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©2000 Rohm and Haas Company EDS 0359 A - Apr. 96 - 1/2

AMBERJET® 1200 Na

ENGINEERING DATA SHEET(H2SO4, Co-flow regeneration)

These data provide information to calculate the sodiumleakage and operating capacity of AMBERJET 1200 Naused in water demineralisation with co-flowregeneration with sulphuric acid. The properties ofAMBERJET 1200 Na are described in the Product DataSheet PDS 0354 A.These data are valid for Amberjet 1200 H but theresults obtained refer to the Na form and must becorrected for the reversible swelling between the Naand H forms.

SODIUM LEAKAGE

The average sodium leakage is obtained by multiplyingthe basic leakage value from Table 1 by the correctionfactors A and B from Tables 2 and 3.

Leak = Leak0 x A x B

Table 1 : Basic Sodium Leakage versus H2SO4Regenerant Level

H2SO4 g/L Leakage % EMA

(Leak0)

60 11.770 10.480 9.2

100 7.2120 5.7140 4.5160 3.5200 2.2240 1.4

Note : Sodium leakage values are expressed as apercentage of the equivalent mineral acidity (EMA).

Table 2 : Leakage Correction Factor A vs Alkalinity toTotal Anions Ratio

Alk % Factor A0 0.6520 0.7740 0.9160 1.0880 1.2899 1.52

Table 3 : Leakage Correction Factor B versus Sodium toTotal Cations Ratio

Na % Factor B10 0.0620 0.1730 0.3340 0.5250 0.7560 1.0070 1.2880 1.5890 1.91

Table 4 : Suggested Operating Conditions

Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 800 mmService flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ H2SO4 in stepped concentrations

Level ________________________________________ 60 to 200 g/LMinimum contact time ________________________ 20 minutesConcentration ________________________________ 0.7 to 6 % according to Ca content

Slow rinse _____________________________________ 2 BV at regeneration flow rateFast rinse ______________________________________ 1 to 3 BV at service flow rate

* 1 BV (Bed volume) = 1 m3 solution per m3 resin

Rohm and Haas/Ion Exchange Resins - Philadelphia, PA - Tel. (800) RH AMBER - Fax: (215) 537-4157Rohm and Haas/Ion Exchange Resins - 75579 Paris Cedex 12 - Tel. (33) 1 40 02 50 00 - Fax : 1 43 45 28 19

WEB SITE: http://www.rohmhaas.com/ionexchange

AMBERJET is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to which organicby-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user must ensurecompliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and Haas Company doesnot recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult your Rohm and Haas technicalrepresentative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eye and skin contact. Nitric acidand other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipment to prevent rapid buildup ofpressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with Ion Exchange Resins, consult sourcesknowledgeable in the handling of these materials. Rohm and Haas Company makes no warranties either expressed or implied as to the accuracy of appropriateness of this data and expressly excludes any liability upon Rohm and Haasarising out of its use. We recommend that the prospective users determine for themselves the suitability of Rohm and Haas materials and suggestions for any use prior to their adoption.Suggestions for uses of our products of the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommendingthe use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Material Safety Data Sheets outlining the hazards andhandling methods for our products are available on request.


OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Na withsulphuric acid regeneration is obtained by multiplying thebasic capacity value from table 5 by the correction factorsC to F from tables 6 to 9.

Cap = Cap0 x C x D x E x F

Table 6 : Capacity Correction Factor C versus Alkalinity toTotal Anions Ratio

Alk % Factor C0 0.9330 0.9750 1.0070 1.03

100 1.08

Table 5 : Basic Capacity vs H2SO4 Regenerant Level and

Sodium to Total Cations Ratio (Co-flow reg.)

% Na 0 25 50 75 100

H2SO4(g/L)

60 0.53 0.56 0.62 0.71 0.8570 0.57 0.61 0.69 0.79 0.9480 0.60 0.66 0.75 0.87 1.02

100 0.65 0.73 0.85 0.99 1.15120 0.68 0.78 0.92 1.09 1.26140 0.71 0.81 0.97 1.16 1.35160 0.73 0.83 1.00 1.21 1.42200 0.76 0.86 1.04 1.28 1.54240 0.80 0.92 1.10 1.34 1.66

Table 7 : Capacity Correction Factor D versus Magnesium to Hardness Ratio, Sodium to Total Cations Ratio and Alkalinity toTotal Anions Ratio

Mg/TH 0 % Na 50 % Na 80 % Na% 0 50 99 % Alk 0 50 99 % Alk 0 50 99 % Alk0 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

20 1.11 1.09 1.07 1.06 1.05 1.04 1.02 1.02 1.0140 1.22 1.18 1.14 1.11 1.09 1.07 1.04 1.04 1.0360 1.33 1.27 1.21 1.17 1.14 1.11 1.07 1.05 1.0480 1.44 1.36 1.28 1.22 1.18 1.14 1.09 1.07 1.06

100 1.55 1.45 1.35 1.28 1.23 1.18 1.11 1.09 1.07

Table 8 : Capacity Correction Factor E versus Run Length(Production Time)

Run Time 0 50 99 % Alk (hours)

5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02

Table 9 : Capacity Correction Factor F versus WaterTemperature

Temperature°C 0 50 99 % Na

5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06


AMBERJET® 1200 Na

ENGINEERING DATA SHEET(H2SO4, Reverse flow regeneration)

These data provide information to calculate the sodiumleakage and operating capacity of AMBERJET 1200 Naused in water demineralisation with reverse flow(counterflow) regeneration with sulphuric acid.The properties of AMBERJET 1200 Na are described inthe Product Data Sheet PDS 0354 A.These data are valid for AMBERJET 1200 H but theresults obtained refer to the Na form and must becorrected for the reversible swelling between the Naand H forms.

SODIUM LEAKAGE

The average sodium leakage can be read directly fromTable 1. In reverse flow regeneration, the leakage isalways very low so that in industrial applications atreated water conductivity of about 1 µS/cm or lowercan be obtained in most cases.

Table 1 : Average Sodium Leakage versus H2SO4Regenerant Level

H2SO4 g/L Leakage ppm Na

40 0.1250 0.0760 0.0570 0.0480 0.03

OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Na withsulphuric acid regeneration is obtained by multiplyingthe basic capacity value from Table 2 by the correctionfactors A to E from Tables 4 to 8 overleaf.

Cap = Cap0 x A x B x C x D x E x F

Table 2 : Basic capacity versus H2SO4 Regenerant level

H2SO4 g/L Capacity eq/L

(Cap0)

40 0.6250 0.7260 0.8070 0.8780 0.9390 0.99

100 1.03120 1.11140 1.18160 1.24


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ H2SO4 in stepped concentrations

Level ______________________________________ 40 to 160 g /LMinimum contact time _______________________ 20 minutesConcentration ______________________________ 0.7 to 6 % according to Ca content




WEB SITE: http:// www.rohmhaas.com/ ionexchange



Table 4 : Capacity Correction Factor A versus Sodium toTotal Cations Ratio

Na % Factor A0 0.7410 0.8120 0.8630 0.9140 0.9650 1.0060 1.0470 1.0780 1.1090 1.13

100 1.16

Table 7 : Capacity Correction Factor D versus WaterTemperature


5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06

Table 5 : Capacity Correction Factor B vs Alkalinity toTotal Anions Ratio

% Alk Factor B

0 0.9425 0.9850 1.0075 1.0299 1.03

Table 6 : Capacity Correction Factor C versus Resin BedDepth

Bed depth Factor Cmm

900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10

Table 8 : Capacity Correction Factor E vs Run Length(Production Time)


5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02


AMBERJET® 1200 Na

ENGINEERING DATA SHEET(HCl, Co-flow regeneration)

These data provide information to calculate thesodium leakage and operating capacity ofAMBERJET 1200 Na used for waterdemineralisation with co-flow regeneration withhydrochloric acid. The properties of AMBERJET1200 Na are described in the Product Data SheetPDS 0354 A.These data are valid for Amberjet 1200 H but theresults obtained refer to the Na form and must becorrected for the reversible swelling between theNa and H forms.

SODIUM LEAKAGE

The average sodium leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factor A from Table 2.

Leak = Leak0 x A

Table 1 : Basic Sodium Leakage versus HClRegenerant Level

HCl g/L Leakage % EMA(Leak0)

50 3.960 3.070 2.580 2.0

100 1.5120 1.2150 0.9

Note : Sodium leakage values are expressed as apercentage of the equivalent mineral acidity(EMA).

The value obtained in meq/L must be convertedto mg/L as Na and eventually to a conductivityvalue, using the graph supplied in the Memento ofIon Exchange published by Rohm and Haas.

Table 2 : Leakage Correction Factor A versusSodium to Total Cations Ratio

Na % Factor A10 0.1520 0.3030 0.5040 0.7550 1.0060 1.3070 1.7080 2.2090 2.80

100 3.60


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 800 mmService flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ HCl

Level ______________________________________ 50 to 150 g/LMinimum contact time ______________________ 20 minutesConcentration ______________________________ 4 to 10 %







OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Na withhydrochloric acid is obtained by multiplying thebasic capacity value from table 4 by the correctionfactors B to E from tables 5 to 8.

Cap = Cap0 x B x C x D x E

Table 4 : Basic Capacity versus HCl Regenerant Level(co-flow regen.)

