cereal based biorefinery : new initiatives with the biohub ......one of the leading global producers...
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RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 1
Cereal Based Biorefinery : New Initiatives with the BioHub™ Programme
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 2
AGENDA
ROQUETTE PresentationVegetal Based Chemistry & InnovationCereal based BiorefineryFrench Agency for Industrial InnovationBioHub™ ProgrammeVegetal Based Chemistry & Initiatives , outlook and needs
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 3
Turnover of more than 2 billion €
6 000 salaried staff
A Research & Development Center
• 400 people• 50 million €
4 Agricultural Raw Materials :CornWheat Starch potatoes Pea
Lestrem : Headquarters
THE ROQUETTE THE ROQUETTE COMPANY TODAYCOMPANY TODAY
An active portfolio of more than 150 patents250 research contracts by year with universities and private partners worldwide.
One of the leading global producers of starch products :Number 2 in Europe ; In the Top 4 in the world World leading producer of polyols and gluconates
6 mio.t/year550,000 hectares cultivated
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 4
ROQUETTE SUSTAINABLE STRATEGY
DIVERSIFICATION INTEGRATION
COOPERATION
• Vegetal based chemistry incl. WB (BioHub™ Programme supported by the AII)
• Nutrition & Health Programme(Fibers, Pea Protein, Polyols)
INNOVATION
• “Biorefinery” concept from cereals
• Green “Verbund” concept for specialty products (Polyols & Derivatives)
• Over the fence JV worldwide (ROQUETTE-SETHNESS JV for caramel color at Lestrem France)
• Agriculture raw materials(Corn, Wheat, Potato, Pea…)
• Geographical area (Europe, Americas, Asia)*
• Alternative energies : biomass, geothermal
• Markets (Food, Chemical, Pharmacy, Paper, Feed,…)
• UPSTREAM : With farmers (JV for the bioethanolproduction at Beinheim France) & associations
• DOWNSTREAM :With leading industrial groups
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 5
VEGETAL BASED CHEMISTRY AT THE HEARTH OF INNOVATION FOR SUSTAINABLE DEVELOPMENT
What doessociety
request ?
What doconsumers and market
need ?
White Biotech.Green Chemistry
Nanotech.New Catalysis
Health & NutritionMobility
EconomyFeasability
Renewable resources,Social and
environmentalEthics of industry
Vegetal Based Chemistry
WHAT IS POSSIBLE ?
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 6
VEGETAL BASED CHEMISTRY : A MAJOR TOOL FOR SUSTAINABLE INNOVATION
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK
Sustainable Development
Health &
NutritionCommunication
THREE MAIN PILARS FOR INNOVATION
Renewable resources
Polyols, proteins and fibers for food & pharmaceuticals
Green solvents and complexing agents
for electronics
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 7
BIOREFINERY : A NEW EXAMPLE FOR SUSTAINABLE DEVELOPMENT
The refinery based on fossil resourcesSource Transformation Products Downstream process
Raffinage &
CrackingOilfields
Native Oil Naphta Monomers & polymers
ChemicalTransformation Formulation
End Product
The biorefinery based on renewable resources (cereals)Source Transformation Products Upstream process
Biotech Trans-
formation
Chemical Trans-
formation
Starch
production
Agriculturalfields Formulation
Maize/Wheat Glucose Monomers & polymers End Product
Shared role between biotechnology and chemistryLeading role of chemistry
Leading role of biotechnology
The Concept Definitions
NEW CEREALS BASED BIOREFINERY
MMeeting the needs of the present without compromising the ability of future generations to meet their own needs.PProcessing starch and using chemical, biological and physical means to refined value added end-products for use in food and non-food applications.
