tds and hardness qualities comparison of potable water of patiala and around
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1978
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Published On: February 24, 2016
International Journal of Informative & Futuristic Research ISSN: 2347-1697
Volume 3 Issue 6 February 2016 Reviewed Paper
Abstract
Water is the most precious gift of the nature and one of the substances, essential for sustenance of life. Water was never unsafe as today due to contamination from various sources. Unplanned agricultural activities, deforestation, industrialization, rapid urbanization, depletion and contamination of water resources, problems of wastage and sewage have played a crucial role in weakening of ecosystems on the earth. Elevated concentrations of pollutants in these systems have resulted in bioaccumulation of toxic contaminants and a serious environmental problem, which threatens aquatic environment and human health. The concentration and composition of dissolved constituents in water determine its suitability for use. Over one billion people each year are exposed to unsafe drinking water due to poor source water quality and lack of adequate water treatment. This results in 900 million cases of diarrhea each year. Water pollution is a serious problem in India as almost 70 percent of its surface water resources and a growing percentage of its groundwater reserves are contaminated by biological, toxic, organic and inorganic pollutants. The water quality monitoring results obtained by CPCB during 1995 to 2009 indicate that organic, inorganic and bacterial contamination was critical in the water. The concentration of dissolved constituents in groundwater is comparatively higher than surface water. It is common thinking that the potable water has few numbers of dissolved inorganic constituents but the real picture is quite different, as about 58 elements have been enlisted in the literature. Unsanitary disposal of refuge and garbage, increased use of agricultural pesticides and fertilizers, industrial operations, use of pit
TDS And Hardness Qualities Comparison
Of Potable Water Of Patiala And Around Paper ID IJIFR/ V3/ E6/ 033 Page No. 1978-1987 Subject Area Chemistry
Keywords Environment, Development, Information, Knowledge, Pollution, TDS, Hardness,
Water, Potable, Patiala, Comparison
Dr. Avtar Singh Rahi
Head and Associate Professor,
Department of Chemistry,
Government Post-Graduate College, Ambala Cantt.
Haryana (India)
1979
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
latrines and problems with septic tank systems constitute major anthropogenic activities causing groundwater pollution. The water for different purposes has its own requirements for the composition and purity and each body of water has to be analyzed on a regular basis to confirm to suitability. Patiala district is one of the famous princely states of erstwhile Punjab. Patiala presents a beautiful bouquet of life-style even to a casual visitor to the city. Chemicals that are toxic and might be found in drinking water may cause either acute or chronic health effects. TDS and Total hardness qualities of Patiala do not match with other areas but also not with standards. There should be more attention on the analysis and further use of collected data so that the end product of monitoring is information. If the data collected is not utilized in framing strategies and management, then the motive to collect data is lost. Water quality data, today, are in many ways just lying about waiting to be combined, analyzed and interpreted in more meaningful and relevant ways for the public and managers.
1. INTRODUCTION
Water is the most precious gift of the nature and one of the substances, essential for
sustenance of life. Water is considered as one of the nutrients, although it yields no
calories; it enters into structural composition of the cell and is an essential component of
diet (Baloch et al. 2000). Its availability in sufficient quantity and of right quality is a
necessary infrastructure for promoting better quality of life. Our natural environment
supplies us clean drinking water. But while falling as rain, water picks up small amounts
of gases, ions, dust, and particulate matter from the atmosphere. Then, as it flows over or
through the surface layers of the earth, it dissolves and carries with it some of almost
everything it touches, including that which is dumped into it by man. A correct balance
in the sensory, physical, chemical and microbiological qualities of water makes it
suitable for drinking. Water meeting these conditions is termed “Potable” meaning that
it may be consumed in any desirable amount without concern for adverse effects on
health (AWWA 1990). Water is used in both productive and consumptive activities and
contributes to rural and urban livelihoods in complex ways. But, water was never unsafe
as today due to contamination from various sources. Unplanned agricultural activities,
deforestation, industrialization, rapid urbanization, depletion and contamination of water
resources, problems of wastage and sewage have played a crucial role in weakening of
ecosystems on the earth. Human activities have led to accumulation of toxic metals in
the natural environment (Karbassi and Bayati 2005) and the extensive exploitation of
natural resources has led to increased pressure on aquatic ecosystems. Due to an
increased load of contamination the aquatic ecosystems have severely disrupted.
