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25.1 Nuclear Radiation >
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Chapter 25Nuclear Chemistry
25.1 Nuclear Radiation
25.2 Nuclear Transformations
25.3 Fission and Fusion
25.4 Radiation in Your Life
25.1 Nuclear Radiation >
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What makes some types of radiation
more dangerous than other types?
CHEMISTRY & YOU
Lengthy or
frequent exposure
to X-rays can
damage cells in
your body.
25.1 Nuclear Radiation >
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Radioactivity
Radioactivity
How do nuclear reactions differ from
chemical reactions?
25.1 Nuclear Radiation >
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Radioactivity
In 1896, the French chemist Antoine
Becquerel made an accidental discovery.
• He was studying the ability of uranium salts
that had been exposed to sunlight to fog
photographic film plates.
25.1 Nuclear Radiation >
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Radioactivity
In 1896, the French chemist Antoine
Becquerel made an accidental discovery.
• He was studying the ability of uranium salts
that had been exposed to sunlight to fog
photographic film plates.
• During bad weather, when Becquerel could not
expose a sample to sunlight, he left the
sample on top of the photographic plate.
• When he developed the plate, he discovered
that the uranium salt still fogged the film.
25.1 Nuclear Radiation >
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Radioactivity
Two of Becquerel’s associates were Marie
and Pierre Curie.
• The Curies were able to
show that rays emitted by
uranium atoms caused the
film to fog.
• Marie Curie and her
husband Pierre shared the
1903 Nobel Prize in physics with Becquerel for
their pioneering work on radioactivity.
25.1 Nuclear Radiation >
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Radioactivity
Marie Curie used the term radioactivity to
refer to the spontaneous emission of rays
or particles from certain elements, such as
uranium.
25.1 Nuclear Radiation >
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Radioactivity
Marie Curie used the term radioactivity to
refer to the spontaneous emission of rays
or particles from certain elements, such as
uranium.
• The rays and particles emitted from a
radioactive source are called nuclear
radiation.
25.1 Nuclear Radiation >
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Radioactivity
Radioactivity, which is also called
radioactive decay, is an example of a
nuclear reaction.
• Nuclear reactions begin with unstable
isotopes, or radioisotopes.
25.1 Nuclear Radiation >
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Radioactivity
Radioactivity, which is also called
radioactive decay, is an example of a
nuclear reaction.
• Nuclear reactions begin with unstable
isotopes, or radioisotopes.
• Atoms of these isotopes become more stable
when changes occur in their nuclei.
25.1 Nuclear Radiation >
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Radioactivity
Radioactivity, which is also called
radioactive decay, is an example of a
nuclear reaction.
• Nuclear reactions begin with unstable
isotopes, or radioisotopes.
• Atoms of these isotopes become more stable
when changes occur in their nuclei.
• The changes are always accompanied by the
emission of large amounts of energy.
25.1 Nuclear Radiation >
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Radioactivity
Unlike chemical reactions, nuclear
reactions are not affected by
changes in temperature, pressure, or
the presence of catalysts. Also,
nuclear reactions of a given
radioisotope cannot be slowed
down, sped up, or stopped.
25.1 Nuclear Radiation >
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Radioactivity
Radioactive decay is a spontaneous
process that does not require an input of
energy.
25.1 Nuclear Radiation >
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Radioactivity
Radioactive decay is a spontaneous
process that does not require an input of
energy.
• If the product of a nuclear reaction is
unstable, it will decay too.
25.1 Nuclear Radiation >
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Radioactivity
Radioactive decay is a spontaneous
process that does not require an input of
energy.
• If the product of a nuclear reaction is
unstable, it will decay too.
• The process continues until unstable isotopes
of one element are changed, or transformed,
into stable isotopes of a different element.
25.1 Nuclear Radiation >
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Radioactivity
Radioactive decay is a spontaneous
process that does not require an input of
energy.
• If the product of a nuclear reaction is
unstable, it will decay too.
