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    BENCHMARK FOR DEEMED-TO-SATISFY RULES (XD, XS)

    FORfib-CONGRESS February 2014 MUMBAI

    Greve-Dierfeld, S. vonformer Materials Science and Testing (MST), TU Muenchen, Baumbachstr. 7, 81245 Muenchen,Germany.

    Gehlen, Ch.Chair of Materials Science and Testing (MST), TU Muenchen, Baumbachstr. 7, 81245

    Muenchen, Germany.

    Abstract

    The current system for specifying and ensuring durability of new concrete structures in standards is

    commonly of a prescriptive type. In prescriptive specifications, durability is guaranteed indirectly

    by ensuring compliance with limiting values for concrete composition and construction details.

    These empirical provisions have typically evolved from local experience and the local

    availability of concrete constituents. They are based on the individual preferences on safety without

    any type of mathematical or scientific verification. One of the practical results is that there is an

    enormous variation in requirements between the various countries all over the world and even in

    Europe when close regional proximity is given. However, the different national provisions cannot

    be explained on a rational basis and it is likely that they do not lead to a consistent exposure

    resistance.

    The aim of this work is to perform a benchmark for deemed-to-satisfy rules for the exposure

    classes XD and XS. Within the benchmark it is determined which reliabilities against chloride-

    induced depassivation of rebars can be expected if the deemed-to-satisfy rules of different countries

    are considered. This includes not only calculations mainly based on short term laboratory data, but

    also an independent assessment of existing structures.

    The calculated reliability ranges determined are compared with the target reliabilities proposed by

    current specifications and, based on the above comparison, a proposal for improving deemed-to-

    satisfy rules and specifications is made.

    Keywords: Durability, deemed-to-satisfy rules, performance based rules, chloride, reliabilitydesign, assessment of existing structures

    1

    Introduction

    In prescriptive specifications durability with respect to chloride induced corrosion is guaranteed by

    ensuring compliance with limiting values for:

    - maximum w/c-ratio, minimum cement content, limits on the permitted types of cement andtheir components and / or limits for the compressive strength, together with

    - a minimum concrete cover mostly combined with an allowed tolerance, both in dependenceof

    - exposure class, giving the classified degree of severity of the environmental load.Although globally these limiting values vary over a wide range of values and although these

    values are often combined differently, they all follow the same goal: provide enough resistance in

    order to avoid chloride induced corrosion with sufficient reliability.

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    Hence, one aim of the benchmarking was to determine whether the limiting values and their

    various combinations fulfil the target reliabilities of current specifications. In order to verify the

    reliability provided by the deemed-to-satisfy rules, the initial goal was to

    -identify those prescriptive values that mainly affect the material performance and to relatematerial performance (under constant, standardized conditions) to the prescriptivespecifications.

    -transfer the definitions of the exposure classes in meso-climatic environmental loads in orderto describe the material performance under exposure.

    2 Background: model, parameters and data used for the benchmark

    task

    2.1Mathematical model

    Diffusion, permeation and convection are the means by which chlorides penetrate concrete.

    Assuming, diffusion to be the prevailing transport process, the following mathematical expressionis used to describe the rate at which chlorides penetrate the concrete, Eq. (1).

    =

    =

    t

    tD(t)Dwitht

    C

    C1erf)t(D2t)x(C, 00app

    s

    1-

    app (1)

    Here x in [m] is the depth with a defined critical chloride content (C = Ccrit) at time t, Cs is the

    chloride surface concentration [wt.%/cement],Dapp(t)in [m2/s] is the apparent diffusion coefficient

    at time t [s],D0is the diffusion coefficient measured at a reference time t0and in [-] is the agingexponent, giving the decrease over time of the apparent diffusion coefficient.

    This is a simple transformation of the well-known expression, where the chloride content

    C(x,t)[wt.%/cement] at depthxand time tis given by Eq. (2).

    t)t(D2

    xerfC)t,x(C

    app

    s

    = (2)

    The initial chloride content (Ci) can be included in both the above equations (ISO 16204, 2012).

    One can conclude that the rate at which chlorides penetrate concrete is governed by the diffusivity

    of the concrete (material) and concentration of the chloride load (environment).

    2.2 Data

    Material

    The apparent chloride diffusion coefficient is used to describe the diffusivity of the concrete. Insaturated concrete, the apparent diffusion coefficient is mainly controlled by the pore structure

    (amount, size and tortuosity) and is less affected by ionic interactions.

    Usually, the chloride diffusion coefficients for specific concrete compositions are either

    determined in accelerated tests or in short term tests both under different experimental condition.

    Mostly, non-steady-state diffusion coefficients are determined. In the accelerated tests methods,

    migration coefficients are determined by accelerating the chlorides in an electric field, where

    transport by diffusion is negligible (e.g. NT BUILD 492, 1999), or the diffusion coefficients are

    determined with increased chloride concentrations (e.g. NT BUILD 443, 1995). In short term tests,

    diffusion coefficients are determined under natural chloride load (e.g. DD EN/TS 12390-11,

    2010). The migration coefficient is assumed to correlate well with the diffusion coefficients at early

    ages (Tang et al. 2010, Gehlen, 2000, Tang, 1996).