Elevated concentrations of pollutants in these systems have resulted in bioaccumulation
of toxic contaminants and a serious environmental problem, which threatens aquatic
environment and human health (Sasmaz et al. 2008). Chemical quality of water is a
1980
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
significant factor to evaluate the suitability of water for irrigation (Gupta 1989). The
concentration and composition of dissolved constituents in water determine its
suitability for use. Over one billion people each year are exposed to unsafe drinking
water due to poor source water quality and lack of adequate water treatment. This results
in 900 million cases of diarrhea each year (Rijal and Fujioka 2001). A number of other
diseases correlated with water hardness include nervous system defects, various types of
cancers and prenatal mortality (Stocks 1970). Water pollution is a serious problem in
India as almost 70 percent of its surface water resources and a growing percentage of its
groundwater reserves are contaminated by biological, toxic, organic and inorganic
pollutants. The water quality monitoring results obtained by CPCB during 1995 to 2009
indicate that organic, inorganic and bacterial contamination was critical in the water.
Parikh (2004) estimated a loss about Rs 366 billions, which account for about 3.95
percent of the GDP, due to ill effects of water pollution and poor sanitation facilities.
The use of fiscal instruments (other than the expenditure policy) in the environmental
policy has been limited, even though the need to employ economic and fiscal policy
instruments for the control of pollution and management of natural resources has gained
recognition since the 1990s (Rajaram and Das 2008). There are provisions in law for the
use of levies, cess, fines, and penalties, etc. for polluters, but their implementation and
effectiveness needs strengthening (Kumar and Managi 2010). Collective action
involving all the relevant parties for water pollution abatement (factories, affected
parties and the government) is an institutional alternative for dealing with the problem of
water pollution abatement in industrial estates, especially in India. Murty and Kumar
(2002) specified that the management of environmental resources can no longer be taken
as the responsibility of a single institution like a market or the government. India has
defined wastewater discharge standards for the domestic and industrial sectors, there are
no discharge standards for the pollution emanating from agriculture. Corrections in
fertilizer and pesticide and electricity pricing policies could be an instrument for
addressing the non-point water pollution in India.
2. DISSOLVED CONSTITUENTS
Everyone knows that water sustains life but not everyone knows that water
endanger life as ingestion or exposure to contaminated water can cause several health
hazards. The concentration of dissolved constituents in groundwater is comparatively
higher than surface water. It is common thinking that the potable water has few numbers
of dissolved inorganic constituents but the real picture is quite different, as about 58
elements have been enlisted in the literature. Many factors contribute to the quality of
water. Pollution of surface and groundwater resources occurs through Point and Diffuse
sources. Examples of point source pollution are effluents from industries, sewage-
treatment plants and untreated domestic sewage. The main sources of diffuse pollution
may be anthropogenic activities, such as agricultural applications of fertilizers and
pesticides or of geo-chemical origin, such as natural contamination of groundwater
1981
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
sources by fluoride, arsenic and dissolved salts. The impact of anthropogenic activities
has been so extensive that the water bodies have lost their self-purification capacity to a
large extent (Sood et al. 2008). Unsanitary disposal of refuge and garbage, increased use
of agricultural pesticides and fertilizers, industrial operations, use of pit latrines and
problems with septic tank systems constitute major anthropogenic activities causing
groundwater pollution (Baloch et al. 2000; Sichingabula and Nkhuwa 1998; Knox and
Canter 1996; Koppe 1973). Besides anthropogenic activities, groundwater because of
long contact with rocks and mineralized soils, usually contain greater concentrations of
inorganic additives than surface water. In addition to the beneficial nutrients, sewage
water may also contain significant amounts of heavy metals. Soil and plants cannot
accommodate these all harmful entities. These heavy metals may be returned to human
beings and animals through food chain (Gulfraz et al. 1997). The water for different
purposes has its own requirements for the composition and purity and each body of
water has to be analyzed on a regular basis to confirm to suitability.
