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Delrin ® Acetal resins Design with Delrin ® Start with DuPont Engineering Polymers ® DuPont’s registered trademark Do You Speak Delrin ® ? Introduction Outstanding Attributes List of Grades Low Wear, Low Friction Series Key Properties Table Stiffness & Strength Creep Resistance Stress Relaxation Fatigue Resistance Impact Resistance UV Resistance Temperature Chemical Resistance Typical Applications Radii Uniform Wall Thickness Ribs Bosses Threads Snap Fits Rapid Prototyping Stockists/Machinists Colours Processing Regrind & Recycling Laser Marking Medical Applications Further Reading Design Basics Performance ▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲▲ 7 9 11 13 17 19 21 23 25 27 29 31 33 37 39 41 43 45 47 49 51 53 55 57 59 61 63 65 5

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  • Delrin®Acetal resins

    Design with Delrin®

    Start

    with DuPont

    Engineering Polymers

    ® D

    uPon

    t’s r

    egis

    tere

    d tr

    adem

    ark

    ▲ ▲ ▲

    Do You Speak Delrin®?▲▲

    Introduction

    Outstanding Attributes

    List of Grades

    Low Wear, Low Friction Series

    Key Properties Table

    Stiffness & Strength

    Creep Resistance

    Stress Relaxation

    Fatigue Resistance

    Impact Resistance

    UV Resistance

    Temperature

    Chemical Resistance

    Typical Applications

    Radii

    Uniform Wall Thickness

    Ribs

    Bosses

    Threads

    Snap Fits

    Rapid Prototyping

    Stockists/Machinists

    Colours

    Processing

    Regrind & Recycling

    Laser Marking

    Medical Applications

    Further Reading

    Design Basics

    Performance

    ▲▲▲▲

    ▲▲▲▲

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  • ‘Design with Delrin®’Data at your fingertips

    Delrin®

    Acetal resins

    Design

    with

    Delrin®

    Start

    with DuPont

    Engineering P

    olymers

    ® D

    uPon

    t’s r

    egis

    tere

    d tr

    adem

    ark

    ▲ ▲ ▲

    Do You Speak

    Delrin®?

    ▲▲

    Introduction

    Outstanding A

    ttributes

    List of Grades

    Low Wear, Low

    Friction Serie

    s

    Key Properties

    TableStiffnes

    s & Strength

    Creep Resista

    nce

    Stress Relaxatio

    n

    Fatigue Resista

    nce

    Impact Resista

    nce

    UV Resistance

    Temperature

    Chemical Resis

    tance

    Typical Applic

    ationsRadii

    Uniform Wall T

    hickness

    Ribs

    Bosses

    Threads

    Snap Fits

    Rapid Prototyp

    ing

    Stockists/Mach

    inists

    Colours

    Processing

    Regrind & Recy

    cling

    Laser Marking

    Medical Applic

    ations

    Further Readi

    ng

    Samples

    Design Basics

    Performance

    ▲▲▲▲

    ▲▲▲▲

    ▲▲▲▲

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    5

    ▲▲

    & Strength

    ▲▲▲▲

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    79

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    5

    This handbook makes basic information easily available todesigners and others and gives a quick reminder of theimpressive range of Delrin®properties.

    It is illustrated with a selectionof photographs showing someof the enormous variety ofapplications for which Delrin®has already been successfullyused.

    Use the colourcoded bars to helpyou ‘flick’ through tothe relevant sectionand data

    ‘Design with Delrin®’

  • Back to index

    Delrin® versatility: snap fits to ski bindings, clips to conveyors,buckles to bicycle parts

    Designers – use sim

    ple rules

    to get the best from

    Delrin® in

    “Design Basics”

    View applications

    throughout this bind

    er

    . . .Do you speak Delrin®? Are you as fluent as youwould like to be?

    . . .Are you up to speed withall the new grades includingLow Wear, Low Friction, UVResistant and the ElevenSeries?

    . . .Do you know whereDelrin® is used – and why?Have you heard of Delrin®but don’t know what it feelslike?

    . . .This Delrin® “phrase book”will help you brush up onyour acetal knowledge until itbecomes your first language.

    Delrin® has a uniq

    ue blend of

    properties – under

    stand them in

    “Performance”

    ▲▲

    Do You Speak Delrin®?▲

    This publication is also available at http://www.dupont.com/enggpolymers/europe

    4 5

    http://www.dupont.com/enggpolymers/europe/index.html

  • Back to index

    Delrin® versatility: skate parts, ski bindings, speaker grilles

    What is Delrin®?Delrin® is an engineeringthermoplastic with a combination ofphysical properties not availableeither in metals or other plastics.

    It has a well balanced profile ofmechanical properties, environmentalresistance and processability atmoderate cost.

