cylindrical cr battery - produktsøknrfportal.vvsnrf.no/assets/1163/hms/sikkerhetsdatablad...

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1/4 Product Name: Sizes: Date of preparation: Cylindrical Type Lithium Manganese Dioxide Battery (CR) All Jan. 1, 2015 Company: Telephone Numbers: Hitachi Maxell, Ltd., Energy Division 81-(0)794-63-8054 Address (Number, Street, City, State, and ZIP Code): Fax Numbers: 5, Takumidai, Ono-shi, Hyogo 675-1322, Japan 81-(0)794-63-8445 Ingredient CAS# Content (wt%) Manganese Dioxide (MnO2) 1313-13-9 30 to 50 Propylene Carbonate (C4H6O3) 108-32-7 3 to 10 1,2-Dimethoxyethane (C4H10O2) 110-71-4 5 to 15 Lithium trifluoro methane 33454-82-9 0.1 to 1.5 sulphonate (LiCF3SO3) Lithium or Lithium Alloy (Li) 7439-93-2 2 to 5 Carbon (C) 7782-42-5 0.5 to 3 The batteries are exempt articles and are not subject to the OSHA Hazard Communication Standard Requirement. This sheet is provided as technical information only. The information and recommendations set forth are made in good faith and are believed to be accurate as of the date of preparation. However, Maxell makes no warranty expressed or implied. Cylindrical Type CR Battery Product Safety Data Sheet Section 1 - Product and Company Identification Section 2 - Composition/Information on Ingredients Model Li content (g) CR17335 A 0.6 CR17335 0.6 Model Li content (g) CR17450 A 0.85 CR17450 0.85 Section 3 - Hazards Identification This contains lithium, organic solvent, and other combustible materials. For this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, or fire and cause human injury or equipment trouble. Please strictly observe safety instructions. (* Leakage is defined as an unintended escape of liquid from a battery.) Section 4 - First Aid Measures None unless internal materials exposure. If contents are leaked out, observe following instructions. Inhalation Fumes can cause respiratory irritation. Remove to fresh air and consult a physician. Skin Immediately flush skin with plenty of water. If itch or irritation by chemical burn persists, consult a physician. Eyes Immediately flush eye with plenty of water for at least 15 minutes. Consult a physician immediately. Ingestion If swallowing a battery, consult a physician immediately. If contents come into mouth, immediately rinse by plenty of water and consult a physician. Lithium content for each cell Reference No. CC150101-1

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Page 1: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

1/4

Product Name: Sizes: Date of preparation:

Cylindrical Type Lithium Manganese Dioxide Battery (CR) All Jan. 1, 2015

Company: Telephone Numbers:

Hitachi Maxell, Ltd., Energy Division 81-(0)794-63-8054

Address (Number, Street, City, State, and ZIP Code): Fax Numbers:

5, Takumidai, Ono-shi, Hyogo 675-1322, Japan 81-(0)794-63-8445

Ingredient CAS# Content (wt%)

Manganese Dioxide (MnO2) 1313-13-9 30 to 50

Propylene Carbonate (C4H6O3) 108-32-7 3 to 10

1,2-Dimethoxyethane (C4H10O2) 110-71-4 5 to 15

Lithium trifluoro methane33454-82-9 0.1 to 1.5sulphonate (LiCF3SO3)

Lithium or Lithium Alloy (Li) 7439-93-2 2 to 5

Carbon (C) 7782-42-5 0.5 to 3

The batteries are exempt articles and are not subject to the OSHA Hazard Communication StandardRequirement. This sheet is provided as technical information only. The information and recommendationsset forth are made in good faith and are believed to be accurate as of the date of preparation. However,Maxell makes no warranty expressed or implied.

Cylindrical Type CR Battery

Product Safety Data Sheet

Section 1 - Product and Company Identification

Section 2 - Composition/Information on Ingredients

Model Li content (g)

CR17335 A 0.6

CR17335 0.6

Model Li content (g)

CR17450 A 0.85

CR17450 0.85

Section 3 - Hazards IdentificationThis contains lithium, organic solvent, and other combustible materials. For this reason, improper handling of the battery could lead todistortion, leakage*, overheating, explosion, or fire and cause human injury or equipment trouble. Please strictly observe safetyinstructions.(* Leakage is defined as an unintended escape of liquid from a battery.)

Section 4 - First Aid MeasuresNone unless internal materials exposure. If contents are leaked out, observe following instructions.

Inhalation Fumes can cause respiratory irritation. Remove to fresh air and consult a physician.

Skin Immediately flush skin with plenty of water. If itch or irritation by chemical burn persists, consult a physician.

Eyes Immediately flush eye with plenty of water for at least 15 minutes. Consult a physician immediately.

Ingestion If swallowing a battery, consult a physician immediately. If contents come into mouth, immediately rinse by plenty of water and consult a physician.

Lithium content for each cell

Reference No. CC150101-1

Page 2: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

2/4

Cylindrical Type CR BatteryProduct Safety Data Sheet

Section 5 - Fire Fighting MeasuresExtinguishing Media Extinguisher of alkaline metal fire is effective.

