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BUCKMAN LABORATORIES, INC. MATERIA~ SAFETY DATA SHEET ~ WSCP I Revisiondate: 11J3JfOO6 Buckman Laboratomes,Inc. I 1256 North McLean Boulevard '. I Memphis, TN 381O~ Phone 1-800-lnJCKMAN 24 Hour Emergency Phone: (901~767-2722 [[!:ECTION 1 I] I :::; I OSHA HAZARD CLASSIFICATIONS Irritating to eyes. '[SECTION 2 L H.AZ.ARiJo~s C~MPONENTS i Che1nlcal Name CAS Number % bv Wei1!ht . Based on best available ~nformation.this product doesnot eontain $ny'report$bleOSIJA hazardOl15materials. , I] ~ TLV SECTION 3 I FIRST AID INFORMATION .€:c!!. Flushim~ediatelY with copious amou~ts of tap water or normal saline (minimum <If15 . EXlJosure: minutes)f Take exposed individullito a health care professional~preferably an ophthalmologist, for further evaluation. . Inhalation: Wash exposed area with plenty of water. Repeat washing. Remove contaminated c10thing and wash tho'roughly before reuse. If irritation persists consult a bealth care profession,]. 1£expos~re by inhalation is suspected, immediately move exposed indiVIdual to fresp-tair. H indMdufl experiences nausea, headache, dizziness, has difficulty in breathing 0.. is !cyanotic, seek a ht1llithcare professional immediately. DO Not INDUCE VOMITING. Rinse with copious amounts of water or milk, fir8 i Irrigate the esop~agusand dilute stomach contents by slowlygiving one (1) to two (2) glass ofwater 0.. milk. Avbidgivingalcohol or akobolrelated products. In cases where the individu I is semi- comatost comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case intentional ingestio~of the product seek medical assistanceimmediately; take individual to ne rest medical facility. SM.!1. Ji;jgzosure: llfg,e:rtion: PRIMARY ROUTES OF EXPOSURE J ~ I SECTION 4 L 1. Effects from Acute fxposure: ~ SlightlY: bazardous incase of eye contact (irritant). ~XVosure: I I Skin Slightl)j hazardousin caseof skincontact(irritant). Non-sensitizer for skin. Sl' fdgJosure: inflamiation is characterized by itching, scaling,reddening, or, occasionally, blis1ering. USA WSCP ~~

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BUCKMAN LABORATORIES, INC.

MATERIA~ SAFETY DATA SHEET~

WSCPI

Revisiondate: 11J3JfOO6Buckman Laboratomes,Inc.I

1256 North McLean Boulevard'. I

Memphis, TN 381O~

Phone 1-800-lnJCKMAN

24 Hour Emergency Phone: (901~767-2722

[[!:ECTION 1 I]I:::;

I

OSHA HAZARD CLASSIFICATIONS

Irritating to eyes.

'[SECTION2 L H.AZ.ARiJo~s C~MPONENTSi

Che1nlcal Name CAS Number % bv Wei1!ht

. Based on best available ~nformation.this product does not eontain $ny'report$bleOSIJA hazardOl15materials.,

I]

~ TLV

SECTION 3 I FIRST AID INFORMATION

.€:c!!. Flushim~ediatelY with copious amou~ts of tap water or normal saline (minimum <If15 .

EXlJosure: minutes)f Take exposed individulli to a health care professional~preferably an ophthalmologist,for further evaluation. .

Inhalation:

Wash exposed area with plenty of water. Repeat washing. Remove contaminated c10thing andwash tho'roughly before reuse. If irritation persists consult a bealth care profession,].

1£expos~re by inhalation is suspected, immediately move exposed indiVIdual to fresp-tair. H

indMdufl experiences nausea, headache, dizziness, has difficulty in breathing 0.. is !cyanotic,seek a ht1llithcare professional immediately.

DO Not INDUCE VOMITING. Rinse with copious amounts of water or milk, fir8

iIrrigate

the esop~agusand dilute stomach contents by slowlygivingone (1) to two (2) glass ofwater 0..milk.Avbidgivingalcoholor akobolrelated products. In caseswhere the individu I is semi-comatost comatoseor convulsing,DO NOT GIVEFLUIDSBY MOUTH. In case intentionalingestio~of the product seek medical assistanceimmediately;take individual to ne rest medicalfacility.

SM.!1.Ji;jgzosure:

llfg,e:rtion:

PRIMARY ROUTES OF EXPOSURE J ~I SECTION 4 L

1. Effects fromAcute fxposure:~ SlightlY:bazardous incase of eye contact (irritant).~XVosure: I

I

Skin Slightl)jhazardousin caseofskincontact(irritant).Non-sensitizerforskin. Sl'fdgJosure: inflamiation is characterized by itching, scaling,reddening, or, occasionally,blis1ering.

