chapter 24 nuclear chemistry (p. 858-899) i iv iii ii

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CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

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Page 1: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

CHAPTER 24

Nuclear Chemistry

CHAPTER 24

Nuclear Chemistry

(p. 858-899)(p. 858-899)I

IV

III

II

Page 2: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Section 24.1 Nuclear Radiation

Section 24.2 Radioactive Decay

Section 24.3 Nuclear Reactions

Section 24.4 Applications and Effects of Nuclear Reactions

Table Of ContentsCHAPTER24

Page 3: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

CHAPTER 24

Nuclear Chemistry

CHAPTER 24

Nuclear ChemistryI. Nuclear I. Nuclear RadiationRadiationI. Nuclear I. Nuclear RadiationRadiation

I

IV

III

II

Page 4: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Summarize the events that led to understanding radiation.

nucleus: the extremely small, positively charged, dense center of an atom that contains positively charged protons, neutral neutrons, and is surrounded by empty space through which one or more negatively charged electrons move

• Identify alpha, beta, and gamma radiations in terms of composition and key properties.

SECTION24.1

Nuclear Radiation

Page 5: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Student Learning essential questions-Section 1

• How was radioactivity discovered and studied?• What are the key properties of alpha, beta, and

gamma radiation?

Page 6: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Isotope

Radioisotope

X-ray

penetrating power

Under certain conditions, some nuclei can emit alpha, beta, or gamma radiation.

SECTION24.1

Nuclear Radiation

Page 7: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Warm -up

• List the three different types of radiation and their charges.

• Tell me the composition of the radiation type that can not penetrate paper because it is too large.

1. Alpha, +2; Beta, _1; Gamma, 0

2. Alpha, 2 protons and 2 neutrons

Page 8: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The Discovery of Radiation• Nuclear reactions are different from other types of

reactions.

• Nuclear chemistry is concerned with the structure of atomic nuclei and the changes they undergo.

• Marie Curie and her husband Pierre isolated the first radioactive materials.

SECTION24.1

Nuclear Radiation

Page 9: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The Discovery of Radiation (cont.)

SECTION24.1

Nuclear Radiation

Page 10: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Warm-Up

C. Johannesson

Page 11: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Isotopes

Page 12: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Isotopes …

Therefore, isotopes of the same element have different masses.

…of the same element have the same number of protons and electrons but different numbers of neutrons.

Page 13: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Isotopes ……don’t have to be radioactive.

Some isotopes are unstable and decay, releasing alpha or beta particles, or gamma rays.

But, there are many stable isotopes that don’t decay.

Page 14: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Isotopes …

Mass number - the sum of the protons and neutrons in the nucleus.

Atomic number - the number of protons in the nucleus of an atom.

…have different mass numbers but the same atomic number.

Page 15: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Symbols for Isotopes

EA

Z

Symbol of element

Mass number

Atomic number

A is the symbol for mass number

Z is the symbol for atomic number

Page 16: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

U235

92

Symbols for Isotopes

Symbol of Element

Mass number

Atomic number

An isotope of uranium

Page 17: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Symbols for Isotopes

U235

92

Mass number

Symbol of Element

Atomic number An isotope of uranium

This form solves the word processor dilemma.

Page 18: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

U-235

Symbol of Element

Mass numberHow do you know the atomic number?

Find U in the periodic table.

Symbols for Isotopes

Z = 92

Page 19: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Some elements have several Isotopes

Lead has four naturally occurring isotopes, Pb-204, Pb-206, Pb-207, and Pb-208; but there are 23 man-made isotopes of lead.

Page 20: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Some elements have several Isotopes

Bismuth has only one naturally occurring isotope, Bi-209, but there are 22 man-made isotopes of bismuth.

Page 21: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

How are isotopes of the same element alike and different?

Alike:1. Number of

protons and electrons

2. Atomic number3. Chemical

properties

Different:1. Number of

neutrons

2. Mass Number3. Atomic mass of

the isotopes

Page 22: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Types of Radiation

• Isotopes of atoms with unstable nuclei are called radioisotopes.

• Unstable nuclei emit radiation (release energy) to attain more stable atomic configurations in a process called radioactive decay.

• The three most common types of radiation are alpha, beta, and gamma.

SECTION24.1

Nuclear Radiation

Isotope- Atoms of the same element with different number of neutrons.

Page 23: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Types of Radiation (cont.)