    In Fig. 1 (left) a summary of migration coefficients (t0= 28 d) in dependence of the type ofcement and w/c-ratio is given since these two parameters strongly affect the pore structure of the

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    concrete. The amount of binder, providing a minimum for sufficient compaction is guaranteed, as

    well as by the type, shape and size of aggregate are less important (Lay & Schiel, 2002). The

    migration coefficients where derived from (Bjegovic et al., 2012, Heinz et al., 2011, Mller &

    Severins, 2009, Mller et al., 2009, Visser & Nijland, 2009, Gruyaert et al., 2009, Wiens, 2005,Lay & Schiel, 2002, Gehlen, 2000, Chrisholm & Lee, 2001). In Fig. 1 (right) the correlation

    between chloride migration coefficient and chloride diffusion coefficient according to (NT BUILD

    443, 1995) and (DD EN/TS 12390-11, 2010) is shown (Tang et al., 2010).

    Fig. 1 Chloride diffusion coefficient at time t0= 28 d (left), correlation between chloride migration and

    chloride diffusion coefficient (Tang et al, 2010) (right).

    In Fig. 1 the symbols represent the mean value of the chloride migration coefficients determined by

    various authors. An exponential function was fitted to the mean values. Due to the random scatter

    for CEM II/A,B-LL, CEM II/A,B-V and CEM III/A,B (A: full symbols, B: empty symbols) one

    curve was fitted to both cement clinker contents (A and B).

    In Fig. 1 (left) it can be seen that chloride migration coefficients increase exponentially with

    w/c-ratio. At the same w/c-ratio, concretes with high contents of ground granulated blast-furnace

    slag (GGBS) show low chloride migration coefficients due to their low porosity (CEM III).Generally, the chloride migration coefficients decrease continuously from 30 wt.% GGBS content

    up to 50 wt.% GGBS (Lay & Schiel 2002). Concretes with silica fume (SF) (CEM II/A-D)

    possess low chloride migration coefficients mainly due to the beneficial filler effect of SF. The

    same holds for concretes with fly ash (FA) (CEM II/A-V, CEM II/B-V), but with less effect. The

    highest chloride migration coefficients are possessed by concretes with limestone (LS) which is

    due to the increased porosity - especially if more than 15 wt.% is used (Lay & Schiel, 2002).

    CEM I concretes show slightly lower migration coefficients than CEM II/A,B-LL concretes.

    The chloride diffusion coefficient decreases due to ongoing hydration and reaction products

    that lead to changes in the pore structure. The decrease in chloride diffusion coefficient is

    represented by the aging exponent.

    The aging exponent under constant saturated conditions is mainly affected by the type of

    cement and its components (Gehlen, 2000). Ordinary Portland cement concretes (OPCC), andconcretes with components like LS (CEM II/A, B-LL), SF (CEM II/A-D) or low contents of GGBS

    (CEM II/A, B-S) have the lowest aging exponents ( ~ 0.30), due to the negligible ongoinghydration and the low binding capacity. Higher aging exponents are possessed by concretes with

    higher amounts of GGBS (CEM III) due to the ongoing latent hydraulic reaction and the higher

    binding capacity ( ~ 0.45). Concretes with fly ash (CEM II/A, B-V) show the highest aging

    exponent due to the ongoing puzzolanic reaction and the high binding capacity ( ~ 0.60). Thevalues for the ageing exponents given are derived from (Caballero et al., 2010, Polder et al., 2010,

    Markeset & Skjlsvold, 2010, Nokken et al., 2006, Stanish & Thomas, 2003, Gehlen, 2000).

    Taking into consideration aging behaviour of different types of cement: concretes with lower

    resistances (with higher migration coefficients or diffusion coefficients, respectively) determined inshort-term tests may have a higher long-term resistance. Thus, from the migration coefficients of

    Fig. 1, the apparent diffusion coefficients at time t = 50 years where calculated with the aging

    0

    5

    10

    15

    20

    25

    30

    0.4 0.45 0.5 0.55 0.6

    DRCM

    [10-12m2/s]

    w/c-ratio [-]

    CEM II/A,B-LL

    CEM I

    CEM III/A,B

    CEM II/A,B-V

    CEM II/B-S

    CEM II/A-D

    05

    10

    15

    20

    25

    30

    0 5 10 15 20 25 30

    Dapp

    (t0

    )[10-12m/s]

    DRCM(t0) [10-12 m/s]

    prEN/TS 12390-11

    NT BUILD 443

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    function (Eq. (1) right) and the aging exponents for the specific type of cement introduced above,

    see Fig. 2.

    Fig. 2 Apparent chloride diffusion coefficients at time t= 50 years, calculated for the cement types of Fig.

    1 (left) using Eq. (1) (right) and the aging exponents introduced above.

    Environment

    The chloride surface concentration strongly affects the concentration gradient. The chloride surface

    concentration under saturated conditions depends on the chloride concentration of the ambient

    solution as well as on the adsorption and binding capacity of the concrete. Especially under

    immersed conditions, the chloride surface concentration is affected by the type of cement. The

    surface concentration of concretes with GGBS or FA is increased due to their higher binding

    capacity (higher C3A, C4AF contents). For concretes with OPC or additives like SF, the chloride

    surface concentration is decreased due to the lower binding capacity. Furthermore, the chloride

    surface concentration increases with increasing w/c-ratio (adsorption). The amount of binder has

    less effect.

    The environmental load is loosely defined in the exposure classes by the description of the chloridesource and humidity conditions. The effect of chloride load on material performance is governed

    by the chloride surface concentration Cs. The effect of moisture content is included in the surface

    concentration Csand the aging exponent .The chloride surface concentration under real exposure conditions is subject to systematic

    spatial variations documented in dependence of the distance of the concrete surface to the chloride

    source in urban (DARTS 2004) as well as marine environments (Markeset & Skjlsvold, 2010,

    Helland et al., 2010, Wall, 2007, Nokken et al., 2006, Ghods et al., 2005, Fluge et al., 2001), Fig. 3.

