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BTEC/NYSERDA Off-Gassing Project BTEC NYSERDA Pellet Storage Stakeholder Session # 3 1 PM ET J l 23 2013 1 PM ET , July 23, 2013 This Webinar is brought to you by: Biomass Thermal Energy Council (BTEC) and the New York State h d l h ( ) Energy Research and Development Authority(NYSERDA) 1

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  • BTEC/NYSERDA Off-Gassing Project

    BTEC NYSERDA Pellet Storage Stakeholder Session # 3

    1 PM ET J l 23 20131 PM ET, July 23, 2013This Webinar is brought to you by:

    Biomass Thermal Energy Council (BTEC) and the New York State h d l h ( )Energy Research and Development Authority(NYSERDA)

    1

  • BTEC/NYSERDA Off-Gassing Project

    Quick notesTwo Audio Options: Streaming Two Audio Options: Streaming Audio and Dial-In.1. Streaming Audio/Computer

    Speakers (Default)2 Dial In: Use the Audio Panel2. Dial-In: Use the Audio Panel

    (right side of screen) to see dial-in instructions. Call-in separately from your telephone.

    Ask questions using the Questions Panel on the right side of your screen.

    The recording of the webinar and the slides will be available after the event. Registrants will be notified by emailnotified by email.

  • BTEC/NYSERDA Off-Gassing Project

    Speakers

    Joseph Seymour, Biomass Thermal Energy

    CouncilCouncil

    Ray Albrecht, Biomass Thermal Energy

    Council

    Dr. Alan Rossner, Clarkson University

    Dr. Philip Hopke, Clarkson University

    Tim Cullina, Fauske & Associates

    3

    Cu a, aus e & ssoc ates

  • BTEC/NYSERDA Off-Gassing Project

    Presentation OutlineI. Project overview and survey results–Seymour

    II. Update on ventilation techniques–Albrecht

    IV. Preliminary results of wood pellet storage research–

    Hopke & Rossner

    V E l f i l ti f t d ti V. Examples of implementing safety recommendations –

    Cullina

    VI Q&A –SeymourVI. Q&A Seymour

    4

  • BTEC/NYSERDA Off-Gassing Project

    Joseph SeymourExecutive Director, Biomass Thermal Energy Council

    P j t O i d S Project Overview and Survey Results

    5

  • BTEC/NYSERDA Off-Gassing Project

    About BTECThe Biomass Thermal Energy Council (BTEC) is the industry trade association dedicated to advancing the use of biomass for heat and other thermal energy applications.

    Why was BTEC established?1. To advocate for and promote the biomass thermal industry in the

    national energy policy debate2 T h t t d d t th bli d d i i k th 2. To reach out to and educate the public and decision makers on the

    benefits and advantages of using biomass for heat and CHP3. To develop biomass energy research and analysis that enables

    sound investment and policy decisions 1. Technical and Regulatory Affairs Committee (TRAC) created to

    help address safety and regulatory concerns, increase markets2. Member-led3 Will assist NYSERDA project when needed

    6

    3. Will assist NYSERDA project when needed

  • BTEC/NYSERDA Off-Gassing Project

    About the Pellet Storage Surveyg y

    Online, conducted mid-April 2013 to June 2013Distributed through BTEC/PFI networksDistributed through BTEC/PFI networksNational and regional breakdown

    Nat’l – 18 respondentsNE - 13 respondentsp

    Preliminary findings, limited responses, warrants further study

    Use for descriptive purposesp p pComplete results available at conclusion of projectOption of conducting annually

  • BTEC/NYSERDA Off-Gassing Project

    Fuel Type

    Wood Pellets Sold/Used for Bulk Delivery

    39% Softwood39% Softwood22% Hardwood44% Blend of Softwood and Hardwood

    (some are a combination of the three)

    8

  • BTEC/NYSERDA Off-Gassing Project

    3035

    Frequency of Bulk Pellet Deliveries

    15202530

    05

    105

    Percent

    Once a Week

    Once Every Two

    Weeks

    Once Every Month

    Once Every Two Months+

  • BTEC/NYSERDA Off-Gassing Project

    Typical Pellet Storage Size

    46%

    40%

    45%

    50%

    25%

    30%

    35%

    40%

    8%

    15% 15%

    8%10%

    15%

    20%

    25%

    0% 0% 0%0%

    5%

    1 ton bulk 2 ton bulk 3 ton bulk 10 ton bulk 20 ton bulk 40 ton bulk 1 ton pallet, 40 lb bag