SECTION24.1

Nuclear Radiation

Page 24: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

He42

A. Types of Radiation

• Alpha particle ()– helium nucleus paper2+

Beta particle (-) electron e0

-11-

leadPositron (+)

positron e01

1+

Gamma () high-energy photon 0

concrete

Page 25: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Alpha particles have the same composition as a helium nucleus—two protons and two neutrons.

• Because of the protons, alpha particles have a 2+ charge.

• Alpha radiation consists of a stream of particles.

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 26: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Alpha radiation is not very penetrating—a single sheet of paper will stop an alpha particle.

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 27: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Beta particles are very fast-moving electrons emitted when a neutron is converted to a proton.

• Beta particles have insignificant mass and a 1– charge.

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 28: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Beta radiation is a stream of fast moving particles with greater penetrating power—a thin sheet of foil will stop them.

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 29: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Gamma rays are high-energy electromagnetic radiation.

• Gamma rays have no mass or charge.

• Gamma rays almost always accompany alpha and beta radiation.

• X rays are a form of high-energy electromagnetic radiation emitted from certain materials in an excited state. (gamma rays)

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 30: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• The ability of radiation to pass through matter is called its penetrating power.

• Gamma rays are highly penetrating because they have no charge and no mass.

SECTION24.1

Nuclear Radiation

Types of Radiation (cont.)

Page 31: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Why do radioisotopes emit radiation?

A. to balance charges in the nucleus

B. to release energy

C. to attain more stable atomic configurations

D. to gain energy

SECTION24.1

Section Check

Page 32: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

X rays are most similar to what type of nuclear emissions?

A. gamma rays

B. alpha particles

C. beta particles

D. delta waves

SECTION24.1

Section Check

Page 33: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

CHAPTER 24

Nuclear Chemistry

CHAPTER 24

Nuclear Chemistry

II. Radio Active II. Radio Active DecayDecay

II. Radio Active II. Radio Active DecayDecay

I

IV

III

II

Page 34: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Explain why certain nuclei are radioactive.

radioactivity: the process by which some substances spontaneously emit radiation• Apply your knowledge of

radioactive decay to write balanced nuclear equations.

• Solve problems involving radioactive decay rates.

SECTION24.2

Radioactive Decay

Page 35: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Student Learning essential questions-Section 2

• Why are certain nuclei radioactive?• How can you use radioactive decay rates to analyze

samples of radioisotopes?

Page 36: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Transmutation

Unstable nuclei can break apart spontaneously, changing the identity of atoms.

half-life

SECTION24.2

Radioactive Decay

Page 37: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Stability

• Except for gamma radiation, radioactive decay involves transmutation, or the conversion of an element into another element.

• Protons and neutrons are referred to as nucleons.

• All nucleons remain in the dense nucleus because of the strong nuclear force.

SECTION24.2

Radioactive Decay

Page 38: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

B. Nuclear Decay

• Alpha Emission

He Th U 42

23490

23892

parentnuclide

daughternuclide

alphaparticle

Numbers must balance!!

Page 39: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

B. Nuclear Decay

• Beta Emission

e Xe I 0-1

13154

13153

electronPositron Emission

e Ar K 01

3818

3819

positron

Page 40: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

B. Nuclear Decay

• Electron Capture

Pd e Ag 10646

0-1

10647

electronGamma Emission

Usually follows other types of decay.

Transmutation One element becomes another.

Page 41: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Types of Radioactive Decay

• Atoms can undergo different types of decay—beta decay, alpha decay, positron emission, or electron captures—to gain stability.

SECTION24.2

Radioactive Decay

Page 42: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Types of Radioactive Decay (cont.)

• In beta decay, radioisotopes above the band of stability have too many neutrons to be stable.

• Beta decay decreases the number of neutrons in the nucleus by converting one to a proton and emitting a beta particle.

SECTION24.2

Radioactive Decay

Page 43: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• In alpha decay, nuclei with more than 82 protons are radioactive and decay spontaneously.

• Both neutrons and protons must be reduced.

• Emitting alpha particles reduces both neutrons and protons.

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 44: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 45: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Nuclei with low neutron to proton ratios have two common decay processes.

• A positron is a particle with the same mass as an electron but opposite charge.

• Positron emission is a radioactive decay process that involves the emission of a positron from the nucleus.