    Herein, our own data (black symbols) is included derived from four car parks in Munich (XD3) and

    from exposed specimens in Helgoland (XS3). In Fig. 3, the chloride surface concentration

    determined from field exposure (meso-climatic conditions) is shown in dependence of the distance

    to the chloride source to the concrete surface and related to the exposure classes.

    Fig. 3 Chloride surface concentration in dependence of the distance to chloride source for urban (DARTS,

    2004) (left) and marine environments (Markeset & Skjlsvold, 2010, Helland et al., 2010, Wall, 2007,

    Nokken et al., 2006, Ghods et al., 2005, Fluge et al., 2001) (right) meso-climatic conditions both in wt. % percement.

    0

    1

    2

    3

    4

    5

    0.4 0.45 0.5 0.55 0.6

    Dapp

    (t=50)[10-12m

    2/s]

    w/c-ratio [-]

    CEM II/A,B-LL

    CEM I

    CEM III/A,B

    CEM II/A,B-V

    CEM II/B-S

    CEM II/A-D

    0

    1

    2

    3

    4

    5

    6

    0 1 2 3 4 5

    Chloridesurface

    concentration[wt.%/c.]

    Distance to chloride source [m](height above road)

    XD1

    XD2

    horizontal distancefrom road:

    0.5 m

    2.0 m

    carprarks

    XD3

    0

    1

    2

    3

    4

    5

    6

    -5 0 5 10 15 20 25

    Chloridesurface

    concentration[wt.%/c.]

    Distance to chloride source [m]

    XS1XS3XS2

    < MLT ~ wave crest

    CEM I+FA

    CEM I

    CEM I

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    In Fig. 3 (left) for wet, rarely dry conditions (XD2) no systematic spatial variability is considered.

    For cyclic wet and dry conditions (XD3) and in moderate humidity (XD1), a constant decrease with

    the distance to the chloride source occurs.

    In Fig. 3 (right) for permanently submerged conditions (XS2) no systematic spatial variabilityis reported. The chloride surface concentration corresponds with the salinity of the ambient

    solution. For tidal and splash zone (XS3), the chloride surface concentration decreases rapidly with

    the distance to the chloride source. In the spray zone (XS1), a further decrease in chloride surface

    concentration occurs. Furthermore, it can be seen that differences due to chloride binding and

    adsorption in the exposure classes XS3 and XS1 disappear against the background of random

    spatial variability.

    The effect of humidity is empirically included in the lower surface concentration and is partly due

    to the reduced adsorption. Furthermore, the diffusion process is reduced in partly saturated concrete

    (spray zone: XD1, XS1), which results in an increased aging exponent (Fig. 4). The degree of

    saturation in dependence of relative humidity decreases with increasing pore radius. Because of

    this, higher differences in the aging exponents for OPCC (more dry) concretes are reported, smallerdifferences are reported for FA concretes (less dry) see Fig. 4 (cf. left with right). The aging

    exponents in Fig. 4 are taken from (Caballero et al., 2010, Polder et al., 2010, Markeset &

    Skjlsvold, 2010, Nokken et al., 2006, Stanish & Thomas, 2003, Gehlen, 2000).

    Fig. 4 Aging exponents for nominally saturated conditions (XS2, XS3, XD2, XD3) (left) and partly

    saturated conditions (XS1, XD1) (right) from (Caballero et al., 2010, Polder et al., 2010, Markeset &

    Skjlsvold, 2010, Nokken et al., 2006, Stanish & Thomas, 2003, Gehlen, 2000).

    Furthermore, it is known, that temperature affects binding capacity and ion mobility and hence the

    diffusion process. The effect of temperature on the diffusion coefficient is accounted for by the

    Arrhenius function with the regression parameters given in (fib, 2006).At least, deviations from Ficks second law of diffusion for example due to leaching,

    capillary suction and interactions with effects like carbonation in the exposure classes XD3, XS3

    have to be taken into consideration. One possibility is to use an apparent chloride surface

    concentration calculated for the surface at x = 0. Another possibility is to use the highest chlorideconcentration (Cs,x) in the depth xand to deduct the depth xfromx, as applied here.

    Summary

    The prescriptive values minimum w/c-ratio and recommendations with respect to the type of

    cement and its components are the decisive parameters that govern material resistance. The

    cement content, provided a minimum for sufficient compaction is guaranteed, is of less

    importance. The effect of compressive strength is already given by the w/c-ratio and may be

    regarded as supplementary control measure.

    An increase in w/c-ratio leads to an increased chloride diffusion coefficient and higher

    chloride surface concentrations. In contrast, types of cement which yield low diffusion coefficients

    lead to high chloride surface concentrations and vice versa. Furthermore, the effect of cement type

    0.0

    0.2

    0.4

    0.6

    0.8

    1.0

    CEM I

    (+ LL, S, D)

    CEM I

    (+ FA)

    CEM III

    ageexponent

    [-]

    0.0

    0.2

    0.4

    0.6

    0.8

    1.0

    CEM I

    (+ LL, S, D)

    CEM I

    (+ FA)

    CEM III

    ageexponent

    [-]

    XD2, XD3, XS2, XS3 XD1, XS1

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    on material performance is strongly time dependent. Type of cement with low diffusion

    coefficients at young ages may possesses higher diffusion coefficients at higher ages.

    3

    Benchmarking

    3.1 Selection of countries

    Regarding material performance under immersed conditions (more or less constant), the w/c-ratio

    and the type of cement are the decisive parameters that affect material performance. Regarding

    material performance under exposure, the decisive parameters are the location (distance to chloride

    source, humidity condition and the chloride content of the ambient solution) to be taken into

    account when selecting a country.

