cold spray technology for - navy metalworking center (nmc)
TRANSCRIPT
-Cold Spray Technology for Repair of Magnesium
Rotorcraft Components
Marc PepiMaterials Engineer
ARL Center for Cold SprayUS Army Research LaboratoryAberdeen Proving Ground, MD
NAVAIR Corrosion Resistant Alloy Workshop8-9 November 2006
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Center for Cold Spray at the
US Army Research Laboratory (ARL)
Aberdeen Proving Ground, MD 21005-5069
ARL Cold Spray Research TeamPhillip Leyman Process Engineer (410) 306-0818
Dr. Dennis Helfritch Process Engineer (410) 306-1928
Dr. Andrew Davis Materials Engineer (410) 306-0808
Michael Lister Materials Engineer (410) 306-1592
Mathew McCarry Process Technician (410) 306-2026
Dr. William DeRosset Modeling/Simulation (410) 306-0816
Marc Pepi Mechanical Engineer (410) 306-0848
Victor Champagne Team Lead/Materials (410) 306-0822
Overview of Cold Spray Technology
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N2 or
He gas
Electric HeaterGas Control Module
Powder Feeder Supersonic Nozzle
Substrate
Particle Stream
Deposit
N2 or
He gas
Electric HeaterGas Control Module
Powder Feeder Supersonic Nozzle
Substrate
Particle Stream
DepositMain Gas Stagnation Pressure 100-500 psi Gas Temperature 0-1300ºF Main Gas Flow Rate 30-100 CFMPowder Feed Rate 10 to 30 pounds/hour Particle Velocity 300-1500 m/sec.Particle Size 1-100um diameter
Overview of Cold Spray Technology
Cold Spray: a process by which particulates are deposited by means of ballistic impingement upon a suitable substrate at super sonic velocities to form a coating or a free-standing structure.
Cold Spray System Configuration
-Cold Spray AdvantagesCold Spray Advantages
Super Plastic Particle Agglomerate Mixing (SPAM) bondSuper Plastic Particle Agglomerate Mixing (SPAM) bondplastic deformation may disrupt thin oxide surface films to permplastic deformation may disrupt thin oxide surface films to permit bondingit bondingsimilar to explosive weldingsimilar to explosive welding
Compressive residual stressesCompressive residual stressesparticles particles ““peenpeen”” surface surface plasma and wireplasma and wire--arc thermal spray coatings tend to be in tensionarc thermal spray coatings tend to be in tension
High densityHigh density Thick coatingsThick coatingslow porosity: < 0.5 %low porosity: < 0.5 % freefree--form fabricationform fabricationlow oxide content <0.3%low oxide content <0.3%
Low Temperature ApplicationLow Temperature Applicationthermally sensitive substratesthermally sensitive substrateslow stresses due to CTE mismatchlow stresses due to CTE mismatch
Cold Spray is performed at lower temperatures at high particle velocities
Cold Spray vs. Thermal SprayCold Spray vs. Thermal Spray
Particle/Substrate Interaction*
*from H. Assadi, www.modares.ac.ir/eng/ha10003/CGS.htm
Cross section of the impact site between a copper particle and a stainless steel substrate.
Copper Particle Impact SiteCopper Particle Impact Site
Photo: Dykhuizen et al, J. Thermal Spray Tech, Dec 1999.
5 nsec 20 nsec
35 nsec 50 nsec
Schematic: *M. Grujicic,et al, “Computational Analysis of the Interfacial Bonding Between Feed-Powder Particles and the Substrate in the Cold-Gas Dynamic-Spray Process”, Applied Surface Science, April 2003
Advantages of Low Advantages of Low Temperature ProcessTemperature Process
www.gordonengland.co.uk
Thermal Spray Cold Spray
The melting of particles that occurs during most thermal spray processes can result in oxidation of both the coating and substrate materials. The resulting oxides decrease the adhesive and cohesive strengths of the coating. The cold spray process avoids such reactions.