    2 ton pallet, 40 lb bag

    Typical Pellet Storage SizeTypical Pellet Storage Size

  • BTEC/NYSERDA Off-Gassing Project

    OtherI d O tdIndoor vs. Outdoor

    1-25% of reported serviced consumers have outdoor systems5 and 10 ton storage were most common

    75-99% have indoor systems75 99% have indoor systems3 ton storage was most common

    VentilationMost Common

    Vented cap on filling pipes

    Also usedOpen window/vent or mechanical active ventilation system

    Safety/Warning Signage69% indicated that warning signs are in use15% said no or did not know15% said no or did not knowThe remainder sometimes use safety/warning signs depending on the application

  • BTEC/NYSERDA CO Off-Gassing Project

    Ray AlbrechtTechnical Consultant, Biomass Thermal Energy Council

    Update on Ventilation pTechniques

    12

  • Update on BTEC/NYSERDA Project                             

    Ventilation in Bulk Pellet Storage

    For

    Residential and Commercial Pellet‐fired Boiler Systems

    R d J Alb ht P ERaymond J Albrecht, P.E.Technical AdvisorBiomass Thermal Energy Council (BTEC)

    [email protected]

  • Information Gathering Relating to Policies and Standards

    Austria, Germany, Sweden and Canada

    English translation of Austrian M 7137 standard for delivery and storage of bulk pellets

    Technical resource for development of US pguidelines

  • Information Gathering Relating to Policies and Standards

    Austria, Germany, Sweden and Canada

    English summary translation of German g yVDI 3464 pellet storage standard 

  • Bioenergy 2020 gy

    Technical Research Reports 

  • Sample Graph of CO Formation Rate vs TimeSample Graph of CO Formation Rate vs Time

    Laboratory Testing

    CO formation rate in mg CO per kg of pellets per 24 hrs

    Most pellet samples show less than 1 mg/kg conversion to CO per day but occasional higher rates up to 3 mg/kg have been measured with some samples of softwood pellets sa p es o so t ood pe ets

    Rapid drop after initial period

    Ventilation needs to meet  peak i t f fi t 1 2 krequirements for first 1 or 2 weeks 

    after delivery

    Longer term CO formation rate typically less than 10% of peak

  • CO Formation Rate in Samples of Fresh Softwood Pelletsp

    Bioenergy 2020 ‐ Austria

    Strong majority of pellet samples have lower CO formation rates

    But exceptions occur – science of CO formation not fully understood

    No data yet for hardwood pellets

    No data for US pellets

  • European Recommendation for Pellet Storage Ventilation

    14,0

    European Recommendation for Pellet Storage Ventilation

    Target CO concentration of 30 ppm in 

    10,0

    12,0

    1/

    h]

    VPellets : VAir 1:1VPellets : VAir 1:2VPellets : VAir 1:3VPellets : VAir 1:15

    storage compartment

    Summary:

    1 mph cross‐ventilation airflow

    6,0

    8,0

    an

    ge

    rate

    n [

    1 1 mph cross ventilation airflow through a 4 inch opening provides 30 ppm CO level for storage system filled with 5 tons of worst‐case (3 mg CO per kg pellets per 24 hrs) pellets

    2 0

    4,0

    Air

    exch

    a

    Airflow   =   4 cfm

    About 5% of typical bathroom exhaust fan volume

    0,0

    2,0

    0,01 0,1 1 10Emission rate CO [mg/ kg fuel] in 24 h

    7 inch diameter opening to maintain 9 ppm in storage compartment

    slide 19

  • Ventilated Fill Caps – Laboratory Testing Results

    Twist‐on caps with ventilation slots

    Primary driving force for air exchange is  difference in temperature (inside storage compartment– outside)

    h f l f ³ ll

    r excha

    nge rate [m

    ³/h] Graph of test results for 8 m³ pellet storage 

    silo – with ventilated caps and 1 meter length fill piping 

    Airflow at 5 deg C temperature difference is OK for majority of pellet reactivity levelsAir is OK for majority of pellet reactivity levels

    But average airflow at zero temperature difference only 2 ft3 per hour compared to recommended ventilation rate of 4 ft3 per minute for most reactive pelletsminute for most reactive pellets

  • Comparison of Air‐tight Storage With and Without Ventilated Caps

    Laboratory Testing Results

    Reduced CO concentrations in pellet storage with ventilated caps

    But additional openings needed to achieve 30 ppm in air‐tight storage compartments

    More effective ventilation could be accomplished with variety of combined wind/temperature‐driven passive openings including integrated fill i / til ti th ll fittifill pipe/ventilation thru‐wall fittings similar to sealed combustion air supply/exhaust terminations for gas‐fired appliance 

