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    ACADBASIC CURRICULUM

    NUCLEAR SCIENCE

    CHAPTER 1

    COMPONENTS,STRUCTURE,AND IDENTIFICATION OF THE ATOM

    STUDENT TEXT

    REV 2

    TM

    2003General Physics Corporation, Elkridge, Maryland

    All rights reserved. No part of this book may be reproduced in any form or by

    any means, without permission in writing f rom General Physics Corporation.

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    TABLE OF CONTENTS

    FIGURES AND TABLES ........................................................................................................... ii

    OBJECTIVES ............................................................................................................................ iii

    ATOMS ........................................................................................................................................ 1

    History ...................................................................................................................................... 1

    Structure .................................................................................................................................... 1

    Atomic Mass Unit ..................................................................................................................... 2

    Identification Of Atoms ............................................................................................................ 3

    Isotopes ..................................................................................................................................... 4

    Chart of the Nuclides ................................................................................................................ 5

    SUMMARY ................................................................................................................................. 7

    PRACTICE EXERCISES ............................................................................................................ 8

    GLOSSARY ................................................................................................................................. 9

    EXAMPLE EXERCISE ANSWERS ......................................................................................... 10

    PRACTICE EXERCISE ANSWERS ........................................................................................ 11

    NUCLEAR SCIENCE - CHAPTER 1 - i 2003 GENERAL PHYSICS CORPORATION

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    FIGURES AND TABLES

    Figure 1-1 Structure of Helium Atom ........................................................................................ 2

    Figure 1-2 Standard Notation for an Atom ................................................................................ 3Figure 1-3 Isotopes of Oxygen .................................................................................................. 4

    Figure 1-4 Portion of the Chart of the Nuclides ........................................................................ 5

    Table 1-1 Electrical Properties of Atomic Particles .................................................................. 2

    Table 1-2 Atomic Particle Location ........................................................................................... 2

    Table 1-3 Atomic Weight of Atomic Particles .......................................................................... 2

    Table 1-4 Standard Notation for Selected Atoms ...................................................................... 3

    NUCLEAR SCIENCE - CHAPTER 1 - ii 2003 GENERAL PHYSICS CORPORATION

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    OBJECTIVES

    Upon completion of this chapter, the student will be able to perform the following

    objectives at a minimum proficiency level of 80%, unless otherwise stated, on an oral

    or written exam.

    1. STATEthe characteristics of the following atomic particles, including relative mass, charge,and location within the atom:

    a. Protonb. Neutronc. Electron

    2. DEFINE the following terms:a. Atomic Mass Unit (AMU)b. Nucleonsc. Nuclided. Isotope

    3. STATE the two terms that represent the method by which atoms and subatomic particles aremeasured.

    4. Given a sample Chart of the Nuclides, IDENTIFY elements and isotopes.5. Given a standard XA

    Znotation for an electrically neutral atom, DETERMINE the following:

    a. Number of Protonsb. Number of Neutronsc. Number of Electrons

    NUCLEAR SCIENCE - CHAPTER 1 - iii 2003 GENERAL PHYSICS CORPORATION

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    ATOMS

    HISTORY

    Early Greek philosophers speculated that theearth was made up of different combinations of

    basic substances, or elements. They consideredthese basic elements to be earth, air, water, and

    fire. Modern science shows that the early Greeks

    held the correct concept that matter consists of acombination of basic elements, but they

    incorrectly identified the elements.

    In 1661 the English chemist Robert Boyle

    published the modern criterion for an element.

    He defined an element to be a basic substancethat cannot be broken down into any simpler

    substance after it is isolated from a compound,

    but can be combined with other elements to formcompounds. To date, 109 different elements

    have been confirmed to exist. Researchers claim

    to have discovered nine additional elements. Of

    the 109 confirmed elements, 90 exist in natureand the rest are man-made.

    Another basic concept of matter that the Greeks

    debated was whether matter was continuous or

    discrete. That is, whether matter could becontinuously divided and subdivided into ever

    smaller particles or whether eventually an

    indivisible particle would be encountered.

    Democritus in about 450 B.C. argued thatsubstances were ultimately composed of small,

    indivisible particles that he labeled atoms. He

    further suggested that different substances werecomposed of different atoms or combinations of

    atoms, and that one substance could be converted

    into another by rearranging the atoms. It was

    impossible to conclusively prove or disprove thisproposal for more than 2000 years.

    The English chemist John Dalton first proposed

    the modern proof for the atomic nature of matter

    in 1803. Dalton stated that each chemical

    element possesses a particular kind of atom, and

    any quantity of the element is made up of

    identical atoms of this kind. What distinguishes

    one element from another element is the kind ofatom of which it consists, and the basic physical

    difference between kinds of atoms is their

    weight.

    For almost 100 years after Dalton established theatomic nature of atoms, it was considered

    impossible to divide the atom into even smaller

    parts. All of the results of chemical experiments

    during this time indicated that the atom wasindivisible. Eventually, experimentation into

    electricity and radioactivity indicated that

    particles of matter smaller than the atom didindeed exist. In 1906, J. J. Thompson won the

    Nobel Prize in physics for establishing the

    existence of electrons. Electronsare negativelycharged particles that have 1/1835 the mass of

    the hydrogen atom. Soon after the discovery of

    electrons, protons were discovered. Protonsarerelatively large particles that have almost the

    same mass as a hydrogen atom and a positive

    charge equal in magnitude (but opposite in sign)

    to that of the electron. The third subatomicparticle to be discovered, the neutron, was not

    found until 1932. The neutron has almost thesame mass as the proton, but it is electrically

    neutral.

    STRUCTURE

    All matter (gas, liquid or solid) is made up ofone or more elements (hydrogen, oxygen, gold,

    etc.).

    An element is a substance that cannot be

    decomposed or broken into more elementary

    substances by ordinary chemical means. Atoms

    make up all elements. An atom is the smallestamount of matter of an element that retains the

    elements properties.

    Three fundamental (atomic) particles make up an

    atom. The individual numbers of these particles

    NUCLEAR SCIENCE - CHAPTER 1 - 1 of 13 2003 GENERAL PHYSICS CORPORATION

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    within an atom determines the characteristics of

    the atom. These particles are as follows:

    Table 1-1 Electrical Properties of Atomic

    Particles

    Particle Charge

    Proton +1

    Neutron 0

    Electron 1

    An atom having the same number of electrons in

    its shells as protons inside the nucleus is

    electrically neutral. Figure 1-1 represents anelectrically neutral atom of helium.

    The measurement of energy associated with the

    atomic particles is in units termed electron volt(eV). The electron volt is the amount of kinetic

    energy gained by an electron when acceleratedthrough an electric potential difference of 1 volt.

    One electron volt is equivalent to 1.603 1019

    joules, or 1.18 1019

    foot pounds (ft lb f). Forlarger values, the units of energy are keV for

    thousand electron volts, MeV for million

    electron volts, or BeV for billion electron volts.

    Figure 1-1 represents the traditionally acceptable

    model of a helium atom. It shows neutrons andprotons making up a nucleus of the atom.

    Particles within the nucleus are often referred to

    as nucleons. The electrons are in concentricorbits (also called shells) around the nucleus.

    ELECTRONS

    IN VARIOUS

    ORBITS P N

    N P

    Figure 1-1 Structure of Helium Atom

    Table 1-2 Atomic Particle Location

    Particle Location

    Proton Nucleus

    Neutron Nucleus

    Electron Shell outside nucleus

    ATOMIC MASS UNIT

    Atoms and their subatomic particles aremeasured on the atomic scale that is based on

    mass and energy. Energy measurements are in

    units of eV, as discussed previously. The unit ofmeasure for mass is the atomic mass unit

    (AMU).

    The AMU is based on the mass of the carbon-12atom and is equal to 1/12 of the carbon-12 atom

    resulting in a value of 1.66 1024

    grams.Table 1-3 displays the properties of the three

    particles that make up the atom.

    Table 1-3 Atomic Weight of Atomic Particles

    Particle Mass (AMU)

    Proton 1.00727

    Neutron 1.00866

    Electron 0.00055

    Nuclides do not vary significantly in size. The

    radius of the typical atom is approximately

    2 108

    cm. Significant is that the radius of the

    nucleus may vary from approximately1.25 10

    -13cm for the smaller nuclides to

    8 1013

    cm for the largest nuclides. Comparing

    this to the typical radius of the entire atom showsthat the entire atom is more than 25,000 times

    the size of the largest nucleus.

