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Personal Protective Equipment (PPE) Christian Rantzau Specialist Chemical Adviser University of Melbourne

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Page 1: Christian Rantzau Specialist Chemical Adviser University ... · • Sandals, thongs (flip flops), peep-toe and/or strappy designer heels, Crocs, ballerina shoes etc. are not acceptable

Personal Protective Equipment (PPE)

Christian Rantzau

Specialist Chemical Adviser

University of Melbourne

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Scope of the course

• Understand why PPE is needed

– What hazards are in the working environment?

– What parts of the body we need to protect?

• Determine what PPE is needed

– What basic PPE should I wear?

– What items of specialised PPE might I need?

• Ensure PPE is worn

– How does it fit correctly?

– What are the Dos and Don’ts?

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Why do we need protection?

• A hazardous environment may have:

– Airborne materials

• Dusts, fumes, particulates

– Biological materials

• Bacteria, viruses, other microbes

– Chemicals

• Corrosives, toxics, irritants, hazardous substances etc..

– Light

• Ultra Violet, Infra Red

• What other hazards exist in our environment?

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Why do we need protection?

These hazards can enter the body via 4 ways:

Ingestion• Eating food that has come into contact with contaminants

Absorption (skin & mucous membranes)• Liquids, fumes, vapours etc. being absorbed• Radiation (UV, IR, Ionising)

Inhalation• Breathing in dusts, vapours, fumes etc.

Injection• Needlestick, scalpel cuts etc.

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What is PPE?

Personal Protective Equipment includes:

• Eye Protection

– Glasses, goggles, face shields, barriers

• Gloves

– latex, nitrile, thermal, Kevlar, rubber, PVC, vinyl

• Safety Shoes

– Safety boots (i.e. steel caps), closed shoes, rubber boots

• Protective Clothing

– Lab coats, aprons, hairnets, overalls

• Respiratory Protection

– Masks (P1 + P2), respirators, SCBA

• Head Protection

– Hard hats, helmets

• Hearing Protection

– Ear muffs (Peltors) , ear plugs

Page 6: Christian Rantzau Specialist Chemical Adviser University ... · • Sandals, thongs (flip flops), peep-toe and/or strappy designer heels, Crocs, ballerina shoes etc. are not acceptable

What is PPE?

Personal Protective Equipment includes:

• Eye Protection

– Glasses, goggles, face shields, barriers

• Gloves

– latex, nitrile, thermal, Kevlar, rubber, PVC, vinyl

• Safety Shoes

– Safety boots (i.e. steel caps), closed shoes, rubber boots

• Protective Clothing

– Lab coats, aprons, hairnets, overalls

• Respiratory Protection

– Masks (P1 + P2), respirators, SCBA

• Head Protection

– Hard hats, helmets

• Hearing Protection

– Ear muffs (Peltors) , ear plugs

Each part of the body has

its own requirements:

Anywhere else????

Eye, Face

Hand

Feet

The body(torso, arms, legs)

Lungs

Head

Ears

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Priority for Protection

What areas are most at risk?

The list below is in order of areas that are most important to protect on our body:

Priority 1:

• Eyes, Lungs, Face, Hearing

Priority 2:

• Torso, Hands, Feet

Priority 3:

• Arms, Legs, Thermal core

With each of these areas, there is specific equipment we should use. The key is to know what items work on what parts of the body, and what they are best designed to protect us from.

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Control Measures

Use a less hazardous chemical

Use Class II cab or fume hood

SOPs training and review

Glasses, coat, gloves, mask etc.

National Institute for Occupational Safety and Health

- From the CDC web site

- http://www.cdc.gov/niosh/topics/hierarchy/

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PPE is the last risk management option – why?

PPE is the last option that should be considered when controlling risk.

We humans are lazy and forgetful – PPE use requires us to remember

to use it and to use the right/suitable equipment.

• Using PPE usually means we are up close and personal to the risk.

• It is considered to be a “passive” option

• PPE is not always there or “switched on”

• Its use requires us to take conscious action in order for it to work as

a safety control.

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PPE is the last risk management option – why?

Imagine working as this bomb technician – would you prefer to be

wearing your PPE and directly working on the bomb, or using a robot

from a safe distance away?

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What is NOT PPE?

Sometimes we wear what we think is PPE, but we are actually wearing

items to protect ONLY what we are working with.

These items provide very little protection:

• Sterile gloves

• Surgical masks

• Paper gowns

• Booties

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Why am I here doing training?