  • Pellet Storage CO ConcentrationPellet Storage CO Concentration 

    Ventilated Cap with Supplemental Opening

    Bioenergy 2020

    Still has initial CO concentration peak but equilibrium value near zero ppm with supplemental opening

    More effective cross‐ventilation or larger single opening would reduce or eliminate initial peak concentration of CO

    Blue =  Ventilated Cap only

    Green = Ventilated Cap plus Supplemental OpeningGreen   Ventilated Cap plus Supplemental Opening

  • International Pellet Safety Workshop

    Organized by European Pellet Council  ‐ BTEC is now observing member

    70 participants from Europe and US/Canada

    27 discussion groups over 3 days

    Pellet production, transport  and storage

    Report available at www.pelletcouncil.eu

    Industry database and blog to be posted onlineIndustry database and blog to be posted online

    2nd Workshop planned for May or June 2014

  • Upcoming Pellet Storage Project Tasks

    Safe Pellet Project Workshop – Austria

    Briefing for government agencies

    Final report

    Technical article for biomass publication 

  • BTEC/NYSERDA CO Off-Gassing Project

    Dr. Philip Hopke

    Dr. Alan Rossner Professors, Clarkson Universityy

    Preliminary Results of yWood Pellet Storage Research

    25

  • CO Monitoring ProjectCO Monitoring Project

    Philip K. Hopke and Alan RossnerInstitute for a Sustainable Environment

    Clarkson [email protected]@clarkson.edu

  • MotivationMotivation

  • MotivationMotivationThe installation of wood pellet heating as a cost-effective and climatically neutral source of energy for private households has increased steadily in recent years. We report two deaths that occurred within the space of about a year in wood pellet t f i t h h ld i G kistorerooms of private households in German-speaking

    countries and were investigated by forensic medical teams. This is the first report of fatalities in this special context as is shown in the literature review Both victims died of carbonshown in the literature review. Both victims died of carbon monoxide (CO) poisoning; one of the victims was a woman who was 4 months pregnant. Measurements at the scene detected life-threatening CO concentrations (7500 ppm,detected life threatening CO concentrations (7500 ppm, >500 ppm), which were not significantly reduced after ventilation of the storerooms as required by regulations.

  • Health ImplicationsHealth ImplicationsToxic 

    CO Concentration  Inhalation Time Symptoms(ppm)

    9 Short term exposureASHRAE recommended maximum allowable concentration in living area.The maximum exposure allowed by OSHA in the

    35 8 hoursThe maximum exposure allowed by OSHA in the workplace over an eight hour period.

    200 2‐3 hoursSlight headache, tiredness, fatigue, nausea and dizziness.

    400 1‐2 hours Serious headache‐other symptoms intensify.Life threatening after 3 hours.

    800 45 minutes Dizziness, nausea and convulsions.Unconscious within 2 hours.Death after 2‐3 hours.

    1,600 20 minutes Headache, dizziness and nausea.Death within 1 hour.

    3,200 5‐10 minutes Headache, dizziness, nausea.D th ithi 1 hDeath within 1 hour.

    6,400 1‐2 minutes Headache, dizziness, nausea.Death within 25‐30 minutes.

    12,800 1‐3 minutes Death within 1‐3 minutes

  • Pellet StoragePellet Storage

  • Scope of WorkScope of Work– Monitoring a series of pellet bins

    • 1 ton of storage in our Energy Cabin (20 kW)\• 10 ton bin at the Walker Center 150 kW system• 20 ton bin at the Wild Center for their 500 kW boiler.• 10 ton storage facility in a residential basement• 20 ton storage facility at elementary school• ~30 ton storage in coal bunker at middle schoolg• Up to 100 ton storage facility at SUNY-ESF

    – Monitor forMonitor for• CO• PM in some cases• CO O T and RH in others• CO2, O2, T and RH in others

  • Energy CabinEnergy Cabin

  • Initial MeasurementsInitial Measurements

    • Used a Langan L76 CO/CO2 monitorUsed a Langan L76 CO/CO2 monitor

    CO Concentrations

    80 0

    100.0

    120.0

    CO Concentrations

    20 0

    40.0

    60.0

    80.0

    CO (ppm)

    ‐20.0

    0.0

    20.0

    0 50 100 150 200Temporal Variations

  • Pellet BagPellet Bag

  • Pellet SiloLocation of sensorof sensor

    This is at the Elementary School in Saranac Lake

  • Middle School Coal Bunker

    Pellet Storage BinPellet Storage Bin

    Area where the two 1 MMBTU boilers are placed

  • Sensor PackagesSensor Packages

    • We are make sensor packages using City TechWe are make sensor packages using City Tech sensors.– CO – electrochemical– O2 – electrochemical– CO2 – NDIR2– RH and T using Vaisala HUMICAP systems

