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Chapter 8 Solutions
Section 1: Solutions and Other MixturesSection 1: Solutions and Other MixturesSection 1: Solutions and Other MixturesSection 1: Solutions and Other Mixtures
• What is a heterogeneous mixture?
• What is a homogeneous mixture?
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•A heterogeneous mixture does not
have a fixed composition.
–Every spoonful will have a different
amount of each component
�Ex) fruit salad, dirt, granite
Heterogeneous MixturesHeterogeneous MixturesHeterogeneous MixturesHeterogeneous Mixtures
1) Suspensions
• A suspension has particles that settle out when the mixture is allowed to stand.
– Ex) orange juice with pulp
Types of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous Mixtures
• Particles can be filtered out with a paper filter.
• Particles can be evenly dispersed throughout a
liquid or gas.
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A mixture in which the particles are
dispersed throughout but are not
heavy enough to settle out.
Types of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous Mixtures
2) Colloids
– Ex) latex paint,
gelatin, egg whites,
blood plasma,
whipped cream,
marshmallows, fog.
• A colloid in which liquids that usually do not mix are spread throughout each other.
Types of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous MixturesTypes of Heterogeneous Mixtures
3) Emulsion
Ex: Mayonnaise• Egg yolk, oil and vinegar
Not uniformCoated
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•Mixture looks uniform even because
the components are too small to be
seen.
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
• Example: Kool-Aid, tea,
• A solution is a homogeneous mixture throughout
which two or more substances are uniformly
dissolved.
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
Solution
Solute - substance being
dissolved
Solvent - present in greater
amount
Ex: salt
Ex: water
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•Two or more
liquids that blend
together to form a
solution.
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
Miscible
•Liquids that do
NOT blend or
mix to form
solutions
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
Immiscible
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Solutions are not always liquid!– Amalgam= mercury dissolved in solid silver. Used in tooth fillings
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
• Solids to solids.
• 2 or more metals.
Homogeneous MixturesHomogeneous MixturesHomogeneous MixturesHomogeneous Mixtures
Alloys
Example: Brass is an alloy of
copper and zinc
Example: Bronze is n alloy
of tin and copper
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• Why is water called universal
solvent?
• Why do substances dissolve?
Section 2: How Substances Dissolve
• Water is found in almost everything.
–2/3 of Earth’s surface is water.
Water: A Common SolventWater: A Common SolventWater: A Common SolventWater: A Common Solvent
The “Universal Solvent”
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• The structure of water helps it dissolve charged particles.
Water: A Common SolventWater: A Common SolventWater: A Common SolventWater: A Common Solvent
Water is a polarmolecule.
•The oxygen atom attracts shared electrons more strongly than the hydrogen atoms in a water molecule.
“Like dissolves like”
Polar -Polar moleculesEx: methanol and water.
Water: A Common SolventWater: A Common SolventWater: A Common SolventWater: A Common Solvent
Polar and nonpolar substances do not mix.
•Oil is nonpolar
•do not have separate positive and
negative areas
•Water is polar
•has separate positive and negative
areas.
Non-polar -non-polar Ex: gasoline and oil.
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What makes solutes
dissolve faster?
• Larger surface area
• small pieces dissolves faster
than the same substance in big
pieces
• Stirring or shaking
• Heat
• more collisions between
particles
Water: A Common SolventWater: A Common SolventWater: A Common SolventWater: A Common Solvent
Section 3: Solubillity and
Concentration
• What is solubility?
• What happens when you add more solute to a saturated solution?
• How do you describe how much of a solute is in a solution?
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• If you continue adding sugar to lemonade, eventually the point is reached when no more sugar dissolves and the excess granules sink to the bottom of the glass.
How much can dissolve?
•Solubility : is the
maximum amount of a solute that can be dissolved in a given amount of solvent at a given temperature.
Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
Solubility varies with temperature
Soluble – anything that dissolves in another substance. Insoluble – anything that does not dissolve in another substance.
Insoluble Soluble
Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
Ex: Salt is soluble in water.
Ex: Oil is insoluble in water.
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Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
� Unsaturated� more solute can be dissolved in the
solvent� Saturated
� no more solute can be dissolved in the solvent at the current temperature
� Supersaturated� the temperature of the solution is
raised so more solute can be dissolved. When the temperature drops, the solution holds more solute than normally capable.
• Concentration: the quantity of solute dissolved
in a given quantity of solution.
– different concentrations, depending on how much
solute and solvent are present.
Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
Dilute – weak solution “less” solute present
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SATURATED SOLUTION
no more solute dissolves
UNSATURATED SOLUTIONmore solute
dissolves
SUPERSATURATED SOLUTION
becomes unstable, crystals form
concentration
Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
• Temperature and pressure affect the
solubility of gases.
Solubility in WaterSolubility in WaterSolubility in WaterSolubility in Water
When the pressure is released, the carbon
dioxide bubbles out.
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Chapter 9 Acids, Bases, and Salts
• What are the properties of acids?
• What are the properties of bases?
• How is pH related to the concentration of
hydronium ions and hydroxide ions in
solution?
Section 1: Acids, Bases, and pH
Acid and Base Clip
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Acids are substances which release
hydrogen ions (H+) when added to water.
