II
2o3
APPENDIX J
NUS
DATA REDUCTION, VALIDATION AND REPORTING
flR300657
OATA REDUCTION, VALIDATION, AND REPORTING
The following procedures summarize practices routinely used by
laboratory and office, staffs for data reduction, validation, and reporting.
Numerical analyses including manual calculations, mapping, and conputeri
modeling, are documented and subjected to quality control review. Records
of numerical analyses are legible and ...complete enough to permit
reconstruction of the work by a qualified individual other than the
originator. . . . ._._. , .'.
: _ . _ ' . .laboratory Data Validation
Data validation begins with data reduction and continues through to
reporting of data. Data processing and data processing review are
performed by the .analysts and group leaders. After the draft
report is prepared, Laboratory Supervisors review the draft report.
The NUS Laboratory Manager reviews the report and approves it for
issue. The procedure is outlined in Figure 1.
Data processing is performed by the analyst in one of the following
ways:
o ffenual computation of the results directly in the benchbookor on calculation sheets , :
o Direct acquisition of reduced computer data
o Input of raw data for computer processing.
If" data are manually ccmputated, all steps performed are provided
including equations..used and the source of input information (response
constants, etc.) . Ttie analyst initials and dates each page of
calculations.
J3R30Q658
ACTIVITY RESPONSIBILITY
DataProcessing
v
VCheckingof Draft
Data Jteport
Final Review
Approval forIssue
Analysts
Reviewof Group DsadersData
Processing
Preparationof laboratory SupervisorsDraftReports
laboratory Supervisors
laboratory Onager
Laboratory Manager
FIGURE 1
LABORATORY DATA VALIDATION PROCESS
AR3QQ659
If data are computer processed, the input data is recorded in the
benchbook (if entered directly form .the benchbook) or with the raw data
file. Ttie analyst initials and dates all data input pages.
If reduced data are directly acquired from a computer, the analyst
verifies the sample numbers, calibration constants, response factors
and output parameters. The analyst initials and dates the resulting
output.
Data processing is checked by the group leader or by an analyst other
than the anayst who performed the data processing. The checker reviews
the data for the following:
o Utilization of the proper equations-
o Correctness of numerical input -
o Correctness of computationsi
o Correct interpretation of raw data (chronatographs, stripcharts, etc.) .
The checking process is thorough enough to verify the results. If the
checker disagrees with any part of the computations, the checker marks
through the number with a single line and places the revised number
above it. The originator reviews all changes made by the checker. If
the originator agrees with the change, no action is necessary. If
there is a disagreement between checker and originator, the differences
are resolved and the result is agreed upon. The checker initials and
dates all pages of the computations to indicate his agreement with the
calculation and the originator's agreement with any changes.
When data conputations are performed with a conputer, the checker
reviews all input entries. If the checker disagrees with any entry,fiR300660
the checker marks through the number with a single, line and places the
revised number above it. The originator reviews all changes as
discussed previously. The revised input entries are reprocessed. The
checker initials and dates all entry input sheets, original and
revised, to indicate agreement.
Review of data reports is performed to verify that reported information
corresponds with processed analytical results. A draft report is
prepared. After validation of processed data, steps taken to prepare
the draft report do not need to be validated.
Reported results contained in the draft report are checked against the
validated process data to verify transcription errors are not present.
The checker does not have to be independent of the work. Incorrect
entries are marked through with a single line and the correct entry
placed above it. The checker initials and dates all~'pages of the draft
report. The draft report is maintained to document the review.
After the draft report is typed, Laboratory Supervisors review the
report to verify typographical errors are not present. All errors are
marked through with a single line and the correct entry placed above.5laboratory Supervisors review the corrected report and jaends the report
to the Laboratory Itenager for final review. The Laboratory Manager
approves the report for issuance.
AR3Q066
i» 2.0 Office Data Validation
Analytical activities are performed" in a planned and controlled manner.
Performance" responsibility rests with _t_he Project Onager. Prior to
initiating activities, the Project £fenger discusses scope of work,-•-, |contractual and regulatory requirements, and applicable QA/QC
procedures with project personnel. At the request of the Project
Manager, this will be done by the QA Officer..
To provide evidence of satisfactory work performance and the basis for• t
information transmitted, external analyses and their results are
completely ..documented. Documentation may include calculations,
computer programs/ logs, drawings, and tables.
2.1 Calculations . .,_.„.._ „„. „_....,.„,,. .. ..... - - •> •
Calculations, as appropriate, include a statement of calculation
intent, description of methodology used, assumptions and their
justification, input data and equation references, numerical
calculations including units, and results. Input data may include:
o Regulatory requirements
o Bsrformance and operational requirements under variousconditions
o teterial, geological, environmental, and geotechnicalrequirements
o Results of field and laboratory testing or calculations
o Information obtained from external personnel or literatureand site data surveys.
Computer printout that become an integral part of calculations are
referenced in the calculations by run number or other unique means of
identi fication.
ftR300662
At the end of calculations, results are summarized to provide clarity.
Assignments for checking are made or approved by the Project Manger.
Verification is performed by an individual(s) other than the person(s)
who performed the original work or (specified the method or input
parameters to be used.) The individual (s) selected will have technical
expertise in the calculation subj ect. It is enphasi zed that a
numerical check is not sufficient. The checker is responsible for
every item on every sheet.
When calculations are performed utilizing a computer program, the input
data is checked as described in Section 13.1.
2-2 Logs, Drawings, and Tables __
The results may be presented in logs, drawings, and tables of various
forms. The format of logs and tables is governed by information to be
presented. Drawings are uniquely identified by drawing or figure
number and appropriate title. Standardized symbols and nationally
accepted drafting standards are used. References to 'other drawings and
sources of information are provided, as necessary.
Drawings signed and dated by the draftsperson performing the work and
the responsible member of the project group who has checked the
drawing.
flR300663
Revisions are noted on the original , drawing with a brief note* I
describing each revision. The note is signed and dated by the
draftsperson performing the wsrk and the repsonsible member of the
project group who has checked the revision.
Final subsurface logs are. verified by a responsible member of thet• iproject group. Verification provides that changes from original field
representative's logs to final log sheets are consistent with results
of laboratory testing or other investigations. Final log sheets are
checked and the checker initials and dates each sheets.
Indication of final drawing and revision approval is through signing
and dating of drawings by the Project Manager or a member of project
staff delegated this responsibility by the Project ffenager. Drawings
are not issued without completion of the checking cycle as evidenced by
the checker's signature.1 ....--.. h
2.3 Field Data Validation .. , -
Field data generated in accordance with the project work plan will
be validated by review of project documentation to check that all formsfspecified in the sampling plan and QAPP have been completely and
icorrectly filled out and that documentation exists for required
instrument calibration. This documentation will be considered
sufficient to provide proper procedures have been followed during the
field investigation.
Software Verification
Computer software used to acquire, process, or report data is verified
to demonstrate its intended functions are performed correctly.
Externally prepared prograns are accepted as valid. Verification by
NUS is not necessary.
Programs developed within NUS and externally prepared prograns modified
by NUS undergo a complete verification before being used. The
verification procedure is dependent upon the function of the software.
For software that only performs numerical manipulation, sample sets of
numbers are processed. Results are compared to results from hand
manipulation of the sample sets. The sample set is chosen so that all
program options are tested. Ability of the software to store and
manage files is also tested.
Software operational performance . for an instrument is tested by
processing standard materials through the system. Instrument response
is compared to the known result of standard materials.
The individual performing verification signs and dates computer outputs
and manual computations. The verifier's signature indicates acceptable
comparison of output and manual computations. When standard materials
are used for verification, the know values are included. All
documentation is maintained.
AR3QQ665
2.5 Recorded Entries . ::— ...:..-, n_ .;/t.-.. r - .; "
All entries made in benchbooks, data sheets, computation sheets, input
sheets, etc. are made in ink. No entry will be rendered illegible.
2-6 Hounding of Numbers , : .. .
Whenever a value needs to be rounded, the following procedures are
used:
o If the digit "following the digit to be rounded is greaterthan five, the digit to be rounded is raised to the nexthigher digit.
o If the digit following the digit to be rounded is less thanfive, the digit to be rounded remains as is.
o If the digit following the digit to be rounded is a five andno digits follow the five, and if the digit to be rounded isodd, the digit to be rounded is raised to the next higherdigit. If the digit to be rounded is even, the digit remainsas is.
o If- the digit following the digit to be rounded is a five,followed by other digits, the digit to be rounded is raisedto the next higher digit.
2.7 Analytical Reports
Analytical data will be reported as specified in CLP protocol. The
following information will be included in the data package:
o Efcraneters analysed, report units, values, and qualifiers.
o Sample number; laboratory name and code; contract number;case, SAS and SDG number; and corresponding lab sanple ID.
o Date of sample receipt and analysis./i
o Sanple matrix and level.
o Tentatively identified organic compounds and estimated values.
o Surrogate, matrix spike, matrix spike duplicate, and duplicaterecover ies.
o tethod blank results.
o GC/MS tuning and mass calibration.
o Initial calibration and continuing calibration check data
o GQ/MS internal standard areas*
o Pesticide evaluation standards summary.
o Efesticide/PCB confirmation data*
o AA and ICP CRDL standard data.
o ICP interference check data.
o Inorganic laboratory control sample data.
o Standard addition results.
o ICP serial dilutions data.
o Inorganics holding times.
o Inorganics instrument detection limits.
o ICP interelament correction factors.
o ICP linear ranges.
The following figures contain the reporting forms:
IIfIIIIIIIIIIIII
N,
APPENDIX K
DATA SUMMARY FORMS
DATA VALIDATION SUMMARY FORMS
DATA PACKAGE REPORTING FORMS
p1 . ; RR300668
1 1 1 1 11 1 1C J CP & CT l ^
M , • *c- — . c — <-• • -? i. ' r ; : | : ; * .• • c r — ; . , c
, 3 i - .. i -1 C i C i W ' '- < - . • si y i o t c i t n i - i ft i *• I Ci r i e i *» i f1 i *I •- i i y i y i ci : • c i t - •- T
f . •* IS 13 1C l 30. C ! C i ft i : Ci C l •- i l C ' T
; 7 1 £ i IT1* t 1 1 !(<* 1 1 IS't 1 1 It'f 1 1 1 1> < 1 1 1 1, 1 1 1 1• i i i < i
• T i i i i« 1 1 1 11 I 1 I I' I i i 1 t: ' 1 1 1 1. t 1 . 1 1.J ...:....'.....,..'....
* i l l '
; ' 1 ! ! !
t i1 1 1 'f 1 I 1 1 1. . 1 1 1 1 1
> 1 1 1 1 1
• •• 1 1
t 1 ,i - - r 1
:-s L..L.L.L.I...• * . i t i i' i • r i r
i l l i i• > i i i
' i i t i ii i l I l
» \ ' i l t lt • i i i i
' ' t r I
' 1 1 1 1 11 1 1
' 1 i ' 1 T 1. 1 i i i | |
> ] • 1 1 1 t
i i 1 1
t i l l
1 ' li : i 1
. ' i i 1
i i : ii i ; -
i
I ' ; i ; ;
r ; i | |.: l i
• ! i !1
|
tfi P
c3Caf!y»•«ecft<•yi
c
c<£
t
f
tl)
tfl
IIn£
I
^
«
*
-*
^
E
IV
X
_
1
Cf
1cnP"p^
.
ii
r>
f
tr."
*&
iN>IO
pn
«e^
i
ii(71
m
OO
d.n
rc1•K
1
5?c§
^
|
(1
••ft.
_ _ _ .
e
r-
8c
e
I
r
PI
e
?
3
if£
.
M np- n 7S' ii r n
c !• «t " 5
i..i<fii"i r-n eu ftn •*1! *"
" '• S1! Snuituiiitti»iUi)IIUU -NII
!(H"ifM
i
r -i1
i intiititMIIIIIt
MIIUIIl!ir
ii inituiu"n1nn11 . _ _nnt rM"M,llh*1''Mi ;nn,iiinMIf1II
I1 '
M1 1f11
D
C
f.tt
«
•• il!ll11l1l1i
l/v
[B>
fi
II11111
!
•
'1
••
_
'
:
Cfr
c•»
4i *•i ?i «i •«iiiiiitiiiiiiiiiiiiiiiiiii fc! *ri «•'i
iiiiiiii'iiiiit
t n ^c
£ T"i C *
i £f *•i < C: t*
] £ Cli r- ^! § rt »i C ^1 ?" W
i •—i f
i •—
i
itii
i
i
rtrl*C
?3
V.c
-oc£c
C
R300669
1 i r 1 1 I
* , c • c , = ! c ! c. i
•t i Z S X | a i 0-
| i •* (r • » i e » • V §• r • - : ? 'f^ £ ; — i c 10: in• ;S 1?, « •• 1C < T.' *•** 'I ? ' ' ?* ' 6• I i i < 1 4 a < f i *i! l e i r- l "• l 3 i C'» i i r • i c • *-> i i » t 3 * •• i U. i r i • » i ci i t £ i t i *ri i i 1^1 i ^i l l i 1 * 1 i " 5'! i t i £ i 1 1£tt i i i p- i i *•> 1 t i * i 1 wt i i i i i r• i i i *• i i r-i t i ) 3 1 I 3"M < i i e ' i ii| t r l l l ^lj 1 1 1 I 11 1 1 I 1. 1 1 1 1 11 1 1 ' 1 t> > 1 1 t1. ( i t 1 1. 1 . 1 1• ' 1 t I 1' ' 1 1 t J1 1 1 1 t 11 i 1 1 1 11, 1 . 1 1 1•1 l ; - 1 'it t 1 1 1 I.* 1 . I 1 11 1 1 1 11 1 1 1 1 11 '.' 1 1 1 1 1- 1 1 1 1 1
tJ 1 , 1 1 1..* .....'....... :....'...
