an analysis of the lack of investment and implementation...
TRANSCRIPT
Energy and Energy Policy:
An Analysis of the Lack of Investment and Implementation of Plasma Gasification in the United States
Prepared by:
Duncan McGillivary
Emily Yi
Ferdinand Chan
Gabriel Loboguerrero
Kelvin Lee
Kevin Wei
Prepared for:
Dr. George Tolley
Dr. R. Stephen Berry
The University of Chicago
December 4, 2015
Abstract
The technological capacity to use plasma gasification in Waste-to-Energy (WtE) systems
has been available for several decades. From carbon-based parts of waste materials varying from
municipal solid waste, hazardous waste, etc., plasma is used to generate a synthetic gas (syngas)
that can be used in generating electricity, steam, and other fuel sources. Plasma gasification has
many purported benefits, such as eliminating landfill waste, low environmental emissions, low
operational costs, and the highest efficiency of converting waste to energy, among many others.
Internationally, plasma gasification has taken hold as an efficient energy source in countries such
as the United Kingdom, Japan, and many others. However, there are currently no successful
implementations of plasma gasification across the United States among many failed projects.
Using the successes and failures of international and domestic plasma gasification plants as case
studies, we conclude that the economic and political environment is infeasible for plasma
gasification to be an effective renewable energy source in the United States. With the correct
incentives and policies, plasma gasification can provide many unique benefits and be a
successful diversification of energy in the United States.
i
Table of Contents
1 Introduction 1
1.1 Traditional Plasma Waste Treatment Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.2 Factors to Consider in Plasma Waste Gasification . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.3 Purported Benefits of Plasma Gasification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.4 Purported Benefits of Plasma Gasification: Environmental . . . . . . . . . . . . . . . . . . . 7
1.5 Purported Benefits of Plasma Gasification: Economic . . . . . . . . . . . . . . . . . . . . . . 14
1.6 Purported Benefits of Plasma Gasification: Summary . . . . . . . . . . . . . . . . . . . . . . 16
2 International Case Studies 18
2.1 China . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
2.2 Japan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
2.3 India . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
2.4 Common Issues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
3 United States Case Studies 23
3.1 Domestic Plasma Gasification Case Study: Sacramento, California . . . . . . . . . . . 23
3.2 Covanta . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
4 Technological Barriers 28
4.1 Biomass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
4.2 Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
4.3 Fuel Moisture Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
4.4 Selection of the Gasifier . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.5 Moving Bed Reactors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.6 Fluidized Bed Reactors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
ii
4.7 Twin Fluidized Bed Reactors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
4.8 Plasma Gasification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
4.9 Operating Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.10 Residence Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.11 Gasifying Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.12 Gasifying Agent-Biomass Ratio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.13 Air-Fuel Ratio and Equivalent Ratio (ER) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
4.14 Reaction Temperature and Pressure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
4.15 Cleaning System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
4.16 Gas Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
5 Economic Barriers and Cost-Benefit Analysis 37
6 Implementation and Overcoming Barriers 40
7 Appendix 45
8 References 47
iii
1 Introduction
Persistent population growth both domestically and internationally has served as an
impetus for increasing industrial development. With a recovering global economy that has
showed similarities to the pre-financial crisis economic state, consumer sentiment has risen.
These factors, combined with a myriad of other forces, have led to a substantial increase in our
generation of municipal solid waste (MSW). In 2011, the United States alone generated an
estimated 389 million tons of said waste. Of this number: 22.6% was recycled, 6.3% composted,
7.6% used as fuel in waste-to-energy (WtE) plants, and 63.5% landfilled [1]. In 1989, municipal
solid waste generation totaled an estimate 269 million tons. Thus, waste production has
approximately increased by 44.6% in 21 years, spurring the discussion on how the problem of
increasing waste can be best handled [2].
Figure 1: MSW Generation and Distribution (EPA, 2008)
!1
Issues such as global warming and the detrimental effects to the environment as a result
of increased landfilling has taken center stage, leading society in an effort to counter the effects
of greater MSW generation. Globally, the development of waste-to-energy plants has
proliferated. Currently, the largest number of WtE facilities exist in Europe, totaling an
approximate 520 operational facilities [3]. As of 2014, the United States alone had 87 WtE plants
that handled approximately 30 million tons of waste per year. By converting this waste, the
United States was able to create an estimated 15 billion kWh of energy. Similarly, Asian nations
including Japan, but not limited to, have also taken advantage of environmentally-friendly
energy production activities. In fact, a staggering 70% of Japan’s MSW is processed through
facilities that convert the waste into usable energy. Theoretically speaking, a conversation rate of
70% in the United States would yield over 100 billion kWh of energy [4]. As mentioned
previously, a large driving force behind MWS generation is population growth. Nations like
China, where recent removal of population limiting policies like the One Child Policy, also have
ambitious plans to develop approximately 200 operational WtE facilities by year 2020 [5]. When
considering WtE operations, there are several methods in which one can go about converting
waste to energy: Incineration, capturing landfill gas, gasification, and most importantly, plasma
waste gasification.
Incineration is an oxidizing reaction that is commonly seen within WtE facilities. It is a
process that requires burning mass MSW brought to facilities from cities and landfills. MSW that
will be treated in this fashion either gets combusted as soon as it is transported or pre-treated so
that it is more easily [6]. After being burnt at temperatures ranging from 850°C - 1200°C, gases
are generated that can be used to produce energy via steam. Advantages include rapid volume
!2
reduction and energy recovery, but downsides include high initial costs and public disapproval
[7]. Further, there is no flexibility in the use of its energy product as seen in other reactions.
Capturing landfill gases is a different process in which the natural state of landfills is
utilized. As MSW builds up in landfills, it is anaerobically broken down by bacteria due to the
oxygen-deprived environment in which the MSW sits. A combination of gases is subsequently
emitted from the anaerobic breakdown including CO2 and CH4. The gases are captured and used
in various forms including conversion to renewable energy. Advantages include the ability to
turn MSW into usable energy, but disadvantages include the difficulty of capturing all the gases
as well as the need of significant landfill space [8].
Gasification itself is a process that involves various physical and chemical interactions
that occur at temperatures from 400°C to 900°C. MSW first goes through heating and drying,
which involves mixing liquid water and steam at temperatures of around 160°C [9]. The next
step involves thermal decomposition, in which the MSW is heated at temperatures around 700°C
leading to the release of syngas (a mixture of hydrogen and carbon monoxide among a variety of
other gases). The syngas that is produced is much more flexible than the gases that can be
captured from simple incineration or capturing of landfill gases. Advantages also include the fact
that SOx and NOx emissions are less than that of the other WtE processes [10].
The process changes slightly yet improves significantly when we introduce the plasma
arc, leading to plasma waste gasification. Being that it is a process that avoids incineration,
emission byproducts are significantly lower than other WtE processes. The main product is
similar to gasification itself where a synthesis gas is produced as well as an inert vitreous
material commonly known as slag [11]. However, through this external heat source, a majority of
!3
the carbon present is converted to fuel gas. Such technology is the closest society has come to
pure gasification.
1.1 Traditional Plasma Waste Treatment Process
Plasma waste gasification plants primarily consist of the following components seen in
Figure 2. MSW first undergoes waste pre-treatment which can vary depending on the type of
MSW being treated. Waste that has a higher moisture content will undergo a drying process prior
to entering the plasma furnace. For waste that does not require such a drying process, there tends
to be a shredder that reduces MSW size prior to entering the plasma furnace [12].
The plasma furnace is where the heating takes place. Two electrodes – in most instances
made of graphite – which are known as the plasma arcs torches, are inserted into the plasma
furnace. Electric currents are subsequently passed through the electrodes, generating an electric
arc between the tips of the electrodes and the conductive receiver, which is usually a slag at the
bottom of the furnace. This electric arc subsequently heats the furnace to very high temperatures
that break down the MSW in a way that other WtE processes cannot replicate. As this MSW is
broken down, a synthesis gas is formed, later to be converted to energy [13].
The synthesis gas then travels to a gas cleaning system in which hazardous by products
are removed. As detailed in other WtE processes, some of these gases include SOx as well as
other acid gases like HCl and particulates. After the syngas is sufficiently cleaned, it is brought to
the energy recovery system. Such system can revolve around a steam cycle, gas turbine cycle, or
even a gas engine. All are capable of converting syngas to electrical, thermal, or steam energy,
but depending on the nature of the syngas, one method may be preferred over the other [14].