To remind you to use the right

PPE and not use unapproved

alternatives.

To reinforce to you that you DO

NOT modify PPE for any reason!

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Where/when do we wear PPE?

• When directed to by Risk Assessments (RA) or Standard Operating

Procedures (SOP).

• When stated in MSDS information.

• When Laboratory or Workshop Signage indicates.

• When directed to by Supervisory Staff.

White on blue signs (as below) at entry points to labs indicate that it is

mandatory to wear the applicable PPE beyond that point.

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Selection of the appropriate PPE?

Once your area has been assessed for hazards, your

employer must select, with your help, appropriate

personal protective equipment for you to use while

performing your work.

All PPE selected and supplied at the University

complies with one of the many specific Australian

Standards.

You can find further information on these standards

from:

• SAI Global website - EResource through the library)

• Health & Safety Unit – UoM

• Chemical Management Guidelines book

• Worksafe website

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Appropriate PPE

PPE

What do I wear?

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Appropriate PPE

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Appropriate PPE

Many people are blinded each year

from work related eye injuries.

Injuries that could have been

prevented, if only those persons had

been wearing eye or face

protection.

• Contact with chemicals

• Flying objects and particles

• Swinging cables and ropes

• Radiant energy

• Small particles

• Dusts, powders, fumes and mists

• Molten metals

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Appropriate PPE

TRIFLUOROMETHANESULPHONIC ACID 98%

(TRIFLIC ACID)

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Why do we wear eye protection

devices?

You only have two eyes.

Lose one, and life can be difficult.

Lose both and life will never be the

same.

They don’t grow back!!

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Safety Glasses

• One of the main types of injury that can occur in a Laboratory or

Workshop is a splash or projectile to the eye/s.

• Safety Glasses provide protection from chemical splashes,

particulates and projectiles.

• Current Standard AS 1337:2010

• Safety Eyewear MUST be worn AT ALL TIMES in designated areas.

• General prescription glasses do not conform to AS 1337 and are

not considered Safety Glasses.

• When purchasing any eye protective devices make sure you are

purchasing the ones that will give the right protection.

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Safety Goggles

• When handling substances or completing a process that

produces dust, fumes or vapours, safety glasses may not

provide adequate protection as the dust, fume or vapour may

penetrate around the glasses.

• For these tasks, it is recommended you wear Safety Goggles.

• Safety Goggles form a seal around the eyes and provide

protection from chemical fumes.

• Note the subtle difference in the symbols for Safety Glasses and

Safety Goggles

Glasses Goggles

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Face Shields

Face Shields:

• provide protection for your face as well as your eyes.

• should be used when working with aerosols or liquids under

pressure or cryogenic liquids and frozen samples.

• should be used where the risk of a splash on the face is as

dangerous as a splash in the eye (e.g.. handling liquid nitrogen).

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Maintenance of eye protection devices

• Most lenses in eye protection devices are made from

Polycarbonate.

• The best method for cleaning Polycarbonate lenses is

using warm soapy water to wipe the lenses.

• Some solvent based glass cleaning products can

leave the lenses smeary and brittle.

• Damaged or overly scratched eye protection devices

should be thrown away and replaced as their integrity

could be compromised and/or restrict your vision.

• Basically, damaged eye protective

devices are unsafe and using them

is putting yourself in danger.

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Storing eye protection devices

• Eye protection devices should be stored when not in use.

• The storage should be in an area where they are not likely to be

scratched or exposed to vapours or liquids that may deteriorate

the lenses i.e. hanging beside the fume cabinet is NOT

appropriate.

• It is ideal that you have your own pair of safety glasses so that

they are always available when you need them.

• Your supervisor/lab is required to provide you with a pair of basic

safety glasses and replace them if damaged.

• Purchasing your own safety glasses is a tax deduction. You

generally take better care of them when they are your own and

you can buy ones that make you look good!! If you require

prescription safety glasses, you can go to the Eyecare Clinic

Swanston St (30% discount)

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Eye protection only works when used

correctly!

They only work when covering your eyes!!

Maybe a face

shield would

have been a

better option

They really do work!

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Gloves

• Gloves provide protection for your hands whilst working with or being exposed to chemicals and hazards associated with some equipment and/or machinery.

• Different types of gloves are used for handling different substances.

• Never wear gloves that have handled chemicals outside a Laboratory as you may contaminate items such as door handles and/or contaminate your gloves.

