zapp precision metals gmbh medical alloys medical … · pure titanium grade 1 3.7025 pure titanium...

Zapp Precision Metals GmbH

MEDICAL ALLOYS

MEDICAL TECHNOLOGY

CONTENTS

03 MEDICAL ALLOYS

04 LOGISTICS AND QUALITY

05 PRODUCT PORTFOLIO

06 DELIVERY FORMS

07 SPECIAL IMPLANT MATERIALS

08 IMPLANT MATERIALS MADE OF

TITANIUM

09 MATERIALS FOR INSTRUMENTS

10 MATERIALS FOR INSTRUMENTS –

MARTENSITIC

11 SPECIAL MATERIALS FOR MEDICAL

AND DENTAL

12 ADDRESSES

/12 MEDICAL ALLOYS

SOLUTION PROVIDER MEDICAL ALLOYS

For decades now, the companies of the Zapp Group have

been supplying semi-finished metal products made of

stainless steel, titanium and titanium alloys, nickel and

cobalt-based alloys, as well as a large number of special

materials. Building on this experience with a view to

becoming a specialist in medical technology needs, the

alignment of MEDICAL ALLOYS’ organization is unique

to the steel industry: it concentrates exclusively on your

metal semi-finished product requirements. Our staff

provides you with expert support to help you select the

ideal material for your specific application. Across the

complete spectrum of product forms – from wires, bars,

profiles, strips and sheets to tubes – we offer a compre-

hensive, continuously expanding range of material

solutions comprising our own products as well as trade

activities.

YOUR PURCHASING DEPARTMENT BENEFITS

Along with our extremely broad product portfolio we are

able to offer you the technical service and development

capabilities of an established manufacturer, saving you the

time and expense of a long search for the right partner.

Joint developments to address special requirements are

part of our everyday business. Take advantage of our

expertise:

_ Comprehensive application engineering support from

the initial idea right through to serial production

_ Special material variants created by combining material-

specific product characteristics and sophisticated pro-

cess engineering to induce particular mechanical/tech-

nological properties

_ A sales team trained in commercial technology to sup-

port your product selection process

MEDICAL ALLOYS

/12 MEDICAL ALLOYS | LOGISTICS AND QUALITY

LOGISTICS

The comprehensive distribution and logistics network of

the entire Zapp Group is your worldwide guarantee of

outstanding service and of the availability of our semi-

finished products. From America to Scandinavia to

China, in production facilities, service centers and sales

offices around the globe, our own staff and affiliated

partners are at your service to respond as quickly as

possible to your delivery requests. We overcome time-

consuming logistical obstacles through the continuous

expansion of our distribution network and service

centers. Selected partners ensure reliable transport over

land, air and sea to deliver our materials to your location

on-time. Express delivery services are also available for

direct delivery of samples and small lots to meet short-

term needs. We offer a wide range of packaging options

specifically designed to facilitate transport and protect

quality from the shipping department to the final

destination.

QUALITY

Products made to satisfy the highest quality demands form

the core of our corporate philosophy. It takes raw materi-

als from qualified production sources to manufacture safe

and reliable products for the medical and dental industry.

Zapp guarantees documented product traceability from

the original melt right through to the final semi-finished

product. The systematic archiving of documentation and

retention samples enables us to assure you unequivocally

of the quality of our products, even decades later.

And, thanks to our expert staff’s many years of experience

in research, development and manufacturing, we offer un-

surpassed product reliability that satisfies the extremely

sensitive demands placed on medical semi-finished pro-

ducts. We combine validated manufacturing processes

with integrated test technology and continuous monitor-

ing by our own trained team of specialists to maintain

these high material quality standards. Our products are

clearly designed to meet your specifications and comply

with qualitative requirements from the relevant standards

for medical semi-finished products. Beyond regulatory

requirements, the highest quality levels are achieved

through specifically targeted chemical compositions in

combination with highly specialized process engineering

technology.