Plenty of cold water is also effective to cool the surrounding area and control the spread fire. But hydrogengas may be evolved by the reaction of water and lithium and it can form an explosive mixture. Therefore in thecase that lots of lithium batteries are burning in a confined space, use a smothering agent (e.g. carbon dioxideor dry sand).

Fire fighting procedure Use self-contained breathing apparatus and full protective gear not to inhale harmful gas.

Section 6 - Accidental Release MeasuresIf the battery releases liquid, wipe it with a dry cloth.Keep the battery away from fire or heat.

Section 7 - Handling and Storage1) Handling

• Never swallow.If a battery is accidentally swallowed, see Section 4 - First Aid Measures.

• Never charge.The battery is not designed to be charged by any electrical source. Charging can generate gas and internal short-circuiting, leading todistortion, leakage, overheating, explosion or fire.

• Never heat.Heating the battery to more than 100 deg. C can increase the internal pressure, causing distortion, leakage, overheating, explosion orfire.

• Never expose to naked flames.Exposing to naked flames can cause the lithium metal to melt, causing the battery to catch fire and explode.

• Never disassemble or deform.Disassembly or deforming the battery can cause leakage, overheating, explosion or fire due to internal short-circuits.

• Never reverse the positive and negative terminals when inserting in electrical equipment.Inserting the battery incorrectly can lead to short-circuiting, charging or forced-discharging. This can cause distortion, leakage,overheating, explosion or fire.

• Never short-circuit the battery.Do not allow the positive and negative terminals to short-circuit. Never carry or store the battery with metal objects such as necklacesor hairpins. Do not take multiple batteries out of the package and stack or mix them when storing. Otherwise, this can lead todistortion, leakage, overheating, explosion or fire.

• Never weld the terminals or weld wire to the body of the battery.The heat of welding or soldering can cause the lithium to melt or cause damage to the insulating material in the battery. This cancause distortion, leakage, overheating, explosion or fire.

• Never use different batteries together.Using different batteries together, i.e. different types or old/used and new or those of different manufacturers, can cause distortion,leakage, overheating, explosion or fire because of the differences in battery properties. Please consult Maxell before designing devicesthat use two or more batteries connected in a series or parallel, even with the same battery type.

• Never touch liquid leaking from a battery.If the liquid enters the eyes or mouth, see Section 4 - First Aid Measures.

• Never allow battery liquid to come into contact with a naked flame.If leakage or a strong odor is detected, keep the battery away from all naked flames. The leaked liquid is inflammable.

• Never attach a battery to the skin.Attaching a battery to the skin using tape, etc. should be avoided. Moisture from the skin can cause battery discharge, which canproduce certain chemical substances that burn the skin.

2) Storage

Never let the battery contact with water. Never store the battery in hot and high humid place.

Page 3: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

3/4

Cylindrical Type CR BatteryProduct Safety Data Sheet

Section 8 - Exposure Controls, Personal ProtectionRespiratory Protection NA

Ventilation Local Exhaust NA

Mechanical NA

Special NA

Other NA

Eye Protection NA

Protective Gloves NA

Other protective clothing NA

Section 9 - Physical/Chemical CharacteristicsCylindrical shape with primary cell of 3V nominal voltage

Section 10 - Stability and ReactivityStability Stable (Performance deterioration depends on circumstances.)

Incompatibility Water

Hazardous polymerization Will not occur.

Condition to avoid See section 7.

Hazardous Decomposition or Byproducts Hydrogen

Section 11 - Toxicological InformationAs the contents are sealed in the battery case, there is no toxicity.

Section 12 - Ecological InformationIf the battery is disposed of on land or in water, the battery case may corrode and liquid may leak from the battery. Ecologicalinformation has not been reported.

Section 13 - Disposal ConditionThe battery may be regulated by national or local regulation. Please follow the instructions of proper regulation. As electric capacity isleft in a discarded battery and it comes into contact with other metals, it could lead to distortion, leakage, overheating, or explosion, somake sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal.

Section 14 - Transportation Information1) Shipping Name (UN Number) Lithium metal batteries (UN3090)

Lithium metal batteries packed with equipment (UN3091)

Lithium metal batteries contained in equipment (UN3091)

2) Hazard Classification Class 9 (Miscellaneous)

3) Method of transportation: As the cells are manufactured under a quality management program in an ISO9001 certified factory and thecells meet all the requirements of a UN manual of tests and criteria, Part III, sub-section 38.3, the applicable packing instructions (PI)or special provisions (SP) are as per the following table.The cells or batteries classified in Section II of any Packing Instruction or SP 188 may be exempted from Class 9 Dangerous Goods ifcomplying with all requirements of applicable Section II or SP 188. But lithium metal cells and batteries transported as cargo arerestricted to Cargo Aircraft Only beginning Jan. 1, 2015.

Note. This does not apply to lithium metal batteries packed with equipment (PI 969) or contained in equipment (PI 970).

Page 4: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

4/4

Please confirm the aggregate lithium content when transport the battery.

