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Technology Solutions to Benefit from RecentMarket Trends in the Petrochemical Sector

Jose CarrazzaGlobal Business Director - Petrochemicals

Catalyst, Adsorbent & Specialties

UOP LLC, A Honeywell Company

©2012 UOP LLC. All rights reserved.

32nd Latin American Petrochemical Annual Meeting

Rio de Janeiro. November 12, 2012

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Honeywell’s Businesses

y$36.5 billion in revenues in 2011, 50% outside of U.S.

y Nearly 130,000 employees operating in 100 countries

y Morristown, NJ global corporate headquarters

Aerospace Automation &

Control SolutionsPerformanceMaterials &Technologies

TransportationSystems

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Energy Efficiency

By immediately and

comprehensivelyadopting existing

Honeywell products,

the United States could

reduce energyconsumption by

20 to 25 percent

More than 50% of

Honeywell’s portfolio offers

energy efficiency benefits

Green Buildings

Biofuels Air Traf fic

Modernization

Reduced Emissions

Fuel Efficiency Industrial ProcessEfficiency

Energy Efficiency,Demand Response,

& Smart Grid

EnergyPerformance

Contracts

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UOP Company ProfileServing the Refining, Petrochemical & Gas Processing Industries

Profile

Business Units: Process Technology & Equipment (PT&E) Catalysts, Adsorbents & Specialties (CA&S) Gas Processing and Hydrogen (GP&H) Renewable Energy and Chemicals (RE&C)

Offering: Technology, Catalyst & Services to the Refining,

Petrochemical and Gas Processing Indust ries Supplier of molecular sieve adsorbents to process

and manufacturing industries

Significant Technology Posit ion

Global Customers

UOP Facilities - WW HQ: Des Plaines, Ill inois(suburban Chicago) Employees: 3500+

Global Footprint

Licensing12%

Products51%

Services12%

Equipment25%

Diverse Offering

Sales: Geographic

19 Offices

16 Countries

12 Manufacturing Facili ties

5 Engineering Centers

UOP Off icesUOP Manufactur ing sites

Sales: Breakdown

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UOP Project Cycle

Technology

Delivery

UOP delivers total technology solutions

y Planning & Consulting Studies

y Engineering Services

y Basic Engineering Design

y Advanced Process Control

y Equipment

y Catalyst, Adsorbent, Chemicals

y Training

y Start-up Assistancey Ongoing Services & Inspection

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UOP – Strong History of Innovation

1914 Dubbs Cracking Process 1970s UOP Parex TM Process

1938 High Octane Aviation Gasoline 1990 UOP Oleflex TM Process

1949 UOP Platforming TM Process 2005 National Medal of Technology Honor

1957 Zeolites for Catalytic Cracking 2005 UOP Becomes a Honeywell Subsidiary

1960s Unleaded GasolineTechnologies 2008 Methanol to Olefins, Uniflex TM,Green J etFuel Technology

1968 Biodegradable Detergents Today UOP licenses more than 50 processesand more than 90 catalysts to refinersworldwide1970s Automotive Catalytic Converter

Continuous Innovation for Almost 100 years

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Fundamentals of Innovation at UOP

NovelMaterials

Novel

ManufacturingTechnologies Technical

Service

Training“ Voice of the Customer”

Advanced Process/

Equipment Technology

Advanced Design

Techniques

NovelCatalyt ic and Adsorptive

Concepts

HumanFactor

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UOP Technologies in Petrochemicals

PetrochemicalProduct

Customer NeedUOP

Technology

p-Xylene• Higher ROI on new units and revamps

• Lower energy consumption and operating costParex TM

Olefins

• Lower capital and energy consumption per MT

of propylene Oleflex TM

• Highest yield from cost advantaged feedstock

(coal and NG) MTO

Detergents

(LAB)

• Higher production with no increase in

paraffin/olefin input

• Lower capital and utilities

Detal-Plus TM

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Sustained Profitability Into 2014

P-Xylene & Naphtha Price - NE Asia

p-Xylene producers investing to benefit from current up-cycle

UOP P TM T h l

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UOP ParexTM Technology:>40 Years Strong

y First commercialized in 1971

y Based on the UOP Sorbex TM

technology; generically referred toas Simulated Moving Bed, SMB

y Since introduction, >80% newp-xylene capacity has been basedon this technology

y >100 Parex trains have been bui lt;

>90% of them still in operation

y Incorporates the UOP rotary valve,– Simultaneously directs inlet and outlet

flows with only one moving part

y In 2012, the 200th rotary valve will becommissioned,– Many of the original rotary valves are

sti ll in service after >40 year of operation.