    • Built into 1 or 8 gallon cansg– Filter on top– Fan on the bottom to provide flow through

  • Sensor PackagesSensor Packages

  • CalibrationCalibration120

    Calibration Plot

    ppm

    ) 100 r ² =0.9987

    ntra

    tion

    (p

    60

    80

    CO

    Con

    ce

    40

    0 4 0 5 0 6 0 7 0 8 0 9

    C

    0

    20

    Output Voltage (V)0.4 0.5 0.6 0.7 0.8 0.9

  • Sensor PackagesSensor Packages

    • For the Middle School andFor the Middle School and ESF bins, we will also measure PM concentrations to examine the dust levels during pellet delivery.g p y

    • Use a commercial PM monitor (Met One Model (831) that gives PM1, PM2.5, PM4, and PM10.

  • Monitoring to DateMonitoring to Date

    • We have data fromWe have data from– The residential basement in Massena

    Two of the three locations in the Malone school– Two of the three locations in the Malone school– The Saranac Lake Elementary School

    E C bi– Energy Cabin

  • Massena Residence Basement1-hr values

    80

    Massena Residence

    60

    80

    (ppm

    )

    40

    60

    OSHA Limit

    CO

    (

    20

    40 OSHA Limit

    20ASHRAE Limit

    Date

    04/01

    00

    05/01

    00

    06/01

    00

    07/01

    00

  • Massena Residence Basement

    M R id

    801-hr values

    Massena Residence

    60

    O (p

    pm)

    40 OSHA

    CO

    20

    ASHRAE

    Date

    03/01

    00

    04/01

    00

    05/01

    00

    06/01

    00

    07/01

    00

  • Massena Residence Basement8-hr rolling average

    Massena Residence

    30

    20

    CO

    (pp 10pm)

    Date

  • Malone Middle SchoolI hr Values

    10

    Malone Middle School

    8 C0 (Boiler Room) CO (Hallway)

    (ppm

    ) 6

    CO (Hallway)

    CO

    (

    4

    0

    2

    03/04

    00

    03/11

    00

    03/18

    00

    03/25

    00

    04/01

    00

    04/08

    00

    04/15

    00

    04/22

    000

  • Malone Middle School

    18000

    1 hr PM Values

    14000

    16000 PM1.0PM2.5PM4.0

    μg/m

    3 )

    10000

    12000 PM10

    PM ( μ

    6000

    8000

    0

    2000

    4000

    DateMon 25 Mon 11 Mon 25 Mon 08 Mon 22

    0

  • Malone Middle School

    18000

    1 hr ValuesNOTE:

    14000

    16000 PM1.0PM2.5PM4.0

    NOTE: These values are all well less than the

    μg/m

    3 )

    10000

    12000 PM10explosive limits for wood dust.

    PM ( μ

    6000

    8000

    0

    2000

    4000

    DateMon 25 Mon 11 Mon 25 Mon 08 Mon 22

    0

  • Saranac Lake School1 hr Values

    250

    Saranac Lake School

    200

    O (p

    pm) 150

    CO

    50

    100

    00 00 00 00 00

    50

    Date

    04/01

    00

    04/08

    00

    04/15

    00

    04/22

    00

    04/29

    00

  • Saranac Lake School1 hr Values

  • Lab StudiesLab Studies

    • We are also performing a limited series ofWe are also performing a limited series of laboratory studies to determine the kinetics of off-gassing of CO and VOCs

    • Fill 15 gallon cans with 10 pounds of pellets– Hardwood, softwood, mixed hard/soft– Triplicate cans (9 in all)

    • Daily measurements of CO, CO2, O2, RH, and T• Collect 300 ml canisters from each sample after 1

    day and after 30 days to measure VOCs by GC/MSGC/MS

  • COCO200

    H d 1

    160

    180Hard 1 Hard 2 Hard 3 Soft 1

    (ppm

    )

    100

    120

    140 Soft 2 Soft 3 Blend 1 Blend 2

    CO

    (

    60

    80

    100Blend 3

    20

    40

    0 2 4 6 8 10 120

  • VOC EmissionsVOC Emissions

    • Canister samplers for VOC analyses wereCanister samplers for VOC analyses were obtained at 1 day after placing the pellets in the drums and after 30 daysthe drums and after 30 days

    • Samples are being analyzed to examine VOC being off gassedbeing off-gassed

    • Blended pellets clearly had the strongest smell.