    NUCLEAR SCIENCE - CHAPTER 1 - 2 of 13 2003 GENERAL PHYSICS CORPORATION

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    Complete the table for the properties of anatom.

    Particle Charge Mass

    (AMU)

    Location

    Proton

    0

    0.00055

    Example 1-1

    The mass of an electron is:

    a. equal to a protonb. equal to a neutronc. greater than a protond. less than a neutron

    Example 1-2

    IDENTIFICATION OF ATOMS

    The number of protons within the nucleusdetermines the atomic number of an element. It

    is represented by the symbol Z. This is thereference number used in the periodic table of

    elements (Hydrogen with 1 proton, Helium with

    2, Oxygen with 8, Uranium with 92, etc.) forelement identification.

    The total number of nucleons (neutrons andprotons) in the nucleus is called the mass

    number. It is given the symbol A. The number of

    neutrons can be calculated by (A Z = N)

    Figure 1-2 shows the standard notation for

    identification of an atom:

    XA

    Z

    Where:

    A = atomic mass number (protons andneutrons)

    X = element symbol

    Z = atomic number (protons)

    Figure 1-2 Standard Notation for an Atom

    Table 1-4 provides examples of standard

    notation for several elements.

    Table 1-4 Standard Notation for Selected Atoms

    Helium He4

    2

    Boron B105

    Carbon C126

    Oxygen O168

    Uranium U23892

    Plutonium Pu23994

    There are many different possible combinations

    of protons and neutrons within the nucleus. Eachunique combination is referred to as a nuclide.

    Each one of the atoms shown inTable 1-4 is a

    nuclide.

    NUCLEAR SCIENCE - CHAPTER 1 - 3 of 13 2003 GENERAL PHYSICS CORPORATION

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    ISOTOPES

    The number of neutrons in an atom of a

    particular element may vary. Atoms of the same

    element (those with same number of protons)with different numbers of neutrons are called

    isotopes of the element. It is common to identify

    isotopes by including the atomic number withthe symbol or the name of the element.

    Figure 1-3 represents three isotopes of oxygen:

    O-16, O-17, and O-18.

    ISOTOPES OF OXYGEN

    16 17 18

    8 8 8O O O

    8 PROTONS

    8 NEUTRONS

    8 PROTONS

    9 NEUTRONS

    8 PROTONS

    10 NEUTRONS

    NATURAL ABUNDANCE - ATOM PERCENT

    99.758% 0.038% 0.204%

    Figure 1-3 Isotopes of Oxygen

    Additionally, there are at least eight moreunstable or artificially made isotopes of oxygen.

    The Chart of the Nuclides provides a visualrepresentation of stable and unstable isotopes of

    all elements.

    Because each isotope represents a unique

    combination of neutrons and protons in the

    nucleus, they are also nuclides.

    Important to note here is that isotopes of thesame element all behave the same in chemical

    reactions (because they have the same number of

    protons and electrons). Isotopes can behavesignificantly different from each other in nuclear

    reactions (because they have different numbers

    of neutrons).

    Define the following Nuclear Science terms:

    a. Nucleon

    b. Isotope

    Example 1-3

    How many neutrons are in an atom of U23892 ?

    Example 1-4

    State the name of the element and the number of

    protons, electrons, and neutrons in the nuclides

    listed below.

    Symbol Name Neutron Proton Electron

    H11

    B10

    5

    N147

    Co6027

    Pu242

    94

    Example 1-5

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    CHART OF THE NUCLIDES

    A tabulated chart called the Chart of the

    Nuclides lists the stable and unstable nuclides in

    addition to pertinent information about each one.Figure 1-4 shows a small portion of a chart. This

    chart plots a box for each individual nuclide,

    with the number of protons (Z) on the verticalaxis and the number of neutrons (N = A Z) on

    the horizontal axis.

    Located in the box on the far left of each

    horizontal row is general information about the

    element. The box contains the chemical symbolof the element, the average atomic weight of the

    naturally occurring substance, and the name of

    the chemical. The known isotopes (elements

    with the same atomic number Z but differentmass number A) of each element are listed to the

    right.

    Complete charts contain much more details than

    shown in the example here. This chart shows the

    isotopes, and either the percentage of naturally

    occurring atoms or the half-life of radioactiveisotopes. By consulting a complete chart, other

    types of isotopes can be found, such as naturally

    occurring radioactive types. Complete charts arecommonly color coded to show similar half-lives

    and neutron cross section for absorption.

    Notice there are three isotopes of Hydrogen;

    H11 , hydrogen; H2

    1 , deuterium; and H3

    1 , tritium.

    H11 , hydrogen and H2

    1 , deuterium are in gray

    boxes, they are stable. Hydrogen occurs

    99.985% of the time in nature. Deuterium

    occurs 0.015% of the time in nature. Tritium isunstable; it has a half life of 12.3 years.

    43

    2

    6

    0 1

    1

    2

    0

    3

    4

    5

    N

    B 1019.9

    B 98E-19 s

    B 8770 ms

    B 74E-22 s

    Be 9100

    Li 80.84 s

    Be 8~7E-17 s

    Li 792.5

    Be 753.28 d

    Li 67.5

    Be 65.0E-21 s

    Li 5~3E-22 s

    He 73E-21 s

    He 6807 ms

    He 57.5E-22 s

    He 499.999862

    B 1220.20 ms

    B 1180.1

    Be 1113.8 s

    Li 9177 ms

    He 9Extremely

    short

    He 8199 ms

    He 30.00138

    H 20.015

    H 199.985

    H1.0079

    Hydrogen

    He4.002602

    Helium

    Li6.941

    Lithium

    Be9.012182

    Beryllium

    B10.811

    Boron

    Z

    H 312.3 a

    Be 101.6E6 a

    Figure 1-4 Portion of the Chart of the Nuclides

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    Using Figure 1-4 Portion of the Chart of the

    Nuclides

    a. How many elements are identified?

    b. How many isotopes of Lithium are

    identified?

    Example 1-6

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    SUMMARY

    Atoms consist of three basic subatomic particles.

    Protons are particles that have a positivecharge, have about the same mass as ahydrogen atom, and exist in the nucleus ofan atom.

    Neutrons are particles that have noelectrical charge, have about the samemass as a hydrogen atom, and exist in the

    nucleus of an atom.

    Electrons are particles that have a negativecharge, have a mass about eighteen

    hundred times smaller than the mass of ahydrogen atom, and exist in orbital shells

    around the nucleus of an atom.

    The model of the atom consists of a dense nucleus

    of protons and neutrons (nucleons) surrounded by

    electrons traveling in discrete orbits at fixeddistances from the nucleus.

    Nuclides are atoms that contain a particular

    number of protons and neutrons.

    Isotopes are nuclides that have the same atomic

    number and are therefore the same element, but

    differ in the number of neutrons.

    The atomic number of an atom is the number ofprotons in the nucleus.

    The mass number of an atom is the total numberof nucleons (protons and neutrons) in the nucleus.

    XAZ represents a specific nuclide.

    A represents the mass number, which isequal to the number of nucleons (protons

    and neutrons).

    X represents the chemical symbol of theelement.

    Z represents the atomic number, whichis equal to the number of protons (andelectrons).

    Number of neutrons N = A Z

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    PRACTICE EXERCISES

    1. Use the figure below of an atom to completethe exercises below:

    a.

    Assuming the same number of each ofthe particles that make up this atom,

    give a label to each particle.

    b. What would need to be changed in thefigure to make it represent another

    isotope?

    c. Label each of the particles in the figurewith the appropriate electrical charge.

    d. List the atomic number and atomicmass number for this atom.

    2. The two primary means used formeasurement of atoms are: (select one)

    a. size and shapeb. mass and energyc. shape and massd. energy and size

    3. Complete the following table by inserting thecorrect number for each part of the associated

    atom.