• Some gloves, such as Latex and Nitrile are designed to be disposable – throw them away as they become contaminated.

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Selecting the right glove

Chemical Handling Gloves

• It is important to wear the correct glove for the product that you are handling to protect yourself – the MSDS for the chemicals you are using will tell you the correct glove to use in order to provide the best protection.

• Ansell produces a comprehensive guide on the resistance of its range of laboratory gloves to a variety of chemicals:

• http://www.ppe.ansell.com.au/chemical-glove-guide

The MSDS information and

guidance like that provided by

Ansell needs to be considered

when making the choice about

the suitability of gloves to be

used when handling chemicals.

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Don’t forget gloves can protect more

than just chemical hazards

While so far we have mainly spoken about gloves protecting us

from chemical hazards, there are other situations where gloves

can provide other protection:

• Handling very hot or very cold items (i.e.: working

with liquid nitrogen or heaters/ovens):

– Thermal insulating gloves can be used

to provide thermal protection.

• Handling sharp objects:

– Leather gloves can be used to prevent

cuts to hands.

• Washing glassware:

– Dishwashing gloves can help prevent/reduce

cuts from broken glass as well as scalds from hot water.

NOTE: cuts to hands from broken glassware during washing is one of the most

common Chemistry & FMDHS Laboratory injuries – wear some gloves!!

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Why do we wear gloves?

To protect ourselves from painful

and disfiguring injuries!!

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Why do we wear gloves?

When things go wrong:

Dimethyl Mercury

- A few drops from a pipette onto the latex glove.

- Glove not removed, but cleaned up the area and spill.

- Dimethylmercury can penetrate the glove and skin in 15 secs

- 5 months after exposure, noticed neurological problems

- In hospital – urinary mercury at 234 ug/L;

- Toxic >50ug/L; normal is 1-4 ug/L

- Use multilayered neoprene gloves

https://en.wikipedia.org/wiki/Karen_Wetterhahn

https://www.youtube.com/watch?v=h049Hgfk-BI

Hydrofluoric acid or hydrogen fluoride

- Have calcium gluconate gel available

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Safety footwear

• In the commercial/industrial business world, the symbol for safety

footwear means “Safety cap footwear” i.e.: Steel cap boots.

• At the University, this symbol means “Solid, closed shoes”.

• Solid closed shoes are those that encase the foot and provide a

stable walking/standing posture.

• Open toes, opens back, open top shoes (even if wearing socks) are

not acceptable to wear, as they leave parts of the foot exposed to

potential spills or other contamination.

• Sandals, thongs (flip flops), peep-toe and/or strappy designer heels,

Crocs, ballerina shoes etc. are not acceptable.

• Runners and other shoes that enclose the foot are acceptable.

Leather shoes are the best option.

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Safety footwear

https://www.youtube.com/playlist?list=PLNhVwA0X

ZE27h8uh8ug8kX3362W2CAvai

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Safety footwear

• It is up to you to ensure that you have the correct footwear to be

allowed to enter the lab.

• If you are in the habit of wearing casual footwear, then it is

highly recommended that you leave some suitable shoes that

your can change into whilst working in a laboratory or workshop.

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Lab coats, aprons and other long

sleeve/long leg clothing

• The white on blue symbol here indicates legs and arms must be

covered. There are a variety of PPE that can achieve this. The

main one used at the University are lab coats.

• Coverall and overalls are also available.

• These are coats designed specifically for use in the laboratory.

They are made of medium weight 100% cotton twill.• Lab coats are designed as a single layer of instant protection,

generally from chemical splashes, for both your skin and you ownclothing.

• It’s better to damage a lab coat that your own clothing!• You should not wear your lab coat in public areas or to the tea or

rest rooms to prevent contamination of non-chemical areas.• Lab coats should be washed regularly. A lab coat washing service

is available through the Chemistry Store.• DO NOT take your lab coat home to wash it as you may

contaminate family or housemates clothes!!

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Lab coats, aprons and other long

sleeve/long leg clothing

When things go wrong:https://www.youtube.com/watch?v=MS6XaKhzV3Q

Tert-butyl lithium

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Aprons

• Some tasks performed in labs may require the use of an

apron as further body/clothing protection.

• Aprons can be made of different materials, and like gloves each

material will have different chemical resistance characteristics.

• The MSDS’s will tell you when an apron should be worn and the

specific type of apron material.

If the right kind of apron is not available in

your lab, cease the task and speak to

your supervisor about purchasing the

correct type.