* 1 1 I 1 1
i l ! : , ' : jt: 1 1 1 1 11 1 < 1 I t
f 1 1 I t I'" 1 ' 1 1 11 1 1 1 1 1
1 1 (t ' 1 1 t
i : t 1 l l• • • i t t i» 1 ' t 1 1* t l ' i 1> i 1 i 1 1
i 1 i 1 1- 1 * 1 1 11 i , > t if l i . 1 t< • 1 i > i' 1 i 1 1 I
• ' i l lI i i l
i i t 1 1......................1 1 l l
i . i 1 . t• i . 1 1• ' t i l t
.. ......L.LA...L.i . » j ii i i i i
• ' . i tt 1 1 1 1 !1 i < > i •1 l • l - 1j 1 ' 1 1 1| 1 « *
l 1 I 1• l t
j ! !
» ii i• i
I :
i : '
1c
c
— •
o
r,-iCs»ny••»*
ftift
"
'
iO i C
r
C i -
N 1 l»£ I C«- | M
i r>
r« i e£ l ft
1 Zl N
(ITtiiiitti11iiiltllll
{
i
1li
t
liIiI1I
11t1II
"" ilr„ iiii
T
iiiii*ii
ititiiti
ii
i'i
i
O
*
ieMlr.
izN
" ""
_,
-
-
i
C
N)l
e
i
'
_
.~
--
o
cru
9n
|wf*
i
--
u »riisr 113=c i. r-*• n
II XH<ii r-n mnlM mM \r<uiinM11IIIIIIHMIIIIIIII
ItII'UK1'IIIittnIIItII11II11It11HIIIIItII11IIIIiinnnI-nnnnniii1111iiiii
.... _." .Muntin11Hi.npnn11n11nnui.nn" n11M
11IIt iC l(1IIt rnH
1.rtnnnl«ItPnnt.ii
V
V
I
Cl«
X
1
'
wny
D
tot
C
,
1
<*
9
£R
1(71
TJV
rvi-ift
n
81
1
.__
1
W
•Hm
IP
O
ttX
i.
— -
r
C
1at
•LfviT3
J
——
(rii n1, X
n iIi
CD H"* nC "11!— • n r>
3 |||
niin11nn rn cit nit *u (•n ••n cII 9nnHItIIHIIIiII
IIII
IIIIMIIIIIIIInu1 !IIt l
' 1 1niintiM
hItIIIIIIl lIIIIIIIIIIIIn~Nn"nrnMII
ItItllII
iiirnititnnnnhIiMMMII
PIIIit lMP "HU
II
ItIIntt11itn1!
. .. p11
nM
p s ni; fl R
?^«•>
5.••
ll
"
b
MIIII11n11 B LftH r •-11 ^ ^ti C CPll C ZII •*• *" iH fi eH | .,11 Jn •€11 w
»i 3It |0II *•11IA ii
t "!i!*- IIc nII
M•• II
II 'HiijinIi
nu• HMtlP
_ .11
II
"ii 1i. /* r-.~~" C X
II tfii ' S V*1. ^Sn -3ii ^n r-H " W
•• u , tni.M
_ p_l_P
_ J '___n "
-- nu^ l!"hj>
ttpl i
n 1*1 n cH n xti C Hi| g r^e_"nc »r
' tl C'' Cn g e —ti"^ c e•- n ?*-i£ isH Xti r •«•-
,....!' © r>n PCii p *• &II T* W 5
n *- tf
~" n — fn — ••"1C Cii a yn Vn —n "li 3... c -
1lii.ni.i
p
'0:Q67f
\s>
3
Z
zX
c
; i i '{ C _ =, ; C ,. C
i c '. j. '• jv i x-I r " z ' 'j. ' r1^^ . - i t i -1 ^ > -• ' C . fta B; £ i 3 i r
•j .-« Hi? ifj • ft . r t c i sif i 3 • C I "0 i ft• I > — i y ti — ' 1 1 C I.' C i 1 3 l' e • i i c ii r t i i ••• ii 1 i i i i -< I t t i i1 * 1 i i ii i i i i1 ' i i ii t i iii i i ii i t ii i t i
i i i ii i i i t1 , 1 1 1• 1 I 1 F
1 - 1 1 1 t. I ; i ; '"J i I 1 1
I'M MJ J....L. J....L.i i i i iI ' l l !' 1 1 1 1I t 1 ! 1
..j ...... ...:...'....! S J 1 t
•> i i ! 1
I I I II I I I
; i i I l
< ! i i t t1 • i i f ' ti i t t l< ' i l (j l i ( i1 - 1 i l l' • i l i •.., .'...J...J...J....
i t i i ii t i i I• 1 l ! i 'i \ ' t 1 i
!| ! ! 1 !. * . 1 | 1
' i l l
' ( . ; » ; •• 1 : 1 1
1 I ' 1 I
1 . |
t ' 1> 1 : 1 1 1
•1 : i i ii i i ii ii i i
• \f !
' 1
1
Si
u1z
D
I
....
C.
fV«*
"tp3
CC
ft
_
ic
f
1ft
"
io
psy
*c
s
e
IVz
esI
"
-
i
c
ty'cs1y
»"
g
^r,
oC
e
IV
tf't^r.*•
e
HuK*chl orocc I «kf**nt-*di en*
"
"
o
ryi
*cMB311ft3ft
O
1y0ei
If
e
fffc
»cftfiv•s
1
c
1yee
I
c-
!l
o
*
1
r.y•*•r
I1•
-
ite
V
1pn
0
"
c
eru
r/
Bw1y
_
!O
ftCIt
M
ft
f t
(i nC " Ctl F
M ]
llrv itW tlJ, nt HO n
liil^ tl *,,,£
I"D ll*• IItl fiii • nM •ti •••11 fiM 9IIIIIIIIII11IIIIIIIIIIIIIIIIItIIII11iiiti it tiinn11pPn11pPPPn1!
t init11ppUnnnMnhHlil i
. tiP; . p
itppPM1.htitl
IIM
HII1'U
, I'ttUliI IP1.rPpti
' h11II
P1.
HIT
: I1 '
D
C
[
4
iiii
iiiiiiin iiift 11
fl1• 11"• 11»11111111••
R
e»fte
t int fti _5
i T: *•1 2i tfii •>iiiiiiiiitiiiiiiitiii•i
ii
F /•
i C_:! r1 W
ii
iiiiiiif* rl m JCi Ci s; rl C *1 1/ ci S *•! < ct -n »i & Ci r ri f" "' C 6IS t
In <i *i ^
it S1 tfi1
1
'
30(
t
\
1r»X
r-u-
cn&nC— •ftrv3bv
C
£C£
e
3
36
ftur
r
7
Z2
' I . > t .) = C t C • Ci . 1 1 1* I . I
. . , t
Iu T if [F •?ie t K, i s i &5 ; £ ; i ; c,
i «- , r*. « (t t X" 1 y£ • «• < > ' W l w
1 •• 1 - IT "•.!->
• tin t 1 i * i *. r - &. • i 3 i 3* i i i f- t #•
< I t 1 i i ij I t e t i ti t i i ii i i i iI t t i i
t t t i• t i i• i t i ii i i i it ! ' I !1 '• . . !'I 7-,-VV-
t 1 1 t I
t ' ' Ii i 1 I 1ti . t t t• I i l i iI i < i i
' / t i l l' " • t i t> i i ' i. . i i i t•1 ' t i t
ij i l l li > i ii **- ii i i l i11 1 1 ti i i i
i i i i
i . i iii i i
•" i i i i1 > i i
. 1 1 1 11 1 i l .
( i l lI ' l l1 ' I „ '. t 1 1*1> i i i ii i i t i•. * i t iij • i i i
4 i i i i1 i i t ii i i t t
4 1 t 1I t 1 I 1
t i l l1 • 1 11 t I t
1 11 1 I
I ' 1 (..................
i ; '; i. 1 1 1 1
J : ' : ;t i l l
• i : f
ic
c
cfff-<£.i—
3-**•ft
I ' •• ii i]
. i i1 > i i
C
crVr-TV1I*I?if,iC«••X
f*
ft
c
<£.eI
~~
-
''
11
iO
wtNCft
f
•
c
uu1fl.
Ei
_
-
_
p
wcr*£
§N*£
y»M*
ft
ft
.
1
t
P
?
"
_
-
_.
~
P
§
.
-
::._
'
—
o
pI3iri+
I
i*
"
_
-
——
•
C
f*
n
D
•e
*
1
.
smmz
"
c
X
?§
D
i
1
••ft
i
C
H-MI tro»cHiipttwiHjl**iin«
2A
tD3
0iIV1
I
1
_
-
i
•I-NI tro*ni I inn
-
O
g
i
Mit r>^ li 90
ll *M in
-V IIt 11r- ny Mc n ft
i Pf "f M3 M r£ n e••I* ft• M ft?u &
It 3llII 1IIIIIIItIItltlIIIIIIIIIIIIP ~~I)npitituuP "nnM11It
liM
M11P11I thttuPPPntlIIItlillnlililiilli1.iiMh11
IIP
IIIIUl iI II tP11
Htl
III rPIIP1'
IIH
IIIIIIHIIIIIIII
III I
rpn
< £
u11li O I/1 ftti ft * ftt; t r ftIt C Z Zt > 3 3It tfl C 9-" t " In j *ii <t i ••it *- i
D It "• l*• H 5 l•• It £ l£. ." » *-•in u iSh P i
-li iM| |& ? i •n i
i i
n ii-n iii inrr in <it i. tt i i•• it eIt £ii _ —TiIT -~ <,?.t Z11 3n - 5" &rr *c
"i! 1 =-4V - c x sn «C ••
" ' x
•ii r• i m -f
i 3rr~tv —- - wnnn!inpM
" P "li
i" ' £ — ~- i m x•• c *• c r- ft
i C » f. l/i C• y o —!I -ti < C C
§G- t»3 3
M "C
Ti ft C_ p T niiz £ cn *- ^ &: p -
__ . v* t
! £
ll "P —
'! " 3 Cr* C
II '1. l
P C1 "n! >-^ i- ii. >f — t
^00672
- i e •
f '
r ' iii41
1
1
f
1t
;
i
i
iiiii
ii
iii
i
j
i!
1€
C I
v ;
sr
*'
r
|
C ic" 1
cjo(Jl I
Aruclur- lUlto
-
*. iP i
ftfOXHPHCH£
C-*
_
oI*
•HLPHH CHLOADANIE
p
5
Endrin fcatctnu
etft
•rtt.HOXVlHLOR
C
e^
I
oo
Endu»ull«n Sul fat*
O
O
A
-
oO
§
_
eO
Hiram*
- •
eC
a"j.•iS
D
O
O 1
sm
wr*•*
ps
xf&F
oS
uupfu
_ ,
.. ...
.fr, .-....-
D
8
aOTMTMJdTMw
es
Fir~
_____
-
P
8ift
'
- ;
C
5F
ft
t
o P r
u /n» M
f i:ft n
R n !!§ii 2 rPC Cii nH ftII f*If *•II 0K 3hititMHnunllnniinnnpnnHnPl!IInnHMt.
1.1"
IIP1,liIIl«IIt
' IIII
1.M1!MIIItPtl
PHUPPPhlitlPITII
tlIIIIIIt'Mhn
PpunpMP
llP
IIIIIIII11IIMU
IIP
HPIfHl lP1rnu
Dilution factor
Hlli:nn » •• &It f* r+ t>l' ft C Citn o z z" •» g c
J 4 ," :f« ?•* tl ifift ti ••
t'Z l• IIII
II1111IIIIII1.1 .tl« 1n«iunnliPp
"!• §11 *K ~ fi-ll C »i, £II XV*" '"ii. r-rr F>
•• II VI11
1111
PI
-- t1
11I
P
PII
I Il l
t! m r oP 3Cii Enup r 0IIs- —n c * r,!!s *Zn x — -ti "C C C
II §|! F ^xi e •» £If" w ~,.,-.- ,-i Z *•. — fr> "* ^i *• ••• c el = 3
) *•3.. , •-
iii
i
iii
IIL*
Omi/
tC
ftR300673
9IX&AXIC IATA ¥AL1UT10K SUWWtY HP 1 if
ftate tevltw CompleteC«e No. m SSfte IUH-Xai^lt ftos.
4AS lo. IMIIII contract Lab
Contract w.Labt*tfif'
eOHCEPCTJUTIONIUTR1X "low Mtoil/solidaoueousether
0 MflW -K/U1II KUTEB
»Dever*• Keoion n
f COWEKTS
r pnonePT* •
ICPHoTSTng T1neCalibration Blanks.Initial CalibrationContinuing CalibrationPreparation BlankInterference Check SanpleLab Control SanpleLab Duplicateftatri* SpikeSerial Dilution
OK m ACTION COWEMTS
•
FU*NACEHolding TimeCalibration BlanksInitial CalibrationContinuing CalibrationPreparation Blanktab Control SancieLab DuplicatePatrii SpikeDuplicate InjectionsAnalytical Seifce
•
HERCUftY t CYM1DEHolding Tl»eCalibration Blankinitial CalibrationContinuing Calibrationpreparation BlankLab DuplicatePatrlx Spike
- —'s comrrrs:
•OOCUHENTAT10K ATTACHED (Set following P•»*»). MR30067U
ORGANIC DATA VALIDATION SUMMARY page 1 of•- '-'•• y*1 ^ T *
Date Review ConpletedCase No. SA5~Rb. Contract LabSite Name Contract Ho.Sancle Nos. Lab DPO
Reviewerfrom Region Phone
FTSV •»
CONCENTRATIONMATRIX 1soil/solidaqueousother
low med hi 9*1 MATRIX RELATED COMMENTS
VOLATILESGC/MS tuning--BFBInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding times
OK FYI ACTION COMMENTS
*
SEMI-VOLATILESGC/MS tuning— OFTPPInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding times
PESTICIDESInstrument PerformanceInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding times
OVERALL CASECoroound IdentificationData Concleteness
REVIEWER'S COMMENTS:
"DOCUMENTATION ATTACHED (see following pages)
3H3Q0675
U.S. EPA - CLPf1 COVER PAGE - INORGANIC ANALYSES DATA PACKAGEj
4 Lab Name: ______" ______ Contract: _____
I Lab Cods: _____ Case No.: ____ SAS No.: _____ SDG No.
SOW No. :
EPA Sample No. " T t? Sample ID.
Were ICP interelement corrections applied? Yes/No
Were ICP background corrections applied? Yes/NoIf yes-were raw data generated beforeapplication of background corrections? Yes/No
Comments:
Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on floppy diskette has been authorizedthe Laboratory Manager or the Manager's designee, as verified by thefollowing signature.