    Thus for the selection of countries, i.e. the respectively national specifications, the following was

    considered:

    I. diversity in deemed-to-satisfy rules: w/c-ratio, cover, types of cement and the diversity in

    construction practice given by the local availability of specific types of cementII. diversity in environmental load (exposure class definition, salinity of seawater,

    temperature conditions and frequency of de-icing salt application)

    Point I: a significant diversity in deemed-to-satisfy rules in comparison with EN 1992-1-1/EN 206-

    1 (EN 1992-1-1, 2002, EN 206-1, 2001) may be found when considering Australia (AUS), United

    States of America (USA), Portugal (P), Spain (E) and Great Britain (GB), the Netherlands (NL),

    Germany (D), Denmark (DK) and Norway (N). The variety of permitted types of cements and their

    combination with w/c-ratio and / or cover are summarized in Table 1.

    Table 1Diversity in deemed-to-satisfy rules for structures exposed to chloridesCountry Diversity in deemed-to-satisfy rules and permitted types of cement

    Spain (E) CEM III, CEM IV,

    CEM II/B-S, B-P, B-V, A-D combined

    with a lower cover for one w/c-ratio

    Others

    combined with a higher cover for

    one w/c-ratio

    Portugal (P) CEM II/A-D, CEM II/B, CEM III/A, CEM

    III/B, CEM IV/A, CEM IV/B, CEM Vcombined with a higher w/c-ratio for one

    cover

    CEM I, CEM II/A

    combined with a lower w/c-ratio forone cover

    Great Britain (GB) Groups of types of cement combined with w/c-ratio correlated with cover

    The Netherlands (NL) All types of cement; One cover and w/c-ratio within each exposure class

    Germany (D) All except: CEM II/B-LL, CEM II/B-L, CEM II/A-W, CEM II/B-W, CEM

    IV/A, CEM III/C{1}, one cover and w/c-ratio within each exposure class

    Denmark (DK) XD1, XS1, XS2:CEM I, CEM II/A-L, CEM II/A-LL and

    CEM II/A-V

    XS3, XD2, XD3:CEM I and CEM II/A-V

    One cover and w/c-ratio within each exposure class

    Norway (N) XD1, XS1:CEM I, CEM II/A-S, CEM II/B-S, CEM

    II/A-D, CEM II/A-V, CEM II/B-V, CEM

    III/A

    XD2, XD3, XS2, XS3:CEM I + 4 M.% SF/c., CEM II/A-

    S, CEM II/B-S, CEM II/A-D, CEM

    II/A-V, CEM II/B-V, CEM III/A

    One cover and w/c-ratio within each exposure class

    United States of America

    (USA)

    All, except LS or GGBS contents > 70 % (Beushausen & Fernandez, 2011)

    One cover and w/c-ratio within each exposure class

    Australia (AUS) No recommendations on type of cement and w/c-ratio: durability is verified

    with respect to compressive strength combined with cover

    {1}Not considered in exposure classes XD2 and XS2

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    In the Netherlands traditionally concretes with BFSC are preferred. In Germany preferably CEM II

    concretes are used. In Norway concretes with additives like SF of FA are favoured.

    Point II: while in P, GB, NL, D, DK and N the exposure classes (European definition: XD and XS)are applied as defined in (EN 1992-1-1, 2002), in AUS, USA and E exposure classes are defined

    individually. Especially in AUS the class definition is not identical with the European definition,

    which leads to an overlap of the classes. The salinity of oceans is similar with ~35 g/L (except the

    Baltic Sea with a salinity of ~8 g/L). Temperature affects the mobility of ions and hence the

    diffusion rate, as well as the frequency of usage of de-icing salts. The temperature ranges from

    ~15C (E and P Southern Europe, AUS), ~10C (GB, NL, D Central Europe, USA) to ~8C

    (DK, N Northern Europe) mean annual temperature.

    Thus the following countries are considered, see Table 2. Herein, additionally the respective

    specifications are summarized.Table 2

    Selected countries and specifications taken into accountCountry Considered specifications

    Spain (E) EHE-08 (2008)Portugal (P) LNEC E 464 (2007), NP EN 206-1 (2007)

    Great Britain (GB) BS 8500-1 (2006), BS 8500-2 (2006), EN 206-1 (2000)The Netherlands (NL) NEN 8005 (2008), EN 206-1 (2000)

    Germany (D) DIN 1045-2 (2008), EN 206-1 (2000)Denmark (DK) DS/EN 1992-1-1 DK NA: 2011, DS 2426 (2011), EN 206-1 (2000)

    Norway (N) NS-EN 206-1 (2007), NS-EN 1992-1-1 (2008), NS EN 13670 (2010)United States of America (USA) ACI-318-08 (2008)

    Australia (AUS) AS 3600 (2009)

    In all countries, except USA, deemed-to-satisfy rules are provided for a design service life ofaround 50 years. In some countries additionally rules for a design service life of 100 years are

    given. In this publication resistances and reliabilities provided from deemed-to-satisfy rules were

    analysed for a design service life of 50 years.

    3.2Procedure

    Based on Table 1 and Section 2 the following may be concluded.

    I. All prescriptive specifications give freedom in choice of cement type. Some prescriptivespecifications give freedom in the choice of combined limiting values (E, P, GB). Hence,

    within one exposure class, a concrete composition with a lower resistance (low-resistance

    concrete) or a concrete composition with a higher resistance (high-resistance concrete)

    may be chosen (Fig. 2).

