safety data sheet - antala

Product Name: BETAPRIME (TM) 5600-1 Revision Date: 2013/09/05

Print Date: 27 Jan 2014

®(TM)*Trademark

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Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

Section 1. Identification of the substance/preparation and of the

company/undertaking

1.1 Product identifiers Product Name

BETAPRIME ™ 5600-1

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

An activator -- For use in automotive applications. 1.3 Details of the supplier of the safety data sheet

COMPANY IDENTIFICATION

Dow Chemical Company Ltd Diamond House, Lotus Park Kingsbury Crescent TW18 3AG Staines, Middlesex United Kingdom Customer Information Number: 0203 139 4000 [email protected]

1.4 EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 0031 115 694 982 Local Emergency Contact: 00 31 115 69 4982

Section 2. Hazards Identification

2.1 Classification of the substance or mixture

Classification according to EU Directives 67/548/EEC or 1999/45/EC

F R11 Highly flammable. Toxic for reproduction - category

3. R63 Possible risk of harm to the unborn child.

Xn R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Safety Data Sheet Dow Chemical Company Ltd

Safety Data Sheet according to Reg. (EC) N. 453/2010

mailto:[email protected]


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Xn R20/21 Harmful by inhalation and in contact with skin.

Xn R65 Harmful: may cause lung damage if swallowed.

Xi R36/37/38

Irritating to eyes, respiratory system and skin.

R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause

long-term adverse effects in the aquatic environment.

2.2 Label elements Labelling according to EC Directives

Hazard Symbol:

F - Highly flammable. Xn - Harmful. Risk Phrases : R11 - Highly flammable. R63 - Possible risk of harm to the unborn child. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R20/21 - Harmful by inhalation and in contact with skin. R65 - Harmful: may cause lung damage if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R43 - May cause sensitization by skin contact. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Safety Phrases : S9 - Keep container in a well-ventilated place. S16 - Keep away from sources of ignition - no smoking. S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of water and soap. S33 - Take precautionary measures against static discharges. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where

possible). S51 - Use only in well-ventilated areas. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets. S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S63 - In case of accident by inhalation: remove casualty to fresh air and keep at rest. Contains: Toluene

Xylene Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <= 700)

Contains epoxy constituents. See information supplied by the manufacturer.

2.3 Other Hazards No information available.

3.2 Mixture

This product is a mixture.

Section 3. Composition/information on ingredients


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CAS-No. / EC-No. / Index

REACH No. Amount Component Classification: REGULATION (EC) No 1272/2008

CAS-No.

108-88-3 EC-No.

203-625-9

Index

601-021-00-3

—

> 50.0 - < 60.0 %

Toluene Flam. Liq., 2, H225

Repr., 2, H361d

Asp. Tox., 1, H304

STOT RE, 2, H373

Skin Irrit., 2, H315

STOT SE, 3, H336

Aquatic Chronic, 3, H412

CAS-No.

1330-20-7 EC-No.

215-535-7

Index

601-022-00-9

—

> 30.0 - < 40.0 %

Xylene Flam. Liq., 3, H226

Acute Tox., 4, H332

Acute Tox., 4, H312

Skin cor/irr, 2, H315

Asp. Tox., 1, H304

STOT SE, 3, H335

Eye cor/irr, 2, H319

CAS-No.

100-41-4 EC-No.

202-849-4

Index

601-023-00-4

—

< 5.0 % Ethylbenzene Flam. Liq., 2, H225

Acute Tox., 4, H332

STOT RE, 2, H373

Asp. Tox., 1, H304

CAS-No.

25068-38-6 EC-No.

500-033-5

Index

603-074-00-8

—

> 2.5 - < 5.0

%

Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <= 700)

Skin cor/irr, 2, H315


Skin Sens., 1, H317

Aquatic Chronic, 2, H411

CAS-No.

67-64-1 EC-No.

200-662-2

Index

606-001-00-8

—

> 1.0 - < 5.0

%

Acetone; propanone

Flam. Liq., 2, H225


STOT SE, 3, H336

CAS-No. / EC-No. / Index

Amount Component Classification: 67/548/EEC

CAS-No.

108-88-3 EC-No.

