concept 6.5 photosynthesis, light energy, and chemical energy kimberly javier & kaylin malinit
TRANSCRIPT
Concept 6.5 Photosynthesis, Light energy, and Chemical Energy
Kimberly Javier & Kaylin Malinit
During Photosynthesis, Light Energy is Converted to Chemical EnergyThe energy released by catabolic pathways in all organisms (animals, plants, and prokaryotes) ultimately come from the sun.
Photosynthesis- an anabolic process by which the energy of sunlight is captured and used to convert carbon dioxide (CO2) and water (H20) into carbohydrates (which represent as a six-carbon sugar, C6H12O6) and oxygen gas (02). 6CO2+6H20 C6H1206+602
,
Involves Two Pathways: The light reactions convert light energy
into chemical energy in the form of ATP(Adenosine triphosphate.) and the reduced electron carrier NADPH(Nicotinamide adenine dinucleotide phosphate).
The carbon-fixation reactions do not use light directly, but instead use the ATP and NADPH made by the light reactions, along with CO2 to produce carbohydrates
Both the light reactions and the carbon-fixation reactions stop in the dark because ATP synthesis and NADP+ reduction require light.
In plants, both pathways proceed within the chloroplast, but they occur in different parts of that organelle.
http://vcell.ndsu.nodak.edu/animations/photosystemII/movie-flash.htm
Light energy is absorbed by chlorophyll and other pigments.. Photochemistry:
-Light is a form of electromagnetic radiation.- Propagated in waves , and the amount of energy in
the radiation is inversely proportional to its wavelength
- (shorter wave length = greater energy)
Shorter wavelengths are more energetic. Longer wave lengths are less energetic.
- -Light also behaves as particles called photons.
- Photons have no mass.
- Receptive molecules absorb photons in order
to harvest their energy for biological
processes. These receptive molecules absorb
only specific wavelengths of light – photons
with specific amounts of energy.
When a photon meets a molecule:
1. The photon may bounce off the molecule-
scattered or reflected
2. The photon may pass through the molecule-
it may be transmitted.
3. The photon may be absorbed by the
molecule, adding energy to the molecule.
In absorption, the photon disappears and its energy is absorbed by the molecule.
When the molecule acquires energy of the photon it is raised from a ground state (with lower energy) to an excited state (with higher energy)
The difference in free energy between the molecule’s excited state and its ground state is approximately equal to the free energy of the absorbed photon.
The increase in energy boosts one of the electrons within the molecule into a shell farther from its nucleus; this electron is now held less firmly, making the molecule unstable and more chemically reactive.
Photobiology Pigments - molecules that absorb wavelengths
in visible spectrum. When a beam of white light (containing all the
wavelengths of visible light) falls on a pigment, certain wavelengths are absorbed.
The remaining wavelengths are scattered or transmitted and make the pigment appear colored.
Ex) The pigment chlorophyll absorbed blue and red light, and we see the remaining light which is primarily green.
Plotting light absorbed by a purified pigment against wavelength results is an absorption spectrum for that pigment.
An action spectrum is a plot of the biological activity of
an organism against the wavelengths of light to which it
is exposed.
Light Absorption results in photochemical
change
Chlorophyll absorbs light excited state (unstable
situation).
Chlorophyll rapidly returns to its ground state, releasing
most of absorbed energy.
Most chlorophyll molecules embedded in the thylakoid
membrane, the released energy is absorbed by other,
adjacent chlorophyll molecules.
The pigments in photosynthetic
organisms are arranged into energy-
absorbing antenna systems, light-
harvesting complexes.
They form part of a large multi-protein
complex, photosystem(spans the
thylakoid membrane and consists of
multiple antenna systems with their
associated pigment molecules, all
surrounding a reaction center.
Ground-state chlorophyll molecule at reaction center
(Chl) absorbs energy from adjacent chlorophylls and
becomes excited(Chl*).
Chlorophyll returns to ground state – the reaction center
converts the absorbed light energy into chemical energy.
Chlorophyll molecule absorbs sufficient energy that it gives up
its excited electron to a chemical acceptor.
Chl* acceptorChl+ + acceptor-
The reaction center chlorophyll (Chl*) loses its excited electron in
a redox reaction and becomes Chl+.
The chlorophyll gets oxidizes while the acceptor molecule is
reduced.
Reduction leads to ATP and NADPH formation
Electrons are passed from one carrier to another in a
“downhill” series of reductions and oxidations.
Thylakoid membrane has an electron transport system similar
to the respiratory chain of mitochondria.
As in mitochondria, ATP is produced chemiosmotically during
the process of electron transport (photophosphorylation).
http://www.youtube.com/watch?v=jHvXfplbS9Y
There are 2 Photosystems, each with its own reaction center:
Photosystem I- (contains the “P700”
chlorophylls at its reaction center) absorbs light energy at 7nm, and passes an excited electron to NADP+, reducing it to NADPH.
Photosystem II- (with “P680” chlorophylls at its reaction center) absorbs light energy at 680 nm and produces ATP and oxidizes water molecules.
Photosystem II After an excited chlorophyll in the reaction center (Chl*)
gives up its energetic electron to reduce a chemical
acceptor molecule
Chlorophyll lacks an electron and is very unstable
Strong tendency to “grab” an electron from another
molecule to replace the one it lost
It is a strong oxidizing agent
Electron transport system: the energetic electrons are
passed through a series of membrane-bound carriers to a
final acceptor at a lower energy level
Photosystem I An excited electron from Chl* at the reaction center reduces
an acceptor
Oxidized chlorophyll (Chl+) “grabs” an electron
Electron comes from last carrier in electron transport
system of photosystem II
Links two photosystems chemically
Linked spatially
Two photosystems adjacent to one another in thylakoid
membrane
Energetic electrons from photosystem I pass through several
molecules and end up reducing NADP+ to NADPH
Carbon-fixation reactions- require more ATP than NADPH
Cyclic electron transport makes up for imbalance Uses only photosystem I and
produces ATP but not NADPH Cyclic because an electron is
passed from excited chlorophyll and recycles back to same chlorophyll