USA WSCP

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Last revision ... 11/3/2006 I WSCP Pag~ :2, I

lnhalatiorz: sughtly

f

'hazaroous in case of inhalation. Effects W

,

ill depend on concentration and tength oftime of xposure.

InflestlOl/: Ingestio is not expected to be a primary route of exposure.

2. Effects from Chronic EXTJOSUTe;

'The effects fromchrhnic exposure to this product bave not been fully evaluated.

If SECTION5 i 'ToxicologicalInforma1io1tAcute Eff~C1S:

IAcute Oral (LD50);;; 19511nglkg Male ratAcute

I

Oral (LD50)= 2587 mglkg Female ratAcute Dermal (LD50)->2000 mglkg RabbitAcute I Inhalation(LC50)=2.9 ppm ( 4 bours) Rat

1 . IS .. . Ecl;rntant ensmzatlon :

. Slightly ardousin caseofeyecontact(irrItant).Slightlyh~ardous in case of skin contact (irritant). Non-sensitizer for skin. Skin iIammationis charact I . ed by itching, scaling, reddening, or, occasionally, blistering.

Slightly hrrdous in case of inhalation. Effects will depend on concentration and Ie h of timeI

of exposurj , '

CarCill()f!enicPotential: I ' ' " '"

. . Not tested by Buckman Laboratories. Not shownas a carcinogen by OS~ IARC, or~~ A twoyear rat ca~cinogenicity study showed a slight increase in c-cell adenomas in female r s. Studieswith male r~ts and male and female mice did not show any evidence of carcinogenic r s{>onse.This prodU

1

't is not considered a carcinogen.Ta1'f!elOrI!ansEffects: "

May cause amageto the followingorgans: tipper respiratory tract, skin, eyes..

Other Health Effects:Noneknown. '

ISECTION 6 r EtniironmentaJ Toxicological Information

iLC50 = 0.37 mg/l 48 hours InvertebrateLC50 =0.26 rngll96 hburs Fathead minnowLC50 = 0.21 mgll96 hpurs Bluegill sunfishLC50 = 0.047 mg/196 hours Rainbow 1rOutLC50 = >600 mg/196 fuours Sheepshead minnowLC50"" 13 mg/l96 hoJrs Mysid shrimp

II SECJ'ION 7 L Physicaland ~hemicalPropertiesAppearance J Clear, pale yellowliquid

Odor m ~ Mild.Density 1.15 glcm3

Flash POIl/t ) Closed cup: >l000C (212°F).(Tagliabue.)

MeltinglFree'dhgPOlltl I<-16°C (3.2°F)BoJ[JngPoint""""""""""'r""" >100oC (212°F)

Solubility 1.., Easily soluble in cold water. Easily soluble in hot water.~

. I ]1

I]

USA WSCP

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LeISt -revision ... J 1/3/2006 WSCPPag13I

pH (NeaJ) i 7 [NeutraI.j

pH (100ppm in water)"""'-i'-- 6-7Vf)porPressure."""""""""T- Not available.oIlYPartition Coefficient..)... Not available.

Oxidizing/ReductngPrope1es. N?t a~anable.V{scosity"""""""""""""""]'"" Kinetic: 125 cSAdd/ilona/pH Information j pH (neat) =6.0- 8.0

NOTE: The phYSiCa11ata presented above are typical values and should not be construed as Specifitation$,1ISECTION 8 Fire and E.

Ji'Ja~a~/e.Limit$,: t.. Not available, .. .EJalngulshmgMedia Water fog,carbon dioxide, foam, dry chemIcal.

~pecia/Fireflght/ng I Fire--fightersshouldwear positivepressureself-containedbreathingaJ1paratusProced#.res""""""""""""",""(SeRA) and full turnout gear.

~SECTION 9 I 'Reactivity Information rStability l Stable under normal conditions of use and storage.

I .. IIncompatibility..,m : AniOniCpOrIDers'. I .'

~Z:~:~~~~~~~~~~~~.JCarbon monoxidemay be ior~ed upon burning.I

ii

~

SECTION 10 Hand/im! Precautions;

tEye-wash fountains in ,the work place are recommended. Rubber gloveS, safety glasses Or goggle and bodyproteciiye clothing anq shoes are required. The handling precautions for this product are based on thecharacteristics ofthe neat product unlessotherwise specified. . .