!4
Figure 2: Plasma Waste Gasification Process [15]
1.2 Factors to Consider in Plasma Waste Gasification
As mentioned previously, the composition and physical properties of the MSW being
gasified is a significant factor in the performance of a WtE operation. Prior to carrying out a WtE
process, one must consider the ash content, moisture levels, degree of volatile matter, as well as
variables such as density and the size of the objects. Although most MSW is pre-treated prior to
heading into any sort of process, many plants that carry out plasma waste gasification prefer to
use pre-treated refuse-derived fuel (RDF) rather than using the MSW as is. Certain combinations
of compositions can lead to processes in which there are possible synergies, leading to a
reduction in carbon loss and an increase in energy content [16].
Arguably the most important factor to consider when analyzing WtE processes is the
equivalence ratio. The equivalence ratio measures the oxygen content in the oxidant supply
versus the oxygen content that is required for full stoichiometric combustion. Said ratio strongly
!5
affects the composition of the syngas that is produced from the MSW. Under standard conditions
that gasification procedures undergo, the optimal equivalence ratio falls somewhere from 0.25 to
0.35. At an equivalence ratio within this range, gasification processes can convert most of the
free carbons into fuel, maximizing energy output. Depending on the type of WtE process that a
plant utilizes, a different equivalence ratio may be required [17].
Figure 3: Equivalence Ratio versus Syngas Composition [18]
1.3 Purported Benefits of Plasma Gasification
WtE technologies have been significantly rising in popularity, due to increasing concerns
about waste accumulation and environmentally-friendly energy alternatives. Plasma gasification
!6
provides a solution to both eliminating landfill waste and diversifying renewable energy options.
Landfill waste is increasing at an alarming rates and with the current effects of our conventional
energy use mainly from natural gas, petroleum, and coal, people are searching for viable long-
term energy sources. With recent technological developments and research, plasma gasification
is purported to have many unique benefits in these areas over current conventional energy
sources. However, the use of plasma gasification in WtE is only very recent and many of these
claims have not been fully examined and proven. The theoretical advantages of plasma
gasification are concentrated in two main areas: environmental benefits and economic feasibility.
Throughout the analysis of plasma gasification’s benefits, comparisons will be made between
conventional WtE technologies, mainly landfill use and incineration. It is important to keep in
mind that the context of these benefits: we are examining the application of plasma gasification
in its current state of advantages and disadvantages. Our goal is to provide an analysis of why
plasma gasification represents another diversified alternative to our current WtE sources, and in
its current state, is not able to operate on a scale of major energy players like petroleum or coal.
1.4 Purported Benefits of Plasma Gasification: Environmental
The environmental benefits of plasma gasification are highly attractive, as it confronts
two important issues that are harming our planet: increasing amount of material waste and
emissions. In the following analysis, we shall compare plasma gasification and its environmental
benefits to landfill waste and incineration, two of the conventional methods that use waste as
material requirements.
!7
The most common type of waste generated by manageable sources is municipal solid
waste. The United States population is consistently the largest producer of MSW, with its
individual waste generation of 4.4 pounds per person per day [19]. One of the main methods of
MSW disposal is creating landfill sites. Landfills are the oldest and most common method of
organized waste disposal in the world, and while some energy can be reused from landfill sites,
this disposal method has several costly drawbacks that outweigh its usages. According to the
EPA, the United States has over 3,000 active landfills and over 10,000 old municipal landfills.
These landfills have two major disadvantages: harmful greenhouse gas emissions and a large
potential to leak/contaminate the local habitat. Landfills are notorious for its methane emissions,
and “methane is responsible for 10.6% of global warming damage from human-sources in the
U.S. Of this, 35.8% is from landfill gas. Thus, 3.8% of U.S. global warming damage is from
methane in landfill gas, a significant amount” [20]. In addition to the emissions issue, "...82% of
surveyed landfill cells had leaks while 41% had a leak area of more than 1 square
feet” [21].These leaks present long term threats to local groundwaters and connected surface
waters. With natural resources such as land and water becoming rarer, it’s an important concern
to limit landfill usage.
However, with all of these disadvantages to using landfills, there are little to no signs of
stopping its utilization. Although the number of landfills is decreasing, the pure volume of trash
is simply being consolidated into larger and larger areas. The United States population currently
shows an increasing rate of MSW, one of the main contributors to landfill waste. In 2012,
Americans generated over 270 million tons of MSW and 54% of that waste was discarded in
landfills [22]. This consistent usage of landfills demonstrates the United States lagging behind
!8
other developed countries in terms of waste utilization. In the below graph, figure whatever, a
disproportionate amount of waste is transferred into landfills compared to other international
countries.
Figure 4: Comparison of methods of waste management between United States and other
European countries [23]
In addition, in the figure below, we can see that since 1960, the rate of waste generation
within the United States has tripled; with these kinds of waste disposal rates, using valuable
resources such as land and capital to create landfills with such high risk and low benefit is
unsustainable.
!9
Figure 5: Growth of U.S. MSW Generation [24]
In contrast, plasma gasification presents a strong alternative to landfills, solving the
emissions and contamination issue. It has a large potential for almost infinitely different types of
feedstock, one of the main sources being municipal solid waste among many others such as
agricultural waste, hazardous waste, etc. Westinghouse Plasma, a leader in plasma gasification
technologies, has proven that unlike the typical incineration process, a plasma gasifier can
process almost any feedstock, including a blend; owners can even optimize revenue and other
needs by determining the ideal mix of feedstocks based on energy efficiency and costs [25]. This
flexibility lends itself to an extremely long life-span in comparison to conventional landfills
which are consistently being added across the nation. With plasma gasification using wastes that
would otherwise be put in landfills, it presents a viable solution to the United States’ current
track of increasing improper trash disposal. A growing number of countries have set regulations
!10
to reduce landfill waste by at least 25%, and with its unique advantages in emissions and
eliminating waste, plasma gasification has marketed itself as an asset to achieve this goal.
Plasma gasification is also extremely environmentally friendly in the area of greenhouse
gas emissions. As previously noted, plasma gasification requires the use of wastes (municipal,
agricultural, etc.) as a conversion into syngas, which is then converted to various energy sources.
The material requirements of plasma gasification uses waste that would otherwise be incinerated
or put into a landfill, both of which generate harmful carbon emissions that weakens the state of
Earth’s atmosphere and threaten harmful climate change. Therefore, since the feedstock of
plasma gasification is composed of material that is waste that would otherwise be used in waste
disposal methods that would be increasingly harmful to the atmosphere with emissions, plasma
gasification’s emissions footprint is significantly smaller than most WtE sources.
In fact, analyses of the plasma gasification process has been shown to have a ‘negative’
greenhouse gas footprint in comparison to incineration and landfills, produce virtually zero
emissions and has the highest landfill diversion rate of any available technology [26]. In
comparison, landfills are the largest third source of methane emissions in the United States,
constituting 16% of man-made CH4 emissions [27]. In the figure below, we can see that
compared to regular waste disposal technologies (landfill gas collection and incineration),
plasma gasification has superiority in the area of accumulated carbon emissions.
!11
Figure 6: Plasma Gasification Life Cycle Environmental Effects [28]
In addition, currently installed plasma gasification plants already exceed U.S. EPA
standards for emissions requirements, as shown in the figure below.
!12
Figure 7: Energy Recovery from Waste Comparison [29]
In comparison to conventional incineration standards of emissions and efficiency, plasma
gasification outperforms by a significant amount. Less than 2% of the material introduced into a
Westinghouse Plasma Corp. gasification plant needs to be sent to landfill. In comparison, about
20% to 30% of the waste processed in an incinerator must be sent to landfill [30].
Compared to alternative WtE sources, plasma gasification easily exceeds the
environmental standards put forth by previous technologies. In the areas of both emissions and
waste contamination, it manages to have advantages over landfill usage and incineration. While
the former technologies have been used throughout history to get rid of waste, plasma
!13
gasification uses new techniques and methods that ensures an environmentally friendly and
efficient method of converting waste into energy.
1.5 Purported Benefits of Plasma Gasification: Economic
In regards to theoretical economic feasibility, plasma gasification has two main strengths
over its WtE competitors: flexibility and efficiency. The wide variety of inputs and outputs that
plasma gasification can deal with is vastly superior to anything that incineration or landfills can
process. The different waste streams available for plasma gasification processing varies from
refinery wastes. Aside from MSW, there are many different waste streams that are available in
certain locations that have unique benefits such as higher waste tipping values, high fuel value,
and toxic qualities (leading to higher processing values). A few other examples of potential fuels
that can be processed are medical waste, construction debris, industrial waste from petroleum
and chemical plants, telephone poles, etc. Additionally, there are millions of tons of low-grade
waste coal that exist in massive piles throughout the Appalachian region of Pennsylvania and
West Virginia, US, that can be utilized for gasification. This waste feedstock flexibility leads to
long term survival and economically, it ensures that the plant will have consistently low
operation and feedstock costs.