Lab Manager:
——— — «-_• r- rr-COVER PAGE - IN A K 3 U 0 6 7 6 7/3?
U.S. EPA - CLP
1 EPA SAMPLE NO,INORGANIC ANALYSIS'DATA SHEET ___________
Lab Name: _______ ________ Contract:
Lab Code: ____ Case No.: ____ SAS No.:____ SDG No.:
Matrix (soil/water): ____ - Lab Sample ID: __
Level (low/med): ____ . Date Received: __
% Solids: ____
Concentration Units (ug/L or mg/kg dry weight): ___
- 1CAS No. | Analyte
17429-90-5 I Aluminum7440-36-0 (Antimony7440-38-2 | Arsenic7440-39-3 | Barium7440-41-7 | Beryllium7440-43-9 | Cadmium7440-70-2 (Calcium7440-47-3 | Chromium7440-48-4 | Cobalt7440-50-8 (Copper7439-89-6 I Iron7439-92-1 1 Lead7439-95-4 (Magnesium7439-96-5 (Manganese7439-97-6 (Mercury7440-02-0 (Nickel7440-09-7 I Potassium7782-49-2 (Selenium7440-22-4 1 Silver7440-23-5 1 Sodium7440-28-0 [Thallium7440-62-2 (Vanadium7440-66-6 I Zinc
1 Cyanide1
1Concentration | C
Ii1iI11
' 111iI!1S1iii11i;!!11t
I
M Q
Color Before: ______ Clarity Before: ____ Texture:
Color After: ______ Clarity After: ____ Artifacts:
Comments:
FORM i - ik flR300677 7/37
U.S. EPA - CLP
! . 2AINITIAL AND CONTINUING CALIBRATION VERIFICATION
Lab Name: _______ ____ Contract:
Lab Code: ____ Case No.: ____ SAS No.: ,__ SDG No.:
Initial Calibration Source: _________
Continuing Calibration Source: _________
Concentration Units: ug/L :
' ' i MInitial Calibration | Continuing Calibration I \
I (Analyte | True Found %R(1)True Found %R(1) Found %R(1) i i M
1 I Aluminum 1 ij 1 Antimony I 1
1 Arsenic [ jf (Barium i 1i (Beryllium! I1 (Cadmium I [
1 Calcium j j| {Chromium j j1 (Cobalt 1 !
I Copper _ | |I llron 1 11 I Lead 1 1(Magnesium) i
j (Manganese] f(Mercury 1 I(Nickel I 1
. I Potassium 1 11 Selenium ] t
* (Silver i 1I Sodium | !
t (Thallium f 1I (Vanadium I 1IZinc | |
f 1 cyanide 1 I1 1 1 1
-
™
(1) control Limits: Mercury 80-120; Other Metals 90-110; cyanide 85-115,
7/87
• U.S. EPA - CLP
J ! . 2§CRDL STANDARD FOR AA AND ICP
Lab Name: _______________ ___ Contract::
Lab Code: ____ Case No,: ____ SAS No.;; . SDG No.: __
AA CRDL Standard Source: _________•
ICP CRDL Standard Source: -______i . • . _ - < - - . -
Concentration Units: ug/L ri———j n————————| | CRDL Standard for AA | | CRDL Standard for ICP( I I I Initial " Finalj Analyte | True Found %R j j True Found %R Found %R
.11.1 Aluminum 11 Antimony 1(Arsenic I1 Barium 1| erylliumj
.dmium j! Calcium j(Chromium I1 Cobalt 11 Copper |I Iron |(Lead 1I Magnesium jI Manganese I1 Mercury 1(Nickel 1I Potassium 11 Selenium |1 Silver 1(Sodium |(thallium 1(Vanadium |IZinc 11 = 1
f I I 1 I I1 I I 1 I I1 I I I I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 1 11 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 II 1 1 11 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I1 I I 1 I I
n ««,„-^
I U.S. EPA - CLP
{ ' BLANKS
iLab Name: __________ Contract:
Case No.: "__ SAS No.: . SDG No.
Preparation Blank Matrix (soil/water): ____
Preparation Blank Concentration Units (ug/L or ag/kg):
1 1 I '| I Initial |( | Calib. | Cont.1 | Blank 1(Analyte | (ug/L) C| lI " 1 I1 Aluminum | 1 |I Antimony I i _|_1 Arsenic I I II Barium j 1 j .1 Beryllium! 1 J(Cadmium I 1 I1 Calcium I ( I[Chromium j j j(Cobalt 1 I (1 Copper 1 ( (I Iron 1 ( 1(Lead 1 1 I.Magnesium! 1 I'Manganese) 1 I1 Mercury 1 1 1' Nickel | I |Potassium! 1 j
i Selenium I I j(Silver 1 1 |Sodium I I 1.Thallium I 1 i(Vanadium I 1 |Zinc I I |.cyanide 1 1 !1 1 (I
LmB:cling Calib.Lank (ug/L
2
raiIC
tion3 C
Prepa-rationBlank C
1
M
•_
FORM in-IN flR300680 7/87
U.S. EPA - CLP
4ICP INTERFERENCE CHECK SAMPLE
Lab Name: Contract:
Lab Code: _____ Case No: ____ " SAS No.: _____ SDG No.
ICP ID Number: ICS Source: __
Concentration Unit$:_ug/iL
1| True| Sol. Sol.
Analyte | A AB1
Aluminum I IAntimony 1 1Arsenic 1 jBarium j jBeryllium! jCadmium I jCalcium I jChromium j jCobalt | |Copper. I |iron I !Lead I [Magnesium! jManganese | iMercury 1 1Nickel 1 IPotassium! 1Selenium 1 1Silver 1 1Sodium | 1Thallium j IVanadium j IZinc | I
I 1
Initial Foun<Sol. Sol.A AB
(I111i!11111iI11I1II1h11
i
%R
i
iF
: 3Sol.A
Final FouneSol.AB
1
%R
FORM IV - IN fl R $ 0 0 fi R I V87
U.S. EPA - CLP
EPA SAMPLE
Lab Name: ._____________ Contract:
Lab Code: _____ Case No.: ____ SAS No.: ____ SDG No.:
Matrix (soil/water): ____ - Level (low/med):•
Concentration Units (ug/L or mg/kg dry weight):
111 -| Analyte1| Aluminum| Antimony_1 Arsenic1 Barium1 BerylliumI Cadmiumj Calcium1 Chromium1 Cobalt| Copperllron(Lead1 Magnesium| Manganese1 Mercury1 Nickel1 Potassium| Selenium(Silver(Sodium|Thalliu«_j Vanadium(ZincI Cyanide1
Comments :
1Control |Limit j Spiked Sample%R | Result (SSR)
1111111I111111111111111111
C
"
. sampleResult (SR)•
C. spikeAdded (SA) %R Q
>•»
<
M
r
FORM V (PART 1)-IN flRJ00682 7/87
. U.S. EPA - CLP
SB , EPA SAMPLE NOPOST DIGEST SPIKE SAMPLE RECOVERY .———________
! Lab Name: ___________________ Contract:
Lab Code: ____. Case No.: ____ SAS No.: ____ SDG No.:
Matrix (soil/water): ____ - Level (low/med):
Concentration Units: ug/L
! i I Control1 L Limit|Analyte |~ %R
' {Aluminum 11 Antimony \
! 1 Arsenic 1J 1 Barium 1
f Beryllium 1i I cadmium I\ l Calcium j| Chromium |
•' Cobalt I-pper 1 _
i— .on... I1 Lead 1
I (Magnesium!' ! Manganese I
i Mercury I\ ( Nickel (i (Potassium I
1 Selenium Ij {Silver Ij (Sodium _.. i
(Thallium 1. (Vanadium I
1 Zinc 11 1 Cyanide (' 1
1 I !
Comments :
j
Spiked SampleResult (SSR)
4
CSample
Result (SR)
.
•
i
cSpike
Added (SA) %R
_
Q M
„
FORM V (PART 2) - IN 7/87
U.S. EPA - CLP
6 EPA SAMPLE NO,DUPLICATES
Lab Name: ________________ Contract:
Lab Code: _____ Case No.: ____ SAS No.: _____ SDG No.:
Matrix (soil/water): ____ - Level (low/med) :
% Solids for Sample: _____ % Solids for Duplicate:
Concentration Units (ug/L or mg/kg dry weight): ___
1 1 iI - I control || Analyte | Limit (1 ! 1{ Aluminum f 11 Antimony 1 1(Arsenic 1 1j Barium i I1 Beryllium I (1 Cadmium 1 11 Calcium i I1 Chromium 1 jI Cobalt | [I Copper 1 1( Iron I 11 Lead i 1(Magnesium! I| Manganese | |1 Mercury 1 11 Nickel i 1(Potassium! j(Selenium 1 j1 Silver 1 f1 Sodium ( I(Thallium ( I(Vanadium I I1 Zinc I |1 Cyanide i i1 i 1
Sample (S)
_
c.\Duplicate (D) C RPD Q M
1
4
FORM VI- i* SR30068U 7/87
^U.S. EPA - CLP
7LABORATORY CONTROL SAMPLE
Lab Name: _________ ___ Contract:
Lab Code: _____ Case No.: ____ SAS No.: _____ SDG No,•
Solid LCS Source: _________
Aqueous LCS Source: _________
AnalyteAqueous (ug/L) | Solid (mg/kg)
True Found %R j True Found C Limits %R
( Aluminum_|Antimony_I ArsenicI Barium(Berylliumt <?admium
IciumI -aromium1 CobaltI Copper _.,.(Iron(Lead(Magnesium| Manganese1 Mercury1 Nickelj Potassium| Selenium1 Silverj Sodium| Thalliumj VanadiumIZincI Cyanide1
11111111111111111111111I1
1111111111111111111111111
1|
-I._l.-I.J.-I.-I._l._lJ.-I,
FORM VII -IN flR300S85
U.S. EPA - CLP
8STANDARD ADDITION RESULTS
1 Lab Name: _______________ Contract:
Code: ____ Case No.: ____ SAS No.: _____ SDG No.:
Concentration Units: ug/L
1 11 EPA |j Sample |"| ' No. (An1 11 11 11 11 11 11 11 11 1^V i1 11 1M 1
1 11 1! 11 11 11 11 11 1! 1! 11 1> I
Dil0 ADDABS CON
,
1 ADDABS
2CON
ADDABS
3CON
ADDABS
FinalCone.
-
" r
1
iQlJJ
1J
1JJ.1J
i
JJ
1111
,11111I
,11
FORMVTII-INJ J5R300686 7/87
1 ICP SERIAL DILUTIONS
1 me: ______M____ Contract:
U.S. EPA - CLP
SPA SAMPLE NO.
-ode: ____ Case No.: ____ SAS No.: ____ SDG No.:
Lx (soil/water): ____ - Level (low/med) :
Concentration Units: ug/L
1 1 II! | (I Initial Sample
lAnalyte || Result (I) Ci '1 II! (Aluminum 1 1 1
(Antimony 1 1 j1 Arsenic 1 1 1
{ 1 Barium i 1 11 1 Beryllium 1! I
1 Cadmium I I 11 calcium 1 1 11 Chromium I I 11 Cobalt 1 1 I
! 1 Copper I I 1i 1 Iron 1 1 1
1 Lead II - 1I Magnesium! 1 1I Manganese I j I(Mercury 1 I 11 Nickel I 1 1I Potassium I 1 1I Selenium I I 1(Silver II 1I Sodium 1 1 1(Thallium 1 1 1(Vanadium 1 1 1
' (Zinc II 1i 1 II 1
SerialDilutionResult (S) C
Differ-ence Q :M
300687
U.S. EPA - CLP
I 10* HOLDING TIMES
Contract:
Lab Code: ____ Case No.: ____ SAS No.: _____ SDG No.:
1 1 11 1 1| • EPA • | |. Date[Sample No. j Matrix (Received1 1 11 1 1
1 11 1 1
1 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 »1 11 11 1
1 1I Mercury (MercuryI Prep (Holding1 Date j Time1 11 11 11 11 11 11 !1 11 f1 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 1
CyanidePrepDate
Cyanide(-Holding)
Titte |11!
111111I111f1111111
FORM X-IH fiRHH
U.S. EPA - CLP
11INSTRUMENT DETECTION LIMITS (QUARTERLY)
3 Name:
3 Code: Ca:
? ID Number:
ime AA ID Number:
rnace AA ID Number:
-
1!I(AnalyteiI Aluminum^1 Antimony^I Arsenic _j Bariumj BerylliumI Cadmium _[ Calcium _j Chromiumi Cobalt _1 Copper _miillronILeadj Magnesium![ Manganese |I Mercury ]1 Nickel ~|j Potassium![Selenium |(Silver 1I Sodium 1IT&alliumJ[Vanadium jfZinc |I i
ments :
•e No. :
Wave-length(nm)
...
i
Back-ground
, ,
ContraSAS No
Date:
'
CRDL(ug/L)
200601020055
5000105025100S
5000150.240
5000510
5000105020
ct:.. .