Parex Has Been Global Leader Since its Inception in 1971

C ti I ti D i

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Continuous Innovation DrivesTechnical Leadership

122% Base ROI115% Base ROIBase ROI

2004 2005 2006 2007 2008 2009 2010 Future

ADS-37 Adsorbent

• +6% pX capacity

• Now in 33 operating units

R-264 PlatformingCatalyst

• +18% more feed

• Now in 70+ operating units TA-20HP Catalyst

• Greater stabili ty, better Bz

• Now in 10 operating un itsI-400 Catalyst

• +20% throughput

• Now in 3 units

High Capacity Revamp

• +6-10% pX capacity

• 9 units revamped

TA-30 Catalyst

• Higher stability and ringretention

• Now in two operating units

I-350 Catalyst

• Improved stability

• Now in 6 operating units

ADS-47 Adsorbent

• Over 20% extra throughput

• Commercial unit started 10/2011

Newly Commercialized

• R-284 UOP PlatformingTM Catalyst

• I-500 UOP Isomar TM Catalyst

• Tatoray PTDTM process

Largest Single Train

• UOP ParexTM unit started-up

Energy Efficiency

• In design and construction

Substantial Improvements in Productivity Last Three Years

130% Base ROI

Net energy required

Reduced by 1/3 vs.

Best 2009 designs

Addi tional 14%+Energy

Reduction vs.

Best 2010 design

20122011

In Development

• Next generation PlatformingTM Unit Design

• Next generation Energy Efficiency• Next generation UOP TatorayTM Catalyst

ADS 47

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ADS-47Latest Generation Parex Adsorbent

ADS-47 is the result of improving mass transfer andcapacity properties applied

to the same proven chemistry

1971 – ADS-3

1980 – ADS-7

1990 – ADS-27

2004 – ADS-37

2011 – ADS-47

Continuous Innovation in Product Technology

ADS 47

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ADS-47Features and Benefits

y Effective capital deployment

for new units (less adsorbent,smaller chambers)

y Significantly lower capitalper ton of pX for revamps

y Up to $5/MT pX benefit over ADS-37 from energy savings

y Fast revamp execution;

implement across standardturnaround

ADS-47 Benefits

UOP’s Parex Technology Leads Innovation and Value

Drop-in replacementfor existing units

20 – 30% higher capacity than ADS-37

5 – 20% improvedenergy efficiency

Strongest adsorbentfor Parex service

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Advanced Process/Equipment Technology

y Enhanced heat exchangers

y High capacity fractionation

internalsy High efficiency reaction

internals

y Novel Process Design

B

A

ABC

C

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Energy Requirement

*Aromatics Complex pX Capacity = 900K MTA pX

Total EnergyRequirement(MMBtu / hr)

Energy Savings Energy Savings*@ $6 / MMBtu

UOP Design – 2009 1150 MMBtu / hr Base Base

UOP Design – 2011 455 MMBtu / hr (40%) $23MM / yr

Energy Benefit / MT pX 4.2 MMBtu / MT pX $26 / MT pX

ADS-47 Energy Benefit $5 / MT pX

TA-30 Energy Benefit $1 / MT pX

I-500 Energy Benefit $3 / MT pX

Additional Energy Benefitfrom Upgraded Products

1.2+ MMBtu / MT pX $9 / MT pX

Total Energy Benefit / MT pX 5.4+ MMBtu / MT pX $35 / MT pX

Latest Integrated Process Design Reduces Energy Use by over 53%

E i t I t th h

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Equipment Improvements through Advanced Design Techniques

y Computational Fluid Dynamic (CFD) Modeling– Adsorbent chamber flow, mixing and distribution

y Cold Flow Modeling

– Validation of CFD modelingy Engineering Design

– Reduction to practice

yPerformance Demonstration

– Design validation

UOP P T h l

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Chamber internals and rotary valve designs have been improvedy 1,000 KMTA single train Parex on stream in 2010

y Single Rotary Valve can now handle over 750 KMTA of pX product

High capacity fractionation internals and heat exchange equipment crit ical

to minimizing capital costs

UOP Parex TechnologyTrain Size Increases Over Time

Single Train Capacity Exceeds 1.5MM MTPA

p - X y l e n e , k

M T A

Commissioned

In Design / Construct ion

1400

1200

1000

800

600

400

200

01970 1975 1980 1985 1990 1995 2000 2005 2010 2015

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Parex Technology Highlights

y Significant improvements in productivity by exploit ingsynergies between process and product innovations

y Continuous enhancements in yield, selectivity and

energy efficiency for new and existing complexes

y Most energy efficient means of producing para-xylene

from naphtha

y Opportunities for revamps.

