33.6 6i12 1o0s rs+.+ isl - paceinstitute.lk · nle) +-r rr(8) -r 2 t'if3@ gr6sooo oqoc aho =...
TRANSCRIPT
80701
= 8.314J trCl mol-l= 6.O22x lf mol-l
= 6.626x lOs J s
=3xlOtms-l
R,VA
hc
{+ qc0U8roc Oq0ad c,erccc qtED.lN+ oOO gdar ogo ge 0E4lr, grdo eO.{+ 6€09 3 gdar06O 8ergft rooonftn.116 0.r!6 odg oOoog tilO.Gg.aGI.a.{e 6.rdrod opocl SoOro d0capsJ Ooa O@o qoao €orrJar.{e 6rtrad ogocl Egt:. Q qr8 gourz$ Cc:oQlj ore8€Od O goOrrJro.* I Ao 50 0l5d ozs oz$ gdarco (r),(2),(,),(4),!5) orn 8p4QOel'J 60Gd€cdg@gd0reoooroil
C*G; c6E a6Ood-m .@c cdoda
odocqioro ogoo Epaq o oracoanJod'dgo 96.'qcroeBo ordq ao odg rog Eqaoqoc ogocf,(1) guardo dq6o6' e) odcaa o€rorrL (3) aeJ oanu.(4) q$gzrJ ooCeDtJoBaJ. (5) oozrj6 ,oU6. \-/
c,lolD q€ aoosjooorrJ oal4our ooulgo gooo oaloal q?CO2, BF3, PF1, CF4, XeFo, SF.
(l) 8og O q€OeO el6o ootcogd OulOar q1rs.(2) 8og O q€OeO soard olOorrl q1o.(3) 8og O q€ qdOrs BEcs qgoOuro oancrsdg.(4) 8og o qq! 86&Eo oO.(5) q€ cq,o', oor6d docoog oo:r odocd rctgo oaod g0grdegJrn go6f oo6.ooro qz$ooa aoocldoocJ ILTPAC rocOo zgOzf q?
2.
(l)(3)(s)
(2) 4-formyl-3-hydroxyhex- l-yne(4) 3-hydroxy4ethyl-t-ynepentahal
(3) NO2F (4) NH3 (s) NHzOH
Ooerdog&o go6f drc68o oquro rod og0ul durrso O
sU6o, T-o1Oo,8-ooC.to$o Soofefcrocd, oroC&a, T-o10o.
5.
(2)(4)
cHoH-C=C-gn-cn-cHrcrl
6n
4-formylhex- I -yn-3-ol2-ethyl-3-hydroxy4ynepentanal2-ethyl-3-hydroxypent-4-ynat
4. i'r8odd:'r8 o.JSrDdG gOcJOcO -l Or,Jerur,(l) Nro4 (2) NzO
OOr od@oqiO OOc $ocar6 (EBdOOcacdq€Oe olOouf 68ood q1o- d0c uro,(l) oUEo, otoC&ro, 8-eoC.(3) oU8o, $ocar8 SdOO*oc4 T-ro1Oo.(5) oBEo, a@o SoaCacrocd, B-oaC.
qlooJEoo ro8oeBo a?e cd{6doocl Q, :o8oddul ocgo, old8da, oqgo oc dg ocdo acq6ut dooC6roogo EooJdroo oo- oo@to 6,dadoocl Q oc Eornecft qlooJSoo iaaeua-2qog Etoocdrno EqorrjEoroqa $O Ocg @Od tcoolcO O€od.(H= 1,N= 14,o= 16, 3oora 6dadoecl Q oc Bourocl Q ocg oBg oars o6ocD eo6 22.4@0.)(1) 33.6 (2) 6i12 (3) 1o0s - (o rs+.+ isl 23s2
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AX ao Blt og 69oo8 qgio ooaocs, gron co.c6 c{ro6. acod 6dadoocd Q dococcg gcDracSgoog,"j *rr, ot tr"pr 6o' AX I gcoraoo p oa qod Bx2g oo qoo q oo. oid oad goao og o
(4) a.6 onr ;;(5) orrr oar a614. ococqnrra:J.?*f
tpff.*r*:^:.*._f:? toqord.poo ocaro rodra eQ. oego,oclDcs qooe ogoco vorn qa.s ocda:oa aJronjoo -,,e-eb- ;il;ff;Jii"#l"lt;If"*1,:.3:;$J,X"-:H:::;,f i?: 3.: ?d +. EcsE oi.o oo onrcqrrrac ocso our oqaocdrmdoqc, (r) oc 8o_rnec,
{pl ozoeai 6oE ocrosoo'oarunu ;;:;"ffi;ffi; "Ht#
ourcqalanc ocgoo8 ogelo drorrJoo bo, .qa qz
(3) (n-rylnrPV
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zdocd ooc zdcc60 .co(t .,ecoo aooaroooa, 'rrJ
zgoa oorrgo go@ oo q?(1) 8og o adocBo T:S "€j, N, ?rgo tooo soe 6dar:fiDod Q g8Soc rod8.