    Delrin® acetal resins providesubstantial strength, stiffness andcreep resistance.

    Delrin® has gained widespreadrecognition for reliability ofperformance in many thousands ofengineering components all overthe world.

    Since its commercial introduction byDuPont in 1960 it has been used in

    the automotive, appliance,construction, hardware, electronicsand consumer goods industries.

    I N T R O D U C T I O N

    Delrin® acetal homopolymer was introduced by DuPont in 1960.Copolymer acetal followed somewhat later, around 1962.

    Typical examples of Delrin® applications appear throughout this handbook

    Trade name: Delrin®

    Generic name: acetalSub class: homopolymer

    Abbreviation: POM (polyoxymethylene)

    Structure: highly crystalline polymerized formaldehyde

    6 7

  • Back to index

    Delrin® versatility: coloured lighters to carousels, pumps to pegs

    O U T S TA N D I N G AT T R I B U T E S

    This unique balance of properties makes Delrin® suitable for many metal replacement projects

    The outstanding attributes of Delrin® acetal resins include:

    Toughness at low temperatures(down to –40°C)

    High mechanical strength and rigidity

    Fatigue endurance unmatchedby other plastics

    High resistance to repeatedimpacts

    Excellent resistance tomoisture, petrol, solvents etc.

    Excellent dimensional stability

    Natural lubricity

    Resilience

    Good electrical insulatingcharacteristics

    Ease of fabrication

    Wide useful temperature range(in air –50 to +90°C withintermittent use up to 160°C

    8 9

  • Back to index

    Delrin®: whether standard or specialised, a grade forevery application

    100 High viscosity100P High viscosity, easy processing.111P High viscosity, easy processing,

    improved stability

    500 Medium viscosity 500P Medium viscosity, easy processing511P Medium viscosity, easy

    processing, improved stability

    900P Low viscosity, easy processing911P Low viscosity, easy processing,

    improved stability

    1700P Very low viscosity, easyprocessing, improved stability

    DE 9156 1,5% PTFE micropowder120MP 20% PTFE micropowderDE 9152 1,5% PTFE micropowder520MP 20% PTFE micropowder500AF 20% PTFE fibres500CL Chemical Lubricant500AL Advanced Lubricant900SP Special Polymer500SC Silicone Concentrate100KM Kevlar® Modified

    LIST OF DELRIN® GRADES

    Standard Low Wear/Low Friction

    100ST Super tough, high viscosity100T Toughened, high viscosity500T Toughened, medium viscosity

    Toughened

    510GR 10%GR525GR 25%GR570 20%GF577 20%GF, UV resistant

    Glass Reinforced/Filled

    127UV High viscosity, best UV527UV Medium viscosity, best UV927UV Low viscosity, best UV1727UV Very low viscosity, best UV107 High viscosity, UV507 Medium viscosity, UV

    Delrin® 100=high viscosity 500=medium viscosity 900=low viscosity

    UV

    1110

  • Back to index

    Level 1Tribological system

    Level 2 Requirements:

    how can I avoid...?

    Level 3Solution: appropriate

    grade of Delrin®

    High wear resistanceagainst aluminium

    Delrin® 100KM ($$$)Delrin® 500CL ($$)Delrin® 500AL ($$)

    ($) . . . . ($$$$) = relative cost

    L O W W E A R , L O W F R I C T I O N S E R I E S

    The natural lubricity of Delrin® means it may be found unlubricated in many gear and bearing applications

    Choosing Delrin® is a good starting point for applications inwhich wear and friction are majorissues. Unmodified Delrin® haslow friction and wear against steelas can be seen from the chartbelow.

    THE FACTORS AFFECTINGWEAR AND FRICTION ARE:* Pressure of contact* Relative velocity* Temperature* Geometry of motion* Frequency of motion* Nature and finish of surface

    * Lubrication

    For metal as acounter surface,

    the harder the surface the better the wear and

    friction behaviour of the system.

    Aim for a hardness of greater than

    50 HRc

    1000

    100

    10

    1

    0.00 0.10 0.20 0.30 0.40

    P R O T O T Y P E T E S T I N G I S I M P O R T A N T

    Spec

    ific

    wea

    r ra

    te(1

    0-6 m

    m3 /N

    m)

    Dynamic coefficient of friction, µ

    Countersurface= steel PPO▲

    ABS ▲

    PBT▲ ▲ PA66

    POM▲(Delrin®)

    ▲POM+20%PTFE(Delrin®)

    New!

    high PV

    steel

    Delrin®againstmetal

    low PV

    Delrin® with low specific wear rate, ·wsDelrin® 100/500/900 ($)Delrin® DE9156/DE9152 ($$)Delrin® 500CL ($$)Delrin® 500AL ($$)Delrin® 100KM ($$$)Delrin® 520MP ($$$)Delrin® 500AF ($$$$)