203-625-9

Index

601-021-00-3

> 50.0 - < 60.0 % Toluene F: R11; Repr. 3: R63; Xn: R48/20, R65; Xi: R38; R67

CAS-No.

1330-20-7 EC-No.

215-535-7

Index

601-022-00-9

> 30.0 - < 40.0 % Xylene R10; Xn: R20/21, R65; Xi: R36/37/38

CAS-No.

100-41-4 EC-No.

202-849-4

Index

601-023-00-4

< 5.0 % Ethylbenzene F: R11; Xn: R20; Xn: R48/20; Xn: R65


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CAS-No.

25068-38-6 EC-No.

500-033-5

Index

603-074-00-8

> 2.5 - < 5.0 % Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <= 700)

Xi: R36/38; R43; N: R51, R53

CAS-No.

67-64-1 EC-No.

200-662-2

Index

606-001-00-8

> 1.0 - < 5.0 % Acetone; propanone F: R11; Xi: R36; R66; R67

For the full text of the H-Statements mentioned in this Section, see Section 16. See Section 16 for full text of R-phrases.

Section 4. First-aid measures

4.1 Description of first aid measures

General advice: First Aid responders should pay attention to self-protection and use the

recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth

use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.

Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area. Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Suitable emergency eye wash facility should be available in work area. Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.

4.2 Most important symptoms and effects, both acute and delayed

Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), no additional symptoms and effects are anticipated.

4.3 Indication of immediate medical attention and special treatment needed

Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) symptoms. Bronchodilators, expectorants, antitussives and corticosteroids may be of help. If burn is present, treat as any thermal burn, after decontamination. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. Alcohol consumed before or after exposure may increase adverse effects. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Repeated excessive exposure may aggravate preexisting lung disease. Skin contact may aggravate preexisting dermatitis.

Section 5. Fire Fighting Measures

5.1 Extinguishing Media Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.


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Extinguishing Media to Avoid: Do not use direct water stream. Straight or direct water streams may

not be effective to extinguish fire.

5.2 Special hazards arising from the substance or mixture

Hazardous Combustion Products: During a fire, smoke may contain the original material in addition

to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Container may vent and/or rupture due to fire. Electrically

ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures above flash point; see Section 9.

5.3 Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay

upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Avoid accumulation of water. Product may be carried across water surface spreading fire or contacting an ignition source. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing

apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

Section 6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures: Isolate area. Keep

unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Refer to Section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. 6.2 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or

groundwater. See Section 12, Ecological Information. 6.3 Methods and materials for containment and cleaning up: Contain spilled material if possible.

Absorb with materials such as: Cat litter. Sand. Sawdust. Ground and bond all containers and handling equipment. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information.

Section 7. Handling and Storage

7.1 Precautions for safe handling

Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes, skin, and

clothing. Avoid prolonged or repeated contact with skin. Do not swallow. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. No smoking, open flames or sources of ignition in handling and storage area. Ignition sources can include and are not limited to pilot lights, flames, smoking, sparks, heaters, electrical equipment, and static


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discharges. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Never use air pressure for transferring product unless a risk assesment has been conducted that includes consideration of the flammability of the product. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. 7.2 Conditions for safe storage, including any incompatibilities

Storage

Minimize sources of ignition, such as static build-up, heat, spark or flame. Keep container closed. Flammable mixtures may exist within the vapor space of containers at room temperature.

Shelf life: Use within Storage temperature: 12 Months 5 - 25 °C

7.3 Specific end uses

See the technical data sheet on this product for further information.