In addition to flexibility of feedstock inputs, multiple outputs and revenue streams can be
produced from a single facility. Plasma gasification only has two products: synthetic gas and
vitrified slag, both of which have a commercial value [31]. Syngas is an incredibly useful fuel
source, as it can be generate heat, steam, electricity production, and many more fuel sources that
can be sold or combined with ethanol or hydrogen production to maximize resources [32]. Slag
!14
is the solid byproduct of the gasification process and has many unique properties that make it
valuable for profiteering. Slag has high potential for use in construction projects due to its
density and flexibility; government subsidies for slag and similar positive environmental
externalities have been used across the country and can additionally offset the costs of plasma
gasification implementation. Due to the high valuation of its multiple inputs and outputs, plasma
gasification processes generate a diverse and unique combination of revenues that cannot be
compared to any other WtE technology. For example, in the case of an average plant using
100,000 tons of MSW could generate steady revenue streams from multiple sites, with the 5
below being the most common [33]:
• Tipping fees for the waste it receives
• Sale of any recyclables removed
• Electricity generated (sold to the local grid on long-term power purchase agreement)
• Heating or cooling sold to local companies, eg hospitals, offices
• Sale of the glassy by-product, produced by the process and sold as building material
Clearly, the value of the plasma gasification process is significantly amplified due to its
diverse potential, which translates well into diverse streams of revenue, increasing profits for
shareholders and the environment.
The technological advantages of plasma gasification’s efficiency is another major asset to
its economic strength. The extreme heat (3,000+°Fahrenheit) that plasma gasifiers maintain the
trash conversion with is factually the most efficient method of converting the waste into actual
usable energy. Compared to incineration, most of which have low efficiency rates of 19-27%
[34], plasma gasification has virtually a 100% carbon conversion rate ([35], leading to an
!15
efficiency rate of over 80% [36]. When using waste as a feedstock instead of planting it within a
landfill, it’s important to consider opportunity costs and what potential profits are being lost;
with plasma gasification, the technology is the most efficient so that the energy recovery is
maximized. Another result of the higher efficiency is the cost savings associated with
government intervention with respect to certain subsidies or tax credits. For example, most
plasma gasification plants qualify for some kind of landfill tax avoidance and have an added
value of the potentially reusable by-products and the end product, i.e. within a regulatory
context, it is regarded as a recovery, as opposed to a disposal, technology [37]. Finally, the
strongest piece of evidence for plasma gasification’s economic success over any other WtE
comes from Westinghouse Plasma Corporation’s statistic that for similar capital and operating
costs, a plasma gasification plant can generate ~ 50% more energy from the waste in a combined
cycle configuration [38].
1.6 Purported Benefits of Plasma Gasification: Summary
In terms of long-term potential, plasma gasification’s ability to exist and thrive as a
lasting energy source is dependent on how well policies consider and value the environmental
and economic advantages such that the benefit outweighs the cost. Plasma gasification’s extreme
flexibility in converting almost any kind of waste into efficient energy translates into many
strengths that technologies like incineration or landfill usage cannot compete with. The
efficiency and flexibility leads to lower emission standards, less contamination risk, higher
revenue streams, low operation costs, and many other benefits. From the purported benefit
analysis above, it’s clear that plasma gasification offers unique benefits that no other WtE source
!16
can compete with, from minimizing environmental impact to maximizing economic profits. With
these benefits that plasma gasification boasts, some may claim that “’We've finally reached a
point where it's actually going to be cheaper to take garbage to a plasma plant and make energy
than it is to take the garbage and just dump it into a landfill’" [39]. However, it is important to
acknowledge the gravitas of the specific policies that have allowed plasma gasification to
succeed in certain areas. Without any government intervention in the economic and political
sphere, it is unlikely that plasma gasification plants can ever actually be feasible. In the
following sections, we will take a look at how the above theoretical benefits are actually put into
practice, especially in the case studies around the world.
After a broad overview of the technological aspects, potential, and current state of plasma
gasification, we must examine its viability as a feasible alternative energy source. The
technology of utilizing plasma gasification for WtE purposes has been available for decades, and
it has many unique benefits over conventional energy sources. However, it has yet to be proven
as an effective alternative source of energy in the United States. In this paper, we will examine
the specific barriers that prevent plasma gasification implementation in the United States through
a discussion of different case studies. First, an examination of international plasma gasification
plants will provide the specific policy adaptations that different countries have allowed plasma
gasification to be effective. In contrast, the case studies of the United States and its multiple
failed attempts will demonstrate the high technological, economic, and political costs of plasma
gasification implementation. We use Covanta, a leading waste disposal and renewable energy
production company, as the main case study within the United States due to its expertise in Waste
to Energy industries. We will then present an economic analysis of constructing a plasma
!17
gasification plant in the United States, including a cost-benefit analysis, which ultimately
demonstrates that the cost of implementation largely outweighs the benefits. We arrive at the
conclusion that there is a lack of economic, political, and infrastructural incentives that makes
plasma gasification a poor alternative to incarnation or landfill usage. Finally, we will provide
potential policy adaptations, both economic and political, which we believe would aid and propel
the success of plasma gasification in the United States.
2 International Case Studies
Plasma gasification plants around the world have been relatively successful. Plasma
gasification has benefits that can successfully deal with many problems that are currently not
issues in the United States. The often-high fixed cost associated with plasma gasification often
requires that countries have other necessities that plasma gasification can fix. By examining
some of the reasons for plasma gasification in other countries, one can potentially identify
situations in the United States, or a lack thereof, that would effect investment into plasma
gasification.
!18
2.1 China
In 2013, Wuhan Kaida successfully completed a demonstration facility in China. It
currently processes 100 tons of biomass a day and produces syngas [40]. The monumental plant
was constructed as a solution to a much larger issue within central China: removal of industrial
waste.
Central China is known for its industrial output, which can easily meet the amount of
biomass required for full scale industrial projects. One of the benefits of plasma gasification is
that it can process almost any kind of industrial waste [41]. The plant in Wuhan specifically
processes wood waste, a major contributor to air pollution. It has been tremendously successful
largely because there have been no issues with feeding the plant in such an industrial area.
Wuhan Kaida in China has used its success as a stepping stone on their much larger
initiative which has recently added a project in Nanjing, China to process 500 tonnes of waste
daily [42]. Similarly, the plants are able to produce foam insulation after passing technical tests
in China. This gives the plants in China a greater ability to reap the profit of their slag [43]. The
vicinity of the plant, the availability of waste from the nearby industrial towns, and the ability to
sell the slag as insulation means that funding and implementing the plants requires less risk and
can give greater reward. The United States has a similar company focused on plasma
gasification, the Jacoby Group. However, it does not have the same attention from the
government nor the high premium placed on hazardous waste disposal as is available in China.
!19
2.2 Japan
There are three active plasma gasification plants in Japan. There is a 166 ton per day
plant in Yoshi, a 165 ton per day plant in Utashinai City, and a 28 ton per day plant in the twin
cities of Mihama and Mikata. In many ways, Japan has taken itself to the forefront of plasma
gasification.
The plant in Utashinai city, a collaboration between Hitachi Metals and Westinghouse
Plasma Corp., was one of the first plasma gasification facilities worldwide. It was built in 2002
and required 5 years of research and development. It now processes a mixture of auto shredder
residue and municipal solid waste. This facility was not designed primarily for electricity
generation but was instead designed for waste removal [44]. The plants location meant that
originally it had a significant amount of business from auto plants who needed to destroy their
auto-shredder waste. However, during the time that the plant was inactive, many of the auto
plants found other ways to remove their waste. Hitachi Metals ceased the plants operations in
2013 since it was running at only half capacity and losing money.
The takeaways from the origins and then halt on operations for the Ecovalley plant could
indicate some of the primary reasons that plasma gasification has not caught on in America. It is
a risky investment since even short malfunctions of the complicated equipment can reduce profit.
Similarly, its high initial cost and the energy required to maintain the plasma torch left the
Ecovalley plant with only enough electricity to dry its slag rather than the expected 1.5MW,
enough to power 30,000 US households [45]. Overall, these issues left the plant unprofitable.
However, there have since been improvements to the design of the plasma gasification
mechanisms which would eliminate many of the risks facing earlier plants. The primary concerns
!20
at Ecovalley were an improperly sized gasifier, a low quality refractor, and excessive particulate
carryover. The new gasifiers have all taken into account these issues and plants without these
problems, such as the Mihama Mikata facility between the twin cities for which it was named
have been successful and still operate to this day. Rather than create electricity the syngas is used
to further. The primary issues for the Ecovalley plant were mechanical failures and customer
retention, which might be a cause of concern for American investors.