[3] *1?::::::*::.=:--!s::*:--]{;;-d9o6 eoccrooso ooc o1E} o. 1
(3)H,:.&?":.,qo-i.'oJ.6"-,ilil;;-;;E;;;ffi X"%L*jfffi ffit?EIL..oul1l zdocEo cr*q oet to-cq1u gcog o oEloeazdtcBo 906 odo oO-(5) adocd oeito oaopczdcc-aao6-gouoco -racrdoocl-.,Jea-o.a .o.EEoOB (Li) aog6roc aogdog&ooO qlorors to0g urtffiho qco6Co6o,(Li,Z=3 oc ocodzdo odOoqiro dloulOo=f)(l) +3 o toocur o.
{?l .1o ooc qA cr. (3) +3 o ooc 016 o.(4) +7o oOcar o. (5) +Zo o0o qfl o.Q ft8 6d+rrfDoro Q oo0ao qod ocdaoad tge otoo oO4@roacoo oog.
2sO3G) =r 2so2(g) + o2(goo 6dr6doocl Q ocdurc! Eggo qoad.oJg.gag"rr* oro4 rodur eQ. aoeEormooo roloro o€E€Bd ooa6.racoscs8 B0 qooo ooajoaJq;,,,d6,o?_op lg ir".iHr"#; # asoa q?(t) gr8$oco0 oOtgearac gaao (2) o{og"d 6O-goisa(3) cl{o8od *I lortttsocacl (4) o{a8oa qr8 SO3(g 9oa6cr(5) o{oAod ftB O2(g gecsG!
11. asoddrrJ Eodoonj8 o-N-osacoo ooozdooord ooo aqord zg@ 6D oo q?(l) No;' No;' No, , *ol- @\ Noi-, No;, Noz > No;(3) No; r No, r No*, No]- (4) *"_t, *o; , r.r";, .r;(s) No; , No;, uo]- > No,
lll' Gcogod qeor qcog&oocJ 6d roecoocs8 (470 nm) rododoo 6.0J odgozf goqog. oercoocro loxd_?-: BBo toqoc ecogo oacoo.a roc6ozd Rd6o sFD Q? Ess*. -J€'tc
(l) 2.4s @l l.ts (g)'8ss €- r'
(4) 92s (5) loss13' g8socod 298 K oc 10o kPa Eornocl Q-fo1!{o ors qod oo sos 6dadood'q ,; goaocr idocoo8{o erocso' ooo gr66oco .qt -298
K s i oo l00'lckSoaJod E ooa ccgord rgod 56.o qr l
AG AH AS(l) orn o; o,ol?l e5 @d ;;tJ, q6 a6 Oro
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(l) dRTP
(4) (ry-q)nPV
(s) l.\-(^r__anlln
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:B:%1 j*?fj;J?":':T:_T_q?y":iFo,i-.,1s-?9"ueorc,occ,oo.605qos Eaoa soao K. rg. ciocdrdoa scoaecc8 nn_qro-pr-i;;pil;[.""t8]kT',j;3 3'J:aqoul rqo:o grocorao O6lrJ Cr,Cz,%.r Vroqoc SOlOlabardo.ro-6ao4 qf
(r) fi.OffiO.rc(4) *.\fih.rc
S*qqfu"oc-u
1< dtJ- < tO
(3) #'ffi.,0(2\
(s)
16. q.aeuj I aogrgdo ogoozs cs.d ooro gziloour 6rgrrJ ago,f q?