    II. Within one exposure class a high or low chloride load is possible (Fig. 3).Both I. and II. will result in different structural reliabilities (spectrum of reliabilities) within

    one exposure class. Therefore, the goal of this work was to determine the spectrum of reliabilities

    provided by choosing unfavourable design situations (lower reliability level) and favourable design

    situations (upper reliability level). Unfavourable design situations are characterized by a low-

    resistance concrete composition (type of cement and w/c-ratio) in combination with a high chloride

    load. Favourable design situations are characterized by a high-resistance concrete composition in

    combination with a low chloride load.

    The procedure to determine the levels of reliability is explained with the example of Germany

    exposure class XS3 in detail. The limiting values for the exposure class XS3 as stated in DIN 1045-

    2, 2008 are summarized in Table 3.

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    Table 3Limiting values (DIN 1045-2, 2008)

    Environ-

    mental load

    Material performance Structural

    performanceExposure

    class

    Minimum cement

    content [kg/m]

    Minimum

    w/c-ratio [-]

    Type of cement [-] Nominal concrete

    cover cnom= cmin+ c[mm]

    XS3 320 0.45 All except CEM II/B-LL, CEM II/B-L,

    CEM II/A-W, CEM II/B-W,

    CEM IV/A, CEM III/C

    55 = 40 + 15

    The nominal concrete cover is stated in the specification. The difficulty which arises is the question

    as to which type of cement in combination with maximum w/c-ratio yields the low-resistance

    concrete or the high-resistance concrete? Which chloride loads in combination should be selected?

    Fig. 5 Material performance in dependence of type of cement and w/c-ratio (left), chloride surface

    concentration in dependence of the exposure class (right).

    In Fig. 5 (left) it can be seen that a low-resistance concrete is provided by CEM II/A-LL. A high-

    resistance concrete is provided by CEM III/B, both with a minimum w/c-ratio of 0.45.

    In Fig. 5 (right) obviously a high chloride load occurs at a short distance from the chloride

    source and a low chloride load further from the chloride source.Based on the above considerations the unfavourable design situation was chosen for a CEM

    II/A-LL and a chloride surface concentration of 4.0 wt.%/c. The favourable design situation was

    chosen for a CEM III/B and a chloride surface concentration of 2.0 wt.%/c. Both with a w/c-ratio

    of 0.45.

    All the parameters, which have been described in detail in Section 2 with respect to their

    effect on material performance, are listed in in Table 4. In addition to the explanations in Section 2,

    all these variables are linked with uncertainties due to the inhomogeneity of material, execution

    quality, random temporal and spatial variability of the environmental conditions etc. In order to

    take these uncertainties into account each variable was described as a random variable with a

    distribution function and its distribution parameters (mean and standard deviation). These

    uncertainties were quantified as follows.

    Chloride diffusion coefficients are sufficiently described by a normal distribution (Gehlen,2000). The reproducibility is taken into account with a constant coefficient of variation of 0.4.

    According to (Gehlen, 2000), the aging exponent may be sufficiently described using a beta

    distribution with the boundary conditions 0 < < 1. For saturated conditions (XD2, XD3, XS2,XS3) the standard deviation was set to 0.12, 0.15 and 0.20 for CEM I, CEM II and CEMIII

    concretes, respectively. For dry conditions (XD1, XS1) the standard deviation was set to 0.12.

    The chloride surface concentration varies randomly due to variations in the chloride content

    of the ambient solution, frequency of use of de-icing salts, temporal and spatial variations in the

    humidity conditions of the concrete etc. The chloride surface concentration may be sufficiently

    described with a lognormal distribution. For urban environments (XD1, XD2 and XD3) a CoV of

    75% is documented in DARTS, 2004 because of the huge variability in frequency and amount of

    used de-icing salts. For submerged conditions in marine environments (XS2) a low CoV of 25 % is

    given which is mainly due to the inhomogeneity of concrete surfaces and the variation in

    composition of the ambient solution. With increasing distance to the chloride source (XS3, XS1),

    0

    1

    2

    3

    4

    5

    0.4 0.45 0.5 0.55 0.6

    Dapp

    (t=50)[10-12m

    2/s]

    w/c-ratio [-]

    CEM II/A,B-LL

    CEM I

    CEM III/A,B

    CEM II/A,B-V

    CEM II/B-SCEM II/A-D

    0

    1

    2

    3

    4

    5

    6

    -5 0 5 10 15 20 25

    Chloridesurface

    concentration[wt.%

    /c.]

    Distance to chloride source [m]

    XS1XS3XS2

    < MLT ~ wave crest

    favourable

    favourableunfavourable

    unfavourable

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    the random spatial variations increase from a CoV of 45 % (DARTS, 2004) up to 65% (Wall,

    2007).

    The concrete cover may be sufficiently described with a normal distribution. The mean

    concrete cover is the nominal concrete cover a which is the sum of minimal cover and an allowedtolerance. The standard deviation is independent of the mean value and is given by 9 mm (Gehlen,

    2000, JCSS, 1999).

    Information on the critical chloride content may be found for example in (Breit et al., 2011,

    Angst et al., 2009). The critical chloride content may be described by a beta distribution with mean

    of 0.6 and a standard deviation of 0.15 with a lower boundary of 0.2 and an upper boundary of 2.0.

    The reliability index was calculated according to Eq. 3, where the depth with a critical chloride

    content (C = Ccrit) is compared with the concrete cover a. Both are described as random variables

    (Ditlevsen & Madsen, 2005).

    ( ) { } ( )00crit.dep pa)t,C(xpp

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    Fig. 6 Reliability index versus design service life for the unfavourable and the favourable design situation.

    Reliability spectrum provided when following the recommendations of deemed-to-satisfy rules of German

    specification for XS3.

    3.3Reliability spectra

    This methodological approach was applied for each country and exposure class.