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Respiratory protection

Why is respiratory protection so important?

Safety and Health hazards in the workplace are a major concern for

both employers and employees.

It is important, though, to remember that hazardous materials only

present a health hazard when they come into contact with your

body.

Hazardous materials can enter your body in four ways.

• Ingestion.

• Skin absorption.

• Inhalation.

• Through the eyes.

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Respiratory protection – Particle Size

Material Microns

Metal fumes 0.001 - 100

Molecules 0.001 - 0.1

Chysotile 0.02 - 0.03

Erionite (Zeolite silicate) 0.02 - 0.03

Viruses 0.01 - 0.1

Smoke / Mist 0.01 - 5

Bacteria 0.1 - 10

Spore / Pollens 5 - 100

Dust 5 - 100

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Respiratory protection

There are two major types of respirators.

• Air Purifying

– Dust masks, respirators

• Supplied Air.

What does SCBA and SCUBA mean?

Self Contained Breathing Apparatus

• Have air tanks and a full face respirator

• Require specialised training and certification

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Respiratory protection

Surgical Mask:

• Provides absolutely NO protection

Basic Mask (P1)*:

• Filter out 80% of particles (>1 micron)

• Designed for dusts, dander, basic home duties

• Disposable – discard after use

Specialised masks (P2)*:

• Filter out 94% of particles (>0.3 micron)

• Designed for most short term exposure in a lab environment

• Disposable – discard after use

Full Face masks (P3)

• Filter out 99.955 of particles (>0.3 micron)

• Have specific cartridges for different materials

NOTES: *Only provides a few hours protection so change at least daily

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Selecting the right Dust Mask

• Your MSDS will tell you if a chemical you are working with should

be used with a Dust Mask.

• The MSDS should also advise as to which “P” the Dust Mask

should be.

• Don’t buy Dust Masks from places like the “$2 Shop” as they don’t

conform to the required Australian Standards (AS1716) for

respiratory protective devices and won’t filter to the level you need.

• Always purchase Dust Masks from a reputable safety product

provider – try your Chemistry Store.

• If supplied masks have a metal strip, the strip

goes over your nose – press it in to form a seal

around the ridge of your nose.

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Selecting the correct respirator

To select the correct respirator, you must determine the hazard

posed by the environment.

You must answer these four basic questions:

• What type of contaminant is present?

• What form is the contaminant?

• How toxic is the contaminant?

• What is the concentration of the contaminant?

In addition, to determining the level of the hazard, you must also consider:

• How long will you be exposed to the contaminant?

• What is your individual sensitivity to the contaminant?

• What are your individual requirements?

Individual requirements:

• Do you wear glasses?

• Do you have a beard or other facial hair?

• Do you wear dentures?

• Will you have to wear other PPE?

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Maintenance/Storage of Dust Masks

• Dust Masks need to be stored in a dust proof bag or container (the

box they were supplied in, so long as left closed, is sufficient) so as to

prevent them from being contaminated before they have been used.

• There is no maintenance needed on a Dust Mask. They are

disposable items and should be thrown away once dirty on the

outward side.

• If there is dirt/contamination on the inside, do not use and dispose of.

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Respirators

• Respirators are sometimes needed when working with

chemicals that create dangerous fumes or vapours.

• Respirators provide protection depending upon which cartridge is used – not all cartridges provide the same filtration.

• Paper type cartridges will only block dust and particulates but not vapours.

• Specialised charcoal or vapour specific cartridges provide protection against fumes and vapours.

• Cartridges need to be changed regularly. Again, no standard time, it depends on the work.

• If you can smell the fume/vapour through the respirator it is not working. Check it’s seal and change cartridges.

• Always refer to MSDS and Cartridge manufacturer for specific product information.

• Full Face Respirators do the same thing except they also have in built eye protection.

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Maintenance of respirators

• Respirators must be kept in dust proof containers and away from

areas of potential contamination to the inside of the mask or filter.

• Sharing Respirators is not recommended.

• If you do share respirators you should clean before and after use,

using an alcohol swab. Wipe around the whole mouth piece and

leave to dry before using

• If you have your own respirator, once a year the valves should be

taken apart and cleaned as well.

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Fitting the respirators

Donning the respirator:

• With one hand, hold the respirator to

your face.

• While holding the respirator in place,

slip the head harness over your head.

• Adjust and tighten the harness straps

until it fits snugly.