    Proton Neutron Electron Nucleons

    Hydrogen H1

    1

    Tritium H31

    Silver Ag10747

    Uranium U23592

    Uranium U23892

    4. Using the figure below,

    U2362.34E7 a

    U2357.04E8 a

    U2342.46E5 a

    U2331.59E5 a

    U23923.5 m

    U23270. a

    U2376.75 d

    U2384.47E9 a

    Pu23887.7 a

    Pu23745.2 d

    Pu2362.87 a

    Pu23525.3 m

    Pu24114.4 a

    Pu2392.41E4 a

    Pu2348.8 h

    Pu2406.56E3 a

    Th23322.3m

    Th23424.10d

    Th2357.2m

    Th2321.40E10a

    Th2307.54E4a

    Th2311.063d

    Th23637.5m

    Pa23524.4 m

    Pa2346.69 h

    Pa23327.0 d

    Pa2321.31 d

    Pa2382.3 m

    Pa2369.1 m

    Pa2313.28E4a

    Pa2378.7 m

    Np2361.55E5 a

    Np2372.14E6 a

    Np2351.085 a

    Np2344.4 d

    Np2401.032 h

    Np23336.2 m

    Np2382.117 d

    Np2392.355 d

    a. Identify each nuclide.

    b. Determine the number of isotopes ofuranium.

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    GLOSSARY

    Atomic Mass Unit

    (AMU)

    A unit of measurement equal to 1/12 the mass of a Carbon 12 atom

    (1.6605402 x 1024

    grams).

    Electron Sub-atomic particle that makes up an atom, has a mass of 0.00055 AMU, anegative charge, and is located outside the nucleus in probability shells

    (orbits).

    Electron Volt (eV) Amount of kinetic energy (eV) gained by an electron when accelerated

    through an electric potential difference of 1 volt. It is equivalent to

    1.603 1019

    joule. It is a unit of energy or work, not of voltage, and is

    the common measure of a neutrons energy. Larger multiple units of the

    electron volt are frequently used: keV for thousand or kilo electron volts,MeV for million electron volts, and BeV for billion electron volts.

    Element A basic substance that cannot be broken down into any simpler substanceafter it is isolated from a compound, but can be combined with other

    elements to form compounds.

    Isotopes A nucleus of the same element (same number of protons) with a different

    number of neutrons.

    Neutron Sub-atomic particle that makes up an atom, has a mass of 1.00866 AMU, a

    neutral charge, and is located in the nucleus.

    Nucleon Any particle that is part of the nucleus of an atom, neutrons and protons.

    Nuclide Any atom containing a unique combination of neutrons and protons in the

    nucleus.

    Proton Sub-atomic particle that makes up an atom, has a mass of 1.00727 AMU, a

    positive charge, and is located in the nucleus.

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    EXAMPLE EXERCISE

    ANSWERS

    Complete the table for the properties of an

    atom.

    Particle Charge Mass

    (AMU)

    Location

    Proton +1 1.00727 Nucleus

    Neutron 0 1.00866 Nucleus

    Electron 1 0.00055 Shell

    Example 1-1

    The mass of an electron is:

    a. equal to a protonb. equal to a neutronc. greater than a protond. less than a neutron

    ANSWER: "dless than a neutron

    Example 1-2

    Define the following Nuclear Science terms:

    a. Nucleon

    Any particle that is part of the

    nucleus of an atom; neutrons and

    protons.

    b. Isotope

    A nucleus of the same element (same

    number of protons) with a different

    number of neutrons.

    Example 1-3

    How many neutrons are in an atom of U23892 ?

    AZ = N

    238 92 = 146 neutrons

    Example 1-4

    State the name of the element and the number of

    protons, electrons, and neutrons in the nuclides

    listed below.

    Symbol Name Neutron Proton Electron

    H11 Hydrogen 0 1 1

    B105 Boron 5 5 5

    N147 Nitrogen 7 7 7

    Co6027 Cobalt 33 27 27

    Pu24294 Plutonium 138 94 94

    Example 1-5

    Using Figure 1-4 Portion of the Chart of the

    Nuclides

    a. How many elements are identified?

    a. Five; hydrogen, helium, lithium,

    beryllium, and boron

    b. How many isotopes of Lithium are

    identified?

    b. Five; Li-5, Li-6, Li-7, Li-8, and Li-9

    Example 1-6

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    PRACTICE EXERCISE

    ANSWERS

    1. Use the figure below of an atom to completethe exercises below:

    a. Assuming the same number of each of

    the particles that make up this atom,give a label to each particle.

    b. What would need to be changed in thefigure to make it represent another

    isotope?

    Change number of neutrons in the

    nucleus.

    c. Label each of the particles in the figure

    with the appropriate electrical charge.

    Electrons labeled with negative

    charge, neutrons no charge, protons

    positive charge.

    d. List 1) the atomic number and 2) atomicmass number for this atom.

    Atomic mass number of 4 and atomic

    number of 2

    2. The two primary means used formeasurement of atoms are: (select one)

    b. mass and energy

    3. Complete the following table by insertingthe correct number for each part of the

    associated atom.

    Proton Neutron Electron Nucleon

    Hydrogen

    H

    1

    1

    1 0 1 1

    Tritium H31 1 2 1 3

    Silver Ag10747 47 60 47 107

    Uranium U23592 92 143 92 235

    Uranium U23892 92 146 92 238

    4. Using the figure below,

    U2362.34E7 a

    U2357.04E8 a

    U2342.46E5 a

    U2331.59E5 a

    U23923.5 m

    U23270. a

    U2376.75 d

    U2384.47E9 a

    Pu23887.7 a

    Pu23745.2 d

    Pu2362.87 a

    Pu23525.3 m

    Pu24114.4 a

    Pu2392.41E4 a

    Pu2348.8 h

    Pu2406.56E3 a

    Th233

    22.3m

    Th234

    24.10d

    Th235

    7.2m

    Th232

    1.40E10a

    Th230

    7.54E4a

    Th231

    1.063d

    Th236

    37.5m

    Pa23524.4 m

    Pa2346.69 h

    Pa23327.0 d

    Pa2321.31 d

    Pa2382.3 m

    Pa2369.1 m

    Pa2313.28E4a

    Pa2378.7 m

    Np2361.55E5 a

    Np2372.14E6 a

    Np2351.085 a

    Np2344.4 d

    Np2401.032 h

    Np23336.2 m

    Np2382.117 d

    Np2392.355 d

    c. Identify each nuclide.5, thorium, protactinium, uranium,

    neptunium, plutonium,

    electrons

    two neutrons and two protons

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    d. Determine the number of isotopes ofuranium.

    8, U-232, U-233, U-234, U-235, U-236, U-

    237, U-238, U239

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    ACADBASIC CURRICULUM

    NUCLEAR SCIENCE

    CHAPTER 2

    MASS DEFECT AND BINDING ENERGY

    MASS DEFECT

    Mass of all of the individual particles isgreater than the mass of the combinednucleus. The difference is called the

    Mass Defect.

    INDIVIDUAL

    PARTICLES

    COMBINED

    NUCLEUS

    p

    p

    p

    p

    p

    n n n

    n

    n

    e

    e e

    STUDENT TEXT

    REV 2

    TM

    2003 General Physics Corporation, Elkridge, Maryland

    All rights reserved. No part of this book may be reproduced in any form or by

    any means, without permission in writing f rom General Physics Corporation.

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    TABLE OF CONTENTS

    FIGURES AND TABLES ........................................................................................................... ii

    OBJECTIVES ............................................................................................................................ iii

    FORCES WITHIN THE ATOM.................................................................................................. 1

    Electrostatic and Nuclear Force ................................................................................................ 1

    Nuclear Force And Nuclear Stability ........................................................................................ 2

    Neutron Contribution To Nuclear Stability .............................................................................. 2

    TYPES OF RADIATION ............................................................................................................ 3

    Alpha Particles .......................................................................................................................... 3

    Beta Particles ............................................................................................................................ 4

    Gamma Rays ............................................................................................................................. 4

    Neutrons .................................................................................................................................... 4

    MASS DEFECT AND BINDING ENERGY .............................................................................. 5

    Mass Defect .............................................................................................................................. 5

    Binding Energy ......................................................................................................................... 7

    Binding Energy Per Nucleon .................................................................................................... 8

    Binding Energy Per Neutron ................................................................................................... 10

    Energy Released by Fission .................................................................................................... 11

    SUMMARY ............................................................................................................................... 13

    PRACTICE EXERCISES .......................................................................................................... 14

    GLOSSARY ............................................................................................................................... 16

    EXAMPLE EXERCISE ANSWERS ......................................................................................... 17

    PRACTICE EXERCISE ANSWERS ........................................................................................ 20

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    FIGURES AND TABLESFigure 2-1 Electrostatic and Nuclear Forces .............................................................................. 1

    Figure 2-2 Nuclear Force Boundary .......................................................................................... 2

    Figure 2-3 Neutron to Proton Ratio ........................................................................................... 2

    Figure 2-4 Radiation Types ....................................................................................................... 5

    Figure 2-5 Mass Defect .............................................................................................................. 5

    Figure 2-6 Mass Energy Equivalence ........................................................................................ 7

    Figure 2-7 Mass Defect .............................................................................................................. 7

    Figure 2-8 Binding Per Nucleon vs. Mass Number ................................................................... 8

    Figure 2-9 Binding Energy of a Neutron ................................................................................. 10

    No Tables

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    OBJECTIVES

    Upon completion of this chapter, the student will be able to perform the following

    objectives at a minimum proficiency level of 80%, unless otherwise stated, on an oral

    or written exam.