2.3 India
In India the primary plasma gasification facility is in Pune, the 8th largest city in India. It
currently produces 1.6MW/day and has a capacity for 72 tonnes. One of the main issues that
faces the Indian states is that they have such a large amount of trash that the dioxide produced
would damage their health. They have already run out of landfills so the question becomes one of
gasification of incineration. There are currently 8000 tonnes of trash produced by Bombay daily,
which is likely to grow with the population of India [46].
The profitability of the plant in Pune is through its ability to process many different types
of waste. The city around it generates 1500-1600 tonnes of waste every day. Twenty-three
different cities in India end up generating over 100 tonnes of waste daily [47]. Therefore there is
a need to get rid of the trash. If they were to solely use incineration then there would be a
tremendous amount of dioxides in the air, which would be detrimental to any positive
environmental change. India’s need for waste removal services, the decreasing availability of
landfills, and the dangerous effects of dioxide from incineration have left India in need a new
!21
disposal system. Currently, there are 6 more new waste to energy plants under construction to fill
this need.
2.4 Common Issues
The issues and reasons for producing plasma gasification in each of these countries are
unique, and not necessarily applicable the United States. The facilities themselves are
tremendously expensive and can cost an exceptional amount to produce electricity. They also
require a solid amount of waste to be economically feasible. In China, the facility was able to
take advantage of significant industry in the area and dispose of hazardous waste. Similarly, in
India there is such a large amount of waste that the plasma gasification process is necessary and
was used by the government to reduce the need for landfills and incinerators.
Some of the major problems in the United States can be gleaned from these plants. The
first issue is a lack of investment. The United States does not have the land issues or waste issues
that other countries do. It is much cheaper and simpler for a county to simply put their trash in a
landfill than to risk millions of dollars building a plasma gasification plant. Similarly, the
reduction in air pollution leaves a cheaper option, incinerators, as a more economically feasible
solution to waste issues. The Hitachi metals plant in Japan reveals even more issues with the risk
of building a plant. Unless it is produced at a location that will have enough consistent waste to
reduce then the returns from the electricity generated and funds from hazardous waste removal
will make the process unprofitable.
!22
3 United States Case Studies
3.1 Domestic Plasma Gasification Case Study: Sacramento, California
The failures of implementing a plasma gasification plant in Sacramento, California by
U.S. Science & Technology, a private company, demonstrates several of the current domestic
barriers in moving forward with this new WtE technology. In particular, the two main barriers
that this case study encountered were economic and political. Sacramento issued a Request for
Qualifications (RFQ) on August 24, 2007 to attract development partners to meet 5 specific
goals: (1) be environmentally friendly and reduce greenhouse gas emissions; (2) be economically
viable and cost-neutral to rate-payers; (3) leave little or no residuals requiring treatment or
landfill disposal; (4) continue the City’s existing recycling program; and (5) utilize a proven
technology at a commercial scale [48]. After evaluating eleven different companies that
responded to the RFQ, a committee decided that USST’s plasma gasification proposal held the
most merit.
USST was selected to tackle Sacramento’s growing waste problem as a result of their
unique purported benefits. “In 2007, Sacramento collected an average of 750 tons/day of
municipal solid waste. About 348 tons/day (46%) of this was recycled, leaving 402 tons/day to
be landfilled in the state of Nevada. The city’s commitment would be limited to the diversion of
300 tons of residential municipal solid waste per day that is otherwise exported to Nevada” [49].
The biggest draw for the city of Sacramento toward USST was the fact that USST aimed for a
public/private partnership with the city of Sacramento, where the private company would invest
all capital necessary to build and maintain the facility, and the public city would only contribute
!23
waste. This was an extremely attractive deal to the city council, who, at no cost from the city,
could pioneer a new technology in addition to solving its waste problems. However, this deal
was simply too good to be true.
On November 18th, 2008, several interest groups including La Raza Network,
Environmental council of Sacramento, Global Alliance for Incinerator Alternatives, and many
more, banded together, presented their research, and petitioned the Sacramento City Council to
reject the USST plasma gasification contract based on 5 main reasons [50]:
1. Based on previous studies, plasma gasification does not accomplish the needed goals; due
to the fact that 65% of their residential MSW is recyclable, ton for ton recycling and zero
waste programs offer better environmental benefits for less risk.
2. There is limited data that there would not be emissions of toxic and criteria pollutants due
to the lack of widespread plasma facilities around the nation.
3. Under California law there are no credits or incentives that can be given for facilities that
produce renewable energy through combustion of municipal solid waste. The cost and
risk was too high for perceived benefit
4. Several community concerns about the implications of a facility being built. For example,
it would be located nearest to low-income and people of color residents, which would
raise serious environmental justice and racial concerns.
5. After further research, the City Council deemed USST to have made many incorrect and
misleading claims, such as plasma gasification receiving carbon credits (no such thing),
financial viability, and many other string attached.
!24
On January 15, 2009, the Sacramento City Council voted 8-0 to cease working with
USST as a result of analyzing poor economic returns and lack of financial viability. After
consulting with several experts, including economists and energy consulting firm Advanced
Energy Strategies, it was determined that USST’s financial projects had not point of comparison
and seemed purely speculative. The council cited the fact that “there would not be a positive cash
flow until the 11th year of operation … [and] AES’s estimate the facility would operate $70
million in the red” [51].
The failure of plasma gasification in Sacramento is representative of two main domestic
barriers: a discouraging lack of precedent and a lack of financial security. When major players do
not have any domestic plants to compare their plans for plasma gasification, there is no guarantee
of success. This leads to a negative feedback loop; since there is no precedent set in the U.S.,
companies and governments lack the initiative to create their own plasma gasification plant,
leading to further apprehension and lack of presence. Sacramento’s reliance on external
economists and energy consultants is a damning piece of evidence for the information
asymmetry of building a plasma gasification plant. While the lack of precedent is more of a high-
level and long-term barrier, the economic obstacles that plasma gasification is very well
demonstrated by the Sacramento case study. While many other countries allow incentives and
credits for plasma gasification, a lack of political awareness and understanding leads to
underutilization of this efficient waste-to-energy technology. Internationally, plasma gasification
plants are rewarded by ‘recovering’ energy from waste, while in the United States, plasma
gasification is seen in the same unhealthy vein as incineration, which leads to a lack of subsidies
and public disapproval. Constructing a new technological plant that a country has never seen
!25
before is a high undertaking, and without policy support, hypothetical costs will always exceed
benefit, leading to failed implementation everywhere. As we have seen from the city council’s
decision, government intervention in the economic and financial sphere is absolutely essential
and has the potential to make or break the culture of inefficient waste processing.
3.2 Covanta
Next, we turn our attention to Covanta, a leading owner and operator of EfW
infrastructure in both the United States and abroad. Under their portfolio, Covanta owns
approximately 45 EfW facilities with the ability to process approximately 20 million tons of
MSW. Known for their consistent track record of operating performance, Covanta has an
experienced team that consistently achieves boiler availability in excess of 90%. Thus, Covanta
provided the perfect opportunity to highlight the state of plasma waste gasification.
When speaking with Covanta’s Director of Strategy Richmond Young, he was able to
provide us with his perspective on the state of plasma gasification with in the United States, his
firm, and internationally. Advised to focus on two specific plants, our team – with the assistance
of Richmond Young – compared and contrasted a facility located in Florida at Pinellas County
and a facility located in Canada referred to as Durham-York. These two facilities provide us with
a clear perspective into the state of plasma gasification.
Pinellas County EfW facility is a gasification facility that Covanta was selected to operate
for the next ten years starting in December of 2014 via a lease. This contract entails a joint
venture of sorts, in which Covanta will complete a number of projects, primarily funded by their
!26
client, in order to improve the operating performance of the facility. Covanta serves a partner that
is essentially leasing the facility with minimal downside.
The Durham-York EfW facility, however, is a facility that Covanta began constructing
from scratch starting in 2011. It is a municipally-owned 480 metric ton-per-day EfW facility.
Such a facility will be able to generate a substantial amount of electricity and will in fact qualify
for preferential pricing under Canada’s renewable feed-in tariff.
Understanding the processes used in the development of both of these facilities very
clearly highlights the issue at hand regarding not only plasma gasification, but EfW facilities in
general. In the United States, there is a lack of substantive policy that allows for EfW to be a
preferable option for firms like Covanta. As a result, many of Covanta’s investments
domestically are like that of the facility in Pinellas County, joint ventures in which they often
lease facilities instead of constructing them. There is little incentive for Covanta to explore new
technologies within the United States. On the other hand, Covanta is putting a substantial equity
investment in their facility in Durham-York because international countries tend to have more
favorable policies that would justify an equity investment in a new EfW facility.