,,,d" ,rd' (3)-,S (4) dt (s)
17.
ffia;ffi fiffiH#:toro 86roco Ro oc ooo sooo ft oo. qc@oro acrrgoo s0% sur qe B(r)k e)i (3)* (o+ (s)+Ifrtr:o "l.lNiG)
oo cuh(aq, l-.0 M)/co(r) quo .lodl', oof6fooodod o6rJ loc co.6 o€r,eo8uJ86oorJ Eqeof do..o8a olbdoccd *16-.- ca. :0g66 "nno ""-5tlo-;r.'[;U;oaco oqrorog Eo ooCdEOOdo€!8 qcdooa oorlcoroo oEo"l,
({r,*^, = -o24v to {oz*/co = + o.s+v)
(l) Ni2*(aq) + Cu(s) --+ Ni(s) + Cu*(aq) ; 0.00 V(2) cu].ta$ + Ni(s) -+ Cu(s) + Nihfaql ; +0.58 V(3) C"].t"et + Ni(s) -.+ Cu(s) + ni2.faql ; -0.58 V(4) cu2*(aq) + Ni(s) --+ Cu(s) * **<rql ; 0.00 V(5) cu(s) + Ni(s) -* cua(aq) + xih(a4l + 4e ; +0.58 v19. acOd 6dadoocl Q toar Ogqo8al ooajoOrdrcl0 Cpr rocalr, oOcsroudrcg0 ccOo g8€oc ad
:ff:iXr':f:j.1i,_tl--T:i:o.e,l-,a'*'.o,.aru*caosocr6..olsooqoceooto€ tottD' 5odm3 oq6 -lcooeort
rro.ea"e l€ozr 4pnr ooc, torffiT'*ir;J:g'ja::L$irr";ff
flT:]fff :?:3"Tfff"*mm"'f ::::.^il;,$;il#;+,esco6ordoooq€ocoaro aoro eQ. qoor Q Narsro, o@co ro00cm3;. "r€
rccoogocJ rocouJ J3]H;f#;;:(ppm o€uI) ogocl, (C = 12, O = iO, o.5 ocoogocl toa*SDo = f.q, * ,o=-a , ;*;(l) too (2) 2So G) soo (4) ?oo (s) looom. acou oo oB aoooco toooaJoso,,l ooa aqozl zgoar oourBca q!E* oulorl q?(l) S og ozd8rod.rn qot$oc _2 go +6 odoaord q.b eoe&ooa.(z) ozd oeozd ogtc Sor66c oqouJ.r*s dio];; s-;s6os rod8.(3) edfk,cdrD.rd too oidgocorsard ora oqqcacdooo soro soc a€ o,ro.(4) Eoc6 grOcaorrlcoui S qorao aOO qO6'",gu"Jqr# .O.(5) acrrlg Hrsono goe qosord, or*a-rdrno; .,J.si;o--..rd osto Soc ros u1ro.
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2l' ?T " l^E
nle) +-r rr(8) -r
2 t'IF3@ gr6sooo oqoc aHo = -xi3kJ mor-r oo. N=N oo N-F orrJora Etoorn
i,f*F?rE5fl=:e'r e46ki mor-roc Tt2kt ",ot-t'u.
.-.uri-* ;;- Eoorn orro16f8 qoo(l) -423 (2) -3e3 (3) -l4l (4) t4t (s) 42s
t6n0o6€gO Oodo.
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?. Eqed DDodqa oraColf tD€ 89 oa aFf(ao) + 3e+611s) + 6 F-(aq) q6o 96soco rooouJoocsuJ ooraaqoul zgor$ ooo eO q? \-/ Yv3 vu'('ure(l) Al Od8ad.6ca oO.@ AlFl ozd8odrro eO.(3) ru A" Oz*groOa qoddco -3 gO0 qzilOc oo:orJ oO.(4) F-OrJSocdroor$ oga Soc adg.(5) F-od8odrro oO.
cH3cHo oH-,p f ,q (l)cl.{sMgBr,*(2) Ir
goro qdooar g6fioo qEeooog B e oo R g opo ggoOer ogoa,
OH nrrt--- q1(l) CIr3cH2CI{CHo , cH3cH:cHcHo , cH3cH:cu_C, _ottt11
OH(2) cq&ncupno
(1)
OH
(3) cn Jncupno , cH2:cncH2clro , cHr=411-"rr-EH,
OH(4) orEl"rr"ro , crr3crFcucrro , cH3cH-cH-ffL,
OHI(5) Cr{3cr{2orcHo ' CIfcrrdlrcHo ,
GJDccDcEro da6 8l gradcOtfiaar droroo Ddotil,
j#4L#:(T
Qggoloro ro6ao oooar eooo6} qzdoc q1ra. ooo e€goloog ro6co roo!D,,,4Oar OorIEo ar6m oO q?
lll l,,lrtrGrogco tcoe€oocoocJ ooErn T,paddo orod q1a.
