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Co-Matrix™ Filters for Electrolyte Filtration SpinTek Filtration, Inc. Delkor South America Ltd. Co-Matrix™ Filters for Electrolyte Filtration SpinTek Filtration, Inc. Delkor South America Ltd.

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Page 1: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Co-Matrix™ Filters for Electrolyte Filtration

SpinTek Filtration, Inc.Delkor South America Ltd.

Co-Matrix™ Filters for Electrolyte Filtration

SpinTek Filtration, Inc.Delkor South America Ltd.

Page 2: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Organic RecoveryOrganic Recovery

Page 3: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

SpinTek InstallationsSpinTek Installations

hh CVRD USINA, BrazilCVRD USINA, Brazil 129 m129 m33/hr/hrhh Chelopech, BulgariaChelopech, Bulgaria 225 m225 m33/hr/hrhh Gaby, ChileGaby, Chile 1,400 m1,400 m33/hr/hrhh Kansanshi Copper, Zambia Kansanshi Copper, Zambia 494 m494 m33/hr/hrhh BHPBHP--Billiton (Escondida), Chile 1,700 mBilliton (Escondida), Chile 1,700 m33/hr/hrhh Spence, ChileSpence, Chile 2,400 m2,400 m33/hr/hrhh Goro Nickel, New Caledonia 1,750 mGoro Nickel, New Caledonia 1,750 m33/hr/hr

Page 4: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

SpinTek InstallationsSpinTek Installations

hh Skorpion Zinc, Nambia Skorpion Zinc, Nambia 700 m700 m33/hr/hrhh Nkana Leach, Zambia Nkana Leach, Zambia 145 m145 m33/hr/hrhh Mufulira, Zambia Mufulira, Zambia 145 m145 m33/hr/hrhh Sable Zinc, Zambia Sable Zinc, Zambia 100 m100 m33/hr/hrhh Gunpowder, Australia Gunpowder, Australia 400 m400 m33/hr/hrhh Toquepala, Peru Toquepala, Peru 825 m825 m33/hr/hr

Page 5: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Dual-Media FiltersDual-Media Filters

Tankpic.jpg

Page 6: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

SX Dual-Media FilterSX Dual-Media Filter

Page 7: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

GunpowderGunpowder

Page 8: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

CoMatrix FilterCoMatrix Filter

Page 9: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

CoMatrix™ Electrolyte FilterDesign Operation – 60m3/hr.m2CoMatrix™ Electrolyte FilterDesign Operation – 60m3/hr.m2

0

10

20

30

40

0 2 4 6 8 10 12Elapsed Time (hours)

Org

anic

Ent

rain

men

t (pp

m)

Inlet

After Matrix Plates

Outlet

Page 10: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

OperationOperation

Page 11: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Aqueous

Filtered AqueousService Mode

Filter Service FlowFilter Service Flow

AnthraciteGarnet

Packing

Page 12: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Aqueous OrganicPurge

Organic Purge

Filter Organic PurgeFilter Organic Purge

AnthraciteGarnet

Packing

Page 13: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Coalescing Droplets on

Matrix Plate Surface

Coalescing Droplets on

Matrix Plate Surface

Page 14: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Air

Aqueous RecoveryFeed Evacuation

Filter Feed EvacuationFilter Feed Evacuation

AnthraciteGarnet

Packing

Page 15: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Water InletVent

Water Fill Step

Filter Water FillFilter Water Fill

AnthraciteGarnet

Packing

Page 16: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Air Outlet

Air InletAir Scour Step

Filter Air ScourFilter Air Scour

AnthraciteGarnet

Packing

Page 17: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Backwash Outlet

Water InletBackwash Step

Filter BackwashFilter Backwash

Anthracite

Garnet

Packing

Page 18: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Aqueous

Filtered AqueousService Mode

Filter Service FlowFilter Service Flow

AnthraciteGarnet

Packing

Page 19: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Technical CommentsTechnical Comments

ii Process Design considers 12 hour cycle Process Design considers 12 hour cycle

ii Mechanical Design considers the filters rated at 350 kPa.Mechanical Design considers the filters rated at 350 kPa.

ii Operating CostsOperating Costs for CoMatrix will be lower, value depends on for CoMatrix will be lower, value depends on

backwashbackwash

ii Coalescing Plates not considered a consumable. Some extra cost Coalescing Plates not considered a consumable. Some extra cost

added into Capital Spares (see op cost tables)added into Capital Spares (see op cost tables)

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Organic RecoveryOrganic Recovery

• To Recover - Entrained Organic solution from the electrolyte prior to Electro-winning

• Entrained Organic defined as droplets of organic solution not miscible in the aqueous portion

• Current technology considers the use of Column Flotation

Coalescers

SX Dual Media Filters

• This presentation reviews the electrolyte filtration step in theorganic recovery process.