LOGISTICS AND QUALITY

CERTIFIED TO ISO 9001

/12 MEDICAL ALLOYS | PRODUCT PORTFOLIO

THESE ALLOYS

Special Implant Materials

Austenite, AISI 316LVM 1.4441

Austenite, Alloy 734 1.4472

Austenite, nickel free 9.9007

Co-Ni-Cr-Mo-Alloy, Implant 9.9035

Co-Cr-Mo, Forging Alloy 9.9135

Co-Cr-W-Ni-Alloy 2.4964HL

Pure Titanium grade 1 3.7025




Titanium Alloy Ti6AL4V ELI 3.7165

Titanium Alloy Ti15Mo 9.9150

Titanium Alloy Ti6AlNb7 9.9367

Instrument grades

Martensite 13 % Cr, AISI 420A 1.4021

Martensite 13 % Cr, AISI 420B 1.4028

Martensite 13 % Cr, AISI 420X 1.4031

Martensite 13 % Cr, AISI 420C 1.4034

Martensite 13 % Cr, AISI 420C (+S) 1.4035

Martensite 13 % Cr, AISI 420F mod. 1.4197

Martensite 17 % Cr, AISI 430F 1.4104

Martensite 17 % Cr, AISI 431 1.4057

Martensite 17 % Cr, AISI 440A 9.9440

Martensite 17 % Cr, AISI 440B 1.4112

Martensite 17 % Cr 1.4122

Martensite 17 % Cr, AISI 440C 1.4125

Precipitation hardenable steels

Special Alloy 17-4-PH 1.4542

Special Alloy 17-7-PH 1.4568

Special Alloy XM-16, Alloy 455 1.4543

Austenite 1.4310

Special materials

Austenite, nickel-free 1.4456

Co-Ni-Cr-Mo-Alloy, dental 9.9035

Ferrite 1.4105

Austenite 1.4301

Austenite 1.4303

Austenite 1.4305

Austenite 1.4306

Austenite 1.4571

DEVELOPED AND MANUFACTURED FOR YOU

Bars

0.7 - 100 mm

drawn, peeled, ground, polished

chamfered, centered, pointed

annealed, cold worked, stress released

straightness 0.5 mm/m on demand up to 0.2 mm/m

special surface roughness up to Ra < 0.3 µm

ISO 286-2 in tolerances ISO h11 to ISO h05

integrated crack detection

Fine Wire and Premium Wire

0.07 – 20 mm

bright drawn, diamond drawn, specially coated

ISO 286-2 in tolerances ISO h11 to ISO h05

crack detected products

Profiles

0.3 x 0.3 mm – 63 x 6.35 mm

milled, rolled, drawn

dull, bright, extreme bright

square, hexagonal, octagonal

½, ⅓ and ¼ tube

implant-special shapes

»near net shape«

precision profile according drawing

water-jet-cut blank

Precision Strip

thickness from 0.02 – 2.50 mm

width from 2 – 1066 mm

sheets up to 6.00 mm thickness

cold worked, final annealed

tempered

Plates

square or in circular blanks

water-jet-cut

Tubes

thin-walled, seamless < 20 mm

drawn, ground

FOR YOUR APPLICATION

bone screw

bone nail

bone plate

intra-medullary nail

joint replacement

shoulder, hip, knee

spinal implant

endoprosthesis

dental implant

maxillofacial surgery

vascular surgery

cerclage

fixation system

surgical needle

instrument

bone saw

abrasor

rotating instrument

dental burr

dental cutter

orthodontic brace

scalpel

scissors

laboratory equipment

stamping and bending part

MEDICAL ALLOYS – PRODUCT PORTFOLIO

/12 MEDICAL ALLOYS | DEL IVERY FORMS

WIRE

in coils, on metal carriers,

in barrels, on spools

PREMIUM WIRE

in barrels,

on spools

BAR

in commercial lengths,

in special lengths

PROFILE

in coils, in bars,

on spools

PRECISION STRIP

in coils, on spools,

in straightened bars,

in sheets

PLATES


tailor made

BLANKS

in defined geometries,

in circular blanks, tailor made

TUBES


in special lengths

DELIVERY FORMS

/12 MEDICAL ALLOYS | SPECIAL IMPLANTAT MATER IALS

OUTSTANDING QUALITY ADVANTAGES

_ large and product-based selection of steel materials,

non-ferrous metals, pure titanium and titanium alloys

_ chemical compositions in compliance with the

requirements of listed national and international

standards

_ inducement of customer-specific material properties

through precisely targeted chemical analysis and

special manufacturing processes

_ guarantee of optimized properties relative to corrosion

(high PRE), bio-compatibility, fatigue strength and slag

purity in re-melted materials

_ substitution of nickel (by manganese and nitrogen) in

special nickel-free materials for use with patients who

have nickel allergies

_ extremely high corrosion resistance through the use of

special cobalt-based alloys

SPECIAL IMPLANT MATERIALS

Brand Name Material- Chemical Composition (Mass-%)

norms C Si Mn P S Cr Ni Mo Nb Cu N Fe

Ergste® 1.4441LA ASTM F138

ASTM F139

ISO 5832-1

min.

max.