Section 15 - Regulatory InformationMajor applicable regulations for the transportation of lithium metal cells and batteries are as follows:

1) UN (United Nations) Recommendations on the Transport of Dangerous Goods: Model Regulations 18th revised edition

2) UN (United Nations) Recommendations on the Transport of Dangerous Goods: Manual of Test and Criteria 5th revised edition,Amendment 2

3) International Civil Aviation Organization (ICAO): Technical Instructions for the Safe Transport of Dangerous Goods by Air, 2015-2016Edition

4) International Air Transport Association (IATA): Dangerous Goods Regulations, 56th Edition 6) International Maritime Organization (IMO): International Maritime Dangerous Goods (IMDG) Code, 2014 Edition

Section 16 - Other InformationMajor environmental regulation is as follows:

EU Battery Directive 2006/66/EC

If you want further information, please contact your locall sales representative.

NA=Not Applicable

Cylindrical Type CR BatteryProduct Safety Data Sheet

As specific districts, countries and airlines may establish their own special requirements, the shipper must confirm requirementswith the forwarder in advance.

Li content per cell Product name

Air *See Section 15 4)Sea *See

Section 15 5)Cell only Cell packed with

equipmentCell contained in

equipment

Not more than 0.3 g (No) PI 968 Section II PI 969 Section II PI 970 Section II SP 188

More than 0.3 gbut not more

than 1 g

CR17450 A, CR17450,CR17335 A, CR17335

PI 968 Section IB(8 or less cells:

Section II)PI 969 Section II PI 970 Section II SP 188

More than 1 g (No) PI 968 Section IA PI 969 Section I PI 970 Section I SP 230

Page 5: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Safety lnstructions

This bahery a hgh energy densityseied batteiy ntaining dan9erous (Utlium) and deletedaus fYhion Chiodde) materiale. For iNs mason, improperhandling at Ihe battery cauld led to dstortion, leakage, overheating, explosion, be. ar generation of irritatinWcorrosive gases, causing bodily injury areqipment tmuble. Please abserve the fallawing insbuctioris ta prevent accidents.For fram your customers to your industdal waste processors (including recycied pmcessor, please have them fully understand these instnjctians.

Leakage is dermed ss the urntentionaI escape at a liquid fram a ballery.)

Warnings — Handling

Do not recharge

• Never swallow.Aiways keep the battery aut af the reach at infants and youngchildren to prevent it from being swallowed. II swallowed. consult aphysidan immediately.

• Never apply an excessive force to the positive terminal.Because the positive termina! is seajed by a glass. subjecting thisarea to sudden jolts and excessive force (over 19.6 N) could destroythe glass seal. This cauld cause teakage and the genemtian atirritating/corrosive gases.

• Never drop.Dropping the battery could destroy the g!ass seal leading to leakageand the generation at irdtating/carrasive gases.

I Never weld the terminals or weld a wire to the body et thebafte, directly.

Tha hest at we!ding ar soldedng coutd cause the lithium to mek, orcause damage to Ihe insulating maledal in the battery, leading topossible distartian, leakage, overheating, explasian, ar fire, orgeneration at irritating/corrosive gases. When soldering the batterydirecily to equipment, solder only the tabs ar leads. Even then, thetemperature af the sotdedng iran must be below 350 deg. C and thesoldering time less than 5 seconds. Do not use a soldedng bath,because Ihe circuit board with battery attached could stop movingar the battery cauld drap into the bath. Mareaver do not usaexcessive solder, because the solder cauld flow to unwantedportions at the baard, leading to a shah-circuit ar charging at thebattery.

• Never short-circuit the battery.Do not allow the positive and negative terminals to short-circuit.Never cany ar store the battely with metal objects such as anecklace ar a hairpin. Do not take multiple battedes aut of thepackage and pile ar mix tham when storing. Otherwise, this couldlead to distortion, teakage, overheating. and explosian at the battery.

• Never charge.The battery is not designed to be charged by any other electrical

source. Charging cauld generate gas and internal short-circuiting,leading to distodion, leakage. averheating, explosion, fire, argenemtian at irritating/coaosive gases.

• Never forcibly discharge.Forcibly discharging by an extemal power source or olher batieriescould cause the voltage to fall below CV (reversing the poles),generating gas inside the battery and leading ta distartion, leakage.averheating, explasian. fire, ar generalion at irritatingJcorrosivegases.

• Never hest.Heating the battery to more than 100 deg. G cauld increase theintemal pressure, causing distortion, leakage, overheating,explosion, tre, ar generatian at initating/carrasive gases.

• Never expose ta open tiames.Exposing to flames could cause (he lithium metal to malt, causingthe battery to catch on fire and explode.

• Never disassembie the battery.Disassembty could generate the irritatingfcontsive gases. Inaddition, the lithium metal inside the baftery could overheat leadingto catch on fire.

• Never detorm.Defonning could cause leakage, overheating, explosion, fire, Drgeneration at irritating/corrosive gases.

• Never reverse the positive and negative terminals whenmounting.

lmproper mounting af the battery cauld lead to short-circuiting,charging ar forced-discharging. This could cause distortion,leakage. overheating, explosion, fire, ar generation atirritating/carrosive gases.

• Never lise different batteries togeiher.Using different battanes together, i.e. ditterent type ar used and newar different manufacturer could cause distortion, leakage,overheating, explosion, fire, ar generatian at irritating/corrosivegases because at the ditferences in battery property. If using two ormore battedes connected in sedes or in parallel even same battedes,please consult with Maxell betore using.