:?I l,'lrtr_L-eco aoe€orocoss3 oo8ur T,proddo 6rozd q1ro.
9l lr,l oc Grogco tcO4@orocOoal oOgar T,paddo oazd qia.\1I Sr,L oc G rogco tcO4€raacOecJ oo8ar T,proddo orozd qlo.(5)
',cc., o,i*roO D16 oaazf tc0q@rooc0ocJ oogur T, p add0 4arzdrogoo rcOoora8 gdoo.
gtCHrCH:CH-tuOft
f'-\-, I (3) tcH, crtf -t
crl. H -l
)-( IcH, *f(2)
H HI\/l
f\"1-aOOrrJOsorrJ oors aqoal
P
sr
9H', CH.CH:CHCHO , CH-ell:gtt--,t-Off
C_,,
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n lmOK Q 2No(e)+Brr(8)+ 2NoB($g6$oco oqoc oorB8arsc foroo l25xl0-2mol-rdm3 oo.oOO 6,dadOod Q ooro aqoaf zgour grocoo/gnoco 6ed! oO q?(a) 604€l' ogmoo8 No(g) oc BrJg) gg@o q16 qad qcog g86oco aqoo taoeer$tDc g3orao
S0moldm{oO. ' --(b) aoqetD ogooo8 NoB(g)gr$ao gt6 qrsd gog gs6oco aqoc aoq@oar gorao g0moldm{oo.(c) tcoq@o ograoo8 No(g) oc nrle) sgao qr6 qod qoog g86.rco toqoc aoq6aao 63orao
l2'xl0-2 mol-l dm3 oo.
@ oo4@o fuooro8 NoB(g)egao q(6 q'od qccrE e,E6b',o oqoc ao4@raac Soroo125 x l0-2 mol-l dm3oo.
Xifffjl":"q--9-P-e*6j*.d:ooulooorrlooatoqout4oaoozdao/oozilBaedgoo(a) g66clcoo8 ouzsoroudo:oo 86eeo adrn 6q oere o+s oa3oal ggsoaoula .;;; ffi;(D) gaSoroog cccalg6 qoerctD I :3 oa 6o gr86ocoo8 oozforrcdorso BUrao rodan gq oog 4a oo.(c) od g8Sorooro oculgero qSroo ooc oalaulqaudoroo Eo6 oooorrJ qg oar Eo g6@oceog
EOnocO OO g8$oaoo8 acalgaoog, GJOrs!&! oO.(d) Soro 6dadDoro Q g66oa qo.q ogorag o6oco qg ae Eo gBsora qoo olQo qg Eoo016 oO.
oors aqoul rgoar oozd6o/EloalEl so6d oaurgrl, (eocg8rel) aqoc 6edQ oo q?,
CFo,"oEb.r(a) 8og O ac0al o@oqg OaO rl6ozo gSOg.
(D) 8og O zocOnl acArl, OaJOalo6 Qo O6oauoO rcOo:a sO.(c) €og O rDcad coElAddsl Oul0ra0g Qo O6ouuoO toOcar oO.(d) on*Q C-C-C oaioar 9!or66EJ l2b".rd 60.ocg ga6o' .ooosioooaj ooa Q q6 zgoar oo:rJr8o / o.Drrjr6r aedG oo Q?(a) dg G&DerrOOe qrE o6lotiO OcgooC@o HrSg goOo6(b) NO(e)oEaJ SOr($,SOr(B)ooo o8oBromo Eo 66 adg.G] ooc8g galOro
!r_?.J Q BAoro NO(g) oqg gczootil o6a oaroccl6ozd.@ oqeooceocJ ft8 SO2(g Ce€ oloAo o8rrJ god eo.
qoro 41 8o 50 oraas od 6zd gdrno 6q!oc groco.g5:o arszrr 9Q6oril ad q1a. oo groco gogoo ccdolsoogocl ooro oqoo8 gdooa o6Q (l), (2), (31, r+l io (sj trrr ggocdo@uJ rood g6ocdo g,g oa36rdad opoo8 6,5ra ogo eEeqi todrrJrrr.
