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    Lecture 8:

    AEROBIC (BIOLOGICAL) PROCESS

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    INTRODUCTION

    Principal application of biological processes

    removal of biodegradable dissolved and colloidalorganic matter

    nitrification

    denitrification phosphorus removal

    waste stabilisation

    The cheapest treatment process

    Classified into two (based on growth of micoorganisms) Suspended growth activated sludge, oxidation ditch,aerated lagoon, sequencing batch reactor (SBR)

    Fixed film growth - trickling filter, rotating biologicalcontactor

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    MICROBIAL PROCESS DESCRIPTION

    Oxidation and synthesis

    (bacteria)

    COHNS + O2 + nutrientsp p p

    CO2 + NH3 + C5H7NO2 + otherend products

    (Organic) (cells)

    Endogenous respirationC5H7NO2 + 5O2 p p p 5CO2 + 2H2O + NH3 + energy

    (bacteria)

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    FACTORS AFFECTING AEROBIC

    PROCESS

    Dissolved oxygen (DO) > 0.5 mg/L (2 mg/L)

    DO > 3.0 mg/L for nitrification process

    Temperature affects growth rate and oxygen transfer pH between 4.0 to 9.5; optimum at 6.5 7.5

    Nutrients BOD5 : N : P = 100 : 5 : 1

    Free from toxic materials

    Mixing (turbulence, flat propeller, blades, rpm, etc.) Time (sufficient for adsorption, permeation, oxidation,

    synthesis)

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    ACTIVATED SLUDGE

    Suspended growth system

    Wastewater stabilised biologically under aerobic conditions

    Consists of two main reactors i.e. aeration tank and clarifier

    Aerobic environment created in aeration tank by mechanicalaeration or diffused air

    Biomass produced separated from liquid effluent in clarifier

    Portion of sludge is recycled into aeration tank

    Three types

    Completely mixed without sludge recycle

    Completely mixed with sludge recycle Plug-flow with sludge recycle

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    COMMON VARIATIONS OF

    ACTIVATED SLUDGE PROCESS

    Step aeration

    Tapered aeration

    Contact stabilization

    Pure-oxygen activated sludge

    Oxidation ditch

    High rate

    Extended aeration

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    Design Activated Sludge

    Description Unit Design Criteria

    Minimum number - 2

    F/M ratio kg BOD/kg

    MLSS.d

    0.25 0.50

    HRT h 6 16

    Oxygen requirements kg O2/kg BOD rem 1.5

    MLSS mg/L 1500 3000

    DO in tank mg/L 1.0

    Sludge yield, Y kg MLSS/kg BOD 0.8 1.0

    Decay coefficient, kd d-1 0.03 0.07

    Sludge age, c d 5 10

    Organic loading kg/m3/d 0.3 0.7

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    DESIGN AND OPERATIONAL

    PARAMETERS

    Types of A/S

    tcday

    F/M

    kg BOD5/kg MLSS

    VLkg BOD5 /m

    3 t

    hr

    kg O2/kg BOD

    MLSS

    mg/L

    Completelymixed

    4-15 0.2-0.4 0.8-2.0 3-5 0.7-1.0 3000-6000

    Extended

    Aeration

    20-30 0.5-0.15 0.16-0.40 18-24 1.2-2.0 3000-6000

    R = )P(42.1f

    10S)-Q(Sx

    -3

    o

    v

    f= conversion factorfor converting BOD5 to BODu (~0.68)

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    ACTIVATED SLUDGE

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    MASS BALANCE ANALYSIS

    Aeration Tank

    Q Q + QR

    X

    Qe

    Xe

    QR

    XRQw

    Accumulation = inflow

    outflow

    0 = X (Q+QR) Xe(Qe) XR(QR) XR(Qw)

    XR

    Aeration Tank

    Q Q + QR

    X

    Qe

    Xe

    QR

    XRQwXR

    Accumulation = inflow

    outflow

    0 = XR(QR) X(Q+ QR)

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    FORMULATION / EQUATIONS

    dcd

    t

    g

    obsk

    Y

    U

    kYU

    dtdS

    dtdXY

    U!

    !!

    1/

    /yield,growthObserved

    wwee QSSQSS

    VMLSSageSludge

    vv

    v

    !Q

    Vperiod,Aeration !U

    X

    )S-S(

    VX

    )S-Q(SUn,utilizatiosubstrateSpecific eoeo

    U!!

    X

    S

    VX

    QSoo

    U!!

    M

    F

    %100Q

    QratesludgeReturn

    in

    rv!

    o

    wastewaste

    QS

    XQProductionSludge

    v

    !

    dckU!