  • ChromatogramsChromatogramsHardwood S ft d

    al alanal

    Softwood

    hexa

    na

    hexa

    na

    pent

    a

    acet

    one

    ol ane

    enta

    nal

    α-pi

    nene

    met

    hano

    pent

    a pe

  • Methanol Production RatesMethanol Production Rates30000

    Hardwood

    tion

    25000

    HardwoodSoftwoodBlend

    Con

    cent

    rat

    15000

    20000

    Rel

    ativ

    e C

    10000

    R

    0

    5000

    Day0 2 4 6 8 10 12

  • Additional ExperimentsAdditional Experiments

    Index Preprocess characteristics

    Regular Not processed reference

    Dried Dried overnight in drying oven Low RHDried Dried overnight in drying oven Low RH

    Aq.Phase With an aqueous phase present Highest RH

    DisinfectedDisinfected by an autoclave sterilizer at 115ºC for 20 min

    Killed all microbes and fungus, (Second highest RH)

  • Additional ExperimentsAdditional Experiments250

    200

    250As IsDriedWith waterAutoclaved

    PPM

    ) 150

    Autoclaved

    CO

    (P

    100

    50

    X Data

    04/17 04/21 04/25 04/29 05/03 05/07 0

  • Relevant U.S. Safety Standards: Confined Space Entry and

    Carbon Monoxide

    Timothy Cullina P. E. Senior Safety Engineer

    Fauske & Associates, LLC (FAI)[email protected]

  • Proprietary property of Fauske & Associates, LLC 2

    Dangers of Confined Spaces

  • Proprietary property of Fauske & Associates, LLC 3

    Related OSHA Standards

    General Industry Standards

    - 1910.38 - emergency action plans- 1910.94 – ventilation- 1910.132 - personal protective equipment- 1910.134 - respiratory protection- 1910.146 – confined spaces- 1910.1200 - hazard communication

    - General Duty Clause

    - Others depending upon hazards

  • Proprietary property of Fauske & Associates, LLC 4

    Related OSHA Standards

    Emergency Action Plan - who, what, where, when, how…

    Industrial Ventilation - control emissions, exposures, and chemical hazards in the workplace

    Personal protective equipment - hazard assessment and equipment required

    Respiratory protection - respirator shall be provided to each employee when necessary to protect the health of the employee

  • Proprietary property of Fauske & Associates, LLC 5

    Related OSHA Standards OSHA Hazard Communication

    The five key elementsWritten Program

    Material Safety Data Sheets

    Labeling

    Training

    Materials Inventory and Hazard Assessment

  • Proprietary property of Fauske & Associates, LLC 6

    General Duty ClauseSection 5(a) of the “Act”

    SEC. 5. Duties (a) Each employer --

    (1) shall furnish to each of his employees employment and aplace of employment which are free from recognized hazards that are causing or are likely to cause death or serious physical harm to his employees;

    (2) shall comply with occupational safety and health standardspromulgated under this Act.

  • Proprietary property of Fauske & Associates, LLC 7

    Permit-Required Confined Spaces29 CFR 1910.146

    Scope and applicationDefinitionsGeneral requirements (to include development of written plan)Permit-required confined spacesPermit systemEntry permit

    TrainingDuties of authorized entrantsDuties of attendantsDuties of entry supervisorsRescue and emergency servicesEmployee participation

  • Proprietary property of Fauske & Associates, LLC 8

    How to Identify Confined Spaces29 CFR 1910 .146 Permit-required confined spaces

    Space large enough to enter

    Limited or Restricted Entry or

    Exit

    Not Designed for Continuous

    Worker Occupancy

  • Proprietary property of Fauske & Associates, LLC 9

    Two Types of Confined Spaces29 CFR 1910.146

    Permit required- Meets confined space

    definition, and- Has inadequate ventilation,

    or- Has a hazardous health or

    safety condition, or- Has a known or potential

    hazardous atmosphere, or- Any other recognized

    serious hazard

    Non-permit required- Meets confined space

    definition- Has adequate

    ventilation- Does not contain any

    hazards that can cause death or harm

    - There is absolutely no potential for a hazardous atmosphere

    WARNING: Don’t make a false assumption that a non-permit space or a space that is not “confined” is a

    SAFE SPACE.

  • Proprietary property of Fauske & Associates, LLC 10

    Confined Spaces29 CFR 1910.146

    . .

    WARNING: Don’t make a false assumption that a non-permit space or a space that is not “confined” is a

    SAFE SPACE.