Lowest operating cost positionat the lowest investment

Maximize

Capacity

and

Energy

Efficiency

UOP 5521A-20

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Customer NeedUOP

Technology



Olefins




(coal and NG) MTO

Detergents

(LAB)




Detal-Plus TM

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Propylene Supply Discussion - Global

y “ Propylene Gap” is growing

– Steam Crackers shifting tolighter feedstocks, which

produce less propylene– Refiners limited by flat gasoline

growth in some regions, whichlimits propylene from FCCs

y “ On-Purpose Propylene” isfilling the gap

– Propane Dehydro (PDH)

– MTO (from gas & coal)

– High Severity FCC

– Olefin Cracking

0

20

40

60

80

100

120

140

2001 2006 2011 2016 2021

m i l l i o n M T

A

Supply from Refinery FCCsSupply from Steam Crackers

Demand (Polymer/Chemical Gr.)

“ Propylene Gap”

On-Purpose Propylene will supply 25% of global propylene by 2021

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Why Propane Dehydro (PDH)?

A PDH plant converts one feed (C3 LPG) …into one primary product (propylene) …with the option to export by-product hydrogen

C3 LPG Propylene

Hydrogen

yOne feed – one productySimple back integration

yProven Investment

yLow Capital IntensityyHighest Yield of Propylene

y Attractive Rate of Return

Key Features …

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0% 20% 40% 60% 80% 100%

Advanced MTO

MTO

Propane Dehydro

Lt. Nap. Cracking + Metath.

Lt. Nap. Cracking

Propane Cracking

Wt-%

Ethylene

Propylene

Butadiene

Mixed C4's

Pygas/Gasoline

Fuel Gas

Hydrogen

Fuel Oil

Coke

PDH - Product Mix Comparison

PDH provides highest yields of propylene

High-Value Chemicals

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UOP OleflexTM Process

Heater Cells

NetSeparator

Off Gas

To FracSection

Dryer

TurboExpander

Fresh& Recycle

Feed

H2 Recycle

CCR

Rx EffluentCompressor

RegenerationSection

Reactor Section

Product Recovery Section

y Continuous Operation Design

y Easy to Operate (>250 CCR’s)

Catalyst Flow

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UOP OleflexTM Technology Evolution

1990-1992 - 1st Commercial Oleflex Unitswith DeH-6 Catalyst

1992 – DeH-8 Catalyst





1995 – 250 kMTA propylene designed

1998 – 300 & 350 kMTA propylene designed




2010 – 750 kMTA propylene design available

UOP 5556J-26


UOP OleflexTM

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UOP OleflexTM

Features and Benefits

y Low capital cost

y

Low cash cost of production(CCOP) – Lowest energyrequirements

y Lowest CO2 emissions

y Six times lower NOx emissions

y Lowest waste water – no processsteam / all condensate recycled

y Non-hazardous, non-toxic, fullyrecyclable Pt catalyst system

Oleflex Benefits

Pt Based CatalystSystem

High propyleneselectivity

CCR RegenerationSectiion

Posit ive PressureDesign

UOP’s Oleflex Technology Leads Innovation and Value

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0

1,000

2,000

3,000

4,000

5,000

6,000

7,000

8,000

9,000

10,000

O l e f i n C

a p a c i t y ,

k M

T

Aw ard, Des ign or Construction

Commissioned

iC4 DehydroC3 Dehydro

5units

8units

2 units

C3/iC4 Dehydro

UOP OleflexTM Installed Capacity

3 units

1 unit

12units

UOP has been awarded 15 of the last 17PDH projects world-wide since 2011

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Oleflex Technology Highlights

y

PDH is a key proven technology for on-purpose propyleneproduction

– Low capital cost

– High propylene yield

– Attractive IRR

y The Oleflex Process is the leading PDH technology

– UOP C3 Oleflex Process is leading technology with most

operating and l icensed PDH units– UOP has been awarded 15 of the last 18 dehydro projects

world-wide since 2011

– Lowest CCOP and highest IRR PDH option via

•Lowest capital and energy cost per MT of C3= product

•Highest time-averaged product yield

– Largest single train capacity

UOP 5556J-29

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Customer NeedUOP

Technology



Olefins




(coal and NG) MTO

Detergents

(LAB)