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 46: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• During positron emission, a proton in the nucleus is converted to a neutron and a positron, and the positron is then emitted.

• Electron capture occurs when the nucleus of an atom draws in a surrounding electron and combines with a proton to form a neutron.

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 47: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 48: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.2

Radioactive Decay

Types of Radioactive Decay (cont.)

Page 49: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

B. Nuclear Decay• Why nuclides decay…

– need stable ratio of neutrons to protons

He Th U 42

23490

23892

e Xe I 0-1

13154

13153

e Ar K 01

3818

3819

Pd e Ag 10646

0-1

10647

DECAY SERIES TRANSPARENCY

Page 50: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

C. Half-life

• Half-life (t½)– Time required for half the atoms of a radioactive

nuclide to decay.– Shorter half-life = less stable.

Page 51: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

C. Half-life

nif mm )( 2

1

mf: final massmi: initial massn: # of half-lives

Page 52: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

C. Half-life/Warm-Up

C. Johannesson

Fluorine-21 has a half-life of 5.0 seconds. If you start with 25 g of fluorine-21, how many grams would remain after 60.0 s?

n = (t) ÷ (T); t = total elapsed time, T = length of half life.

GIVEN:

T½ = 5.0 s

mi = 25 g

mf = ?

t = 60.0 s

n = 60.0s ÷ 5.0s =12

WORK:

mf = mi (½)n

mf = (25 g)(0.5)12

mf = 0.0061 g

Page 53: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

C. Half-life

C. Johannesson

The half-life of radium-224 is 3.66 days. What was the original mass of radium-224 if 0.0500 grams remains after 7.32 days? Show all work!

GIVEN:T½ = 3.66 days

mi = ?

mf = 0.0500

Elapsed time (t) = 7.32 days

n = 7.32 days ÷ 3.66 days = 2.00

WORK:

mf = mi (½)n

mf = (mi)(0.5)2

mf = 0.0500 g

.0500 g = (mi)(0.5)2

mi = 0.0500 g ÷ 0.25 = 0.2 g

Page 54: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

C. Half-life

C. Johannesson

Exactly 1/16th of a given amount of protactinum-234 remains after 26.75 hours. What is the half-life of protactinum-234? Show all work!

GIVEN:Lets say original amount (mi) = 100g proctactinum-234.100 g X (1/16) -= 6.25 g

50 g = 1st half-life

25 g = 2nd half-life

12.5 g = 3rd half-life

6.25 g = 4th half-life

WORK:

mf = mi (½)n

n = 4- half lives

T = 26.75 ÷ 4 = 6.69 hours

Page 55: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Radioactive Decay Rates (cont.)

SECTION24.2

Radioactive Decay

Page 56: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.2

Radioactive Decay

Radioactive Decay Rates (cont.)

Page 57: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• The process of determining the age of an object by measuring the amount of certain isotopes is called radiochemical dating.

• Carbon-dating is used to measure the age of artifacts that were once part of a living organism.

SECTION24.2

Radioactive Decay

Radioactive Decay Rates (cont.)

Page 58: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The process of converting one element into another by radioactive decay is called ____.

A. half-life

B. nuclear conversion

C. transmutation

D. trans-decay

SECTION24.2

Section Check

Page 59: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

An unknown element has a half-life of 40 years. How much of a 20.0g sample will be left after 120 years?

A. 0.00g

B. 2.50g

C. 5.00g

D. 7.50g

SECTION24.2

Section Check

Page 60: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

CHAPTER 24

Nuclear Chemistry

CHAPTER 24

Nuclear ChemistryIII. Nuclear III. Nuclear ReactionsReactionsIII. Nuclear III. Nuclear ReactionsReactions

I

IV

III

II

Page 61: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Understand that mass and energy are related.

mass number: the number after an element’s name, representing the sum of its protons and neutrons• Compare and contrast

nuclear fission and nuclear fusion.

• Explain the process by which nuclear reactors generate electricity.

SECTION24.3

Nuclear Reactions

Page 62: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Student Learning essential questions-Section 3

• How are nuclear equations balanced?• How are mass and energy related?• How do nuclear fission and nuclear fusion compare

and contrast?• What is the process by which nuclear reactors

generate electricity?

Page 63: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

nuclear fission

Fission, the splitting of nuclei, and fusion, the combining of nuclei, release tremendous amounts of energy.

nuclear fusion

SECTION24.3

Nuclear Reactions

Page 64: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Induced Transmutation

• One element can be converted into another by spontaneous emission of radiation.