HCl g/L Capacity eq/L(Cap0)

50 0.9360 1.0270 1.1080 1.1790 1.23

100 1.28120 1.37150 1.47

Table 7 : Capacity Correction Factor D versusWater Temperature


5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06

Table 5 : Capacity Correction Factor B versus Sodiumto Total Cations Ratio

Na % Factor B

0 1.0010 0.9820 0.9730 0.9740 0.9850 1.0060 1.0270 1.0580 1.0990 1.13

100 1.16

Table 6 : Capacity Correction Factor C versusAlkalinity to Total Anions Ratio

% Alk Factor C

0 0.9530 0.9850 1.0070 1.0299 1.05

Table 8 : Capacity Correction Factor E versus RunLength (Production Time)


5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02


AMBERJET® 1200 Na

ENGINEERING DATA SHEET(HCl, Reverse flow regeneration)

These data provide information to calculate thesodium leakage and operating capacity ofAMBERJET 1200 Na used in waterdemineralisation with reverse flow (counterflow)regeneration with hydrochloric acid.The properties of AMBERJET 1200 Na aredescribed in the Product Data Sheet PDS 0354 A.These data are valid for AMBERJET 1200 H butthe results obtained refer to the Na form and mustbe corrected for the reversible swelling betweenthe Na and H forms.

SODIUM LEAKAGE

With reverse flow regeneration, the averagesodium leakage is always very low (less than 100ppb as Na when regenerated with HCl) so that inindustrial applications a treated water conductivityof about 1 µS/cm or lower can be obtained inmost cases.

OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Nawith hydrochloric acid regeneration is obtained bymultiplying the basic capacity value from Table 1by the correction factors A to E from Tables 3 to 7overleaf.

Cap = Cap0 x A x B x C x D x E

Table 1 : Basic capacity vs HCl Regenerant Level(reverse flow regeneration)


40 1.0350 1.1560 1.2470 1.3280 1.3990 1.44

100 1.49120 1.57


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ HCl

Level ______________________________________ 40 to 120 g /LMinimum contact time ______________________ 20 minutesConcentration ______________________________ 4 to 10 %

Slow rinse _____________________________________ 2 BV at regeneration flow rate

Fast rinse ______________________________________ 1 to 3 BV at service flow rate






Table 3 : Capacity Correction Factor A versus Sodiumto Total Cation Ratio

Na % Factor A0 0.9510 0.9620 0.9730 0.9740 0.9850 0.9960 0.9970 1.0080 1.0190 1.01

100 1.02



5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06

Table 4 : Capacity Correction Factor B versusAlkalinity to Total Anions Ratio

% Alk Factor B

0 0.9430 0.9850 1.0070 1.0299 1.03

Table 5 : Capacity Correction Factor C versus ResinBed Depth


900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10



5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02


AMBERJET® 1200 Na

ENGINEERING DATA SHEET(Softening, Co-flow regeneration)

These data provide information to calculate thehardness leakage and operating capacity ofAMBERJET 1200 Na used for water softening withco-flow regeneration.The properties of AMBERJET 1200 Na aredescribed in the Product Data Sheet PDS 0354 A.

HARDNESS LEAKAGE

The average hardness leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factors A and B from Tables 2and 3.


Table 1 : Basic Hardness Leakage versus NaClRegenerant Level

NaCl g/L Leakage meq/L(Leak0)

70 0.063100 0.051130 0.042150 0.036200 0.026250 0.018

Table 2 : Leakage Correction Factor A vs TotalDissolved Solids Concentration

TDS Factor Ameq/L

< 10 1.015 1.920 3.030 5.840 9.1

Table 3 : Leakage Correction Factor B versusSodium to Total Cations Ratio

Na % Factor B< 5 1.0

10 1.320 1.630 1.950 2.570 3.190 3.7


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 800 mmService flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ NaCl

Level ______________________________________ 80 to 240 g/LMinimum contact time ______________________ 20 minutesConcentration ______________________________ 10 %








OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Na inwater softening is obtained by multiplying the basiccapacity value from table 5 by the correction factorsC to F from tables 6 to 9.


Table 5 : Basic Capacity versus NaCl Regenerant Level(co-flow regeneration)

NaCl g/L Capacity eq/L(Cap0)

80 1.07100 1.19120 1.28150 1.40200 1.56250 1.68

Table 6 : Capacity Correction Factor C versus SodiumConcentration

Na meq/L Factor C< 5 1.00

10 0.9820 0.9530 0.9240 0.89

Table 7 : Capacity Correction Factor D versusHardness Concentration

TH meq/L Factor D< 5 1.00

10 0.9820 0.9330 0.8840 0.83

Table 8 : Capacity Correction Factor E versusRegenerant Concentration

NaCl % Factor E

3 0.955 0.9710 1.00

Table 9 : Capacity Correction Factor F versus SpecificFlow Rate in Production

BV/h Factor F

5 1.0510 1.0215 1.0020 0.9930 0.9740 0.96


AMBERJET® 1200 Na

ENGINEERING DATA SHEET(Softening, Reverse flow regeneration)

These data provide information to calculate thehardness leakage and operating capacity ofAMBERJET 1200 Na used for water softening withreverse flow regeneration.The properties of AMBERJET 1200 Na aredescribed in the Product Data Sheet PDS 0354 A.

HARDNESS LEAKAGE

The average hardness leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factors A and B from Tables 2and 3.


Table 1 : Basic Hardness Leakage versus NaClregenerant level


50 0.01470 0.013

100 0.010130 0.008150 0.007


TDS Factor Ameq/L

< 10 1.015 1.920 3.030 5.840 9.1

Table 3 : Leakage Correction Factor B versusSodium to Total Cations Ratio

Na % Factor B

< 5 1.010 1.320 1.630 1.950 2.570 3.190 3.7


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ NaCl

Level ______________________________________ 50 to 150 g /LMinimum contact time ______________________ 20 minutesConcentration ______________________________ 10 %








OPERATING CAPACITY

The operating capacity of AMBERJET 1200 Na inwater softening is obtained by multiplying the basiccapacity value from table 5 by the correction factorsC to G from tables 6 to 10.

Cap = Cap0 x C x D x E x F x G

Table 5 : Basic Capacity versus NaCl regenerant level(reverse flow regeneration)


50 0.7860 0.9070 1.0080 1.0890 1.16

100 1.23120 1.34150 1.49


Bed depth (mm) Factor C

1000 0.921200 0.961500 1.021800 1.062000 1.092500 1.15

Table 7 : Capacity Correction Factor D versusHardness Concentration


10 0.9820 0.9330 0.8840 0.83

Table 8 : Capacity Correction Factor E versus SodiumConcentration

Na meq/L Factor E

< 5 1.0010 0.9820 0.9530 0.9240 0.89

Table 9 : Capacity Correction Factor F versusRegenerant Concentration

NaCl % Factor F

3 0.955 0.9710 1.00

Table 10 : Capacity Correction Factor G versusSpecific Flow Rate in production

BV/h Factor G

5 1.0510 1.0215 1.0020 0.9930 0.9740 0.96

©2000 Rohm and Haas Company EDS 0549 A - April 96 - 1/2

AMBERJET® 1500

ENGINEERING DATA SHEET(H2SO4, Reverse flow regeneration)

These data provide information to calculate the sodiumleakage and operating capacity of AMBERJET 1500used in water demineralisation with reverse flow(counterflow) regeneration with sulphuric acid.The properties of AMBERJET 1500 are described inthe Product Data Sheet PDS 0446 A.

SODIUM LEAKAGE

The average sodium leakage can be read directly fromTable 1. In reverse flow regeneration, the leakage isalways very low so that in industrial applications atreated water conductivity of about 1 µS/cm or lowercan be obtained in most cases.

Table 1 : Average Sodium Leakage versus H2SO4Regenerant Level


40 0.1250 0.0760 0.0570 0.0480 0.03

100 0.02

OPERATING CAPACITY

The operating capacity of AMBERJET 1500 withsulphuric acid regeneration is obtained by multiplyingthe basic capacity value from Table 2 by the correctionfactors A to E from Tables 4 to 8 overleaf.


Table 2 : Basic capacity versus H2SO4 Regenerant level

H2SO4 g/L Capacity eq/L

(Cap0)

40 0.6250 0.7360 0.8270 0.9080 0.9790 1.03

100 1.09110 1.14120 1.18150 1.30


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 10 to 120 BV*/hMaximum linear velocity ________________________ 120 m/hRegenerant ____________________________________ H2SO4 in stepped concentrations

Level ______________________________________ 40 to 150 g /LFlow rate ___________________________________ 4 to 12 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 1.5 to 4 %







Table 4 : Capacity Correction Factor A versus Sodium toTotal Cations Ratio

Na % Factor A0 0.7410 0.8120 0.8630 0.9140 0.9650 1.0060 1.0470 1.0780 1.1090 1.13

100 1.16



5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06

Table 5 : Capacity Correction Factor B vs Alkalinity toTotal Anions Ratio

% Alk Factor B

0 0.9430 0.9850 1.0070 1.0299 1.03



900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10

Table 8 : Capacity Correction Factor E vs Run Length(Production Time)


5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02

Note : All capacity values relate to the resin in its sodium form. In case AMBERJET 1500 H is purchased, a volume correctionis required.