3. LITERATURE SEARCH
Industrial and agricultural activities in urban areas of Punjab (Saxena et al. 2007) have
led to a considerable increase in heavy metal levels in different environmental
compartments, especially in soils over the course of recent decade. Investment in
Industries and agriculture (Molden 2010) has made a positive contribution to livelihood,
food security and poverty reduction, but its negative effects are unforgettable. In the
vicinity of industrial houses in almost all cities of India, surface and ground water is
polluted due to dumping of industrial wastages. Approximately 70% of fresh water is
consumed by agriculture (Baroni et al. 2007). Water pollution is a serious problem as
almost 70% of India’s surface water resources and a growing number of its groundwater reserves have been contaminated by biological, organic and inorganic pollutants (Rao
and Mamatha 2004). Industrial and agricultural activities in urban areas of Punjab
(Saxena et al. 2007) have led to a considerable increase in heavy metal levels in different
environmental compartments, especially in soils over the course of recent decade. TDS
and total hardness was found above the desirable limit by Jadeja et al. (2006) in all the
groundwater samples collected from Dharampur industrial area Porbandar city. Goyal et
al. (1981) indicated that out of total groundwater reservoir in Punjab, 76.5%
groundwater is fit and the rest showing varying degree of salinity. The fit water zone
being the main attraction for the intensive industrialization and urbanization in the state
is polluted by unsatisfactory disposal of industrial waste and lack of proper sewerage
facilities. High concentration of nitrates, cyanides, and trace elements has been reported
in the groundwater samples from Ludhiana town.
A study by Thakur et al. (2008) found level of As, Se, Hg in ground water at
Talwandi Sabo more than the permissible level where as at Chamkaur Sahib the level of
Se were above the permissible level. Similarly, As, Se were also above permissible level
in tap water at Talwandi Sabo whereas as in Chamkaur Sahib only As levels were more
1982
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
than the permissible limit in tap water. Ground water quality in the close vicinity of
sewage outlets of Patiala city, Punjab was evaluated by Mittal et al. (1994) for alkalinity,
hardness, sodium, potassium, pH and conductivity. Some of the samples exceeded the
maximum permissible limits of total hardness and sodium content as per
recommendations of World Health Organization. Mittal et al. (1997) evaluated the
ground water quality in Patiala, Punjab. Higher concentrations of various inorganic ions
were observed in the close vicinity of sewers. Leaching of contaminants from the sewers
was the only cause of ground water pollution of that area. Kumar et al. (2005) studied
sensory, physico-chemical and micro-biological parameters of water of Patiala city and
indicated that water samples collected from the different localities and various water
samples were found satisfactory in terms of sensory parameters except samples from
hand pumps. Numerous water samples from various localities and sources failed in
terms of their alkalinity, hardness and total dissolved salts as per the BIS specifications.
According to Central Ground Water Board (2007), Patiala district is mineral poor,
except nitrates of Na, K and Ca. Central Ground Water Board (2008) has found Patiala
district affected by salinity with EC > 3000 μS/cm. Essential metals for humans are Iron,
Copper, Cobalt, Manganese, Zinc, Cromium and their deficiency would result in many
clinical abnormalities (Caussy et al. 2003), but high doses of these essential elements
can also cause toxic effects. Other metals such as Hg, Pb, Cd, and As are not known to
be essential for any animals. The damage that they cause on the cellular level can result
into cancer, mental and nervous disorders and many other diseases. The pollution status
of drinking water systems in the study area is of great environmental and health
concerns. Punjab Pollution Control Board has identified number of sources of pollution
of Ghaggar where industrial units are discharging their toxic waste water into water
streams. Besides industrial units, waste water from various domestic sources is also
discharged into Ghaggar River.
4. STUDIED QUALITIES
Patiala district is one of the famous princely states of erstwhile Punjab. Patiala
presents a beautiful bouquet of life-style even to a casual visitor to the city. The district
is occupied by Indo-Gangetic alluvial plain of Quaternary age and falls in Ghaggar
basin. Forming the south-eastern part of the state, it lies between 29°49’ and 30°47’ north latitude, 75°58’ and 76°54' east longitude. The stage of ground water development
ranges between 149% (Ghanaur ) to 409% (Patran).The net ground water resource of
Patiala district have been estimated to be 1490.83 MCM and the gross ground water
draft of the district is 2911.65 MCM leaving behind a shortfall of 1443.30 MCM. It is
predominantly a rural district, where an overwhelming 65% lived in rural areas.
