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86
93 rd Annual Conference 2018 James L Barnard, Ph.D., D.Ing. h.c. BCEE, WEF Fellow Biological Nutrient Removal - Quo Vadis June 24, 2018

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Page 1: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

93rd

Annual Conference 2018

James L Barnard, Ph.D., D.Ing. h.c. BCEE, WEF Fellow

Biological Nutrient Removal -

Quo Vadis

June 24, 2018

Page 2: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Contents

Historical Background

The development of activated sludge

Eutrophication and indirect recycling

Intensification of processes

Energy self-sufficiency

The Gorilla in the room

Conclusions

June 24, 2018

Page 3: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Population Structures by Age and Sex, 2005 Millions

300 100 100 300300 200 100 0 100 200 300

Less Developed

RegionsMore Developed

Regions

Male Female Male Female

80+ 75-79 70-74 65-69 60-64 55-59 50-54 45-49 40-44 35-39 30-34 25-29 20-24 15-19 10-14

5-90-4

Age

Source: United Nations, World Population Prospects: The 2004 Revision, 2005.

Age Distribution of the World’s Population

7.2 Billion

Population

June 24, 2018

Page 4: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

The Culture of Flushing

June 24, 2018

Page 5: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Victor Hugo –

Les Misérables

"A great city is the most powerful of stercoraries. To

employ the city to enrich the plain would be a sure

success. If our gold is filth, then our filth is

gold….these fetid streams of subterranean slime

which the pavement hides from you, do you know

what all this is? It is the flowering meadow, it is the

green grass, it is marjoram and thyme and sage, it

is game, it is cattle, it is the satisfied low of huge

oxen at evening, it is perfumed hay, it is golden

corn, it is bread on your table, it is warm blood in

your veins, it is health, it is joy, it is life."

June 24, 2018

Page 6: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Before activated sludge

June 24, 2018

Page 7: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Activated sludge plant as a

sustainable process (1914)

Developed by Arden and Lockett

Has served us for a century to produce effluent fit for re-use

Used a batch reactor and observed nitrification some denitrification and removal of some phosphorus

They formed a granular sludge

The process keeps evolving to make it more versatile more adaptable while lowering energy and cost

June 24, 2018

Page 8: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

The Haber – Bosch Process

Supplies world nitrogen needs

The Haber process now produces 450 million tonnes of nitrogen

fertilizer per year, mostly in the form of anhydrous ammonia,

ammonium nitrate, and urea. Three to five percent of the world's

natural gas production is consumed in the Haber process (around 1–

2% of the world's annual energy supply).