    In Fig. 7 a and b (left) the w/c-ratio and the concrete cover is given for each country and

    exposure class. Additionally, the favourable and unfavourable types of cement are stated which

    may be selected when taking into consideration the permitted types of cement of Table 1. In Fig. 7

    a and b (right) the reliability spectrum (bars) derived from the unfavourable and favourable design

    situation at the end of design service life (50 years) is shown for each country and exposure class.

    Fig. 7a Favourable and unfavourable type of cement, maximum w/c-ratio and minimum cover (left),

    reliability spectra (right).

    -2

    -1

    0

    1

    2

    3

    4

    0 10 20 30 40 50

    Reliabilityindex

    [-]

    Time t [a]

    CEM III/B

    favourable

    CEM Iunfavourable

    reliabilityspectrum

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    2

    3

    4

    0.3

    0.4

    0.5

    0.6

    0.7203040506070

    0.30.4

    0.5

    0.6

    0.72030405060700.3

    0.4

    0.5

    0.6

    0.7

    2030

    40506070

    XD1

    XD2

    XD3

    E P GB NL D DK N USA AUS

    Reliability index [-]

    w/c-ratio[-]

    cmin[mm]

    w/c-ratio[-]

    cmin[mm]

    w/c-ratio[-]

    cmin[mm]

    E P GB NL D DK N USA AUS

    CEMIII

    CEMI

    w/c = 0.45

    w/c = 0.60

    CEMI

    CEM III

    favourable CEM III/B, II/A-V

    unfavourable CEM I, II/A-LL

    favourable CEM III/B, II/A,B-V

    unfavourable CEM I , II/A-LL

    favourable CEM III/B, II/A,B-V

    unfavourable CEM I, II/A-LL, II/A-S

    CEMIII

    CEMI

    w/c = 0.4

    w/c = 0.55

    CEMI

    CEM III

    CEMIII

    CEMI

    w/c = 0.35

    w/c = 0.5CEMI

    CEM III

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    Fig. 7b Favourable and unfavourable type of cement, maximum w/c-ratio and minimum cover (left),

    reliability spectra (right), AUS: w/b ratios appraised from concrete strength requirements, exposure class C1was assumed to be equivalent to XS1, USA: concrete cover in dependency to bar diameter, cover tabled

    refers to bars of diameter ds> 19 mmThe lower reliability level (bottom of bars) results when selecting CEM I, CEM II/A-LL,

    CEM II/A-S cements. The upper reliability level (top of bars) results when selecting CEM III or

    CEM II/A,B-V cements.

    In all exposure classes, an increased cover (E) for low-resistance types of cements or the

    exclusion of low-resistance types of cement (N) leads to a narrower reliability spectrum. The same

    holds for a reduced w/c-ratio (P) for low-resistance types of cement, but with less effect. An

    increase in w/c-ratio of about 0.1 in combination with an increase of cover of about 10 mm yields

    no significant change in reliability spread (GB).

    The above reliability spectra were calculated with the listed data in Section 2. These

    calculations were subject to simplifications and effects that, strictly, are not taken into properconsideration. Some effects and simplifications are due to:

    -the variety of specific surface effects ,-neglecting the effect of discrete changes in diffusion coefficient during the design service life,-neglecting the time-dependent development of chloride surface concentration in the first five

    to ten years of exposure (Bioubakhsh, 2011, Markeset & Skjlsvold, 2010)

    -neglecting the effect of binding on the concentration gradient (Baroghel-Bouny et al., 2012)In order to quantify the effect of these simplifications, the reliabilities of some existing structures

    where checked.

    0.3

    0.4

    0.50.6

    0.7

    2030405060700.3

    0.40.5

    0.6

    0.7

    203040506070

    0.3

    0.4

    0.5

    0.6

    0.7203040506070

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    23

    4XS1

    XS2

    XS3

    E P GB NL D DK N USA AUS

    Reliability index [-]

    w/c-ratio[-]

    cmin[mm]

    w/c-ra

    tio[-]

    cmin[mm]

    w/c-ratio[-]

    cmin[mm]

    E P GB NL D DK N USA AUS

    CEMIII

    CEMI

    w/c = 0.35

    w/c = 0.55CEMI

    CEM III

    favourable CEM III/B, II/A-V

    unfavourable CEM I , II/A-LL

    favourable CEM III/B, II/A,B-V

    unfavourable CEM I, II/A-LL

    favourable CEM III/B, II/A,B-V

    unfavourable CEM I, II/A-LL, II/A-S

    CEMIII

    CEMI

    w/c = 0.4

    w/c = 0.55CEMI

    CEM III

    CEMIII

    CEMI

    w/c = 0.35

    w/c = 0.5

    CEMI

    CEM III

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    3.4 Verification by assessing existing structures

    By assessing existing structures, the in-field performance of the material was determined. In-field

    performance is given by measured chloride profiles and is used to

    - analyse whether the predicted chloride concentrations reflect the real behaviour.- verify the reliability spectra determined by reliability design with field reliability.

    MethodologyIn order to verify the model predictions all measured chloride profiles for individual structures

    where compared with the predicted performance represented by the calculated chloride profiles.

    Chloride contents were calculated for the specific design situation using Ficks second law (Eq.

    (2)). The model parameters where varied randomly in a Monte Carlo approach to yield chloride

    concentration distributions (50 % and 95% quantiles) at discrete depths (Ditlevsen & Madsen,

    2005).

    In order to verify the calculated reliability spectra in Figs. 7, the measured depth-dependent

    chloride contents where used to calculate the reliability at the end of design service life within a

    Bayesian update as is well-documented in (Ditlevsen & Madsen, 2005). This requires that the

    material composition on-site fulfils the requirements stated in the specifications.