    1. DESCRIBE the characteristics of the following, including relative effective distance, changewith distance, and nucleons involved with each:

    a. Electrostatic Forceb. Nuclear Force

    2. STATE the role that neutrons have regarding the stability of a nucleus.3. DEFINE the following terms:

    a. Binding energyb. Binding energy per nucleonc. Fissiond. Mass defecte. Mass-energy equivalencef. Nuclear Stability

    4. STATE the purpose of radioactive decay.5. IDENTIFY the four basic types of radiation.6. For each of the four basic types of radiation, DISCUSS the following:

    a. Relative ability to penetrate substances when compared to the other three types ofradiation.

    b. Size or mass.c. Electrical charge.

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    OBJECTIVES

    7. Given a Chart Of Nuclides, or equivalent information, CALCULATE the binding energy andbinding energy per nucleon of a given nucleus.

    8. Given a plot of binding energy per nucleon, EXPLAIN the changing slope of the curve.

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    FORCES WITHIN THE

    ATOM

    ELECTROSTATIC AND NUCLEAR

    FORCE

    One basic law of electricity is that objects withthe same electrical charge repel each other and

    objects with opposite charges attract. This is

    termed electrostatic force (also called coulombforce). The force acts over relatively long

    distances and is cumulative.

    Because the nucleus is composed of positively

    charged protons and neutrally charged neutrons,

    an attractive force of some kind must exist in astable nucleus to overcome the repulsive

    electrostatic force associated with the protons.This attractive force is termed nuclear force.

    Nuclear forces are much stronger than

    electrostatic forces when acting over very short

    distances, but decrease dramatically withincreasing distance.

    The nuclear forces act upon any adjacent

    nucleons: proton to proton, neutron to proton,

    and neutron to neutron. Figure 2-1 shows asimplified diagram of the concept of electrostatic

    and nuclear force.

    Like charged particles slightly

    separated will experience a

    coulomb force of repulsion:

    Nuclear forces of attraction

    are produced when adjacent

    nucleons are involved:

    ELECTRONS

    - -

    PROTONS

    + +

    PROTONS

    + +

    PROTON AND NEUTRON

    + n

    NEUTRONS

    n n

    Figure 2-1 Electrostatic and Nuclear Forces

    Nuclear force is strong over ________(long/short) distances and is _________

    (stronger/weaker) than electrostatic forces

    at that distance.

    Example 2-1

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    NUCLEAR FORCE AND NUCLEAR

    STABILITY

    Nuclear stability is the inherent ability of anatom to resist changing its atomic structure or

    energy.

    Stability of the nucleus depends upon the

    balance between the repulsion of the electrostatic

    forces and the attraction by the nuclear force. Asshown in the simplified illustration ofFigure 2-2,

    there is a short boundary surrounding a proton

    within which it is attracted to its nearest protonsor neutrons. Outside this boundary, it repels all

    other protons within the nucleus by electrostatic

    force.

    Proton

    NuclearForce

    Boundary

    Figure 2-2 Nuclear Force Boundary

    The limited range of effectiveness of the nuclearforce has a major role in the stability of the

    nucleus.

    Define nuclear stability.

    Example 2-2

    NEUTRON CONTRIBUTION TO

    NUCLEAR STABILITY

    Because there is no electrostatic repulsion

    between protons and neutrons or between

    neutrons and neutrons, the effective boundary for

    nuclear force is larger between these nucleons.To put it another way, the nuclear force is more

    effective between a neutron and proton, and most

    effective between two neutrons. This mightsuggest that a nucleus having a greater number

    of neutrons than protons would be more stable

    (tightly bound) than one that does not. Thefollowing discussion shows this to be true to a

    point.

    Figure 2-3 is a graph that has two plots. The

    dashed line is a reference plot showing what the

    graph would look like if all nuclides had thesame number of neutrons as protons (N=Z). The

    line of random dots represents the plot of

    naturally occurring stable nuclides.

    LINE OF

    STABILITY

    NUMBER OF NEUTRONS (N = A - Z)

    NUMBE

    R

    OFPROTONS(Z)

    100

    80

    60

    40

    20

    0

    0 20 40 60 80 100 120 140

    NZ = 1

    Figure 2-3 Neutron to Proton Ratio

    The plot shows that for small nuclei the ratio of

    neutrons to protons is nearly equal to one. In

    progressively larger nuclei the neutron to proton

    ratio

    Z

    ZA becomes larger. This

    phenomenon is mainly due to the neutrons

    contributing a strong but very short nuclear force

    and no repulsive electrostatic force. With

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    increasingly larger nuclei the ratio of neutrons to

    protons increases to add enough nuclear force to

    overcome the sum of the electrostatic repulsive

    forces and maintain a stable nucleus.

    As the size of the nuclei increases there is a pointwhere increasing the population of neutrons no

    longer results in the balance of the repulsive andattractive forces within the nucleus. At thispoint, the addition of neutrons will result in an

    unstable nucleus.

    There is no known stable nucleus with an atomic

    number larger than bismuth ( Bi20983 ). Nuclei with

    more than 83 protons are unstable and

    spontaneously undergo radioactive decay and

    emit various types of energy in the process.

    Describe the plots shown in Figure 2-3

    Neutron to Proton Ratio

    Z

    N=1

    Line of Stability

    Example 2-3

    TYPES OF RADIATION

    Radioactive decay is the process by which anunstable nucleus spontaneously transmutes from

    one form (element) to another to reach a more

    stable state. Radioactive decay is discussed ingreater detail in Chapter 3. The term is

    introduced here because it is the birthplace of

    most of the radiation occurring in a nuclear

    power plant.

    The radioactive decay process is normallyaccompanied by the emission of one or more

    types of radiation. The radiation is in the form

    of either particles or electromagnetic energy(gamma rays or photons).

    In general, the following statements are trueregarding radiation interactions:

    The larger the mass, the greater the ability tointeract with a target substance, resulting in

    lesser ability to penetrate the substance

    The greater the electric charge, the greaterthe ability to interact with a target substance,

    and lesser ability to penetrate the substance.

    The greater the velocity, the greater theability to penetrate a target substance.

    There are four basic types of radiation: alpha

    particles, beta particles, gamma rays, and

    neutrons.

    ALPHA PARTICLES

    An alpha particle () is a charged particle

    consisting of two protons and two neutrons.Another way to look at it is as a Helium nucleus

    with a double positive charge and a relatively

    large mass. The large mass and the double

    positive charge cause it to interact easily withany substance it contacts. The large mass and

    charge results in a very short range of travel,

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    because it interacts so much. A piece of paper

    stops most alpha particles. Typically alpha

    decay occurs at the upper end of the line of

    stability.

    BETA PARTICLESA beta particle () is a positively (+) ornegatively () charged particle emitted from thenucleus with a mass equal to that of an electron.

    It is a high-energy particle of small mass, but theelectrical charge causes an immediate interaction

    with the atoms of any material it comes in

    contact with. A thin sheet of metal and mostsafety glasses stops beta particles.

    There are two types of beta particles: electron

    and positron.

    An electron (beta minus ) is a negative betaparticle. It is typically emitted from unstablenuclei decaying below the line of stability. It is

    commonly found with fission products created

    from the fission of fuel in commercial reactors.

    A positron (beta plus +) is a positive betaparticle that is typically emitted from unstable

    nuclei decaying above the line of stability. It is

    not commonly seen in commercial nuclear powerplants.