    Wear

    Best

    Delrin® with low coefficient of friction, µ

    Delrin® 100KM ($$$)Delrin® 100/500/900 ($)Delrin® DE9152/DE9156 ($$)Delrin® 500CL ($$)Delrin® 500MP ($$$)Delrin® 500AL ($$)Delrin® 500AF ($$$$)

    Friction

    Best

    friction

    wearaluminium

    RESIN SELECTOR – DELRIN® AGAINST METAL

    wear

    Delrin® with low specific wear rate, ·ws

    1312

    Delrin® 100/500/900 ($)Delrin® 500CL ($$)Delrin® DE9152/DE9156 ($$)Delrin® 500AL ($$)Delrin® 100KM ($$$)Delrin® 520MP ($$$)Delrin® 500AF ($$$$)

    Wear

    Best

    PV= pressure • velocity

  • Back to index

    L O W W E A R , L O W F R I C T I O N S E R I E S

    Please refer to the grades list for details of Low Wear, Low Friction Resins

    When two parts are in contact in a wearsituation it is normal to choosedissimilar materials (eg Delrin® acetaland Zytel® nylon). Factors such asdimensional stability may make such achoice impossible, in which case thenew Low Wear, Low Friction gradesof Delrin® may be suitable. The tablebelow shows the improvement inwear and friction compared tostandard grades.

    0.10 0.20 0.30 0.40

    Spec

    ific

    wea

    r ra

    te(1

    0-6 m

    m3 /N

    m)

    New Grades

    ●900SP

    StandardGrades

    100P●

    10000

    100

    1000

    10

    1

    Countersurface

    = Delrin®

    Quieter too!Certain grades reduce noise(squeak) dramatically comparedwith standard grades

    . . . continuedLevel 1Tribological

    system

    Level 2 How can I

    avoid...?

    Level 4 Solution: otherthan material

    choice

    Level 3Solution: appropriate

    grade of Delrin®

    ($) . . . . ($$$$) = relative cost

    15

    friction

    impactnoise orfailure

    wear

    squeak

    Non-squeaking grades of Delrin®

    Delrin® toughened grades(external lubrication needed)

    Delrin®againstDelrin®

    Delrin® 500SC@10% ($)Delrin® 500AL ($$)Delrin® 900SP ($$)Delrin® 120MP/520MP ($$$)Delrin® 500AF ($$$$)

    Delrin® with low specific wear rate, ·wsDelrin® DE9156/DE9152 ($$)Delrin® 500SC @ 5% ($)Delrin® 500AF ($$$$)Delrin® 500AL ($$)Delrin® 900SP ($$)Delrin® 500SC @ 10% ($)Delrin® 120MP/520MP ($$$)

    Delrin® with low coefficient of friction, µ

    Delrin® DE9156/DE9152 ($$)Delrin® 500AF ($$$$Delrin® 520MP ($$$)Delrin® 120MP ($$$)Delrin® 500AL ($$)Delrin® 500SC @ 5% ($)Delrin® 900SP ($$)Delrin® 500SC @ 10% ($)

    Friction

    Best

    Delrin® 100T ($)Delrin® 500T ($)Delrin® 100ST ($$)

    Wear

    Best

    external lubrication

    other material forcounter surface

    external lubrication

    external lubrication

    optimise design

    reduce pressure

    14

    RESIN SELECTOR – DELRIN® AGAINST DELRIN®

    ●500AL

    DE 9152●

    ●520MP

    Dynamic coefficient of friction, µ

  • Back to index

    K E Y P R O P E R T I E S TA B L E

    Delrin® 100 is the toughest unmodified acetal available with a unique combination of elongation and stiffness

    Based on Delrin® 100 high viscosity acetal

    Yield stress

    Yield strain

    Strain at break

    Flexural modulus

    Izod notched impactstrength @ 23°C

    @–40°C

    Temperature of

    deflection under load

    Melt temperature

    Flammability

    Shrinkage

    Melt Flow Index

    Chemical Resistance

    Density

    71

    25

    70

    2800

    128

    115

    177

    HB

    1,9 to 2,2

    2,2

    outstanding

    1,42

    MPa

    %

    %

    MPa

    kJ/m2

    °C

    °C

    %

    g/10 min

    g/cm3

    Property Units Value

    For graphssee next section

    Campusdiskette

    available

    Delrin®: stiff, strong, tough, chemically resistant

    16 17

  • Back to index

    The exceptional elongation coupled with stiffness makes Delrin® suitable for snap fits

    To judge the stiffness and springiness of Delrin® ask your nearest DuPont Engineering Polymers office for test bar samples.

    The modulus of Delrin® isaffected by changes in thetemperature as shownbelow.