PROCESSES :
White Biotech
Plant Based Chemistry
New chemical products for specialties and biopolymers markets
New industrial biotechnological processes for chemical intermediates and active ingredients
New platform chemicals
The BioHub™ PROGRAMME
RRB Conference 6th – 8th Sept 2006 The University of York York UK
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 10
ECO-INNOVATION FROM CEREALS TO END-PRODUCTS
BioHub™ Programme
• Largely available• High content of
fermentable sugar (corn = 62 %)
• Become more competitiv• Reduce CO2 emission• Preserve fossil resource
e
s
• Biopolymers
• Biomonomers for specialties and commodities markets
Eco-productsEco-conception
• More ecological and cleaner processes
• Simplified processes with integrated steps
• Technically proven for many decades
Agricultural raw materials : cereals
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 11
FRENCH AGENCY FOR INDUSTRIAL INNOVATION
Prospection
Selection
Follow-up
Large companies
Research Centers
Customers
SME
PMII ProgrammeAgency for Industrial
Innovation
Budget : 1.7 bn € (2006;2007)
Consortium with a leading company (Roquette for the
BioHub™ programme)
PMII : Mobilizing Program for Industrial Innovation
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 12
THE FIRST SIX PROGRAMMES SELECTED BY THE FRENCH AGENCY FOR INDUSTRIAL INNOVATION *
BioHub™ (Roquette) : new chemical products and new processes from renewable resources (cereals)
TVMSL (Alcatel) : no limit mobile TV (TV broadcast on mobile hone through satellite and terrestrial links)
VHD (PSA) : electric gasoil hybrid vehicle
Quaero(Thomson) : multimedia
search engine
Homes (Schneider
Electric) : energy saving
building
Neoval (Siemens) : new
transportation equipment
*subject to EC agreement
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 13
BioHub™ Strategy : PMII ROQUETTE
Targets :
Develop cereals based chemical products to the point that they are sustainable substitutes
for fossil origin products
Means :
Consortium of European Industrials and Scientists led by ROQUETTE and supported by the French Agency for Industrial Innovation
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 14
BioHub™ Programme : PMII ROQUETTE
BioHub™
New products
Substitutes for petchem
Current products with new biotech. processes
BiosolventsBioplasticisersBiolubricantsBio fluxing agentsBiopolymersBiocomplexing agents
Chemical intermediates
Active ingredients
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 15
ISOSORBIDEA SUSTAINABLE DIOL FOR CHEMICALS AND POLYMERS
(isosorbide)
Di Methyl Isosorbide« sustainable solvent »
O
O
OCH3
OCH3
COOH – (CH2)n – COOH Diacids
Or other chemicals
Isosorbide Diester« PVC-plasticizers »
O
O
O CO
R
OCO
R
O
R-C
OHFatty acids
H
CH2 OH – (CHOH)4 – C
O
(sorbitol)CH2 OH – (CHOH)4 – CH2OH
(glucose)H2, P
Polyesters
PEIT
PolyurethanesPolycarbonateOther polymers
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 16
ISOSORBIDE MODIFIED PET REACTION
PTA EG Isosorbide
+ PEIT+
O OH
OHO
HO OHO
O
HO
OH=
Higher Tg performance creates new opportunities for PET beyond today’s limitations
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 17
ISOSORBIDE VALUE CREATION FOR MULTIPLE MARKETS
Glass-Transition Temperature of PEIT
0 040
60
80
100
120
140
160
180
200IsosorbideCHDMIsophthalic Acid (IPA)
Mole % (X)
Engineering Resins
CD’s
3GT4GT
PEN
Hot-fillContainers
ThickSheet
PETGPCHDM
IPA
Comonomer Effect on Glass Transition Temperature (Tg)
g T(°
C)
20 4 60 80 100
First target = HOT-FILL CONTAINERS (THERMORESISTANT PET)
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 18
BioHubTM Programme
Institut des Molécules et de la Matière Condensée de Lille (IMMCL)
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 19
BioHub™ Program : main figures
Global cost of the Programme = 98 mio. € ( 6 years )
Aids from the French Agency of Ind. Innov. : 43 mio. €
(22 mio. € subsidy and 21 mio. € reimbursable loans)
Industrial investments = 730 mio. € (starting after 2010)
Expected volumes and surfaces = 1.3 mio. tons corn or 150 000 ha
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 20
VEGETAL BASED CHEMISTRY AT THE HEARTH OF INNOVATION FOR SUSTAINABLE DEVELOPMENT
• The BREW project (6th R&D framework programme)
• The Epobio programme (6th R&D framework programme)
• The Suschem Platform for the 7th R&D framework programme
• The BioHub™ programme supported by the French Agency for Industrial Innovation
MANY EUROPEAN INITIATIVES IN VEGETAL BASED CHEMISTRY WITH INVOLVEMENT OF
GRAIN PROCESSORS
THE GRAIN PROCESSORS ARE WITH ENZYMES AND CHEMICAL COMPANIES THE MAIN DRIVERS OF INDUSTRIAL BIOTECHNOLOGY
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 21
POSITIVE OUTLOOK FOR VEGETAL BASED CHEMISTRY
Global chemical sales derived from renewable materials or produced by fermentation or enzymatic methods
2005 2010billion €uro 77 125% / global chemical sales 7 10
Source : McKinsey and Co
• Biofuels, with significant government support, is the largest and most rapidly growing segment
• Bioproducts developments grow slowly but with a higher sustainability
RRB Conference, 6th – 8th Sept., 2006 The University of York, York, UK 22
NEW CEREAL BASED BIOREFINERY : CONCLUSION
Now : real assessment by the industrial, scientific and political communities on the real opportunity of the vegetal based chemistry for the future
Need : to develop new incentives in order to facilitate acceptance
• of the cereal based biorefinery products by the industrial users
• of these end-products by the consumers (examples : French plastic bags, German packaging tax)