 2
• Flammability = 4
• Reactivity = 1
• Special Info =
None Noted ?
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 1
• Flammability = 1
• Reactivity = 0
• Special Info =
None Noted ?
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 4
• Flammability = 4
• Reactivity = 4
• Special Info =
Code “X”
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= 1
• Flammability = 3
• Reactivity = 0
• Special Info =
Code C
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
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• Health Hazard= ?
• Flammability = ?
• Reactivity = ?
• Special Info?
This is printed in
Japanese. I threw
it in for a laugh.
Good luck trying
to read it if you
encounter one.
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OTHER
HAZARD
IDENTIFICATION
SYSTEMS
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Other systems do exist!
For example, some
corporations may use the
“HFR” system on some of
their tanks within their plants.
When this system is used within
the plant the letters and numbers are NOT color coded
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HFR EXAMPLE
If you observed the following stenciled
on a bulk storage tank:
H3 F2 R1
It would mean:
Health = 3
Flammability = 2
Reactivity = 1
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“HFR” SYSTEM PRACTICE Review the following examples
H4 F4 R4
H0 F4 R0
H2 F2 R4
H1 F0 R1
H4 F4 R0
H0 F0 R0
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ALDRICH PRODUCT LABELS (Proprietary identification label ?)
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A COMBINATION LABEL (Proprietary identification label ?)
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The GHS
The GHS (Globally Harmonized System of
Classification and Labeling of Chemicals) is here!
The intent of the system is to make identifying special hazards,
such as systemic toxins and aquatic pollutants easier, as
well as provide instructions on appropriate protective equipment.
The GHS is already in use in many countries, including the United States.
IMPORTANT: See pages 14 and 15 of the
2016 Emergency Response Guidebook for basic information.
For details on OSHA implementation of the GHS in the United States visit:
http://www.osha.gov/dsg/hazcom/
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The GHS
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• You find the symbol at
left on a label. What
does this signify?
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• You find the symbol at
left on a label. What
does this signify?
• It could signify any
of the following:
– Irritant
– Skin sensitizer
– Acute toxicity
– Respiratory tract irritant
– Hazardous to ozone layer
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• You find the symbol at
left on a label. What
does this signify?
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• You find the symbol at
left on a label. What
does this signify?
• A Health Hazard such as:
– Carcinogen
– Mutagen
– Reproductive toxicity
– Respiratory sensitizer
– Target organ toxicity
– Aspiration toxicity
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What is the difference
between the two
symbols at left?
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• What is the difference
between the two symbols
at left?
• The top one could signify
any of the following:
– Flammables
– Pyrophorics
– Self heating
– Emits flammable gas
– Self reactives
– Organic peroxides
• The bottom one signifies
it is an oxidizer.
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For details regarding the above please visit
http://www.osha.gov/Publications/HazComm_QuickCard_Pictogram.html
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Proprietary GHS Samples:
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The GHS
IMPORTANT:
For Information on Safety Data Sheets
(formerly known as MSDS)
see the next two slides and visit:
http://www.osha.gov/Publications/HazComm_QuickCard_SafetyData.html
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OSHA Safety Data Sheets
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OSHA Safety Data Sheets
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http://www.osha.gov/dsg/hazcom/effectivedates.html
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Intermodal
Transportation
Hazard Identification Issues
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Intermodal Shipments …
• Can present special identification problems
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Intermodal Shipments …
• Can present special identification problems
• While most fire departments will not
have to deal with a sea response …
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Intermodal Shipments …
• Can present special identification problems
• While most fire departments will not have
• to deal with a sea response …
• Your department may have to
respond to a port, highway, rail,
or other emergency involving
intermodal containers.
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Intermodal Shipments …
• Can present special identification problems
• While most fire departments will not have
• to deal with a sea response …
• Your department may have to respond to
a port, rail, highway, or other emergency
involving intermodal containers
• Therefore, take your time to properly identify
the container(s) and product(s) involved.
(Some example Intermodal Shipments follow) 204
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COFCs Double Stacked
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COFCs (Top) TOFC (Bottom)
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IM-101 (Left) and a COFC (Right)
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“TCSZ” Rail Shipment
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Containers on a Flatbed Trailer (Left)
vs. Regular Highway Trailer (Right)
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IM-101 Acid Shipment (Left)
Refrigerated IM Shipment (Right)
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CONSENT TO USE
Permission is granted for unaltered non-commercial use of these slides provided the
user agrees with the terms herein, the “Limit of Liability / Disclaimer of Warranty”
found in slide #3, the inclusion of all copyright slides, and agreement to
those terms found within these slides. Use or duplication of these slides
requires the inclusion of all copyright slides. Any use that violates these
terms immediately and unconditionally voids this Consent to Use.
© 2017 Lee Silvi
LAKELAND COMMUNITY COLLEGE
Home of Classroom Based and OnLine
Fire Science Courses and Degrees
http://www.lakelandcc.edu/firesafety
and an OnLine Emergency Management (aka Disaster Planning / Homeland Security) Degree
http://www.lakelandcc.edu/emergencymgmt
7700 Clocktower Drive
Kirtland, Ohio 44094
(440) 525-7252
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215
IFSAC is currently the only organization in the
world recognized by “CHEA” to grant fire and
emergency related ( including “Emergency
Management” ) program accreditation.
IFSAC membership or accreditation
is NOT limited to one college per state.
Every college in the United States that holds
regional accreditation may seek IFSAC voting
membership and program accreditation.
For colleges outside the United States
appropriate governmental recognition is
required to become a voting IFSAC member
and seek program accreditation.
If your college is not accredited
by IFSAC please visit
https://ifsac.org/
to learn more.
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Some images obtained from Miscellaneous WWW
Sites and unknown published sources.
WARNING: Read Slide #3 and Slide #4
completely before using!
New materials and slide program
concept / design is © 2017 Lee Silvi
LAKELAND COMMUNITY COLLEGE
Home of a Classroom Based and
an OnLine Fire Science Degree Program
and an OnLine Emergency Management
(aka Disaster Planning / Homeland Security) Degree
Both are Internationally Accredited by IFSAC
7700 Clocktower Drive
Kirtland, Ohio 44094
(440) 525-7252