    3

    2

    Temperature (°C)

    Youn

    g’s

    mod

    ulus

    (G

    Pa)

    1

    0 —20 0 20 40 60 80 100

    The mechanical response to short term loads

    is shown above

    Strain (%)

    Str

    ess

    (MPa

    )

    20

    0 0 2 4 6 8 10

    40

    60

    80

    -20°C 23°C

    90°C

    Material chosen and whyDelrin® 100 was chosen for its unique balance of stiffness and strength

    Description/ApplicationSnap fit buckle

    18 19

    P E R F O R M A N C E

    Stiffness and Strength

    Young’s modulus of Delrin®

    as a function of temperature

    Stress v Strain at –20°C,23°C and 90°C

  • Back to index

    P E R F O R M A N C E

    Upon removal of a 14 MPa deforming stress, Delrin® immediately recovers 40% of the imposed strain

    Creep is defined as time dependentstrain, resulting from stress.

    Str

    ess

    (M

    Pa)

    20

    15

    10

    5

    00 0,5 1,0 1,5 2,0 2,5

    I s o c h r o n o u s s t r e s s / s t r a i nD e l r i n® 1 0 0 @ 2 3 ° C

    1h10

    h10

    0 h

    1000

    h50

    00 h

    1000

    0 h

    Total strain (%)

    Creep

    Always try to design partsso that they arenot permanentlyloaded

    The factors affecting creep are:*Stress level*Time*Temperature

    Material chosen and whyDelrin® 100 was chosen for its good spring characteristics and superior creep

    compared with polyamide, polypropylene and acetal copolymer

    Description/ApplicationClothes peg

    20 21

    100

    000

    h

    (proje

    cted) Delrin® Acetal Resins

    have extremely goodcreep resistance for anunreinforced polymer

  • Back to index

    P E R F O R M A N C E

    Stress free mouldings may be obtained by annealing Delrin®

    at 160°C for 45 mins

    Stress relaxation is defined asdecrease of the stress required to

    maintain constant strain.

    % o

    f in

    itia

    l st

    ress

    100

    80

    40

    20

    10

    0,01 0,1 1,0 10 100 1000 10000

    Te n s i l e s t r e s s r e l a x a t i o n o fD e l r i n®1 0 0 a n d 5 0 0 @ 2 3 ° C

    Hours

    Stress relaxation

    Strain 0,3%. 17 MPa0,9%. 34 MPa

    5%. 66 MPa

    12,5%.Yield point strain 69 MPa

    Stress relaxation is particularlyimportant whenconsidering press-fit assembly

    Material chosen and whyDelrin® 100P was chosen for its good friction properties and a balance of

    impact and creep resistance with high dimensional stability

    Description/ApplicationCar window guides

    22 23

  • Back to index

    P E R F O R M A N C E

    Delrin® Acetal Resins have extremely high resistance to fatigue failure from –40°C to +80°C

    Fatigue

    When materials are stressed cyclically at high levels of stress in relation to their tensile strength,they tend to fail at levels of stressbelow their ultimate tensilestrength.

    This phenomenon is termed “fatigue failure.”

    Str

    ess

    (M

    Pa)

    50

    40

    30

    20

    10

    0103 104 105 106 107

    C y c l e s t o f a i l u r e

    Fatigue failure stress of Delrin®compared withother plastics106 cycles, 23°CMaterial Stress

    (MPa)Polycarbonate 10ABS 11Polypropylene 15Delrin® acetal 32

    Material chosen and whyDelrin® 100 was chosen for the best balance of stiffness and strength coupledwith flex fatigue resistance needed for the spring fingers of the tool gripper

    Description/ApplicationTool changer carousel

    24 25

  • Back to index

    P E R F O R M A N C E

    Delrin® acetal maintains its high toughness down to very low temperatures

    Impact resistance is definedas the ability to withstand asudden blow rather than aslowly applied load.

    Impact Resistance

    60

    Charpy Impact Strength (23°C)

    Impa

    ct s

    tren

    gth,

    kJ/m

    2

    500 500T 100 100T 100ST

    50

    40

    30

    20

    10

    0

    20

    15

    10

    Temperature, °C

    Impa

    ct s

    tren

    gth,

    kJ/m

    2

    5

    0

    R

    -40 -20 0 20 40 60

    Izod Impact v Temp Delrin 100

    See also Effect of Radii in‘Design Basics’

    Description/ApplicationRollerblade brake

    Material chosen and whyDelrin® 100ST was chosen for the best combination of stiffness and

    impact resistance at low temperature, combined with good mouldability

    2726

  • Back to index

    P E R F O R M A N C E

    The Delrin® UV family of resins are well suited for sporting goods and otheritems which are used outdoors but stored indoors

    Acetal resins, like mostpolymers, are affected bylight, particularly sunlightwhich includes ultra-violetradiation of wavelength290-400 nm.

