chap.1 processing of iron and s

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    Processing ofProcessing of

    Iron and SteelIron and Steel

    CHAPTER 1CHAPTER 1

    Iron OreIron Ore

    is mined from the groundis mined from the ground

    it is a rock that may contain only 30% ofit is a rock that may contain only 30% of

    iron.iron.

    is in chemical compound or the iron isis in chemical compound or the iron is

    combined with oxygen or sulfur.combined with oxygen or sulfur.

    is found intermixed in rock, gravel, clay,is found intermixed in rock, gravel, clay,sand or even mud.sand or even mud.

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    The iron ore is chemical compoundThe iron ore is chemical compound

    with oxygen or sulfur.with oxygen or sulfur.

    Sulfur Oxygen

    Iron

    Silicon IronSulfur Oxygen

    Iron

    Silicon Iron

    Sulfur

    Sulfur Oxygen Iron

    Silicon Iron

    Oxygen Iron Sulfur

    Types of iron oreTypes of iron oreIron ore Iron Compound % iron

    Hematite Fe2O3 70%

    Magnetite Fe3O4 65%

    Siderite FeCO3 48%

    Limonite 2Fe2O3 H2O 52% 66%

    Taconite Various 22% - 40%

    Hematite

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    Iron ore is found intermixed inIron ore is found intermixed in

    rock, gravel, clay, sand or mudrock, gravel, clay, sand or mud

    Rock Gravel

    Mud

    ClayRock

    Iron

    Oxygen

    Iron

    Oxygen

    Iron Ore ProcessingIron Ore ProcessingCrushing the stone by Gyratory crusher - (smaller pieces)

    Milling process in the roll mill or ball mill (fine particles)

    Separation process by magnetic separator

    Floatation process

    Impurities bubble to the top and are skimmed awayand leaving an iron rich mixture

    The particle is immersed in a liquid

    Iron ore (~70% iron)

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    Iron Ore ProcessingIron Ore Processing(Explanation)(Explanation)

    First, the large chunks of stone are brokenFirst, the large chunks of stone are brokenup by giant crushers such as Gyratoryup by giant crushers such as Gyratorycrusher.crusher.

    These smaller pieces are then fed into rollThese smaller pieces are then fed into rollmill or rod mill and ball mill.mill or rod mill and ball mill.

    The mill rotate and hardened steel rollersThe mill rotate and hardened steel rollersor ball rotate with the ore and steadilyor ball rotate with the ore and steadilypound it into finer particles.pound it into finer particles.

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    After being crushed and milled, the rockAfter being crushed and milled, the rock

    particles become so fine that they feel like sugarparticles become so fine that they feel like sugar

    or dry sand.or dry sand.

    In this condition the valuable iron ore particlesIn this condition the valuable iron ore particles

    can be separated by magnetic separator fromcan be separated by magnetic separator from

    others.others.

    The strong magnetic will separate the iron oreThe strong magnetic will separate the iron ore

    from others particles during separator rotates.from others particles during separator rotates.

    Iron Ore ProcessingIron Ore Processing

    (Explanation)(Explanation)

    Next the powder goes to flotation process,Next the powder goes to flotation process,

    where the particles are immersed in a liquid.where the particles are immersed in a liquid.

    Impurities bubble to the top and are skimmedImpurities bubble to the top and are skimmed

    away and leaving an iron rich mixture.away and leaving an iron rich mixture.

    After magnetic separation and flotation the oreAfter magnetic separation and flotation the ore

    may contain as much as 70 % iron.may contain as much as 70 % iron.

    Iron Ore ProcessingIron Ore Processing(Explanation)(Explanation)

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    Steel ProcessingSteel Processing

    There are 2 basic steps in steelThere are 2 basic steps in steel

    processing:processing:

    Step 1Step 1 -- Iron ore is converted to pig ironIron ore is converted to pig iron

    Step 2Step 2 -- Pig iron is made into steelPig iron is made into steel

    Steps for Making SteelSteps for Making Steel

    Blast

    FurnaceSteel

    Making

    FurnaceIron ore

    Pigiron

    Steel

    Step 1 Step 2

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    The Blast FurnaceThe Blast Furnace

    Blast FurnaceBlast Furnace

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    The Blast FurnaceThe Blast Furnace

    A blast furnace may be more than 250A blast furnace may be more than 250

    feet high, taller than 12feet high, taller than 12--storey buildingstorey building

    and 30 feet in diameter.and 30 feet in diameter.

    Fire resistant brick lines the inside wall ofFire resistant brick lines the inside wall of

    the blast furnace.the blast furnace.