Mechanical Mixing at Interface
EDS X-ray Mapping showing mechanical mixing between coating material and substrate
Particle Velocity DistributionMeasured by DPV 2000
Millimeters0 2 4 6 8
Mill
imet
ers
0
2
4
6
8
500 m/sec600 m/sec700 m/sec800 m/sec900 m/sec
20 micron copper particles25 mm downstream400 psi, 400 C N2 gas
-Cold Spray Coating of Nickel On 6061-T6 Al
Cold Spray Ni has a hardness of HRC 41 and a resistivity of 6.84uohm/cm
Nickel
Coating
100% Dense
316L SS
Cold
Spray
Coating
316L SS Deposited by the Stationary System Using He
Aluminum
Substrate
ZE 41A-Mg
Coating / Substrate Interface
Cold Spray CP-
Al Coating
Cold Spray Coating of CP-Al On ZE 41A-Mg
~100% Dense
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Robot-Controlled, High Pressure, He and N Gas
Stationary Cold Spray System at ARL
Main Gas Stagnation Pressure 100-500 psi Gas Temperature 0-1300ºF Main Gas Flow Rate 30-100 CFM
Powder Feed Rate 10 to 30 pounds/hour Particle Velocity 300-1500 m/sec.
System ArrangementSystem Arrangement
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Hand-Held Heater-NozzleShop Compressed AirParticle Velocity 300-500 m/s
Portable Cold Spray Systems at ARL
Portable ARL Cold Spray SystemPortable ARL Cold Spray System
Highpressurefeeder
Helium cylinder
Regulator Flow control valve Nozzle
Braided flex hose
Helium Tank
Powder Feeder
Spray Nozzle
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Flame Spray Sn & Steel Coating, 12.2% Porosity
Cold Spray Al Coating,0.83% Porosity
Cold Spray Sn Coating,0% Porosity
Cold Spray vs. Thermal Spray
Aluminum Powder MorphologyAluminum Powder Morphology
-325 mesh 5056 Al Flake
-325 mesh Pure Al Spherical
Aluminum Powder MorphologyAluminum Powder Morphology
Coating quality is critically dependent on the feed powder composition, morphology, oxygen content, and mechanical properties.
1-5 um Pure Al Agglomerated
-325 mesh Pure Al Atomized
-325 mesh 5056 Al Flake
-325 mesh Pure Al Spherical
Purity of Cold Sprayed AluminumPurity of Cold Sprayed Aluminum
*The oxygen content of the cold spray coating is largely determined by the oxygen content of the original powder, not the process.
Cold Spray CP-Al Coating
0.34 %Oxygen 0.25 %Oxygen
Oxygen content measured by Inert Gas Fusion ASTM E 1019-03
-325 Mesh Cp-Al Powder
•The hardness of a cold-sprayed material is significantly higher than that of a conventional wrought material.
•The hardening is a result of the plastic deformation that occurs during particle impact and the refined microstructure of the material.
Cold Sprayed vs. Wrought MaterialsHardness Comparison
Cold Sprayed vs. Wrought Materials: Hardness
Cold Sprayed vs. Wrought Materials: Hardness
Cold Sprayed vs. Wrought Materials: Hardness
Yield Strengths of Worked Al AlloysYield Strengths of Worked Al Alloys
*The cold working that occurs during cold spray results in aluminum coatings having yield strengths greater than or equal to that of the underlying magnesium alloy.
Gas Pressure, psi
Gas Temp, °C
Nozzle Length, mm
Particle Velocity, m/s
Particle Temp, °C
Deposition Efficiency, %
400 20 150 1120 -114 99.99 400 300 120 624 147 22.67 400 300 150 637 139 50.88 400 300 150 + 100 672 117 99.06 400 300 100 + 150 637 183 92.50 400 350 150 661 167 98.94 400 350 150 + 100 697 146 99.99 400 350 100 +150 661 224 99.99 650 300 150 646 145 85.26 650 300 150 + 100 684 122 99.91 650 300 100 + 150 646 177 99.41 650 350 150 672 176 99.98 650 350 150 + 100 711 153 99.99 650 359 100 + 150 672 218 99.98
* Helium in red ** 20 micron MMD, SD = 4, for DE calculation
Effect of Nozzle Length, Gas Temperature & Pressure on Particle Velocity (20 micron CP-Al Particle)
Recent Cold Spray Applications
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Conductive material needed to fill seams
HMMWV shelters require EMI shielding to prevent entrance/escape of electronic signals.