Detal-Plus TM

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Raw Material Prices

$0

$2

$4

$6

$8

$10

$12$14

$16

$18

$20

1985 1990 1995 2000 2005 2010 2015

p e r m i l l i o n B t u

$0

$20

$40

$60

$80

$100

e q u i v a l e

n t p e r b a r r e

l o f o i lWest Texas Intermediate Crude Oil Price

Cost of Natural Gas Delivered to ElectricGenerating Plants

Cost of Coal Delivered to ElectricGenerating Plants

Oil

Gas

Coal

Values in U.S.A

Growing advantage to util ize feedstocks

derived from Natural Gas & CoalUOP 5618O-31

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Olefin Production via MTO

y Ethyleney Propylene

MTOMethanol to Olefins

SynGas MethanolReformer Converter

Olefin DerivativeUnits

y Methanol

Products (examples)y Polyethylene

y Polypropyleney Ethylene Dichloridey Ethylene Oxidey Ethyl Benzeney Acrylonitriley

Propylene Oxidey Acrylic Acidy Others

Feedstocksy Natural gas or y Coal or y Petroleum Coke or y

Biomass

Commercial Technologies

New Feedstock and Catalyst using

Commercially Proven Equipment

Commercial Technologies

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UOP Advanced MTO Technology

Regen Gas

Air

Methanol

Water

DMERecovery

LightOlefin

Recovery

Ethylene

C4+

Propylene

C4/C6 andC6+ Purges

MTO Process Integrated withOlefin Cracking Process (OCP)

SepSection

OCP

MTO

y Fluid catalytic cracking (FCC) systembest fit for SAPO-34 catalyst system

y UOP has l icensed over 280 FCC unitsin petroleum refineries

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UOP Advanced MTO Technology

0

10

20

30

40

50

60

70

80

90

100

Naphtha MTP MTO Advanced

MTO

C - y i e l d %

Other high value products

Ethylene

Propylene

Advanced MTO Light Olefin Yields

Advanced MTO provides the highest light olefin yieldsover a broad range of propylene/ethylene (P/E) product ratios

Yields of High Value Products

70

80

90

100

1.0 1.2 1.4 1.6 1.8 2.0

Propylene/Ethylene (P/E) Product Ratio, Wt.

L

i g h t O l e f i n C a r b o n Y i e l d s ,

W t - %

2.6 MT of Methanol consumed per

MT of Light Olefin produced

UOP 5618O-34

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Total Petrochemicals MTO PDU

y

Semi-commercial demo unit inoperation since 2009

y More than 18,000 operating hoursas of 3Q 2012

– Stable operation demonstrated

– Recovery and recycle of oxygenatesdemonstrated

– Olefin recovery and purif icationdemonstrated

y Continuous polymerization on existingpolymerization demonstration unitdemonstrated successfully

– Polyethylene

– Polypropylene

Polymer productmade fromMTO PDU

UOP MTO C i li ti St t

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UOP MTO - Commercialization Status

Owner Location ScopeLO

Capacity

MTA

Expected

On-Stream

Wison (Nanjing) Clean

Energy Company, Ltd.

Nanjing,Jiangsu

MTO / OCP 295,000 2013

Jiutai Energy (Zhungeer)

Company, Ltd.

Ordos, Inner Mongolia

MTO 600,000 2014

Shandong YangmeiHengtong Chemicals

Company, Ltd.

Linyi,Shandong

MTO / OCP 295,000 2014

Commercialization of MTO has become a reality

MTO T h l Hi hli ht

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MTO Technology Highlights

y MTO provides a link between cost advantaged raw materials andthe need for more ethylene and propylene

– Lower costs of production compared to oil derived feed

– Higher ratios of propylene/ethylene production

y Semi-commercial industrial experience has validated UOP Advanced MTO technology

– Complete demonstration of long-term performance

y Commercialization of MTO has become a reality

– UOP Advanced MTO Technology first commercial unit

expected to start-up in China in 2013– UOP’s Second Commercial MTO project announced in

September 2012

– Third unit announced in November 2012

UOP 5618O-37

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Customer NeedUOP

Technology

p-Xylene•

Higher ROI on new units and revamps• Lower energy consumption and operating cost

Parex TM

Olefins




(coal and NG) MTO

Detergents

(LAB)




Detal-Plus TM

D t t T h l i

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Detergent Technologies

Kerosene/Jet Fuel

Linear Alkylbenzene

(LAB)

Feedstocks Processes Products

LABDehydrogenation

& Alkylation

n-Paraffin Adsorption &

Extraction

Linear Alkylbenzene Sulfonates (LAS)represent over 50% of all surfactants

used in household detergents,

institutional & industrial cleaners,and personal care products

Benzene

Kerosene/Jet Fuel

LAS

Sulfonation

Liquid FuelsGTL / CTL

FT Synthesis

Normal Paraffin

Methaneor Coal

SO3

UOP/CEPSA Detal Plus™ Process

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Recycle n-Paraffins

Heavy Alkylate

(HAB)