AMBERJET® 1500

ENGINEERING DATA SHEET(HCl, Reverse flow regeneration)

These data provide information to calculate the sodiumleakage and operating capacity of AMBERJET 1500used in water demineralisation with reverse flow(counterflow) regeneration with hydrochloric acid.The properties of AMBERJET 1500 are described inthe Product Data Sheet PDS 0446 A.

SODIUM LEAKAGE

With reverse flow regeneration, the average sodiumleakage is always very low (less than 100 ppb as Nawhen regenerated with HCl) so that in industrialapplications a treated water conductivity of about 1µS/cm or lower can be obtained in most cases.

OPERATING CAPACITY

The operating capacity of AMBERJET 1500 withhydrochloric acid regeneration is obtained bymultiplying the basic capacity value from Table 1 by thecorrection factors A to E from Tables 3 to 7 overleaf.




40 1.0250 1.1660 1.2770 1.3780 1.4590 1.51

100 1.57110 1.62120 1.66


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 10 to 120 BV*/hMaximum linear velocity ________________________ 120 m/hRegenerant ____________________________________ HCl

Level ______________________________________ 40 to 120 g /LFlow rate ___________________________________ 4 to 5 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 5 to 6 %







Table 3 : Capacity Correction Factor A versus Sodium toTotal Cation Ratio

Na % Factor A0 0.9510 0.9620 0.9730 0.9740 0.9850 0.9960 0.9970 1.0080 1.0190 1.01

100 1.02



5 0.97 0.95 0.9210 0.99 0.98 0.9715 1.00 1.00 1.0020 1.01 1.01 1.0225 1.01 1.03 1.04

> 30 1.02 1.04 1.06

Table 4 : Capacity Correction Factor B versus Alkalinity toTotal Anions Ratio

% Alk Factor B

0 0.9430 0.9850 1.0070 1.02

100 1.03


Bed depth Factor C

mm

900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10



5 0.96 0.98 1.008 0.98 1.00 1.01

10 0.99 1.00 1.0120 1.01 1.01 1.01

> 25 1.01 1.01 1.02

Note : All capacity values relate to the resin in its sodium form. In case AMBERJET 1500 H is purchased, a volume correction isrequired.


AMBERJET® 4200 Cl

ENGINEERING DATA SHEET(Co-flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of AMBERJET 4200 Clused for water demineralisation with co-flowregeneration.The properties of AMBERJET 4200 Cl are described inthe Product Data Sheet PDS 0347 A.

SILICA LEAKAGE

The average silica leakage is obtained by multiplyingthe basic leakage value from Table 1 by the correctionfactors A, B, C and K* from Tables 2 to 4.

Leak = Leak0 x A x B x C x K

*K (the influence of sodium leakage) can bedetermined from the graph given in EDS 0299 A.

Table 1 : Basic Silica Leakage versus NaOH RegenerantLevel

NaOH g/L Leakage ppm SiO2(Leak0)

60 0.08870 0.06880 0.054

100 0.037120 0.027150 0.019

Table 2 : Leakage Correction Factor A versus Silica toTotal Anions Ratio

SiO2 % Factor A

1 0.15 0.510 1.025 2.550 5.075 7.5

Table 3 : Leakage Correction Factor B versus WaterTemperature

Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3

Table 4 : Leakage Correction Factor C versusRegenerant Temperature

NaOH °C Factor C10 1.6615 1.3725 1.0035 0.7645 0.58

TABLE 5 : SUGGESTED OPERATING CONDITIONS

Maximum operating temperature_________________ 60°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ NaOH

Level ________________________________________ 60 to 150 g/LFlow rate_____________________________________ 2 to 8 BV/h (minimum contact time : 20 minutes)Concentration ________________________________ 2 to 5 %







OPERATING CAPACITY

The operating capacity of AMBERJET 4200 Cl is obtainedby multiplying the basic capacity value from table 6 by thecorrection factors D to G from tables 7 to 10.

Cap = Cap0 x D x E x F x G

Table 6 : Basic capacity versus NaOH Regenerant Level (co-flow regen.)

NaOH g/L Capacity eq/L(Cap0)

60 0.5970 0.6480 0.68

100 0.74120 0.80150 0.85

Table 7 : Capacity Correction Factor D versus Sulphate toTotal Anions Ratio

SO4 % Factor D

0 0.9220 0.9650 1.0070 1.0499 1.08

Table 8 : Capacity Correction Factor E versus CO2 to Total

Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica to TotalAnions Ratio and NaOH temperature (°C)

5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs Silica Endpoint (∆∆SiO2 = difference between average

leakage and endpoint)

∆SiO2 Factor G

(ppb)

50 0.90100 0.96200 1.00300 1.04

©2000 Rohm and Haas Company EDS 0357 A - Oct. 96 - 1/2

AMBERJET® 4200 Cl

ENGINEERING DATA SHEET(Reverse flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of AMBERJET 4200 Clfor water demineralisation in reverse flow regeneratedunits including floating bed and packed bedapplications.The properties of AMBERJET 4200 Cl are described inthe Product Data Sheet PDS 0347 A.

SILICA LEAKAGE



*K (the influence of sodium leakage) can be deter-mined from the graph given in the EDS 0299 A.



30 0.02240 0.01550 0.01060 0.00880 0.005

100 0.003120 0.002

Table 2 : Leakage Correction Factor A vs Silica to TotalAnions Ratio

SiO2 % Factor A

1 0.25 1.010 2.025 5.050 10.075 15.0


Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58


Maximum operating temperature_________________ 60°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ NaOH








OPERATING CAPACITY



Table 6 : Basic Capacity versus NaOH Regenerant Level(reverse flow regeneration)


30 0.4440 0.5350 0.6060 0.6670 0.7180 0.75

100 0.81120 0.87


SO4 % Factor D

0 0.9220 0.9650 1.0070 1.0499 1.08


Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica to TotalAnions Ratio and NaOH Temperature (°C)

5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs SilicaEndpoint (∆∆SiO2 = difference between

average leakage and endpoint)

∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04

©2000 Rohm and Haas Company EDS 0550 A - Mar. 96 - 1/2

AMBERJET® 4400


These data provide information to calculate the silicaleakage and operating capacity of AMBERJET 4400used in water demineralisation with reverse flow(counterflow) regeneration with caustic soda.The properties of AMBERJET 4400 Cl are described inthe Product Data Sheet PDS 0430 A.

SILICA LEAKAGE






40 0.01550 0.01060 0.00880 0.005

100 0.003120 0.002


SiO2 % Factor A

1 0.25 1.010 2.025 5.050 10.075 15.0


Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58


Maximum operating temperature_________________ 60°CMinimum bed depth ____________________________ 700 mm (Stratabed), > 1400 mm (single beds)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/hRegenerant ____________________________________ NaOH

Level ________________________________________ 40 to 120 g/LMinimum contact time ________________________ 30 minutesConcentration ________________________________ 2 to 4 %







OPERATING CAPACITY

The operating capacity of AMBERJET 4400 is obtained bymultiplying the basic capacity value from table 6 by thecorrection factors D to G from tables 7 to 10.




40 0.5450 0.6160 0.6770 0.7280 0.77

100 0.84120 0.90


SO4 % Factor D

0 0.9225 0.9650 1.0075 1.0499 1.08


Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs SilicaEndpoint (∆SiO2 = difference between


∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04

Note : All capacity values relate to the resin in its chloride form. In case AMBERJET 4400 OH is purchased, a volume correction isrequired.

©2000 Rohm and Haas Company EDS 0410 A - July 96 - 1/2

AMBERJET® 4600 Cl


These data provide information to calculate the silicaleakage and operating capacity of AMBERJET 4600 Clused for water demineralisation with co-flowregeneration. The properties of AMBERJET 4600 Clare described in the Product Data Sheet PDS 0370 A.

SILICA LEAKAGE






50 0.23060 0.15770 0,11380 0.08690 0,067

100 0.054


SiO2 % Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.535 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87


Maximum operating temperature_________________ 35°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/h

Regenerant _________________________________ NaOHLevel ______________________________________ 40 to 100 g/LFlow rate ___________________________________ 2 to 8 BV/h (minimum contact time : 20 minutes)Concentration ______________________________ 2 to 5 %







OPERATING CAPACITY



Table 6 : Basic capacity versus NaOH Regenerant Level (co-flow regen.)


50 0.7960 0.8470 0.8780 0.90

100 0.94


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica to TotalAnions Ratio and NaOH temperature (°C)

5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92



∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04


AMBERJET® 4600 Cl


These data provide information to calculate the silicaleakage and operating capacity of AMBERJET 4600 Clused for water demineralisation in reverse flowregenerated units including floating bed and packedbed applicationsThe properties of AMBERJET 4600 Cl are described inthe Product Data Sheet PDS 0370 A.

SILICA LEAKAGE






30 0.06240 0.03650 0.02460 0.01770 0.012


SiO2 Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 1.8


NaOH °C Factor C10 1.6615 1.3720 1.1625 1.0030 0.87


Maximum operating temperature_________________ 35°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 50 BV*/hMaximum linear velocity ________________________ 60 m/h








OPERATING CAPACITY





30 0.7040 0.7850 0.8360 0.8770 0.9180 0.93


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92



∆SiO2 Factor G

(ppb)50 0.90

100 0.96200 1.01300 1.04

©2000 Rohm and Haas Company EDS 0264 A - March 98 - 1/2

AMBERLITE® IR120 Na


These data provide information to calculate the sodiumleakage and operating capacity of Amberlite IR120 Naused in water demineralisation with co-flowregeneration with sulphuric acid.The properties of Amberlite IR120 Na are described inthe Product Data Sheet PDS 0210 A.These data are valid for Amberlite IR120 H but theresults obtained refer to the Na form and must becorrected for the reversible swelling between the Naand H forms.