HydrogenFrom natural gas

Gases are cooled and ammonia turns ot liquid

Unreacted gases

recycled

Nitrogen

From the air 400 – 500 °C200 bar

Ion catalyst

Liquid ammonia

Well designed and operated BNR 30 kWh/person/aJune 24, 2018

Page 9: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

A Process of Selection

The basis of the process is to change conditions and select for

specific organisms. Below is a rough time-line for developing of

the process

June 24, 2018

Page 10: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

ge

wit

h N

itri

fica

tion

Hig

h-R

ate

Act

ivate

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lud

ge

Exp

lod

ing o

f N

ew P

lan

ts i

n U

SA

Adap

t to

Tre

atm

ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

-Ch

emic

als

Sel

ect

for

Den

itri

fica

tion

Sel

ect

for

Ph

osp

hate

Acc

um

ula

tin

g O

rgan

ism

s

Ad

sorp

tion

of

PP

CP

Sel

ecti

ve

Wast

e of

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Fo

rmers

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ecti

ve

for

An

am

mox

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eria

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ecti

ve

for

Gra

nu

lar

Act

ivate

d S

lud

ge

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ecti

ng f

or

Ret

ain

ing A

na

mm

ox

Bact

eria

in

Main

Str

eam

usi

ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Mem

bra

ne

Bio

react

or

Activated Sludge Time-line

June 24, 2018

Page 11: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

ge

Pro

cess

an

d N

itri

fica

tion

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h-R

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ivate

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ect

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ecti

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ecti

ve

for

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am

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for

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nu

lar

Act

ivate

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ge

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ng f

or

Ret

ain

ing A

na

mm

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Bact

eria

in

Main

Str

eam

usi

ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Mem

bra

ne

Bio

react

or

Adap

t to

Tre

atm

ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

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emic

als

June 24, 2018

Page 12: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

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lud

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Pro

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ve

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am

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ve

for

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nu

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ivate

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ecti

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or

Ret

ain

ing A

na

mm

ox

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eria

in

Main

Str

eam

usi

ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Adap

t to

Tre

atm

ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

-Ch

emic

als

Mem

bra

ne

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react

or

June 24, 2018

Page 13: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

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Pro

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ycl

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Adap

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Wast

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etro

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June 24, 2018

Page 14: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

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lud

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Pro

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mm

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eria

in

Main

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ng C

ycl

on

es

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Adap

t to

Tre

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ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

-Ch

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Mem

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ne

Bio

react

or

June 24, 2018

Page 15: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

ge

Pro

cess

an

d N

itri

fica

tion

Hig

h-R

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ivate

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Exp

lod

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f N

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ect

for

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itri

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for

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osp

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trop

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ati

on

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sorp

tion

of

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ve

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Form

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ve

for

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am

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ve

for

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nu

lar

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ng f

or

Ret

ain

ing A

na

mm

ox

Bact

eria

in

Main

Str

eam

usi

ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Adap

t to

Tre

atm

ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

-Ch

emic

als

Mem

bra

ne

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react

or

June 24, 2018

Page 16: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

ge

Pro

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an

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tion

Hig

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or

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in

Main

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t to

Tre

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ent

of

Ind

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Wast

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ch a

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etro

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als

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react

or

June 24, 2018

Page 17: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

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lud

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an

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itri

fica

tion

Hig

h-R

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ge

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ect

for

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ge

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ecti

ng f

or

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na

mm

ox

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eria

in

Main

Str

eam

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ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Adap

t to

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ent

of

Ind

ust

rial

Wast

e su

ch a

s P

etro

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als

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bra

ne

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react

or

June 24, 2018

Page 18: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

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lud

ge

Pro

cess

an

d N

itri

fica

tion

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ate

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ge

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ect

for

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ect

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um

ula

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for

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mm

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eria

in

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ng C

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1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

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ent

of

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rial

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June 24, 2018

Page 19: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

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lud

ge

Pro

cess

an

d N

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ate

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ng C

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1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

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ent

of

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ch a

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June 24, 2018

Page 20: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

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lud

ge

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cess

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in

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ycl

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Adap

t to

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ent

of

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ch a

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Sid

e-S

trea

m E

BP

R

-M

ore

late

r

June 24, 2018

Page 21: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

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Pro

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Hig

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lar

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ng f

or

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ain

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nam

mox

Bact

eria

in

Main

Str

eam

usi

ng C

ycl

on

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Adap

t to

Tre

atm

ent

of

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ch a

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etro

-Ch

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als

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e-S

trea

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-M

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June 24, 2018

Page 22: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Act

ivate

d S

lud

ge

Pro

cess

an

d N

itri

fica

tion

Hig

h-R

ate

Act

ivate

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lod

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f N

ew P

lan

ts i

n U

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ect

for

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fica

tion

Sel

ect

for

Ph

osp

hate

Acc

um

ula

tin

g O

rgan

ism

s

Ad

sorp

tion

of

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CP

Sel

ecti

ve

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e of

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Form

ers

Sel

ecti

ve

for

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am

mox

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eria

Sel

ecti

ve

for

Gra

nu

lar

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ivate

d S

lud

ge

Sel

ecti

ng f

or

Ret

ain

ing A

nam

mox

Bact

eria

in

Main

Str

eam

usi

ng C

ycl

on

es

1914 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2014

Adap

t to

Tre

atm

ent

of

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ust

rial

Wast

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ch a

s P

etro

-Ch

emic

als

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trea

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R

June 24, 2018

Page 23: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Eutrophication and Water

Quality for Re-use

June 24, 2018

Page 24: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Town of Brits

Indirect Re-use.