SECTION 1) Satisfactory Materials of Construction

Bllna-N robberButyl rubberPolypropylenePlexiglasTeflon.PVC -rigidVitonEPnM rubberPVC -flexibleFiberglass

Neoprene IPolyethylene -low d~nsityTYgon 'Tyril 880Gum rubber

.Silicone rubberHypalon I

Polyethylene -high density

Stainless steels 304 ard 316

USA WSCP

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Last r~vi$iDn ,.. 11/3/2006 W$CPPaget 4

ABS (plastic)Morton test liner (1OSIT44LV)6/6 NylonFRP lined mild steel

SECTION 12! Spill,Leak, andDisposalProceduresI

SPILL ANDLEAK RESPONSEGUIDELINES:I

Impor~nt: Before responding to a spill or leak ofthis product, review each section oftMs MSDS. Followthe recom

*ndations

2iven in the Handling Precautions sedions. Check tbe Fire and Explosion Data section to determine if the use oillon parking toolsis merited.Insurethat spiUbdor leakedproductdoesnotcomeintoCOntactwithmaterialslistedas incompatible.If i ritating .fumes are present, conside~evacuation of enclosed areas.

Emer2ency Response Assisrance:Emergency technical assistance i$available at any time from Buckman Laboratorits, Inc., bycaning (901) 767-2722. .

Initially minimi.z:e area affefted by the spill or leak. Block any potential routes to water systems (e.g.. sewers, stream, lakes, etc.).Based on the product's toxij:ol02ical and chemical properties, and on the size and location of the spill Or leak, :IIssess e impact oncontaminated environmentk (e.g. water systems, ground, air equipment, etc.). There are DOmethods available to' cO' Ictelyeliminate any toxicity this

~

Iroductmayhaveonaquaticenvironments.Minimizeadnr$(!effectsontheseenvironme ts. RuckmanLaborato,.;es, Inc. can be c ntacted for technical il$sistance. Determine if federal. state, and/or local release notifica on isrequired (seeRegulatory Coassificationssection af this MSDS).Recover as much of the pure product as possible int appropriatecontainers. Later, detefml~e if this recovered product can be used fO'rltsintended purpose. Address clean-up of con aminatedenvirO'nments.Spill or leaklresiduals may h:llveto be collected and disposed of. Clay, soil, or commercially available bsorbentsmay beuS,edto recover an)!material that can hot readily be recovered as pure prQduct.Flusbin~ residual material t an industrialsewer..if present at the site lora spill or leak incident, may be acceptable if authQrized approval is obtained. If prodo and/orspilIlleak residusls are flusfed to an industrial Sewer,insure that they do not come intO'contact with incompatible m tcrlals.CQntact the person(s) responsible far the operatian afyoor facility's industrial sewer system prior to intentionally n sbing arpumping spills or leaks Qfijbisproduct to the industrial sewer.

DISPOSAL GUIDELINEs!

Note: Fo}Jawfederal, s~teJand local regulations \:overning the disposal of wastematerials.

Neat Pi-oduct: Contact yoJ Buckman represeJttative or Buckman Laboratories, Inc., at (901)278-0330.I .

Contaminated Materials: ~etermine if wa$tecontainin~ this product can be handled by nailable Industrial efflllen

~

J'Aeh1or-,other on-sitewaste.manag~lJIentunit. If off-sitemanagement is required, CQntacta company (!:Jperlencedin industri I wastemanage)nent This produ~ Isnot specificallylisted in 40 CFR 261 as a Resource ConserVationand Recovery Act (R RA)hazardous waste. However:..spill or leak residuals may meet the cri1eria of a characteristic hazardous waste under t is Act. Checkthe characteristics of the ~aterial to be disposed of and/or the physical and reactivity data given in this MSDS for t neat'~~ .Container Disposal: Emptjr containers, as defined by appropriate sections Qftbe RCllA, are nQt ReRA hazardous )1J'I~~(:$.However. insure proper m~nagement of any residuals remaining in container.

SECTION 13 TransporlanonandSh'-

DOT Shipping Informana/!.

Not Regulated.

lMO/IMDGShippingIf/formation:I

UN3082 , ENVIRpNlVIENTALL Y HAZARDOUS SUBSTANCE, LIQUID, N.O.S., ( Poly[oltYethylene(dhnethyliminio)e!tbylene(din1ethyliminio)ethylenedichloride]), Class 9, P.G. ill, MARIrkEPOLLUTANT (EmS No. F-A, S-F. ERG Guide 171, HazMat Code 4960131)

. IUTA ShippingInforma1i4n:

Not Regulated.

USA WSCP

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Last revisicn ... J1/312006 I WSCP

-t--~ ~ ~ nn n____------------------------------------

DOT "RQ": NONE

pagj 5

Unless otherwise stated, the~hipping infomw.lion provided above applies only to non-bulk co"tldllers of this producL

~er shipping

name and general shipping 1nformaiion may vary depending on packaging and mode of shipment. All p'toducts shipped rom Buckman

locations have been proper1 p(1ckaged and labeled according to appropriate hazardous materials shipping regulations. anyaltet"fltJon of packaging, pro'(Juct,tJt"mDde oftransporlailon is further iI,rended, different shipping information, includin but not limitedto proper shipping name, R~ tjtlSignatton, and labeling may apply. FtJrfurther information pertaining to the shipping r quirements forthis prtJduct, contact Buckman's Transportation Department Or/)0 T CtJordinator.