Agriculture is the single most important economic activity in the district. 81% of
geographical area out of 3290 square kilometers in Patiala district is cultivable. 93% of
the area is irrigated through tube-wells and 3% by canals. Though the people of Patiala
District depend mainly on agriculture for earning their livelihood, it is also fast emerging
1983
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
as an important industrial growth centre on the industrial map of the state. Besides
traditional goods, high quality and sophisticated items are now produced including small
cutting tools, industrial cables, power cables, electrical goods, milkfood, vanaspati ghee,
biscuits, horlicks, bicycles and agriculture implements including harvester combines and
threshers, milk products, pesticides, diesel component workshop etc.
As water travels, the soil, the air and the human’s involvement decide the final water profile. From source to destination, various water soluble solids change the
composition of water. Hardness in water is caused by dissolved calcium and to a lesser
extent, by magnesium. Hard water is slightly alkaline in nature. Hardness above 200 can
result in scale deposition and below 100 leads to low buffering capacity. The hardness in
water is derived largely from contact with the soil and rock formations. In general, hard
waters originate in areas where top soil is thick and lime stone formations are present.
Soft waters originate in areas where the top soil is thin and lime stone formations are
sparse or absent. Rain water as it falls upon the earth is incapable of dissolving the solids
found in natural waters. The ability for the rain water to dissolve is gained in the soil
where CO2 is released by the bacterial action. The dissolved CO2 in rain water is
sufficiently acidic to attack the insoluble carbonates in the soil and lime stone
formations converting them to soluble bicarbonates. Since lime stone is not pure
carbonate, but includes impurities such as sulphates, chlorides and silicates, these
materials become exposed to the solvent action of water as the carbonates are dissolved
and they pass into solution too. The total hardness is conventionally expressed in mg/L
units as calcium carbonate, even if it is due to calcium sulphate, magnesium carbonate or
any other polyvalent metal salt. Hard water consumes soap before lather will form,
deposits soap on bathtubs and forms scale in boilers, water heaters and pipes. Waters of
hardness less than 60 mg/L are termed soft; 61 to 120 mg/L moderately hard; 121 to 180
mg/L hard; and more than 180 mg/L very hard.
TDS stands for Total Dissolved Solids, refers to the amount of organic and
inorganic dissolved substances that may be found in water such as minerals, metals and
salts. Essentially, it is everything present in water other than pure H2O and suspended
solids. Water with high TDS is of inferior potability and may induce an unfavorable
physiological response to the body of consumer (Basheer et al. 1996). The concentration
of total soluble inorganic content of a water sample can be measured by evaporating a
known volume of the water sample to dryness and finding the weight of the solid. A
much simpler and quicker way of determining the dissolved solids is by the conductivity
cell method. Total dissolved solids concentrations are useful for comparison to
established water-quality standards.
TDS ≈ [Ca2+ + Mg
2+ + Na
+ + K
+ + Cl
- + SO4
2- + HCO3
- + CO3
2-]
The acceptable value of TDS in water is 500mg/L. Water with more than 1000
mg/L of dissolved solids may contain minerals which impart a distinctive taste. Water
with more than 2000 mg/L dissolved solids is generally too salty to drink.
1984
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
5. RESULTS AND DISCUSSION From ancient time onwards history has spoken a lot on the role and importance
of water in religious, cultural and socioeconomic traditions. Approach to water for
everyone and anytime, is not feasible and easy because it is not uniformly and evenly
distributed. Water quality is the combination of properties of water that are manifested
in relation to human, other living creatures, items and substances. The contamination of
natural water with domestic/ industrial/ agricultural/ human/ livestock waste and pasture
runoff may result in an increased risk of disease transmission to humans (Geldreich
1991). The major causes of water pollution are discharges of untreated domestic sewage
and untreated industrial wastes in to the surface water bodies and on land, increasing use
of fertilizer, pesticides and dumping of organic and inorganic wastes in to water.