•
r
IDL(ug/L) M
SDG No.:
-
-
«
————— |——————————
FORM XI -IN flR3Q0689 7/87
JJ.S. EPA - CLP
12AICP INTERELEMENT CORRECTION FACTORS (QUARTERLY)
! Lab Name: __________________. Contract:
Lab Code: ; Case No.: ____ SAS No.: ____ SDG No.:
ICP ID Number: _________ Date:
IiI(Analyte1I Aluminum| Antimony^(Arsenic _j Bariumj Beryllium[Cadmium _1 Calcium _j Chromium•bait
pper __(IroniLead(MagnesiumI Manganesei MercuryNickel
f Potassiumj SeleniumSilver. Sodium|Thallium_'VanadiumZinc[
Wave-length(nm)
ii - iji1 Al1111111111111111111111111
iterelement Correction
Ca Fe
111111111——— 1 ———1111111111111
Factors for: |
Mg ]1
1 11 11 11 11 11 11 11 111 11 11 11 11 11 11 11 11 11 11 11 11 11 11 1
osiments:
FORM XII (PART 1) - IN flR300690 V87
U.S. EPA - CLP
12BICP INTERELEMENT CORRECTION FACTORS (QUARTERLY)
Lab Name:
Lab Code: Case No
ICP ID Number:•
1 i M1 ( Wave-- | ( UI " 1 length 1 |(Analyte I (nm) i I1 f I!(Aluminum 1 1 (1 Antimony 1 1 (1 Arsenic f ( !1 Barium I I 1! Beryllium! I 1! cadmium I I 1I Calcium ( | I! Chromium 1 I I1 -»balt i I (
pper I 1 (1 iron 1 1 !1 Lead 1 1 !| Magnesium! ! ((Manganese! I I1 Mercury I 1 1(Nickel 1 ||(Potassium! I 11 Selenium I 1 11 Silver ! - III Sodium | | I(Thallium I 1 1(Vanadium 1 1 11 Zinc 1 1 11 I II
.. .
at er element
Contract :SAS No. :
Date:
Correction
SD<•
Factors fo:
I I I N I
3 No. :
r:
^Bpr
Comments:
FORM XII (PART 2) - IN 7/87
flR30069I
Comments:
U.S. EPA - CLP
13ICP LINEAR RANGES (QUARTERLY?
! Lab Name: __________ • Contract:
j Lab Code: • Case No.: ____ SAS No.: _____ SDG No.
* ICP ID Number: - Date:
I I Integ. | |! . . | Time J Concentration j(Analyte | (Sec.) ( (ug/L) | M1 , I ______ I __________ f_I Aluminum |
_I Barium IBeryllium!
; Cadmium_ _ |Calcium _ |Chromium_ |Cobalt __ |Copper __ |Iron ___ (Lead i(Magnesium)(Manganese!|Mercury_J(Nickel f|Potassium|{Selenium |
_ISodium __ |IThallium || Vanadium"!
!
; flR300692I FORM XIII - IK 7/87
1A EPA SAMPLE NO,VOLATILE ORGANICS ANALYSIS DATA SHEET ____________
II
Lab Name: _____ Contract:________ |____
Lat> Code: _____ Case No.: . SAS No.: ______ SDG No.:•"' "' —— — -— _ . " .Matrix: (soil/water)____ Lab Sample ID: __
Sample wt/vol: _____(g/fflL)___ Lab. File ID: __
Level: (low/med) ____ Date Received: __
% Moisture: not dec.____ Date Analyzed: __
i Column: (pack/cap) ____ Dilution Factor:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg)_____
I74-87-3———————Chloromethane__74-33-9———————Bromomethane__75-01-4——————Vinyl Chloride^75-00-3——————Chloroethane75-09-2——————Methylene Chloride,67-64-1——————Acetone75-15-0——————-Carbon Disulfide_________75-35-4———————1,1-Dichloroethene________75-34-3———————1,1-Dichloroethane________540-59-0——————1,2-Dichloroethene (total)_67-66-3———————Chloroform107-06-2—————l,2-Dichloroethane_78-93-3———————2-Butanone71-55-6———————1,1 r l-Trichloroethane_56-23-5——————-Carbon Tetrachloride_^108-05-4—————-Vinyl Acetate75-27-4——————Bromodichloromethane78-87-5———————1,2-Dichloropropane10061-01-5————cis-l,3-Dichloropropene_79-01-6——————-Trichloroethene124-48-1—————-Dibromochloromethane_79-00-5—————l,l,2-Trichloroethane_71-43-2———-——Benzene10061-02-6———~trans-l,3-Dichloropropene_75-25-2——————Bromoform108-10-1——————4-Methyl-2-Pentanone____591-78-6—————2-Hexanone____________127-18-4——————Tetrachloroethene______79-34-5———————l,l/2/2-Tetrachloroethane-108-88-3—————Toluene108-90-7——————Chlorobenzene_100-41-4—————'Ethylbenzene_J100-42-5—————styrene1330-20-7—————Xylene (total)
FORM I VOA 1/87 Rev,
flR300693
"IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
_ La
Ra
Lab Name: Contract:
Code: Case No.: SAS No.: SDG No.:
» Matrix: (soil/water)____ Lab Sample ID:
f Sample wt/vol: _____(g/n»L)___ Lab File ID:
Level: (low/med) ___ Date Received:
» % Moisture: not dec.____ dec.____ Date Extracted:I ———— ————Extraction: (SepF/Cont/Sonc) ___ Date Analyzed:
GPC Cleanup: (Y/N)__ pH:___ Dilution Factor:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg)______
108-95-2——————Phenol_______________111-44-4——————bis(2-Chloroethyl)ether_95-57-8————————2-Chlorophenol541-73-1——————l,3-Dichlorobenzene_106-46-7——————1,4-Dichlorobenzene"100-51-6——————Benzyl alcohol95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol108-60-1——————bis(2-Chloroisopropyl)ether106-44-5——————4-Methylphenol621-64-7——————N-Nitroso-di-n-propylamzne_j67-72-1———————Hexachl or oe thane_________|98-95-3——————Nitrobenzene____________|78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0——————-Benzoic acid111-91-1—————bis (2-Chloroethoxy) methane^120-83-2——-—~2,4-Dichlorophenol_120-82-1—————1,2 f 4-Trichlorobenzene91-20-3——————Naphthalene,106-47-8——-——4-Chloroaniline87-68-3—————-Hexachlorobutadiene___59-50-7—————4-Chloro-3-nethylphenol91-57-6———————2-Methylnaphthalene77-47-4——————Hexachlorocyclopentadiene_ga-06-2—————-2 f 4,6-Trichlorophenol__"95-95-4——————2,4,5-Trichlorophenol___91-58-7——————2-Chloronaphthalene____88-74-4——————2-Nitroaniline131-11-3——————Dimethylphthalate,208-96-8—————-Acenaphthylene606-20-2——————2,6-Dinitrotoluene
FORM I SV-1 1/87 Rev,
1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________
II
Lab Name: Contract: . I
Lab Code: _______ Case No.: _____ SAS No.: ... SDG No.:
Matrix: (soil/water)____ Lab Sample ID: __
Sample wt/vol: _____(g/*L)___ Lab File ID: __
Level: (low/med) ____ Date Received: __
% Moisture: not dec. dec. Date Extracted:
Extraction: (SepF/Cont/Sonc) ____ Date Analyzed:
GPC Cleanup: (Y/N)__ pH:___ Dilution Factor:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg)_____
99-09-2 ——————— 3-Nitroaniline83-3 2-9 —————— Acenaphthene51-28-5 ——————— 2 , 4-Dinitrophenol100-02-7 —————— 4-Nitrophenol132-64-9 —————— Dibenzofuran121-14-2 —————— 2,4-Dinitrotoluene84-66-2 —————— -Piethylphthalate7005-72-3 ————— 4-Chlorophenyl-phenylether _
100-01-6 —————— 4-Hitroaniline534-52-1 —————— 4 , 6-Dinitro-2-methylphenol86-30-6 ——————— N-Nitro»odiphenylamine (1) _101-55-3 —————— 4-Bromophenyl-phenylether118-74-1 —————— Hexachlorobenzene87-86-5 —————— Pentachlorophenol
120-12-7 —————— Anthracene84-74-2 —————— Di-n-butylphthalate206-44-0 —— • — —— Fluoranthene129-00-0 ————— Fyrene85-68-7 ——— — —— Butylbenzylphthalate91-94-l——f- — -S.S'-Dichlorobenzidine56-55-3 — • ———— Benzo (a) anthracene218-01-9 —————— Chrysene117-81-7 —————— bis (2-Ethyih.xyl) phthalat.117-84-0 —————— Di-n-octylphthalate205-99-2 ————— Benzo (b)fluoranthene207-08-9 —————— Benzo (k) f luoranthene50-32-8 —————— Benzo(a)pyrene193-39-5 —————— Indeno (1,2, 3-cd) pyrene53-70-3 ——————— Dibenz (a,h) anthracene191-24-2 —————— Benzo (g,h,i)perylene
111111111111111111111111I1
' 1111111i
(1) - Cannot be separated from Diphenylamine
FORM I SV-2 1/87 Rev,
UR300695
, ID . . . „ , _.._,..-=. EPA SAMPLEPESTICIDE ORGANICS ANALYSIS DATA SHEET
kLab Name: __ _____ Contract
Lab Code: ______ Case No.: _____ SAS No.: ______ SDG No.:
Matrix: (soil/water)____ Lab Sample ID: __
Sample wt/vol: _____(g/mL)___ Lab File ID: __
Level: (low/med) ____ Date Received: __
% Moisture: not dec.____ dec.____ Date Extracted:
Extraction: (SepF/Cont/Sonc) ____ Date Analyzed:
GPC Cleanup: (Y/N)__ pH:___ Dilution Factor:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg)______
319-84-6———————alpha-BHC_________319-85-7———————beta-BHC_______319-86-8———————delta-BHC _____58-89-9———-———gamma-BHC (Lindane)76-44-8——————Heptachlor_______'309-00-2——————Aldrin1024-57-3—————Heptachlor epoxide959-98-8—————Endosulfan I____~60-57-1——————Dieldrin_____72-55-9————————4,4 '-DDE__________72-20-8——————Endrin33213-65-9————Endosulfan II72-54-8————————4,4'-ODD1031-07-8—————Endosulfan sulfate50-29-3————————4 , 4 ' -DOT________"72-43-5——————Methoxychlor__53494-70-5————Endrin ketone_5103-71-9——»——alpha-Chlordane_5103-74-2—————gamma-Chlordane~8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2—————Aroclor-122l"11141-16-5—————Aroclor-1232"53469-21-9—————Aroclor-1242"12672-29-6—————Aroclor-1248~11097-69-1—————Aroclor-125411096-82-5—————Aroclor-1260"
FORM I PEST 1/87 Rev.'. /1R300S96
IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _______________TENTATIVELY IDENTIFIED COMPOUNDS |"
ILab Name: _______________ Contract:__________ |_____
Lab Code: ____._ Case No.: ____ SAS No,: _____ SDG No.:
Matrix: (soil/water)____ Lab Sample ID: __
Sample wt/vol: _____(g/fflL)___ Lab File ID: __
Level: (low/med) ____ Date Received: __
% Moisture: not dec.____ Date Analyzed: __
Column: (pack/cap) ____ Dilution Factor:
CONCENTRATION UNITS:Number TICs found: _____ (ug/L or ug/Kg)____
!GAS NUMBER | COMPOUND NAME
1. 12. 13. 14. 15. 16. 17. 18. 19. 110. |11. 112. I13. 114. 115. 116. |17. 113. I19. 120. 121. I22. I23. |24. I25. |26. I27. |28. |29. |30. |
1
RT EST. CONC.•»»•••;— -B» -— = 3B*»»—B — -m
,
Q
W—41
_ mFORM I VOA-TIC 1/87 Rev.
BR30Q697
PLa
1 IF EPA SAMP!_£ NOSEMXVOIATILE ORGANICS ANALYSIS DATA SHEET ______________
TENTATIVELY IDENTIFIED COMPOUNDS | '< I
Lab Name: __ ______ Contract:___._____ |_____
b Code: Case No.: _____ SAS No.: ____ SDG No.:! —————————" ' ——————— ' I ————————
' Matrix: (soil/water)____ Lab Sample ID: __
j Sample wt/vol: _____(g/mL)___ Lab File ID: __
Level: (low/med) ____ Date Received: __
I % Moisture: not dec.____ dec.____ Date Extracted:__s •• —— - - - — _ "Extraction: (SepF/Cont/Sonc) ____ Date Analyzed: __
' GPC Cleanup: (Y/N)__ pH:___ Dilution Factor:
1 CONCENTRATION UNITS:Number TICs found: ____ (ug/L or ug/Kg)_____
CAS NUMBER
1.2.3.
f 5:6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.
|30.'
1COMPOUND NAME | RT
1111111111111111111111111111111
EST. CONC.
'
Q
FORM I SV-TIC 1/87 Rev.i AR3Q0698
2AWATER VOLATILE SURROGATE RECOVERY
Lab Name: ... ;______________ Contract:iLab Code: _____ Case No.: _____ SAS No.: ______ SDG No.:
| 010203!
I 04]* 05|
06|07|
? 08109 |10|
f "I-f 12|
131! "iI 15|
16|17 |
f 18119120 |
i 21|1 22|
23|] 24!f 25|
26|77 iI *' I28|,
1 29'301
EPASAMPLE NO.