0.030

0.75

2.00

0.025

0.01

17.00

19.00

13.00

15.00

2.25

3.00

-

0.50

0.10

bal

Ergste® 1.4472RN ASTM F1586

ISO 5832-9

min.

max.

0.080

0.75

2.00

4.25

0.025

0.01

19.50

22.00

9.00

11.00

2.00

3.00

0.25

0.80

0.25

0.25

0.50

bal

Ergste® 9.9007CN ASTM F2581

min.

max.

0.15

0.25

0.20

0.60

9.50

12.50

0.020

0.01

16.50

18.00

0.05

2.70

3.70

-

0.25

0.45

0.55

bal

Ergste® 1.4456CA Zapp-

Special Analysis

min.

max.

0.10

1.00

16.00

20.00

0.05

0.05

16.00

20.00

0.20

1.80

2.50

- -

< 0.1

bal


norms C Si Mn P S Cr Ni Mo W Fe Ti N Co

Ergste® 9.9035 ASTM F562

ISO 5832-6

min.

max.

0.025

0.15

0.15

0.015

0.01

19.00

21.00

33.00

37.00

9.00

10.50

-

1.00

1.00

- bal

Ergiloy® 9.9135HL ASTM F1537

(Alloy 1)

ISO 5832-12

(Low C)

min.

max.

0.14

1.00

1.00

-

-

26.00

30.00

1.00

5.00

7.00

-

0.75

-

0.25

bal

Ergiloy® 2.4964HL ASTM F90

ISO 5832-5

min.

max.

0.15

0.40

2.00

0.04

0.030

19.00

21.00

9.00

11.00

-

14.00

16.00

3.00

-

- bal

SPECIAL IMPLANT MATERIALS

/12 MEDICAL ALLOYS | IMPLANT MATERIALS MADE OF TITANIUM


_ customized product range for medical devices and

dental implants, pure titanium grades 1,2,3,4, re-

melted TiAl6V4, Ti-15Mo, TiA6lNb7

_ complete range of hardnesses and grain structures –

from work hardened to final annealed

_ improved mechanical technological properties

through sophisticated process engineering, e.g. with

pure titanium to increase fatigue strength

_ improved corrosion resistance properties through

special Titanium-Molybdenum-Alloys

_ Micro structural modification with extra fine grain size

to promote special characteristics in the final product

_ From production and ex-warehouse: tightest tolerances,

above-average straightness characteristics and the

highest surface conditions

_ outstanding bio-compatibility

IMPLANT MATERIALS MADE OF TITANIUM


norms C Fe O H N Al V Mo Nb Ti

Ergitan® 3.7025MG ASTM F67

ISO 5832-2

min.

max.

0.080

0.20

0.18

0.0125

0.03

- - -

-

bal


ISO 5832-2

min.

max.

0.080

0.30

0.25

0.0125

0.03

-

- - - bal


ISO 5832-2

min.

max.

0.080

0.30

0.35

0.0125

0.05

-

- - - bal


ISO 5832-2

min.

max.

0.080

0.50

0.40

0.0125

0.05

-

- - - bal


ISO 5832-3

min.

max.

0.080

0.25

0.13

0.0120

0.05

5.5

6.5

3.5

4.5

- - bal


ISO 5832-14

min.

max.

0.100

0.10

0.20

0.0150

0.05

- - 14.0

16.0

- bal


ISO 5832-11

min.

max.

0.080

0.25

0.20

0.0090

0.05

5.5

6.5

- - 6.5

7.5

bal

IMPLANT MATERIALS MADE OF TITANIUM

/12 MEDICAL ALLOYS | MATERIALS FOR INSTRUMENTS


_ greatest possible variety of hardenable and temperable

materials to match the broad spectrum of instruments,

mainly for use and applications within the ASTM F 899

_ increased corrosion resistance of grades with 17 %-

chromium content versus grades with 13 %-chromium

_ best corrosion resistance of martensitic grades based

on the combination of precision ground surface and

induration process

_ optimal machinability with slight loss of corrosion

resistance in materials containing sulfur

_ from production ex-warehouse, especially for rotating

instruments: tightest tolerances, above-average

straightness characteristics and highest surface

conditions

_ special high-tech-grades for surgical needles, bone saws,

orthodontic braces, reamer and files, burrs, cutters, and

much more

_ unique special materials, e.g. garde1.4310FE (re-melted),

1.4034YK (high chromium content), or 1.4028MO(+Mo)