    Field investigations

    Chloride profiles from structures older than 5 years where provided by the members of fib-TG5.11. In Table 5 the age of the investigated structural elements, the country, the related exposure

    class, the description of the location, the concrete composition (w/c-ratio and type of cement) as

    well as the cover required by the specific specification are summarized.Table 5

    On-site investigations fromfib-TG 5.11

    No. age[a]

    Coun-try

    Exposureclass

    Description of location Type of cement w/c-ratio[-]

    cmin[mm]

    1 5 P XS3 Setenave shipyards, Atlantic Ocean CEM I + 5 % SF 0.35 45

    2 18 NL XS3 Box girder bridge wall, North Sea CEM III/B 0.45 40

    3 6 D XS2 Specimens exposed to Eckenfrde, Baltic

    Sea (exposed specimen)

    CEM I 0.47 40

    4 6 XS2 CEM III/A 0.47 40

    5 6 XS3 Specimen exposed to wall of Eider barrage,

    North Sea (exposed specimen)

    CEM I 0.45 40

    6 6 XS3 CEM III/A 0.45 40

    7 30, 40 XS3 Wall of Eider barrage, North Sea

    (Osterminski & Gehlen, 2009)

    CEM I + 5 % trass 0.45 40

    8 12 DK XS3 Bridge pile CEM I + FA 0.38 35

    9 32 XS3 Bridge pile CEM I 0.40 35

    10 8 N XS2 Floating structure Troll B

    (Helland et al., 2010)

    CEM I +7 % SF 0.35 50

    11 5, 9 XS3 Floating structure Heidrun

    (Helland et al., 2010)

    CEM I + 5 % SF 0.39 50

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    Fig. 8 shows some of the locations.

    Fig. 8 Some of the locations investigated by fib-TG 5.11 (www.somague.pt, www.shz.de, www.

    eiderstedt.net, Helland et al., 2010).

    ResultsIn Figs. 9 (left) the measured chloride profiles from each field investigation are compared with the

    calculated chloride profiles. In Figs. 9 (right) the evolution of the reliability indices is shown as

    determined by reliability designs presented in Section 3.2 and 3.3. Furthermore, the field

    reliabilities are given. Here the field reliabilities are based on the measured chloride profiles and

    the concrete cover required by the standards.

    Fig. 9a Measured chloride concentrations and calculated chloride concentrations (left), reliability index

    versus time determined by reliability design and by assessing existing structures (right) Southern Europe.

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    Fig. 9b Measured chloride concentrations and calculated chloride concentrations (left), reliability index

    versus time determined by reliability design and by assessing existing structures (right) Central Europe.

    0

    2

    4

    6

    0 10 20 30 40 50 60 70 80

    tinsp = 40 years

    -2

    -1

    0

    1

    2

    3

    4

    0 10 20 30 40 50

    Reliabilityindexb[-]

    2

    4

    6No. 7

    tinsp = 30 years

    -2

    -1

    0

    1

    2

    3

    4

    0

    1

    2

    3

    4

    5

    6No.6

    -2

    -1

    0

    1

    2

    3

    4

    Reliability

    index

    [-]

    0

    1

    2

    3

    4

    5

    6No.2

    -2

    -1

    0

    1

    2

    3

    4

    Reliabilityindex

    [-]

    0

    1

    2

    3

    4

    5

    6No.3

    -2

    -1

    0

    12

    3

    4

    Reliabilityindex

    [-]

    0

    1

    2

    34

    5

    6No.4

    -2

    -1

    0

    1

    2

    3

    4

    Reliabilityindexb[-]

    0

    1

    2

    3

    4

    5

    6No.5

    Chloridecontent[wt.%/c.]

    Reliabilityindex

    [-]

    Depth x [mm] Time t [a]

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    Fig. 9c Measured chloride concentrations and calculated chloride concentrations (left), reliability index

    versus time determined by reliability design and by assessing existing structures (right) Northern Europe.

    In Figs. 9 it can be seen that the measured chloride profiles agree very well with the calculated

    chloride profiles. Furthermore, the field reliabilities are mostly higher than the ones determined by

    reliability design (No. 1, 2, 3, 4, 5, 6, 7, 10, 11). The field reliability is only lower for No. 8 and 9,

    where high chloride contents where measured. For structure No. 8, the performance of FA was

    overestimated because no information about the actual FA content existed. In the case of No. 10 the

    performance of SF was underestimated.

    3.5 Comparison and discussion

    In Fig. 10 the reliability spectra determined by the reliability design shown in Figs 8 (right) is

    reproduced. Here, the field reliabilities are added using symbols. The ranges of all reliabilities are

    marked by the grey beams.

    -2

    -1

    0

    1

    2

    3

    4

    0 10 20 30 40 50

    0

    2

    4

    6

    0 10 20 30 40 50 60 70 80

    tinsp = 9 years

    2

    4

    6No.11

    tinsp = 5 years

    -2

    -1

    0

    1

    2

    3

    4

    0

    1

    2

    3

    4

    5

    6No.9

    Chloridecontent[wt.%/c.]

    Reliabilityindex

    [-]

    -2

    -1

    0

    1

    2

    3

    4

    0

    1

    2

    3

    4

    5

    6No.10

    Depth x [mm]

    -2

    -1

    0

    1

    2

    3

    4

    0

    1

    2

    3

    4

    5

    6No.8

    Time t [a]

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    Fig. 10 Spectra of reliabilities provided by deemed-to-satisfy rules for a design service life of 50 years

    determined by reliability design (bars) and by assessing existing structures (symbols).In Fig. 10 it can be seen that the reliability spectrum is always broad, independent of the exposure

    class. The lower reliability level determined when selecting low-resistance types of cements is

    confirmed by the field investigations (CEM I). The same holds for the upper reliability level

    determined when selecting high-resistance types of cement (CEM III, CEM II/A-D). Therefore, it

    can be concluded that the wide spread of reliability within each exposure class results from the

    huge differences in material performance.