• The best way to tighten a respirator is

to tighten the straps from the bottom

up.

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Fitting the respirators

Fitting the respirator:

To ensure an airtight seal, you must ‘Fit Test’ the respirator.

Positive Pressure Test

• Close the exhalation valve with your hand.

• Breath out slowly.

• Ensure no air leaks.

Negative Pressure Test

• Close the respirators inhalation valves with your

hands, breath slowly.

• Hold your breath for 10 seconds, check for leaks.

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Self Contained Breathing Apparatus

Self Contained Breathing Apparatus (SCBA) is used at the

University for emergency response events such as:

• Investigation and response to laboratory gas alarms;

• Spill clean up of chemicals that give off highly dangerous or toxic

vapours.

Only certified and approved

operators are allowed to use

the SCBA units.

If you think you need to be

SCBA qualified, discuss with

your supervisor – SCBA

training is available at a cost.

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Hearing protection is not usually needed in most labs.

However, if you do need to use it, or visit sites where you need to

use it you need to know:

• Quality ear muffs from safety product providers are MUCH

better than ones from the local hardware store.

• Some types of ear plugs are “one-use” foam disposable and

others are “re-useable” rubber.

• Ear muffs are better for long term/daily use as they don’t cause

dirt/oil from your hands to build up inside your ears.

Hearing protection

One-use disposable

foam ear plugs Re-useable rubber ear plugs Ear muffs

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Hearing protection – Noise levels

Daily Noise Dose (DND)

All of these are equivalent to a DND of 1.

Level Period

85 dB (A) for 8 hours

88 dB (A) for 4 hours

91 dB (A) for 2 hours

95 dB (A) for 50 minutes

105 dB (A) for 5 minutes

An office or routine laboratory is about 60-70dB

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Hearing protection – Noise levels

When Should You Wear Hearing Protection?

You must wear hearing

protection whenever you are

exposed to noise that is 85

decibels or greater for an 8

hour period of time.

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Fitting PPE

Fitting Foam Earplugs

To insert the earplug:• Reach around the back of your head,

gently pull your ear back and up.

• Roll the plug into a small diameter

and insert into the ear canal.

• Hold the plug in place for a few

seconds while it expands to a good

seal.

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Hearing protection

• Inserting foam ear plugs

is a skill to do it correctly.

• If done incorrectly, they

won’t provide the noise

attenuation they are

designed for.

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Fitting PPE

Fitting PVC Earplugs

To insert the earplug:

• Reach around the back of your head,

gently pull your ear back and up.

• Begin to insert the plug into the ear

canal.

• Work the plug well into the ear using

a circular motion.

• One inserted, wait a few seconds to

make sure the plug is securely fitted

into your ear.

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Fitting PPE

Fitting Earmuffs

• Limited effectiveness if the seal around

your ear is poor.

• Make sure that the earmuffs fit snugly

around your ear.

• Use earplugs if you wear glasses,

earrings, or cannot get a good seal.

• A good quality earmuff e.g. Peltor by

3M, will offer much more comfort and

can be worn or longer periods.

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Other PPE

There are many other kinds of PPE that you may see in your

working life, such as:

• Hard hats

• Harnesses & fall arrest systems

• Sun protection

• Manual handling aids (knee pads, back braces etc.)

These are not generally used by University Staff and Students, and

therefore not covered in this lecture.

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Obtaining & replacing PPE

• Each Research Group is responsible for purchasing and maintaining their own PPE as required (see your Supervisor).

• Students are responsible for providing their own lab coats. Other items needed should be provided by your supervisor.

• Basic PPE (gloves, glasses, goggles, lab coats, safety footwear) is available for purchase, on-campus, from the Chemistry Store.

• Only buy PPE from reputable safety product providers.

• For eye protection, only purchase AS1337 compliant items.

• For respiratory protection, only purchase AS1716 compliant

items.

• For hearing protection, only purchase AS1269 compliant items.

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Summary – Right product for the job

Use the right PPE for the hazard involved, and only use PPE that

has been designed/engineered to do the job you are asking of it.

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Further information

If you have further questions about:

• Types of PPE needed in your studies,

• PPE available in your lab,

• PPE that must be used in your lab,

First ask your supervisor or senior persons in you lab.

If you need specific OHS advice about PPE types or recommendations

on where to purchase PPE from, contact the knowledgeable staff in

the Chemistry Store or the Health & Safety Unit at the University:

Christian Rantzau

[email protected] or

[email protected]

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