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Slide: of 10 1 A Pore Scale Microlab to Perform Fundamental Laboratory-based Studies of CO 2 Transport and Reactivity in Reservoirs Mechanical and Industrial Engineering; University of Toronto, ON, Canada sintonlab.mie.utoronto.ca/ Email: h.fadaei@utoronto.ca Hossein Fadaei

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Page 1: A Pore Scale Microlab to Perform Fundamental Laboratory ...Slide: 4 of 10 Summary of the projects, microfluidic approach CO 2 sequestration 1. CO 2 diffusivity in brine 2. Reservoir

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A Pore Scale Microlab to Perform Fundamental Laboratory-based Studies of CO2 Transport and

Reactivity in Reservoirs

Mechanical  and  Industrial  Engineering;  University  of  Toronto,  ON,  Canada  sintonlab.mie.utoronto.ca/  Email:  [email protected]  

Hossein  Fadaei  

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CMC-Project B04 Collabora'ng  universi'es:  

David  Sinton  (PI)  –  Microfluidics  

Aimy  Bazylak  –  Modelling    

Savvas  Hatzikiriakos  –  Rheology  

Steve  Larter  –  Petroleum  Geology  

John  Shaw  –  Petroleum  Thermodynamics  

Zhenghe  Xu  –  Oil  Sands  Engineering  

3

4

5

Postdoc

PhD

PhD

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Motivation •  Long  experiments  •  Costly  •  Large  sample  requirement    

•  Fast  experiments  •  Cheap  •  Safe,  small  sample  

Many  tesDng  required   PVT  

Viscosity  

Petrophysics  

Miscibility  

Fluid  flow  

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Summary of the projects, microfluidic approach CO2 sequestration

1.  CO2 diffusivity in brine 2.  Reservoir brine dry-out during CO2 injection 3.  CO2 pipeline dew point detection 4.  Fiber optic based CO2 and reservoir fluid detection

Oil recovery 1.  Solvent-bitumen diffusion measurement (collaboration with

Prof. J. Shaw) 2.  Microfluidics for SAGD analysis 3.  Microfluidics for downhole fluid detection 4.  Bitumen swelling with CO2 and diffusion 5.  CO2 foam for oil recovery

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  Supercritical CO2 transport •  Impurities change fluid mixture

http://cdn.globalccsinstitute.com/sites/default/files/publications/16876/effects-impurities-geological-storage-co2.pdf

http://corrosion.curtin.edu.au/research/mining.cfm 18

Impure CO2 dew-point measurement

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Microfluidic approach

[Song et al. (2014) Environmental Science & Technology] 10

P>Pdew

P≤Pdew

~ 100 µm

Small content (~ 500 ppm) water detection Not possible with current PVT methods Cheaper, safer and easier to operate Faster than conventional methods

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Dew visualization, pure CO2

Supercritical CO₂ and impurities

10µm

10

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Coal  power  plant  

CO2  

Oil  

Oil  e-­‐  

CO2 nanoparticle-stabilized foam for enhanced oil recovery

CHALLENGE:  Viscous  fingering  of  CO2,  poor  storage,  poor  oil  recovery  

APPROACH:  Mobility  control  with  nanopar'cle-­‐stabilized  CO2  foam  

Grain  Oil  CO2   Foam  

Foam prevents early CO2 breakthrough

& increases the oil recovery

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Foam stability results Current foam stability analysis method

SDS foam

0 h 24 h

NP foam

0 h 10 days

0 h

20 h

0 h

10 h

Microfluidics based analysis

%10

Microscale screening of CO2 foam

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Summary

Conventional measurement methods in the oil and gas industry can be replaced by faster, cheaper and safer micro-scale techniques.

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Thank you

&

Thank you CMC

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Validation / Application

3x precision improvement in measured dew point pressures

[Song et al. (2014) Environmental Science & Technology] 18