    GAMMA RAYS

    A Gamma ray () is an electromagnetic energythat possesses neither mass nor charge. It is in a

    class of energy known as photons. Photons are

    discrete bundles of energy that have

    characteristics of waves and particles. Withessentially no mass and with generally high

    energy (velocity), it penetrates materials easilyand does not interact electrically with a

    materials atoms. The distance a gamma ray

    travels relies greatly on the density of thematerial it interacts with. It often requires

    several inches of metal or a couple of feet of

    concrete to stop.

    NEUTRONS

    A Neutron ( n10

    ) is a particle with no electrical

    charge originating in the center (nucleus) of anatom. Energy level can vary greatly. It has a

    relatively large mass when compared to Beta

    particles, but small in comparison to an alphaparticle. It has no electrical charge, so it easily

    penetrates substances. The only way for a

    neutron to interact is through collisions with thematerials atoms. It continues to travel until it

    gives up all its energy and is absorbed by the

    nucleus of an atom terminating its travel. Itusually requires about a foot of water to stop a

    neutron.

    Figure 2-4 shows these radiation types.

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    GAMMAELECTROMAGNETIC

    RADIATION

    CHARGE: 0

    MASS: 0

    NEUTRON10

    n

    CHARGE: 0

    MASS: 1 AMU

    n

    BETA MINUS

    0

    -1e

    ELECTRON

    CHARGE: -1

    MASS: 1/1800 AMU

    -

    BETA PLUS

    +0

    +1e

    POSITRON

    CHARGE: +1

    MASS: 1/1800 AMU

    +

    ALPHA

    42

    He++

    HELIUM

    NUCLEUS

    CHARGE: +2

    MASS: 4 AMU

    +

    +

    Figure 2-4 Radiation Types

    Of the four radiation types, which one is leastpenetrating and why?

    Of the four radiation types, which carry no

    electrical charge?

    Example 2-4

    MASS DEFECT AND

    BINDING ENERGY

    MASS DEFECT

    Whena nucleus is assembled from its component

    parts (protons and neutrons and electrons), thetotal mass of the nuclide is less than the total

    mass of the individual particles (Figure 2-5).

    This mass difference is called the mass defect

    (m).

    MASS DEFECT

    Mass of all of the individual particles isgreater than the mass of the combinednuclide. The difference is called the MassDefect.

    INDIVIDUALPARTICLES

    COMBINEDNUCLEUS

    p

    pp

    p

    pn n n

    n

    n

    e

    ee

    Figure 2-5 Mass Defect

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    The mass defect is measured in atomic mass

    units (AMU). One AMU is equal to

    1.66 10-24

    grams. It is possible to calculate the

    mass defect for each nucleus usingEquation 2-1.

    MmZ)-A(Zmm nH +=

    Where:

    m = mass defect (AMU)

    Z = atomic number (number of

    protons)

    mH = mass of H11 atom

    (1.0078 AMU)

    A = atomic mass number (number

    of nucleons)

    mn = mass of a neutron(1.0087 AMU)

    M = mass of the atom

    Equation 2-1

    The values for the variables in the aboveequation can be found in the Chart of the

    Nuclides. To account for the mass of an atoms

    electrons, we use the mass of a hydrogen atomvice the mass of a proton. The mass of the

    hydrogen atom has been experimentally

    determined and includes the mass of theelectrons.

    Calculate the mass defect of the U-235

    atom. Uranium-235 has a mass of235.0439 AMU.

    M = 235.0439 AMU

    MmZ)-A(Zmm nH +=

    0439.235

    )92)(1.0087-235(1.0078)(92m

    +=

    0439.2352441.1447176.92m +=

    AMU9178.1m=

    Example 2-5

    Calculate the mass defect of the U-238

    atom. Uranium has a mass of

    238.0508 AMU.

    MmZ)-A(Zmm nH +=

    =m

    Example 2-6

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    BINDING ENERGY

    Equation 2-2 is derived from Einsteins Theory

    of Relativity. Initially postulated, it was later

    experimentally proven to be:

    2mcE=

    Where:

    E = energy released (MeV)

    m = mass (AMU)

    c = speed of light

    sec

    m

    Equation 2-2

    Figure 2-6 shows a simplified sketch of this

    mass-energy equivalence.

    MASS-ENERGY EQUIVALENCE

    E = mc2

    TWO FORMS OF THE SAME THING

    MASS ENERGY

    Figure 2-6 Mass Energy Equivalence

    Incorporating various conversion factors, a

    simplified equation for the mass defect to energyequivalence results:

    ( ) ( )

    =AMU

    MeV5.931AMUmMeVE

    Equation 2-3

    The energy term, as related to mass defect, is

    known as binding energy (BE). Binding energy

    is defined as the energy equivalent of the massdefect and has units of MeV (mega electron

    volts). Binding energy represents the amount of

    energy released when protons, neutrons, and

    electrons combined to form an atom, as shown in

    Figure 2-7.

    MASS DEFECT

    Mass of all of the individual particles isgreater than the mass of the combinednuclide. The difference is called the MassDefect.

    INDIVIDUALPARTICLES

    COMBINEDNUCLEUS

    p

    pp

    p

    pn n n

    n

    n

    e

    e e

    Figure 2-7 Mass Defect

    Binding energy also represents the amount of

    energy that must be supplied to the atom to

    separate the atom into its individual protons,

    neutrons, and electrons. The more tightly boundthe atom, the greater the binding energy required

    to dismantle the atom.

    In a previous example, it was determined that a

    mass defect occurred when forming a U-235

    atom from its component parts. The missingmass was converted into binding energy that

    holds the atom together. It is possible to relate

    the mass defect to a certain amount of energy.

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    Consider the following examples:

    Determine the energy equivalence of themass defect of a U-235 atom.

    The mass defect for a U-238 atom was1.9178 AMU.

    ( )

    =AMU

    MeV5.931AMUmE

    E = (1.9178)(931.5)

    E = 1786.4307 MeV

    Example 2-7

    Determine the energy equivalence of the massdefect of a U-238 atom. Recall that the massdefect for a U-238 atom was 1.937 AMU.

    Example 2-8

    BINDING ENERGY PER NUCLEON

    The binding energy of an individual member of

    the nucleus, or the binding energy per nucleon

    A

    BE, is another important concept. This term

    represents the average energy required to remove

    a nucleon from a given nucleus. Dividing the

    total binding energy by the number of nucleonsequals the binding energy per nucleon.

    Plotting binding energy as a function of atomicmass number results in a curve similar to the one

    inFigure 2-8. Note that the binding energy pernucleon increases to a maximum of 8.6 MeV at a

    mass number of 60. Binding energy per nucleon

    slowly decreases as the mass number increasesbeyond 60. For A > 209, no stable nuclei exist.

    B

    INDINGE

    NERGYPER

    NUCLEON

    (MeV)

    MASS NUMBER

    Figure 2-8 Binding Per Nucleon vs. Mass

    Number

    The area of interest in this curve is the region of

    decreasing binding energy per nucleon with an

    increasing mass number.

    This occurs because the proton-to-protonrepulsive force increases faster than the nuclear

    attractive forces. In this region, there is a net

    gain of energy (energy is released) in a fissionreaction. The total binding energy of the system

    after a fission reaction is greater than the total

    binding energy of the system before the fission

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    reaction. The increase in binding energy results

    in the release of energy from the system. In

    other words, some amount of mass is lost after

    the fission reaction. This missing mass convertsinto energy and radiates from the system.

    Calculate the mass defect of the Nickel 58atom. Ni-58 has a mass of 57.9353 AMU.

    M = 57.9353 AMU

    m = ZmH+ (A Z) mn M

    m = 28(1.0078) + (58 28)(1.0087)

    57.9353

    m = 28.2184 + 30.261 57.9353

    m = 0.5441 AMU

    Example 2-9

    Calculate the binding energy for Ni-58.

    Example 2-10

    Calculate the binding energy per nucleon for

    Ni-58.

    nucleonperMeV74.858

    8.506

    A

    BE==

    Example 2-11

    Given the binding energy for U-238 is

    1804.3, calculate the binding energy pernucleon for U-238.