    In Fig. 10 it can be seen that the reliability level (grey beams) is systematically higher for the

    exposure classes XD1 and XS1 and systematically lower for the exposure classes XD2, XD3, XS2,

    XS3. The lowest reliability level (bottom bar) for the exposure classes XD1 and XS1 is = 1.5, for

    the exposure classes XD2, XD3 and XS2is -1.0 and for the exposure class XS3is -1.5.

    In current standards and supplementary documents a variety of reliability levels 0 areproposed for durability limit states for example:

    0= 0.5 (Gehlen et al., 2008, DAfStb, 2008, Zilch & Schiel, 2001), 0= 0.8 (Teply & Novak,

    2012), 0= 1.0 (Sarja, 2005), 0= 1.2 (LNEC E 465, 2007), 0= 1.3 (fib, 2006, Gulvanessian et

    al., 2002, JCSS, 2000), 0= 1.5 (EN 1990, 2002), 0= 1.7 (JCSS, 2000), 0= 1.8 (NEN 6700,

    2005), 0= 2.0 (LNEC E 465, 2007, Zilch & Schiel, 2001) and 0= 2.3 (Sarja, 2005,Gulvanessian et al., 2002, JCSS, 2000). Except for the exposure classes XD1 and XS1, the

    reliability level provided by deemed-to-satisfy rules is, at least for unfavourable design situations,

    below all the proposed target reliabilities.

    Therefore it can be concluded that the major consequences of the current prescriptive approach are:

    - lack of safety for specific design situations,- lack of economic viability of prescriptive designed structures.This results mainly from the lack of reliable information on the durability properties of the concrete

    (type of cement) which makes it difficult to evaluate concrete quality and performance in the

    respective environmental load. In order to overcome the current problems an adaption of deemed-

    to-satisfy rules is required, where the limiting values are derived from scientifically verified

    material resistances (performance based deemed-to-satisfy rules). Therefore, a system with

    exposure resistance classes is proposed (Leivestad, 2013).

    4 Proposal for performance based deemed-to-satisfy rules

    The methodological approach for ensuring durability based on exposure resistance classes inanalogy to the approach for ensuring load-bearing capacity based on strength classes is shown in

    Fig. 11.

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    2

    3

    4

    XD1 XD2 XD3

    XS1 XS2 XS3

    Reliabilityindex

    [-]Reliabilityindex

    [-]

    E P GB NL D DK N USA AUS E P GB NL D DK N USA AUS E P GB NL D DK N USA AUS

    CEM I

    CEM IIICEM III

    CEM IIISF

    SFSF

    CEM I

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    Fig. 11 Methodological approach for ensuring durability based on exposure resistance classes in comparison

    with the approach for ensuring load-bearing capacity based on strength classes (RSD for Exposure Resistance

    Class Sea/De-Icing Salts, RC for Exposure Resistance Class Carbonation).Exposure resistance classes classify concrete performance. Compliance of a specific concrete

    composition with the exposure resistance class is tested under standard conditions using a certain

    test specification. The class definition gives the characteristic material performance and the

    environmental action. For example the exposure-resistance class RSD45 stands for a characteristic

    chloride ingress depth (depassivation will occur with a probability of 10%) of 45 mm (chloride

    resistance class). Based on the characteristic material performance the cover required to withstand

    the specific environmental load (exposure class) is derived from (reliability) design. This approach

    is comparable with the approach for ensuring load-bearing capacity based on strength classes.

    Here, material performance is classified and characterized by strength classes. Compliance is tested

    under standard conditions. The dimensions of the structural component required to withstand the

    actual load are derived from (reliability) design based on the characteristic strength of the concrete.

    In order to maintain the prescriptive concept deemed-to-satisfy rules have to be determined.

    Deemed-to-satisfy rules have to be laid down for the concrete composition parameters (w/c-ratio,

    type of cement etc.) for which a reliable relationship with the relevant material performance

    (exposure resistance, e.g. chloride ingress depth) is documented. For the relevant material

    performance, the different cover required to withstand the conditions of the individual exposure

    classes may be given in design tables for a specified design service life. Thus, for common design

    situations, no reliability design is to be performed. For the carbonation resistance classes (RC),

    deemed-to-satisfy values have been developed and introduced in (Greve-Dierfeld & Gehlen, 2014).

    Those rules are also based on a benchmark for deemed-to-satisfy rules performed for the exposure

    classes XC1, XC2, XC3 and XC4 (Gehlen & Greve-Dierfeld, 2013).

    The advantage of this new approach is that reliable information on the durability properties of theconcrete composition is available. This results in (see Fig. 12)

    - an increased safety margin for specific design situations and- an improved economic viability of the structures.

    Fig. 12 Reliability spectra provided by current deemed-to-satisfy rules (left), reliability spectra provided

    when specifying cover in dependence of exposure resistance class (right).

    -2

    -1

    0

    1

    2

    3

    4

    -2

    -1

    0

    1

    2

    3

    4

    Reliabilityindex

    [-]

    XS3

    E P GB NL D DK N USA AUS

    Reliabilityindex

    [-]

    XS3

    E P GB NL D DK N USA AUS

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    Acknowledgement

    The authors wish to acknowledge the assistance and support of thefib-TG 5.11.

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