Most influent

from the JHB

Northern Works

1970

June 24, 2018

Page 25: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

Google Earth

700 km Alternative supply

Namibia – Direct Water

re-use

June 24, 2018

Page 26: Biological Nutrient Removal - Quo Vadis · BNR Wastewater Treatment only 30 Switching one lamp to low energy fixtures 102 Pumping water from north to south of California 355 Lack

The Demise of Activated

Sludge 1970?

1970

Was the activated sludge process reliable enough for nutrient removal?

June 24, 2018

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Replace with Tertiary High Lime

and Ammonia Stripping

Lake Tahoe – Right and Pretoria Left

June 24, 2018

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Or Clinoptilolite Ion Exchange

for Ammonia Recovery

June 24, 2018

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Development of BNR

Changed Perceptions

Removal of N&P without chemicals

Remove PPCP

Remove many industrial compounds

Low energy use

June 24, 2018

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Variations of Phoredox Process

L e g e n d

(A) (B)

(C) (D)

Anaerobic Anoxic Aerobic

Millbury noted that all plug-flow

plants released phosphorus at the

inlet side of the aeration basinJune 24, 2018

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Side-stream EBPR

June 24, 2018

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Putting low TP in

perspective

Point SourcesDiffused Sources

0.1 mg/L

6 mg/L

Can these costs be used more

effectively reducing Diffused

June 24, 2018

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Boise – Dixie Drain

• Alternative approach to remove residual phosphorus from WWTP

• Low cost P removal in BNR plant of 93% of influent TP

• Removing remainder would be costly due to high chemical demand

• Cheaper to remove 150% of residual from a drain with high P content flowing

into the same river

• Metal/P molar ratio is less at higher P concentration

• The result is an improvement of environment, lower cost, lower GHG

June 24, 2018

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Lay-out of Dixie Drain

June 24, 2018

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Water re-use –

Important issues

June 24, 2018

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World’s 1st

Potable re-use

at Windhoek Namibia

June 24, 2018

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NITROGEN REMOVAL PROBLEMS

REQUIRED ADDITION OF AN

ACTIVATED SLUDGE PLANT

BNR

plant

Intermediate

Ponds

June 24, 2018

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Ruhr – Indirect re-use

River Ruhr receives treated

wastewater from 2.1 Mio. inhabitants

River Ruhr receives treated

wastewater from 0.4 Mio. PE from

industry

River Ruhr serves as raw water

source for drinking water supply for

4.6 Mio. inhabitants (plus industry)

Source: Ruhrverband, Essen

all WWTP with full nutrient removal,

discussion on the elimination of

micropollutants is on the way

June 24, 2018

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ACTIVATED SLUDGE FOR

INDIRECT RE-USE IN ZIMBABWE

Needed even in Developing countries

June 24, 2018

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NITRATES ARE BENEFICIAL

Recent studies showed that nitrates discharged to lake has

benefits – Cubas et al Wat Res, Feb. 2014June 24, 2018

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SOME REWARDS

WW&T April 2018

Source: Chesapeake Bay ProgramPhase 4.3 Watershed Model 2005

June 24, 2018

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Recuperation of Lake

Paranoa

June 24, 2018

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The activated sludge

process as barrier for

undesirable chemicals for

DPR

June 24, 2018

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Future Health Concerns –

EDCs, PPCPs…….

Aka: Microconstituents or micropollutants

Most likely a wastewater treatment issue

Source control, product modification?