  • Proprietary property of Fauske & Associates, LLC 11

    Examples of “Typical” Confined Spaces

    PipelinePitPumping stationReaction or process vesselMillsSiloStorage tank

    BargesSewerUtility vaultTrenchesShaftsCaissonsCoal bins

  • Proprietary property of Fauske & Associates, LLC 12

    Large Enough to Enter

    source: osha.gov Training Grant Materials

    Limited Openings for Entry/Exit 

    Not for Continuous Occupancy

  • Proprietary property of Fauske & Associates, LLC 13

    Who Decides What A Confined Space Is?

    Employer must evaluate a space based on the definition, NOT on whether or not you may enter the space.

  • Proprietary property of Fauske & Associates, LLC 14

    Examples of “Pellet Storage”Are They Confined Spaces?

    Silo, above or below groundStorage room

    Converted Coal bins

  • Proprietary property of Fauske & Associates, LLC 15

    Not Designed for Continuous Worker Occupancy

    Most OSHA defined confined spaces are not designed to enter and work in on a regular basisThey are designed to:- Store a product at location or in transit- Enclose materials or processes- Allow occasional entry for inspection, repair, cleanup,

    and maintenance, etc

    http://www.google.com/url?sa=i&source=images&cd=&cad=rja&docid=f_8ZtbOoSz2f3M&tbnid=OHJEUynYCbRdTM:&ved=0CAgQjRwwAA&url=http://www.mywoodpelletsolution.com/wood-pellet-storage/&ei=eprtUbqoEKmpyAHY34GQCA&psig=AFQjCNFKCL107zdXE76cEjDnVgJuA9Rz-w&ust=1374612474315899

  • Proprietary property of Fauske & Associates, LLC 16

    Is It an OSHA Confined Space?

    Cut-away of Converted Coal Storage Room

  • Proprietary property of Fauske & Associates, LLC 17

    Is It Potentially Hazardous?

    Cut-away of Converted Coal Storage Room

  • Proprietary property of Fauske & Associates, LLC 18

    Is It an OSHA Confined Space?Is it Potentially Hazardous?

    Combination Work Area and Wood Pellet Storage Room

    http://www.google.com/url?sa=i&source=images&cd=&cad=rja&docid=f_8ZtbOoSz2f3M&tbnid=OHJEUynYCbRdTM:&ved=0CAUQjRw&url=http://www.pellergy.com/wood-pellet-central-heating-products/&ei=uZrtUcCzHYLlyAHZu4CoAw&psig=AFQjCNFKCL107zdXE76cEjDnVgJuA9Rz-w&ust=1374612474315899

  • Proprietary property of Fauske & Associates, LLC 19

    Confined Space? - follow the OSHA Standard! Appendices 29 CFR 1910.146

    Appendix A - Permit-Required Confined Space Decision Flow ChartAppendix B - Procedures for Atmospheric TestingAppendix C - Examples of Permit-Required Confined Space ProgramsAppendix D - Confined Space Pre-Entry Check List

    http://www.google.com/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=oS3NJESKztjnWM&tbnid=YDLkpqfRvJee0M:&ved=0CAUQjRw&url=http://yff.myy2y.co.uk/Learners_Online/Road_skills/RevRight/RR.html&ei=gFYiUfGNA8-tqQHNjIHgDg&psig=AFQjCNFH2dcS1AwhDM4UCIkWlQ82QbmjWw&ust=1361291087722856http://www.google.com/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=_n0NV_WqL6AoIM&tbnid=hNnywumAvREjiM:&ved=0CAUQjRw&url=http://www.speakdigital.co.uk/personal.php&ei=5lYiUf7tE9O1qQGz1oGoCQ&psig=AFQjCNFH2dcS1AwhDM4UCIkWlQ82QbmjWw&ust=1361291087722856

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    Not a Confined Space? – focus on the Hazard

    What is a hazard?

    A hazard is the potential for harm

    In practical terms, …

    a hazard often is associated with a condition or activity that, if left uncontrolled, can result in an injury or illness

    http://www.google.com/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=oS3NJESKztjnWM&tbnid=YDLkpqfRvJee0M:&ved=0CAUQjRw&url=http://yff.myy2y.co.uk/Learners_Online/Road_skills/RevRight/RR.html&ei=gFYiUfGNA8-tqQHNjIHgDg&psig=AFQjCNFH2dcS1AwhDM4UCIkWlQ82QbmjWw&ust=1361291087722856http://www.google.com/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=_n0NV_WqL6AoIM&tbnid=hNnywumAvREjiM:&ved=0CAUQjRw&url=http://www.speakdigital.co.uk/personal.php&ei=5lYiUf7tE9O1qQGz1oGoCQ&psig=AFQjCNFH2dcS1AwhDM4UCIkWlQ82QbmjWw&ust=1361291087722856

