dibenzo[g,m]azacorannulene esi 170108dibenzo[g,m]azacorannulene esi 170108 author: ltscott created...
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5-Azadibenzo[a,g]corannuleneV.M.Tsefrikas,A.K.GreeneandL.T.Scott*
ElectronicSupplementaryInformation
NMRspectraofcompounds6,9,10,11,12,13a,13b,14a,14b,15,18,20,and22 pagesS2-S27
FigureESI1.UV-VISspectraof5-azadibenzo[a,g]corannulene(6)beforeandafteracidaddition pageS28
FigureESI2.UV-VISspectraof5-azadibenzo[a,g]corannulene(6)plusacidplusbase pageS28
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.This journal is © the Partner Organisations 2017
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0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
8.00
8.50
9.00
N
TMS
1 H N
MR
(500
MH
z, C
DC
l 3)
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050
100
150
200
N
TMS
13C
NM
R (1
25 M
Hz,
CD
Cl 3)
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0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
7.50
8.00
8.50
9.00 1 H
NM
R (5
00 M
Hz,
CD
Cl 3)
N
H
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1 H N
MR
(500
MH
z, C
DC
l 3)
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
8.00
8.50
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Figure ESI 1. UV-VIS spectra (CH2Cl2) of 5-azadibenzo[a,g]corannulene (6) before and after addition oftrifluoroaceticacid.
FigureESI2.UV-VISspectra(CH2Cl2)of5-azadibenzo[a,g]corannulene(6),neutralizedwithtriethylamineafteradditionoftrifluoroaceticacid.