    UV Resistance

    R

    Exposure, kJ/m2

    Rel

    ativ

    eG

    loss

    0

    1,0

    0,5

    500 1000

    x27UV BK

    x07 BKx00 BK

    Exposure, kJ/m2

    Rel

    ativ

    eTe

    nsile

    Stre

    ngth

    0

    0,5

    500 1000

    UV Stabilised

    Standard

    1,0

    Accelarated Interior Weatheringaccording to SAE J-1885

    Coloured Delrin® resinsoffer some UVprotection. High levelsof carbon black act asan effective UV screenfor non-critical outdoorapplications

    Typical values for Delrin® grade 527UV compared with other grades.

    Material chosen and whyDelrin® 127UV was chosen for its excellent balance of mechanical

    properties combined with good UV resistance

    Description/ApplicationMoped brake lever

    29

    Colours

    28

  • Back to index

    P E R F O R M A N C E

    The thermal stability ofDelrin® means it finds use in applications from –50°C to +90°C

    The highly crystallinenature of Delrin® means it is suitable for short-termexposure to temperaturesclose to the melting pointof 177°C.

    Temperature

    Specific HeatThermal Conductivity(W/m • K)

    Key ThermalCharacteristicsProperty

    Melt temperatureVicat Softening10 N50 NRelative ThermalIndex (w/o impact)HDT (1,8 MPa)Ball Pressure Test

    °C

    177

    174160

    90115165

    1 2 5 10

    100

    75

    50

    Exposure time in years for which tensile strength in excess of 55 MPa is retained

    Air

    Tem

    pera

    ture

    (0 C

    )

    If you need higher temperature resistance,consider DuPont Zytel® nylons , Crastin® and Rynite®

    polyesters or Zenite™ LCPs.

    Material chosen and whyDelrin® 100 was chosen for its good thermal stability combinedwith a low coefficient of friction and superior impact resistance

    Description/ApplicationBearing roll cages

    30 31

    After 1 yearat 100°CDelrin® retains80% of itstensile strength

    0,35

    0,30to0,37

  • Back to index

    Delrin® has excellent resistance to moisture, gasoline, lubricants, solvents and many neutral chemicals

    Do not use Delrin®

    in strong acids or

    bases outside the

    range of pH 4 to 9

    CHEMICAL BEHAVIOUR

    Acetic acid (5%) resistantAcetic acid (50%) unsatisfactoryAcetone resistantAir (all pressures) resistantAlcohol (all types) resistantAmmonia (10%) unsatisfactoryAniline limited resistanceBenzene resistantBleaching fluid (10% chlorine) unsatisfactoryBrake fluid resistantButane resistantCalcium chloride (10%) resistantCarbon dioxide resistantCarbon monoxide resistantChloracetic acid (10%) unsatisfactoryChlorine gas unsatisfactoryChlorinated water < 0,5 ppm resistantChloroform limited resistanceChromic acid (10%) unsatisfactoryCitric acid resistantCyclohexane resistantDetergents resistantDiesel fuel resistantEthanol resistantEthyl acetate resistant

    P E R F O R M A N C E

    Chemical Resistance

    The factors affec

    ting

    chemical resistan

    ce are:

    * Concentratio

    n

    * Time

    * Temperature

    * Stress Level

    14 Alkali

    9

    7 Neutral

    4

    0 Acid

    Description/ApplicationPool cleaner swivel bearing

    Material chosen and whyDelrin® 500P was chosen for its excellent wear properties, chemical