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    Hazards of Storage Spaces

    Oxygen Deficient AtmospheresOxygen Enriched AtmospheresFlammable AtmospheresToxic AtmospheresTemperature Extremes

    Engulfment hazardsSlick/wet surfaces, falling objects, noiseMechanical hazardsConfiguration hazardsOther hazards

    http://www.google.com/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=BzdxOrztVQCe4M&tbnid=aw_cMdYzf04fQM:&ved=0CAUQjRw&url=http://www.hydro-klean.com/ProjectLibrary/GrainBinEntry/&ei=LgccUcXRJcbIqQGnyYCYAg&bvm=bv.42261806,d.aWc&psig=AFQjCNEEGTvW2VfucFECNO4PAQ4Cf3Pv_Q&ust=1360877730968444

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    Flammable/Explosive AtmospheresCombustible Dust

    Critical Factors:- Oxygen content in the air- Presence of dust - Confined area- Dispersed in air- Ignition source

    Proper dust mixture can lead to explosionTypical Ignition Sources:- Sparking or electric tool- Welding/cutting operations- Smoking- Static Electricity

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    NFPA Standards

    OSHA uses NFPA Standards as RAGAGEP - “Recognized and Generally Accepted Good Engineering Practices”

    OSHA may cite the “General Duty Clause”(Section 5(a)(1) of the OSHA Act ) 

    if hazards are not identified and mitigated per RAGAGEP

    Section 5(a)(1) of the OSHA Act states:"Each employer shall furnish to each of his employees employment and a place of employment which are free from recognized hazards that are causing or are likely to cause death or serious physical harm to his employees."

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    Toxic Atmospheres in Storage Spaces

    Product in a Storage Space:- Gases released when cleaning- Materials absorbed into walls of storage space- Decomposition of materials in the storage space

    Work performed in a space:- Welding, cutting, brazing, soldering- Painting, scraping, sanding, degreasing- Sealing, bonding, melting

    Areas adjacent to a storage space- Exhaust , pumps, generators

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    If Unfavorable Natural Ventilationin Wood Pellet Storage Area

    Lack of air movement in and out of the space can create an atmosphere much different than the outside atmosphereDeadly gases can be trapped insideOrganic materials can decomposeMay not be enough oxygen due to presence of other gases or chemical reactions such as rusting

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    Carbon Monoxide

    Carbon monoxide is an odorless, colorless and toxic gas Because it is impossible to see, taste or smell the toxic fumes, CO can kill you before you are aware of it

    More than 150 people in the Unites States die every year from accidental non-fire related CO poisoning associated with consumer products

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    Test Before Entry

    Before employee enters space, internal atmosphere shall be tested, with calibrated direct-reading instrument, for following conditions in order given- Oxygen content- Flammable gases and vapors- Potential toxic air contaminants (e.g., carbon monoxide)

    Source: osha.gov Training Grant Materials

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    OSHA RequiredCarbon Monoxide Monitoring

    Carbon Monoxide is listed in Table Z‐1

    An exposure to any substance listed in Tables Z‐1, Z‐2, or Z‐3 shall be limited in accordance with the requirements of 1910.1000.   Exposures to hazardous and toxic substances are also addressed in specific standards, such as powered industrial trucks (forklifts, etc)

    1910.178 (i)(1)     Internal combustion engine powered industrial trucks (forklifts, etc)…employers shall monitor environmental exposure of employees to CO whenever internal combustion engine powered industrial trucks are operated indoors to ensure that CO levels do not exceed 50ppm

  • Proprietary property of Fauske & Associates, LLC 29

    Symptoms of CO Poisoning

    HeadacheDizzinessWeaknessNauseaVomitingChest painConfusion

    Carbon monoxide molecules are 200 times more likely

    to bind to hemoglobin thanare oxygen molecules

    Carbon monoxide crowds out the oxygen molecules depriving the body

    of the oxygen

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    Carbon Monoxide

    An Odorless, Colorless, Tasteless Gas

    PPM Effect

    50 . Permissible Exposure Level

    200 Slight headache, discomfort

    200 Headache, discomfort

    1000-2000 Confusion, nausea, headache

    1000-2000 Tendency to stagger

    1000-2000 Slight heart palpitation

    2000-2500 Unconsciousness

    Extended exposures can lead to brain and organ damage and death

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    Exposure Limits

    OSHA PEL OLD ACGIH  TLV 50 ppm 

    NIOSH REL BASED ON CARDIOVASCULAR EFFECTS 35 ppm 

    ACGIH TLV BASED ON CARBOXYHEMEGLOBIN EFFECTS 25 ppm

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    Two Types of Pellet Storage Spaces