Speaking with Richmond Young, it appears that Covanta has no plans to implement
plasma waste gasification within the United States in the near term. Reasons include a lack of a
favorable environment due to low power prices, a waste market that is dominated by two
companies, and lack of subsidies from the government. As a result, it is important for society and
our government to consider these factors moving forward, granted that the United States will
continue to lose significant EfW investment.
!27
4 Technological Barriers
4.1 Biomass
Gasification plants are fed through biomass, which is a heterogeneous mixture of organic
matter, and to a lesser extent, inorganic matter, including several solid and liquid phases with
different contents. Biomass fuels are not all the same and can be produced from agricultural
wastes, energy crops, forestry wastes, industrials wastes, etc. The diversity of the biomass fuels
is critical to the design and type of the power plant that will convert the fuel into electricity. Such
decisions of type and design of the gasification power plant should be made after the type of fuel
used to create energy has been determined. More research is required on the type of biomass
fuels that most effectively work to provide consistent and reliable syngas [52]. For example,
plasma gasification can be utilized with several types of municipal solid waste or organic waste.
There are algorithms that can simulate the gasification process for 80 different types of biomass
(On a methodology for selecting biomass materials for gasification purposes, 2015). This allows
for a better and more precise decision on the suitable type of biomass that should be chosen for
creating syngas with a particular set of characteristics.
4.2 Preparation
After the consideration of which biofuel to use, the preparation of the biomass needs to
occur. The process of preparation or pre-processing phases have a major impact on the
gasification outcomes. The most important factor to take into account is the size of the biomass.
Several experiments have been done to see the effects on biomass size and the effects on product
!28
gas composition. These experiments and results are not based on solely on plasma gasification
but on several types of gasification methods for producing syngas, which we can apply the
findings to plasma gasification.
An experimented conducted with a downdraft reactor using pine bark as biomass fuel,
demonstrated that with different biomass sizes the reaction of the biomass was different based on
its size. The conclusion drawn from that specific experiment was that the optimal biomass
particle size should be between 2 and 6 mm [53]. An increase in particle size led to lower
consumption rates, fuel/air equivalent ratios, maximum process temperatures, and lower flame
front velocities.
For entrained bed gasifiers, pyrolyzing biomass at temperatures of 400°C is shown to be
a viable option because of the effect it has on the process. Pyrolysis acts to remove the
oxygenated components from the biomass. As a result, the resulting biomass has an increased
energy density. There are other forms of pyrolysis including and under-researched technique
called torrefaction. Torrefaction is pyrolysis at a temperature of 200-300°C in an inert
atmosphere [54].
A study conducted utilizing the fluidized bed gasification treatment of untreated and pre-
treated olive residue and pre-treated olive residue mixed with reed, pine pellets, and Douglas fir
wood chips demonstrates the importance of the pre-processing phase [55]. The pre-processing
treatment used in this case was leaching. Leaching targeted metals such as K and Na in addition
to chlorine to reduce and even eliminate the problems caused by ash during the gasification
process. As was expected, the lower total tar yield of the producer gas resulting from the leached
olive residue compared to that of the untreated olive residue was the best fuel/mixture tested.
!29
The syngas produced from pelletized biomass in downdraft reactors has good
composition - H2 17.2%, N2 46.0%, CH4 2.5%, CO 21.2%, CO212.6% and C2H4 0.4%. In
addition, more syngas can be produced per kilo of biomass at 2.2–2.4 N m3/kg with a high cold
efficiency of 67.7–70.0% [56]. Pelletized biomass has been proposed as a supplement to other
types of fuels in order to improve the energy content as well as reduce the average moisture
effects. Pelletized biomass is a possible solution to the issue of variability in biomass in untreated
biomass a destabilizing source in gasifiers.
4.3 Fuel Moisture Content
A key element that needs to be looked at when conducting the gasification process is the
moisture content found in the fuel. An increase in the moisture content in the biofuel results in an
increase in energy required for water evaporation and steam gasification reactions. Thus, it
lowers the gasifiers operating temperature. Though bed temperatures tend to be stable with
moisture contents at or below 15%, the moisture level is dependent on the gasifier: an updraft
type reactor requirements can be as high as 50% moisture content [57].
One of the major sources of instability in the gasification process is the fluctuations of
biomass moisture content because it leads to variations in bed temperature. As a result, these
variations alter the composition of the syngas being produced. Syngas composition is linked to
biomass content. When looking at dry and moist fuels, the CO composition increases for dry
fuels, while the CO2 increases for the moisture fuels. Consequently, this increase in composition
reduces the calorific power of the syngas and the process efficiency, when looking at
experiments conducted with updraft fixed bed gasifiers with air [58].
!30
4.4 Selection of the Gasifier
The main component to a gasification plant is the gasifier. A gasifier is the piece that
converts the feedstock or biofuel in an energy plant into syngas. The gasifier functions as a
stabilizer for the syngas production. In the gasifier, the biomass fuel and gasifying agents along
with other inert materials, catalysts or additives are mixed to create the reaction. This section of
the paper will focus on the type gasifiers that include the following: moving bed reactors,
fluidized bed reactors, entrained bed reactors, plasma gasification.
4.5 Moving Bed Reactors
Moving bed reactors contain two types: updraft or countercurrent and downdraft or co-
current. In short, a moving bed reactor has the biomass flow through the reactor. An updraft
reactor hast fuel fed from the top of the reactor. A gasifying agent is then added (usually air,
oxygen, steam or a mixture of both). The agent then mixes with descending biomass and ash.
The area above the gasification is where the pyrolysis of the biomass takes place. The heat
transferred to the biomass from the gas updraft causes it dry up resulting in a mixture of products
due to pyrolysis and gasification.
Like the updraft reactor, the downdraft reactor has the fuel fed in from the top, but the
gasifying agent is injected from the side of the reactor, and combines with the products of
pyrolysis. The gas produced during gasification and pyrolysis in a downdraft reactor can be
burned during the process to provide the heat energy required for drying, pyrolysis, and
gasification. This is known as “pyrolytic flame” [59]. Because gas is fed from the bottom of the
!31
reactor, the hot gas passed downward through the hot char, which means a reduction in tar
production, but also a reduction in the caloric power.
4.6 Fluidized Bed Reactors
Fluidized bed reactors have the fuel fed in quickly from the top of the reactor and the
gasifying agent, as the name would suggest, is inserted in the form of fluidized gas fed in from
the bottom. Solid particles of fuel are brought into contact with a hot bed of solids, which rapidly
rises the temperature of solid particles causing pyrolysis to occur, producing char and gases.
However, the char produced from a fluidized bed reactor does not achieve full conversion
because of the continuous mixing of solids. These particles of partially gasified char can cause
losses in the gasifier. In addition, fluidized bed gasifiers have low level dissemination of oxygen
from bubbles to the emulsion phase. Consequently, the resulting combustion reactions takes
place in a fluidized state, decreasing the efficiency of the reaction. Advantages to fluidized bed
reactors lie in their ability to process fuels with high ash contents because of their operating
temperatures of 800-1000°C [60]. Fluidized bed reactors also work with many types of biomass
fuels due to its high thermal inertia and vigorous mixing, useful for large-scale biomass
gasification plants such as plasma plants.
4.7 Twin Fluidized Bed Reactors
On top of a single fluidized bed reactor, there are twin fluidized bed reactors that are used
to produce gas with greater calorific power. The two reactors each serve to have a single
function. The first reactor acts as a pyrolyzing reactor that is heated from sand or other material
!32
from the second reactor. The second reactors uses the heat produced by the burning of char from
the first reactor [61].
4.8 Plasma Gasification
The plasma gasification process is currently being used in conjunction with fluidized bed
gasifiers and plasma process arranged in series [62]. The biofuel used for this process mainly
involves organic MSW (municipal solid waste), and other wastes such as paper, plastics, glass,
metals, textiles, wood, rubber, etc. The formation of plasma occurs when an electric arc is
generated by running an electric current through a gas. The resulting temperatures in the plasma
current cause molecules within the current to break its bonds, thus generating syngas. Unlike
other gasification process, the gasifiers used during plasma gasification must be able to work at
significantly higher temperatures of 2,000 to 30,000°C.
More specifically a paper written by M. Materazzi et al suggest that the inherent flaws of
a single stage fluidized bed- plasma process can be corrected by using a two-stage fluidized bed
plasma process using RDF as the biofuel. RDF is refused derived fuel. It is produced from
combustible components of MSW, which is the most common feedstock used for plasma
gasification. The single-stage FBG process has higher deficiencies because it produces a higher
quantity of tars in the syngas, which reduces the gas yield of the steam and the carbon conversion
efficiency when compared to the results from the two-stage FBG [63]. However, more research
is needed to be done to see what the effects would be on a commercial plant.
