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B. TECH Minor course Indian School of Mines, Dhanbad

March 2015

COURSE STRUCTURE

Sem. Course No. Courses L T P Credit Hr.

I Theory

ACR 21111 Physical Chemistry 300 6

ACR 21112 Inorganic Chemistry 300 6ACR 21113 Organic Chemistry 300 6

ACR 21114 Analytical Chemistry 300 6

ACR 21115 Seminar 000 2

Practical

ACR 21116 Physical Chemistry Lab 003 3

ACR 21117 Inorganic Chemistry Lab 003 3

ACR 21118 Organic Chemistry Lab 003 3

Total 1209 35


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ACR 21111 Physical Chemistry 300

Thermodynamics

Second law of thermodynamics: Carnot cycle and its efficiency, Carnot theorem.

Thermodynamic scale of temperature. Concept of entropy, entropy as a criteria ofspontaneity and equilibrium. Entropy change in ideal gases and mixing of gases. Gibbsand Helmholtz functions

Third law of thermodynamics: Nernst heat theorem, statement and concept of residual

entropy, evaluation of absolute entropy from heat capacity data.

Electrochemistry

Electrolytic and Galvanic cells, reversible and irreversible cells, conventional

representation ofElectrochemical cells. EMF of a cell and its measurements, Calculation of

thermodynamic quantities of cell reactions, polarization, over potential and hydrogen

overvoltage. Concentration cell with and without transport, liquid junction potential,application of concentration cells, potentiometric titrations. Determination of pH using

hydrogen, quinhydrone and glass electrodes, by potentiometric methods.

Solid state Chemistry

Definition of space lattice, unit cell. Crystallography, Symmetry elements in crystals. X-ray diffraction by crystals. Derivation of Bragg equation. Determination of crystal by

Lauesmethod and powder method.

Chemical Kinetics

Effect of temperature on rate of reaction, Arrhenius equation, concept of activation

energy, Simple collision theory based on hard sphere model, transition state theory(equilibrium hypothesis). Expression for the rate constant based on equilibrium constant

and thermodynamic aspects.

References:

1. P. Atkins, J. D. Paula. Physical Chemistry, Oxford, 8thEdition, 2010.

2. K. J. Laidler, Chemical Kinetics, Pearson, 3rdEdition, 1987.

3. B.R. Puri, L.R. Sharma, M.S. Pathania, Principles of physical chemistry Vishal

publishing Co. 46thEdition, 2013.

ACR 21112 Inorganic Chemistry 300

Oxidation and ReductionUse of redox potential data analysis of redox cycle, redox stability in water Front,

Latimer and Pourbaix diagrams. Principles involved in the extraction of the elements.


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Coordination CompoundsWerners coordination theory and its experimental verification, effective atomic number

concept, chelates, nomenclature of coordination compounds, isomerism in coordinationcompounds, valence bond theory of transition metal complexes, electronic structure (CFT

only). Magnetic properties; general chemistry of d-block elements

Chemistry of Lanthanide ElementsElectronic structure, oxidation states and ionic radii and lanthanide contraction, Magnetic

properties, complex formation,occurrence and isolation, lanthanide compounds and

applications. Definition, nomenclature and classification of organometallic compounds.

Bioinorganic Chemistry

Essential and trace elements in biological processes, metalloporphyrins with special

reference toHemoglobin and myoglobin. Biological role of alkali and alkaline earth metal ions with

special reference to Ca2+. Nitrogen fixation. Inorganic polymers.

References:

1. P.W. Atkins, T. Overton, J. Rourke, M. Weller and F. Armstrong; Shriver &

Atkins: Inorganic Chemistry, 4th ed. Oxford University Press, 2006.2. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann; Advanced

Inorganic Chemistry, 6th ed. Wiley, 1999.3.

K.F. Purcell and J.C. Kotz, Inorganic chemistry, Holt Saunders international.

ACR 21113 Organic Chemistry 300

Electrophilic & Nucleophilic substitution reactions in aromatic systems: Electrophilicattack on benzene and C6H5Y-nitration, halogenation, sulphonation, Friedel Crafts

reactions, Electronic effect of Y, Kinetic vs. thermodynamic control, important reactions

of phenols, aromatic amino compounds and naphthalene. Nucleophilic attack on aromaticspecies: substitution of hydrogen, substitution of atoms other than hydrogen, substitution

via aryne intermediates. Synthesis and reaction of heteroaromatic compounds- furan,

pyrrole, thiophen and pyridine.