SI(TOL) #
S2(BFB) 1
S3(DCE) *
OTHER TOTOUT
QC LIMITSSl'(TOL) « Toluene-d8 (88-110)S2 (BFB) - Bromofluorobenzene (86-115)S3 (DCS) « l,2-Dichloroethane-d4 (76-114)
I Column to be used to flag recovery values *
* Values outside of contract required QC limits
D Surrogates diluted out
page _ of _FORM II VOA-1 1/87 Rev.
flR30Q699
Lab Name: _______________ Contract,:
fLab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Level:(low/med) ____
Oil02 |03|04|05 |06 |07 |08 |09 i10|HI12 |
17 |18|19120|21|22|23|24 i25126|27j28!29j30
EPA | SISAMPLE NO. | (TOL)#
aB-S-Bac gatag-gss-s -s j ae»=:z=«
111111111111111111111111111
- 111
S2 | S3(BFB)#| (DCE)#
1111|11111111111111I1111111111
OTHER
3SSSS=3S_3
TOTOUT
' QC LIMITSSI (TOL) » Toluene-d8 (81-117)S2 (BFB) - Bromofluorobenzene (74-121)S3 (DCE) « l,2-Dichloroethane-d4 (70-121)
# Column to be used to flag recovery values '
* Values outside of contract required QC limits
D Surrogates diluted out
page ofFORM II VOA-2 1/87 Rev,
AR3007QQ
2CWATER SEMIVOLATILE SURROGATE RECOVERY
Lab Name: ___ _______ Contract:
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
i
| EPA | SI| SAMPLE NO. | (NBZ)#
Oil 1021 103! 1041 1051 !061 1071 I081 !091 I101 |111 1121 I131 1141 I151 I16| |17! I181 |191 1201 |211 I22| |23| I241 I251 I261 I271 I281 I291 I301 I
S2(FBP) *
S3(TPH) |
S4(PHL)#
S5(2FP)#
S6(TBP) f
OTHER TOTOUT
1
111
^
QC LIMITSSI (NBZ) * Nitrobenzene-d5 (35-114)S2 (FBP) - 2-Fluorobiphenyl (43-116)S3 (TPH) » Terphenyl-dl4 (33-141)S4 (PHL) « Phenol-d5 (10-94) .S5 (2FP) * 2-Fluorophenol (21-100) '36 (TBP) * 2,4,6-Tribromophenol (10-123)
# Column to be used to. flag recovery values* Values outside of contract required QC limitsD Surrogates diluted out
pag© _ of _FORM II SV-1 1/87 Rev.
flR30Q7Qj
*2ff * 'SOIL SEMIVOLATILE SURROGATE RECOVERY"
Lab Name: __ ____ Contract:
FLab Code: _______ Case No.: _____ SAS No.: ______ SDG NoI , ' ; '1 Level:(low/med)____
1I-
oil
EPA | SI | S2 | S3 | S4 | S5SAMPLE NO. | (NBZ)f | (FBP)#| (TPH)f | (PHL)#| (2FP) *
1 I 1 1 1
1 1 1 1 1021 1 1 1 1 1031 1 1 1 1 1041 1 1 1 1 10 5 1 I I I I . I061 1 1 1 1 1071 1 1 1 1 1081 1 1 1 1 1091 1 1 1 1 1101 1 1 1 1 1HI 1 1 1 1 1121 1 I 1 1 1131 1 1 1 1 1141 1 1 1 1 1151 1 1 1 1 1161 1 1 1 I 1171 1 1 1 1 1181 1 1 1 1 1191 1 1 1 1 120| 1 1 1 1 1211 1 1 1 1 1221 1 1 1 1 123|_ 1 1 1 1 1241 1 1 1 1 125f -1- 1 1 1 12 6 1 . 1 1 1 127 L 1 1 1 1 1281 1 1 1 1 12 9 1 I I 1 1 130|_ 1 1 1 1 1
S6 | OTHER |TOT(TBP) # j | OUT==- — | ==____ | _ —
1 11 11 11 11 11 11 11 11 1
1 11 11 11 11 11 11 11 11 11 11 11 1! 11 11 11 11 11 11 11 1
QC LIMITSSI (NBZ) Nitrobenzene-d5 (23-120)S3 (FBP) 2-Fluorobiphenyl (30-115)S3 (TPH) Terphenyl-dl4 (18-137)S4 (PHL) Phenol-d5 (24-113) ,S5 (2FP) 2-Fluorophenol (25-121) 'S6 (TBP) 2,4,6-Tribromophenol (19-122)
f Column to be used to. flag recovery values* Values outside of contract required QC limitsD Surrogates diluted out
page _ of _ _ _ _ _ _ . .FORM II SV-2 1/87 Rev.
flR300702
2EWATER PESTICIDE SURROGATE RECOVERY
Lab Name: _________________ Contract:
Lab Code: ___ Case No.: ____ SAS No.: .. .._.. SDG No,
| EPA| SAMPLE NO.)______»»
Oil02103104!05|06|07|OS!09|10111112113114|15|16|17118119120|21122123|24125126127|28129|301
SI(DBC) *
.
OTHER
W, "f BBia*! ^
ADVISORYQC LIMITS
SI (DBC) - Dibutylchlorendate (24-154)
# Column used to flag recovery values
* Values outside of QC limitsD Surrogates diluted out
page _ of _FORM II PEST-1 1/87 Rev.
flR30Q7Q3
2FSOIL PESTICIDE SURROGATE RECOVERY
Lab Name: ________________ Contract:__
ib Code: ______ Case No.: _____ SAS .Mp..:....,_____ SDG No,
Level:(low/med)____
| EPA| SAMPLE NO.»«a3 ========
on02103104105|06|07|08|09|10|11112113114115|16|17118119120|21122)23124125126127|28|291301
SI(DBC)#K3S3B:-5S
OTHER
JK B Bgj J,. Ji
ADVISORYQC LIMITS
SI (DBC) - Dibutylchlorendate (20-150)
I Column to be used to flag recovery values,i* Values outside of QC limits
D Surrogates diluted out
page _ of _FORM II PEST-2 1/87 Rev.
1 flR30Q7Qtf
3AWATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
l b Name:
[Lab Code: Case No.:
Matrix Spike - EPA Sample No*:
I SPIKE| ADDED
COMPOUND i (ug/L)
1 , 1-Dichloroethene 1Trichloroethene 1Benzene 1Toluene |Chlorobenzene I
1
Contract: ^
SAS No.: SDG No_: ^^
SAMPLE | MS | MS | QCCONCENTRATION | CONCENTRATION | % | LIMITS
(ug/L) | (ug/L) | REC #| REC.
1 _ 1 161-145I t 171-1201 I 176-1271 1 176-1251 1 175-1301 1 1
11COMPOUND |
1 , 1-Dichloroethene ITrichloroethene |Benzene |Toluene |Chlorobenzene 1
1
SPIKEADDED(ug/L)
MSD |CONCENTRATION |
(ug/L) |
111111
MSD*
REC i
i•
1
1 ^% | QC LIMITSRPD f| RPD | REC.
I 14 161-145!I 14 171-1201I 11 176-127]I 13 176-1251I 13 175-13011 1 1
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD:____ out of ____ outside limitsSpike Recovery:____ out of ____ outside limits
COMMENTS:
FORM III VOA-1 1/87 Rev,
AR300705 ,
, 3BSOIL VOLATILE MATRIX .SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: ___ _____ Contract; _,... .-
FLab Code: ____ Case No.: _____ SAS No.: ______ SDG No,. —•'•' -—-— i "Matrix Spike - EPA Sample No.: _________ Level:(low/med)
COMPOUND
1, 1-DichloroetheneTr i chl or oe theneBenzeneTolueneChlorobenzene
1 SPIKE| ADDED1 (ug/Kg)
« _ii!111
| SAMPLE| CONCENTRATION1 (ug/Kg)
111111
MSCONCENTRATION
(ug/Kg).-.« ——— _^____
MS | QC% i LIMITS
REC #| REC.
159-172162-137166-142159-139160-1331
| SPIKE | MSD 1 MSD | || ADDED | CONCENTRATION | % | % | QC L:
COMPOUND | (ug/Kg) | (ug/Kg) | REC #| RPD #| RPDS— =___= 3 — -* ——— ==« | =S_
1, 1-Dichloroethene |Trichloroethene jBenzene |Toluene |Chlorobenzene |
1 1 | | 221 i | | 241 | | | 21( I i ! 211 I i I 21
1 1 i l l
CMITSREC.
59-17262-13766-142:59-139160-133!
i
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD:____ out of ____ outside limitsSpike Recovery:____ out of ____ outside limits
COMMENTS:
FORM III VOA-2 1/87 Rev,
. ! 5R3007Q6
3CWATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: _______________ Contract:_________
Lab Code: _______ Case No.: _____ SAS No.: ______ SDG No.:
Matrix Spike - EPA Sample No.:
COMPOUNDaimm-K-BxacK mac m a:»3B3E=35ss = .Essssssm
Phenol2-Chlorophenol1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2 , 4-DinitrotoluenePentachlorophenolPyrene
SPIKE | SAMPLEADDED | CONCENTRATION(ug/L) | (ug/L)
i1111!!111I1
MS | MS | QCCONCENTRATION | % | LIMITS
(ug/L) | REC #| REC.
1 112- 89;! 127-12311 136- 97!1 141-116'I [39- 98!I 123- 97;I 146-1181I 110- 801I 124- 96I | 9-103I 126-1271 I
COMPOUND
Phenol2-Chlorophenol1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2 , 4-DinitrotoluenePentachlorophenolPyrene
SPIKEADDED(ug/L)
MSDCONCENTRATION
(ug/L)
MSD |* 1 %
REC #| RPD #
111111111111
QC LRPD
4240233828423150385031
IMI_y i| REC. 1i|12- 89127-123-|36- 97!| 41-116139- 98!|23- 97(146-1181|10- 80)|24- 96|| 9-103||26-127|1 1
(1)' N-Nitroso-di-n-propylaaine
# Column to be used to flag recovery and RPD values with an* asterisk* Values outside of QC limits
RPD:____ out of _____ outside limitsSpike Recovery:____ out of ____ outside limits
COMMENTS:
FORM III SV-1 1/87 Rev,
fiR300707
3DSOIL SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: ____ Contract:
FLab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Matrix Spike - EPA Sample No.: _________ Level:(low/med) _
COMPOUND
Phenol2 -Chlorophenol1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2 , 4-DinitrotoluenePentachlorophenolPyrene
SPIKEADDED(ug/Kg)
SAMPLECONCENTRATION
(ug/Kg)MS | MS | QC
CONCENTRATION | % | LIMITS(ug/Kg) | REC ft REC.
! 126- 9C1 [25-1021 [28-104i [41-1261 138-107I 126-1031 131-1371 t 11-1141 128- 89I 117-109I 135-142i !
1 SPIKEj ADDED
COMPOUND | (ug/Kg)
Phenol j2 -Chl orophenol I1 , 4-Dichlorobenzene |N-Nitroso-di-n-prop. (i) I1,2, 4-Trichlorobenzene 14-Chloro-3-methylphenol jAcenaphthene I4-Nitrophenol 12 , 4-Dinitrotoluene IPentachlorophenol jPyrene I
i
MSD | MSDCONCENTRATION | *
(ug/Kg) | REC *
111111111111
1% 1 QC
RPD #| RPD_ j
1 35I 501 27i 381 23I 331 19! 501 47i 471 36i
LIMITS| REC.
-I——— -|26- 90125-102128-104141-126138-107126-103131-137111-114|28- 89117-109[35-142!
(1) N-Nitroso-di-n-propylamineI Column to be used to flag recovery and RPD values with an. asterisk* Values outside of QC limits
RPD:_____ out of _____ outside limitsSpike Recovery:____ out of ____ outside limits
COMMENTS:
FORM III SV-2 1/87 Rev.
' fl~R3Q07Q8
3EWATER PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: _______________ Contract:________
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Matrix Spike - EPA Sample No.: _________
COMPOUND
Lindane
I SPIKE| ADDED
- 1 (ug/L)
1
| SAMPLE| CONCENTRATION1 (ug/L)
1Heptachlor 1 |Aldrin i |Dieldrin 1 1Endrin 1 I4,4' DDT ( |
i 1
MSCONCENTRATION
(ug/L)
MS |% 1
REC #|
i111111
QCLIMITSREC.
56-12340-13140-12052-12656-12138-127
11| COMPOUND
I Lindanej HeptachlorI Aldrinj DieldrinI EndrinI 4,4' DDT
-
SPIKEADDED(ug/L)
mmssssaESSEm
MSDCONCENTRATION
(ug/L)X-xm-KSasssss-KataBS
MSD%
REC i
i ^% | QC LIMITS
RPD #| RPD 1 REC.
i 15 156-123I 20 140-131| 22 140-120i 18 152-126I 21 156-121| 27 |38-1271 1
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC Units
RPD:_____ out of ____ outside limitsSpike Recovery:____ out of ____ outside limits
COMMENTS:
FORM III PEST-1 1/87 Rev,
4R300709
3F . , .-. .=SOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: Contract:
,b Code: _______ Case No.: _____ SAS No.: ______ SDG No.:
Matrix Spike - EPA Sample No.: _________ Level:(low/med) _
COMPOUND
LindaneHeptachlorAldrinDieldrinEndrin4,4' DDT
SPIKEADDED(ug/Kg)
| SAMPLE1 CONCENTRATION1 (ug/Kg)j :B=SS==SS-5=.:===:3==5S
1111111
i MS| CONCENTRATION1 (ug/Kg)
1111111
MS | QC% | LIMITS
REC #| REC.—————————— 1 ——— - —————
[46-127135-130134-132131-134142-139123-134I
\COMPOUND
LindaneHeptachlorAldrinDieldrinEndrin4,4' DDT
I SPIKE| ADDEDt (ug/Kg)
iiiiiii
MSDCONCENTRATION
(ug/Kg)
MSD | |% 1 % 1
REC f| RPD If-.•-.•-at | ==_3 —— [ =
I 1I 11 11 1I 11 !1 1
QCRPD
503143384550
LIMITS| REC.
146-127135-130134-132131-134142-139123-134!
f Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC liaits
RPD:____ out of ____ outside limitsSpike Recovery:____ out of ____ outside limits
i
COMMENTS:
FORM III PEST-2 1/87 Rev.
4AVOLATILE METHOD BLANK SUMMARY
Lab Name: ______________ Contract:
Lab Code: _______ Case No.: _____ SAS No.: ______ SDG No.:
Lab File ID: ___________ Lab Sample ID: __
Date Analyzed: ________ Time Analyzed:
Matrix: (soil/water) ____ Level:(low/med)
Instrument ID:
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD;
| EPA | LAB| SAMPLE NO. | SAMPLE ID
Oil I021 !031 |04| |051 |06| |07| |081 |091 |10! |HI 112| |131 |141 |15 1 |16 j ' - 1171 |18! 1191 I20! I211 |221 I231 |241 |25| |26| }271 |28| |29 1 130| |
LABFILE ID
'
TIMEANALYZED
.
,
•
- - ....... ^COMMENTS:
page _ of _FORM IV VOA 1/87 Rev.
4R30071 i
4BSEMIVOLATILE. .METHOD BLANK SUMMARY
Lab Name: Contract.:
>Lab Code: _______ Case No. : ; SAS No. ; SDG No.:
Lab File ID: ___________ _ . _„ Lab Sample ID: __
Date Extracted: _______ Extraction:(SepF/Cont/Sonc)
1 Date Analyzed: ________ Time Analyzed: __
Matrix: (soil/water) ____ Level:(low/med) __
Instrument ID: _______, - iTHIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:
I EPA j LAB j LAB j DATE |I SAMPLE NO. I SAMPLE ID I FILE ID | ANALYZED I
01!02|03|04|05|.06|07|.08|09 |'101;111.12113|.14115|."I.17 I.18|."I.20|211.'22 |231;24|.25|.26|.27|.28 |29 |30|.