!33
4.9 Operating Parameters
When considering gasification as a source of energy production there are several
operating parameters that must be taken into account. The gasification process goes beyond the
simple process of combustion. The operating parameters of the gasification process are the
following: residence time, gasifying agents, gasifying agent-biomass ratio, air-fuel ratio, and
equivalent ratio (ER), reaction temperature, and pressure [64]. The control of these parameters
allows for a consistent and quality operation performance without issues that can cause unwanted
stoppages of the process.
4.10 Residence Time
The residence time of a solid or gas particle is the average period for which the particle
remains within the boundaries of the reactor [65]. The residence time should be long enough for
the reaction taking place in the gasifier to produce the expected syngas. Each gasifier should
have the optimal residence time chosen according to its type. For example, fixed bed gasifiers
have longer residence times than those of entrained bed gasifiers. The residence time of gasifier
ranges from 1-2 seconds for entrained bed gasifiers [66].
4.11 Gasifying Agents
There are several types of gasifying agents that are used with the most common of the
being air since it is the most economical. The other types are steam, oxygen, CO2, and a mixture
of all four can be used as well. In ranking order of calorific power of the syngas produced, air
produces the least calorific power. Steam produces moderate calorific power with its cost
!34
between that of air and oxygen. Oxygen produces the highest calorific power, but is also the
most expensive one [67].
4.12 Gasifying Agent-Biomass Ratio
The gasifying agent ratio is the ratio between the gasifying agent and biomass feedstock
utilized during the reaction. The optimization of this ratio, depending on the type of reactor,
produces syngas with different chemical contents. For example an interconnected fluidized bed
gasifier where gasification and combustion are conducted separately, the steam to biomass ratio
can alter the amount of tar produced and the amount of CO, H2, CO2, and CH4 produced in the
process [68].
4.13 Air-Fuel Ratio and Equivalent Ratio (ER)
The air-fuel ratio is the ratio between the air and fuel used. This ratio can be calculated
through the default values: rair-fuel = mol of air/mol of fuel. The equivalent ratio is between the
air- fuel ratio for the current process and the air-fuel ratio for complete combustion, express as:
ER = rair-fuel (actual)/ rair-fuel (complete combustion) [69]. When considering the calorific power of the syngas
generated, the air-fuel ratio has the greatest impact. The equivalent-ratio enables the controlling
of tar and char generation.
!35
4.14 Reaction Temperature and Pressure
The reaction temperature is considered to be one of the most important parameters.
Depending on the type of fuel, the reaction temperature affects problems caused by ash build-up
and sintering. There is a decrease or increase in process efficiency that can happen by either
raising or lowering temperature that can lead to higher concentrations of tars and lower char
conversion e.g. raising the temperature causes an increase in CO and H2, but it reduces the CO2,
CH4, and H2O in the syngas [70]. Meanwhile, there are two types of pressure that can be used
during the gasification process, atmospheric pressure or pressurized (at higher pressures). The
consideration of costs must also be taken into account as pressurized is more efficient but also
implies a higher cost. An increase in operating pressure of the gasifier results in a reduction in
the amount of char and tar in the syngas generated [71].
4.15 Cleaning System
The gasification process causes the creation of tars in the syngas which are caused by
several factors: temperature, gasifying agent, equivalent ratio, residence time, and catalyst
additives. Controlling or treatment for the tar can be done during the primary process (inside the
gasifier) and during the secondary process (the hot cleaning of the gases generated).
Economically the more important of the two is the primary process [72]. The configuration of the
gasifier and the correct combination of catalysts used as well as the type of gasifier will directly
influence the reduction in tars generated.
!36
4.16 Gas Cleaning
In addition for the need to reduce tar during gasification, many more unwanted
substances are generated. Just as the need for the right combination of gasifier and additives/
catalysts to reduce the amount of particles created. There are two was of cleaning the gases
generated and that is both cold and hot cleaning systems with the latter increasing the efficiency
of gasification by 3-4% because the syngas will carry a greater amount of energy than when it is
cooled [73]. The main components of the gas systems are the following: cyclones, ceramic,
textile, bag filters, rotating particle separators, wet electrostatic precipitators, and water
scrubbers. The gas systems function to remove or capture the tars in the syngas. Consequently,
the capture or removal of the tars discards the energy they contain.
5 Economic Barriers and Cost-Benefit Analysis
In consideration of recent climate changes and environmental solutions to increase both
awareness and efficiency in the way corporations producing and utilizing fuels understand the
usage of energies, plasma gasification was introduced as a way to productively eliminate climate
collateral damage. Through examination of economical barriers, there is clear analysis of the cost
benefit scale that acknowledges both sides of the argument of maintaining and producing a
plasma gasification plant. Although extremely costly to begin with, there are ways to eliminate
costs into the future, and each plant should at least break even within five years.
Looking at the specifically economic side of a plasma gasification plant, we have to
understand the way costs play into the development of both the technology and implementation.
!37
According to a Columbia University study, analysis demonstrates that “capital costs of plasma-
assisted WtE are higher than the traditional WtE plant, especially due to the cost of the plasma
torches. The base plasma scenario conducted yielded a capital charge of $76.8 per ton of MSW
processed, higher than the estimated capital charge of $60/ton for a grate combustion WtE plant.
The detailed costs of each process were higher than the base case: $81/ton for Alter NRG, $86/
ton for Europlasma. The capital costs of the Plasco process was estimated at $86/ton, on the basis
of data from their pilot plant.” Given the costs provided, the energy/ton produced by the
technology of plasma gasification combustion is not justified by the costs it takes to create and
implement the technology – simply put, for most costs, given the current technological
conditions, the economic benefits derived do not outweigh the lost of capital for the short term.
Although there is a standard cost analysis of the way we interpret the energy utilized in
order to conduct plasma gasification, there is substantial evidence that the actual implication of
our understanding of plasma gasification actually lies in the already existence pool of waste
generation accumulated over the years. Instead of introducing the plasma gasification technology
as a brand new mechanism with no establishment of tools, we should instead look at MSW as an
“energy feedstock.” Currently, just in the United States alone, there is a 54% increase in waste
production in the past 17 years (See Figure 8).
Although there are current technologies for handling waste accumulation, none of which
is as effect or productive for the environment as plasma gasification. Instead of seeing waste as
trash, we should see it as an energy source. The currently reuse of waste and recycling only
reaches about 30% of all US households. We believe that the more effective way of creative a
cost benefit analysis is by taking into account the waste that already exists and using that as an
!38
asset to expedite the time period in which a plasma gasification plant becomes profitable. Any
type of feedstock (excluding nuclear waste), especially if already in existence, can be directly
processed. An important calculation to note is that although plasma gasification utilizes a lot of
electricity to power, the scales can still be easily tipped financially if the capital and operating
costs remain at a low once the technology becomes automated. We have accounted for all the
variables in our cost benefit analysis (See Figure 9). The analysis should demonstrate that given
the technological and economic barriers and limitations, there are still advantages to be played
into the benefits. We have accounted for the benefits and projected all financial forecasts beyond
two calendar years to demonstrate that there will be an acceleration of increased benefits after
the plant is set up. Including all mergers and acquisition costs and synergies as well, we believe
that generally, after two years, the plant should be able to produce more benefits than its cost
(including environmental concerns, not necessarily pure financials).
Currently the base plant costs are divided into $600 per ton of capacity, which ultimately
adds up to $220,000 per ton. Given the calculations, a typical 300 tpd plant is about $86.5
million dollars. The capital costs for an annual calculation capacity of 28 tons will generation a
payment of 10% per year, with an investment of $27 million to begin with. These costs added up
(also taken into account for our cost benefit analysis) will demonstrate that although the costs are
incredibly high when the plant first gets installed and built – the capital will be generated back.
However, the main economic barrier to be addresses is in fact that the plant is extremely costly.
At least for the first few years the plant is open, the cost will largely outweigh the benefits. This
investment is a long-term plan that both private and public investors (mainly the government)
need to able to be on board with.
!39
6 Implementation and Overcoming Barriers
The main political barrier for plasma gasification to gain widespread acceptance is the
lack of information and public support. Government intervention is impossible when both the
public and officials are misinformed or have no idea what the benefits/costs of plasma
gasification implementation are. As we have seen from the case studies in the U.S., there are
many false ideas that people have about plasma gasification. A few examples from the case
studies include how people think plasma gasification and incineration are synonymous, the
unjustified fear-mongering of high toxic emissions in St. Lucie, Florida (whereas plasma
gasification actually has a negative carbon footprint), among many more misconceptions. In a
political system where policies are enacted based on the amount of support an idea has, it is
extremely difficult for any plasma gasification implementation to occur with favorable policies
when the public has no informed opinion of what it actually is.