    resistance, snap-fit ability and dimensional stability

    32 33

  • Back to index

    P E R F O R M A N C E

    CHEMICAL BEHAVIOUR

    Ethyl ether resistant

    Ethylene glycol resistant

    Formaldehyde (37%) resistant

    Formic acid unsatisfactory

    Fuel oil resistant

    Gasoline resistant

    Glucose (sat.sol.) resistant

    Heptane resistant

    Hexane resistant

    Hydrochloric acid (10%) unsatisfactory

    Hydrofluoric acid unsatisfactory

    Hydrogen peroxide (1%) resistant

    Hydrogen peroxide (30%) unsatisfactory

    Hydrogen sulphide unsatisfactory

    Insecticides resistant

    Isoctane resistant

    Jet fuel /kerosene resistant

    Lubricating oil resistant

    Methyl chloride limited resistance

    Methylene chloride limited resistance

    Methyl ethyl ketone limited resistance

    Mineral oil resistant

    Motor oil resistant

    Nitric acid (10%) unsatisfactory

    CHEMICAL BEHAVIOUR

    Nitrous acid unsatisfactory

    Nitrous oxide (dry) unsatisfactory

    Oils (food) resistant

    Oils (mineral) resistant

    Oleic acid resistant

    Palmitic acid resistant

    Paraffins resistant

    Perchloric acid (10%) unsatisfactory

    Phosphoric acid (30%) unsatisfactory

    Phthalic acid resistant

    Potassium hydroxide (10%) unsatisfactory

    Propane (liquified gas) resistant

    Sodium chloride (10%) resistant

    Sodium hydroxide (10%) unsatisfactory

    Sodium hypochlorite (5%) unsatisfactory

    Sulfur dioxide unsatisfactory

    Sulphuric acid (30%) unsatisfactory

    Tetrahydrofuran resistant

    Toluene resistant

    Trichloroacetic acid unsatisfactory

    Trichloroethane (1,1,1) resistant

    Turpentine / white spirit resistant

    Urea (5%) resistant

    Vinegar resistant

    Chemical Resistance cont.

    Material chosen and whyDelrin® 500P was chosen for its good petrol resistance,

    good mechanical properties and ease of moulding

    Description/ApplicationFuel level device

    34 35

  • Back to index

    T Y P I C A L A P P L I C AT I O N S

    The exceptional balance of properties has led to a diverse use ofDelrin® around the world

    Ski Bindings

    Clips Door Handles Fuel Systems

    Zips Conveyors

    Fasteners Speaker Grilles

    Lighters Gears

    Toughness @–40°CUV performance

    Strength,stiffness, lowwear, low friction

    Low friction, brightcolours

    Elongation, fatiguestrength

    Stiffness, low friction,UV performance

    Chemical resistance

    Economical, toughness Easy flow, impact performance

    Low wear, quietoperation

    Chemical resistancePressure vessel

    Do it in Delrin®. . .

    . . . nothing does it better

    36 37

  • Back to index

    D E S I G N B A S I C S

    Delrin® like many plastics, is notch-sensitive but unlike other resinsit has high impact strength at low temperatures

    Str

    ess

    Fac

    tor

    R/T

    Radii use of radii has three main functions* Reduces notch effect * Helps material flow* Eases ejection frommould

    see also

    ImpactPerformace

    Always use radii

    at rib junctions

    and stressed areas

    but also consider

    thread terminations,

    knurled inserts and

    surface textures

    Material chosen/Design commentDelrin® 111P was chosen for this application. Radii lowers stress

    concentration when parts are put under load

    Description/ApplicationSpring clips

    38 39

    0 0,2 0,4 0,6 0,8 1,0 1,2 1,41,0

    1,5

    2,0

    2,0

    Usual

    P = Applied LoadR = Fillet RadiusT = Thickness

    P

    T

    R3,0

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    Even wall section will greatly benefit highly crystallinepolymers such as Delrin®

    Even wall thicknes

    s

    gives:

    * Even shrinkage

    – less distortion

    * Even set-up

    – quickest mouldin

    g

    cycle

    * Less material

    – low cost

    Choosing the correct wallthickness for a moulded partis a function of end useconstraints (what does thepart have to do?), moulding factors, (what is the thinnestsection that can be moulded?)and overall cost.

    The exact thickness may beestimated by the use of FiniteElement Analysis (FEA) usedin both part design and flowanalysis, but where possibleshould be relatively constant throughout.

    D E S I G N B A S I C S

    Uniform Wall Thicknesses

    Description/ApplicationRatchet mechanism

    Material chosen/Design commentDelrin® 500P. Low distortion and cost efective part ensured

    by use of even wall thickness

    40 41

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    If ribbing is unacceptable, Delrin® 510GR and 525GRoffer significant increase in stiffness

    Ribs are an effec

    tive way

    to improve the ri

    gidity of

    moulded parts.

    For Delrin®, ribs s

    hould be

    1/2 to 2 /3 the

    general wall

    thickness, with

    1/4° to

    1/2°draft angle p

    er side.

    Sink marks caused byribs may be hidden

    by use of textured surface orsuitable interruption in thearea of the sink.

    D E S I G N B A S I C S

    Ribs

    Proper use of ribs will:

    * Save material and weight

    * Shorten moulding cycle

    * Eliminate voids in thicksections

    Description/ApplicationCross beam

    Material chosen/Design commentDelrin® 100P enables increased stiffness to be achieved by

    use of ribs without compromising surface finish

    42 43

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    Weld lines should be avoided in bosses. Delrin® being generallyunreinforced, has excellent weld line strength

    D E S I G N B A S I C S

    Bosses are used for

    mounting purposes or for

    reinforcement around holes.

    As a rule the outside

    diameter of a boss should be

    2 to 3 times the hole

    diameter.

    Heavy sections may be

    avoided by stepping the boss

    off the adjoining wall.

    Use radii at all junctions.

    Always use screws designed forplastics when consideringassembly. These may be singleor twin-start threaded ortrilobular screws. Repeatedassembly and disassembly ispossible with Delrin®.

