chapter 4/25
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Chapter 4/25. Atomic Structure Nuclear Chemistry. A Long, Long Time Ago…. Greek Philosophers- 4 elements are Earth, Water, Fire, and Air Aristotle- first recorded atomic thoughts Matter is continuous (no atoms) Democritus (400 B.C.) - first recorded atomic theory - PowerPoint PPT PresentationTRANSCRIPT
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Chapter 4/25 Chapter 4/25
Atomic StructureAtomic Structure
Nuclear ChemistryNuclear Chemistry
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A Long, Long Time A Long, Long Time Ago…Ago… Greek Philosophers- 4 elements Greek Philosophers- 4 elements
are Earth, Water, Fire, and Airare Earth, Water, Fire, and Air Aristotle- first recorded atomic Aristotle- first recorded atomic
thoughtsthoughts Matter is continuous (no atoms)Matter is continuous (no atoms)
Democritus (400 B.C.) - first Democritus (400 B.C.) - first recorded atomic theoryrecorded atomic theory
Atoms are smallest part of matter, each Atoms are smallest part of matter, each type of matter has different atomstype of matter has different atoms
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Aristotle and Aristotle and DemocritusDemocritus
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A Long Time Ago…A Long Time Ago…
Antoine Lavoisier (1782)Antoine Lavoisier (1782)– Used experiments in closed containers to Used experiments in closed containers to
develop the LCMdevelop the LCM Joseph Proust (1799)Joseph Proust (1799)
– Analyzed water to develop the Law of Analyzed water to develop the Law of Definite ProportionsDefinite Proportions
John Dalton (1803)John Dalton (1803)– Compiled past research to develop the Compiled past research to develop the
first useful atomic theoryfirst useful atomic theory
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Lavoisier and ProustLavoisier and Proust
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John DaltonJohn Dalton
Dalton’s theory Dalton’s theory had 4 major tenetshad 4 major tenets
1.1. All matter is All matter is composed of atomscomposed of atoms
2.2. Atoms are Atoms are indivisibleindivisible
3.3. Atoms of 1 element Atoms of 1 element are alike, but are alike, but different from those different from those of other elementsof other elements
4.4. Atoms combine in Atoms combine in small, whole small, whole number ratios to number ratios to form compoundsform compounds
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A ReminderA Reminder
Observation, Observation, Observation, Observation, ObservationObservation
ResearchResearch HypothesisHypothesis Experiment, Revise hypothesis lots Experiment, Revise hypothesis lots
of timesof times Results match….may become a Results match….may become a
theorytheory
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A Little While Ago…A Little While Ago…
1897- J.J. 1897- J.J. Thomson Thomson discovers the discovers the electron using a electron using a cathode ray tubecathode ray tube
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Cathode Ray Tube Cathode Ray Tube ExperimentExperimenthttp://www.aip.org/history/electron/jjappara.htm
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The Nucleus Exists!The Nucleus Exists!
1911- Ernest 1911- Ernest Rutherford uses Rutherford uses the gold foil the gold foil experiment to experiment to “discover” the “discover” the nucleusnucleus
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The Gold Foil The Gold Foil ExperimentExperiment
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Results of Gold Foil Results of Gold Foil Experiment…Experiment… http://online.cctt.org/physicslab/content/Phy1
/lessonnotes/atomic/atomicmodelsandspectra.asp
http://micro.magnet.fsu.edu/electromag/java/rutherford/
Over 98% of the particles went straight Over 98% of the particles went straight throughthrough
About 2% of the particles went through About 2% of the particles went through but were deflected by large anglesbut were deflected by large angles
About 0.01% of the particles bounced About 0.01% of the particles bounced off the gold foiloff the gold foil
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Rutherford’s Rutherford’s ConclusionConclusion
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Rutherford's Nuclear ModelRutherford's Nuclear Model
1. The atom contains a tiny dense 1. The atom contains a tiny dense center called the nucleuscenter called the nucleus – the volume is about 1/10 trillionth the the volume is about 1/10 trillionth the
volume of the atom volume of the atom 2. The nucleus is essentially the 2. The nucleus is essentially the
entire mass of the atomentire mass of the atom 3. The nucleus is positively charged3. The nucleus is positively charged
– the amount of positive charge of the the amount of positive charge of the nucleus balances the negative charge of the nucleus balances the negative charge of the electrons electrons
4. The electrons move around in the 4. The electrons move around in the empty space of the atom empty space of the atom surrounding the nucleussurrounding the nucleus
Coworker James Chadwick later Coworker James Chadwick later adds neutronsadds neutrons
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Understanding Understanding Periodic BlocksPeriodic Blocks
19 19
KK
39.098339.0983
Atomic NumberAtomic Number– # of protons# of protons
Element SymbolElement Symbol
Mass NumberMass Number– Protons + Protons +
NeutronsNeutrons
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Can 20.0983 Neutrons Can 20.0983 Neutrons Exist???Exist??? No, 39.0983 is an average mass No, 39.0983 is an average mass
of all natural K atomsof all natural K atoms– All K atoms MUST have 19 protonsAll K atoms MUST have 19 protons– Some have 20 neutrons, some 19, Some have 20 neutrons, some 19,
some 21…some 21…– Average is 20.0983 neutronsAverage is 20.0983 neutrons– Individual isotopes are identified by Individual isotopes are identified by
the number of the number of neutronsneutrons
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Identifying Protons, Identifying Protons, Neutrons, and Neutrons, and ElectronsElectrons Chlorine-35 (element-mass number)Chlorine-35 (element-mass number) # of protons = 17# of protons = 17 # electrons = # protons# electrons = # protons # neutrons = mass number – protons# neutrons = mass number – protons
– 35-17 = 1835-17 = 18 Why no electrons in atomic mass?Why no electrons in atomic mass?
