dispex ultra px 4290 - basf · 2020. 9. 11. · dispex® ultra px 4290 new high molecular weight...
TRANSCRIPT
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Dispex® Ultra PX 4290 Dispersing agent with a broad
use range and best results with
inorganic and organic pigments
Ludwigshafen, 09. April 2020
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2
Peter Bene
Technical Sales
Formulation Additives
EMEA region
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3
1. Introduction
2. Performance highlights resin-free Pigment Concentrates
3. Performance highlights Furniture & Flooring
4. Performance highlights Printing & Packaging
(e.g. ink-jet inks)
5. Summary
Agenda
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Our comprehensive portfolio enables
solutions for various industries
4
Architectural
Coatings
Industrial Coatings
Automotive
Coatings
Furniture &
FlooringAdhesives Construction
Printing &
PackagingComposites
BASF is the premiere provider of Performance & Formulation Additives
for the paints and coatings industry
Rheology
ModifiersDefoamers
Dispersing
Agents
Film-forming
Agents
Wetting Agents &
Surface
Modifiers
Light Stabilizers
& Anti-oxidants
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Strong brands to empower your business
5
Water-based brands Application Solvent-based* brands
Dispex® / Dispex® Ultra DISPERSING AGENTS Efka®
Foamaster® / FoamStar® DEFOAMERS Efka®
Rheovis® (organic) / Attagel® (clays) RHEOLOGY MODIFIERS Efka®
Hydropalat® WETTING AGENTS Efka®
Loxanol® FILM-FORMING AGENTS Efka®
Tinuvin® / Lignostab® LIGHT STABILIZIERS Tinuvin® / Chimassorb®
Irganox® ANTIOXIDANTS Irganox® / Irgafos® / Irgastab®
*Efka® includes also High Solids and 100% Solid Systems
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A typical challenge…
many standard dispersing agents only show peak performance
with a few pigments.
Customers are increasingly looking for dispersing agents with a
broad use range and best results with both inorganic and
organic pigments.
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Dispex® Ultra PX 4290 is a broad spectrum, high molecular weight
dispersing agent for a broad range of both - organic and inorganic -
pigments in aqueous coating systems, printing inks and adhesives.
❖ with excellent pigment stabilizing characteristics
❖ and outstanding color strength and viscosity reduction
This allows higher pigment loadings while excellent flow
characteristics are maintained.
…a simple solution
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Dispex® Ultra PX 4290New high molecular weight dispersing agent for organic and inorganic pigments in aqueous coating systems,
printing inks and adhesives.
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Performance highlights:
Dispex® Ultra PX 4290 is a dispersing
agent for organic and inorganic pigments
in aqueous systems.
Due to the excellent stabilizing
characteristics, outstanding color strength
and excellent viscosity reduction can be
achieved.
This allows also higher pigment loadings
while excellent flow characteristics are
maintained.
◼ Designed to stabilize inorganic and organic pigments in aqueous
formulations
◼ Improved color strength and transparency
◼ Improved gloss
◼ Anti-flooding behavior
◼ Excellent flocculation stability
◼ Solvent-free
Application: Characteristic Values:
Appearance Clear, yellowish liquid
Solvent water
Density ~ 1.06 g/cm3
Active content ~ 40%
◼ Label-free
◼ Food Contact Compliance
◼ Suitable for a broad range
of applications
Sustainability
highlights:
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9
1. Introduction
2. Performance highlights resin-free Pigment Concentrates
3. Performance highlights Furniture & Flooring
4. Performance highlights Printing & Packaging
(e.g. ink-jet inks)
5. Summary
Agenda
-
Dispex® Ultra PX 4290 offers excellent pigment stabilizing
characteristics with inorganic and organic pigments
10
-2
-1
0
1
2
Benchmark 1 Dispex® Ultra PX 4290before storage
Dispex® Ultra PX 4290after storage
Kronos® 2160
Bayferrox® 3920
Hansabrillant® Yellow 2GX70
Hostaperm® Violet RL special
Hostaperm® Red Violet ER 02
Irgazin® Red L 3660 HD Novoperm® Red F3RK 70
Hostaperm® Pink E
Bayferrox® 130 M
Novoperm® Orange HL 70 NF
Hostaperm® Yellow H3G
Novoperm® Yellow HR 70
Heliogen® Blue L 6875 F
Heliogen® Green L 8730
Colour Black® FW 200
Monarch® 1000
Raven® 5000
Viscosities of resin-free
Pigment Concentrates before
and after storage (2w 50°C).
