hcl, h+ + cl hcl+ f(hcl*) x(hcl): agust,heima,....rempi/hcl/hcl,agust07-/hcl-potentials-181007ak.pxp...
Post on 20-Dec-2015
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HCl, H+ + Cl HCl+ F(HCl*) X(HCl):
agust,heima, ....REMPI/HCl/HCl,agust07-/HCl-Potentials-181007ak.pxpagust,www, ....rempi/hcl/HCl,agust07-/HCl-Potentials-181007ak.ppt
REMPI via F, v´=0,1,2
•HCl+ and HCl** potentials from Chichinin et al (JCP, 124,224324, (06)) included as:
• X(HCl+), A(HCl+*), (2) 2P (repulsive) originating from Pradhan et al.Superexcited states from table IV in Chichinin et al (JCP, 124,224324, (06))
150x103
100
50
0
E [c
m-1
]
54321
r [Å]
H+Cl*(4P)
H+Cl*(2P)
V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)
H+Cl*(4D)
H+Cl*(2D)
H+Cl*(2D)
E <-- H+Cl*(2P)
F <-- H+Cl*(4S)
H+Cl*(2S/2P)
H+Cl*(4D)H+Cl*(4F)H+Cl*(4P)
H+Cl*(2D)
H+Cl*(2F)
H+Cl*(2P)
H+Cl
H+Cl+
H+ +Cl
X(HCl+) 2
HCl**
(4p) 1
HCl**
(4s) 1
A(HCl+) 2
A(HCl+) (2)
2
r/A
F
160x103
140
120
100
80
E [c
m-1
]
54321
r [Å]
H+Cl*(4P)
H+Cl*(2P)
V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)
H+Cl*(4D)
H+Cl*(2D)
H+Cl*(2D)
E <-- H+Cl*(2P)
F <-- H+Cl*(4S)
H+Cl*(2S/2P)
H+Cl*(4D)
H+Cl*(4F)H+Cl*(4P)
H+Cl*(2D)
H+Cl*(2F)
H+Cl*(2P)
H+Cl
H+Cl+
H+ +Cl
X(HCl+) 2
HCl**
(4p) 1
HCl**
(4s) 1
A(HCl+) 2
A(HCl+) (2)
2
Excitation via F,v´=0
160x103
140
120
100
80
E [c
m-1
]
54321
r [Å]
H+Cl*(4P)
H+Cl*(2P)
V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)
H+Cl*(4D)
H+Cl*(2D)
H+Cl*(2D)
E <-- H+Cl*(2P)
F <-- H+Cl*(4S)
H+Cl*(2S/2P)
H+Cl*(4D)
H+Cl*(4F)H+Cl*(4P)
H+Cl*(2D)
H+Cl*(2F)
H+Cl*(2P)
H+Cl
H+Cl+
H+ +Cl
X(HCl+) 2
HCl**
(4p) 1
HCl**
(4s) 1
A(HCl+) 2
A(HCl+) (2)
2
Excitation via F,v´=1
160x103
140
120
100
80
E [c
m-1
]
54321
r [Å]
H+Cl*(4P)
H+Cl*(2P)
V <-- H+ + Cl- H*(2s2S)+ClH*(2p2P)+Cl H+Cl*(4P)
H+Cl*(4D)
H+Cl*(2D)
H+Cl*(2D)
E <-- H+Cl*(2P)
F <-- H+Cl*(4S)
H+Cl*(2S/2P)
H+Cl*(4D)
H+Cl*(4F)H+Cl*(4P)
H+Cl*(2D)
H+Cl*(2F)
H+Cl*(2P)
H+Cl
H+Cl+
H+ +Cl
X(HCl+) 2
HCl**
(4p) 1
HCl**
(4s) 1
A(HCl+) 2
A(HCl+) (2)
2
Excitation via F,v´=2