• Elements can also be forced to transmutate by bombarding them with high-energy alpha, beta, or gamma radiation.

SECTION24.3

Nuclear Reactions

Page 65: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Warm-Up: Writing Nuclear Equations

• Write a balanced equation for the alpha decay of thorium-232. Turn to Pg. 868, Table 3, and page 869 in Text book, to help getting started.

Answer:

Page 66: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Warm-Up:Balancing a Nuclear reaction

• NASA uses the alpha decay of plutonium-238, as a heat source on spacecraft. Write a balanced

equation for this decay.

Analyze this problem- You are given that a plutonium atom undergoes alpha decay and forms an unknown product. Plutonium-238 is the initial reactant, while the alpha particle is one of the products of the reaction. The reaction is summarized in the equation below.

Determine the unknown product of the reaction, X

Page 67: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Writing and Balancing Nuclear Equations

• Nuclear reactions are expressed by balanced nuclear equations.

• In balanced nuclear equations, mass numbers and charges are conserved.

–Ex. A plutonium-238 atom undergoes alpha decay, write a balanced equation for this decay.

SECTION24.2

Radioactive Decay

Page 68: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.2

Radioactive Decay

Writing and Balancing Nuclear Equations

Page 69: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Induced Transmutation (cont.)

• The process of striking nuclei with high-velocity charged particles is called induced transmutation.

SECTION24.3

Nuclear Reactions

Page 70: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Particle accelerators use electrostatic and magnetic fields to accelerate charged particles to very high speed.

• Transuranium elements are the elements with atomic numbers 93 and higher, immediately following uranium.

SECTION24.3

Nuclear Reactions

Induced Transmutation (cont.)

Page 71: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Reactions and Energy

• Mass and energy are related.

• Loss or gain in mass accompanies any reaction that produces or consumes energy.

SECTION24.3

Nuclear Reactions

Page 72: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Reactions and Energy (cont.)

• Most chemical reactions produce or consume so little energy that the accompanying changes in mass are negligible.

• Energy released from nuclear reactions have significant mass changes.

SECTION24.3

Nuclear Reactions

Page 73: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• The mass of a nucleus is always less than the sum of the masses of the individual protons and neutrons that comprise it.

• The difference between a nucleus and its component nucleons is called the mass defect.

• Binding together or breaking an atom’s nucleons involves energy changes.

SECTION24.3

Nuclear Reactions

Nuclear Reactions and Energy (cont.)

Page 74: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Nuclear binding energy is the amount of energy needed to break 1 mol of nuclei into individual nucleons.

SECTION24.3

Nuclear Reactions

Nuclear Reactions and Energy (cont.)

Page 75: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Fission

• The splitting of nuclei into fragments is known as nuclear fission.

• Fission is accompanied with a very large release of energy.

SECTION24.3

Nuclear Reactions

Page 76: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Fission (cont.)

• Nuclear power plants use fission to produce electricity by striking uranium-235 with neutrons.

SECTION24.3

Nuclear Reactions

Page 77: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Fission (cont.)

• Each fission of U-235 releases two additional neutrons.

• Each of those neutrons can release two more neutrons.

• The self-sustaining process is called a chain reaction.

SECTION24.3

Nuclear Reactions

Page 78: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.3

Nuclear Reactions

Nuclear Fission (cont.)

Page 79: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Without sufficient mass, neutrons escape from the sample before starting a chain reaction.

• Samples with enough mass to sustain a chain reaction are said to have critical mass.

SECTION24.3

Nuclear Reactions

Nuclear Fission (cont.)

Page 80: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.3

Nuclear Reactions

Nuclear Fission (cont.)

Page 81: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

U-235

U-235

U-235

Nuclear fission

Neutron

Neutrons

Fission fragment

Fission fragment

Page 82: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear fission

U-235

U-235

Neutrons

Fission fragment

These U-235 atoms can split when hit by neutrons, and release

more neutrons, starting a chain

reaction.

Page 83: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear fission

To picture a chain reaction, imagine 50 mousetraps in a wire cage.

And on each mousetrap are two ping-pong balls.

