industrial graphene applications. -...

Industrial Graphene Applications.

Dr. Javier Perez jperez@avanzare.es www.avanzarematerials.com

Monterrey 2017,

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Índice:

- Quienes somos?

- Que hacemos?

- Grafeno, que es y porque tanta expectación

- Aplicaciones futuras

- Aplicaciones industriales

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Índice:

- Quienes somos?- Que hacemos?

- Grafeno, que es y porque tanta expectación

- Aplicaciones futuras

- Aplicaciones industriales

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-Spanish group, leader in the nanomaterials production and specialized from 10

years ago in the production of 2D nanomaterials and its dispersions for different

industries: automotive, aeronautic, plastic, rubber, painting, building industries, wire an

cable sector, packaging and paper, among others.

- avanzare has 2 facilities located in the north of Spain with more than 5.000 m2 and

annual production 100 Tm/year

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2000 m2 plant

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10 Tm/year HRGO

20 Tm/year GO

50 Tm/year GRM

3000 m2 2nd plant

Positive turnover of the

graphene line/division

Positive turnover

10000 m2 new plant

China and IndiaMexicoEurope

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Sales in more than 45 countries avanzare

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Desarrollo completo desde la idea hasta la certificación del producto

Donde interviene el grupo avanzare?

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Desarrollo

e investigación de la idea

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Certificación producto

Producción de

nuevos aditivos

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Índice:

Quienes somos?-

Que hacemos?-Grafeno, que es y porque tanta expectación -

- Aplicaciones futuras

- Aplicaciones industriales

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Avanzare not only commercializes graphene and its derivatives, but since the

beginning we have been closely linked to the nanomaterials sector. Avanzare offers

different solutions: by one hand, solutions only based on nanomaterials; and on the

other, products in which we are looking for synergistic effects between different

types of materials.

• ANTISTATICS

• ANTI-BACTERIAL

• FLAME-RETARDANT

• CHEMICAL

TRADEMARK

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What allows us to offer nanotechnology when designing an anti-static additive?

• Permanent Effect

• Colorable

• Non humidity dependence

• Low Dosage required

• Resistivity Range 106-109

Ohms

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What allows us to offer nanotechnology when designing an anti-static additive?

Movilidad iónica en la matriz

Conductores IónicosIonic Conductors

Ionic mobility through the matrix

Migration

Percolation

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What allows us to offer nanotechnology when designing an anti-static additive?

Graphene-basedsolutions

TPU

Rubber

PU

EVA

PVC

Epoxi

Polyolefins

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What allows us to offer nanotechnology when designing an anti-bacterial additive?

• ANTI-BACTERIAL

• ANTI-FUNGI

• ANTI-MOLD

• ANTI-ALGAE

• ANTI-ODOR

• COLORABLE

• ULTRA-LOW DOSAGE

• COST-EFFECTIVE

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What allows us to offer nanotechnology when designing a flame-retardant additive?

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• LOW DOSAGE

• HALOGEN-FREE

• ANTIMONY OXIDE FREE

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What allows us to offer nanotechnology when designing a chemical

tademark additive?

• They allow differentiating your material/blend so that illegitimate claims will

be avoided.

• Disincentive and entry barrier for unsafe raw materials suppliers.

• They enable to reduce costs on civil liability insurance.

• Tailor made in terms of design and security levels preferences.

• Very low required dosage and cost repercussion.

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Índice:

Quienes somos?-

Que hacemos?-

Grafeno, que es y porque tanta expectación -- Aplicaciones futuras

- Aplicaciones industriales

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graphene-flagship.eu/

Proyecto europeo único y pionero.

- Inversión Publico privada de 1.000 Millones de euros en 10 años--- (22,000 Millones de Pesos)

Mas de - 150 entidades (todos los ámbitos de la ciencia, universidades, centros aplicadores, productos)

Avanzare Productor de - bulk grafeno oficial

Similares programas hay en china y USA.

CUIDADO CON LA BURBUJA:

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MARKETING ?????????

PERFORMANCE

0,04% graphene

Electrical conductivity

and non black

50-100% increase in

mechanical properties

Why graphene????Por que tanto revuelo???

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Márquetin o no !!!!!!!

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Types and classification Performance:

Why there are so many potential application..

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2 Grandes metodos…

METANO

GRAFITO

Descomposicion, CVD etc

Exfoliaion

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METANO

Características:

- Tranparente

- Monocapa

- Eje X/Y …. En cm…

- Precio imposible para composites..

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- Valido para ser dispersado con otros materiales ( composites)

- Material en apariencia negro

- Tamaño X/Y …. Micras.

- Precios de todo tipo.

