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Chemistry Topic 11 Organic Chemistry

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Page 1: Chemistry Topic 11

Chemistry Topic 11

Organic Chemistry

Page 2: Chemistry Topic 11

• Chemistry

• Organic Chemistry

• Obj: SWBAT elucidate partial structures of organic compounds based on structure, formula, and names

• Do Now: What comes to mind when you hear the word “organic”?

Page 3: Chemistry Topic 11

Bonding of Carbon Atoms • Organic Chemistry = study of carbon-based

compounds

• Carbon can form 4 covalent bonds (tetravalent)

• Saturated = compound only has single bonds

• Unsaturated = compound contains one or more double

or triple bonds

Page 4: Chemistry Topic 11

Structural Formulas

• Molecular formula shows the number of atoms of each element

• Structural formula shows the arrangement of those atoms

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Hydrocarbons

• Compounds that ONLY have HYDROGEN and CARBON

• Split up into 3 homologous series alkanes, alkenes, and alkynes

• Generally, the larger (heavier) the compound, the higher the boiling point.

• Table Q

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Alkanes

• Only single bonds

• Alkanes are saturated

• Formula CnH2n+2

• Name ends in “-ane”

• Ex. CH4, C2H6, C3H8

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Alkenes

• Contain a double bond

• Unsaturated

• Formula CnH2n

• Name ends in “-ene”

• Ex. C2H4, C3H6, C4H8

Page 9: Chemistry Topic 11

Alkynes

• Contain a triple bond

• Unsaturated

• Formula CnH2n-2

• Name ends in “-yne”

• Ex. C2H2, C3H4, C4H6

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Isomers

• SAME MOLECULAR FORMULA, DIFFERENT STRUCTURAL FORMULA

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• Practice Problems

Page 12: Chemistry Topic 11

• Chemistry

• Organic Chemistry

• Obj: determine the correct name of an organic compound based on the structural features of that compound

• Do Now:

• HW:

• Worksheet

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Naming Organic Compounds

• 1. Find longest carbon chain (they can bend!)

– This is called the parent chain

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• 2. Identify alkyl groups (groups hanging off chain, put them in alphabetical order)

• Halides also

– F = fluoro

– Cl = chloro

– Br = bromo

– I = iodio

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• 3. If necessary assign numbers to alkyl groups (Final name has lowest possible numbers)

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• 4. If more than one of the same alkyl group is present give prefixes

– Di for 2

– Tri for 3

– Tetra for 4

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Where’s the longest Carbon Chain?

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How should we number it?

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Are there any groups coming off the parent chain?

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What are the names of those groups?

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What’s the correct numbering?

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What’s the final name?

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Name these

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• Chemistry

• Organic Chemistry

• Obj: determine what functional groups are found within different organic compounds

• Do Now: Name this

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Functional Groups

• Functional groups = atoms or groups of atoms that give a compound distinctive physical and chemical properties

• R = Carbon Chain

• R’ = another carbon chain

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Halides

• When a halogen (F, Cl, Br, or I) replaces a hydrogen in an alkane organic halide

Page 35: Chemistry Topic 11

Alcohols

• Alcohol = organic compound in which one or more H are replaced by OH (hydroxyl)

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Classifying alcohols

• Look at the C the OH is attached to

• The number of Carbons touching that Carbon designates whether the alcohol is primary, secondary, or tertiary.

• Names end in -ol

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Classifying Alcohols

• If there are 2 OH s dihydroxy alcohol

– diol

• If there are 3 OH s trihydroxy alcohol

– triol

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Aldehydes and Ketones

• Carbonyl (C=O)

• Aldehyde = carbonyl is at the end of chain

– Names end in -al

• Ketone = carbonyl is not at the end of chain

– Names end in -one

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Ethers

• Carbon chains joined by an oxygen atom

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Organic Acids

• Have a carboxyl group (-COOH)

– Name ends with –oic acid

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• Chemistry

• Organic Chemistry

• Obj: Determine the products of different organic reactions

• Do Now: What class

of compounds does this

belong to?

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Esters • Contain R-COO-R’

• Formed from an alcohol and organic acid

– Have strong fragrances (found in fruits and perfumes)

– Names end in -oate

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Amines

• When a H in ammonia (NH3) is replaced with a carbon chain

– Name ends in -amine

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Amino Acid

• Have carboxylic (COOH) group and amine group

– Building blocks of proteins

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Amides

• Combination of 2 amino acids

• Held together by peptide bonds

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• If all else fails look

at Table R

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Combustion

• Hydrocarbon + oxygen CO2 + H2O

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Substitution • Replacing one or more Hydrogen atom in an

alkane with another atom or group

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Addition

• Adding one or more atom at a double or triple bond

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Esterification

• Organic Acid + Alcohol Ester + H2O

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Saponification

• Ester + Base Soap + Glycerol

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Fermentation

• Sugar Alcohol + CO2

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Polymerization

• Polymers = organic compounds made up of chains or smaller units

– Ex. Nylon, rayon, polyethylene, proteins, starches

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Addition Polymerization

• Joining of monomers of unsaturated compounds

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Condensation Polymerization

• Bonding of monomers by removing water

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• Chemistry

• Organic Chemistry

• Obj: SWBAT review concepts of Organic Chemistry through practice problems and offering explanations backed by their knowledge.

• Do Now: Take out homework from last night to be checked.

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• What careers did you learn about today?

• Which did you find most interesting? Why?

• Did any change your mind about your future?

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• Go to codeacademy and work on HTML and CSS

• By the end of the class, you should be at least 30% done with the course. If not, please ask for help if needed.

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• Chemistry

• Organic Chemistry

• Obj: SWBAT review concepts of Organic Chemistry through practice problems and offering explanations backed by their knowledge.

• Do Now: What are the reactants and products of saponification?

• Get worksheet

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• Chemistry

• Organic Chemistry

• Obj: SWBAT review concepts of Organic Chemistry through practice problems and offering explanations backed by their knowledge.

• Do Now: What are the reactants and products of esterification?

• Homework: STUDY!!!

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Test Instructions

• Get Test (doesn’t matter which version), Zipgrade, and Reference Tables from Desk

• START ON NEW SIDE OF ZIPGRADE!!!! – PUT YOUR NAME ON EVERYTHING AND YOUR ID # ON

ZIPGRADE (DON’T FORGET YOUR VERSION)

• START AT #1 • Answer extended response on test itself • If extended response is in the middle of the test,

skip it on zipgrade. Keep the numbering the same.