LABn-Paraffins UOP

PEP™Process

Solid Bed Alkylation

(DetalProcess)

UOPPacol™ &DeFine™

Processes

Featuresy 5% increase in LAB production with no

increase in paraffin/olefin input viatransalkylation of HAB into LAB

yResulting LAB/LAS comparable inquality to products produced in Detalprocess

y Simple design

UOP/CEPSA Detal-Plus™ Process

Trans Alkylation

Detal-Plus Process

+

R (C10-C14)

2

R (C10-C14)

R (C10-C14)

Transalkylation Reaction

Simple approach to increase LAB yields

Detal-Plus Process

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Detal Plus Process Advantages for New LAB Complex

y Improves the return on investment for a newLAB complex by decreasing the overall capital investment

while improving plant profitability

Higher profitability via improved feed utilization

N-Paraffin Requirements

0.72

0.73

0.74

0.750.76

0.77

0.78

0.79

Detal Detal-Plus

M T o f N P / M

T o f L A B

Lower n-paraffin requirements

reduces size of upstreamunits, resulting in 2% lower CAPEX investment and 5%lower utilit ies and catalyst

consumption

Detal-Plus Process

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Advantages for Existing Detal Units

y Improves the profitability of existing Detal units byconverting excess HAB by-product into higher valued LAB

product with small capital investment

Attractiveness dependent on HAB-LAB price spread

CAPEX investment of under 5 MM$ for typical Detal unit(80 kmta LAB capacity)

Profitability Improvement vs.HAB-LAB Price Spread

0

1

2

3

4

5

6

7

25 50 75

HAB Pric ing (as % of LAB)

A d d e d P r o f i t a

b i l i t y

( M M $ / y r )

ZDA 2: New Alkylation Catalyst

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ZDA-2: New Alkylation Catalyst

Targetsy Operate at lower benzene to olefin

ratios (B:O) compared to currentUOP DA-114 Alkylation Catalyst

y “ Drop-in” replacement into existingDetal process units with minimalplant modifications

y Maintain high product quality

Benefits

y Lower utili ties

yLower capital due to smaller benzene column size

y Increase LAB capacity of existing Detal units

0%

25%

50%

75%

100%

DA-114 ZDA-2

0.70

0.75

0.80

0.85

0.90

0.95

1.00

DA-114 ZDA=2

Comparison of B:O Operating Condit ions

Comparison of Utili ty Requirements

Ready for commercialization

R e l a t i v e $

/ M T o f L A B

B : O

R a t i o ( M o l a r )

% o

f C u

r r e n t D e s i g n

Detal Plus and ZDA 2 Synergies

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LAB Yields Versus B:O Ratio

-2

-1

0

1

2

3

4

5

6

25% 50% 75% 100% 125%Benzene : Olefin Ratio (% of Base Case)

L A B Y i e l d

( i n c r e m e n t a l % p

o i n

t s )

H i g h e r Y i e l

d s

Implementation of ZDA-2results in higher LAByields at lower B:O

operationsy Lower feedstock

consumption

y Lower utilityconsumption

y Lower capitalinvestment

BaseCase

(Detal)

Detal-Plus and ZDA-2 Synergies

Offers greater flexibility and profitability

Lower Utilities Detal-Plus

Detal-Pluswith ZDA-2

Detergent Technologies Highlights

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Detergent Technologies Highlights

yUOP and CEPSA are committed to continual improvementof Solid Bed Alkylation process technology

– Detal-Plus increases LAB production without additionalfeedstock need

– ZDA-2 lowers energy consumption and capital (new units)– Both new LAB complexes and existing Detal units

benefit from these improvements

yNew Detal-Plus process technologyincorporating HAB transalkylationand new alkylation catalyst wil lprovide licensees with:

– Reduced capital costs– Reduced operating costs

– Safe and reliable operations

Final Thoughts

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Final Thoughts

yThis has been a brief summary highlighting just a sampleof some key developments in UOP petrochemicalstechnologies

yUOP is committed to further improve our existing

technologies and we are actively developing newtechnologies to meet the future needs of petrochemicalsproducers

– Focus on safety

– Reliable performance and operation

– Greater economies of scale

– Improved feedstock uti lization

– Use of cost-advantaged feedstocks– Reduced environmental footprint

UOP 5556J-46

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