In order to overcome this lack of information, there should be two main efforts: private
and public. We have already demonstrated that certain policies and economic incentives are
absolutely necessary for successful implementation. However, without any public support, these
policies cannot be put into practice. Private companies have a major a role in educating its
consumers about plasma gasification’s benefits such that it is clear how it is simply the best WtE
technology that the world currently has. This can be achieved through several methods, such as
lobbying government officials, creating marketing campaigns, starting grassroots efforts,
promoting infrastructure/company synergies, etc. all of which require capital that energy
companies have at their disposal. It is extremely important that private companies acknowledge
!40
how large of a factor public support can be in forming and enacting policies that can assist in
changing the way the U.S. processes waste.
Public effort refers to government support. Besides providing policies that contribute
economic incentives, the government should have a role in legitimizing plasma gasification as
the best WtE alternative. With the technology to potentially supply 5% of U.S. total energy usage
while decreasing landfill waste and being economically feasible, plasma gasification represents a
strong case for being given a regulatory body [74]. Once a standardized organization is formed
within all types of government, (municipal, state, and federal), these task forces can consolidate
resources and gather public support that no private company has the ethos to do so. By having a
type of committee at the government level, similar to the EPA, the knowledge of plasma
gasification can be effectively spread with little distortion, due to the credibility and backing of a
legal force. This centralization of resources can have ripples throughout the scientific community
and general public, as the technical community will finally have a channel to convey the benefits
of plasma gasification to the average person. In the same manner that the U.S. EPA can provide
unbiased and strong research about the environment, the government has a large potential in
helping pave the way for information symmetry for plasma gasification implementation.
In order for most plasma gasification plants to overcome the economic barriers explained
previously, there must be a lot of measurements and actions taken by the government to provide
economic subsidies to compensate for the increase cost needed to maintain a plant annually.
There needs to be enough political push to find another way of reducing waste in an
environmentally efficient way. If there is not federal fiscal policies enacted to reduce the cost of
maintaining a plasma gasification plant, there might be complications in terms of keeping the
!41
plant sustainable. If we choose to not look at the government for financial subsidies, then
perhaps internal management at the plants must seek private investors looking for long term
return and are okay with there not being an immediate financial return. According to our
discounted cash flow analysis, it would take about a decade for the plant to able to pay off
dividends, so most likely private investors are the best way to overcome any economic barriers in
the way. Additionally, although very short term, it would also be extremely helpful in
overcoming plasma gasification plants’ biggest economic barrier if the plants can somehow cut
costs significantly to maintain the plant’s functions. However, this is another internal question
raised, though it is an effective way to reduce costs and knock down economic barriers.
A comparison between international and domestic case studies clearly demonstrates the
fact that there is an inopportune economic and political environment for plasma gasification
implementation in the United States. Plasma gasification offers many unique opportunities as a
new WtE technology, from reducing landfill waste and having lower emission footprints, all
while being economically efficient and flexible. From the international case studies, we see that
each country has had their own unique policy adaptations. In Japan, the government has the
initiative to invest capital and policies into new plasma gasification technologies. In China, as a
result of the policy cities taking responsibility of their own waste generation, plasma gasification
was the best WtE choice. In India, the penalties for air pollution had pushed Pune toward
implementing plasma gasification due to its clean emission and large flexibility for trash.
However, when looking at the United States, we see that there are simply no policies that provide
enough economic and political incentives to offset the high initial capital cost of plasma
gasification. In San Francisco, the economic projections were simply infeasible. In St. Lucie, the
!42
political atmosphere and unjustified fear-mongering contributed to the failures of plasma
gasification. As a result of our analyses of cases around the world, we have formulated a few
high-level strategies and policies that would greatly assist.
First, it is necessary for a standard organization or committee to be established such that
it can lead efforts for the technical community, government communication, and developing
standards. This committee would ideally be composed of government officials, plasma
gasification technology experts, community leaders, and representatives from relevant
corporations. The versatility and composition of this group allows this consolidation of talents to
take responsibility for several different challenges in many areas necessary for successful plasma
gasification implementation. This organization and its relevant subcommittees would play a
major role in legitimizing plasma gasification’s viability and existence as the best WtE
technology. After this organization is formed, it must take immediate steps to standardize plasma
gasifying plants and the inputs/outputs that it processes. This organization must have a
representative in the government at a level similar to the EPA that can regulate the design,
installation, and operation of plasma gasification. By providing the nation with information, this
will significantly lower the barriers to entry and provide incentives for plasma gasification
implementation. As we have seen before, the high initial costs are one of the largest barriers that
plasma gasification encounters because of the lack of precedent; this is very well demonstrated in
the case studies of California and Florida. It is absolutely essential that the organization has a
role in persuading the government to positively intervene for plasma gasification’s role in the
WtE sphere.
!43
Here are a few policy suggestions that the committee can implement as a result of its
collaboration with the technical community, private corporations, and government officials.
• Subsidy improvement for WtE technologies, especially differentiating incineration and
plasma gasification so that public opinion is swayed and plasma gasification rightly receives
more credits and incentives to its cleaner operation.
• Establishing criteria and test methods for certification of vitrified materials
• Accountability for specific counties so that areas are compelled to take responsibility for
their waste generation; this can lead to municipalities looking for the best WtE technology, most
likely plasma gasification.
• Community awareness, through the means of campaigns and publicity such that people
can see the true benefit and advantages of plasma gasification
• A demonstration and analysis of historical data such that it proves plasma gasification’s
worth to the country.
• Prioritization of development and implementation
• Further funding of research and literature on the plasma gasification process
• Test plants within Continental United States so that there is a precedent that can be
followed
!44
7 Appendix
Figure 8
!45
$0.00
$1,000.00
$2,000.00
$3,000.00
$4,000.00
$5,000.00
$6,000.00
$7,000.00
CurrentYear(CY)(MM)
YearDeprecia<onCost(MM)
OtherSetUp(MM)
PerAnnum(MM)
CY+1 CY+2
TotalCosts(PresentValue)
TotalCosts(FutureValue)
TotalBenefits(PresentValue)
TotalBenefits(FutureValue)
Figure 9
!46
8 References
1. Themelis, Nickolas J., and Charles Mussche. "2014 Energy and Economic Value of
Municipal Solid Waste (MSW), Including Non-Recycled Plastics (NRP, Currently Landfilled
in the Fifty States." Columbia University, Earth Engineering Center (2014): n. pag. 9 July
2014. Web. 11 Nov. 2015.
2. Ducharme, Caroline. "Technical and Economic Analysis of Plasma-assisted Waste-to-Energy
Processes." N.p., Sept. 2010. Web. 27 Nov. 2015.
3. Gray, Larry. "Plasma Gasification as a Viable Waste-to-Energy Treatment of Municipal Solid
Waste." Solid and Hazardous Waste Prevention and Control Engineering (2014): n. pag. 2
Apr. 2014. Web. 27 Nov. 2015.
4. Gray, Larry. "Plasma Gasification as a Viable Waste-to-Energy Treatment of Municipal Solid
Waste." Solid and Hazardous Waste Prevention and Control Engineering (2014): n. pag. 2
Apr. 2014. Web. 27 Nov. 2015.
5. Gray, Larry. "Plasma Gasification as a Viable Waste-to-Energy Treatment of Municipal Solid
Waste." Solid and Hazardous Waste Prevention and Control Engineering (2014): n. pag. 2
Apr. 2014. Web. 27 Nov. 2015.
6. Gray, Larry. "Plasma Gasification as a Viable Waste-to-Energy Treatment of Municipal Solid
Waste." Solid and Hazardous Waste Prevention and Control Engineering (2014): n. pag. 2
Apr. 2014. Web. 27 Nov. 2015.
7. Ducharme, Caroline. "Technical and Economic Analysis of Plasma-assisted Waste-to-Energy
Processes." N.p., Sept. 2010. Web. 27 Nov. 2015.
!47
8. Ducharme, Caroline. "Technical and Economic Analysis of Plasma-assisted Waste-to-Energy
Processes." N.p., Sept. 2010. Web. 27 Nov. 2015.
9. Arena, Umberto. "Process and Technological Aspects of Municipal Solid Waste Gasification.
A Review." Waste Management 32.4 (2012): 625-39. Web. 28 Nov. 2015.
10. Arena, Umberto. "Process and Technological Aspects of Municipal Solid Waste Gasification.
A Review." Waste Management 32.4 (2012): 625-39. Web. 28 Nov. 2015.
11. Mountouris, A., E. Voutsas, and D. Tassios. "Solid Waste Plasma Gasification: Equilibrium
Model Development and Exergy Analysis." Energy Conversion and Management 47.13-14
(2006): 1723-737. Web. 28 Nov. 2015.