Exfoliaion

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Key features for graphene grades classification

- Oxygen content

- Lateral size

- Average number of layers

- Average thickness

- BETavanzare

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+ Graphene/Graphite

nanoplatelets

Bulk graphene grades categories, according to oxygen content

- Highly reduced graphene

oxide

- Partially reduced graphene

oxide

- Graphene oxide

- Pristine graphene

C2O

C5O

C15O

C35O

C50O

C90O

C150O

C250O

C330O

Ox

yg

en

C

on

ten

t

+ Tailor-made graphene

grades avanzare

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Classification Framework for Graphene-Based Materials. Angew. Chem. Int. Ed. 2014, 53,

7714 – 7718 & Recommended nomenclature for 2D carbon materials: Bianco & all.

CARBON 65, 2013,1-6

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Bulk graphene production methods

- Pristine graphene

- Highly reduced graphene

oxide

- Partially reduced graphene

oxide

- Some Graphene/Graphite

nanoplatelets

- Some Graphene/Graphite

nanoplatelets

- Graphene oxide

avanzare’s GRADES

- Some Graphene/Graphite

nanoplatelets

The global growth of graphene. Nature Nanotechnology 9, 726–

730 (2014)

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As an effective vehicle to transfer nano-scale features to high-throughput industrial production

Nanointermediat

e

Nanomateri

al

Nano-enabled

products

Nano-intermediates

Nanomateri

alsNano-

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Bulk Masterbatch Dispersion Filament for 3D printing

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Continue improving scale-up production (faster, cheaper, with less defects)

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Composites applications

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Electrical Conductivity

Electrical Efficiency

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Electrical conductivity of PA6-composites (from MB)

Ultra-low percolation

threshold by melt compounding

No re-agglomerated

and

well dispersed

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Filament winding

= insulate

Not valid for ATEX application

Conductive Carbon black

Carbon sheet

- Performance good- High Price

Complicate - conectioninside/outsideComplicate small pieces.-

- Difficult Procesability

(unusable viscosity)

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Filament winding

= insulate

Not valid for ATEX application

Graphene/ GNP

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Thermal Conductivity

Material Thermal Conductivity at

25°C (W·m-1·K-1)

Graphite 100-400

Carbon Black 6-174

Copper 483

Silver 450

Boron Nitride 250-300

Aluminium oxide 20-29

Carbon nanotubes 2000-6000

Diamond 2000

Graphene 800-5000

Fonon movements

8-10 times

more

dense

The amount required

depends on the density of

the material

➢ Processing problems

➢ Density

➢ Mechanical Property

➢ Fragility

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Thermal Dissipation

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Solar Thermal Energy

➢ 53% less time to reach 30°C

➢ Temperature 17% higher after 30 min

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Graphite

MWCNTs

Graphene

Graphene + Py-PGMA

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Other applications

Lamp Cooling

Thermostatic Roller

cavity

walls

underfloor

heating

Coolant

Thermal Oil Heating Systems

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Polym. Adv. Technol. 2016, 27 303–307

The results showed that graphene acts as a nucleant agent at very small (0.3

wt%) amount leading to a foam with a smaller average cell diameter with

respect to un-filled foam

At that level (0,3 wt%) the thermal conductivity is lower (18%)

PU foam PU + 0,3% Graphene PU + 0,5% Graphene

More stable

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Flame Retardant

• Each type of material presents different fire behavior, so there must

be different solutions.

• Depending on the type of material (GOx, graphene, GNPs ... other

FR materials) there will be a different fire behavior:

- Active / reactive against fire

- Catalytic Properties

- Barrier or Chart Effect

- Anti-drip

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Physical:• Cooling effect (releasing water, etc.)

• Formation of protective layer

• Dilution

• Decrease in dripping effect

Chemistry:• Free radical scavenger

• Catalytic degradation of the polymer and / or chart creation

• Reduce the concentration of flammable gases in the polymer and / or O2

• Creation of intumescent layers, alone, or combined with other FR

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How does graphene work?

• Barrier formation

• Migrating graphene .... Small size

• Other effects:

o Prevent the movement of macromolecules by crosslinking

the polymer chains

o Catalytic formation of intumescent layers type chart

o Active RF encapsulation / intercalation: ammonium salts ....

o Capture of radicals .... Usually by metals in the layer of

graphene .... "Graphene decorated"

o Smoke Reduction

o Anti-drippingavanzare

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6 BL 0.5M

3 BL 0.5M

1 BL 0.5M

6 BL

3 BL

1 BL

PU

--

6 BL PDAC/GO 0.5M

6 BL PDAC/GO

3 BL PDAC/GO 0.5M

3 BL PDAC/GO

1 BL PDAC/GO 0.5M

1 BL PDAC/GO

PU

0 10 20 30 40 50 60 70 80 90 100Residue [%]

Melt-dripping No Melt-dripping Self-extinguishment

0%FLAMMABILITY OF LBL

COATED PU

V0 with less than 10% ... And even with less than

6% !!!

Epoxy Resin

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PA6

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Mechanical Properties

Test According to

Tensile ASTM D638 - 10

Flexural ASTM 790 - 03

MFI ISO 1133

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Photocatalysis

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Sensing application

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Fire detection in composites..

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