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6rarg OtD qad, oaron Oan ar$d ogpe8 grocoo gOrdq O oop .s.q6.
OBracOoaJO goraooS C-O OaJOar toUDag oO. O8roc0szilO qcturo tJOcB co0ggadro Ogotgurro tcoggrdro $gOad oO:
HOCH2CH2BT Eop 6rld OcODoc, Q Mg oOog6$oi a6oorrt Surc6 grBracorooi gEsoe roe<}2Dclol'R cC.
oSoQudA@ rocdOod qOoe G,oo(cCo ecOo$arc0 grArocdroo g8$coc oancrodg.
tJ0czoo qzD6O rorQdr oO.
6oa 6,dadood E 2H2(g + CO(g) i* CH.OH(g)rco4@ro Ogaoo8 Eoiro 016 B6oosJ tc'046.
8oo 6,drnd0od Q docoEro oOq@roac0oogqB OcgOo Og6oro EOrao or8 66o{9 Q Oge
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qoSro loooccCcocoro gcor:roc0 Og odgar oadgoOo oodzd dqc o0B.
gegrdoeCo8g oroodg qlgtedurOggSgoczor6rtoo ql6fgaro6o ooc {g o.
tocOal loc o8DddrrJ erdOo€i qrld EqAdarfoc0occS qOanto 4Oc gcoc ogcgcrocOalog
EooOoED ocdrrrord e€' fig d6 Ocdo aEoorno Da60 qDO o6odeo8 Ordegcgo eE oO.
tcooaro o{O8oz$ OEul qoooCo.c6o ED€ lDccrccqOO o6odEoS raccrOo g6rrrGo 016 adg.NaOH SdocqrrrocJ Q toc8ra o- croe-.filE
roloraJO agOdo GDc qlorn:rtD zgOdo qoa Od&rooOeoBuJ oOuJ ad q1o.
o06 oofuocl oc8ro Oan qoro Od&cs eO6orotOcorl gD@cd1 OOO 9O ourcoqg.
2.butene oc6$Ocro oOcOoBroocO oorrJ0g. o6oaoa8 qUorr g6EOa r-ro- ogrfrJ2-butene oqrro BEo lorra.
rocOd Cd.adOo€J E MnSG) g dgod gcoaocO pHqoo Ora dqc orocooE
SL(aq) g6ue e0e.- loogdoa odOo oO.
d-eosgo0 e6gO:lD6 gocoro s_oocgo0 pggOlOggOcoroOeO OOc D16 o.
d-oocgo0 gggoaOg ogCoa OaJOur ..g* qot3dccnoo EO toqoc, dao s ooe,rdoa&yr-lr-
IH 2
IIc3
Li4
Be5
B6
c7
NIo
IF
l0Nell
NaL2
Mc13
All4si
l5P
l6s
t7CI
l8Arl9
K20
Ca2lSc
22
fi23
vuCr
25
It[n26
Fe
27
Co28
Ni29
Cu30
7^3lGa
32
Ge33
AE
vSe
35
Br36
KI37
Rb38
Sr39
Y4Zs
42Mo
4tTIb
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Tc4Ru
45
Rh4Pd
4;t
Atlacd
49Itr
50
Sn5lsb
52
rb53
I54
Xe55
Cs56
BaLa.Lu
72
IIf73
Ih74w
75
Re76
O,s
TT
Ir78
Pt79
AulllUnu
80
_e_tt2Uub
8tTI
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Pb83
BiuPo
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Att6Rtr87
FI88
RaAc-Lr
104
Rfl05Db
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Se
tu7Bh
I(tsEE
I(BMt
110
Uunl13Uut
57Lt
58
Ce59
Pr60
Nd61
Pm62
Sm
63
EuuGd
65
Tb6Dy
67
IIo6E
Er69
Tm70
tr7lLu89
Ac90
Th9lPe
92
U93
Np*tPr
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Am96
CmnBK
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CT
99
Es100
tul0lMd
tv2No
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Lr
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