12. Mountouris, A., E. Voutsas, and D. Tassios. "Solid Waste Plasma Gasification: Equilibrium
Model Development and Exergy Analysis." Energy Conversion and Management 47.13-14
(2006): 1723-737. Web. 28 Nov. 2015.
13. Mountouris, A., E. Voutsas, and D. Tassios. "Solid Waste Plasma Gasification: Equilibrium
Model Development and Exergy Analysis." Energy Conversion and Management 47.13-14
(2006): 1723-737. Web. 28 Nov. 2015.
14. Mountouris, A., E. Voutsas, and D. Tassios. "Solid Waste Plasma Gasification: Equilibrium
Model Development and Exergy Analysis." Energy Conversion and Management 47.13-14
(2006): 1723-737. Web. 28 Nov. 2015.
15. Mountouris, A., E. Voutsas, and D. Tassios. "Solid Waste Plasma Gasification: Equilibrium
Model Development and Exergy Analysis." Energy Conversion and Management 47.13-14
(2006): 1723-737. Web. 28 Nov. 2015.
!48
16. Pinto, Filomena, Helena Lopes, Rui Neto André, I. Gulyurtlu, and I. Cabrita. "Effect of
Catalysts in the Quality of Syngas and By-products Obtained by Co-gasification of Coal and
Wastes. 1. Tars and Nitrogen Compounds Abatement." Fuel 86.14 (2007): 2052-063. Web.
17. Arena, Umberto. "Process and Technological Aspects of Municipal Solid Waste Gasification.
A Review." Waste Management 32.4 (2012): 625-39. Web. 28 Nov. 2015.
18. Arena, Umberto. "Process and Technological Aspects of Municipal Solid Waste Gasification.
A Review." Waste Management 32.4 (2012): 625-39. Web. 28 Nov. 2015.
19. "Municipal Solid Waste." United States Environmental Protection Agency. U.S. EPA, 25
June 2015. Web. 04 Dec. 2015.
20. Ewall, Mike. Primer on Landfill Gas as Green Energy. Energy Justice Network, 2013. Web.
04 Dec. 2015.
21. Landes, Lynn. Landfills: Hazardous to the Environment. Zero Waste America, n.d. Web. 04
Dec. 2015.
22. "Municipal Solid Waste Facts and Figures." United States Environmental Protection Agency.
U.S. EPA, Feb. 2014. Web. 4 Dec. 2015.
23. Lacey, Stephen. "Look at How Much Waste America Puts Into Landfills Compared to
Europe." GTM. Green Tech Media, 3 June 2013. Web. 04 Dec. 2015.
24. MSW Generation Rates. Digital image. United States Environmental Protection Agency.
U.S. EPA, 2012. Web. 4 Dec. 2015.
25. "Benefits & Advantages." Westinghouse Plasma Corp, 2015. Web. 04 Dec. 2015.
26. "What Is Plasma Gasification and What Are the Advantages?" UTAG Green Energy
Technologies, 2014. Web. 04 Dec. 2015.
!49
27. "Overview of Greenhouse Gases." United States Environmental Protection Agency. U.S.
EPA, 3 Dec. 2015. Web. 04 Dec. 2015.
28. "Life Cycle Comparisons." Plasma Gasification vs. Incineration. AlterNRG, June 2010.
Web. 4 Dec. 2015.
29. "Energy Recovery from Waste." Plasma Gasification vs. Incineration. AlterNRG, June 2010.
Web. 4 Dec. 2015.
30. "Environmental Performance." Westinghouse Plasma Corp, 2015. Web. 04 Dec. 2015.
31. Lemmens, Bert. Elslander, Helmut. Vanderreydt, Ive. et al. Assessment of plasma
gasification of high caloric waste streams, Waste Management, Volume 27, Issue 11, 2007,
Pages 1562-1569, ISSN 0956-053X, http://dx.doi.org/10.1016/j.wasman.2006.07.027.
32. Dodge, Ed. "Plasma Gasification: Clean Renewable Fuel through Vaporization of Waste."
Harvard University, 7 Jan. 2009. Web. 4 Dec. 2015.
33. "What Is Plasma Gasification and What Are the Advantages?" UTAG Green Energy
Technologies, 2014. Web. 04 Dec. 2015.
34. "Incinerators: Myths vs. Facts about ‘Waste to Energy’." Global Alliance for Incinerator
Alternatives, Feb. 2012. Web. 4 Dec. 2015.
35. "Environmental Benefits." Alliance Federated Energy, 2010. Web. 04 Dec. 2015.
36. "Why Plasma Gasification." Alliance Federated Energy, 2010. Web. 04 Dec. 2015.
37. Gomez, E. Rani, Amutha. Cheeseman, C.R. et al. Thermal plasma technology for the
treatment of wastes: A critical review, Journal of Hazardous Materials, Volume 161, Issues
2–3, 30 January 2009, Pages 614-626, ISSN 0304-3894, http://dx.doi.org/10.1016/j.jhazmat.
2008.04.017.
!50
38. "Plasma Gasification Summary.” Plasma Gasification vs. Incineration. AlterNRG, June
2010. Web. 4 Dec. 2015.
39. Sims, Bryan. "Proving Out Plasma Gasification." BioMass Magazine, 2015. Web. 04 Dec.
2015.
40. "Plasma Gasification Turning Waste to Fuel in China." Waste Management World. 30 Jan.
2013. Web. 4 Dec. 2015.
41. "Scaling Up to 100MW." SGC International Conference on Gasification. Malmo, Sweden.
16 Oct. 2014. Lecture.
42. "Alter NRG Reports 2014 Activities and Financial Resuls." Alter NRG. 18 Mar. 2015. Web.
4 Dec. 2015. <http://www.alternrg.com/wp-content/uploads/2015/03/March-18-2015-Q4-
Results-Press-Release.pdf>.
43. "Alter NRG to Supply 15 MW Plasma Gasification Waste to Energy Plant in China." Waste
Management World. 3 Mar. 2014. Web. 4 Dec. 2015. <http://waste-management-world.com/
a/alter-nrg-to-supply-15-mw-plasma-gasification-waste-to-energy-plant-in-china>.
44. Willis, Ken P., Shinichi Osada, and Kevin L. Willerton. "Plasma Gasification: Lessons
Learned at Eco-Valley WtE Facility." 18th Annual North American Waste-to-Energy
Conference. Print.
45. Circeo, Louis, and Robert Martin. "Plasma Power Environmental & Engineering
Applications of Plasma Arc Technology." Georgia Tech Alumni Seminar Briefing. Lecture.
46. Jha, Prem Shakar. "Turning Garbage into Gas." The Hindu. 17 July 2013. Web. 4 Dec. 2015.
47. Annepu, Ranjith. "A Billion Reasons for Waste to Energy in India." « Recycling « Waste
Management World. 19 Dec. 2013. Web. 4 Dec. 2015.
!51
48. Prinzing, David. "Sacramento Waste-to-Energy Facility." Sacramento Press, 05 Dec. 2008.
Web. 04 Dec. 2015.
49. "Sacramento." USST, 2008. Web. 04 Dec. 2015. <http://www.usstcorp.com/
sacramento.html>.
50. “November 18th Public Comment." Sacramento Granicus, Nov. 2008. Web. 4 Dec. 2015.
<http://sacramento.granicus.com/MetaViewer.php?
view_id=22&clip_id=1652&meta_id=161135>.
51. Veen, Chad. "Plasma Gasification Plan Goes Up in Smoke for Sacramento, Calif." Digital
Communities, 19 Jan. 2009. Web. 04 Dec. 2015.
52. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
53. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
54. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
!52
55. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
56. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
57. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
58. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
59. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
60. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
!53
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
61. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
62. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
63. Materazzi, M., P. Lettieri, R. Taylor, and C. Chapman. "Performance Analysis of RDF
Gasification in a Two Stage Fluidized Bed–plasma Process." Performance Analysis of RDF
Gasification in a Two Stage Fluidized Bed–plasma Process. ELSEVIER, 13 July 2015. Web.
30 Nov. 2015.
64. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
65. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
!54
66. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
67. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
68. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
69. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
70. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
71. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
!55
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
72. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
73. Ruiz, J. A., M. C. Juarez, M. P. Morales, P. Munoz, and M. A. Mendivil. "Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers." Biomass
Gasification for Electricity Generation: Review of Current Technology Barriers.
ELSEVIER, 9 Nov. 2012. Web. 27 Nov. 2015.
74. Pourali, M., "Application of Plasma Gasification Technology in Waste to Energy—
Challenges and Opportunities," in Sustainable Energy, IEEE Transactions on , vol.1, no.3,
pp.125-130, Oct. 2010 doi: 10.1109/TSTE.2010.2061242
!56