COMMENTS:
page _ of _FORM IV SV 1/87 Rev.
flR3007i2
4CPESTICIDE METHOD BLANK SUMMARY
Lab Name: ________________ Contract:
Lab Code: _______ Case No.: _____ SAS No.: ,......._ SDG No.:
Lab Sample ID: ___________ Lab File ID: _____
Matrix:(soil/water) ____ Level:(low/med) ____
Date Extracted: _______ Extraction: (SepF/Cont/Sonc)
Date Analyzed (1): _______ Date Analyzed (2): ___
Time Analyzed (1): ________ Time Analyzed (2): ____
Instrument ID (1): ________ Instrument ID (2): ____
GC Column ID (1): ________ GC Column ID (2): ____
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:
| EPA I LAB| SAMPLE NO. | SAMPLE ID
Oil 1021 1031 1041 |05| |061 107| 108| |091 1101 I111 1121 I131 I14! I151 I161 I171 I181 I191 1201 I211 I221 I23| |24! I25! 126! 1
DATEANALYZED 1
DATEANALYZED 2n sss-aesssKac:
COMMENTS:
of _ /FORM IV PEST 1/87 Rev,
flR300713
5AVOIATILE ORGANIC GC/MS TUNING AND MASSCALIBRATION - BROMOFLUOROBENZENE (BFB)
Lab Name: ___ _______ Contract: ...
,b Code: ______ Case No.: ____ SAS No.; SDG No.:
Lab File ID: ___________ BFB Injection Date:_
Instrument ID: ______• BFB .Injection Time:
Matrix:(soil/water) ____ Level:(low/med) ____ Column:(pack/cap) ___
| j j % RELATIVE| m/e I ION ABUNDANCE CRITERIA I ABUNDANCE
50 | 15.0 - 40.0% of mass 95________75 I 30.0 - 60,0% of mass 95__________95 j Base peak, 100% relative abundance96 I 5.0 - 9.0% of mass 95173 | Less than 2.0% of mass 174_____________________|____( )ij174 | Greater than 50.0% of mass 95________________________I___________I175 I 5.0 - 9.0% of mass 174________________________|____( )l|176 | Greater than 95.0%, but less than 101.0% of mass 174|____( )1|177 | 5.0-9.0% Of mass 176__________________________I_____( }2|___I_______,___________________________________I___________I
1-Value is % mass 174 2-Value is % mass 176
IS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
| E P A j L A B j L A B j D A T E j T I M E || SAMPLE NO. | SAMPLE ID | FILE ID | ANALYZED | ANALYZED |
Oil__________I____________I____________i_________|________I02|__________|_________I____________I________I________I03|__________|__________I__________I_________I________I04|__________|_________I__________I_________I________I05|__________|____________|____________|_________|________|06|__________|__________|___________I ________I________I07|________I____________I____________I.________I_______I08|__________|________I________I______\_______I09|__________|____________|__________I ________\_________I10|__________I_________I________I.________I________IHI_______I__________I____________I.________I________I12)__________I_________I____________I.________I_______\13|__________|____________|___________I.______I________\14|__________|_________I____________I._______I________I15|__________|____________I___________l_________I________I16|_________I____________I____________I_________I_______\17|__________|__________I________I_________I________I18|__________|____________|___________I_________I________I191________I_________I____________I_________I________I20|________I____________I____________I_________I________I211__________|____________|____________I_________I______I22|_________I____________|__________I_________I________I
page _ of _FORM V VOA 1/87 Rev.
flR3007lt.
5BSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS
CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name: _______ ________ Contract:______
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Lab File ID: ___________ DFTPP Injection Date:
Instrument ID: _______ DFTPP Injection Time:
m/emaca=.=K
5168697012719719819927536544144*2443
ION ABUNDANCE CRITERIA
30.0 - 60.0% of mass 198Less than 2.0% of mass 69Mass 69 relative abundanceLess than 2.0% of mass 6940.0 - 60.0% of mass 198Less than 1.0% of mass 198Base Peak, 100% relative abundance5*0 to 9*0% of mass 19810.0 - 30.0% of mass 198Greater than 1.00% of mass 198Present , but less than mass 443Greater than 40.0% of mass 19817.0 - 23.0% of mass 442
% RELATIVEABUNDANCE
( )1
( )1
( )2
1-Value is % mass 69 2-Value is % mass 442
THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARD?
| EPA | LAB| SAMPLE NO. | SAMPLE ID
Oil I021 I031 1041 |051 106| |071 |081 I09! 1101 111! 1121 |131 I141 I151 |161 |171 |181 I191 1201 |211 !221 |
LABFILE ID
DATEANALYZED
TIMEANALYZED
page _ ofFORM V SV 1/87 Rev
6R300715
6AVOLATILE ORGANICS INITIAL CALIBRATION DATA
Lab Name: ________________ Contract:
b Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Instrument ID: _______ Calibration Date(s):_______
Matrix:(soil/water) ____ Level:(low/med) ___ Column:(pack/cap)
Min RRF for SPCC(#) - 0.300 (0.250 for Bromoform) Max %RSD for CCC(*) » 30.0%
|LAB FILE I D : R R F 2 0 » R R F 5 0 « |JRRF100- RRF150- RRF200- I11 1| COMPOUND IRRF20
! Chloromethane #i Bromomethane 1! Vinyl Chloride *! Chloroethane 1IMethylene Chloride Ij Acetone 1| Carbon Disulfide j| 1 , 1-Dichloroethene *1 1 , 1-Dichloroethane I| 1,2-Dichloroethene (total) |jChloroform *•1,2-Dichloroethane IT2-Butanone Ij 1 , 1 , 1-Trichloroethane |I Carbon Tetrachloride j1 Vinyl Acetate i1 Bromodichloromethane fi 1, 2-Dichloropropane *1 cis-1, 3-Dichloropropene i[ Trichloroethene II Dibromochloromethane j1 1, l, 2-Trichloroethane Ii Benzene 1j trans-l , 3-Dichloropropene !j Bromoform ff 4-Methyl-2-Pentanone 11 2-Hexanone Ii Tetrachloroethene f11,1,2, 2-Tetrachloroethane f! Toluene *i Chlorobenzene f[ Ethylbenzene *I Styrene |IXylene (total) I
IToluene-dS Iteromofluorobenzene 1ifl , 2 -Dichloroethane-d4 |1 1
RRF50 RRF100 RRF150 RRF200
'
RRF% 1
RSD |
#|*It
1**1*iiiiii*i!II11f11I#*f*11
111!
FORM VI VOA 1/87 Rev.
flR3007i6
6BSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA
Lab Name: _____ Contract:
Lab Code: ______ Case No,: ____ SAS No,: _____ SDG No.:
Instrument ID: ________ Calibration Date(s):________
Min 5SF for SPCC(f) » 0,050 " Max %RSD for CCC(*) = 30.0.
ILAB FILE ID: RRF20 -[RRF80 - RRF120-11 1| COMPOUND IRRF20| «_isss-S-«-«»M.3«JBsae:a::saB=3.«aB3a3B:s=3£==:e65£ 1 ssss=:===
1 Phenol *i bis (2-Chloroethyl) ether 11 2-Chlorophenol 11 1,3-Dichlorobenzene . j| 1 , 4-Dichlorobenzene *1 Benzyl alcohol !1,2-Dichlorobenzene j|2-Methylphenol i| bis (2-Chloroisopropyl) ether ||4-Methylph«nol I| N-Nitroso-di-n-propylamine #1 Hexachloroethane INitrobenzene I
! Isophorone I1 2-Nitrophenol *2 , 4-Dimethylphenol 1Benzole acid jbis (2-Chloroethoxy) methane 1
1 2 , 4-Dichlorophenol *[1,2, 4-Trichlorobenzene I1 Naphthalene I4-Chloroaniline 1
l Hexachlorobutadiene *4-Chloro-3-methylphenol *2-Methylnaphthalene IHexachlorocyclopentadiene t2,4, 6-Trichlorophenol *2,4, 5-Trichlorophenol 1
I 2 -Chloronaphthalene 1[2-Nitroaniline I[ Dimethylphthalate 1I Acenaphthylene I1 2 , 6-Dinitrotoluene 1|3-Nitroaniline 1! Acenaphthene *2 , 4-Dinitrophenol f
I 4-Nitrophenol I1 1
RRF50
RRF5(RRFK
RRF80
) »50-
RRF120 RRF160J3-«-S-3SS==
"
RRF=-SS = 3= =
%
RSDss: = == j
*
1
!1*iiiii*i*iii*iii**If*iiiiiii**#
FORM VI SV-1 1/87 Rev,
flR300717
6CSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA
Lab Name: ____ ______ Contract:________
Lab Code: ______'m Case No.: _. SAS No, : ______ SDG No.:
Instrument ID: _____ Calibration Date(s):_______
Min RRF for SPCC(i) » 0.050 . . . . . . Max %RSD for CCC(*) « 30.0'-
LAB FILE ID: RRF20RRF80 « RRF12C
COMPOUND
Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenol_N-Nitrosodiphenylamine ( 1 ) *4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenol 'PhenanthreneAnthraceneDi-n-butylphthalateFluoranthene 'PyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2 -Ethylhexyl ) phthalateDi-n-octylphthalate ^Benzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyrene <Indeno (1,2, 3-cd) pyreneDibenz .a,h) anthraceneBenzo (a, h . i) perylene
Nitrobenzene-dS2-FluorobiphenylTerphenyl-dl4Phenol-d52 -Fluorophenol2,4, 6-Tribromophenol
-)«
RRF20SSS== -=
fe
k
k
k
1
RRF50;xs:ssss-3
EaBsacaauM
RRF5CRRFK
RRF80SB-B3K-S-«=«
) -50-
I.RF120 RRF1603ES=:s::-==
«.e:=:=:s:ss:s
RRF%RSD
i
.
1
ll
1
i
*
it
-ST-EJS-SSS
11
1 (1) Cannot be separated from Diphenylamine
FORM VI SV-2 1/87 Rev.
flR3007J8
Lab Name: _ _____ Contract:
Lab Code: _______ Case No.: _____ SAS No.: ______ SDG No.:
Instrument ID: ___ Calibration Date: Time:
Lab File ID: ___________ Init. Calib. Date(s):
Matrix:(soil/water) ____Level:(low/med) ___Column:(pack/cap)
Min RRF50 for SPCC(jf) - 0.300 (0.250 for Bromoform) Max %D for CCC(*) » 25.0%
I1 COMPOUND
j Chloromethane :] Bromomethane1 Vinyl Chloride .j ChloroethaneIMethylene Chloridej Acetone(Carbon Disulfide1 1 , 1-Dichloroethene *j 1 , 1-Dichloroethane =jl,2-Dichloroethene (total)[ Chloroform -j 1, 2-Dichloroethane|2-Butanone| 1 , 1 , 1-Trichloroethanej Carbon Tetrachloride] Vinyl AcetateI Bromodichloromethanej 1, 2-Dichloropropane *i cis-1, 3-Dichloropropene[ Trichloroethenej Dibromochloromethanejl,l, 2-Trichloroethane1 Benzene| trans-1, 3-DichloropropeneI Bromof orm •I 4-Methyi-2-Pentanone12-Hexanone1 Tetrachloroethene[1,1,2, 2-Tetrachloroethane .j Toluene *I Chlorobenzene •| Ethylbenzene i\ StyreneIXylene (total)
| Toluene-d8j Bromof luorobenzenej l,2-Dichloroethane-d4I
RRF
t
k
k'
k
r
••
•k
't
==_SB3t»=a
RRF501
%D |*^ 1
*
!*iiii*ii*iiiiii*iiiiii§iii£
*
#*
1
1SKK3S=S 1
1111
FORM VII VOA 1/87 Rev.
flR3007i9
7BSEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: Contract;
ib Code: ______ Case No.: ____ SAS No,: _____ SDG No.:
Instrument ID: ____ Calibration Date: Time:
Lab File ID: __________ Init. Calib. Date(s):
Min RRF50 for SPCC(#) • 0.050 Max %D for CCC(*) * 25.0%
COMPOUND
Phenolbis (2-Chloroethyl) ether2 -Chl orophenol1, 3-Dichlorobenzene1, 4-DichlorobenzeneBenzyl alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-Chloroisopropyl)ether4 -Methy IphenolN-Nitroso-di-n-propylamineHexachloroe thaneNitrobenzeneIsophorone2-Nitrophenol *2 , 4 -Dime thy IphenolBenzoic acidbis (2-Chloroethoxy) methane2 , 4-Dichlorophenol ^1,2, 4-TrichlorobenzeheNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2 -Me thy InaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichloroph«nol2-Chloronaphthalene2-HitroanilineDiaethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3-NitroanilineAcenaphthene ^2 , 4-Dinitrophenol4-Nitrophenol
RRF:xz3eaB.B:5
f
t
'•'
k
fc
kk
>* _
ir\\ '
RRF503B3S-BC3--m3E
%D
*
4
*
4
*
*
*
f*
<
.
\
FORM VII SV-1 1/87 Rev,
AR300720 '
7CSEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: __ Contract:
Lab Code: ______. Case No.: ____ SAS No.: _____ SDG No,:
Instrument ID: ____ Calibration Date:___ Time:
Lab File ID: _______.___ Init. Calib. Date(s):
Min RRF50 for SPCC(#) - 0.050 Max %D for CCC(*) - 25.0*
COMPOUND
Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenylether_Fluorene4-Nitroaniline4 , 6-Dinitro-2-methy IphenolN-Nitrosodiphenylamine (1) t4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenol *PhenanthreneAnthraceneDi-n-butylphthalateFluoranthene *PyreneButylbenzylphthalate3,3' -Dichlorobenz idineBenzo (a) anthraceneChrysenebis ( 2-Ethylhexyl ) phthalateDi-n-octylphthalate *Benzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyrene *Indeno (1,2, 3-cd) pyreneDibenz (a,h) anthraceneBenzo (g,h,i)perylene
Nitrobenz«ne-d52-FluorobiphenylTerphenyl-dl4Phenol-d52-Fluorophenol2,4, 6-Tribromophenol
RRF
>*
»
»k
B5aCS3B3£K£
RRF50-t -ES-S
S—S2£3=ZS a
%D
4
4
i
•*
4
(1) Cannot be separated from Diphenylamine
FORM VII SV-2 1/87 Rev.