Primary Batteiy

LITHIUM THIONYL CHLORIDE BATTERY

30

Page 6: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Primary Baftenj

• Never allow Iiquid leaking fram the batteiy toget’n your eyesDr mouth.

Because this iquid cauld cause sedaus damage, it it does came incontact with your eyes, tlush them immediately with plenty at waterand cansult a physician. Likewise, if the Ifquid gets in yaur mouth,rinse immediately with plenty ot water and consult a physician.

• Never touch the battery electrodes.Do not allow the batteiy electrodes to come in contact with your skinar tingers. øtherwise, the maisture fram ycur skin cauld cause adischarge ot the battery, which cauld praduce certain chemicalsubstances causing you to receive a chemical bums.

jWarnings — Circuit Design for Back-up Use

This is a primary battery and cannot be charged. If used in memoryor RTC back-up applications, be sure to usa diodes to preventcharging fram the main pawer saurce ar ather battedes, endaprotective resistor to regulate the current as shawn in the figurebelaw. Nate that the paints described belaw shauld be taken intocaretul consideration when selecting diodes and protective resistors.

blod. Diod, — -.r t1 { .5V *1 • {Load]

Diod. + mcd. Å

PmI.cffv,- blod.

resisto, iBanery flaU.,y —

• Supplied voltage to badBecause a diade enda resistor generate the valtage drap onaperating, please take into cansideratian these vottage drops farsupplied voltage ta bad.

• Using diodes to prevent chargingPlease choose diodes with leak current of no more than O.5pA.

• Using and setting protective resistorsA protective resistar is used toprevent the battery from beingcharged by large surges at currentduring diode failure. Please setthe resistor sa that the maximumcurrent shawn in the dght table isnot exceeded. For exampte, sayan ER6 battery is used in samplecircuit (A) in cambinatian with amain power source 5 volt. Since the permitted charge current islODpA and this battery’s voltage is 3.6V, et the resistor be R(5V-3.6\/1COpA=14k ahm, meaning that at least 14k ahm isrequired.

Nate: If the diades brake down! it is necessasy for safety ta replacethem as soan as possible even though using a protective resistar.Cansidering the trauble at diades and resistars, alher safetymeasures should be incarparated in the circuit design.

Warnings — Disposal

The battery may be regulated by Tapenational or local regulatian. Pleasetolbow the instructions ot proper

‘regulation. As electric capacity islett in a discarded battery and itcomes into contact with othermetals, it could lead ta distortian, eleakage, averheating, orexptasian,5° make sure to Gaver the (+) and Tape

(—) terminals with fdction tape ar - — —

same ather insulatar betare (Exwxipte at battery Insulation)

disposal.

ÆCaution — Handling

• Minimum translent voltageThe various tests have shawn that the minimum transient valtage isintluenced greatly by the actual canditians at use and storage.Therefare, please design yaur circuits using no more than thestandard discharge current, taking into accaunt the valtage drap dueto the minimum transient valtage. Please consult with Maxellbetorehand if you are unsure at anything.

• Installing, removing, and disposing of bafteries1) When instalting a battery in a device, make sure that the positiveterminal is tacing up, ar at least ta the side. As this battery usesliquid thianyl chladde as the positive active material, placing thepositive terminal at the bottom wi?I cause the thionyl chladde tobecame maldistributed, which cauld prevent the neededperfarmance fram being abtained when a large amaunt at current isused.

2) Please have the installatian, removal, and dispasat at this batteryperfarmed by a technician with a tharaugh understanding at theWarnings and Cautions on handling.

3) Please remove and dispose at the battery when device is nobanger in use. If the battery is lett in the device, electralyte may teakfram the battery generating irdtating/carrasive gas.

4) If the sealed area is damaged in any way, carrasive andconductive electrotyte may leak fram the battery. Please considerthis when designing devices.

• StorageAvoiding stodng the battery in direct suntight, ar in excessiveby hatand humid bacatians, and store il aut at the way at rainwater andother adverse environmentab ebements.

• BundlingWhen bundling the battery with a praduct, be sure to use cushianingand other packing to pratect the battery (and especialty the positiveterminab) tram jalts and shocks during transpartation.

r• The ER baffery is far industdal use anly.• When replacement is necessary, please contact the

manufacturer at yaur equipment.

Esampi. le) Exanpl. (

Type Maximtmi CurrentER18/50 125pA[P17150 125pA

[P6 lCDpAER6C iCOpA

ER1V33 7OpA[P3 5OpA

ER3S 4CpA -.

31

Page 7: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

jr rprima Baftery

Lithium Thionyl Chioride Battery

Overview

_________ _____________ _______

This batlery is ideal for such long-term applications ss power far etectronic devices and electric power, water, and gas meters. and especially assbackup power source for memory lCs.

11 RasInS.j

- M•IT S,nj

MdL!d -

E.ctoa.

(4

>

0G,La

0

GincLa

232c

Features

______________

Minimum transient voltage

_________

• High 3.6-V voltageThe lithium thianyl chloride battery achieves a high vottage of 3.6V.

• Flat discharge characteristicsThe change of internal resistance during discharge is minimal,allowing for flat discharge voltage Lntil end of discharge life.