EDC PPCP

COEC

June 24, 2018

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Removal of PPCPs

June 24, 2018

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Trends to Smaller Footprint

and Energy Efficiency

Step-feed nitrification/denitrification

Integrated Fix Film Activated sludge

Membrane Bio-reactors

Stacked SBR

Granular sludge – SBR addition flow through

Selectors for improving SVI

Anammox for MainstreamJune 24, 2018

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Reduced Footprint

June 24, 2018

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Selective wastage &

Low SVI

June 24, 2018

Surface

wasting

Satellite

Clarifier

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Granule formation

June 24, 2018

SVI dropped to 20 mL/g

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Granular Activated Sludge

Sludge is wasted from

the top layer.

Possible WERF project

to look at other forms

of selection

• LT 40% of footprint

• LT 60% of power

• Simple operation

• No mixers

• No recycle pumps

June 24, 2018

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Granular Activated Sludge

June 24, 2018

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Epe - Netherlands

June 24, 2018

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NEREDA: One -Tank Process forBiological Nutrient Removal

Total N < 5 mgN/l; total P < 0.5 mgP/l70 % less space; 30 - 40 % lower energy;

25 % lower investment

10 plants build since 2012

Approx. 20 under design

June 24, 2018

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•95-99% magnetite recovery reported

BIOMAGTM

BALLASTED FLOC

SYSTEM

June 24, 2018

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• anaerobic

WHAT IS ANAMMOX?

• First documented in the Netherlands in 19901

• Several species of bacteria

Micrograph by Helen Markewich

oxidationammonium

June 24, 201859

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1.7 gO/gN

0 gC/g N

Makes N recovery less

cost effective

SIDE-STREAM N REMOVAL

ANAMMOX PROCESS

Paques presentationJune 24, 2018

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Mainstream Anammox -

Strass

June 24, 2018 Wett et al 2010

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Energy self-sufficiency

June 24, 2018

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WERF ENER1C12 – ENERGY EFFICIENCY

AND PRODUCTION

End product is a practical tool for use to monitor and manage energy

June 24, 2018

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Comparative Energy Use

Energy used for kWh/c/a

BNR Wastewater Treatment only 30

Switching one lamp to low energy fixtures 102

Pumping water from north to south of California 355

Lack of switch in my office 250

Household per person (2 persons) 14,000

Prof Helmut Kroiss – Our first obligation is to produce the

quality of effluent required then look at energy cost

June 24, 2018

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Wastewater Sector Energy

Recovery Estimates (from WERF ENER6C13)

• There is more energy in wastewater than is needed for

treatment – about 5X more

• Total primary energy potential is 851 trillion BTU/year,

80% of which is thermal energy

Chemical

<1% Hydraulic

Thermal

80%

20%

June 24, 2018

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Strass Plant Austria

• Produces 8% more energy than it consumes

• Effluent Ammonia varies – Design < 14 TN

• Removed no Phosphorus

• SVI enhanced with cyclone selectorsJune 24, 2018

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June 24, 2018

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GHG increase with lower N&P

Falk 2013 WERF Project on SustainabilityJune 24, 2018

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Nitrogen recovery

Only viable if less energy is used than fixing Nitrogen from the atmosphere

Haber-Bosch process uses about 12 kWh/kg nitrogen fertilizer

June 24, 2018

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Gulf of Mexico Hypoxia Action Plan

Aims to reduce size of Hypoxic Zone

Goal: 30 percent reduction in nitrates in next 15 years

90 percent of nitrates are non-point, primarily agricultural

Riverine constructed wetlands possible treatment approach

June 24, 2018

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Denitrifying Wood Chip Beds at Tile

Field Exits

Denitrifying woodchip bioreactor and phosphorus filter pairing to minimize pollution swapping Christianson et al Wat. Res. 121,

2017

June 24, 2018

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Drainage Water Management

Subsurface drains enhance nitrate losses

42.9 kg/ha as opposed to non-drained

watershed at 7 kg/ha (Goswani et al., 2009)

Upper IL and IA USDA report (1897)

estimated that 85% of farm-field drainage

from tile fields.