    1

    )S-YQ(SPsludge,in wastesolidsVolatile eox

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    EXAMPLE 1

    A conventional activated-sludge plant without primary clarification operates under the

    following conditions:

    Design flow = 2.14 MGD

    Influent BOD = 185 mg/LSS = 212 mg/L

    Aeration basins: 4 unit, 40 x 40 ft2 x 15.5 ft deep

    MLSS = 2600 mg/L

    Recirculation flow = 1 MGD

    Waste Sludge Quantity = 39,000 GPDSS in waste sludge = 8600 mg/L

    Effluent BOD = 15 mg/L, SS = 15 mg/L

    Calculate the: aeration period, BOD loading, F/M ratio, SS and BOD removal efficiencies,

    Sludge age and Return activated-sludge age

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    SOLUTION

    Aeration basin volume = 4 (40)2 x 15.5 x (7.481/106) = 0.74 mil gallon

    Aeration basin, dt= 0.74 mil gallon / 2.14 MGD x 24 hr = 8.3 hr

    BOD loading = [(2.14 MGD x 185 mg/L x 8.34) / (4 x 402 x 15.5 /1000 ft3)]

    = 33.3 lb/day / 1000 ft3

    F / M = [(2.14 MGD x 185 mg/L x 8.34) / (0.74 mil gallon x 2600 mg/L x 8.34)]

    = 0.21 lb BOD/day / lb MLSS.

    Suspended Solid removal = [(212 15) / (212) x 100%] = 93%

    BOD removal efficiency = [(185 15) / (185) x 100%] = 92%

    Suspended solids in the effluent = 2.101 MGD x 15 mg/L x 8.34 = 262 lb/day

    Suspended solids in waste activated sludge = 0.039 MGD x 8600 mg/L x 8.34 = 2797 lb/day

    Sludge age = [(0.74 mil gallon x 2600 mg/L x 8.34) / (2797+ 262 lb/day)]

    = 5.2 days

    Return sludge rate = [(1.0) / (2.14) x 100%] = 48%

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    Activated Sludge Treatment

    Aerobic Granulation

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    CONVENTIONAL NUTRIENT REMOVAL

    ACTIVATED SLUDGE SYSTEM

    InfluentPre-treatment Equalization

    tank

    Anaerobic tankDenitrification

    Aerobictank

    Effluent

    SludgeDigester

    CH4 SludgeDewatering

    Sludge

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    AEROBIC GRANULAR SLUDGE

    Influent

    Pre-treatment

    Selector

    Anaerobictank

    Denitrification

    Aerobic tank

    Effluent

    SludgeDigester

    CH4SludgeDewatering

    Sludge

    SBR

    Effluent

    Aerobic GranularSludge Reactor

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    Activated Sludge Treatment

    Extended Aeration

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    Common Variations of Activated Sludge Process

    EXTENDED AERATION

    Long detention time and low F/M ratio in aerator tomaintain culture in endogenous phase

    Secondary

    clarifier

    Influent

    Excesssludge

    Effluent

    Return sludge (omitted in some

    system)

    Reactor

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    EXTENDED AERATION

    Activated sludge processes with long HRT (in theorder of 24 hrs) and long sludge age

    MLSS high, so insensitive to shock loads

    Designed either plug flow or completely mixed Operates at low BOD loading and in endogenous

    phase, thus growth rate and sludge yield are low

    Normally used to handle domestic waste from smallcommunities accept variable loading better thanCMAS

    Disadvantage/Challenge formation of filamentousmicroorganisms species which difficult to settle

    High oxygen requirement

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    EXTENDED AERATION SLUDGE

    Description Unit Design

    Criteria

    Minimum number of aeration - 2

    F/M kg BOD/kg MLSS.d 0.05 0.1

    HRT h 18 24

    Oxygen requirement kg O2/kg BOD rem. 2

    MLSS mg/L 3000 5000

    DO level in tank mg/L 2Sludge yield, Y kg sludge prod./ kg

    BOD rem

    0.4 0.6

    Decay coefficient, kd d-1 0.06

    Sludge age, c d 15 35

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    EXAMPLE 1

    A small extended aeration plant without sludge wasting

    facilities is loaded at a rate of 170 g/m3.d with an aerationperiod of 24 hr. The measured suspended solids buildup ratein the aeration tank is 40 mg/L/d. What percentage of theraw influent BOD is converted and retained as MLSS? If theMLSS concentration is allowed to increase from 2000 to 6000

    mg/L before wasting solids, how long would this builduptake?

