hcl, h+ + cl hcl+ f(hcl*) x(hcl): agust,heima,....rempi/hcl/hcl,agust07-/hcl-potentials-181007ak.pxp...

HCl, H+ + Cl HCl+ F(HCl*) X(HCl):

agust,heima, ....REMPI/HCl/HCl,agust07-/HCl-Potentials-181007ak.pxpagust,www, ....rempi/hcl/HCl,agust07-/HCl-Potentials-181007ak.ppt

REMPI via F, v´=0,1,2

•HCl+ and HCl** potentials from Chichinin et al (JCP, 124,224324, (06)) included as:

• X(HCl+), A(HCl+*), (2) 2P (repulsive) originating from Pradhan et al.Superexcited states from table IV in Chichinin et al (JCP, 124,224324, (06))

150x103

100

50

0

E [c

m-1

]

54321

r [Å]

H+Cl*(4P)

H+Cl*(2P)

V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)

H+Cl*(4D)

H+Cl*(2D)

H+Cl*(2D)

E <-- H+Cl*(2P)

F <-- H+Cl*(4S)

H+Cl*(2S/2P)

H+Cl*(4D)H+Cl*(4F)H+Cl*(4P)

H+Cl*(2D)

H+Cl*(2F)

H+Cl*(2P)

H+Cl

H+Cl+

H+ +Cl

X(HCl+) 2

HCl**

(4p) 1

HCl**

(4s) 1

A(HCl+) 2

A(HCl+) (2)

2

r/A

F

160x103

140

120

100

80

E [c

m-1

]

54321

r [Å]

H+Cl*(4P)

H+Cl*(2P)

V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)

H+Cl*(4D)

H+Cl*(2D)

H+Cl*(2D)

E <-- H+Cl*(2P)

F <-- H+Cl*(4S)

H+Cl*(2S/2P)

H+Cl*(4D)

H+Cl*(4F)H+Cl*(4P)

H+Cl*(2D)

H+Cl*(2F)

H+Cl*(2P)

H+Cl

H+Cl+

H+ +Cl

X(HCl+) 2

HCl**

(4p) 1

HCl**

(4s) 1

A(HCl+) 2

A(HCl+) (2)

2

Excitation via F,v´=0

160x103

140

120

100

80

E [c

m-1

]

54321

r [Å]

H+Cl*(4P)

H+Cl*(2P)

V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)

H+Cl*(4D)

H+Cl*(2D)

H+Cl*(2D)

E <-- H+Cl*(2P)

F <-- H+Cl*(4S)

H+Cl*(2S/2P)

H+Cl*(4D)

H+Cl*(4F)H+Cl*(4P)

H+Cl*(2D)

H+Cl*(2F)

H+Cl*(2P)

H+Cl

H+Cl+

H+ +Cl

X(HCl+) 2

HCl**

(4p) 1

HCl**

(4s) 1

A(HCl+) 2

A(HCl+) (2)

2

Excitation via F,v´=1

160x103

140

120

100

80

E [c

m-1

]

54321

r [Å]

H+Cl*(4P)

H+Cl*(2P)

V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)

H+Cl*(4D)

H+Cl*(2D)

H+Cl*(2D)

E <-- H+Cl*(2P)

F <-- H+Cl*(4S)

H+Cl*(2S/2P)

H+Cl*(4D)

H+Cl*(4F)H+Cl*(4P)

H+Cl*(2D)

H+Cl*(2F)

H+Cl*(2P)

H+Cl

H+Cl+

H+ +Cl

X(HCl+) 2

HCl**

(4p) 1

HCl**

(4s) 1

A(HCl+) 2

A(HCl+) (2)

2

Excitation via F,v´=2