SODIUM LEAKAGE

The average sodium leakage is obtained by multiplyingthe basic leakage value from Table 1 by the correctionfactors A and B from Tables 2 and 3.


Table 1 : Basic Sodium Leakage versus H2SO4Regenerant Level

H2SO4 g/L Leakage % EMA

(Leak0)

60 11.770 10.480 9.2

100 7.2120 5.7140 4.5160 3.5200 2.2240 1.4

Note : Sodium leakage values are expressed as apercentage of the equivalent mineral acidity (EMA).

Table 2 : Leakage Correction Factor A vs Alkalinity toTotal Anions Ratio

Alk % Factor A0 0.6520 0.7740 0.9160 1.0880 1.2899 1.52


Na % Factor B10 0.0620 0.1730 0.3340 0.5250 0.7560 1.0070 1.2880 1.5890 1.91


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ____________________________________ H2SO4 in stepped concentrations

Level ________________________________________ 60 to 240 g/LFlow rate_____________________________________ 2 to 20 BV/h (minimum contact time : 30 minutes)Concentration ________________________________ 0.7 to 6 % according to Ca content





AMBERLITE is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to which organicby-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user must ensurecompliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and Haas Company doesnot recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult your Rohm and Haas technicalrepresentative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eye and skin contact. Nitric acidand other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipment to prevent rapid buildup ofpressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with Ion Exchange Resins, consult sourcesknowledgeable in the handling of these materials. Rohm and Haas Company makes no warranties either expressed or implied as to the accuracy of appropriateness of this data and expressly excludes any liability upon Rohm and Haasarising out of its use. We recommend that the prospective users determine for themselves the suitability of Rohm and Haas materials and suggestions for any use prior to their adoption.Suggestions for uses of our products of the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommendingthe use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Material Safety Data Sheets outlining the hazards andhandling methods for our products are available on request.


OPERATING CAPACITY

The operating capacity of Amberlite IR120 Na withsulphuric acid regeneration is obtained by multiplying thebasic capacity value from table 5 by the correction factorsC to F from tables 6 to 9.


Table 6 : Capacity Correction Factor C versus Alkalinity toTotal Anions Ratio

Alk % Factor C0 0.9325 0.9650 1.0075 1.0499 1.07

Table 5 : Basic Capacity vs H2SO4 Regenerant Level and

Sodium to Total Cations Ratio (Co-flow reg.)

% Na 0 25 50 75 100

H2SO4(g/L)

60 0.53 0.56 0.62 0.71 0.8570 0.57 0.61 0.69 0.79 0.9480 0.60 0.66 0.75 0.87 1.02

100 0.65 0.73 0.85 0.99 1.15120 0.68 0.78 0.92 1.09 1.26140 0.71 0.81 0.97 1.16 1.35160 0.73 0.83 1.00 1.21 1.42200 0.76 0.86 1.04 1.28 1.54240 0.80 0.92 1.10 1.34 1.66

Table 7 : Capacity Correction Factor D versus Magnesium to Hardness Ratio, Sodium to Total Cations Ratio and Alkalinity toTotal Anions Ratio

Mg/TH 0 % Na 50 % Na 80 % Na% 0 50 99 % Alk 0 50 99 % Alk 0 50 99 % Alk0 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

20 1.11 1.09 1.07 1.06 1.05 1.04 1.02 1.02 1.0140 1.22 1.18 1.14 1.11 1.09 1.07 1.04 1.04 1.0360 1.33 1.27 1.21 1.17 1.14 1.11 1.07 1.05 1.0480 1.44 1.36 1.28 1.22 1.18 1.14 1.09 1.07 1.06

100 1.55 1.45 1.35 1.28 1.23 1.18 1.11 1.09 1.07



5 0.91 0.94 0.988 0.95 0.97 0.99

10 0.96 0.98 1.0020 0.99 1.00 1.01

> 25 1.00 1.01 1.01

Table 9 : Capacity Correction Factor F versus WaterTemperature


5 0.94 0.88 0.8210 0.97 0.93 0.9015 0.98 0.97 0.9520 0.99 0.99 0.9825 1.00 1.01 1.01

> 30 1.01 1.02 1.03




These data provide information to calculate thesodium leakage and operating capacity ofAmberlite IR120 Na used for waterdemineralisation in reverse flow regenerated unitsexcluding floating bed and packed bedapplications. The properties of Amberlite IR120Na are described in the Product Data Sheet PDS0210 A.These data are valid for Amberlite IR120 H butthe results obtained refer to the Na form andmust be corrected for the reversible swellingbetween the Na and H forms.

SODIUM LEAKAGE

The average sodium leakage can be read directlyfrom Table 1. In reverse flow regeneration, theleakage is always very low so that in industrialapplications a treated water conductivity of about1 µS/cm or lower can be obtained in most cases.

Table 1 : Average Sodium Leakage versus H2SO4 Regenerant level


40 0.1250 0.0760 0.0570 0.0480 0.03

OPERATING CAPACITY

The operating capacity of AMBERLITE IR120 Nawith sulphuric acid regeneration is obtained bymultiplying the basic capacity value from Table 2by the correction factors A to E from Tables 4 to 8overleaf.


Table 2 : Basic capacity versus H2SO4 Regenerant

level

H2SO4 g/L Capacity eq/L(Cap0)

40 0.5350 0.6260 0.7170 0.7780 0.8390 0.89

100 0.93120 1.02140 1.08160 1.14


Maximum operating temperature ________________ 120°CMinimum bed depth ___________________________ 1000 mm (preferably > 1400 mm)Service flow rate _______________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ___________________________________ H2SO4 in stepped concentrations

Level ______________________________________ 40 to 150 g /LFlow rate __________________________________ 2 to 20 BV/h (minimum contact time : 30 minutes)Concentration______________________________ 0.7 to 6 % according to Ca content

Slow rinse_____________________________________ 2 BV at regeneration flow rateFast rinse _____________________________________ 2 to 4 BV at service flow rate






Table 4 : Capacity Correction Factor A versus Sodiumto Total Cations Ratio

Na % Factor A0 0.7510 0.8120 0.8630 0.9140 0.9650 1.0060 1.0470 1.0780 1.1090 1.13

100 1.16



5 0.94 0.88 0.8210 0.97 0.93 0.9015 0.98 0.97 0.9520 0.99 0.99 0.9825 1.00 1.01 1.01

> 30 1.01 1.02 1.03

Table 5 : Capacity Correction Factor B vs Alkalinityto Total Anions Ratio

% Alk Factor B

0 0.9425 0.9750 1.0075 1.0299 1.03



900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10

Table 8 : Capacity Correction Factor E vs RunLength (Production Time)


5 0.91 0.94 0.988 0.95 0.97 0.99

10 0.96 0.98 1.0020 0.99 1.00 1.01

> 25 1.00 1.01 1.01


AMBERLITE IR120 Na

ENGINEERING DATA SHEET(HCl, Reverse-flow regeneration)

These data provide information to calculate thesodium leakage and operating capacity ofAmberlite IR120 Na used for waterdemineralisation in reverse flow regenerated unitsexcluding floating bed and packed bedapplications.The properties of Amberlite IR120 Na aredescribed in the Product Data Sheet PDS 0210 A.These data are valid for Amberlite IR120 H butthe results obtained refer to the Na form andmust be corrected for the reversible swellingbetween the Na and H forms.

SODIUM LEAKAGE

With reverse flow regeneration, the averagesodium leakage is always very low (less than 100ppb as Na when regenerated with HCl) so that inindustrial applications a treated water conductivityof about 1 µS/cm or lower can be obtained inmost cases.

OPERATING CAPACITY

The operating capacity of Amberlite IR120 Nawith hydrochloric acid regeneration is obtained bymultiplying the basic capacity value from Table 1by the correction factors A to E from Tables 3 to 7overleaf.




30 0.8840 1.0350 1.1560 1.2470 1.3280 1.3990 1.44

100 1.49120 1.57


Maximum operating temperature ________________ 120°CMinimum bed depth ___________________________ 1000 mm (preferably > 1400 mm)Service flow rate _______________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ___________________________________ HCl

Level ______________________________________ 30 to 120 g /LFlow rate __________________________________ 2 to 5 BV/h (minimum contact time : 30 minutes)Concentration______________________________ 5 to 8 %







Table 3 : Capacity Correction Factor A versus Sodiumto Total Cation Ratio

Na % Factor A0 0.9210 0.9320 0.9430 0.9540 0.9750 0.9860 0.9970 1.0080 1.0290 1.03

100 1.04



5 0.94 0.88 0.8210 0.97 0.93 0.9015 0.98 0.97 0.9520 0.99 0.99 0.9825 1.00 1.01 1.01

> 30 1.01 1.02 1.03

Table 4 : Capacity Correction Factor B versusAlkalinity to Total Anions Ratio

% Alk Factor B

0 0.9425 0.9750 1.0075 1.0299 1.03



900 0.941200 0.971500 1.001800 1.032000 1.062500 1.10



5 0.91 0.94 0.988 0.95 0.97 0.99

10 0.96 0.98 1.0020 0.99 1.00 1.01

> 25 1.00 1.01 1.01



ENGINEERING DATA SHEET(HCl, Co-flow regeneration)

These data provide information to calculate thesodium leakage and operating capacity ofAmberlite IR120 Na used for waterdemineralisation with co-flow regeneration withhydrochloric acid. The properties of AmberliteIR120 Na are described in the Product Data SheetPDS 0210 A.These data are valid for Amberlite IR120 H butthe results obtained refer to the Na form and mustbe corrected for the reversible swelling betweenthe Na and H forms.