– Electron has mass 1/1837 of Proton and Electron has mass 1/1837 of Proton and NeutronNeutron
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Nuclear symbol notationNuclear symbol notation (nuclide (nuclide symbols)symbols)– Example: Example: 2727
1313Al or Al or 2727AlAl
– # protons = ______# protons = ______– # neutrons = ______# neutrons = ______– # electrons = ______# electrons = ______
Problems that ariseProblems that arise– Charges and IonsCharges and Ions: only changes the : only changes the
number of electrons!number of electrons!– Finding mass numberFinding mass number: use symbol, # p+ : use symbol, # p+
and nand noo, or periodic table IN THAT ORDER!, or periodic table IN THAT ORDER!
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Atomic Mass UnitsAtomic Mass Units
Carbon-12Carbon-12– 6 protons6 protons– 6 neutrons6 neutrons
1 amu = 1/12 mass of a C-12 1 amu = 1/12 mass of a C-12 atomatom
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Nuclear Stability- too Nuclear Stability- too many neutrons or many neutrons or protons causes protons causes instabilityinstability
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Chemical vs. Nuclear Chemical vs. Nuclear ChangeChange
Chemical ChangeChemical Change- produces new kinds of - produces new kinds of matter with new propertiesmatter with new properties– Involves breaking and forming BONDSInvolves breaking and forming BONDS– Accomplished by rearrangement of Accomplished by rearrangement of
ELECTRONSELECTRONS Nuclear ChangeNuclear Change- produces a new nucleus - produces a new nucleus
that contains less energythat contains less energy– Involves emission or capture of nuclear Involves emission or capture of nuclear
particlesparticles– Accomplished by changing PROTONS Accomplished by changing PROTONS
and NEUTRONS in nucleusand NEUTRONS in nucleus
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Nuclear DecayNuclear Decay
Nuclear ParticlesNuclear Particles– Alpha- rapidly moving He nuclei with Alpha- rapidly moving He nuclei with
a (+) chargea (+) charge– Beta – rapidly moving electrons with Beta – rapidly moving electrons with
a (-) chargea (-) charge– Gamma – rapidly moving Gamma – rapidly moving
electromagnetic radiation with no electromagnetic radiation with no mass or chargemass or charge
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HighHighMedMedLowLowActual Actual HazardHazard
Low-MedLow-MedMedMedHighHighBiological Biological HazardHazard
LowLowMedMedHighHighEnergyEnergy
Hard (2 cm Hard (2 cm lead)lead)
Medium Medium (aluminum (aluminum
foil)foil)
Easy Easy
(skin/(skin/clothes)clothes)
ShieldingShielding
0000γγ00
-1-1ee4422HeHeSymbolSymbol
GAMMA (GAMMA (γγ))BETA (BETA (ββ))ALPHA (ALPHA (αα))
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Other RadiationOther Radiation
Ionizing Radiation- has significant Ionizing Radiation- has significant energy to change atoms and energy to change atoms and molecules into ionsmolecules into ions
– Types: alpha, beta, gamma, x-raysTypes: alpha, beta, gamma, x-rays– Effects to living organisms: changes in, DNA (cell Effects to living organisms: changes in, DNA (cell
death/cancer)death/cancer)
Nonionizing radiation- does not have Nonionizing radiation- does not have significant energy to ionize atoms or significant energy to ionize atoms or molecules (types: microwaves, visible molecules (types: microwaves, visible light, radiowaves)light, radiowaves)
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Nuclear ReactionsNuclear Reactions
– Transmutation- Changing the Transmutation- Changing the nucleus of the atom to create a nucleus of the atom to create a new elementnew element
– How is a Nuclear Equation Written?How is a Nuclear Equation Written? Parent nuclide- initial nucleus that Parent nuclide- initial nucleus that
undergoes changesundergoes changes Daughter nuclide- nucleus resulting Daughter nuclide- nucleus resulting
from decay of parentfrom decay of parent
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Types of Nuclear Types of Nuclear ReactionsReactions Alpha Emission- generally occurs if Alpha Emission- generally occurs if
nucleus has too many protons and nucleus has too many protons and neutronsneutrons
Beta Emission- results from conversion Beta Emission- results from conversion of neutron to proton and occurs if of neutron to proton and occurs if nucleus has too many neutronsnucleus has too many neutrons
Positron Emission- results from Positron Emission- results from conversion of proton to neutron and conversion of proton to neutron and occurs if nucleus has too few neutronsoccurs if nucleus has too few neutrons
Gamma Emission- often accompanies Gamma Emission- often accompanies other decay processesother decay processes
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Example: Alpha DecayExample: Alpha Decay
2522529999Es Es ______ + ______ + 44
22HeHe
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Radioactive Decay Radioactive Decay Half-livesHalf-lives
Half-life is the time taken for Half-life is the time taken for half of the atoms of a radio-half of the atoms of a radio-active substance to decay.active substance to decay.