MARTENSITIC GRADES

1.4035 +S

1.4197 +S

1.4034

1.4028

1.4021

1.4125 +S

1.4112 +S

9.9440

1.4125

1.4112

1.4057

1.4122

1.4543

1.4542

1.4568

1.4310

1.4031 +S

1.4123

Ha

rde

na

bil

ity*

Corrosion resistance

13 % Chrome 17 % Chrome Precipitation hardenable austenitic steels

MATERIALS FOR INSTRUMENTS

* hardness according to specific heat treatment from the solution annealed condition

/12 MEDICAL ALLOYS | MATERIALS FOR INSTRUMENTS - MARTENSITIC

MATERIALS FOR INSTRUMENTS - MARTENSITIC

Brand Name Type ∼ Chemical Composition (Mass-%)

C Si Mn P S Cr Ni Mo N Typical Application

Ergste® 1.4021YB AISI 420A min.

max.

0.16

0.25

1.00

1.00

0.040

0.030

12.00

14.00

1.00

- Instruments, abrasors

Ergste® 1.4028YN AISI 420B min.

max.

0.26

0.35

1.00

1.50

0.040

0.030

12.00

14.00

-

- Bone saws, rotating

instruments, cutter

Ergste® 1.4028MO AISI 420B

(+Mo)

min.

max.

0.34

0.38

1.00

1.00

0.040

0.030

13.00

14.00

- 0.90

1.10

Instruments, abrasors,

bone saws

Ergste® 1.4031YC AISI 420X min.

max.

0.36

0.42

1.00

1.00

0.040

0.030

12.50

14.50

- - Surgical needles

Ergste® 1.4034YN AISI 420C min.

max.

0.42

0.50

1.00

1.00

0.040

0.030

12.50

14.50

1.00

- Instrument handholds,

abrasors, cutter

Ergste® 1.4034YK AISI 420C min.

max.

0.43

0.50

1.00

1.00

0.040

0.030

13.00

14.50

1.00

- Instrument handholds,

abrasors, burrs

Ergste® 1.4035YU AISI 420C

(+S)

min.

max.

0.43

0.50

1.00

1.00

0.040

0.15

0.30

12.50

14.50

1.00

- Precision instruments,

cutter

Ergste® 1.4108 - min.

max.

0,28

0,34

0,30

0,80

0,30

0,60

0,020

0,010

14,50

16,00

- 0,95

1,10

0,30

Drills, screwdrivers, chisels,

Saw blades, cutting tools

Ergste® 1.4197YU AISI 420F

mod.

min.

max.

0.20

0.26

1.00

2.00

0.040

0.15

0.27

12.50

14.00

0.75

1.50

1.00

1.50

Dental burrs, dental cutter,

surgical needles

Ergste® 1.4104YU AISI 430F min.

max.

0.10

0.17

1.00

1.50

0.040

0.15

0.35

15.50

17.50

- - Instrument handholds

Ergste® 1.4057YN AISI 431 min.

max.

0.12

0.22

1.00

1.50

0.040

0.030

15.50

17.00

1.50

2.50

- Medical instruments,

cutting tools

Ergste® 9.9440YA AISI 440A min.

max.

0.60

0.75

1.00

1.00

0.040

0.030

16.00

18.00

-

0.75

Dental applications, dental

instruments, surgical

instruments

Ergste® 1.4112YL AISI 440B min.

max.

0.75

0.95

1.00

1.00

0.040

0.030

17.00

19.00

- 0.95

1.30

Instrument parts, scalpels

Ergste® 1.4122YL - min.

max.

0.33

0.45

1.00

1.50

0.040

0.030

15.50

17.50

1.00

0.80

1.30

Chisels, abrasors, cutting

instruments

Ergste® 1.4123YL

(X15-TN)

- min.

max.

0.35

0.50

1.00

1.00

0.040

0.015

14.00

16.00

0.50

1.00

2.50

Burrs, cutter, reamer,

screwdrivers

Ergste® 1.4125YL AISI 440C min.

max.

0.95

1.20

1.00

1.00

0.040

0.030

16.00

18.00

-

0.40

0.80

Surgical instruments, blades

MATERIALS FOR INSTRUMENTS –

MARTENSITIC

/12 MEDICAL ALLOYS | SPECIAL MATERIALS

OUTSTANDING QUALITY ADVANTAGES –

PRECIPITATION-HARDENABLE MATERIALS

_ The hardenable austenitic steels are characterized by

increased corrosion resistance with generally lower

hardenability potential versus martensitic steels.