SODIUM LEAKAGE

The average sodium leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factor A from Table 2.

Leak = Leak0 x A

Table 1 : Basic Sodium Leakage versus HClRegenerant Level

HCl g/L Leakage % EMA(Leak0)

50 3.960 3.070 2.580 2.0

100 1.5120 1.2150 0.9

Note : Sodium leakage values are expressed as apercentage of the equivalent mineral acidity(EMA).

The value obtained in meq/L must be convertedto mg/L as Na and eventually to a conductivityvalue, using the graph supplied in the Memento ofIon Exchange published by Rohm and Haas

Table 2 : Leakage Correction Factor A versusSodium to Total Cations Ratio

Na % Factor A10 0.1520 0.3030 0.5040 0.7550 1.0060 1.3070 1.7080 2.2090 2.80

100 3.60


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ____________________________________ HCl

Level ______________________________________ 50 to 150 g/LFlow rate ___________________________________ 2 to 5 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 5 to 8 %Slow rinse __________________________________ 2 BV at regeneration flow rate







OPERATING CAPACITY

The operating capacity of Amberlite IR120 Na withhydrochloric acid is obtained by multiplying thebasic capacity value from table 4 by the correctionfactors B to E from tables 5 to 8.

Cap = Cap0 x B x C x D x E

Table 4 : Basic Capacity versus HCl Regenerant Level(co-flow regen.)


50 0.9360 1.0270 1.1080 1.17

100 1.28120 1.37150 1.47



5 0.94 0.88 0.8210 0.97 0.93 0.9015 0.98 0.97 0.9520 0.99 0.99 0.9825 1.00 1.01 1.01

> 30 1.01 1.02 1.03

Table 5 : Capacity Correction Factor B versus Sodiumto Total Cations Ratio

Na % Factor B

0 1.0010 0.9820 0.9730 0.9740 0.9850 1.0060 1.0270 1.0580 1.0990 1.13

100 1.16

Table 6 : Capacity Correction Factor C versusAlkalinity to Total Anions Ratio

% Alk Factor C

0 0.9525 0.9850 1.0075 1.0399 1.05



5 0.91 0.94 0.988 0.95 0.97 0.99

10 0.96 0.98 1.0020 0.99 1.00 1.01

> 25 1.00 1.01 1.01



ENGINEERING DATA SHEET(Softening, Co-flow regeneration)

These data provide information to calculate thehardness leakage and operating capacity of AmberliteIR120 Na used for water softening with co-flowregeneration.The properties of Amberlite IR120 Na are described inthe Product Data Sheet PDS 0210 A.

HARDNESS LEAKAGE

The average hardness leakage is obtained bymultiplying the basic leakage value from Table 1 by thecorrection factors A and B from Tables 2 and 3.


Table 1 : Basic Hardness Leakage versus NaClRegenerant Level


80 0.059100 0.051120 0.045150 0.036200 0.026250 0.018


TDS Factor Ameq/L

< 10 1.015 1.920 3.030 5.840 9.1


Na % Factor B< 5 1.0

10 1.320 1.630 1.950 2.570 3.190 3.7


Maximum operating temperature_________________ 120°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ____________________________________ NaCl

Level ______________________________________ 80 to 250 g/LFlow rate ___________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 10 %







OPERATING CAPACITY

The operating capacity of Amberlite IR120 Na in watersoftening is obtained by multiplying the basic capacityvalue from table 5 by the correction factors C to F fromtables 6 to 9.


Table 5 : Basic Capacity versus NaCl Regenerant Level (co-flow regeneration)


80 1.01100 1.13120 1.22150 1.34200 1.48250 1.60

Table 6 : Capacity Correction Factor C versus SodiumConcentration

Na meq/L Factor C< 5 1.00

10 0.9820 0.9530 0.9240 0.89

Table 7 : Capacity Correction Factor D versus HardnessConcentration


10 0.9820 0.9330 0.8840 0.83

Table 8 : Capacity Correction Factor E versus RegenerantConcentration

NaCl % Factor E

3 0.955 0.9710 1.00

Table 9 : Capacity Correction Factor F versus SpecificFlow Rate in Production

BV/h Factor F

5 1.0510 1.0215 1.0020 0.9930 0.9740 0.96



ENGINEERING DATA SHEET(Softening, Reverse flow regeneration)

These data provide information to calculate thehardness leakage and operating capacity ofAmberlite IR120 Na used for water softening inreverse flow regenerated units excluding floatingbed and packed bed applications.The properties of Amberlite IR120 Na are describedin the Product Data Sheet PDS 0210 A.

HARDNESS LEAKAGE

The average hardness leakage is obtained bymultiplying the basic leakage value from Table 1 bythe correction factors A and B from Tables 2 and 3.


Table 1 : Basic Hardness Leakage versus NaClregenerant level


50 0.01470 0.013

100 0.010120 0.009150 0.007

Table 2 : Leakage Correction Factor A vs Total DissolvedSolids Concentration

TDS Factor Ameq/L

< 10 1.015 1.920 3.030 5.840 9.1


Na % Factor B

< 5 1.010 1.320 1.630 1.950 2.570 3.190 3.7


Maximum operating temperature ________________ 120°CMinimum bed depth ___________________________ 1000 mm (preferably > 1400 mm)Service flow rate________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant____________________________________ NaCl

Level _______________________________________ 50 to 150 g /LFlow rate ____________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration _______________________________ 10 %

Slow rinse _____________________________________ 2 BV at regeneration flow rateFast rinse______________________________________ 2 to 4 BV at service flow rate






OPERATING CAPACITY

The operating capacity of Amberlite IR120 Na in watersoftening is obtained by multiplying the basic capacityvalue from table 5 by the correction factors C to G fromtables 6 to 10.

Cap = Cap0 x C x D x E x F x G

Table 5 : Basic Capacity versus NaCl regenerant level(reverse flow regeneration)


50 0.7560 0.8670 0.9580 1.0390 1.10

100 1.17120 1.28150 1.42


Bed depth (mm) Factor C

1000 0.921200 0.961500 1.021800 1.062000 1.092500 1.15

Table 7 : Capacity Correction Factor D HardnessConcentration


10 0.9820 0.9330 0.8840 0.83

Table 8 : Capacity Correction Factor E versus SodiumConcentration

Na meq/L Factor E

< 5 1.0010 0.9820 0.9530 0.9240 0.89

Table 9 : Capacity Correction Factor F versus RegenerantConcentration

NaCl % Factor F

3 0.955 0.9710 1.00

Table 10 : Capacity Correction Factor G versus SpecificFlow Rate in production

BV/h Factor G

5 1.0510 1.0215 1.0020 0.9930 0.9740 0.96

©2000 Rohm and Haas Company EDS 0248 A - Oct. 95- 1/2

AMBERLITE® IRA402 Cl


These data provide information to calculate thesilica leakage and operating capacity of AmberliteIRA402 Cl used for water demineralisation withco-flow regeneration.The properties of Amberlite IRA402 Cl aredescribed in the Product Data Sheet PDS 0503 A.

SILICA LEAKAGE

The average silica leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factors A, B, C and K* fromTables 2 to 4.


*K (the influence of sodium leakage) can bedetermined from the graph given in EDS 0299 A.

Table 1 : Basic Silica Leakage versus NaOHRegenerant Level


60 0.08870 0.06880 0.054

100 0.037120 0.027150 0.019

Table 2 : Leakage Correction Factor A versus Silicato Total Anions Ratio

SiO2 % Factor A1 0.15 0.510 1.025 2.550 5.075 7.5

Table 3 : Leakage Correction Factor B versusWater Temperature

Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58

TABLE 5 : SUGGESTED OPERATING CONDITIONS







AMBERLITE is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to which organicby-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user must ensurecompliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and Haas Company doesnot recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult your Rohm and Haas technicalrepresentative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eye and skin contact. Nitric acidand other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipment to prevent rapid buildup ofpressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with Ion Exchange Resins, consult sourcesknowledgeable in the handling of these materials.

Rohm and Haas Company makes no warranties either expressed or implied as to the accuracy of appropriateness of this data and expressly excludes any liability upon Rohm and Haasarising out of its use. We recommend that the prospective users determine for themselves the suitability of Rohm and Haas materials and suggestions for any use prior to their adoption.Suggestions for uses of our products of the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommendingthe use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Material Safety Data Sheets outlining the hazards andhandling methods for our products are available on request.


OPERATING CAPACITY

The operating capacity of Amberlite IRA402 Cl isobtained by multiplying the basic capacity valuefrom table 6 by the correction factors D to G fromtables 7 to 10.


Table 6 : Basic capacity versus NaOH RegenerantLevel (co-flow regen.)