• The process continues until unstable isotopes
of one element are changed, or transformed,
into stable isotopes of a different element.
• These stable isotopes are not radioactive.
25.1 Nuclear Radiation >
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Why do unstable isotopes undergo
nuclear reactions?
25.1 Nuclear Radiation >
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Why do unstable isotopes undergo
nuclear reactions?
Unstable isotopes undergo nuclear reactions
so that they may be changed, or
transformed, into stable isotopes.
25.1 Nuclear Radiation >
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Types of Radiation
Types of Radiation
What are three types of nuclear
radiation?
25.1 Nuclear Radiation >
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Types of Radiation
Radiation is emitted during radioactive
decay.
Three types of nuclear radiation are
alpha radiation, beta radiation, and
gamma radiation.
25.1 Nuclear Radiation >
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Characteristics of Some Types of Radiation
Type Consists of Symbol ChargeMass
(amu)
Common
source
Penetrating
power
Alpha
radiation
Alpha particles
(helium nuclei)a, 2+ 4
Radium-
226
Low
(0.05 mm
body tissue)
Beta
radiation
Beta particles
(electrons)b, 1– 1/1837
Carbon-
14
Moderate
(4 mm body
tissue)
Gamma
radiation
High-energy
electromagnetic
radiation
g 0 0 Cobalt-60
Very high
(penetrates
body easily)
He4
2
e0
–1
Interpret Data
25.1 Nuclear Radiation >
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Types of Radiation
Alpha Radiation
Some radioactive sources emit
helium nuclei, which are also called
alpha particles.
25.1 Nuclear Radiation >
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Types of Radiation
Alpha Radiation
Some radioactive sources emit
helium nuclei, which are also called
alpha particles.
• Each alpha particle contains two
protons and two neutrons and has a
double positive charge.
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Types of Radiation
Alpha Radiation
Some radioactive sources emit
helium nuclei, which are also called
alpha particles.
• Each alpha particle contains two
protons and two neutrons and has a
double positive charge.
• An alpha particle is written He or a.42
– The electric charge is usually omitted.
25.1 Nuclear Radiation >
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Types of Radiation
Alpha Radiation
The radioisotope uranium-238 emits alpha
radiation and is transformed into another
radioisotope, thorium-234.
U238
92
Uranium-238
Th +234
90
Thorium-234
He (a emission)4
2
Alpha particle
Radioactive
decay
25.1 Nuclear Radiation >
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Types of Radiation
Alpha Radiation
When an atom loses an alpha particle, the
atomic number of the product is lowered
by two and its mass number is lowered by
four.
• In a balanced nuclear equation, the sum
of the mass numbers (superscripts) on
the right must equal the sum on the left.
• The same is true for the atomic numbers
(subscripts).
U238
92 Th +234
90 He4
2→
25.1 Nuclear Radiation >
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Types of Radiation
Alpha Radiation
Because of their large mass and charge,
alpha particles do not travel very far and
are not very penetrating.
• A sheet of paper or the surface of your skin
can stop them.
• But radioisotopes that emit alpha particles
can cause harm when ingested.
– Once inside the body, the particles don’t have to
travel far to penetrate soft tissue.
25.1 Nuclear Radiation >
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Types of Radiation
Beta Radiation
An electron resulting from the breaking apart
of a neutron in an atom is called a beta
particle.
• The neutron breaks apart into a proton, which
remains in the nucleus, and a fast-moving
electron, which is released.
n1
0
Neutron
p +1
1
Proton
e 0
–1
Electron
(beta particle)
→
25.1 Nuclear Radiation >
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Types of Radiation
Beta Radiation
The symbol for the electron has a subscript
of –1 and a superscript of 0.
• The –1 represents the charge on the electron.
• The 0 represents the extremely small mass of
the electron compared to the mass of a proton.
n1
0
Neutron
p +1
1
Proton
e 0
–1
Electron
(beta particle)
→
25.1 Nuclear Radiation >
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Types of Radiation
Beta Radiation
Carbon-14 emits a beta particle as it decays and
forms nitrogen-14.