Can be managed by restricting flow at

times, allowing more time for denitrification

(Kieser & Associates)

Best applied to flat slopes

Adjust drainage outlet level following

harvest to bring water table closer to

surface, even allow ponding

According to one study, reductions can

range from 17 -94% (Skaggs and Youssef, 2008 from report by

Kieser & Associated)

Implementing on all suitable corn land in

Miwest could reduce 83 m kg/year.

Maximum possible reduction on all drainage

to Gulf 6.4% (Jaynes et al., 2010)

Kieser & Associates

June 24, 2018

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Denitrification Water Treatment

Facility Concept

Target 100 MGD (Max Flow) Unit Facility

Side-Stream Diversion

Low-Head Pumping

Hydrological Analysis

How Many Facilities

Where to Locate

Meet 30% Nitrate Reduction

June 24, 2018

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Creek

Diversion Structure

Influent

Methanol Feed as Carbon Source

115 ftCascadeAerator

Depth 13 ft1 .

Effluent

SAPBR

100 MGD SAPBR – Most Cost

Effective

100 mgd Pump Station

June 24, 2018

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Estimated Cost for 100 MGD

SAPBR Denitrification Unit

Capital Cost $13,210,000

Annual Amortized (30 years @ 4%) $845,638

Annual Operating Cost $2,482,379

Total Annual cost $3,328,017

Nitrates Removed per Year 1248 tonnes

Cost per Tonne $2,330

Pumping Cost per Tonne $ 1,413

Total $ SAPBR $3,744

Total $ Nutrient Farm $3,907

June 24, 2018

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Phosphorus recovery

June 24, 2018

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Future Scenarios

Towards global phosphorus security: A systems framework for phosphorus recovery and reuse options D. Cordell, A.

Rosemarin, J.J. Schröder , A.L. Smit - Chemosphere 84 (2011) 747–758

June 24, 2018

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The first step

June 24, 2018

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Activated sludge process

allows recovery of struvite

Struvite

Mg.NH4.PO4. 6 H2O

Also recovers up to 20%

of nitrogen

June 24, 2018

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100% Recovery of Incinerator P

Noord-Brabant, Holland

June 24, 2018

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The Ultimate Nutrient Recycle

June 24, 2018

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Urine recovery

Urine contains 70% to 80% of the Nitrogen and Phosphorus in domestic wastewater

When urine is separated and stored ammonia is hydrolyzed and the pH goes up

Within a few weeks the urine is totally free or pathogens

Research underway to recover struvite

Excess ammonia recovered with stripping and production of ammonia sulphate

June 24, 2018

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Backyard garden

Kampala Uganda

June 24, 2018

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Apartments in Hong Kong

June 24, 2018

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By Choice or by Need

Working in the garden is also a shared experience for the family, and instills in children an understanding of the natural cycles of growth which provide lessons of lifelong value

June 24, 2018

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Future vegetable gardens?

June 24, 2018

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• Over a century the activated sludge process has proved to protect receiving water bodies

• The activated sludge process keeps evolving with more energy efficiency

• Recovery of nitrogen needs to be cost effective

• Phosphorus ore is in limited supply and all efforts to recover phosphorus should be made

• Granular activated sludge has a future in the scheme of things

• Energy efficiency is important but energy self-sufficiency should not be the only goal

• Eventually we have to address the Gorilla in the room

FINAL MESSAGES

June 24, 2018

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MOTTO OF THE DAY

What doesn´t kill you makes you stronger !!!!!!!!

June 24, 2018

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Do unto those downstream as you

would have those upstream do unto you

The First Commandment According to Wendell Berry

June 24, 2018

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June 24, 2018