60 0.5370 0.5880 0.61

100 0.67120 0.72150 0.78

Table 7 : Capacity Correction Factor D versusSulphate to Total Anions Ratio

SO4 % Factor D

0 0.9225 0.9650 1.0075 1.0499 1.08

Table 8 : Capacity Correction Factor E versus CO2to Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silicato Total Anions Ratio and NaOHtemperature (°C)

5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86



∆SiO2 Factor G(ppb)

50 0.90100 0.95200 1.00300 1.04



ENGINEERING DATA SHEET(Reverse- flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA402Cl used in conventional reverse flow systems withdownflow loading and upflow regeneration with air orwater holddown.The properties of Amberlite IRA402 Cl are describedin the Product Data Sheet PDS 0503 A.

SILICA LEAKAGE



*K (the influence of sodium leakage) can bedetermined from the graph given in the EDS 0299 A.



30 0.02240 0.01550 0.01060 0.00880 0.005

100 0.003120 0.002

Table 2 : Leakage Correction Factor A vs Silica toTotal Anions Ratio

SiO2 % Factor A

1 0.25 1.010 2.025 5.050 10.075 15.0


Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58


Maximum operating temperature_________________ 60°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ____________________________________ NaOH









OPERATING CAPACITY

The operating capacity of Amberlite IRA402 Cl isobtained by multiplying the basic capacity value fromtable 6 by the correction factors D to G from tables 7 to10.




30 0.4040 0.4850 0.5460 0.6070 0.6480 0.68

100 0.74120 0.79

Table 7 : Capacity Correction Factor D versus Sulphateto Total Anions Ratio

SO4 % Factor D

0 0.9225 0.9650 1.0075 1.0499 1.08

Table 8 : Capacity Correction Factor E versus CO2 to

Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica toTotal Anions Ratio and NaOHTemperature (°C)

5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs SilicaEndpoint (∆SiO2 = difference between



50 0.90100 0.95200 1.00300 1.04



ENGINEERING DATA SHEET(Co- flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA410Cl used for water demineralisation with co-flowregeneration. The properties of Amberlite IRA410 Clare described in the Product Data Sheet PDS 0502 A.

SILICA LEAKAGE






40 0.37050 0.23060 0.16080 0.085

100 0.055


SiO2 % Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87











OPERATING CAPACITY



Table 6 : Basic capacity versus NaOH Regenerant Level(co-flow regen.)


40 0.6450 0.7460 0.7870 0.8180 0.84

100 0.88


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica toTotal Anions Ratio and NaOH temperature(°C)

5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92

Table 10 : Capacity Correction Factor G vs SilicaEndpoint(∆SiO2 = difference between average

leakage and endpoint))

∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04




These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA410Cl used with reverse flow (counterflow) regeneration.

The properties of Amberlite IRA410 Cl are describedin the Product Data Sheet PDS 0502 A.

SILICA LEAKAGE






30 0.05040 0.03650 0.02460 0.01780 0.010


SiO2 Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87


Maximum operating temperature_________________ 35°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/h









OPERATING CAPACITY





30 0.6440 0.7250 0.7760 0.8170 0.8680 0.89


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92

Table 10 : Capacity Correction Factor G vs SilicaEndpoint(∆SiO2 = difference between average


∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04



ENGINEERING DATA SHEET(Co- flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA458Cl used in water demineralisation with co-flowregeneration.The properties of Amberlite IRA458 Cl are describedin the Product Data Sheet PDS 0229 A.

SILICA LEAKAGE






50 0.06960 0.05280 0.033

100 0.023120 0.017150 0.012


SiO2 Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87




Slow rinse _____________________________________ 2 BV at regeneration flow rateFast rinse ______________________________________ 4 à 8 BV to service flow rate







OPERATING CAPACITY



Table 6 : Basic Capacity versus NaOH Regenerant Level(co-flow regeneration)


50 0.6060 0.6570 0.6980 0.72

100 0.77120 0.81150 0.84


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92




50 0.90100 0.95200 1.00300 1.04


AMBERLITE® IRA458RF Cl


These data provide information to calculate thesilica leakage and operating capacity of AmberliteIRA458RF Cl used for water demineralisationwith reverse flow (counterflow) regeneration.Theproperties of Amberlite IRA458RF Cl aredescribed in the Product Data Sheet PDS 0428 A.

SILICA LEAKAGE

The average silica leakage is obtained bymultiplying the basic leakage value from Table 1by the correction factors A, B, C and K* fromTables 2 to 4.


*K (the influence of sodium leakage) can bedetermined from the graph given in the EDS0299 A.

Table 1 : Basic Silica Leakage versus NaOHRegenerant Level


30 0.03540 0.02050 0.01460 0.01180 0.007


Si02 Factor A1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87


Maximum operating temperature_________________ 35°CMinimum bed depth ____________________________ 1000 mm (preferably > 1400 mm)Service flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 40 m/hRegenerant ____________________________________ NaOHLevel__________________________________________ 30 to 80 g/LFlow rate ______________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration _________________________________ 2 to 4 %Slow rinse _____________________________________ 2 BV at regeneration flow rateFast rinse ______________________________________ 4 to 8 BV at service flow rate







OPERATING CAPACITY

The operating capacity of Amberlite IRA458RF Cl isobtained by multiplying the basic capacity valuefrom table 6 by the correction factors D to G fromtables 7 to 10.


Table 6 : Basic Capacity versus NaOH RegenerantLevel (reverse flow regeneration)


30 0.5040 0.6150 0.6660 0.7070 0.7380 0.75

Table 7 : Capacity Correction Factor D versusSulphate to Total Anions Ratio

SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06

Table 8 : Capacity Correction Factor E versus CO2to Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silicato Total Anions Ratio and NaOHTemperature (°C)

5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92




50 0.90100 0.95200 1.00300 1.04



ENGINEERING DATA SHEET(Reverse- flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of AmberliteIRA478RF Cl used for water demineralisation withreverse flow (counterflow) regeneration.The properties of Amberlite IRA478RF Cl aredescribed in the Product Data Sheet PDS 0440 A.

SILICA LEAKAGE






40 0.05050 0.03060 0.02070 0.015


SiO2 % Factor A

1 0.33 1.05 1.57 2.010 3.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2

Table 4 : Leakage Correction Factor A versusRegenerant Temperature

NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87


Maximum silica in degassed water ________________ 10 % of total anionsMaximum operating temperature_________________ 35°CMinimum bed depth ____________________________ 1400 mmService flow rate ________________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ____________________________________ NaOH

Level ______________________________________ 40 to 70 g/LFlow rate ___________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 2 to 4 %








OPERATING CAPACITY

The operating capacity of Amberlite IRA478RF Cl isobtained by multiplying the basic capacity value fromtable 6 by the correction factors D to H from tables 7 to11.

Cap = Cap0 x D x E x F x G x H



40 0.8750 0.9260 0.9870 1.00


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.03

100 1.06


Total Anions Ratio

CO2 % Factor E

0 0.9710 0.9820 1.0030 1.02

Table 9 : Capacity Correction Factor F versus Silica toTotal Anions Ratio

SiO2 % Factor F

1 1.023 1.015 1.007 0.9910 0.98

Table 10 : Capacity Correction Factor G versus ServiceFlow Rate

BV/h Factor G

10 1.0320 1.0030 0.9540 0.88

Table 11 : Capacity Correction Factor H vs SilicaEndpoint(∆∆SiO2 = difference between average

leakage and endpoint

∆SiO2 Factor H

(ppb)50 0.90

100 0.95200 1.00300 1.04


AMBERLITE® IRA67

ENGINEERING DATA SHEET

These data provide information to calculate theoperating capacity of Amberlite IRA67 and IRA67RFused for water demineralisation.

The properties of these products are described in theProduct Data Sheets PDS 0226 and 0444 A.

OPERATING CAPACITY

The operating capacity is obtained by multiplying thebasic capacity value from table 1 by the correctionfactors A, B and C from tables 2 to 4.

Cap = Cap0 x A x B x C

Table 1 : Basic Capacity versus SO4/FMA* Ratio

SO4/FMA Capacity eq/L

% (Cap0)

0 1.2620 1.2940 1.3260 1.3480 1.37

100 1.39

*FMA = Free Mineral Acidity = Anions of Strong Acids

Table 2 : Capacity Correction Factor A versusCO2/Total Anions Ratio

CO2 % Factor A

0 0.8810 0.9020 0.9330 0.9550 1.00

Table 3 : Capacity Correction Factor B versus WaterTemperature

Water °C Factor B5 0.9015 1.0020 1.0230 1.0640 1.09

Table 4 : Capacity Correction Factor C versus RunLength (hours)

Run (hours) Factor C4 0.906 0.948 0.96

12 0.9818 0.99

> 24 1.00



Level ______________________________________ 130 % of ionic loadFlow rate ___________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 2 to 4 %

Slow rinse _____________________________________ 2 BV at regeneration flow rateFast rinse ______________________________________ 8 to 16 BV at 10 BV/h





These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA900Cl used for water demineralisation with co-flowregeneration.The properties of Amberlite IRA900 Cl are describedin the Product Data Sheet PDS 0295 A.