Rating: 2 – much better
1 – better
0 – equal to standard
Rating
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…and outstanding color strength and viscosity reduction
11
80
90
100
110
120
Market standard [100% color strength]
Dispex® Ultra PX 4290 relative color strength [%]
Kronos® 2160
Bayferrox® 3920
Hansabrillant® Yellow 2GX70
Hostaperm® Violet RL special
Hostaperm® Red Violet ER 02
Irgazin® Red L 3660 HD Novoperm® Red F3RK 70
Hostaperm® Pink E
Bayferrox® 130 M
Novoperm® Orange HL 70 NF
Hostaperm® Yellow H3G
Novoperm® Yellow HR 70
Heliogen® Blue L 6875 F
Heliogen® Green L 8730
Colorblack® FW 200
Monarch® 1000
Raven® 5000
Benchmark 1 [100% color strength]
Relative color strength of
resin-free Pigment
Concentrates.
2% Pigment Concentrate in
Rubbol BL Azura (wb white PU/Alkyd paint)
relative
color strength
[%]
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12
Storage stability of Pigment Concentrate based on PR 101
(Bayferrox® 130 M)
0
1.000
2.000
3.000
4.000
Benchmark 1 Dispex® Ultra PX 4290
After 2 weeks at 50°C
1 10 100 1000
5610
shear rate in 1/s
Vis
co
sit
y i
n m
Pa
. S
0
1.000
2.000
3.000
4.000
Benchmark 1 Dispex® Ultra PX 4290
Before storage
1 10 100 1000
Vis
co
sit
y
in m
Pa
. S
shear rate in 1/s
◼ Dispex® Ultra PX 4290 shows lower viscosity after 2 weeks at 50°C.
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13
Color strength and rub-out dE with paint based on PR 101
(Bayferrox® 130 M)
0
0,2
0,4
0,6
0,8
1
0
20
40
60
80
100
Benchmark
1
Dispex® Ultra PX 4290
Ru
b-o
ut
in d
E
Rela
tive
Co
lor
str
en
gth
*2% Pigment Concentrate in
Rubbol BL Azura (wb white PU/Alkyd paint)
Dispex® Ultra PX 4290
imparts higher color
strength and improved
rub-out.
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14
Storage stability of Pigment Concentrate based on PB 15:3
(Heliogen® Blue L 6875 F)
0
1.000
2.000
3.000
4.000
Benchmark 1 Dispex® Ultra PX 4290
After 2 weeks at 50°C
1 10 100 1000
shear rate in 1/s
Vis
co
sit
y i
n m
Pa
. S
0
1.000
2.000
3.000
4.000
Benchmark 1 Dispex® Ultra PX 4290
Before storage
1 10 100 1000
5,790
Vis
co
sit
y
in m
Pa
. S
shear rate in 1/s
◼ Dispex® Ultra PX 4290 shows lower viscosity initially and after 2 weeks at 50°C.
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15
Color strength and rub-out dE with paint based on PB 15:3
(Heliogen Blue L 6875 F)
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
0
20
40
60
80
100
120
Benchmark1
Dispex® Ultra PX 4290
Ru
b-o
ut
in d
E
Re
lati
ve
Co
lor
str
en
gth
*2% Pigment Concentrate in
Rubbol BL Azura (wb white PU/Alkyd paint)
Dispex® Ultra PX 4290 shows
comparable color strength
and rub-out .
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16
1. Introduction
2. Performance highlights resin-free Pigment Concentrates
3. Performance highlights Furniture & Flooring
4. Performance highlights Printing & Packaging
(e.g. ink-jet inks)
5. Summary
Agenda
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Rheological behavior in a wb white wood coating
based on Joncryl® 9500
0
1000
2000
3000
4000
5000
6000
Benchmark 1 Dispex Ultra PX 4560 Dispex Ultra PX 4575 Dispex Ultra PX 4585 Dispex Ultra PX 4290 Benchmark 3 Benchmark 4
Vis
cosi
ty[m
Pas
]
1 1/s
10 1/s
100 1/s
400 1/s
1000 1/s
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◼ Dispex® Ultra PX 4290 shows comparable to better results in terms of rheology vs.
most benchmarks.
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Anti-settling behavior after storage in white wood coating
based on Joncryl® 9500
0
1
2
3
4
5
6
Benchmark 1 Dispex Ultra PX 4560 Dispex Ultra PX 4575 Dispex Ultra PX 4585 Dispex Ultra PX 4290 Benchmark 3 Benchmark 4
*5 = good (no settling)
1 = bad (strong settling)
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◼ Dispex® Ultra PX 4290 shows better results with regards to settling of TiO2 against benchmarks . In addition stain resistance was comparable vs. internal and external standards.