    PIG IRON PROCESSINGPIG IRON PROCESSING

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    The blast furnace is charged with iron ore,The blast furnace is charged with iron ore,

    limestone, and coke.limestone, and coke.

    A blast of preheated air burns the coke,A blast of preheated air burns the coke,

    producing heat to melt the iron, whichproducing heat to melt the iron, which

    falls to the bottom of furnace.falls to the bottom of furnace.

    C + OC + O22 = CO= CO22 + Heat+ Heat

    COCO22+ C = 2CO+ C = 2CO

    Reaction at high temperature, so Carbon dioxide will reduce to carbonmonoxide as below:

    The molten limestone combines with mostThe molten limestone combines with mostof the impurities in the ore to form a slag,of the impurities in the ore to form a slag,which separates from the liquid ironwhich separates from the liquid ironbecause it is lighter and floats.because it is lighter and floats.

    The liquid iron and the liquid slag areThe liquid iron and the liquid slag are

    removed periodically from the bottom ofremoved periodically from the bottom ofthe furnace.the furnace.

    FeS + CaO + C= CaS + FeO + COFeS + CaO + C= CaS + FeO + CO

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    The liquid iron is poured into mold to formThe liquid iron is poured into mold to form

    what is known as pig of iron.what is known as pig of iron.

    Pig iron is hard and brittle.Pig iron is hard and brittle.

    It contains considerable amounts ofIt contains considerable amounts of

    dissolved carbon, manganese, silicon,dissolved carbon, manganese, silicon,

    phosphorus and sulfur.phosphorus and sulfur.

    Step 1: Iron OreStep 1: Iron Ore Pig IronPig IronIron ore + Limestone + Coke

    (Charcoal) are put into the furnaceA blast of preheated air burns the

    coke and produce the heat

    Melting process of ironMelting iron falls to the bottom

    Molten limestone mixed withimpurities in ore SLAG (lighter

    and float)

    Molten iron and molten slag areremoved from the bottom

    Iron is poured into mouldPIG IRON

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    Air

    Ore+

    Limestone+

    Coke

    Slag

    Iron

    Air

    Cast into pig iron

    In the Blast FurnaceIn the Blast Furnace

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    Pig IronPig Iron

    Contains considerable amounts ofContains considerable amounts of

    dissolved 4dissolved 4--5% carbon, manganese,5% carbon, manganese,

    silicon, phosphorus and sulfur.silicon, phosphorus and sulfur.

    Hard and brittleHard and brittle

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    PIG IRONPIG IRON

    There are several types ofThere are several types of

    converter/furnace that used in makingconverter/furnace that used in making

    steel:steel:

    Open Hearth FurnaceOpen Hearth Furnace

    Basic Oxygen FurnaceBasic Oxygen Furnace

    Electric Arc FurnaceElectric Arc Furnace

    Step 2: Pig IronStep 2: Pig Iron SteelSteel

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    Open Hearth FurnaceOpen Hearth Furnace

    The oldest converter.The oldest converter.

    Basically a large bowl made of firebrick.Basically a large bowl made of firebrick.

    Molten iron

    Hot Air Hot Air

    Steel is cast into ingot

    OHF ProcessingOHF Processing

    Pig iron and scrap metal are putinto the furnace

    Hot air is blown across the surfaceand produce the heat

    Excess carbon and impurities areburned off

    Refining process

    At the end of the refining process,

    desired amount of carbon oralloying elements are added

    Molten steel is drawn and cast intoingots

    STEEL

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    Basic Oxygen FurnaceBasic Oxygen Furnace

    It is a rapid process (10 times faster thanIt is a rapid process (10 times faster than

    OHF).OHF).

    Lower cost.Lower cost.

    Molten iron

    Oxygen

    Lance

    Pig iron + scrap metal

    BOF ProcessingBOF Processing

    Pig iron + scrap are dumped intothe furnace vessel

    A lance is lowered from above intothe charge

    Pure oxygen is blown through thelance

    The oxygen burns off the carbonvery rapidly

    Once the carbon is removed, the

    lance is withdrawn

    Desired amount of carbon and

    alloying elements are added

    Steel is cast into ingotSTEEL

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    Electric Arc FurnaceElectric Arc Furnace

    It requires about 440 kW/ton of steel.It requires about 440 kW/ton of steel.

    Capacity range: 1Capacity range: 1 100 tons100 tons

    No air is required for melting processNo air is required for melting process

    Materials Outlet

    Molten iron

    EAF ProcessingEAF Processing

    Pig iron + scrap are loaded intothe furnace

    Electrode are lowered from the topof the furnace close to the iron

    An arc is struck to the iron to meltthe iron and burn off the carbon

    Steel is cast into ingot

    STEEL