    Permit required- Has inadequate

    ventilation, or- Has a hazardous health

    or safety condition, or- Has a known or

    potential hazardous atmosphere, or

    - Any other recognized serious hazard

    Non-permit required- Has adequate

    ventilation- Does not contain any

    hazards that can cause death or harm

    - There is absolutely no potential for a hazardous atmosphere

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    Categorizing Confined Spaces29 CFR 1910 .146 Permit-required confined spaces

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    Categorizing Confined Spaces29 CFR 1910 .146 Permit-required confined spaces

    . For OSHA, Enter means to put any part of your bodyinto the space

  • Proprietary property of Fauske & Associates, LLC 35

    Recommendations

    Identify all confined spaces and comply with OSHA standards

    For non-confined space storage areas:- Treat all storage spaces as hazardous until proven otherwise

    - If possible, identify all hazards in storage space before entry

    - Respond appropriately to hazards before entry

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    Categorizing Storage AreasModified from 29 CFR 1910.146 Permit-Required Confined Spaces

  • Proprietary property of Fauske & Associates, LLC 37

    Warning Signs & Safety Instructions from the DEPV

    Source: Gauthier S et al. Ann Occup Hyg 2012;56:755-763

  • Proprietary property of Fauske & Associates, LLC 38

    Thank you

    [email protected]

  • BTEC/NYSERDA Off-Gassing Project

    Q & A

    Ask questions using the Questions Panel on the right side of Ask questions using the Questions Panel on the right side of your screen.

    The webinar slides and recording will be made available after todayafter today.

    Look for future project updates from BTEC staff throughout Q3 of 2013of 2013

    96

  • BTEC/NYSERDA Off-Gassing Project

    Upcoming EventsWebinar: Where Does Biomass Energy Policy Stand?*

    July 26, 12PM ETwww Biomassthermal orgwww.Biomassthermal.org

    PFI Annual ConferenceJuly 28-30, Asheville, NCPelletheat.org Pelletheat.org

    International Training Seminar Biomass Heating -Market development and technologies

    Sept. 9 – 12, 2013, Linz, AustriaNebiomassheat.comScholarships available

    *97

    * Discount for BTEC members

  • BTEC/NYSERDA Off-Gassing Project

    Thank you for attending today’s webinar!Thank you for attending today s webinar!

    For more information, contact:Joseph SeymourJoseph Seymour

    BTEC Executive [email protected]

    202-596-3974 x302202 596 3974 x302

    98

    BTEC_Part1_CO_7.23.2013.pdfuse this one_cullina_CO Off-Gassing of Wood Pellets inStorage Relevant US Safety Standards2 [Recovered]Slide Number 1Dangers of Confined SpacesRelated OSHA StandardsRelated OSHA Standards�Related OSHA Standards �OSHA Hazard Communication General Duty Clause�Section 5(a) of the “Act”�Permit-Required Confined Spaces�29 CFR 1910.146 ��How to Identify Confined Spaces�29 CFR 1910 .146 Permit-required confined spaces��Two Types of Confined Spaces�29 CFR 1910.146 ��Confined Spaces�29 CFR 1910.146 �Examples of “Typical” Confined SpacesLarge Enough to Enter�Who Decides What A Confined Space Is? Examples of “Pellet Storage”�Are They Confined Spaces?Not Designed for �Continuous Worker OccupancyIs It an OSHA �Confined Space?Is It Potentially Hazardous?Is It an OSHA Confined Space?�Is it Potentially Hazardous? �Confined Space? - follow the OSHA Standard! �Appendices 29 CFR 1910.146 ��Not a Confined Space? – focus on the Hazard �Hazards of Storage Spaces�Flammable/Explosive Atmospheres�Combustible DustNFPA StandardsToxic Atmospheres in Storage SpacesIf Unfavorable Natural Ventilation�in Wood Pellet Storage AreaCarbon Monoxide Test Before EntryOSHA Required�Carbon Monoxide MonitoringSymptoms of CO PoisoningSlide Number 30Exposure Limits�Two Types of Pellet Storage Spaces��Categorizing Confined Spaces�29 CFR 1910 .146 Permit-required confined spacesCategorizing Confined Spaces�29 CFR 1910 .146 Permit-required confined spacesRecommendationsCategorizing Storage Areas�Modified from 29 CFR 1910.146 Permit-Required Confined Spaces Warning Signs & �Safety Instructions from the DEPVThank you�������[email protected]

    BTEC_part4