Now imagine dropping one more ping-pong ball into the cage …

Page 84: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Detail of ping-pong balls on mousetraps.

http://www.physics.montana.edu/demonstrations/video/modern/demos/mousetrapchainreaction.html

Page 85: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

http://www.physics.montana.edu/demonstrations/video/modern/demos/mousetrapchainreaction.html

Page 86: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear fission

Billions of splitting atoms releases a huge amount of heat energy.

This energy originally held the nucleus together.

As the chain reaction proceeds, energy is released as heat energy.

Page 87: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear fission

This heat energy can be harnessed to boil water,

creating steam,

that can spin a turbine,

that can turn a generator,

creating electricity.

Page 88: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Fusion

• It is possible to bind together two or more lighter elements (mass number less than 60).

• The combining of atomic nuclei is called nuclear fusion.

• Nuclear fusion is capable of releasing very large amounts of energy.

SECTION24.3

Nuclear Reactions

Page 89: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Fusion (cont.)

• Fusion has several advantages over fission.

− Lightweight isotopes are abundant.

− Fusion products are not radioactive.

− However, fusion requires extremely high energies to initiate and sustain a reaction.

SECTION24.3

Nuclear Reactions

Page 90: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Fusion reactions are also known as thermonuclear reactions.

• Many problems must be solved before nuclear fusion is a practical energy source.

SECTION24.3

Nuclear Reactions

Nuclear Fusion (cont.)

Page 91: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Reactors

• Nuclear fission produces the energy generated by nuclear reactors.

• The fission within a reactor is started by a neutron-emitting source and is stopped by positioning the control rods to absorb virtually all of the neutrons produced in the reaction.

SECTION24.3

Nuclear Reactions

Page 92: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Reactors (cont.)

• The reactor core contains a reflector that reflects neutrons back into the core, where they react with fuel rods.

• Nuclear reactors produce highly radioactive nuclear waste.

• Breeder reactors produce more fuel than they consume.

SECTION24.3

Nuclear Reactions

Page 93: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.3

Nuclear Reactions

Nuclear Reactors (cont.)

Page 94: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Bombarding a nuclei with charged particle in order to create new elements is called ____.

A. nuclear conversion

B. nuclear decay

C. induced decay

D. induced transmutation

SECTION24.3

Section Check

Page 95: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Thermonuclear reactions involve:

A. splitting nuclei into smaller fragments

B. fusing nuclei together to form larger particles

C. bombarding nuclei with charged particles

D. generating electricity in a nuclear reactor

Section CheckSECTION24.3

Page 96: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

CHAPTER 24

Nuclear Chemistry

CHAPTER 24

Nuclear Chemistry

IV- IV- Applications and Effects of Nuclear Reactions

IV- IV- Applications and Effects of Nuclear Reactions

I

IV

III

II

Page 97: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Describe several methods used to detect and measure radiation.

isotope: an atom of the same element with the same number of protons but different number of neutrons

• Explain an application of radiation used in the treatment of disease.

• Describe some of the damaging effects of radiation on biological systems.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 98: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Student Learning essential questions-Section 4

• What are several methods used to detect and measure radiation?

• How is radiation used in the treatment of disease?• What are some of the damaging affects of radiation

on biological systems?

Page 99: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

ionizing radiation

radiotracer

Nuclear reactions have many useful applications, but they also have harmful biological effects.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 100: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Detecting Radioactivity• Radiation with enough energy to ionize matter it

collides with is called ionizing radiation.

• The Geiger counter uses ionizing radiation to detect radiation.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 101: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Detecting Radioactivity (cont.)

• A scintillation counter detects bright flashes when ionizing radiation excites electrons of certain types of atoms.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 102: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Uses of Radiation

• When used safely, radiation can be very useful.

• A radiotracer is a radioactive isotope that emits non-ionizing radiation and is used to signal the presence of an element or specific substrate.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 103: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Uses of Radiation (cont.)

• Radiation can damage or destroy healthy cells.

• Radiation can also destroy unhealthy cells, such as cancer cells.

• Unfortunately, radiation therapy also destroys healthy cells in the process of destroying cancerous cells.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 104: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Biological Effects of Radiation

• Radiation can be very harmful.

• The damage depends on type of radiation, type of tissue, penetrating power, and distance from the source.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 105: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Biological Effects of Radiation (cont.)

• High energy radiation is dangerous because it produces free radicals.

• Free radicals are atoms or molecules that contain one or more unpaired electrons.

• Free radicals are highly reactive.