A hydrogen ion (H+) combines with a
water molecule (H2O) to produce a
hydronium ion (H3O+)
H+ + H2O � H3O+
The more hydronium ions that are
produced, the stronger the acid.
AcidsAcidsAcidsAcids
Properties of Acids
• Sour taste.
• pH below 7
• Changes litmus paper from blue to red.
• Very corrosive to metals (meaning that they react with metals producing hydrogen gas)
• Acids react with bases to produce salts and water
AcidsAcidsAcidsAcids
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• What is a base?
– Any compound that increases the number of hydroxide ions (OH-)when dissolved in water.
Therefore, most bases have hydroxide in the name or formula.
BasesBasesBasesBases
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• Changes litmus paper from red to blue.
• Very corrosive
• Bases react with acids to produce salts and water
Properties of Bases
• Bitter taste.
• Feels slippery.
• pH above 7.
BasesBasesBasesBases
Why do bases feel slippery?
• Bases react with oils and fats on the skin.
Getting bases and bleaches on your
fingers literally turns the fat in your skin,
into soap, hence the slippery.
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• A substance that conducts electricity when
dissolved in water is an electrolyte.
• Strong acids are strong electrolytes.
• Strong bases are also strong electrolytes.
Ions that are created by Ionization and allow the conduction of electricity!
ElectrolyteElectrolyteElectrolyteElectrolyte
pH reflects how much of an
acid or a base a substance is.
pH ScalepH ScalepH ScalepH Scale
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1 2 3 4 5 6 7 8 9 10 11 12 13 14
Neutral
Acid Alkali
A pH of 7 is completely neutral
neither an acid nor a base.
A pH less than 7 is an acid. A pH greater than 7 is a base.
pH ScalepH ScalepH ScalepH Scale
• Ranges from 0 to 14
• 7 is neutral
• Strongest acid is HCl (pH=0)
• Strongest base is NaOH (Drano) (pH=14)
pH ScalepH ScalepH ScalepH Scale
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• The strength of an acid and base depends on the distance it is away from 7.
–The closer to 0 and closer to 14 are the strongest.
pH ScalepH ScalepH ScalepH Scale
Determining pH• The pH of a solution indicates its
concentration of hydronium ions (H3O+)
or the concentration of hydroxide ions (OH-).– The conc. of the two ions are related.
• If one increases, the other has decreased.
OH-H3O+
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More H30+ More OH-
Acids Bases
Acids are high in Hydrogen ion concentration
Bases are high in Hydroxide ion concentration
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Molarity
• (M) is the number of moles of substance per liter of solution.
The hydronium ion [H3O+]
concentration of apple juice is
0.001 mol/L or 1x10-3 M
pH of apple juice: ____, 3
The pH is the negative of the power of 10.
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Neutralization
� Antacids relieve indigestion, usually caused by excess stomach acid.
� Antacid (a weak base) reacts with the strong acid in the stomach to produce a weaker acid, and thus the person will feel better.
AcidAcidAcidAcid----Base ReactionsBase ReactionsBase ReactionsBase Reactions
• A neutralization reaction is the reaction between an acid and a base.
A strong acid can neutralize a strong base.A weak acid can neutralize a weak base.
Acid + Base = Salt• Acid reacts with a base, hydronium ions
react with hydroxide ions to form water and a salt.
ACID + BASE ���� SALT + WATER
Uses: cleaning, de-icing, ceramic glazes,
water softeners, fire extinguishers…
–HCl + NaOH = H2O + NaCl
• Made: by neutralization reactions
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Section 3: Acids, Bases, and Salts
in the Home
ACIDICStomach AcidLemon Juice
GrapesTomatoesBananas
Milk
BASICEggs
Baking SodaSoap
AmmoniaBleach
Oven Cleaner
NEUTRALPure Water
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• Concentrated sulphuric acid is extremely dangerous. It is found in car batteries.
Lemon juice contains citric acid and vinegar contains acetic acid.
Commercial descaling solutions contain strong and corrosive acids to remove
deposits of limescale.
Household AcidsHousehold AcidsHousehold AcidsHousehold Acids
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What Are Some Names of Acids?
� Acetic acid is found in vinegar
� Ascorbic acid is found in citrus fruits
� Hydrochloric acid is found in your stomach
� Phosphoric acid is found in fertilizers and the soft drinks you drink
� Nitric acid is used in some explosives like TNT
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Household BasesHousehold BasesHousehold BasesHousehold Bases
What Are Some Names of Bases?
• Ammonia (NH 3) is often found in cleaning products
• Potassium hydroxide (KOH) has many uses in industry, and can be a precursor to making soaps
• Sodium bicarbonate (NaHCO3) is found in baking soda
• Calcium carbonate (CaCO3) is found in antacids
• Sodium hydroxide (NaOH) is found in lye
KOH in pure form
Antacids neutralize stomach acids
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Acids Bases
Battery AcidStomach AcidLemon JuiceOrange Juice
Acid RainBlack Coffee
VinegarUrineSaliva
Sea WaterBaking SodaDrain CleanerOven Cleaner
AmmoniaSoap
Bleach
Hydrangeas are blue when grown in acidic soil and pink when grown in basic (alkaline soil)