Diarrheal disease from contaminated water continues to be a serious problem in
developing countries and also in developed countries (Grant 1997). Chemicals that are
toxic and might be found in drinking water may cause either acute or chronic health
effects. They are more likely to cause chronic health effects, effects that occur after
exposure to small amounts of a chemical over a long period. Examples of chronic health
effects include cancer, birth defects, organ damage, disorders of the nervous system, and
damage to the immune system. The possible health effects of a contaminant in drinking
water differ widely, depending on whether a person consumes the water over a long
period, briefly, or intermittently. In assessing the quality of drinking-water, consumers
rely principally upon their senses. Sampling area is mostly affected by agricultural and
other anthropogenic activities besides effects of dumping industrial wastes into the land
or nearby water source. The data compared is collected from the various literature
studied by researchers.
Table 1: Comparison of Water Quality Assessment of Patiala and Surroundings
Study Area pH TDS Total Hardness
WHO/BIS Acceptable Limit 7.0 - 8.5 500 100 – 200
Patiala, CGWB1 7.1 – 8.3 - 35 - 657
Patiala City, Punjab2 7.8 - 8.3 682 – 852 271 – 668
Patiala Groundwater3 7.6 – 8.5 330 - 2870 102 - 490
Patiala Rural (average)4 7.6 – 8.2 717 - 987 259 - 481
Rupnagar, Punjab5 8.5 - 8.5 807 - 1000 452 - 498
Muktsar, Punjab6 7.0 – 8.4 517 - 4640 168 - 984
Chandigarh Domestic7 6.4 - 7.2 400 – 650 200 – 350
Chandigarh Industrial7 6.3 - 7.1 500 – 1100 275 – 400
Chandigarh Aquifers8 7.5 - 7.6 281 – 391 186 – 267
Parwanoo9 7.3 - 8.3 234 – 330 130 – 176
Ghaggar River10
7.3 - 8.6 212 - 1052 150 - 381
Source: 1CGWB (2013),
2Kumar et al. (2005),
3Water Quality Assessment
Authority (2008), 4Rahi (2011),
5Sahoo et al. (2014),
6Sharma (2014),
7Kaur and
Malik (2012), 8Sidhu et al. (2013),
9Aggarwal and Arora (2012),
10Kundu (2012)
1985
ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
Dr. Avtar Singh Rahi:: TDS And Hardness Qualities Comparison Of Potable Water Of Patiala And Around
6. CONCLUSION
The data observed by various researchers indicate poor situation of Patiala. TDS
and Total hardness qualities of Patiala do not match with other areas but also not with
standards. Central Groundwater Board has also carried out studies for chemical quality
of ground water in the area. The ground water of the district is alkaline in nature. The
EC in the area ranges from 687 to 4100 μS/cm. Nitrate values ranges between 0.40 to 200 mg/L and fluoride concentration ranges from 0.20 to 2.8 mg/L. At few places high
fluoride and nitrate have been observed, thus the ground water in these places is harmful
for human consumption.
The ultimate goal of monitoring is to provide information and not data. In the
past, many monitoring programmes have been characterized by the "data rich,
information poor syndrome" (Ward et al. 1986). There should be more attention on the
analysis and further use of collected data so that the end product of monitoring is
information. If the data collected is not utilized in framing strategies and management,
then the motive to collect data is lost. Recent developments in computing hardware and
software have made it possible for a broader public to use data more effectively and
obtain almost instantaneously results of simple data analysis. These technological and
scientific improvements in recent years have not been institutionalized in many
monitoring programs. Water quality data, today, are in many ways just lying about
waiting to be combined, analyzed and interpreted in more meaningful and relevant ways
for the public and managers. Strong pressure exerted by human activities on freshwater
resources (Saeijs and van Berkel 1995) has led to increased demands on policy and
decision makers to develop well fundamental strategies and solutions.
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ISSN: 2347-1697
International Journal of Informative & Futuristic Research (IJIFR)
Volume - 3, Issue -6, February 2016
Continuous 30th Edition, Page No.:1978-1987
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