SECTION24.4

Applications and Effects of Nuclear Reactions

Page 106: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• Two units measure doses of radiation.

• The rad stands for Radiation-Absorbed Dose, which is the amount of radiation that results in 0.01 J of energy per kilogram of tissue.

• The rad does not account for the type of tissue that is absorbing the radiation.

• The rad is multiplied by a factor related to its effect on the tissue involved and is called the rem, Roentgen Equivalent for Man.

SECTION24.4

Applications and Effects of Nuclear Reactions

Biological Effects of Radiation (cont.)

Page 107: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

SECTION24.4

Applications and Effects of Nuclear Reactions

Biological Effects of Radiation (cont.)

Page 108: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

• I1d12 = I2d2

2 where I = intensity and d = distance.

SECTION24.4

Applications and Effects of Nuclear Reactions

Biological Effects of Radiation (cont.)

Page 109: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Page 110: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Page 111: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Heat exchangerSteam generator

Water circulates in the core

Steam to turbine

Water from cooling lake

Page 112: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Water from cooling lake

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Water circulates in the core

Steam to turbine

Cadmium control rods – absorb neutrons

Page 113: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Water from cooling lake

Nuclear reactor

Reactor core

Fue

l rod

s

Water circulates in the core

Steam to turbine

The water in the core serves two functions.

(1) The water cools the core and carries away heat. (2) Water is a moderator. The water slows the neutrons so

that they can cause fission. Fast neutrons do not cause fission.

Containment building

Page 114: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Water circulates in the core

Water from cooling lake

Page 115: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Water circulates in the core

Water from cooling lake

Heat exchangerSteam generator

Page 116: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Water circulates in the core

Water from cooling lake

Heat exchangerSteam generator

Page 117: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear reactor

Reactor core

Containment building

Fue

l rod

s

Water circulates in the core

Water from cooling lake

Steam to turbine

Heat exchangerSteam generator

Page 118: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

From nuclear energy to…

Steam to turbine

Water from cooling lake Cooling towers or

lake

turbine generator

Transmission wires

Condensed steam

Heat exchangerSteam generator

Page 119: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Steam to turbine

Water from cooling lake Cooling towers or

lake

turbine generator

Transmission wires

Condensed steam

Heat exchangerSteam generator

Electrical energy

Page 120: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Steam to turbine

Water from cooling lake Cooling towers or

lake

turbine generator

Transmission wires

Condensed steam

Heat exchangerSteam generator

Electrical energy

This part of the system is the same regardless of how the steam is produced. The heat can come from nuclear energy or by burning coal, natural gas or fuel oil.

Page 121: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Electrical energy

In fact, the only purpose of a nuclear reactor is to boil water.

Page 122: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Pros and cons

Cheap, plentiful power, no CO2, nuclear waste, terrorist attack, running out of oil and coal, on-site storage, breeder reactors, transportation of spent fuel, “not in my backyard”, …

Page 123: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

What is a radioisotope that emits non-ionizing radiation and is used to signal the presence of certain elements called?

A. rad

B. rem

C. radiotracer

D. free radical

SECTION24.4

Section Check

Page 124: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Radiation with enough energy to cause tissue damage by ionizing the particles it collides with is called ____.

A. alpha decay

B. beta decay

C. gamma radiation

D. ionizing radiation

SECTION24.4

Section Check

Page 125: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Key Concepts

• Wilhelm Roentgen discovered X rays in 1895.

• Henri Becquerel, Marie Curie, and Pierre Curie pioneered the fields of radioactivity and nuclear chemistry.

• Radioisotopes emit radiation to attain more-stable atomic configurations.

Study Guide

SECTION24.1

Nuclear Radiation

Page 126: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Key Concepts• The conversion of an atom of one element to an atom of another by

radioactive decay processes is called transmutation.

• Atomic number and mass number are conserved in nuclear reactions.

• A half-life is the time required for half of the atoms in a radioactive sample to decay.

• Radiochemical dating is a technique for determining the age of an object by measuring the amount of certain radioisotopes remaining in the object.

SECTION24.2

Radioactive Decay

Study Guide

Page 127: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Key Concepts

• Induced transmutation is the bombardment of nuclei with particles in order to create new elements.

• In a chain reaction, one reaction induces others to occur. A sufficient mass of fissionable material is necessary to initiate the chain reaction.

• Fission and fusion reactions release large amounts of energy.