AR30072!
8AVOLATILE INTERNAL STANDARD AREA SUMMARY
Lab Name: Contract:
Lab Code: Case No.: * SAS No.: SDG No.:
Lab File ID (Standard) : , Date Analyzed:
Instrument ID: Time Analyzed:
Matrix: (soil/water) Level: (low/med) Column: (pack/cap)
| | ISl(BCM) | | IS2(DFB) || | AREA #| RT | AREA #| RT
I 12 HOUR STD| I | |
1 UPPER LIMIT | I | |
I LOWER LIMIT! I | f
| EPA SAMPLE | || |1 NO. | || |
O i l 1 I I I02| ] || |031 i || |
^04| I || || 05| | || |F 06| | || |
07| | || |08 | | || f09| | || |1 0 j j j j jH I 1 I I 11 2 1 1 I I I1 3 | I I I I1 4 | I I I I1 5 ! 1 I I 11 6 1 . 1 I I 11 7 ! t i l l1 8 ! 1 I I 1191 1 1 I 12 0 1 I I I !211 1 1 1 I221 I j 1 1
IS3(CBZ) |AREA || RT
1s__.;s _ . .g j __
i— , ——— _ t __- —— _ — i ____==iiiiiiiiiiiiiiiiiiiiiiiii
IS1 (BCM) =• Bromochloromethane UPPER LIMIT *' + 100%IS2 (DFB) « 1,4-Difluorobenzene of internal standard area.IS3 (CBZ) » Chlorobenzene LOWER LIMIT » - 50%
of internal standard area,. f.# Column used to flag internal standard area values with an asterisk
f g e _ o f _ - - - . - - •
1 FORM VIII VGA ' 1/87 Rev,
1 Lab Name: _______________ Contract:
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No,!
j Lab File ID (Standard): ___________ Date Analyzed:_
Instrument ID: _______ Time Analyzed:_
01020304050607080910111213141516171819202122
| ISl(DCB)| AREA 1
12 HOUR STDImmE«3-BaEsasa-E--«~'2-S5ss3 1 —— ——— _B=—:a
UPPER LIMIT!
LOWER LIMIT!
EPA SAMPLE |NO. |
1111111111111111111111
RT
-____
IS2(NPT)AREA |
—
____
| IS3(ANT)RT | AREA *
1""
1
1_•_-_ m_ | SS — _
11
1111111111111111111111
RT
=====
IS1 (DCB) - l,4-Dichlorobenzene-d4 UPPER LIMIT - + 100%IS2 (NPT) » Naphthalene-dS of internal standard area.IS3 (ANT) * Acenaphthene-d8 LOWER LIMIT - - 50%
of internal standard area.
I Column used to flag internal standard area values with an asterisk
page _ of _
FORM VIII SV-1 1/87 Rev,
SR300723
8CSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY
Lab Name: ________ Contract:
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.
Lab File ID (Standard) : _____________ Date Analyzed:__
Instrument ID: _______ . Time Analyzed:
| | IS4(PHN)I I AREA #
I 12 HOUR STD|
1 UPPER LIMIT!
I LOWER LIMIT |
| EPA SAMPLE 11 NO. |
Oil 1021 I031 I04| |05| |06| |071 |081 I09| |10! I111 1121 I131 |141 I151 I161 |17| |181 I191 1201 I211 I221 |
RT
aesesxaEX
ISS(CRY)AREA * RT
s==53Z-=:s
•KSSISESX
IS6(PRY) |AREA #| RT
1
Is* — •=•_• _ r — «.= ———————— =_ | = —— __s
1
11
•BMX3K33SSS ] JB-K-Z -«SS
111111111111I11i111111
IS4 (PHN) « Phenanthrene-dlO UPPER LIMIT - + 100%IS5 (CRY) * Chrysene-dl2 of internal standard area.IS6 (PRY) - Perylene-dl2 LOWER LIMIT - - 50%
of internal standard area.
# Column used to flag internal standard area values with an asterisk
>age _ of _
FORM VIII SV-2 1/87 Rev.
8DPESTICIDE EVALUATION STANDARDS SUMMARY
Lab Name: ________ Contract:
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.
Instrument ID:________ GC Column ID: ________
Dates of Analyses:________ to _______
Evaluation Check for Linearity
PESTICIDE
ALDRINENDRIN4,4' -DDTDBC
I CALIBRATIONI FACTOR1 EVAL MIX A
111Ii
CALIBRATIONFACTOREVAL MIX B
•»————— «———
CALIBRATIONFACTOREVAL MIX C
i1
%RSD(</-10.0%)
11(1) If > 10.0% RSD, plot a standard curve and determine the ng
for each sample in that set from the curve.
Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)
Oil02103 i04|05 |06 |07]08|09 |10|HI1211314
| DATEI ANALYZED
INITIAL 1EVAL MIX B 1EVAL MIX B |EVAL MIX B |EVAL MIX B 1EVAL MIX B IEVAL MIX B iEVAL MIX B iEVAL MIX B 1EVAL MIX B iEVAL MIX B IEVAL MIX B |EVAL MIX B |EVAL MIX B !EVAL MIX B |
1
TIMEANALYZED
ENDRIN 4, 4 '-DDT
.
.'
COMBINED(2)
(2) See Form instructions.
FORM VIII PEST-1 1/87 Rev.
AR3QG725
8EPESTICIDE EVALUATION STANDARDS SUMMARY
Evaluation of Retention Time Shift for Dibutylchlorendate
Lab Name: Contract:__
'Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Instrument ID: ___ GC Column ID:
Dates of Analyses:________ to
| EPA | LAB SAMPLE| SAMPLE NO. | ID
Oil 1021 1031 1041 1051 1061 I07| |081 1091 I101 |111 1121 |131 I141 I15| |161 |171 |181 |191 !201 |211 |221 |23| |24| I251 I26| |27| |28| |291 I301 |311 |321 |331 |341 |351 |36| |37| |381 |
DATEANALYZED
TIMEANALYZED
Jl M Ji M J. fc t _- 1 Jl
...
* 1D | *
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii!1111 '
* Values outside of QC limits (2.0% for packed columns,0.3% for capillary columns)
page _ of _ .FORM VIII PEST-2 1/87 Rev.
flR300726
9PESTICIDE/PCB STANDARDS SUMMARY
Lab Name: __ _______ Contract:
Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:
Instrument ID:________ GC Column ID: '_____
| DATE (3) OF FROM:1 ANALYSIS TO:| TIME(S) OF FROM:1 ANALYSIS TO:1l i RT
COMPOUND | RT | WINDOW| | FROM TO
alpha-BHC i 1beta-BHC 1 1delta-BHC I Igamma-BHC I iHeptaclor 1 1Aldrin 1 1Hept. epoxidel IEndosulfan I 1 1Dieldrin 1 I4,4' -DDE I 1Endrin 1 IEndosulfan III 14,4' -DDD I 1Endo.sulfate j i4, 4 '-DDT 1 1Methoxychlor i 1Indrin ketone) 1a. Chlordane I ig. Chlordane 1 1Toxaphene 1 1Aroclor-1016 I IAroclor-1221 | IAroclor-1232 1 1Aroclor-1242 1 1Aroclor-1248 1 1Aroclor-1254 1 1Aroclor-1260 | 1
i t
CALIBRATIONFACTOR
DATE OF ANALYSIS |TIME OF ANALYSIS jEPA SAMPLE NO. |(STANDARD) j
RT
1t
CALIBRATIONFACTOR
1QNT|Y/NI
iI11
i%D
t
=*j
——————————
Under QNT Y/N: enter Y if quantitation was performed, N if not performed,%D must be less than or equal to 15.0% for quant it at ion, and less thanor equal to 20.0% for confirmation.
Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,
For multicomponent analytes, the single largest peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition
page _ of _FORM IX PEST 1/87 Rev.
AR30Q727
10 EPA SAMPLE NO.PESTICIDE/PCB IDENTIFICATION
Lab Name: Contract:
b Code: Case No.: SAS No.: SDG No.:
GC Column ID (1): ________ GC Column ID (2):
Instrument ID (1): ________ Instrument ID (2):
Lab Sample ID: ___________
Lab File ID: ___________ (only if confirmed by GC/MS)
PESTICIDE/PCB RETENTION TIME RT WINDOW QUANT? GC/MS?OF STANDARD (Y/N) (Y/N)FROM TO
01 Column 1 ......... - .--,- —
02 Column 2
03___________ Column 1
04 Column 2
05___________ Column 1
06 Column 2
07___________ Column 1
08 Column 2
09__________ Column l10 Column 2
ll__________ Column 112 Column 2
Comments:
page _ of _FORM X PEST 1/87 Rev,
AR3GQ728
I^IIIIIIi
IIII
APPENDIX L
LANCY'S PROGRAM
FOR
CORRECTIVE ACTION
AR300729
14.0 CORRECTIVE
Corrective action is taken vfcenever a nonconformance occurs. A
nonconformace is defined as an event which is beyond the limits established
for a particular operation by the QAPP. tfonconfoomances can occur in a
nunber of activities. Such activities include sampling procedures, sample
receipt, sample storage, sanple analysis, data reporting, and computations.
The following personnel are responsible for detecting and reporting
noncon fbnnances :
o Project Staff - during the performance of fieldinvestigations and testing, supervision of subcontractors,and preparation and verification of numerical analyses.
o Laboratory Staff - during the preparation for analyses,performance of analytical procedures, calibration ofequipment and quality control activities.
o Quality Assurance Ooordinator-during performance audits.
14.1 Corrective Action
Nonconformances are documented by the person originating or identifying
it. Nonconformance fonns are used for this purpose. The
laboratory nonconformance fonns consist of individual forms for each of
the following areas:
o Bctractiorv'Sanple Preparation
o Sample Receiving
o General Chemistry
o Metals/Soils
o (E-OC/MS (Figure 14-1)
flR3007
Docunentation includes the following:
o Identification of the individual (s) originating oridentifying the nonconformance.
o Description of the nonconformance.
o Any required approval signatures (initials) .
o Corrective action taken*
o Corrective action completion date.
Within the laboratory organization, a completed nonconfonuance form is• r.routed through the Qroup Leader to the Laboratory Supervisor. The
Laboratory Supervisor reviews and approves the docunentation and then
routes the form to the QA Coordinator. Ihe nonconformance is entered
into the Nonconformance tog by the QA Coordinator. If M & E needs to
be notified of the nonconformance, the nonconformance form is routed to
the Project Manager. M & E is notified of the nonconformance and the
corrective action taken by a letter of transnittal that is issued with
the Analysis Rsport.
Within the laboratory, a nonconformance that can be corrected during
the course of analysis is corrected by the analyst and/or the Group
Leader. All other nonconformances are corrected by the Laboratory
Supervisor in conjunction with the QA Coordinator.
If the QA Coordinator and the Project fanager or Laboratory Supervisor
disagree on the necessary corrective action, the ffenager-Technical
Operations makes the final decision as to the corrective action that is
to be taken.
AR30073I
M & E is notified of the nonconformance and corrective action if one of
the following is true:-
o A nonconformance causes a delay in work beyond the schedulecompletion date.
o A nonconformance affects information already reported to M & E.
o A nonconformance affects the validity of the data._ • , . 1 .
Ihe QA Coordinator verifies the conpletion of all corrective actions.
Verification of completion is documentated on a nonconformance form and
in the Nonconformance Log*
14-2 Limits of Operation
The limits of operation that are used to identify nonconfocmances are
established by the contents of the QAPP and by control charts produced
by statistical analyses.
SR300732
I
lIl1Ill
APPENDIX M
BIOASSAY QUALITY CONTROL PROGRAM
BR300733
QUALITY CONTROL PROGRAM , . . . .
A. An acceptable degree of precision for definitive bioassays shall be
that the 95 percent confidence or fiducial intervals be within less
than +30 percent of the 96^hour or Incipient LC50 valve.
B. The laboratory shall develop and have on file and available for
inspection a written description of the current laboratory quality
control program. The written description shall outline the procedures
which the laboratory will use In meeting the quality control
requirements. A record.of analytical control tests and quality control
checks on equipment and materials shall be.prepared by the laboratory
and retained for at least five years."
1. The-laboratory shall perform the following analytical quality
control tests to ensure that general laboratory practices and
methodology are in compliance with the requirements.
a. Laboratory pure water shall be analyzed for and meet the
following requirements:
pH ,. 5.5 - 7.5
Conductivity Greater, than 0.2 mehohm-cm asresistivity or less than 5.0micromhos-cm as conductance at 25 C
Trace Metals:
- A single metal - Not greater than 0.05 mg/L
- Total metals Equal to or less than 1.0 mg
- Test for bactericidalproperties of distilledwater (Standard Methods,14 Edition, orMicrobiological Methods - 0.8-3.0EPA, Free chlorine residual 0.0
b. Laboratory pure water checks for pH, conductivity, and free
chlorine residual shall be performed monthly and documented.
flR30073i*
I c. Laboratory pure water checks for trace metals, bactericidal
properties, and standard plate count shall be performed
« annually and documented.t
d. Laboratory grade water shall be analyzed monthly for pH, D.O.,
I chlorine residual, and specific conductance,
e. Laboratory grade fresh water shall be analyzed at least twice
J annually.
I. Each ph meter shall be cleaned Immediately after each use
I period and calibrated prior to usage using two pH buffer
standards and records of each calibration shall be
i maintained; buffer allquots shall not be used more than
once; and commercial buffer solutions shall be dated at
the time of initial use; it .Is recommended that the
, buffer standards bracket the value to be measured;
* II. Top loader or pan balances shall be calibrated annually,
i calibration shall be checked monthly against class "s"i
weights, and a record shall be made of each calibration
? check;
ill. The accuracy of all thermometers used to monitor
~t temperature shall be verified by comparing the readings
of such thermometers with the readings of a certifiedi
f thermometer. A record shall be made containing the
identification number of each thermometer, thef * . . . .I '* temperature displayed on the certified thermometer and
the thermometer being verified, correction factors when
applicable, dates on which quality control checks were
i performed, and the name of the analyst performing such
checks. Glass thermometers shall be verified yearly and
metal thermometers shall.be verified quarterly.
iv. The temperature of air or water-jacketed incubators,
aluminum block incubators, water baths and Incubator
rooms shall be either recorded continuously or recorded
daily from in-place thermometers immersed in liquid and
placed on at least one of the shelves in use.
v. Date, time and temperature shall be either recorded
continuously, or recorded individually during each
sterilization cycle of the autoclave;
vi. Each hot air oven shall be equipped with a thermometer,
the bulb of which shall be placed in sand, or with a
temperature recording device, and records shall be
maintained showing the date, time and temperature of each
sterilization cycle;
vii. The temperature of each refrigerator shall be either
recorded continuously or recorded daily from an in-place
thermometer immersed in liquid and placed on at least onei
of the shelves in use.
vili. Materials of substandard reactivity and deteriorate
materials shall not be used; and
tx. All outdated material shall be discarded immediately.