Electrophilic and nucleophilic addition reaction to C=C: Electrophilic addition reactions

via halonium & carbocation intermediate, hydroboration, regio- & stereochemistry,

Oxidation reactions- hydroxylation, ozonolysis, electrophilic addition to conjugateddienes, Elimination reaction: 1,2-elimination via E1, E1cB, E2 mechanism,

stereoselectivity in E2 reaction, Saytzeff vs. Hoffmann elimination, elimination vs.

substitution, other 1,2-elimination, 1,1-elimination, pyrolytic syn-elimination.

Organomagnesium compounds: the Grignard reagents-formation, structure and chemicalreactions. Organolithium compounds: formation and chemical reactions.


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Organosulphur CompoundsNomenclature, structural features, Methods of formation and chemical reactions of thiols,

thioethers, sulphonic acids, sulphonamides and sulphaguanidine.

Heterocyclic Compounds

Introduction and preparation of simple heterocyclic compounds (furan, pyrrole, thiopheneand pyridine)

References:

1. Micheal Smith, Organic synthesis, 2 nd Edition, McGraw Hill, 2004.

2. F.A. Carey and R.J. Sundberg, Advanced Organic Chemistry Part B, 3 rd

Edition, Plenum Press.

3. J. Clayden, N. Greeves, S. Warren and P. Wothers Organic chemistry (Oxford Press)

4. W. Carruthers Some modern methods of organic synthesis (Cambridge)

ACR 21114 Analytical Chemistry 300

Analytical chemistry and chemical analysis, Errors in Chemical Analysis and Statistical

Evaluation of Data. Systematic and random errors, Accuracy and precision, Ways ofexpressing accuracy and precision, Normal error curve and its equation, Propagation of

error,

Volumetric Analysis, Gravimetric Analysis, Spectral Method of analysis.

Atomic Spectroscopy: Theory, Instrumentation and applications of X-rays (emission,

absorption, diffraction and fluorescence methods), Atomic absorption Spectroscopy,

Atomic fluorescence spectrometry, Atomic emission spectrometry.

Molecular Spectroscopy: UV-visible molecular absorption spectrometry (instrumentation

and applications), Molecular luminescence spectroscopy (fluorescence, phosphorescence,

chemiluminascence), Mass spectroscopy.

Separation Methods: Principle of chromatography, Classifications of chromatography,

Techniques of planar and column chromatography, Gas chromatography, High-performance liquid chromatography.

References:

1. A. I. Vogel, A text-book of quantitative chemical analysis, John Wiley & sons,

Fifth edition, 1989.

2. Gary D. Christian, Analytical Chemistry, Wiley, 7thEdition, 2012.

3. D. A. Skoog, F. J. Holler, S. R. Crouch, Principles of Instrumental Analysis, 6th

Edition, 2006.


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4. D. A. Skoog, D. M. West, F. J. Holler, S. R. Crouch, Fundamentals of Analytical

Chemistry, 8thEdition, 2008.

ACR 21116 Physical Chemistry Lab (0 0 3)

To determine the strength of the given acid conductometrically using standard alkalisolution.

To determine the specific reaction rate of the hydrolysis of methyl acetate/ethyl acetatecatalyzed by hydrogen ions at room temperature.

To compare the strengths of HCl and H2SO4 by studying the kinetics of hydrolysis of

ethyl acetate.

To study the distribution of benzoic acid between benzene and water.

To determine the percentage composition of a given binary mixture by surface tensionmethod.

To determine the solubility and solubility product of a sparingly soluble electrolyteconductometrically.

To verify Beer Lambert law for KMnO4/K2Cr2O7and determine the concentration of

the given solution of the substance.

To determine the ionization constant of a weak acid conductometrically.

ACR 21117 Inorganic Chemistry Lab (0 0 3)

Determination of acetic acid in commercial vinegar using NaOH.

Determination of alkali contentantacid tablet using HCl.

Estimation of calcium content in chalk as calcium oxalate by permanganometry.

Preparation of Ni-DMG complex, [Ni(DMG)2].

Preparation of copper tetraammine complex. [Cu(NH3)4]SO4.

Preparation of cis- and trans-bisoxalato diaqua chromate (III) ion

Synthesis of cis- and trans-[Co(en)2Cl2]+

Preparation of triphenylphosphine Ph3P and its transition metal complexes


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Preparation of cis-and trans- complexes of Copper with glycine

ACR 21118 Organic Chemistry Lab (0 0 3)

Qualitative treatment of determination of functional groups in organic compounds.

Qualitative estimation of few organic compounds.

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