• High energy densityProvides high energy density of 97Cm VMcm3 with drschargecurrent af 1 CøpA (286 type).

• Wide usable temperature rangeCan be used overs wide temperature range —55 deg. C to +85 deg.C (please consult with Maxell if using in temperatures of—40 deg. CDr less).

• Superiar long-term reliabilityThe extremely low seIl -discharge, together with the use af ahermetic seal, allows for stable use over lang periads.

The lithium thionyl chloride battery has remarkably lawersel!-discharge when campared with conventional battehes. This isbecause a litbium chlodde membrane is formed over mo negativelithium sudace, blocking maction with the pasitive matehal. Whenfirst discharging after stamge, resistance fram this lilhium chloddernembrane may temporarily reduce the voltage at the inftiation of&scharge. The lowest voltage at this time is called minimumtransient voltage, and mo lower the temperature, and the larger thedischarge current. the lower the voltage will be. Because minimumtransient voltage is greatly influenced by storage time and conditions,il is necessary to take this into sufficient consideration whendesigning a device.

Construction

-,C-rcu-t

__________

VQ

ER64

3.5

3

2.5

2

1.5

0.5

0

Principle and ReactionsThe lithium thionyl chloride battery uses liquid thionyl chloride(SOCI2) ss its positive active matedal, and lthium (Li) ss its negativeactive matedal. The reactions of the battery are shown below.

• Battery reactionsPositive reactiort 2SOCb+4LÇ.4e —. 4LiCI1S+SO:Negative reaction: Li — Li4&Total reaction: 2SOCb+4Li —. 4LiCI+S+S03

Discharge bad (ohm)

The figure above shows minimum transient voltage using afresh battery.

32

Page 8: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

rimaryBattery ::

Relationship between Discharge Load and Operating VoltageThe operating voltage of a batlery falls as the disoharge badincreases and temperature falis. In the case of initial use, an electricpotential of at least 3V will be maintained even at temperatures at—40 deg. Gal discharge of less than 1 mA.

ER6

Storage CharacteristicsThe lithium thionyl chloride batteiy is made from chemically stableinorganic materials. Additionalby, a sealing method empboying aIaser-welded seal structure and hermetic saab hinders the admittanceof outside air. These features provide superior storagecharacteristics, holding down sebf-discharge to no more than 1% ofcapacity per year at normal temperatures.

The Iithium thionyb chboride baltery is a UL (Underwriters Laboratoriesnc.) recognized component. Çrechnician Replaceable)

Recognized models: ER1B/50, ER17/50, ER6, ER6G,ERI7/33, ER3, ER3S

Cerlification Number: MH12568

• CA Machines (Fax, Copiers, Printers)• Medical lnstruments, Cash Registers• FA Instruments (Measujing Instruments, Onboard

Microcomputers, Sensors)• Elecironie Meters ater, Gas, Electdcity)• ETC (Electronic Toll Cobbection System)• Home Fire/Smoke Alarm

• Dimensions and weight are for the battery itsell, but may vary depending on terminal specifications and other factors.Nominal capacity indicates duralion until the voltage drops down to 3.0V when disoharged at a nominal discharge current at 20 deg. G.

• Data and dimensions are just reference values. For further details, please contact your nearest Maxell deaber or distribulor.

4

3.5

3

2.5

2

1.5

0.5

0

0,fl,I,

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20 deg. G—10 deg. G—40 deg. G

Atter stored for 200 days al 60 deg C(equivalent to storage for 10 years at 20 deg. C)

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10’

After 3 months at 20 deg. CI I I I

Discharge bad (ohm)1o4

UL Recognized Components

Temp:20 deg.CDischarge current: 100 pA

Dbschargo capaclty (%)

Applications

__ _

Model ER1W5O ER17/5G ERS ER6C ER17/33 ER3 ER3S

3650

Nominal Voltage (V) 3.6 3.6 3.6 3.6 3.6 3.6 3.6

1100Nominal Capacity (mAh)**

Nominal Discharge Current (pA)

Operating Temperature Range (deg. C)

Diameter (mm)Dimensions

Height (mm)

Weight (g)*

2000

125

—55 to +85

2750

125

—55 to +85

1800

100

1600

100

—55 to +85

75

—55 to +85

18

52.6

22

40

790

35

—55 to +85

17

52.6

20

14.5 14.5

—55 to +85

53.5

—55 to +85

51

17.0

35

15 15

14.5

29.9

813

14,5

26

7

33

Page 9: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

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Page 10: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Eprimary Ballery

External Dimensions with Terminals and Wire Connectors (unit: mm)

ER17/33 1(2 PC ER17/33 WKP ER3 1(2 PC ER3S 1(2 PC

Visit our website for more informationhttp://biz.maxell.com/enlGa to: Products> Primary Batteries> ER (Lithium Thionyl Chioride Baftery)

to meet customer requests is possible.