.

PRECIPITAION-HARDENABLE MATERIALS FOR MEDICAL AND DENTAL

Brand Name Type Chemical Composition (Mass-%)

C Si Mn P S Cr Ni Mo Ti Al Cu Nb

Ergste® 1.4310FB

Ergste® 1.4310FE*

AISI 301

min.

max.

0.05

0.15

1.20

2.00

0.045

0.030

16.00

19.00

8.00

10.00

- - - - -

Ergste® 1.4542GG AISI 630

17-4-PH

min.

max.

0.07

1.00

1.00

0.040

0.030

15.00

17.50

3.00

5.00

- - - 3.00

5.00

0.15

0.45

Ergste® 1.4568GA AISI 631

17-7-PH

min.

max.

0.09

1.00

1.00

0.040

0.030

16.00

18.00

6.50

7.75

- - 0.75

1.50

- -

Ergste® 1.4543GG

(Alloy 455)

XM-16 min.

max.

0.03

0.50

0.50

0.015

0.015

11.00

12.50

7.50

9.50

0.50

0.90

1.40

-

1.50

2.50

0.10

0.50

OUTSTANDING QUALITY ADVANTAGES –

MATERIALS FOR MEDICAL AND DENTAL

_ Derived over many years market analysis and develop-

ment work, the advanced properties of these special

materials are far superior to those of conventional

commercial grades.

SPECIAL MATERIALS FOR MEDICAL AND DENTAL

Brand Name Type Chemical Composition (Mass-%)

C Si Mn P S Cr Ni Mo Typical Application

Ergste® 1.4310FB

Ergste® 1.4310FE*

AISI 301

min.

max.

0.05

0.15

1.20

2.00

0.045

0.030

16.00

19.00

8.00

10.00

- High-strength wire, root canal-

files, dental instruments

Ergste® 1.4456CA

min.

max.

0.10

1.00

16.00

20.00

0.050

0.050

16.00

20.00

0.20

1.80

2.50

Nickel-free dental wire,

surgical needles

Ergste® 9.9035

MP-35-N min.

max.

0.025

0.15

0.15

0.015

0.01

19.00

21.00

33.00

37.00

9.00

10.50

Orthodontic wire

Ergste® 1.4105IU

AISI 430F min.

max.

0.08

1.50

1.50

0.040

0.15

0.35

16.00

18.00

- - Shafts for rotating instruments

Ergste® 1.4303SA

AISI 305(L) min.

max.

0.06

1.00

2.00

0.045

0.030

17.00

19.00

11.00

13.00

- Dental applications made by

precision strip

Ergste® 1.4305UA

AISI 303 min.

max.

0.12

1.00

2.00

0.060

0.15

0.35

17.00

19.00

8.00

10.00

0.70

Surgical instruments, dental

instruments, parts for braces

* re-melted grade

SPECIAL MATERIALS

FOR MEDICAL AND DENTAL

/12 MEDICAL ALLOYS | ADDRESSES

MEDICAL TECHNOLOGY

Zapp Precision Metals GmbH

MEDICAL ALLOYS

Letmather Straße 69

58239 Schwerte

P.O. BOX 17 20

58212 Schwerte

Germany

Phone +49 2304 79-7259

Fax +49 2304 79-482

[email protected]

Zapp (GB) Ltd.

Unit 1 The Thorncliffe Distribution Centre

Brookdale Road

Chapeltown

Sheffield, S35 2PW

United Kingdom

Phone +44 1142 46-7823

Fax +44 1142 40-9647

[email protected]

Zapp Precision Wire, Inc.

475 International Circle

Summerville, South Carolina 29483

U.S.A.

Phone +1 843 851-0700

Fax +1 843 851-0010

Toll-free +1 888-777-3962

[email protected]

Service Centers | Sales Offices:

www.zapp.com

The illustrations, drawings, dimensional and weight data and other information included

in this brochure are intended only for the purposes of describing our products and

represent non-binding average values. They do not constitute quality data, nor can they

be used as the basis for any guarantee of quality or durability. The applications pre-

sented serve only as illustrations and can be construed neither as quality data nor as a

guarantee in relation to the suitability of the material. This cannot substitute for compre-

hensive consultation on the selection of our products and on their use in a specific

application. The brochure is not subject to change control.

Last revision: May 2018

zapp precision metals gmbh medical alloys medical … · pure titanium grade 1 3.7025 pure titanium...

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