[ SECTION 14 j. Ref(ulat°l'! Information 1 III

The following Regulat~ons are Imown to apply to the use and disposal Qfthis product. Additiona~ Federal,State and Local reguWtionsmay also be applicable. . .I

SARA Su er undAtn Indments and Reauthorizatwn A tSARA 301ExtremelyIf arOOusSubstancesL/$t...

No component~ of this product are listed.SARA 312 RQ1.at"d CatE!gJ", --

:Immediate (ACi'Ute)Health HazardSARA 3JJ Toxic Chemickls List ...

No comp()nent~ ofthis product are present above tbe de minimus levels.

CERCLA (Comprehenkive Environmental Response. Compensation and Liabilitv Act)

. No componentfof this product are present abovethe deminimus levels.RCM (Resource ConJersadon and Recovery Act) Listed Hazardous Waste

No component~ of this product are listed.I

CWA (Clean Water Act) Listed SI/.bstances

No component~ of this product are listed.

FDA (Food and DrJ Adminisf1'ation)Tbis product is not anproved for food COntactuses.

National Sanitation FJundation(NSF) .

This product ~ listed by the NSF under NSF/ANSI Standard 60 for use in potable wate

~PPlications

with the follo~ing maximum aHowable use rates: Concentrations of 2-5 ppm can be u at theinitiation oftr atment for up to 21 days. Thereafter, the muirnumuse rate is 0.5 ppm Ii potablewater systems.

TSCA (Toxic Suhstan es Control Act A licahiliiAIl componenits may not be listed on the TSCA Inventory. Registered pesticides are e:xe..nt from the

requirementsrfTSCA. .FIF"RA {Federal Insecticide. Fum?icide. (lltd Rodenticide Act)

This product ~sa registered pestidde. EPA Reg. No. 1448-32I

Hk11S/NPCARatin!!.J. Health 1 Flammability1 Reactivity0

NF"PARatings lH~th 1 Flammability 1 Reactivity 0 .

State Ref!ll/ations I

. VariousState Right ToKnowActs ...Non-proprieiary hazardous che:micals are listed in Section 2 of this MSDS. Should you tequirefurtber inforp.ation on specificproprietary or inert ingredients please contact Buckmab .

Laboratorie~t Regulatory Mfairs Depart:ment

USA WSCP

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LCJst 'revision... Il/312006 I

iII

WSCP Pag 6

,.The information on this Material Safety Data Sheet reflects the latest information and data that we ha'\le On ha2:ards, pro

[rnes,and

handliojl ofthis prodlJct IJhder tbe r~ommended conditions of use. An)' use olthis pmdl1d or method ofapplication whic is notdescribed in the :DataShett is the responsibility of tbe u.er. This Mater!al Data SlIt",ty She",. was prepared t() c()mplywit the OSHAHazard Communication rfgulations. While some components are claimed Trade Secret under OSlIA H~rd Communica 'onregulations, all known OSHA hazards assocIated with the Trade Secret component(s), if contained in this product, are fill disclosed.I

Buckman Laboratorie&, IJc. warrants that this product conforms to its chemical description and is reasonably fit for the ~urpo$ereferred to in the dir~tiorys for use when used in accordance with the directions under nbrmal conditIOn$.Jl1Jyerassumes ~he risk of anyuse:contrnij' to such dlrec~on$. .

Seller makes no othe.. waJ~r:a.n2'or representation of any kind, express or implied, concernil"lgthe product, Including NOt LIEDWARRANTY OF MERCF." TABILJTY OR FITNESS OF THE GOODS FOR ANY OTIffiR fARTICULAR PDnPO E. No sucllwarranties shall be implie~ by law an(}no agent of sener is autho..lzed to alter this warranty in any way except in writing ith a s~ecificreference to this warranty,.

The exdusive remedy aga0st seHer shall be IJ1a claim for damages not to exceed the purchase price otthe product, wJtho+t regard to

whether such a claim is biStd upon breach of warranty or tort.

Any contrO'\l.:r:!)'Or daim brMng OutOr relating tb this contract, or breach tbereof, shall be settle by arbitratIon in accordlmce with thecommercial arbitration ru~esoCtIleAmerican Arbitration Association, and judgement upon the rendered by the Arbitrat¥,) may be

entered in any COllrthavi1&jurisdlction thereof.