Section 8. Exposure Controls / Personal Protection

8.1 Control parameters

Exposure Limits

Component List Type Value |

Toluene ACGIH TWA 20 ppm BEI UK WEL TWA 191 mg/m3 50 ppm SKIN

UK WEL STEL 384 mg/m3 100 ppm SKIN

EU IOELV TWA 192 mg/m3 50 ppm SKIN

EU IOELV STEL 384 mg/m3 100 ppm SKIN |

Xylene Ireland OELV TWA 221 mg/m3 50 ppm SKIN Indicative OELV

Ireland OELV STEL 442 mg/m3 100 ppm SKIN Indicative OELV

ACGIH TWA 100 ppm BEI

ACGIH STEL 150 ppm BEI


EU IOELV STEL 442 mg/m3 100 ppm SKIN

UK WEL TWA 220 mg/m3 50 ppm SKIN

UK WEL STEL 441 mg/m3 100 ppm SKIN |

Ethylbenzene Ireland OELV TWA 435 mg/m3 100 ppm SKIN Indicative OELV

Ireland OELV STEL 545 mg/m3 125 ppm SKIN Indicative OELV



EU IOELV STEL 884 mg/m3 200 ppm SKIN

UK WEL TWA 441 mg/m3 100 ppm SKIN

UK WEL STEL 552 mg/m3 125 ppm SKIN |

Acetone; propanone Ireland OELV TWA 1,210 mg/m3 500 ppm Indicative OELV


ACGIH STEL 750 ppm BEI

EU IOELV TWA 1,210 mg/m3 500 ppm


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UK WEL TWA 1,210 mg/m3 500 ppm

UK WEL STEL 3,620 mg/m3 1,500 ppm |

n-Butyl acetate Ireland OELV TWA 710 mg/m3 150 ppm Ireland OELV STEL 950 mg/m3 200 ppm

ACGIH TWA 150 ppm

ACGIH STEL 200 ppm

UK WEL TWA 724 mg/m3 150 ppm

UK WEL STEL 966 mg/m3 200 ppm

A BEI notation following the exposure guideline refers to a guidance value for assessing biological monitoring results as an indicator of the uptake of a substance from all routes of exposures. A “skin” notation following the inhalation exposure guideline refers to the potential for dermal absorption of the material including mucous membranes and the eyes either by contact with vapors or by direct skin contact. It is intended to alert the reader that inhalation may not be the only route of exposure and that measures to minimize dermal exposures should be considered. 8.2 Exposure controls

Personal Protection Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent. If exposure causes eye discomfort, use a full-face respirator. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific

items such as face shield, boots, apron, or full body suit will depend on the task. Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective

gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Viton. Polyethylene. Polyvinyl chloride (“PVC” or “vinyl”). Styrene/butadiene rubber. Polyvinyl alcohol (“PVA”). Ethyl vinyl alcohol laminate (“EVAL”). Examples of acceptable glove barrier materials include: Butyl rubber. Neoprene. Chlorinated polyethylene. Natural rubber (“latex”). Nitrile/butadiene rubber (“nitrile” or “NBR”). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed

the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 ºC) Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in

the work area; wash hands and face before smoking or eating.

Engineering Controls Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or

guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Section 9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties Appearance Physical State Liquid.


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Color Colorless to yellow Odor Solvent Odor Threshold No test data available

pH No test data available

Melting Point No test data available

Freezing Point No test data available

Boiling Point (760 mmHg) No test data available. Flash Point - Closed Cup 19 °C Setaflash Closed Cup Evaporation Rate (Butyl Acetate = 1)

No test data available

Flammability (solid, gas) Flammable liquid

Flammable Limits In Air Lower: No test data available Upper: No test data available Vapor Pressure No test data available Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 0.88 Estimated. Solubility in water (by weight)


Partition coefficient, n-octanol/water (log Pow)

No data available for this product. See Section 12 for individual component data.

Autoignition Temperature No test data available Decomposition Temperature


Dynamic Viscosity 2 mPa.s Estimated. Kinematic Viscosity No test data available

Explosive properties No test data available

Oxidizing properties No test data available

9.2 Other information

Section 10. Stability and Reactivity

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under recommended storage conditions. See Storage, Section 7.

10.3 Possibility of hazardous reactions

Polymerization will not occur.

10.4 Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Avoid static discharge.

10.5 Incompatible Materials: Avoid contact with: Acids. Bases. Oxidizers.

Hazardous Decomposition Products: Decomposition products depend upon temperature, air supply and the presence of other materials.

10.6 Hazardous decomposition products

Decomposition products depend upon temperature, air supply and the presence of other materials.

Section 11. Toxicological Information

11.1 Information on toxicological effects

Acute Toxicity Ingestion

Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Swallowing may result in gastrointestinal irritation or ulceration.