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    SOLUTIONS

    Because the aeration period is 24 hr,

    = 170 mg/L. d

    = 23.5%

    3

    3

    m

    .dg/m170

    tankofliter

    load/dayBODy!

    %100mg/L.d170

    mg/L.d40

    appliedBOD

    buildupMLSSv!

    days100mg/L.d40

    mg/L2000-6000timeBuildup !!

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    EXAMPLE 2

    Two activated sludge aeration tanks at Taman

    University, Skudai are operated in series. Each tank

    has the following dimensions: 7 m wide x 30 m long

    x 4.3 m effective liquid depth. The plant operating

    parameters are as follows:

    Flow = 0.0796 m3/s, MLVSS = 1500 mg/L, MLSS =1.40 MLVSS, Soluble BOD5 after primary settling =

    130 mg/L.

    Determine the aeration period and F/M ratio

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    = V/Q = (7x30x4.3)/(0.0796) = 11,344 s

    = 3.15 h x 2 tanks = 6.3 hrs

    F/M = QSo/VX = ??

    [Answer: aeration period = 6.3 h; F/M =

    0.33 mg/mg. day]

    SOLUTIONS

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    Activated Sludge Treatment

    SEQUENCING BATCH REACTOR (SBR)

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    SBR PROCESS

    Batch process which takes place in ONE reactor

    Consists of FIVE basic operating mode

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    DESIGN OF SBR

    Description Unit Design

    Criteria

    Minimum number of reactor - 1F/M kg BOD/kg MLSS.d 0.05 0.2

    Oxygen requirement kg O2/kg BOD rem.

    DO level in tank mg/L ~6.5

    Sludge yield, Y kg sludge prod./ kg

    BOD rem

    0.75 1.10

    Decay coefficient, kd d-1 0.06

    Sludge age, c d 15 35

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    SETTLE

    3 min.

    1 min.

    IDLE

    60 min.

    FILL

    influent

    5 min.DRAIN

    effluent

    121 min.

    REACT

    air

    Cycle

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    FORMULATION / EQUATIONS

    ! suo rQS-QSdt

    dS

    Batch Model Reactor with Completely Stirred Tank Reactor

    S)Y(K

    SX-rwhere

    s

    m

    su

    !

    Q

    Influent = Effluent + Production Wasted (or Consumed)

    Example of Substrate

    SQ)SQ-(Q)(

    ww !

    SKYSXQSs

    mo

    Q

    Substrate in influent Substrate consumed = Substrate in effluent Substrate in

    Wasted

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    BENEFITS OF SBR

    Smaller size than CMFR

    Be able to absorb shock load better than

    CMFR and PFR allow HRT to beprolonged until desired quality is reached

    Better sedimentation tank

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    Activated Sludge TreatmentMembrane Bioreactor (MBR)

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    MEMBRANE BIOREACTOR (MBR)

    A new version of activated sludge system

    Utilises microporous membranes for solid/liquid separation in lieu

    of secondary clarifiers

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    MBR Design Consideration

    Equalization

    Sufficient tank with in-line or off-line storage

    Preliminary Treatment

    Removal of grits and materials (screen < 2mm)

    Solid Retention Time (SRT) and HRT

    SRTs as 5 20 days, not strongly related to biopolymer fouling

    HRT may consider in short, 4 6 h

    Mixed Liquor Suspended Solids (MLSS)

    Immersed MBR of MLSS from 8,000 18,000 mg/L

    Dissolved Oxygen (DO)

    Anoxic = 0 0.5 mg/L;Aerobic = 1.5 3 mg/L; Membrane = 2 6 mg/L

    Flux rates

    Consider in between 25 46 L/m2. h

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    ADVANTAGES OFMBR

    Secondary clarifiers and tertiary filtration processes are eliminated,thereby reducing plant size.

    Quality of solids separation is not dependent on the mixed liquorsuspended solids concentration or characteristics. Since elevatedmixed liquor concentrations are possible, the aeration basin volume

    can be reduced, further reducing the plant size. Can be designed with long sludge age, hence low sludge production.