    Example 2-12

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    BINDING ENERGY PER NEUTRON

    Binding energy is similar in terms of neutron

    binding energy. As shown in Figure 2-9, this

    represents the minimum amount of energy that aneutron imparts to a target nucleus when

    absorbed. This is an important concept; it

    determines the feasibility of a fission eventoccurring. When the neutron is absorbed by the

    target nucleus, the nucleus becomes excited by

    an amount equal to the neutron binding energy

    and the kinetic energy of the neutron. If thisexcitation energy is of sufficient magnitude to

    overcome the nuclear forces holding the nucleus

    together, the target nucleus splits (fissions). Ifthe excitation energy is not of sufficient

    magnitude, fission does not occur and the atom

    reaches stability by radioactive decay.

    Figure 2-9 Binding Energy of a Neutron

    How much energy does a neutron add whenit is absorbed into a nucleus of a U-235

    atom?

    mass

    defect=

    mass oforiginal

    nucleus andneutron

    mass of

    final

    nuclei

    *236

    92

    1

    0

    235

    92UnU +

    Given:

    mass of U-235 = 235.0439 AMU

    mass of n10 = 1.0087 AMU

    mass of U-236 = 236.0456 AMU

    Substituting into the mass defect equation:

    236.0456-1.0087)(235.0439m +=

    Calculating the mass loss from the system:

    ( ) ( )0456.2360526.236m =

    AMU007.0m=

    Now using the mass to energy equivalence,convert the missing mass into the energy

    added into the nucleus.

    ( )

    =

    AMU

    MeV5.931AMUmE

    E = (0.0070)(931.5)

    E = 6.5205

    Neutron absorption into a U-235 nucleus

    adds 6.5 MeV of energy.

    Example 2-13

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    Calculate the amount of energy added whena neutron is absorbed into a nucleus of a U-

    238 atom.

    *239

    92

    1

    0

    238

    92UnU +

    Given:mass of U-238 = 238.0508 AMU

    mass of n10 = 1.0087 AMU

    mass of U-239 = 239.0543 AMU

    Example 2-14

    ENERGY RELEASED BY FISSION

    With an understanding of the energy required to

    hold the nucleus together, it is easy to see that if

    the nucleus is broken apart energy can bereleased from the nucleus. The amount of

    energy released can be calculated using the same

    formulas used to determine the mass defect andthe mass-to-energy conversion. The concept

    remains the same to determine the difference

    between the mass of the reactants and the mass

    of the products. If there is additional mass fromthe reactants that is not accounted for in the mass

    of the products then energy has been released.

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    How much energy is released from thefollowing fission event?

    ++++ n2PdTenPu 10108

    46

    130

    52

    1

    0

    239

    94

    Given:mass of Pu-239 = 239.0522 AMUmass of n = 1.0087 AMU

    mass of Te-130 = 129.9062 AMU

    mass of Pd-108 = 107.9039 AMU.

    Substituting into the mass defect equation:

    mass

    defect=

    mass oforiginal

    nucleus and

    neutron

    mass of

    final

    products

    Calculating the mass loss from the system:

    ( )[ ]0087.129039.1079062.129-1.0087)(239.0522m

    ++

    +=

    ( ) ( )8275.2390609.240m =

    AMU2334.0m=

    Now using the mass to energy equivalence,convert the missing mass into the energy

    released from the system.

    ( )AMUmAMU

    MeV5.931E

    =

    2334)(931.5)(0.E=

    MeV4.217E=

    There are 217.4 MeV released from thisfission event.

    Example 2-15

    How much energy is released from thefollowing fission event?

    ++++ n3XeSrnU 10139

    54

    94

    38

    1

    0

    235

    92

    Given:

    mass of U-235 = 235.0439 AMUmass of n = 1.0087 AMUmass of Sr-94 = 93.9154 AMU

    mass of Xe-139 = 138.9178 AMU.

    Example 2-16

    NUCLEAR SCIENCE - CHAPTER 2 - 12 of 21 2003 GENERAL PHYSICS CORPORATION

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    SUMMARY

    Mass defect is the difference between the massof the atom and the sum of the masses of its

    constituent parts.

    Binding energy is the amount of energy that

    must be supplied to a nucleus to completely

    separate its nuclear particles. Binding energy isthe energy equivalent of the mass defect.

    Mass defect can be calculated by using the

    equation below.

    m = [Z(m H11 ) + (AZ)mn ] matom

    Binding energy can be calculated by multiplyingthe mass defect by the factor of 931.5 MeV per

    AMU.

    ( ) ( )

    =AMU

    MeV5.931AMUmMeVE

    NUCLEAR SCIENCE - CHAPTER 2 - 13 of 21 2003 GENERAL PHYSICS CORPORATION

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    PRACTICE EXERCISES

    1. Define the term nuclear stability.2. For each of the following statements,

    determine if the statement is applicable to a.nuclear force or b. electrostatic force.

    a. Of the two nuclei, it exists only betweenthe protons. ___

    b. Effective over relatively long distancewithin the nucleus.___

    c. Very strong for short distances. ___d. To a point, adding more neutrons to the

    nucleus makes the force less effective.___

    e. Exists between both particles in thenucleus. ___

    3. Generally, the ratio of __________ to___________ is __________ for___________ nuclei. (Select the correct one

    below)

    a. protons, neutrons, larger, smallerb. neutrons, protons, larger, smallerc. protons, neutrons, smaller, smallerd. neutrons, protons, smaller, larger

    4. For the four types of radiation introduced inthis chapter fill in each column in the table

    below, to make the column true

    Has

    Electrical

    Charge

    Order Of

    Penetrating

    Ability(High-Med-

    Low)

    Has

    Mass?

    Is a

    Photon

    5. Describe the relationship between the termsmass defect and binding energy.

    6. State the condition that determines whetherfission does or does not occur when a

    nucleus absorbs a neutron.

    7. Calculate the mass defect of the H-1 atom.Hydrogen-1 has a mass of 1.00782503 AMU.

    8. Determine the energy equivalence of themass defect of a H-1 atom.

    9. Calculate the binding energy per nucleon forH-1.

    10.Calculate the mass defect of the Plutonium-240 atom. Pu-240 has a mass of 240.053808

    AMU.

    NUCLEAR SCIENCE - CHAPTER 2 - 14 of 21 2003 GENERAL PHYSICS CORPORATION

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    11.Determine the energy equivalence of themass defect of a Pu-240 atom.

    12.Calculate the binding energy per nucleon forPu-240.

    NUCLEAR SCIENCE - CHAPTER 2 - 15 of 21 2003 GENERAL PHYSICS CORPORATION

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    GLOSSARY

    Binding Energy (BE) The energy equivalent of the mass defect (MeV). Represents the amount of

    energy that is released when an atom is formed from its component protonsand neutrons. Also, represents the amount of energy that must be supplied

    to the atom to completely separate it into its individual protons and neutrons.

    Binding Energy (BE)

    Per Nucleon

    Average energy required to remove a nucleon from the nucleus.

    Electrostatic Force The attractive or repulsive force that exist between two objects due to their

    electrical charge.

    Fission The splitting of an atoms nucleus resulting from an energy input (excitationenergy) into the nucleus greater than the nuclear forces holding the nucleus

    together.

    Mass Defect (m) The difference in mass between a nucleus and the sum of the masses of theindividual protons and neutrons in the nucleus (AMU).

    Mass-Energy

    EquivalenceThe conversion factor equating mass to energy (931.5

    AMU

    MeV).

    Nuclear Force The strong attractive force in a nucleus between to adjacent nucleons.

    Nuclear Stability The inherent ability of an atom to resist changing its atomic structure orenergy level.

    Radioactive Decay The process by which an unstable nucleus spontaneously transmutes from

    one form to another to reach a more stable state.

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    EXAMPLE EXERCISE

    ANSWERS

    Nuclear force is strong over ________

    (long/short) distances and is _________(stronger/weaker) than electrostatic forcesat that distance.

    Example 2-1

    Define nuclear stability.

    The inherent ability of an atom to resist

    changing its atomic structure or energy.

    Example 2-2

    Describe the plots shown in Figure 2-3

    Neutron to Proton Ratio

    Z

    N=1

    The dashed line is a reference plot ofN = Z.

    Line of Stability

    A plot of naturally occurring stable

    nuclides.

    Example 2-3

    Of the four radiation types, which one is least

    penetrating and why?

    Alpha - very large mass and very large

    electrical charge causing it to interact

    with material on contact.