    Bosses

    Boss Design

    ***

    Hole dia = 0,75 x nominaldia of screw

    Boss dia : 2 to 3 times hole dia

    Hole depth 2 x nominalscrew dia minimum

    Description/ApplicationFuel flange

    Material chosen/Design commentDelrin® 511P. Boss and linking rib design

    provides accurate hole centres

    4544

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    D E S I G N B A S I C S

    When required, threads maybe automatically mouldedinto the part, eliminating theneed for mechanical thread-forming operations.For external threads, it maybe possible to locate theparting line on the centre ofthe thread.For internal threads, anautomatic unscrewing deviceis used in the tool.

    To avoid ‘squeak’ on heavilyloaded threads, consider theLow Wear, Low Friction gradesof Delrin®

    Use of a buttress

    type thread will

    avoid unnecessary

    radial forces on

    the mating part

    Correct termination of threads

    The dimensional stability ofDelrin® makes it very suitable for the moulding of accurate thread forms

    Threads

    Description/ApplicationIndustrial valve

    Material chosen/Design commentDelrin® 500P. Moulded thread form avoids machining

    4746

    1mm

    Round threads

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    The combination of stiffness and elongation makesDelrin® very suitable for snap fits

    L

    R

    D E S I G N B A S I C S

    Snap Fits are a cost effectiveway of assembling partstogether without the use ofspecial tools.

    Usually the parts are at restbefore and after assemblyand pass through a stressedcondition as the snap fit ismade to work.

    With Delrin®, a single use snapfit may be stressed up to 8%strain (Delrin® 100). For afrequently used one refer tothe fatigue stress graph

    Snap Fits

    Delrin® is also excellent forcircular and spherical snapfit designs

    Cantilever Snap Fits

    ***

    Make ‘L’ as long

    as possible

    Taper snap fit lug

    Use radii at root

    Description/ApplicationCable guide

    Material chosen/Design commentSnap fit in Delrin® 500 gives strong, rattle-free connection

    48 49

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    Prototyping tipsKeep heat generatedduring machining to aminimum

    Support thin wallsand long partsBe aware of the notcheffect of machiningparts

    R A P I D P R O T O T Y P I N G

    Delrin® has excellent machining characteristics using conventional tools

    In order to test parts in the actualmaterial it is normally necessaryto mould them. Due to the easeof machining of Delrin®, it maybe possible to prototype partsby NC machining, utilising theCAD data which describesthe part geometry.

    ModifyGeometry

    Mould Parts

    7

    5a

    *

    *

    *

    Delrin®stockists/machinists

    ▲Shoehorn prototype

    CNC machining of simple shapes possible in Delrin®

    50 51

    CAD Data

    1

    Test Parts

    5

    NC MachineMould Tool

    6

    Hand Finish

    4

    Create Tool

    Paths

    Machine Stock Shapes(Block, Rod)

    32

  • Back to index

    S T O C K I S T S / M A C H I N I S T S

    Details of companies experienced in machining Delrin® acetal resinsare also available from your DuPont representative

    Contact your DuPont representative for detailedinformation on your local Delrin® stockist

    Rod stock, slab

    Always ask for Delrin® by name

    52 53

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    C O L O U R S

    No heavy metals are used in Delrin® Colours

    Typical referencecodes for

    Delrin® colours

    I d e a l l y a n y m a s t e r b a t c h s h o u l d b e a c e t a l b a s e d

    NC = Natural

    BK = Black

    WT = White

    GY = Grey

    GN = Green

    BL = Blue

    YL = Yellow

    RD = Red

    Pigmentsmay affectshrinkage –test first!

    Custom colours areavailable as fully

    compounded productfrom DuPont or bymasterbatch from pigment suppliers

    S h r i n k a g e v. C o l o u r

    NC

    WT

    YL

    BK

    BL

    GY

    RD

    GNCOLOUR

    SHR

    INK

    AG

    E(%

    )

    2,1

    2,0

    1,9

    1,8

    Delrin® The heart of a good product

    54 55

    1,7

  • Back to index

    For specific processing information ask for the free booklet‘Delrin® Moulding Manual’

    The most important variablesin producing good parts by

    injection moulding are:

    Above all, a good qualityhomogeneous melt is required.

    * Melt temperature

    * Injection speed

    * Hold pressure

    * Screw forward time

    * Mould temperature

    Always dry toughened gradesfor 4 hours at 80°C

    P R O C E S S I N G

    Melt Temp(°C)

    215 90 100 8 30 1,9 - 2,2

    MouldTemp(°C)

    HoldPressure

    (MPa)Hold PressureTime (s/mm)

    Max Hold Up Time

    (min)Shrinkage

    (%)

    Typical set-up conditions forDelrin® 100 are shown below.

    Material chosen and whyDelrin® 927UV was chosen for its excellent mouldability and impact resistance.