    Produces a MF/UF quality effluent suitable for reuse applications oras a high quality feed water source for Reverse Osmosis treatment.Indicative output quality of MF/UF systems include SS < 1mg/L,turbidity

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    EXAMPLE OFMBR APPLICATION

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    Cauley Creek, GA:MBR

    Constructed in 2 x 2.5 MGD phases (total 5 MGD)

    Plant is optimized for meeting discharge limits of0.13 mg/L

    total P and 0.5 mg/L ammonia

    Staff indicated not much the plant can do to further reduce

    energy consumption without potentially violating systemwarranties or permit

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    Pooler, GA: MBR

    2.5 mgd MBR, operated

    24 hours, staffed 8hr/day

    The plant has dischargelimits for ammonia, but

    not for phosphorus

    Cut back on the aeration

    to only night times Turned off UV to save

    energy

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    Membrane Fouling

    TMP

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    BIOLOGICAL WASTE TREATMENT

    APPLICATION

    Treatment

    Method

    Mode of

    Operation

    Degree of

    Treatment

    Land

    Requirements

    Equipment Remarks

    Activated

    Sludge

    Completely

    mixed or plug

    flow, sludge

    recycle

    > 90% removal

    of organics

    Earth or

    concrete basins

    (3.66 6.10 m

    deep), (0.561

    2.262 m3/m3.day), (5.52

    34.4 m2/ 103

    m3.day)

    Diffused or

    mechanical

    aerators,

    clarifiers for

    sludgeseparation and

    recycle.

    Excess sludge

    dewatered and

    disposed of

    Trickling Filter Continuous

    application;

    may employeffluent recycle

    Intermediate or

    high,

    depending onload

    5.52 34.4

    m2/103 m3. day

    Plastic

    packing, 6.10

    12.19 m);

    Pre-treatment

    before publicity

    ownedtreatment

    works (POTW)

    or activated

    sludge plant

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    BIOLOGICAL WASTE TREATMENT

    APPLICATION

    Treatment

    Method

    Mode of

    Operation

    Degree of

    Treatment

    Land

    Requirements

    Equipment Remarks

    RBC Multistage

    continuous

    Intermediate

    or high

    Plastic disk Solids

    separationrequired

    Anaerobic Complete mix

    with recycle;

    upflow or

    downflow filter;

    fluidized bed,upflow sludge

    blanket

    Intermediate Gas collection

    required; pre-

    treatment

    before POTW

    or activatedsludge plant

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    Choose: Aerobic or AnaerobicAerobic process Anaerobic process

    COD < 3000 mg/l

    BOD 3000 mg/l

    BOD>2000 mg/l

    Slow biodegradable matters

    High-strength waste

    Pre-treatment process

    Biodegradation 2 types:

    Mineralization

    Organic compounds are converted byliving organisms to minerals (non-

    organic) end products MAINLY

    AEROBIC PROCESS

    Biotransformation

    Parent organic compounds are notcompletely mineralized, a portion is

    converted into other organics

    ANAEROBIC PROCESSES

    SEME

    STE

    RIIS

    ESS

    ION CHAPTER 8

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    CONVENTIONAL ACTIVATED

    SLUDGE (CAS)

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    COMPLETE ACTIVATED SLUDGE

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    Common Variations of Activated Sludge Process

    OXIDATION DITCH

    Similar to extended aeration, except the aeration is done bybrush-type aerators, thus reducing electricity

    Effluent

    Influent

    Return sludge

    Brush-type aerators

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    OXIDATION DITCH (OD)

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    AERATED LAGOON SYSTEM

    System Advantages Disadvantages

    Aerated Lagoon Lower land

    requirement

    Equipment

    Relatively simple

    construction,operation and

    maintenance

    Slight increase in the

    sophisticated level.Need a continuous of

    sludge removal (2 5

    years)

    Large efficiency in

    BOD removal

    High energy

    requirementsLow possibility of odor

    problem

    Fast filling of the

    sedimentation lagoon

    with sludge (2 5

    years

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    HOMEWORK 1

    What is the purpose of the activated sludge process in

    treating wastewater?

    What is the functioning of Returned Activated Sludge

    (RAS) in aeration tank? What happens to the air requirement in the aeration

    tank when the strength (BOD) of the incoming

    wastewater increases?

    With an aid of diagram shows the following symbol inthe conventional wastewater treatment plant

    (completely mixed reactor). The diagram must consist

    of primary treatment, biological treatment and

    secondary clarifier.

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    HOMEWORK 2

    A conventional activated sludge plant without primary clarification operates underthe following conditions:

    Design flow = 8100 m3/day

    Influent BOD = 185 mg/L

    SS = 212 mg/L

    Aeration basins: 4 units, 12 m square x 4.5 m deep

    MLSS = 2600 mg/L

    Recirculation flow = 3800 m3/d

    Waste sludge quantity = 150 m3/d

    SS in waste sludge = 8600 mg/L

    Effluent BOD = 15 mg/L, Effluent SS = 15 mg/L

    Calculate the following: aeration period

    BOD loading

    F/M ratio

    SS removal and BOD removal

    Sludge age (SRT)

    Return activated sludge age