    Of the four radiation types, which carry no

    electrical charge?

    Gamma and neutron.

    Example 2-4

    Calculate the mass defect of the U-238atom. Uranium has a mass of

    238.0508 AMU.

    AMU0508.238M=

    MmZ)-A(Zmm nH +=

    0508.238

    )92)(1.0087-238(1.0078)(92m

    +=

    0508.2382702.1477176.92m +=

    AMU937.1m=

    Example 2-6

    Determine the energy equivalence of the massdefect of a U-238 atom. Recall that the mass

    defect for a U-238 atom was 1.937 AMU.

    ( )

    =AMU

    MeV5.931AMUmE

    E = (1.937)(931.5)

    E = 1804.3155 MeV

    Example 2-8

    NUCLEAR SCIENCE - CHAPTER 2 - 17 of 21 2003 GENERAL PHYSICS CORPORATION

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    Calculate the binding energy for Ni-58.

    ( )AMUmAMU

    MeV5.931E

    =

    E = (931.5)(0.5441)

    MeV506.8E=

    Example 2-10

    Calculate the binding energy per nucleon for

    Ni-58.

    MeV7.858

    8.506

    A

    BE==

    Example 2-11

    Given the binding energy for U-238 is

    1804.3, calculate the binding energy pernucleon for U-238.

    Me58.7238

    3.1804

    A

    BE== V

    Example 2-12

    Calculate the amount of energy added whena neutron is absorbed into a nucleus of a U-

    238 atom.

    mass

    defect=

    mass oforiginal

    nucleus andneutron

    mass of

    final

    nuclei

    *239

    92

    1

    0

    238

    92UnU +

    Given:

    mass of U-238 = 238.0508 AMU

    mass of n10 = 1.0087 AMU

    mass of U-239 = 239.0543 AMU

    Substituting into the mass defect equation:

    239.0543-1.0087)(238.0508m +=

    Calculating the mass loss from the system:

    ( ) ( )0543.2390595.239m =

    AMU0052.0m=

    Now using the mass to energy equivalence,convert the missing mass into the energy

    added into the nucleus.

    ( )

    =

    AMU

    MeV5.931AMUmE

    E = (0.0052)(931.5)

    E = 4.8438

    Neutron absorption into a U-238 nucleusadds 4.84 MeV of energy.

    Example 2-14

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    How much energy is released from thefollowing fission event?

    ++++ n3XeSrnU 10139

    54

    94

    38

    1

    0

    235

    92

    Given:

    mass of U-235 = 235.0439 AMUmass of n = 1.0087 AMUmass of Sr-94 = 93.9154 AMU

    mass of Xe-139 = 138.9178 AMU.

    Calculating the mass loss from the system:

    ( )[ ]0087.139178.1389154.93-1.0087)(235.0439m

    ++

    +=

    ( ) ( )8593.2350526.236m = AMU1933.0m=

    Now using the mass to energy equivalence,convert the missing mass into the energy

    released from the system.

    ( )AMUmAMU

    MeV5.931E

    =

    1933)(931.5)(0.E=

    MeV1.180E=

    There are 180.1 MeV released from this

    fission event.

    Example 2-16

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    PRACTICE EXERCISE

    ANSWERS

    1. Define the term nuclear stability.The inherent ability of an atom to resist

    changing its atomic structure or energy.

    2. For each of the following statements,determine if the statement is applicable to A.

    nuclear force or B. electrostatic force.

    a. Of the two nuclei, it exists onlybetween the protons. B

    b. Effective over relatively long distance

    within the nucleus. B

    c. Very strong for short distances. A

    d. To a point, adding more neutrons to the

    nucleus makes the force less effective.

    B

    e. f. Exists between both particles in

    the nucleus. A

    3. Generally, the ratio of __________ to___________ is __________ for

    ___________ nuclei. (Select the correct one

    below)

    a. protons, neutrons, larger, smaller

    4. For the four types of radiation introduced inthis chapter fill in each column in the table

    below, to make the column true.

    Has

    Electrical

    Charge

    Order Of

    Penetrating

    Ability

    (H-L)

    Has

    Mass?

    Is a

    Photon

    Alpha Gamma Alpha Gamma

    Beta Neutron Beta

    Beta Neutron

    Alpha

    5. Describe the relationship between the termsmass defect and binding energy.

    Binding energy is equal to the energy

    released by the mass defect associated

    with the nucleus of any specific atom.

    6. State the condition that determines whetherfission may or may not occur when a

    nucleus absorbs a neutron.

    The target nucleus must receive enoughexcitation energy to overcome the

    nuclear forces holding the nucleus

    together before fission is possible.

    7. Calculate the mass defect of the H-1 atom.Hydrogen-1 has a mass of 1.007825032

    AMU.

    M = 1.007825032 AMU

    m = Z(mp+ me) +(A Z)mn M

    m = 1(1.007276470 + 0.0005485) + (1 1)(1.0086649) 1.00782503

    m = 1.00782497 + 0.0 + 1.007825032

    m = 0.000000062 AMU

    8. Determine the energy equivalence of themass defect of a H-1 atom.

    ( )AMUmAMU

    MeV5.931E

    =

    E = (931.5)(0.000000062)

    E = 5.78 x 105

    MeV

    NUCLEAR SCIENCE - CHAPTER 2 - 20 of 21 2003 GENERAL PHYSICS CORPORATION

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    9. Calculate the binding energy per nucleon forH-1.

    MeV1078.51

    1078.5

    A

    BE 55

    =

    =

    10.Calculate the mass defect of the Plutonium-240 atom. Pu-240 has a mass of 240.053808AMU.

    M = 240.053808 AMU

    m = Z(mH) +(A Z)mn M

    m = 94(1.00782503) + (240 94)(1.0086649) 240.053808

    m = 94.73555 + 1.47.26508 + 240.053808

    m = 1.9468 AMU

    11.Determine the energy equivalence of themass defect of a Pu-240 atom.

    ( )AMUmAMU

    MeV5.931E

    =

    E = (931.5)(1.9468)

    E = 1813.4679 MeV

    12.Calculate the binding energy per nucleon forPu-240.

    MeV56.7240

    4679.1813

    A

    BE==

    NUCLEAR SCIENCE - CHAPTER 2 - 21 of 21 2003 GENERAL PHYSICS CORPORATION

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    ACADBASIC CURRICULUM

    NUCLEAR

    SCIENCE

    CHAPTER 3

    RADIOACTIVE DECAY AND INTERACTIONS

    n

    n

    X

    -ray

    X* X

    STUDENT TEXT

    REV 2

    TM

    2003 General Physics Corporation, Elkridge, Maryland

    All rights reserved. No part of this book may be reproduced in any form or by

    any means, without permission in writing f rom General Physics Corporation.

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    TABLE OF CONTENTS

    FIGURES AND TABLES ......................................................................................................... iii

    OBJECTIVES ............................................................................................................................. iv

    RADIOACTIVE DECAY PROCESSES ..................................................................................... 1

    Unstable Nuclides ..................................................................................................................... 1

    Alpha Decay.............................................................................................................................. 2

    Beta Decay ................................................................................................................................ 4

    Electron Capture ....................................................................................................................... 6

    Photon (Gamma Ray or X-Ray) Decay .................................................................................... 7

    Decay By Neutron Emission ..................................................................................................... 7

    ELECTRON RADIATION INTERACTIONS ............................................................................ 9

    Energy Levels And Location .................................................................................................... 9

    Excitation and Radiation ........................................................................................................... 9

    RADIATION INTERACTIONS ................................................................................................ 11

    Alpha Particle.......................................................................................................................... 11

    Beta Particle ............................................................................................................................ 11

    Gamma Ray ............................................................................................................................ 12

    Photoelectric effect ................................................................................................................. 12

    Compton Scattering ................................................................................................................ 12

    Pair Production ....................................................................................................................... 13

    NUCLEUS RADIATION INTERACTIONS ............................................................................ 15

    Excitation And Radiation ........................................................................................................ 15

    NEUTRON INTERACTIONS ................................................................................................... 15

    Types Of Reactions ................................................................................................................. 15

    Scattering Reactions................................................................................................................ 15

    Absorption Reactions .............................................................................................................. 16

    Radiative Capture ................................................................................................................... 16

    Fission ..................................................................................................................................... 17