Page 21: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Design ConceptDesign Concept

Anthracite bed holding capacity defined in kg organic per m2

anthracite bed surface

Anthracite load bearing capacity defines filter capacity

Coalescing plates take out part of the organic load

Less organic load on anthracite bed means

» Longer cycles without backwash

» Higher feed rates for the same cycle

» Higher organic content in feed

Page 22: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Feed Flow of 1800m3/hrFeed Flow of 1800m3/hrDual Media – Design Base - 12 m3/hr. m2

150m2 of Filter Area

10 x 4.6m (15’) diameter DM Filters

CoMatrix – Design Base - 60 m3/hr. m2

30m2 of Filter Area

3 x 3.6m (12’) diameter Filters

Page 23: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

CoMatrix BenefitsCoMatrix Benefits

o Smaller Foot Print, less instruments, less valves, piping, controls etc.

o Lower Capital Cost

o Lower Operating Cost» Less Filter Media

» Backwash Water Consumption 6lt per m3 Electrolyte

» Dual Media Backwash Consumption +- 19lt per m3 Electrolyte

o Can accept higher Organic in Feed Stream – if lower design rates used

Page 24: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Industrial Scale Pilot Plant TrialsIndustrial Scale Pilot Plant Trials

Objectives:o Compare Operation of CoMatrix Design to standard

Dual Media Design

Test Runs – Oxide Cu Leach Plant in Chileo Dual Media ran at design Rate – 12 m3/hr.m2

o CoMatrix ran at: 3 x DM Filtration Rate - 36 m3/hr.m2

4 x DM Filtration Rate - 48 m3/hr.m2

5 x DM Filtration Rate - 60 m3/hr.m2

Page 25: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Industrial Scale Pilot Plant TrialsIndustrial Scale Pilot Plant TrialsMeasurementso Operating Time – in serviceo Backwash Time – out of serviceo Flow Rateso Pressure drops during in and out of service

operations

Pilot Equipmento 0.05m2 CoMatrix Filter x 3mts high + filter media,

CoMatrix packs, valves, PLC etc.

Page 26: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Results 3 x DM Filtration RateResults 3 x DM Filtration Rate

Dual Media

Dual Media

Dual MediaDual Media

Page 27: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Results 4 x DM Filtration RateResults 4 x DM Filtration Rate

Dual Media Dual Media

Dual Media

Page 28: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Results 5 x DM Filtration RateResults 5 x DM Filtration Rate

Dual Media Dual Media

Dual Media

Organic Break Through after 8 hoursOrganic Break Through after 8 hours

Page 29: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

CoMatrix InstallationsAnglo Base Metals - Skorpion

CoMatrix InstallationsAnglo Base Metals - Skorpion

Loaded Electrolyte Filters

Raffinate & HCl Solution Filters

Page 30: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Escondida Low Grade

Sulphide Project

Escondida Low Grade

Sulphide Project

4 x 4.11m dia CoMatrix 480-625 m3/hr flow to each filter – 1880 m3/hr totalOriginal project contemplated 8 x 4.72m Dual Media Filters60 ppm inlet organic, 2 ppm outlet

Page 31: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

Escondida Low Grade

Sulphide Project

Escondida Low Grade

Sulphide Project

Start up – June / July 2006

Initial problems with services and automated sequence

Initial Data sketchy. 2 to 3ppm organic and 1 to 3ppm inorganics at design flow @ 12 hour cycles

Page 32: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

BHP Billiton Spence

BHP Billiton Spence

6 x 3.81m dia CoMatrix 420-470 m3/hr flow to each filter – 2500 m3/hr totalOriginal project contemplated 12 x 4.57m Dual Media Filters100 ppm inlet organic, 2 ppm outlet

Page 33: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

BHP Billiton Spence

BHP Billiton Spence

Page 34: Co-Matrix™ Filters for Electrolyte Filtrationspintek.com/wp-content/uploads/2013/05/sx_coalesce...SpinTek Installations hCVRD USINA, Brazil 129 m3/hr hChelopech, Bulgaria 225 m3/hr

GRACIAS – THANK YOUGRACIAS – THANK YOU