-wER18/5O 1(2 PC ER17/50 #2 PC ER6 1(2 PC

ar tiER6K-#17 ER6C#2PC(2) ER6CWKP

iLcop

Hosk

Housing: XHP-2 (JST)Conlaci: SXH-OOIGH-P0.6 (JST)Lead wire: AWG2G UL1007

5 Plastjo capInsulaUon sleeve

LJ4JL

Housing: HNC2-2.5S-2 (Hirose)Contact: HNC2.5S-C-9 (03) (Hrose)Lead wLre: AWG2O UL1007

LEI: Hodzontal & Through hale Type

LEI: Wire connector Type

Plasta cap

00

i Insu[ation

M018.2

Housing: HNC2-25S-2 (Hirose)Contact: HNC.2.55-C-B (03) (Hirose)Lead wire: AWG26 UL100T ti

I I: Tin plating

The above are examples, Processing

35

Page 11: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Dangerous Goods Transportation Regulations for Lithium Celis and Balleries

Same transportation regulations have been recently revised and witI come into eftect atter Jan. 1, 2015. The summary is shown in thefollowing table. Please usa updated Dangerous Goods Regulations listed in Normative Reference to conrirm detaiis.

• The major revisions for air transport of Iithium celis and batteries(1) Lithium metal celis and batteries transported as cargo wirl be restricted to cargo aircraft only.

Note. The prohibition does not apply to lithium metal batteries packed with equipment (P1 969) ar contained in equipment (P1 970).(2) Gress mass wiJl change to net quantity for both Iithium on celis and batteries (P1 965 Section IS) and hthium metal celis and batteries

(P1 968 Section IS)

Technical instwctions for Iithium metal batteries (P1 968)

Section Secl’on II Seolion IS Seciion tA

Lilhium Molal Cell: s 03g Cell: s 1.Og C&: 1.09 Gal: >1.09

Conienl Battery: s 0.3g Baltery: 2.Og Batlery. s 2.0 g Batlery: > 2.0 g

‘Quanlity N’A s 2 batteres yr >2 batteries er

Package s 8 cels > 8 celis

Lirnits Net Cargo aircratt only Cargo aircrafi only Carga ai,cratt or.Iy Cargo aircraft onlyWeighi 2.5 kg N/A 2.5 kg 35 kg

Ciassification Exempted Ciass 9

Strong ou’er packa jrPackag:ng

1.2 Mdrcp lestVN perferrrance pad<agig

Labels 411111k 4dIILko:eli .c:aE- No:ea)

Invdce (air waybil’Declaraticn for OG Deciaration for OG

Documents .. ... Air wayb:.IAdditiceal d&oumer.ts

AiicraI documer,ts” Ar waybill

Training Meuaie irstwct:ans DG training

Nate 1): Handling label Nate 2): Cargo airea’t only bud (necessayfor ttftum metal ceils and batleres)Note 3): Glass 9 hazardous label• The words lithium metal batleries, in complianco with Section liv! P1 96W and Cargo Aircraf I Only’ yr ‘CAD’ must appoar on the air waybill, when an air

waybili is used. This descriplion should appear in the Nalure and Quantity of Goods box.The words ‘Dangerous Goods as per attached Shippers Deciaration’ and ‘Cargo Airciaf I Only or ‘CAO’ musi appear in Ihe air waybilrs Handling Intormalion’column.Addilional documenis must indicate:

• The packago conleins lirhium metal celis er batteries;• The package must be handled with caro and that a flammabitity hazard exisis i ihe package is damaged:• Special procedures should be fotowed in the event the package is damaged, to incIude inspection and repacking il necessary; and• A tetephone number for additional information.This iniormation can be written in the Deciaration for DG’s AdditionaI Handling Information’ cotumn or on tho air waybiill.

40

Page 12: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Technical instructions for Iithium-ion bafteries (P1 965)

Seatian Seatian Il Sectian IS Sectian lA

Cell: 2.7 Wh Cell: s 20 Wh Cell: 20 Wh Cell: > 20 WhWatt haur Battery: 2.7 Wh Battery: 100 Wh Battery: s 100 Wh Battery:> 100 Wh

s 2 batteries ar > 2 batteries arQuantity N/A5 ceils > 8 celis N/A

Package I_________Limits I Not

Weight 2.5 kg N/A 10 kg 5 kg: Passenger aircraftPassenger and carga aircraft 35 kg: Carga aircraft

Ciassificatian Exempted Class 9

Packaging Strang auter packaging UN pedarmance packaging1.2 M drap test

CAUrIaNII -

Labels AIIIIIL 411111k

Deciaratian far OG Deciaratian far OGInvaice (air waybilDDacuments Additianal dacumentr Air waybiIIAir waybillAdditianal dacuments***

Training Adequate instructians OG training

• The wards Lithium ian batteries in camptiance with seatian II af P1 955 must appear in tho air waybilrs Nature and Ouantily at Gaads box, when an air waybilIis used. The words ‘Carga Aircratt Onis? ar tAO must appear an mo air waybill, when transparted by cargo.The wards Dangeraus Goads as per attached Shippers Declaratian must appear in the air waybill’s Handling Infarmatian column. Tho words Carga AircraftOnIy ar CA0 must appear an the air waybill, when transparted by carga,Additional dacuments must indicate:

• The package cantains Iithium an celis ar batteries;• The package must be handled with care and that a fIammabiiLty hazard exists il the package is damaged;• Speciat pracedures should be faflawed in the event the package is damaged, ta include inspectian and repacking if necessary; and• A tetephane number far addifianal iniormafian.This infarmatian can be writf en in the Deciaration far DG’s Additianal Handling fn(armafian’ catumn ar an the air waybill.