The joints in al-composite walls must be sealed with a non-porous, conducting metal.
The composite structure requires low-temperature application of sealer.
Composite
Aluminum
EMI Shielding for HMMWV Shelter by Cold Spray
ARL Produces First Prototype Using Cold Spray Technology for theTerminal High Altitude Area Defense (THAAD) Project Office.
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Applying EMI Shielding on the HMMWV Shelter
Copper and Tin Deposited Onto The Doorframe with the Portable Cold Spray System
Aluminum/Zinc Applied to Interior Seams
Cross Section of Cold Spray Coating
Template shielded before spray 0.035 inch thick cold spray repair
Repair of Alclad Aircraft Skinby Cold Spray using CP Aluminum
Machined slot Cold Spray CP Al
Repair of Alclad Aircraft Skinby Cold Spray using CP Aluminum
SPD Copper on Silicon Carbide
Cold Spray Repair of Magnesium Components
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CoCo--Lead:Lead:Bruce SartwellBruce Sartwell
Naval Research LaboratoryNaval Research Laboratory
Code 6170Code 6170
4555 Overlook Ave SW4555 Overlook Ave SW
Washington, DC 20375Washington, DC 20375
Phone: 202Phone: 202--767767--07220722
Fax: 202Fax: 202--767767--33213321
[email protected]@nrl.navy.mil
CoCo--Lead:Lead:Victor ChampagneVictor Champagne
Army Research LaboratoryArmy Research Laboratory
AMSRLAMSRL--WMWM--MDMD
Building 4600Building 4600
Aberdeen Proving Ground, MD 21005Aberdeen Proving Ground, MD 21005
Phone: 410Phone: 410--306306--08220822
Fax: 410Fax: 410--306306--08060806
[email protected]@arl.army.mil
ESTCP Proposal 06ESTCP Proposal 06--EE--PP3PP3--031031
Cold Spray Technology for Repair of Magnesium Rotorcraft Components
Joint Test Protocol (JTP) Joint Test Protocol (JTP) has been developedhas been developed
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Program Objectives:Program Objectives:
To reclaim ZE 41A magnesium alloy components on Army and To reclaim ZE 41A magnesium alloy components on Army and Navy helicopters that have been removed from service due to Navy helicopters that have been removed from service due to severe corrosion and /or wear.severe corrosion and /or wear.
ARL will provide a repair/rebuild cold spray procedure for ARL will provide a repair/rebuild cold spray procedure for scrapped parts and assist in the transition and implementation oscrapped parts and assist in the transition and implementation of f this technology, initially, at NADEP, Cherry Point, NC.this technology, initially, at NADEP, Cherry Point, NC.
Cold Spray Technology for Repair of Magnesium Rotorcraft Components
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•Overview of Cold Spray Technology
•Leveraged Programs ( unprecedented head start)
•Discuss ARL Capabilities and Advantages of Cold Spray
•Present Test Results to Date
•Coating Integrity and Microstructural Analysis
•Adhesion, Hardness and Corrosion Tests
•Coating Material Selection and Powder Development
•Cold Spray Process Development and Hardware Modifications
•Cold Spray Demonstration on ZE 41A Mg Housings
29 – 30 August Meeting Objective: to lay the foundation for a JTP that can be executed by the ESTCP team such that at the completion of the program NADEP, Cherry Point has a fully functional cold spray system that is reclaiming magnesium rotorcraft components.