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Single dose oral LD50 has not been determined. Aspiration hazard

Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death due to chemical pneumonia. Dermal

Prolonged skin contact is unlikely to result in absorption of harmful amounts. The dermal LD50 has not been determined. Inhalation

Vapor concentrations are attainable which could be hazardous on single exposure. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause central nervous system depression. Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Alcohol consumed before or after exposure may increase adverse effects. For the minor component(s): In humans, symptoms may include: Nausea and/or vomiting. Lethargy. The LC50 has not been determined.

Eye damage/eye irritation May cause eye irritation. May cause slight corneal injury. Vapor may cause lacrimation (tears). Vapor may cause eye irritation experienced as mild discomfort and redness.

Skin corrosion/irritation Prolonged contact may cause severe skin irritation with local redness and discomfort. Repeated contact may cause skin burns. Symptoms may include pain, severe local redness, swelling, and tissue damage. Vapor may cause skin irritation. May cause drying and flaking of the skin.

Sensitization Skin

A component in this mixture has caused allergic skin reactions in humans. Respiratory

No relevant data found.

Repeated Dose Toxicity Contains component(s) which have been reported to cause effects on the following organs in animals: Central nervous system. Blood. Kidney. Liver. Nasal tissue. Lung. Toluene has caused hearing loss in laboratory animals upon exposure to high concentrations. Intentional misuse by deliberately inhaling toluene may cause nervous system damage, hearing loss, liver and kidney effects and death. Xylene is reported to have caused hearing loss in laboratory animals upon exposure to high concentrations; such effects have not been reported in humans. Development of cataracts has been reported in laboratory animals after prolonged repeated skin exposure to acetone. Although one early inhalation study on ethylbenzene reported an adverse effect on the testes, recent, more comprehensive studies have not shown this effect.

Chronic Toxicity and Carcinogenicity Ethylbenzene has been shown to cause cancer in laboratory animals. Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol A (DGEBPA). Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has concluded that DGEBPA is not classified as a carcinogen. Although some weak evidence of carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that DGEBPA is carcinogenic.

Developmental Toxicity Contains component(s) which caused birth defects in laboratory animals only at doses toxic to the mother. Contains component(s) which, in laboratory animals, have been toxic to the fetus at doses nontoxic to the mother. Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Exaggerated doses of xylene given orally to pregnant mice resulted in an increase in cleft palate, a common developmental abnormality in mice. In animal inhalation studies, xylene caused toxicity to the fetus but did not cause birth defects. In laboratory animals, toluene has been toxic to the fetus at doses toxic to the mother; it has caused birth defects in mice when administered orally, but not by inhalation. Resins based on the diglycidyl ether of bisphenol A (DGEBPA) did not cause birth defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.

Reproductive Toxicity For the majority of components: In animal studies, did not interfere with reproduction.

Genetic Toxicology


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Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in others. For the component(s) tested: Animal genetic toxicity studies were negative. Component Toxicology - Toluene

Skin Absorption LD50, rabbit 12,267 mg/kg

Component Toxicology - Xylene


Component Toxicology - Ethylbenzene


Component Toxicology - Reaction product: Bisphenol A-(epichlorohydrin); epoxy resin (number

average molecular weight <= 700) Skin Absorption LD50, rabbit 23,000 mg/kg

Component Toxicology - Acetone

Skin Absorption LD50, rabbit > 20,000 mg/kg

Component Toxicology - Toluene

Inhalation LC50, 4 h, Vapor, rat, male and female > 20 mg/l


Inhalation LC50, 4 h, rat 27.5 mg/l Component Toxicology - Ethylbenzene

Inhalation LC50, 4 h, rat 4,000 ppm 17.2 mg/l Component Toxicology - Acetone

Inhalation LC50, 4 h, Vapor, rat 76 mg/l

Component Toxicology - Toluene

Ingestion LD50, rat 5,580 mg/kg



Component Toxicology - Ethylbenzene


Component Toxicology - Reaction product: Bisphenol A-(epichlorohydrin); epoxy resin (number

average molecular weight <= 700) Ingestion LD50, rat > 15,000 mg/kg

Component Toxicology - Acetone


Section 12. Ecological Information

12.1 Toxicity Data for Component: Toluene

Material is toxic to aquatic organisms (LC50/EC50/IC50 between 1 and 10 mg/L in the most sensitive species). Fish Acute & Prolonged Toxicity

LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 h: 5.8 mg/l LC50, fish, flow-through test, 96 h: 5.5 mg/l Aquatic Invertebrate Acute Toxicity

EC50, Daphnia magna (Water flea), static test, 24 h, immobilization: 7 mg/l LC50, water flea Ceriodaphnia dubia, semi-static test, 48 h, mortality: 3.78 mg/l Aquatic Plant Toxicity

EbC50, Pseudokirchneriella subcapitata (green algae), biomass growth inhibition, 72 h: 12.5 mg/l Fish Chronic Toxicity Value (ChV)

Fish, flow-through test, 40 d, growth, NOEC:1.4 mg/l Aquatic Invertebrates Chronic Toxicity Value

Ceriodaphnia Dubia (water flea), 7 d, number of offspring, NOEC: 0.74 mg/l Data for Component: Xylene

Material is toxic to aquatic organisms (LC50/EC50/IC50 between 1 and 10 mg/L in the most sensitive species).


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Fish Acute & Prolonged Toxicity

LC50, Oncorhynchus mykiss (rainbow trout), 96 h: 9.2 mg/l Aquatic Invertebrate Acute Toxicity

LC50, Daphnia magna (Water flea), 48 h, lethality: 14.3 mg/l Aquatic Plant Toxicity

EbC50, Pseudokirchneriella subcapitata (green algae), biomass growth inhibition, 72 h: 3.2 - 4.9 mg/l

Data for Component: Ethylbenzene


LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 h: 4.2 mg/l Aquatic Invertebrate Acute Toxicity

EC50, Daphnia magna (Water flea), static, 1 d, immobilization: 2.2 mg/l Aquatic Plant Toxicity

EC50, Pseudokirchneriella subcapitata (green algae), Growth inhibition (cell density reduction), 72 h: 3.6 - 4.6 mg/l Toxicity to Micro-organisms

EC50; Bacteria, 16 h: > 12 mg/l Toxicity to Soil Dwelling Organisms

LC50, Eisenia fetida (earthworms), 2 d: 0.047 mg/cm2 Data for Component: Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <= 700)


LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 h: 2 mg/l Aquatic Invertebrate Acute Toxicity

EC50, Daphnia magna (Water flea), static test, 48 h, immobilization: 1.8 mg/l Aquatic Plant Toxicity

ErC50, Scenedesmus capricornutum (fresh water algae), static test, Growth rate inhibition, 72 h: 11 mg/l Toxicity to Micro-organisms

IC50; Bacteria, 18 h: > 42.6 mg/l Aquatic Invertebrates Chronic Toxicity Value

Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, NOEC: 0.3 mg/l Data for Component: Acetone; propanone

Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/L in most sensitive species). Fish Acute & Prolonged Toxicity LC50, Oncorhynchus mykiss (rainbow trout), 96 h: 5,500 - 6,100 mg/l Aquatic Invertebrate Acute Toxicity

EC50, Daphnia magna (Water flea), 48 h, immobilization: 6,084 mg/l LC50, Ceriodaphnia Dubia (water flea), 48 h: 8,098 mg/l Aquatic Plant Toxicity

EC50, Skeletonema costatum, biomass growth inhibition, 5 d: 11,800 - 14,400 mg/l

12.2 Persistence and Degradability

Data for Component: Toluene

Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. OECD Biodegradation Tests:

Biodegradation Exposure Time Method 10 Day Window

100 % 14 d OECD 301C Test Not applicable

Data for Component: Xylene

Material is expected to be readily biodegradable.


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100 % 6 d OECD 301E Test pass

Data for Component: Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <= 700)

Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. OECD Biodegradation Tests:


12 % 28 d OECD 302B Test Not applicable

Data for Component: Acetone; propanone



91 % 28 d OECD 301B Test pass

12.3 Bioaccumulative potential Data for Component: Toluene

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient, n-octanol/water (log Pow): 2.73 Measured Bioconcentration Factor (BCF): 13.2 - 90; Fish; Measured

Data for Component: Xylene Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient, n-octanol/water (log Pow): 3.12 Measured Bioconcentration Factor (BCF): 15 - 21; Fish; Measured

Data for Component: Ethylbenzene Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient, n-octanol/water (log Pow): 3.15 Measured Bioconcentration Factor (BCF): 15; Fish; Measured


Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log

Pow between 3 and 5). Partition coefficient, n-octanol/water (log Pow): 3.242 Estimated.