r4r

Page 13: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

• The major revisions for UN Model Regulations l8th Revised Edition(1) Damaged ar defeotive ceils ar batteries shall be transparted as ‘Ciass 9’ hazardous goods accarding to Special Pravisian 376 and

Packing lnstruction P908 ar LP904.(2) Celis and batteries transparted for disposal ar recycling shell be transparted as Gass 9’ hazardaus gaads according to Special

Provision 377 and Packing lnstruction P909.The IMDG Code 2014 edition wiII cantain the descriptians at these UN recammendations. The vatuntary campliance date is Jan. 1,2015. Camp)iance becomes mandatory on Jan. 1, 2016.Although these revisions will be reflected in each cauntry’s regulations, same districts, cauntries ar airlines may estabhsh their awnspecial requirements. Therefore the shipper shatl confirm with the forwarder in advance.

ReferenceExcept tar air transportation, the necessary requirements ta transport lithium metal batteries ar Iithium-ion batteries as exempted framregulation (non-restricted goods) are as fo[Iows;

1. The minimum requirements ta transport Iithium metal batteries as non-restricted goods are as foltaws;a) Celis and batteries shali be manufactured under a quality management program.b) For a litbium metal ar a lithium allay cell, the lithium cantent must not be more than 1 g.

For a lithium metaI ar lithium a’lay battery. the aggregate lithium content must not be more than 2 g.c) Each ccl: ar battery must be at tYie type proven to meel tlie requiremen:s at each test in Ihe UN Manua! at Tests and Criteria, Sth

revised edition, Part III, sub-secton 38.3.d) A battery handhng label mjst be dsplayed on each package. A t&ephoe number must be printed on ihe label far additiona

i nform at on.e) Each consignment must be accompanied by a document for transport with an indca:on that:

• the package contains Iium metal cels ar batteres;• the package must be hardied with care 39d that a fammabihty hazard exists if the package is damaged:• speciai prccedjres should be fol!owed in the event that the package is damaged. to include inspeobon and repackagng if

necessary; and• a telephone number for additianal information.

f) Each package must be cacable at withstanding a 1.2 m drap test.g) Except when batteries are installed in ar packed with equipment, packages shal rot exceed 30 kg grass mass.

2. The minimum requirements to transport the Iithium-ian batteries as non-restricted gaods are as follows;a) Celis and batteries shall be manufactured under a qua[ity management program.b) Far Iithium-ian cells, the Watt-hour rating is not more than 20 Wh. Far lithium-ion batteries, the Watt-haur rating is not more than

100 Wh. Tne Watt-hour rating must be marked an the autside at the battery case except for thase manutactured before Jan. 1,2009.

c) Each cei ar battery is at the type proven to meet the requirement at each test in the UN ManuaI at Tests and Crileria, 5th revisedediton, Part III. sub-sectan 38.3.

d) A battery hand!ing label must be displayed an each package. A telephane number must be printed an the label far additionalinformatian,

e) Each cansignment must be accamoaied by a document for transport wah an indication that:• the paekage contains ithium-icn celis ar batteries;• the package must be hand!ed with cae and that a flammabity hazard exists il the package is damaged:• special procedures shauld be fol.owed in the event the package is damaged, to inciude inspectian and repackaging if necessa’y;

and• a telephane number tar addEtiana informatan.

I) Each package must be capable at withstandng a 1.2 m drap test.g) Except when batteres are instaled in c packed with equipment, packages shall not exceed 30 kg grass mass.

MaxelI will provide certificates for b) and c) as the need anses. Documentatian ford) and e) needs ta be prepared by the customer.II aur package is used tar transport, MaxeII WL provide the certificate fort) as the need anses. However, if the customer’s packageis used, the custamer must confirm the paokage can withstand a 1.2 m drap test. Furthermore, even if aur package is used fartransport, the telephane number pninted on the label must be changed ta Ihat at the sender (custamer).

Major Normative ReferenceUN (United Nations) Recammendations (Air, Marine, Overland transparlation)• UN (United Nations) Recammendations on the Transport at Dangeraus Gaads: Model Regulations lBth revised editian• UN (United Nations) Recammendations on the Transport at Dangeraus Gaads: Manual at Test and Criteria Sth revised editian,Amendment 2

Air Transpartatian• International Civil Aviation Organization (ICAO): Technical lnstructions for Safety Transport of Dangerous Gaads by Air. 2015-2016

edition• International Air Transport Assaciation (IATA): Dangeraus Gaods Regulations, 56th editian 2015

Marine Transpartatian• International Maritime Organization (IMO): International Maritime Dangerous Gaods (IMDG) Cade, 2012 edition (This is appticable

until Dcc. 31, 2015)• International Maritime Organization (IMO): International Maritime Dangeraus Gaods (IMDG) Cade, 2014 editian Çrhis is applicable on

and atter Jan. 1,2015 and will be mandatary on and after Jan. 1,2016)

42

Page 14: Cylindrical CR Battery - Produktsøknrfportal.vvsnrf.no/assets/1163/HMS/Sikkerhetsdatablad 198330.pdf · The cells or batteries classified in Section II of any Packing Instruction