Cold Spray Technology for Repair of Magnesium Rotorcraft Components
1. Defense Science & Technology Organization (DSTO)2. Joint Strike Fighter (JSF)3. National Center for Manufacturing Sciences (NCMS)4. Lockheed Martin 5. Penn State Applied Research Laboratory6. Lawrence Livermore National Labs (LLNL)7. South Dakota School of Mines (SDSM)
ARL Leveraged Formal Programs
•Development of aluminum cold spray coatings for aluminum, magnesium and/or steel substrates has been established with the following:
1. 1. Corrosion protection of ferrous materialsCorrosion protection of ferrous materials-- Painted structures Painted structures –– viz. ALV viz. ALV –– access cover (USMC)access cover (USMC)-- Hardened steel landing structures (Boeing)Hardened steel landing structures (Boeing)-- Iron brake components (Delphi)Iron brake components (Delphi)
2. 2. Corrosion protection and restoration of magnesiumCorrosion protection and restoration of magnesium--Repair ZE41& AZ91Repair ZE41& AZ91--D Magnesium (U.S. Army Research Lab, NADEPD Magnesium (U.S. Army Research Lab, NADEP––
Cherry Point, Ford)Cherry Point, Ford)
3. 3. Corrosion protection and restoration of aluminumCorrosion protection and restoration of aluminum-- repair of Alclad (Boeing commercial, Air logistics, Cherry Poinrepair of Alclad (Boeing commercial, Air logistics, Cherry Point) t)
4. 4. Aluminum brazementsAluminum brazements (Delphi)(Delphi)
5. 5. ColdCold--spray consolidation by Ultrasonicsspray consolidation by Ultrasonics (Solidica)(Solidica)
CTMA* - NCMS** Collaborative Project
* Commercial Technologies for Maintenance Activities** National Center for Manufacturing Sciences
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Cold Spray Al Coating 0.015 inch
CP- Al Cold Spray Coating Applied to ZE 41AMg
8,500 psi adhesion
Interface is free of voids and oxides
ARLARL--DSTODSTO NN22, 380 psi, , 380 psi, 250250°°CC 27432743
ARLARL--DSTODSTO He, He, 380 psi, 380 psi, 2020°°CC >6527>6527
ARLARL--NCMSNCMS He, He, 380 psi, 380 psi, 2020°°CC >8505>8505
Program Conditions Adhesion (psi)
CP- Aluminum Cold Spray Coating Adhesion to Magnesium
ARL Portable System Parameters for ARL Portable System Parameters for Applying CPApplying CP--Al to ZE41A Al to ZE41A -- MgMg
Operating ParameterOperating Parameter SettingSetting
Helium PressureHelium Pressure 400 400 –– 500 psi500 psi
Helium TemperatureHelium Temperature 20 Degree C20 Degree C
Helium FlowHelium Flow 20 SCFM20 SCFM
Powder FlowPowder Flow 1 1 –– 5 gram/minute5 gram/minute
Particle Mean DiameterParticle Mean Diameter 20 micron20 micron
Particle Exit VelocityParticle Exit Velocity 1000 meter/second1000 meter/second
Helium Cylinder LifeHelium Cylinder Life 9 minutes9 minutes
Example of Mg Example of Mg Damage RepairDamage Repair
Machined Pit
ZE 41A Magnesium
Plate
CP-Aluminum Cold Spray Coating Machined Flush
Machined Groove
CP-Al Deposited by the ARL Portable Cold Spray System
CP-Al Deposited by the ARL Portable Cold Spray System
CP-Al Deposited by the ARL Portable Cold Spray System
5056 Al Deposited by the Stationary System Using He
Aluminum
Substrate
5056 Al
Cold
Spray
CoatingInterface
Coating / Substrate Interface
Cold Spray 5056
Coating
5056 Al Deposited by the Stationary System Using He
CP-Al Deposited by the Ktech Cold Spray System ------ Nitrogen at 380 psi, 250 C
ARL Achievements
Corrosion Resistance:
>5,000 hours salt fog resistance-ASTM B117 (Al, 4340 steel substrates)
>619 hours salt fog resistance-ASTM B117 (ZE 41A magnesium substrate)
Hardness:
57 Brinell Hardness
Yield Strength:
22ksi comparable to ZE41A-T6 and AZ91E-T6 magnesium
Density:
>99% with oxide content of 0.25%
Adhesion:
> 8,500 psi
Cold Spray Process Summary:
can be applied in production or in the field at room temperature
Applying CP-Al by Cold Spray over Magnesium
Mg Housing Coated with CP-Al
Flat surface of Mg housing covered with CP-AL Cold Spray
ARL Technical Hurdle
to achieve similar results with the use of nitrogen as the carrier gas
*nozzle design*system modifications (heater, powder feed)*powder morphology and condition
Technical Approach