    HALF-LIFE DETERMINATION.............................................................................................. 18

    Decay Rates ............................................................................................................................ 18

    HALF-LIFE ................................................................................................................................ 19

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    TABLE OF CONTENTS

    SUMMARY ............................................................................................................................... 22

    PRACTICE EXERCISES .......................................................................................................... 24

    GLOSSARY ............................................................................................................................... 25

    EXAMPLE EXERCISE ANSWERS ......................................................................................... 27

    PRACTICE EXERCISE ANSWERS ........................................................................................ 32

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    FIGURES AND TABLESFigure 3-1 Alpha Decay of U-235 ............................................................................................. 2

    Figure 3-2 Alpha Decay Using Chart of Nuclides ..................................................................... 3

    Figure 3-3 Beta Minus Decay on a Chart of Nuclides ............................................................... 4Figure 3-4 Beta Plus Decay on a Chart of Nuclides .................................................................. 5

    Figure 3-5 Electron Capture Decay using Chart of Nuclides .................................................... 6

    Figure 3-6 Orbital Electron Capture by the Nucleus ................................................................. 6

    Figure 3-7 Neutron Emission from First Excited Daughter of Decay Chain ............................ 8

    Figure 3-8 Neutron Decay using Chart of Nuclides .................................................................. 8

    Figure 3-9 Simplified Nucleus and Electron Shells ................................................................... 9

    Figure 3-10 Alpha Particle Specific Ionization versus Distance Traveled in Air ...................... 11

    Figure 3-11 Photoelectric Effect .............................................................................................. 12

    Figure 3-12 Compton Scattering .............................................................................................. 13

    Figure 3-13 Pair Production ..................................................................................................... 13Figure 3-14 Attenuation of Electromagnetic Radiation (in Lead) ........................................... 14

    Figure 3-15Elastic Scattering ................................................................................................. 15Figure 3-16Inelastic Scattering ............................................................................................... 16

    Figure 3-17 Radiative Capture ................................................................................................. 17

    Figure 3-18Fission of U-235 ................................................................................................... 17

    Figure 3-19 Half-Life ............................................................................................................... 19

    No Tables

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    OBJECTIVES

    Upon completion of this chapter, the student will be able to perform the following

    objectives at a minimum proficiency level of 80%, unless otherwise stated, on an oral

    or written exam.

    1. Given an atom with multiple electron shells:a. COMPARE allowed number of electrons in the outer shell to the allowed number of

    the inner shell.

    b. COMPARE the energy carried by an electron in an outer shell to the energy carriedby and electron in an inner shell.

    c. DESCRIBE the response of electrons in the outer shells to the ejection of an electronin an inner shell.

    2. DEFINE the following terms:a. Ground state energyb. Excited state energyc. Iond. Ionizatione. Gamma rayf. X-rayg. Radioactive decayh. Decay chaini. Spontaneous fissionj. Half-life

    3. EXPLAIN how each of the following forms of radiation interact with the surroundingenvironment and lose energy.a. Alpha

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    OBJECTIVESb. Betac.

    Gamma (Photoelectric effect, Compton Scattering, and Pair Production)

    4. EXPLAIN how each of the following radioactive decay processes occur:a. Alphab. Betac. Electron Captured. Photon Decaye. Neutron Emission

    5. EXPLAIN the radioactive decay processes, including the following:a. Difference in atomic and mass numbers between the parent and daughter nuclidesb. Disposition of energy associated with the process

    6. COMPARE elastic and inelastic scattering processes.7. COMPARE radiative capture and fission processes.8. Given a sample of a radioactive element, EXPLAIN the relationship between the number ofatoms contained in the sample and the activity of the sample.9. EXPLAIN the half-life method of determining radioactive decay.

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    RADIOACTIVE DECAYPROCESSES

    UNSTABLE NUCLIDES

    Radioactive decay (or radioactivity) is theprocess by which an unstable nucleus

    spontaneously transmutes (changes) from one

    form (nuclide) to another to reach a more stablestate. It is termed radioactive decay because one

    or more forms of radiation, as discussed inChapter 2, accompany it. Two terms that will be

    used extensively in the discussion of radioactive

    decay are:

    Parent Nuclide, the original nucleuswhich decays.

    Daughter Nuclide, the new nucleuspresent after the decay event.

    Unstable isotopes will emit particles, energy, or

    both particles and energy in an attempt to reach a

    stable condition. However, not all isotopes

    contain the same amount of excitation energy. Infact, some isotopes have too few neutrons and

    others have too many nucleons. An unstablenuclide will attempt to reach a stable conditionby any one, or combination of several decay

    mechanisms. In general, unstable nuclides decay

    by six (6) basic decay mechanisms:

    Alpha decay Beta decay [beta minus or beta plus (also

    known as positron)]

    Electron Capture (k-capture) Neutron emission Photon (gamma or x-ray) Decay

    Internal ConversionEquation 3-1 shows a formula symbolizingradioactive decay.

    ERYX AZA

    Z ++

    Where:

    XAZ = parent nuclide

    YAZ = daughter nuclide

    R = radiation type

    E = energy

    Equation 3-1

    The energy term here includes the kinetic energycarried by the daughter nucleus, and the primary

    and any secondary radiation particles. It is thebinding energy represented by the mass

    difference (m) between the parent nuclide, andthe sum of the masses of the daughter nuclide

    and the radiation particles.

    A substantial number of radioactive (unstable)

    nuclides (also called radionuclides) exist innature. These naturally occurring elements have

    atomic numbers above 83, and are commonlyreferred to as heavy nuclides. Each goes through

    a radioactive decay process at a definite rate,depending upon the nature of the nuclide, to

    reach stability.

    The daughter nuclide resulting from radioactive

    decay is itself often unstable, resulting inadditional radioactive decay. Given that most of

    the nuclides contained within a nuclear plant fuel

    bundle are heavy nuclides, a significant number

    of radioactive decay events are occurring fromthis source.

    Each fission event within the nuclear reactor

    results in two radioactive nuclides, in addition toone or more neutrons and other types of

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    radiation. These nuclides are commonly referred

    to as fission fragments. Each fission fragmentstarts a radioactive decay chain resulting in

    several stages of radioactive nuclides before

    reaching a stable element. This may bedemonstrated as follows:

    ( ) ( )

    ( ) .)etc(ERSW

    ERWYERYX

    3A

    Z

    A

    Z

    2A

    Z

    A

    Z

    1A

    Z

    A

    Z

    ++

    ++++

    Equation 3-2 Fission Fragment Decay Chain

    The decay chains of the fission products are

    significant because after the reactor is shutdown,the decay of the fission fragments continues. A

    very high percentage of the kinetic energy from

    the decay process is absorbed in the system andresults in production of heat energy. Nuclear

    plant design must consider methods of core

    cooling after reactor shutdown. More detail on

    this process will be covered in later chapters.

    The radioactive decay of a parent nuclide

    always results in a stable daughter nuclide(true/false).

    Example 3-1

    ALPHA DECAY

    Alpha decay involves heavy nuclei, generallythose having mass numbers greater than 210.

    These nuclides decay through the emission of an

    alpha particle. Equation 3-3 symbolizes alphadecay of a nuclide.

    EYX4

    2

    4A

    2Z

    A

    Z ++

    Where:

    XA

    Z = parent nuclide

    Y4A 2Z = daughter nuclide

    42 = alpha particle

    E = Energy

    Equation 3-3 Alpha Decay

    The daughter nucleus of alpha decay has two

    neutrons and two protons less than the parent

    nucleus.Figure 3-1 is an example of alpha decayfor uranium-235.

    42

    X4A

    2Z

    -ray

    n++nALPHA ()

    XA

    Z

    4

    2

    KINETIC

    ENERGY

    + + KE +

    +++ KEThU 42231

    90

    235

    92

    Figure 3-1 Alpha Decay of U-235

    The U-235 nucleus emits an alpha particle

    resulting in a daughter nucleus of thorium-231.The energy released in this decay scheme is thecombined kinetic energy (KE) of the alpha

    particle and the daughter nucleus, and the energy

    possessed by the gamma radiation. Most of the

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    energy (well over 95%) associated with alpha

    decay is possessed by the alpha particle.

    Explain the radioactive decay process as

    represented by the following:

    EYX4

    2

    A

    Z

    A

    Z ++

    Example 3-2

    Compare the