• The nitrogen-14 atom has the
same mass number as
carbon-14, but its atomic
number has increased by 1.
• It contains an additional
proton and one fewer neutron.
C14
6
Carbon-14
(radioactive)
N +14
7
Nitrogen-14
(stable)
e (b emission)0
–1
Beta particle
→
25.1 Nuclear Radiation >
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Types of Radiation
Beta Radiation
A beta particle has less charge than an
alpha particle and much less mass than an
alpha particle.
• Thus, beta particles are more penetrating than
alpha particles.
– Beta particles can pass through paper but are
stopped by aluminum foil or thin pieces of
wood.
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Types of Radiation
Beta RadiationBecause of their opposite charges, alpha and beta
radiation can be separated by an electric field.
• Alpha particles move toward the negative plate.
• Beta particles move toward the positive plate.
• Gamma rays are not deflected.
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Types of Radiation
Gamma Radiation
A high-energy photon emitted by a radioisotope is
called a gamma ray.
• The high-energy photons are a form of
electromagnetic radiation.
• Nuclei often emit gamma rays along with alpha or beta
particles during radioactive decay.
Ra +226
88
Radium-226
Th230
90
Thorium-230
He + g4
2
Alpha
particle
Gamma
ray
→
Pa +234
91
Protactinium
-234
Th234
90
Thorium-234
e + g0
–1
Beta
particle
Gamma
ray
→
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Types of Radiation
Gamma rays have no mass and no
electrical charge.
• Emission of gamma radiation does not alter
the atomic number or mass number of an
atom.
Gamma Radiation
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Types of Radiation
Because gamma rays are extremely penetrating,
they can be very dangerous.
• Gamma rays pass easily through paper, wood, and the
human body.
• They can be stopped, although not completely, by several
meters of concrete or several centimeters of lead.
Gamma Radiation
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Gamma rays can be dangerous because
of their penetrating power. What property
determines the relative penetrating power
of electromagnetic radiation?
CHEMISTRY & YOU
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Gamma rays can be dangerous because
of their penetrating power. What property
determines the relative penetrating power
of electromagnetic radiation?
CHEMISTRY & YOU
The wavelength and energy of
electromagnetic radiation determine its
relative penetrating power. Gamma rays
have a shorter wavelength and higher
energy than X-rays or visible light.
25.1 Nuclear Radiation >
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Which process involves a radioactive
nucleus releasing a high-speed
electron?
A. oxidation
B. alpha emission
C. beta emission
D. gamma radiation
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A. oxidation
B. alpha emission
C. beta emission
D. gamma radiation
Which process involves a radioactive
nucleus releasing a high-speed
electron?
25.1 Nuclear Radiation >
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Key Concepts
Unlike chemical reactions, nuclear
reactions are not affected by changes in
temperature, pressure, or the presence of
catalysts. Also, nuclear reactions of a
given radioisotope cannot be slowed
down, sped up, or stopped.
Three types of nuclear radiation are alpha
radiation, beta radiation, and gamma
radiation.
25.1 Nuclear Radiation >
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Glossary Terms
• radioactivity: the process by which nuclei
emit particles and rays
• nuclear radiation: the penetrating rays and
particles emitted by a radioactive source
• radioisotope: an isotope that has an unstable
nucleus and undergoes radioactive decay
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Glossary Terms
• alpha particle: a positively charged particle
emitted from certain radioactive nuclei; it
consists of two protons and two neutrons and
is identical to the nucleus of a helium atom
• beta particle: an electron resulting from the
breaking apart of neutrons in an atom
• gamma ray: a high-energy photon emitted by
a radioisotope
25.1 Nuclear Radiation >
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Electrons and the Structure of Atoms
• Unstable atomic nuclei decay by emitting
alpha or beta particles.
• Often gamma rays are emitted too.
BIG IDEA
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END OF 25.1