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Half-lifeHalf-life
Half-lives can Half-lives can range from a range from a millionth of a millionth of a second to second to millions of yearsmillions of years
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Radioactive DatingRadioactive Dating
Uses carbon-14 to tell age of Uses carbon-14 to tell age of fossilsfossils
C-14 is present constantly in C-14 is present constantly in atmosphereatmosphere
15.3 decays/min in living organism15.3 decays/min in living organism decays/min decreases by ½ every decays/min decreases by ½ every
5370 years an organism is dead.5370 years an organism is dead. Only useful to 60,000 yrs agoOnly useful to 60,000 yrs ago
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TracersTracers
Radioactive isotopes used to Radioactive isotopes used to track pathwaystrack pathways
Chemistry/biology- pathways of Chemistry/biology- pathways of reactions reactions
Industry and environment- path of Industry and environment- path of groundwater, durability of containersgroundwater, durability of containers
Medicine- diagnose malfunctionsMedicine- diagnose malfunctions
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Nuclear Reactions for Nuclear Reactions for EnergyEnergy
Fission- nucleus Fission- nucleus broken into 2 broken into 2 smaller nucleismaller nuclei
Fusion- smaller Fusion- smaller nuclei join to nuclei join to form a larger, form a larger, more stable more stable nucleinuclei
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Reactants and Reactants and ProductsProducts Fission- Fission- 9292
235235U fuel U fuel used in a chain used in a chain reactionreaction
– Limited resourceLimited resource– critical mass- critical mass-
minimum mass to minimum mass to sustain chain sustain chain reactionreaction
– Risk of runaway Risk of runaway chain reactionchain reaction
– Produces Produces radioactive waste radioactive waste productsproducts
– Disposal concernsDisposal concerns– Reaction: Reaction:
Fusion- Fusion- 1122H and H and 11
33H H used as fuelused as fuel
– extracted from sea extracted from sea waterwater
– not a chain reactionnot a chain reaction– No risk of runaway No risk of runaway
reaction reaction – Nonradioactive Nonradioactive
waste: helium waste: helium – Problem: Problem: needs temp needs temp
of 200 Million Kof 200 Million K– Reaction:Reaction:
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Nuclear Power- Nuclear Power- generated generated by a by a controlled controlled fissionfission chain chain reactionreaction
Control rods- absorb Control rods- absorb neutrons to slow neutrons to slow the chain reactionthe chain reaction
Made of cadmiumMade of cadmium Inserted or Inserted or
withdrawn to keep withdrawn to keep temp of reaction temp of reaction steadysteady
Moderators- slow Moderators- slow neutrons down so neutrons down so they DO hit they DO hit uranium fuel rods uranium fuel rods
Made of water, Made of water, beryllium, or beryllium, or graphitegraphite
Intended to allow Intended to allow neutrons to be neutrons to be absorbed by absorbed by uraniumuranium
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Cooling and ShieldingCooling and Shielding
Water- acts as a coolant and Water- acts as a coolant and transfers heat between reactor transfers heat between reactor and turbines that produce and turbines that produce electricityelectricity
Steel & concrete- surround core Steel & concrete- surround core and protect personnel by and protect personnel by absorbing radiationabsorbing radiation
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Nuclear MeltdownsNuclear Meltdowns
Cherynobyl (Soviet Cherynobyl (Soviet Union, 1986)Union, 1986)
– Runaway fission Runaway fission reaction from core reaction from core meltdownmeltdown
– Radiation escaped Radiation escaped to atmosphereto atmosphere
– 31 dead, estimated 31 dead, estimated 15,000 cancer 15,000 cancer deaths in next 50 deaths in next 50 yearsyears
Three Mile Island Three Mile Island (Pennsylvania, (Pennsylvania, 1979)1979)– partial meltdownpartial meltdown– contained before contained before
widespread damageswidespread damages
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