E = mc2

SECTION24.3

Nuclear Reactions

Study Guide

Page 128: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Key Concepts

• Different types of counters are used to detect and measure radiation.

• Radiotracers are used to diagnose disease and to analyze chemical reactions.

• Short-term and long-term radiation exposure can cause damage to living cells.

SECTION24.4

Applications and Effects of Nuclear Reactions

Study Guide

Page 129: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The half-life of a radioisotope is:

A. one-half its total life

B. 2500 years

C. the amount of time it takes to completely decay

D. the amount of time it takes for one-half to decay

Chapter Assessment

Nuclear ChemistryCHAPTER24

Page 130: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

What is a positron?

A. a nucleon with the same mass as a neutron and a positive charge

B. a nucleon with the same mass as a proton and a negative charge

C. a nucleon with the same mass as an electron and a positive charge

D. a type of radioactive emission with a negative charge

Nuclear ChemistryCHAPTER24

Chapter Assessment

Page 131: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

What is the force that holds the protons and neutrons together in the nucleus of an atom?

A. nuclear magnetic force

B. strong nuclear force

C. ionic bonding

D. nuclear bond

Nuclear ChemistryCHAPTER24

Chapter Assessment

Page 132: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

During positron emission, a proton is converted to:

A. a neutron and electron

B. an electron and positron

C. a proton and neutron

D. a neutron and positron

Chapter Assessment

Nuclear ChemistryCHAPTER24

Page 133: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

A thermonuclear reaction is also called ____.

A. nuclear fission

B. nuclear fusion

C. mass defect

D. critical mass

Nuclear ChemistryCHAPTER24

Chapter Assessment

Page 134: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Which statement is NOT true of beta particles?

A. They have the same mass as an electron.

B. They have a charge of 1+.

C. They are less penetrating than alpha particles.

D. They are represented by 0-1β.

Standardized Test Practice

Nuclear ChemistryCHAPTER24

Page 135: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The site that oxidation occurs at in a battery is called ____.

A. anode

B. cathode

C. nothode

D. salt bridge

Nuclear ChemistryCHAPTER24

Standardized Test Practice

Page 136: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

A solution of 0.500M HCl is used to titrate 15.00mL if KOH solution. The end point of the titration is reached after 25.00 mL of HCl is added. What is the concentration of KOH?

A. 9.00M

B. 1.09M

C. 0.833M

D. 0.015M

Nuclear ChemistryCHAPTER24

Standardized Test Practice

Page 137: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

The half-life of K-40 is 1.26 × 109 years. How much of a 10.0g sample will be left after 200 million years?

A. 8.96g

B. 8.03g

C. 7.75g

D. 4.99g

Nuclear ChemistryCHAPTER24

Standardized Test Practice

Page 138: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Elements above the band of stability are radioactive and decay by ____.

A. alpha decay

B. beta decay

C. positron emission

D. electron capture

Nuclear ChemistryCHAPTER24

Standardized Test Practice

Page 139: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter

Symbol

Actually is…

Atomic number

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Stop!Complete the chart on notebook paper, then continue.

Page 140: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter

Symbol

Actually is…

Atomic number

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Page 141: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

Actually is…

Atomic number

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Page 142: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is…

Atomic number

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Page 143: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Page 144: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number

Relative mass

Relative charge

Penetrating

Shielding

Page 145: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number 4 0 NA

Relative mass

Relative charge

Penetrating

Shielding

Page 146: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number 4 0 NA

Relative mass 4 1/1837NA

Relative charge

Penetrating

Shielding

Page 147: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number 4 0 NA

Relative mass 4 1/1837NA

Relative charge +2 -1 NA

Penetrating

Shielding

Page 148: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number 4 0 NA

Relative mass 4 1/1837NA

Relative charge +2 -1 NA

Penetrating Low Medium High

Shielding

Page 149: CHAPTER 24 Nuclear Chemistry (p. 858-899) I IV III II

Nuclear Properties TableProperty Alpha Beta Gamma

Greek Letter Symbol

2He4-1e0 NA

Actually is… He nucleus electron EM energy

Atomic number 2 -1 NA

Mass number 4 0 NA

Relative mass 4 1/1837NA

Relative charge +2 -1 NA

Penetrating Low Medium High

Shielding 2.5 cm of air;anything else

Metal, plastic or wood

Lead or concrete