Potassium formate brine has been produced by Addcon in Norway since 1994
Production Site ADDCON NORDIC AS
Storage tanks for raw materials
Potassium formate production by Addcon
• The first and largest producer of potassium formate
- Brine production capacity : 800,000 bbl/year
- Non-caking powder capacity: 8,400 MT/year
• Direct production from HCOOH and KOH
• High purity product
• Large stocks on quayside location
• Fast service – by truck, rail and sea
• Supplier to the oil industry since 1994
50 % KOH4,500 m3
6,300 MT
94 % Formic acid5,000 m3
Feedstock storage tanks in Norway
Cesium formate produced by Cabot in Canada from pollucite ore
Pollucite ore
Cs0.7Na0.2Rb0.04Al0.9Si2.1O6·(H20)
• Mined at Bernic Lake, Manitoba
• Processed on site to Cs formate brine
• Cs formate brine production 700 bbl/month
W-Cluster
15000'
Z2
Z6
Z5Z7
Z4
5000'
10000'
15000'
18000'
Potassium formate brine has been used to drill deep HPHT gas wells since 1995
First use : ExxonMobil’s Walsrode field, onshore northern Germany - high-angle deep HPHT slim hole low perm gas wells
TVD : 4,450-5,547 metres Reservoir: Sandstone 0.1-125 mDBHST : 157o C Section length: 345-650 mDrilling fluid: SG 1.45-1.55 K formate brine
Potassium formate from Addcon used in 15 deep HPHT gas well constructions in Germany ,1995-99
Well Name Application Fluid Type Density s.g. (ppg)Horizontal Length(m)
Angle (°) BHST (°F) BHCT (°F) TVD (metres) MD (metres)Permeability
(mD)
Walsrode Z5 W/C K Formate 1.55 (12.93) 345 26 315 na 4450 - 4632 4815 - 5151 0.1 - 125 mD
Wasrode Z6 W/C K Formate 1.55 (12.93) 420 40 315 na 4450 - 4632 4815 - 5151 0.1 - 125 mD
Walsrode Z7 Drill-In K Formate 1.53 (12.77) 690 59 315 295 4541 - 4777 5136 - 5547 0.1 - 125 mD
Söhlingen Z3A Drill-In Formix 1.38 (11.52) 855 89 300 270 4908 5600 na
Söhlingen Z3a Drill-In Na Formate 1.30 (10.85) 855 89 300 270 4908 5600 na
Volkersen Z3 W/C Formix 1.40 (11.68) 512 52 320 na na na na
Kalle S108 Drill-In Formix 1.45 (12.10) 431 60 220 na 6000-6500 6200-6600 na
Weißenmoor Z1 W/C Formix 1.35 (11.27) 634 31 300 na na na na
Idsingen Z1a Drill-In K Formate 1.55 (12.93) 645 61 321 290 4632 - 4800 5257 - 5821 0.1 - 125 mD
Söhlingen Z12 Drill-InNa
Formate/Formix1.35 (11.27) 452 28 313 285 4736 - 4937 4846 - 5166 1.0 - 75 mD
Simonswolde Z1 Drill-In K Formate/Formix 1.52 (12.68) 567 35 293 275 4267 - 4572 4236 - 4648 0.1 - 25 mD
Walsrode NZ1 Drill-In Formix 1.51 (12.60) 460 34 290 265 4632 - 4815 4541 - 4693 0.1 - 125 mD
Idzingen Z2 W/C Formix 1.40 (11.68) na na 320 na 4632 - 4800 5257 - 5821 0.1 - 125 mD
Voelkersen NZ2 W/C Formix 1.40 (11.680 na na 320 na na na na
Söhlingen Z13 Drill-In/Frac K Formate/Formix 1.30 (-1.56)(10.85) 1200 90 300 285 4724 5486 - 6400 0,1 - 150 mD
Fluids service provided by M-I and Baroid
Formate brines – Some further important milestones : 1999-2004
19991999 20002000 20012001 20022002 20032003 2004 2004
First production of non-caking
crystalline K formate by
Addcon
First drilling jobs with
K/Cs formate brine:
Huldra and Devenick HPHT
Formate brines used as packer fluids for HPHT wells in GOM. First well : ExxonMobil’s MO 822#7 (215oC BHST) in 2001
Use of Cs-weighted oil-based completion fluids for oil reservoirs : Visund, Statfjord, Njord, Gullfaks, Snorre , Oseberg, Rimfaks 2001 – present
First use of Cs-weighted LSOBM as perforating completion
fluid (Visund)
First use of K/Cs formate
brine : Completion
job in Shearwater well (Shell
UK)
Cs-weighted LSOBM used as OH screen completion
fluid (Statfjord)
First use of K/Cs
formate brine as
HPHT well suspension
fluid (Elgin)
Individual Draugen oil wells (1993) and Visund oil wells (2003) have similar flow rates of around 50,000 bbl oil/day
First of 14 Kvitebjørn HPHT wells drilled and completed with K/Cs formate brines
The first sustained use of K/Cs formate brine was in the world’s largest HPHT gas field development
190oC1100bar
5300m
Water Depth 90m
SIWHPFWHT
830bar180oC
::
GASCONDENSATE
3-4% C0230-40 ppm H2S
320barDEWPOINT
30% O1 Darcy K
Cesium formate brine used by TOTAL in 34 well construction operations in 8 deep gas fields in period 1999-2010
Elgin/Franklin field – UK North Sea
Formate brines – Some published milestones 2005 -2010
20052005 20062006 20072007 20082008 20092009 2010 2010
OMV Pakistan
start using K formate to drill and
complete (with ESS) in
HPHT gas wells
K/Cs formate brines used as well perforating fluids in 11 HPHT gas fields in UK North Sea : Dunbar, Shearwater, Elgin, Devenick , Braemar , Rhum, Judy , Glenelg , Kessog , Jura and West Franklin1999-2011
Saudi Aramco start using K
formate to drill and complete (with ESS) in
HPHT gas wells
Gravel pack with K
formate brine in
Statfjord B
First MPD operation in Kvitebjørn with K/Cs formate
“designer fluid”
First of 12 completions
in the Kashagan field with
K/Cs formate
Total’s West Franklin F9 well (204oC) perforated in K/Cs formate
brine
Petrobras use K
formate brine for
open hole gravel packs
in Manati field