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19
1. Introduction
2. Performance highlights resin-free Pigment Concentrates
3. Performance highlights Furniture & Flooring
4. Performance highlights Printing & Packaging
(e.g. ink-jet inks)
5. Summary
Agenda
-
Dispex® Ultra PX 4290 offers excellent pigment stabilizing
characteristics with inorganic and organic pigments
20
Overall performance rating
Rating: 5; 4-5 – best
4 – acceptable
< 3-4 – not accptable.
0
1
2
3
4
5
Overall rating Pigment Concentratewith Dispex® Ultra PX 4290
Dispex® Ultra PX 4290 Dispex® Ultra PX 4575
Dispex® Ultra PX 4585 Dispex® Ultra FA 4437
Paliotol® Yellow D 0960
Paliotol® Yellow D 1080 J
Paliotol ®Yellow D 1080 J
PY 74
Irgalite® Orange D 2980
Irgalite® Rubin D 4280
Cinquasia® Magenta D 4550
Cinquasia® Magenta D 4500 J
Cinquasia® Magenta D 4570
Irgazin® Red L 3630
Irgazin® Red D 3656 HD
Irgazin® Red L 3670 HD
Cinquasia® Red L 4100 HD
Cinquasia® Violett D 5800
Heliogen® Blue S 7320
Heliogen® Blue D 7086
Heliogen® Blue D 7115 F
Heliogen® Blue D 7490
Heliogen® Green D 8730
PY 155
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21
Performance tests – Formulation based on PY 150
(Paliotol® Yellow D 1085 J)
0
10
20
30
40
50
Dispex® UltraPX 4290
Dispex® UltraPX 4575
Dispex® UltraPX 4585
Dispex® UltraFA 4437
Before storage
1 10 100 1000Rheology in 1/s
Vis
co
sit
yin
mP
a. S
viscosity to high
0
10
20
30
40
50
Dispex® UltraPX 4290
Dispex® UltraPX 4575
Dispex® UltraPX 4585
Dispex® UltraFA 4437
After 2 weeks at 50°C
1 10 100 1000
not applicable
Rheology in 1/s
Vis
co
sit
yin
mP
a. S
◼ Dispex® Ultra PX 4290 shows best viscosity even after storage. Anti-settling and particle sizewas also very good.
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22
Performance tests – Formulation based on PR 57:1
(Irgalite® Rubine D 4280)
0
25
50
75
100
125
150
Dispex® Ultra PX4290
Dispex® Ultra PX4575
Dispex® Ultra PX4585
Dispex® UltraFA 4437
Before storage
1 10 100 1000
Rheology in 1/s
n.a.
343227
Vis
co
sit
yin
mP
a. S
0
25
50
75
100
125
150
Dispex® UltraPX 4290
Dispex® UltraPX 4575
Dispex® UltraPX 4585
Dispex® UltraFA 4437
After 2 weeks at 50°C
1 10 100 1000
Rheology in 1/s
n.a.*Stability is nOK
Vis
co
sit
yin
mP
a. S
*Strong increase of viscosity
after storage
◼ Dispex® Ultra PX 4290 shows best viscosity even after storage in comparison to benchmarks. Anti-settling and particle size was also very good.
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23
1. Introduction
2. Performance highlights resin-free Pigment Concentrates
3. Performance highlights Furniture & Flooring
4. Performance highlights Printing & Packaging
(e.g. ink-jet inks)
5. Summary
Agenda
-
Summary
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Dispex® Ultra PX 4290
▪ Excellent pigment stabilizing characteristics with a broad range of organic pigments but also
for inorganics like TiO2▪ Results in outstanding color strength and viscosity reduction,
▪ which allows higher pigment loadings whilst maintaining excellent flow characteristics
▪ which leads to an enhanced formulation flexibility
▪ New dispersant for water-based applications for a broad range of applications such as
▪ Printing and Packaging (ink-jet, but also resin-free and resin-based Flexo inks)
▪ Furniture and Flooring
▪ General Industrial
▪ Resin-free Pigment Concentrates for industrial applications
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Contacts
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Dr. Sascha Oestreich
Head of Technical Sales Formulation Additives
Phone: + 49 211 7940-9028
Mobile: +49 173 5396101
Peter Bene
Technical Sales Formulation Additives
Phone: +49 211 7940-5927
Mobile: +49 173 5117438
Andrea Schamp
Marketing Formulation Additives Europe
Phone: +49 211 7940-2605
Mobile: +49 173 5936561
internet: http://www.basf.com/additives
email: [email protected]
http://www.basf.com/additivesmailto:[email protected]