SILICA LEAKAGE



*K (the influence of sodium leakage can bedetermined from the graph given in EDS 0299 A)



50 0.12060 0.08870 0.06880 0.054

100 0.037120 0.027150 0.019


SiO2 % Factor A

1 0.15 0.510 1.025 2.550 5.075 7.5

Table 3 : Leakage Correction Factor B versus Watertemperature

Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58


Maximum operating temperature_________________ 60°CMinimum bed depth ____________________________ 700 mmService flow rate ________________________________ 5 to 120 BV*/hMaximum linear velocity ________________________ 5 to 120 m/hRegenerant ____________________________________ NaOH

Level _____________________________________ 50 to 150 g/LFlow rate__________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration _____________________________ 2 to 4 %

Slow rinse ____________________________________ 2 BV at regeneration flow rateFast rinse ____________________________________ 4 to 8 BV at service flow rate







OPERATING CAPACITY



Table 6 : Basic Capacity versus NaOH Regenerant Level(co-flow regeneration)


50 0.3760 0.4170 0.4480 0.46

100 0.50120 0.52150 0.55


SO4 % Factor D

0 0.9225 0.9650 1.0075 1.0499 1.08


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs SilicaEndpoint (∆∆SiO2 = difference between average



50 0.90100 0.95200 1.00300 1.04



ENGINEERING DATA SHEET(Reverse-flow regeneration)

These data provide information to calculate the silicaleakage and operating capacity of AmberliteIRA900RF Cl used for water demineralisation withreverse flow (counterflow) regeneration.The properties of Amberlite IRA900RF Cl aredescribed in the Product Data Sheet PDS 0445 A.

SILICA LEAKAGE



*K (the influence of sodium leakage can bedetermined from the graph given in EDS 0299 A)



30 0.02240 0.01550 0.01060 0.00880 0.005

100 0.003120 0.002


SiO2 % Factor A

1 0.25 1.010 2.025 5.050 10.075 15.0

Table 3 : Leakage Correction Factor B versus Watertemperature

Water °C Factor B5 0.710 0.815 1.025 1.535 2.345 3.3


NaOH °C Factor C10 1.6515 1.3725 1.0035 0.7645 0.58


Maximum operating temperature ________________ 60°CMinimum bed depth ___________________________ 1000 mm (preferably > 1400 mm)Service flow rate _______________________________ 5 to 40 BV*/hMaximum linear velocity________________________ 50 m/hRegenerant ___________________________________ NaOH

Level _______________________________________ 30 to 120 g/LFlow rate____________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration _______________________________ 2 to 4 %

Slow rinse ____________________________________ 2 BV at regeneration flow rateFast rinse _____________________________________ 4 to 8 BV at service flow rate







OPERATING CAPACITY

The operating capacity of Amberlite IRA900RF Cl isobtained by multiplying the basic capacity value fromtable 6 by the correction factors D to G from tables 7 to10.




30 0.3040 0.3550 0.3960 0.4270 0.4580 0.47

100 0.51120 0.53


SO4 % Factor D

0 0.9225 0.9650 1.0075 1.0499 1.08


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12


5 25 50 75 % SiO2

5°C 0.96 0.86 0.74 0.6515 0.98 0.88 0.79 0.7025 1.00 0.92 0.84 0.7635 1.02 0.96 0.87 0.8145 1.04 0.98 0.93 0.86

Table 10 : Capacity Correction Factor G vs SilicaEndpoint(∆∆SiO2 = difference between average



50 0.90100 0.95200 1.00300 1.04




These data provide information to calculate the silicaleakage and operating capacity of Amberlite IRA910Cl used in water demineralisation with co-flowregeneration.The properties of Amberlite IRA910 Cl are describedin the Product Data Sheet PDS 0517 A.

SILICA LEAKAGE






40 0.37050 0.23060 0.16080 0.085

100 0.055

Table 2 : Leakage Correction Factor A versus Silica toTotal anions ratio

SiO2 % Factor A

1 0.25 1.010 2.020 4.030 6.0


Water °C Factor B5 0.710 0.815 1.020 1.225 1.530 2.2


NaOH °C Factor C10 1.6515 1.3720 1.1625 1.0030 0.87











OPERATING CAPACITY



Table 6 : Basic capacity versus NaOH Regenerant Level(co-flow regeneration)


40 0.6050 0.6460 0.6770 0.7080 0.72

100 0.75


SO4 % Factor D

0 0.9425 0.9750 1.0075 1.0399 1.06


Total Anions Ratio

CO2 % Factor E

0 0.9720 1.0030 1.0250 1.0575 1.0899 1.12

Table 9 : Capacity Correction Factor F versus Silica toTotal Anions Ratio and NaOH Temperature(°C)

5 10 20 30 % SiO2

5°C 0.96 0.93 0.87 0.8310 0.97 0.94 0.89 0.8515 0.98 0.95 0.91 0.8720 0.99 0.96 0.92 0.8925 1.00 0.98 0.94 0.9030 1.01 0.99 0.96 0.92



∆SiO2 Factor G

(ppb)50 0.90

100 0.95200 1.00300 1.04


AMBERLITE® IRA96


These data provide information to calculate theoperating capacity of Amberlite IRA96, IRA96RF andIRA96SB used in water demineralisation.The properties of these products are respectivelydescribed in the Product Data Sheets PDS 0211, 0441and 0419 A.

OPERATING CAPACITY

The operating capacity is obtained by multiplying thebasic capacity value from table 1 by the correctionfactors A, B and C from tables 2 to 4.

Cap = Cap0 x A x B x C

Table 1 : Basic Capacity versus SO4/FMA* Ratio

SO4/FMA Capacity eq/L

% (Cap0)

0 1.0120 1.0440 1.0760 1.1080 1.12

100 1.15

*FMA = Free Mineral Acidity = Anions of Strong Acids

Table 2 : Capacity Correction Factor A vs CarbonDioxide Concentration

CO2 meq/L Factor A

0.10 0.930.25 0.940.50 0.960.75 0.98

> 1.00 1.00

Table 3 : Capacity Correction Factor B versus WaterTemperature

Water °C Factor B5 0.9015 1.0025 1.0535 1.0845 1.10

Table 4 : Capacity Correction Factor C versus RunLength (hours)

Run (hours) Factor C4 0.806 0.888 0.92

12 0.9718 0.99

> 24 1.00



Level ______________________________________ 120 % of ionic loadFlow rate ___________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration ______________________________ 2 to 4 %




AMBERLITE® IRC86


These data provide information to calculate theoperating capacity of Amberlite IRC86, IRC86RF andIRC86SB used for water dealkalization.The properties of these products are described in theProduct Data Sheets PDS 0234, 0442 and 0443 A.

OPERATING CAPACITYThe operating capacity is obtained by multiplying thebasic capacity value from table 1 by the correctionfactors A and B from tables 2 and 3. The capacity isvalid for an endpoint of the run corresponding to aleakage of 10 % of the influent alkalinity.

Cap = Cap0 x A x B

Table 1 : Basic Capacity versus Hardness to AlkalinityRatio

TH/TAlk Capacity eq/L

0.60 0.830.70 0.990.80 1.200.90 1.460.95 1.771.00 2.401.10 2.501.20 2.55

> 1.30 2.60

Table 2 : Capacity Correction Factor A versus TotalCations and Water Temperature

Total Cationsmeq/L 10°C 15°C 20°C 25°C

2 0.69 0.80 0.90 1.004 0.82 0.92 1.00 1.076 0.90 0.98 1.06 1.128 0.93 1.02 1.09 1.15

> 10 0.94 1.03 1.11 1.17

Table 3 : Capacity Correction Factor B versus IonicLoad

Load = Temporary Hardness x Running time(meq/L) (h)

Load Factor B30 0.5860 0.7980 0.87100 0.93120 0.97

> 140 1.00


Maximum operating temperature _______________ 120°CMinimum bed depth __________________________ 700 mmService flow rate_______________________________ 5 to 70 BV*/hMaximum linear velocity _______________________ 50 m/hRegenerants __________________________________ HCl H2SO4

Flow rate (BV/h)___________________________ 2 to 8 15 to 40Concentration (%) _________________________ 2 to 5 0.5 to 0.7Level _____________________________________ 104 to 110 % of theoryMinimum contact time ______________________ 30 minutes

Slow rinse ____________________________________ 2 BV at regeneration flow rateFast rinse_____________________________________ 2 to 4 BV at service flow rate


©2001 Rohm and Haas Company EDS 0654 A - Jul. 01 - 1/2

IMAC® HP333


These data provide information to calculate theoperating capacity of IMAC HP333 used for waterdealkalization.The properties of these products are described in theProduct Data Sheet ITS 0200 A.


Cap = Cap0 x A x B



0.60 0.790.70 0.880.80 1.040.90 1.410.95 1.741.00 2.231.10 2.331.20 2.35

> 1.30 2.36



2 0.69 0.80 0.90 1.004 0.82 0.92 1.00 1.076 0.90 0.98 1.06 1.128 0.93 1.02 1.09 1.15

> 10 0.94 1.03 1.11 1.17



Load Factor B30 0.5860 0.7980 0.87100 0.93120 0.97

> 140 1.00


Maximum operating temperature _______________ 100°CMinimum bed depth __________________________ 700 mmService flow rate ______________________________ 5 to 70 BV*/hMaximum linear velocity _______________________ 50 m/hRegenerants__________________________________ HCl H2SO4

Flow rate (BV/h) __________________________ 2 to 8 15 to 40Concentration (%)_________________________ 2 to 5 0.5 to 0.7Level _____________________________________ 104 to 110 % of theoryMinimum contact time______________________ 30 minutes

Slow rinse____________________________________ 2 BV at regeneration flow rateFast rinse ____________________________________ 2 to 4 BV at service flow rate




IMAC is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to whichorganic by-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user mustensure compliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and HaasCompany does not recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult yourRohm and Haas technical representative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eyeand skin contact. Nitric acid and other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipmentto prevent rapid buildup of pressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with IonExchange Resins, consult sources knowledgeable in the handling of these materials.