Hitaohi MaxeII, Ltd.2-18-2, Udabashi,

IIIBXBII i9.8249Fax: (÷81) 3-3515-8305

Visit aur webslte at: biz.maxeII.comNORTU AMERICA / SCUEN AMERICA

Maxell Corporation at Amerlca ManN Latin AmerftaMain Office: Canada Oranch: Oceanla Susiness Plaza. Tower 2000,3 Garret Mauntain Plan, 3rd Flaor, 237 Ramina Drive, Sulte 200 191ti Floar. Office 19-0. Punta Paci(ica,Sulte 4300. Woodland Park, NJ Concord, Ontario L4K 4V3, Canada Panama City. Rep. at Panama07424, USA. Tel: (+1) 905-669-8107 Tel: (+507) 269-6291Tel: (÷1)973-653-2400 Fax: (+1) 905-669-8108 Fax: (÷507) 263-4413Far (÷1) 973-653-2450 Web Site: web Sile:Web Site: hhp:J/wv.maxel)canada.cam/ hUp,//wwwmaellpanconVhttp://wvnmaxell -usacom)

EUROPE

Maxell Europe Ltd.European Headquarters & Frencti Bmnch:UK Sales Otfice: 15 Ruo Des Oziers PA Du Vert Galant,Whlebrook Park. Lower Ceokham SP 97091, St Otjen L’Atjmone 95052Road, Maldenhead, Berkshire Cergy-Ponicise Cedex, FranceSL6 8VA, UK Tel: (÷33)1-3424-8811Tel: (—44) 1628-41-2012 Fax: (÷33) 1-3075-5677Fax: (÷44) 1628-41 -2010 Emat): [email protected]: hqemaaeleucorn Italian &anch:(European Headquarlers) Via Tammaso GuO 39, 20147 Milan. Italysates@maxell eucDm Tel: (÷39)02-48-7861OJK Sa!es Ohice) Fax: (÷39) 02-3919-0574Web Site: 6-maI: Momaxe,1euhttp:Hwwwmaxeteucom -

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Vtir

Hitachl Ma,ell Global, Ltd. MaxeII (Shanghai) Trading Co., Ltd. Masell Asia (Singapore) Pte, Ltd.Main Office: Main Ofiice: Matn OUice:Unit Nas.038-06, 13J No 909 ChBLing 1801, Plan 336, No336, XiZang 24 PeckSeahStreet, #07-03J05. Nehsans Buliding.Sha Wan Road, Cheung Sha Wan, Middle Road. Shanghai 200001, China Singapore 079314Kawtoan. Hang Kong Tel: (÷86) 21-3330-3377 Tel: (÷65) 6220-9291Tel: (÷852) 2733-9243 Fax: (÷86)21-3330-4001 Fax: (÷65) 6220-6070Fax: (—8521 2735-6250 6-mai!: [email protected] Web Site:E-mail: [email protected] Web Site: http:f/WVQWmaxeflcom.sg/Web Site: http-J/www.maxell.com.aV Chennai Ottice:http:Hwwwmaxeicarn.hk/ B&ng Ottice: CIo NICHE SUS:NESS CENTRE.etnam Office: 1009 Tower3, Beijing International No:10, First Roor, Second Avenue,Room Na. 15, Meuanine Floor, Center, No 36 Dongsanhuan Sei Road, Hamnglon Road, Chetpet, Chennai-603031, IndiaSun Wah Tower, 115 Nguyen Hue Chaoyang Oistrict, Beijing 100026. Tel: (÷91)44-2836-5152Boutevard, District 1, Ho ChI Minh China Gur aon OtficeCity. Vietnam Tel: (+86)10-8587-0215 2nd9Floor, Valika SusIness Centro No.24,Tel: (÷84) 8-3821 -9183 Fax: (÷86)10-6587-0238 First India Place, MG Road,Fax: (÷84) 8-3821-9181 6-mai: [email protected] Gurgaon 122002 Haryana. India6-mai: [email protected] Tel: (÷91)124-4028-862

MaxeIl (Shenzhen) Trading Co., Ltd.21B, Bullding A, Honglong CenturyPlaza, 4002nd East Shennan Road,Luahu District, Shenzhen, ChinaTel: (÷86) 755-8280-5220Fax: (÷66) 755-8280-5695

MaxeIl Taiwan, Ltd.14F, No. 111, Sung Chlang Road,Taipel 104, TaiwanTel: (÷886) 2-2516-5553Fax: (÷886) 2-2516-4804E-mail: [email protected] Site:hIt p :llwww. m ax e II. ca m .tw/

MaxeIl is accredited with international uality management standard 150 9001 and international enviranmentat management standard 50 14001 cerlifications.

catalog conlent, accutate a: el Janualy 2015 VEGETABLEData and d;rten:eiis ab ,ctreffirence valurt. lL INNOsniani. an lit calaiag ane .utncl to change wilneul nnt,cOGainTnnned 5 se h0tnst eLaI’ty anjtarcn managnni :tandat je i-eI æ rsp n55tb la li-i- erwamneni.

OAflERIES CATALOGIE) HE022 ‘bot Prnicd en Jjeart