    Its resistance to UV and easy colourability are additional assets

    Description/ApplicationVenting system grille

    5756

    Grades based on the ‘P’ stabilisation system are suitablefor hot runner tools,these include

    100P, 500P, 900P,1700P127UV, 527UV, 927UV,1727UV,111P, 511P, 911P.

  • Back to index

    R E G R I N D & R E C Y C L I N G

    It is important to use analytical techniques in part design to reduce the impact of recyclate on the environment

    RECYCLING

    The combination

    of

    stiffness and elon

    gation

    that makes Delrin

    ® so

    effective in snap fi

    ts also

    means that parts m

    ay be

    disassembled prio

    r

    to recycling.

    The long term sta

    bility

    of Delrin® means th

    at

    parts may be regr

    ound

    and remoulded wi

    th

    little effect on

    properties.

    Incineration is an

    energy

    efficient alternativ

    e

    >POM<

    Description/ApplicationGolf tee

    Material chosen and whyDelrin®100 regrind was chosen for the shank. Capable ofwithstanding high impact, it provides the correct rigidity

    5958

    REGRINDUp to 25% of properlyground sprues and runners may be mixedwith virgin resin with little or no effect onmechanical properties.

    Toughened grades willneed to be dried priorto moulding.For glass reinforcedgrades, use a slow speedon the grinder rotor.

  • Back to index

    L A S E R M A R K I N G

    See also Delrin® colours

    Laser marking is particularly suitable when

    the batch sizes are small and marking variability is required

    (e.g. serial numbers or different languages).

    . . .BK-L01 Black

    . . .BL-L01 Blue

    . . .BN-L01 Brown

    . . .GN-L01 Green

    . . .GY-L01 Grey

    . . .RD-L01 Red

    . . .WT-L01 White

    Advantages* High rate contactlessprocess* Flexibility, easy changeof layout and charactertype* No surface pre-treatment,no solvent, no ink* High durability of themarking

    A range of colours specially optimised for laser marking is available in Delrin®.Tested with severalNd:YAG lasersystems, thesecolours provide highcontrast markingswith almost noengraving

    LASER = Light Amplificat

    ion by

    Stimulated Emission of R

    adiation

    Colours for laser marking 500LM ...

    ▲Material chosen and whyDelrin® 500LM BK-L01 was chosen for its clarity of laser marking

    plus its mechanical properties

    Description/ApplicationSki adjuster

    6160

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    M E D I C A L A P P L I C AT I O N S

    Delrin® acetal resin is notcertified for implants

    Do not use DuPont materials in medicalapplications involving

    permanent implantation in thehuman body or permanentcontact with internal body

    fluids or tissue.

    Do not use DuPont materials in medical

    applications involving brief ortemporary implantation in thehuman body or contact withbody fluids or tissues unless

    the material has been provideddirectly from DuPont under a

    contract which expresslyacknowledges the

    contemplated uses.

    For food contact or pharmaceutical

    applications, regulatorycompliance statements are

    available, please contact your local DuPont

    representative fordetails.

    DuPont makes norepresentation, promise,express warranty or impliedwarranty concerning thesuitability of these materialsfor implantation in the humanbody or in contact withinternal body fluids or tissues.

    ✠CAUTION

    Description/ApplicationMedical tube clip

    Material chosen and whyDelrin® 500P was chosen for its chemical resistance and springiness

    6362

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    F U R T H E R R E A D I N G

    The general brochure covering all DuPont engineering polymersis called ‘From concept to commercialisation’

    To access furtherinformation concerningany topic covered in this

    binder, please contactyour local DuPont office

    Access information onDelrin® at our internet

    address:http://www.dupont.com/

    enggpolymers/europe

    Delrin® Product guide and properties

    DesignInformation

    MouldingManual

    Main Literature for Delrin®

    ▲▲

    DuPont has a wide

    selection of literature

    covering specific

    application areas

    such as Appliances,

    Automotive, Electrical,

    Furniture etc.,

    together with a

    General Design Principles

    handbook which covers all

    DuPont engineering resins

    Technical Information

    A wealth of experience available in various formats64 65

    http://www.dupont.com/enggpolymers/europe/techlit/promo/concep_e.pdfhttp://www.dupont.com/enggpolymers/europe/techlit/products/delrin.htmlhttp://www.dupont.com/enggpolymers/europe/techlit/products/delrin/DELPGPe.pdfhttp://www.dupont.com/enggpolymers/europe/techlit/products/delrin/DELDGe.pdfhttp://www.dupont.com/enggpolymers/europe/techlit/products/delrin/DELMGe.pdf

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    Delrin®. Chosen for reliability of performance in many thousands of engineering components all over the world

    Delrin® Makes the Difference

    66

    F U R T H E R I N F O R M AT I O N

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