Data for Component: Acetone; propanone Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient, n-octanol/water (log Pow): -0.24 Measured Bioconcentration Factor (BCF): 0.69; Fish; Measured

12.4 Mobility in soil

Data for Component: Toluene Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 37 - 178 Estimated. Henry’s Law Constant (H): 6.46E-03 atm*m3/mole; 25 °C Estimated.

Data for Component: Xylene Mobility in soil: Potential for mobility in soil is medium (Koc between 150 and 500). Partition coefficient, soil organic carbon/water (Koc): 443 Estimated. Henry’s Law Constant (H): 7.45E-03 atm*m3/mole; 25 °C Estimated.

Data for Component: Ethylbenzene Mobility in soil: Potential for mobility in soil is low (Koc between 500 and 2000). Partition coefficient, soil organic carbon/water (Koc): 518 Estimated. Henry’s Law Constant (H): 8.44E-03 atm*m3/mole; 25 °C Measured


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Mobility in soil: Potential for mobility in soil is low (Koc between 500 and 2000)., Given its

very low Henry’s constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient, soil organic carbon/water (Koc): 1,800 - 4,400 Estimated.

Data for Component: Acetone; propanone Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 0.37 - 2.0 Estimated. Henry’s Law Constant (H): 1.38E-05 atm*m3/mole; 25 °C Estimated.

12.5 Results of PBT and vPvB assessment

Data for Component: Toluene

This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).


Non-classified PBT substance Non-classified vPvB substance Data for Component: Ethylbenzene

This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB).


This substance is not considered to be persistent, bioaccumulating and toxic (PBT). Data for Component: Acetone; propanone

This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

12.6 Other adverse effects Data for Component: Toluene

This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.







Data for Component: Acetone; propanone This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

Section 13. Disposal Considerations

13.1 Waste treatment methods

This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water. Incineration under approved, controlled conditions using incinerators suitable or designed for the disposal of hazardous chemical wastes, is the preferred method for disposal. Treatment and disposal methods of used packaging: Empty containers should be recycled or

otherwise disposed of by an approved waste management facility. CONTAMINATED PACKAGING: Any disposal of contaminated packaging and washings must be in accordance with State, Territory


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and/or Local government regulations. After container has been cleaned and labelling has been removed, empty containers can be sent for recycling or disposal. If the container is to be reconditioned, the reconditioning company should be made aware of the nature of the original contents.

Section 14. Transport Information

ADR/RID 14.1 UN number

UN1139 14.2 UN proper shipping name

Proper Shipping Name: COATING SOLUTION 14.3 Transport hazard class(es)

Hazard Class: 3 14.4 Packing Group

PG II 14.5 Environmental hazards

Not considered environmentally hazardous based on available data 14.6 Special precautions for user

Special Provisions: Special provision 640D

Hazard identification No:33

ADNR / ADN 14.1 UN number






no data available

IMDG 14.1 UN number

UN1139 14.2 UN proper shipping name Proper Shipping Name: COATING SOLUTION 14.3 Transport hazard class(es)




EMS Number: F-E,S-E 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

ICAO/IATA 14.1 UN number




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no data available

Section 15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

European Inventory of Existing Commercial Chemical Substances (EINECS)

The components of this product are on the EINECS inventory or are exempt from inventory requirements.

15.2 Chemical Safety Assessment Not applicable.

Section 16. Other Information

Hazard statement in the composition section

H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.

Risk-phrases in the Composition section R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36 Irritating to eyes. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R43 May cause sensitization by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through

inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment. R63 Possible risk of harm to the unborn child. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking.


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R67 Vapours may cause drowsiness and dizziness.

Revision

Identification Number: 1004078 / 3005 / Issue Date 2013/09/05 / Version: 7.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.

safety data sheet - antala

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