Rohm and Haas Company makes no warranties either expressed or implied as to the accuracy of appropriateness of this data and expressly excludes any liability upon Rohm andHaas arising out of its use. We recommend that the prospective users determine for themselves the suitability of Rohm and Haas materials and suggestions for any use prior to theiradoption. Suggestions for uses of our products of the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood asrecommending the use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Material Safety Data Sheetsoutlining the hazards and handling methods for our products are available on request.



IMAC® HP336


These data provide information to calculate theoperating capacity of IMAC HP336 used for waterdealkalization.The properties of these products are described in theProduct Data Sheet ITS 0199 A.


Cap = Cap0 x A x B



0.60 0.790.70 0.880.80 1.040.90 1.410.95 1.741.00 2.231.10 2.331.20 2.35

> 1.30 2.36



2 0.69 0.80 0.90 1.004 0.82 0.92 1.00 1.076 0.90 0.98 1.06 1.128 0.93 1.02 1.09 1.15

> 10 0.94 1.03 1.11 1.17



Load Factor B30 0.5860 0.7980 0.87100 0.93120 0.97

> 140 1.00


Maximum operating temperature _______________ 100°CMinimum bed depth __________________________ 700 mmService flow rate ______________________________ 5 to 70 BV*/hMaximum linear velocity _______________________ 50 m/hRegenerants__________________________________ HCl H2SO4

Flow rate (BV/h) __________________________ 2 to 8 15 to 40Concentration (%)_________________________ 2 to 5 0.5 to 0.7Level _____________________________________ 104 to 110 % of theoryMinimum contact time______________________ 30 minutes

Slow rinse____________________________________ 2 BV at regeneration flow rateFast rinse ____________________________________ 2 to 4 BV at service flow rate




IMAC is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to whichorganic by-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user mustensure compliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and HaasCompany does not recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult yourRohm and Haas technical representative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eyeand skin contact. Nitric acid and other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipmentto prevent rapid buildup of pressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with IonExchange Resins, consult sources knowledgeable in the handling of these materials.

Rohm and Haas Company makes no warranties either expressed or implied as to the accuracy of appropriateness of this data and expressly excludes any liability upon Rohm andHaas arising out of its use. We recommend that the prospective users determine for themselves the suitability of Rohm and Haas materials and suggestions for any use prior to theiradoption. Suggestions for uses of our products of the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood asrecommending the use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Material Safety Data Sheetsoutlining the hazards and handling methods for our products are available on request.


©2000 Rohm and Haas Company EDS 0620 A - Feb 2000 - 1/2

IMAC® HP555


These data provide information to calculate thenitrate leakage and operating capacity of IMACHP555 used with co-flow regeneration.

The properties of IMAC HP555 are described in theProduct Data Sheet ITS 0201 A.

NITRATE LEAKAGE

The average nitrate leakage is obtained by multiplyingthe basic leakage value from figure 1 by the correctionfactors A and B from figures 2 and 3.


Fig 1 : Basic Nitrate Leakage vs Endpoint

0

2

4

6

8

10

12

0 10 20 30 40 50

Endpoint NO3 mg/L

Basic leakagemg/L

Fig 2 : Leakage Correction Factor A versusTotal Anions

0.00.20.4

0.60.81.01.2

1.41.61.8

0.0 2.0 4.0 6.0 8.0 10.0Total anions meq/L

A

Fig 3 : Leakage Correction Factor B versusRegenerant Dosage

1.0

1.1

1.2

1.3

1.4

1.5

1.6

100 120 140 160 180 200 220 240NaCl g/L

B

Table 1 : Suggested Operating Conditions (co-flow regeneration)

Maximum operating temperature ________________ 50°CMinimum bed depth ___________________________ 700 mmService flow rate _______________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ___________________________________ NaCl

Level ______________________________________ 100 to 240 g/LFlow rate __________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration______________________________ 6 to 10 %





IMAC is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to which organicby-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user must ensurecompliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and Haas Company doesnot recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult your Rohm and Haas technicalrepresentative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eye and skin contact. Nitric acidand other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipment to prevent rapid buildup ofpressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with Ion Exchange Resins, consult sourcesknowledgeable in the handling of these materials.


©2000 Rohm and Haas Company EDS 0620 A - Feb 2000 - 2/2

OPERATING CAPACITY

The operating capacity of IMAC HP555 is obtained bymultiplying the basic capacity value from figure 4 bythe correction factors C to E from figures 5 to 7.

Cap = Cap0 x C x D x E

Fig 4 : Basic Capacity versus Nitrate to EquivalentMineral Acidity Ratio

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0NO3/EMA Ratio

Bas

ic c

apac

ity e

q/L

Fig 5 : Capacity Correction Factor C versusRegenerant dosage

1.00

1.10

1.20

1.30

1.40

1.50

100 120 140 160 180 200 220 240

NaCl g/L

C

Fig 6 : Capacity Correction Factor D versus NitrateLeakage Endpoint

0.60

0.70

0.80

0.90

1.00

1.10

0 10 20 30 40 50

Endpoint NO3 mg/L

D

Fig 7 : Capacity Correction Factor E versus SpecificFlow Rate

E

0.96

0.98

1.00

1.02

1.04

1.06

0 10 20 30 40 50BV/h

©2000 Rohm and Haas Company EDS 0317 A - Apr 2000 - 1/2

IMAC® HP555


These data provide information to calculate thenitrate leakage and operating capacity of IMACHP555 used with reverse flow regeneration.

The properties of IMAC HP555 are described in theProduct Data Sheet ITS 0201 A.

NITRATE LEAKAGE

The average nitrate leakage is obtained by multiplyingthe basic leakage value from figure 1 by the correctionfactors A and B from figures 2 and 3.


Fig 1 : Basic Nitrate Leakage vs Endpoint

0

2

4

6

8

10

12

14

16

0 10 20 30 40 50

Leakage endpoint mg/L NO3

Ave

rag

e le

aka

ge

mg

/L N

O3

Fig 2 : Leakage Correction Factor A vsSulphate to Total Anions Ratio

0.8

0.9

1.0

1.1

1.2

1.3

1.4

1.5

1.6

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9SO4/TDS ratio

Cor

rect

ion

fact

or A

Fig 3 : Leakage Correction Factor B versus Regenerantdosage

0.600.700.800.901.001.101.201.301.40

50 100 150 200 250

NaCl dosage g/L

Fac

tor

B


Maximum operating temperature ________________ 50°CMinimum bed depth ___________________________ 1000 mm (preferably > 1400 mm)Service flow rate _______________________________ 5 to 40 BV*/hMaximum linear velocity ________________________ 50 m/hRegenerant ___________________________________ NaCl

Level ______________________________________ 60 to 200 g/LFlow rate __________________________________ 2 to 8 BV/h (minimum contact time : 30 minutes)Concentration______________________________ 6 to 10 %





IMAC is a trademark of Rohm and Haas Company, Philadelphia, U.S.A.Ion exchange resins and polymeric adsorbents, as produced, contain by-products resulting from the manufacturing process. The user must determine the extent to which organicby-products must be removed for any particular use and establish techniques to assure that the appropriate level of purity is achieved for that use. The user must ensurecompliance with all prudent safety standards and regulatory requirements governing the application. Except where specifically otherwise stated, Rohm and Haas Company doesnot recommend its ion exchange resins or polymeric adsorbents, as supplied, as being suitable or appropriately pure for any particular use. Consult your Rohm and Haas technicalrepresentative for further information. Acidic and basic regenerant solutions are corrosive and should be handled in a manner that will prevent eye and skin contact. Nitric acidand other strong oxidising agents can cause explosive type reactions when mixed with Ion Exchange resins. Proper design of process equipment to prevent rapid buildup ofpressure is necessary if use of an oxidising agent such as nitric acid is contemplated. Before using strong oxidising agents in contact with Ion Exchange Resins, consult sourcesknowledgeable in the handling of these materials.


©2000 Rohm and Haas Company EDS 0317 A - Apr 2000 - 2/2

OPERATING CAPACITY

The operating capacity of IMAC HP555 is obtained bymultiplying the basic capacity value from figure 4 bythe correction factors C to E from figures 5 to 7.

Cap = Cap0 x C x D x E

Fig 4 : Basic Capacity versus Nitrate to EquivalentMineral Acidity Ratio

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0NO3/EMA Ratio

Bas

ic c

apac

ity e

q/L

Fig 5 : Capacity Correction Factor C versusRegenerant dosage

0.500.600.700.800.901.001.101.201.301.401.50

50 100 150 200 250

Regenerant dosage g NaCl per litre

Fac

tor

C

Fig 6 : Capacity Correction Factor D versus NitrateLeakage Endpoint

0.80

0.85

0.90

0.95

1.00

1.05

1.10

5 10 15 20 25 30 35 40 45 50

NO3 leakage endpoint (ppm)

Fac

tor

D

Fig 7 : Capacity Correction Factor E versus SpecificFlow Rate

0.970.980.991.001.011.021.031.041.051.06

5 10 15 20 25 30 35 40 45 50

Specific Flow Rate BV/h

Fac

tor

E

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