chemistry notes (energy from chemicals)

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Energy from Chemicals (aka Energy Changes) Enthalpy Change o Exothermic H = negative Energy is given out, making surrounding hotter Examples Combustion Dissolving of NaOH Most organic activities (respiration) Bond forming o Endothermic H = positive Energy is taken in, making surrounding cooler Example Photosynthesis Dissolving of NH 4 Cl Thermal decomposition Bond breaking o Overall Overall enthalpy change depends on whether energy taken in by bond breaking is greater/ lesser than energy given out by bond forming Not the number of bonds formed/ broken Energy diagrams o Energy level diagram Only shows enthalpy change o Energy profile diagram Shows enthalpy change + activation energy Hydrogen fuel cell o Obtained from electrolysis of water/ cracking of hydrocarbons (crude oil) o Reacts with oxygen to form water and generate electricity Cathode : O 2 (g) + 2 H 2 O (l) + 4 e - 4 OH - (aq) Anode : 2 H 2 (g) + 4 OH - (aq) 4 H 2 O (l) + 4 e - Nickolas Teo

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Chemistry notes on Energy From Chemicals aka Energy Changes

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Page 1: Chemistry Notes (Energy From Chemicals)

Energy from Chemicals (aka Energy Changes) Enthalpy Change

o Exothermic H = negative Energy is given out, making surrounding hotter Examples

Combustion Dissolving of NaOH Most organic activities (respiration) Bond forming

o Endothermic H = positive Energy is taken in, making surrounding cooler Example

Photosynthesis Dissolving of NH4Cl Thermal decomposition Bond breaking

o Overall Overall enthalpy change depends on whether energy taken in by bond breaking

is greater/ lesser than energy given out by bond forming Not the number of bonds formed/ broken

Energy diagramso Energy level diagram

Only shows enthalpy changeo Energy profile diagram

Shows enthalpy change + activation energy Hydrogen fuel cell

o Obtained from electrolysis of water/ cracking of hydrocarbons (crude oil)o Reacts with oxygen to form water and generate electricity

Cathode : O2 (g) + 2 H2O (l) + 4 e- 4 OH- (aq) Anode : 2 H2 (g) + 4 OH- (aq) 4 H2O (l) + 4 e-

Overall : O2 (g) + 2 H2 (g) 2 H2O (l)

Nickolas Teo