C. The temperature In and flow rate through the exposure chambers and the
maintenance of effluent concentrations, shall be checked initially,
daily during the duration of the test, and upon completion of the test,
adjusted as necessary, and documentation of these adjustments and
measurements shall be made.
RR300736
APPENDIX N
BIOASSAY RECORDS AND DATA REPORTING
HR300737
I•
M
•
B
•
m
*
i1
RECORDS AND DATA REPORTING
A. Each laboratory shall maintain records and report data in accordance
with the requirements set out in this section.
B. Records of bioassay analysis shall be kept by the laboratory for not
less than five years. This requirement Is equally applicable to all
raw data, quality control data, chain of custody forms and laboratory
reports.
C. The following information shall be kept by the laboratory as part of
the daily log of feeding, behavioral observations, and mortality of
organisms during holding and acclimation:
1. Water temperature of holding tanks;
2. Air temperature in culturing/holdlng room;
3. Mortalities of organisms per holding tank;
4. Analysis of laboratory grade water;
5. Food and feeding schedule; and
6. General observations of behavior and condition.
D. A sample report form shall be completed immediately after collection of
either dilution water or effluent composite or grab samples and shall
state the sampling location, date and time of collection, chlorine
residual, collectors name, and any remarks.
E. The bioassay experimental results shall be reported in accordance with
Methods for Measuring Acute Toxicity - EPA, and;
1. The incipient LC50 shall be reported If applicable.
2. A figure showing the toxtcity curve shall be included.
F. The original or true duplicate of the results of the bioassay shall be
sent promptly to the person who requested such test and shall be signed
by the laboratory manager or a designee.
300738
IIfII
APPENDIX O
CLP PRESERVATIVES AND HOLDING TIMES
AND
COMPARISON OF QC PROTOCOLS FOR GC AND GC/MS ANALYSES
AR3Q0739
EPA CONTRACT LABORATORY PROGRAM (CLP)/PRESERVATIVES AND HOLDING TIMES
10/86 Statement of Work
Parameter
Volatiles(Purgeabies)
Semivolati.es(Including Bases, Neutrals Acids,Pesticides, and PCBs)
Preservative
4°C(±2°C)Store in Dark
4°C(±2°C)Until Extraction andAnalysis
Holding Time
Water: 10 DaysSoil/Sediment: 10 Days
Separatorv Tunnel ExtractionWater: 5 DaysSoil/Sediment: 10 Days
Continuous Liquid-LiquidExtractionWater: 5 DaysSoil/Sediment: 10 Days
3-14 NUS CORPORATION
V
Ue.aOii.
OQ.u a
O! i £cc<CLU
fi._jU>*-Ovn
(Bc
00
Analysis by S
2nd Ed
t/iLU
* --»
«"„Cttsg.£Q?^^-S025•ssl•stsJ.S211
a
LU
ou(TS
J3
0
o
COoco
oOJ
aa
se
a
(ft"Pd.c*•**>UJ
ISO.
Wl
U.
«= CO
Tlo .-, ^-fc<u£'E ZrSrf?* *c §o
4> o;
= es<
«rt;
aa
a
Hhs
Ofo-SuN
03Of:-p
002
0/9-82
ds fo
r ri
Q E M
ater an
d
3 s5
ane
8 isEPA-600
The Anae
Ebo>(Cf ,»J
1Z
rq d,
Ad 5O1.
e eth
M M
co
T3Q)
oz
to "
il!H- tSo--D
g«3*; c cr2 3 G>
6-1 NUS CORPORATIONflR3007l4l
C ANALYSIS
ccOLL.
F QC PROTOCOLS
zO~ 2<i-OL ...2 13o<UD.
5oV*0-
JD.12
C
<«CO1
£2.£ *"
C
UJoa_
Analysis of
Wastewater
for Nl
Monitoring
o*.£ S£•M* C
Analysis of
Drin
Water f o
r NPD1
Monitoring
h.•O 4) 3S"P oTO •—— __-3 .2-=c tr<N« s^« a^« -J 0)
|£3•§j:eQW. W^jflj nja.c S-o5oSOC " fU
O Of'£ E
* « fc-rc.ii£ * ** J;_S** h ui > "°w»-C 2 v— *-*o 5 c « oKt 2 S w c4! ° S -e o» ccfg J-|3fiIS«i-S*" •= w 0» 'i5 fec c c ci.cS3 e O ** O *CO£ C u fl£ w w
C W0 *
— *-» E
Run standards a
teminimum of
three
concentrations.
Repeat whenever
continuing
calibra
criteria cannot be
ii^^ t*w flJ w IB -.
Run standards at
minimum of
thre<
concentrations.
Repeat wh
enevei
continuing
calib
r,cri
teria cannot be
§1**3 *)
- 2-i:TO f} 3'£»:r: cr•£ rt 01
4- S . <- ' C
*^ C 3^ "°"O <U *** © * 0. m 3 "-OCdJEo1 ^njQ-Co** MI c o> .•. u
Iff]• • •
Co* »C k T5
0:=_S m ^-- v2^ o cf o-2 s Si|§aej,l'ls|-6|§ SS? g §f «J§tfMLU '<WW«°»-
• *
"Oa.inOf
•fc*OZ
h.OfclUJ
SZ? v|
c c «o: tS E
«J
.1*1 I Ig tJ C !•
' JB-Q S*o7*3c^ c tr c cr0 05^ g 3 0.
it Addressed.
oZ
T30>VI(A<U•oT3<**OZ
•oc *;
0»'5 e — _£.C- >,£ flJ
3 2 S • ; oe tS as 5 ,E,
C 5*5?01^=0
Run an independ
THM standard da
Error m
ust be <2
3c c S.2-2 Em n v
if C cr(3 > |S
6-2
o
u>>-O.12"S_>»"<5c<
GJ gj o o» Ir&o.3£.§« P c o-is= m 3 e 2<t3 v» O *^ o•so s-g^E<N E i *
Not Address
re0)
l«l«vIdlfoi: — *™ 4» v»3 a.3 >'>in^GC vt Z-Z i- =
^ IBOf 4.
. —— 8
£ -«
lN 0) W-0
4)N
"mcre•ucmOJ
-PcTJ4.V)4."P•P
•P0)V)V)4.•P•P
C o> P<• C
nsc _ - oZ
O)UJQ
t£I/*
<z<fl£
Ou-cn-JOyOotrcuua
a.*0 w I*
•St'S>«.fi.t£"™ m £«N*j
V)ft5§
N
-oc054?
"P in0--QT3 OCJ=4- **- 4>
o "O
tS E S "5 g-."
Recomm
some
Drinking
NPDWR
ing
r s
rflys
is o
ter f
orMonito an
ddaily f
orb. d for THMs
blank i
re ze er ire ld ve
IA
a a>u «_
Jf3
e quarterly.
ry must mee
establishe
EPA.
-= .-1 W C £ u't-ys S C <U
z e a S-i* "> •«* "*-2 5 !3S§««
T3a.VIinQJwTOT3<*-•O
2- Q.
1 ^ w -** * >*• ** 2O2O'
o<uS:
(A
C•O
o E
•^s-jcace:ero?
4* E** CnjP S'5a-
Q.OIw-i OC i_ Wooe
6-3 NUS CORPORATION
flR3007t,3
en_i
Z
U
fiCo
OUooa:a.Uau.O
50?"•%UJI13q<ua.
O4/1&
JOVI"5* _ — _
4)<0 TD-pg1- giS
5i3£S
ooI"
i ™1A C
m
i/ltilOa.
f- 2 enO w £
E^Iego
Mro
UlCOC25SQ ?*• Q-.=°Z0o||«>*•- 5•IT fc. O5. 5.i?** *e
Ii
C 41o. a
-K.2-P
** roC 4)4) a.€a>
3a: ,
VI
« L. V)m O W
0
0 3^ 3S.5 c o-a) o o a;
6-4 NUS CORPORATION
vi
i<
i Svi—iOU
au_o*ovio:<a
§oVI
UJ3.—'S
"rec
*£>CO1
V>"O>-l^ "O.-£ c
c
UJOQ.
Owe,*2»S"C_>.Si.t;c § o**• a>
4-*toro
Analysis of
Drinking
Water for NPDWR
Monitoring
<5££
4-
(tI»
CouA.UJ
D
&OQ.
&O+•*mons
**-
Q
•*-Oc:0.
1 Statem
3
J73cV'Ero?6
2wt
,241
M?j..OUl
O••£flj5*•>vt4;
i "P!3oncm315UJ
^.3vt>_ca.o>V)(0
o
i75u1
^C•
001
,j- -n '"P4;tA
'5QC
154;-p41U.
•c« ofcc5 *", 4»
UJ jg| >B| ^C -J3 -Q ^3 P O f"« tj fl.^? _~ 5~ iii* iZm 3 0...
I* Manual
for the **-
Oco43ra4
U
|
Laboratories
CcJZEQOC1(QC<
•pcOSm.=4)•MvlU
41m
cV*3£
COor-
CO..J2c(Uco
•pa?_JA
4>(TKCO .2"S55
Procedures fo
rQuality A
ssurance,
EPA-570/9-82-002.
• Volatile Organic
Compounds in
Water by Purge
and Trap Gas
Chromatographv/
Mass
Spectrometrv,
Method 524.1.
6-5 NUS CORP
oo.-ju
fl?
o
VI "P
v» i'55'_>.(0C
V)LUOCL
VI<* «T:.fiHI^ «:
V1 m5D
OU. _vi c a ?*Ouooeca.UaUs
osc o
UflL
UJIA C*" oe0< -=»*
4? ».
C 4> O .2
4.
« 24V IA
Ic
6-6 NUS CORPORATIONR3007U6
a.OLL.VI
OH-Oa:a.uau.O
o<Uo.
ja
ro
to •s Pcp *" - — *•
C O*4>"o •*" s c 3 ~"« C "" " ~"" "* _
s"ill C" MI «•• n•a/ w 3 W
CC fN O <0 UJ
PDES
fs o
or N
ring
i fAn wa Mo
aste
01COC
!EO g*o
.ira-.Eill«**" 5'0)45
05 0 '..= -d.. - -O "P in1 il' e O ^ . r " C 4 > n o5 wce^iuS WCLUI= ii
c *J
01 47
°. 5 °, "CW OTT W W
4)
c *Jo g"•*- e
re
«!. o-2*<0--<5^?"OertJ'5?"S W
CTC
i-£g8-g.Q£ E u Q£ u w
reO 47
a!w».> g S=*-^ .. — o -o*- Sr c O
oic
§ II c g-= ,-s^ a: E 8 a: S '5 ccwtt GCT*
c§
3P"
latile
CL ding
rcent
or 5.0%.
RF fo
re sow.
ndard
inq
ivola
unds
ates ho nce us mi
ni lis
R sta
ctai
noemi
cpo
soga
tlve
dere
Csm
et m
SPCCs
Run
cont
orse
com
surr
twel
diffe
CCC
Mee
?!
f-' flJ "I
or th
eand
ust be
e fo n
t on
daily
trals
or m
st l
eard
Neu E
n a dn se ids.
20%
u ta a ciR s B Ac <
oUJ
** ns jaw-p 4.,c e «
O ** C r t f c r - rt O.£.2 S E3 ** E Vc W C v
w 4* 3cs E5 e crO <0-f £ 3 4)
Not Addressed
4)(AVtQJ
st
ndent
for y mu
mits
thod.
r li e
indepe
rd daily
Recove
hin t
he li
n the m
n aRu
n a
standa
VOAs.
be wit
listed
i
C C*4? 4/"P >
c reC3 S
ce
_n^ 3= 'C cr03 O> 0.
NUS CORPORATION
V)
eeOu.V).jOUOODCa.
OVIa.
re
o
5 l£"-a l£l "9
C 'vi C
re
V)UJQ&
H-Z O>O j. C.££'E•" O>»<S .ti<o £ ec 3 o< 55"* 4) «
•wVIre
£>£>EO
oo-r
V! J 41 * (TJ
- - -' o
_ U v.4.w O
N
re
O.T3
4;N>irecre•pcre£re£'re
crem (A
Sillp a*
tA Ev re*(D rti -4» 2: a
OIA4-»C
o Ere - '3-JCQCC
Not Addressed
-o•o
o
Not Addressed
3Hg|leire ^-O3 E J5 •o-^2?«S;eAnalyz
Recove
criter
iathe US
o4»re o^; c
o^p-3S £ E crre o m 4)-JU viee
a
ch ria e
or e
eet crit
W
d fo
nMe SO
Require
sample.
accepta
listed
in
-C m«.—"Tj 2 h.
re ^3«<u ** re •—•
9 - -g-ESSS
-c f-g
Required fo
r eac
sample. Meet
internally es
tabl
acceptance
crite
recovery.
•pO
S ESi £o o»'5j= o-3 a 4)V* VI fiC
d "
z 1
eac
lie
oe e st ry
Prepare and a
naly
in 20 sa
mples from
siteasMS/MSD.
Acceptance
limit
in SOW are
"advi
rew
2-^ c'L a-c* (A e
O <uM- S
°-S°c«' .2'^S*goo+. S.E•" * £ E E aJ. -p2g.i5.=l5§
vi (Aja - s» re u
so a
(9
K 4> ^Wr^Q §a Q.V. p
5 .»- wocc
6-8 rt IMUS CORPORATIONflR3007U8
II
IIIIIIIIIIIIII AR30071.9