wild for innovation: nanotechnology at unh - innovative science in support of next generation...

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Nanotechnology at UNH: Innovative Science In Support of Next Generation Consumer Products Glen P. Miller Department of Chemistry and Materials Science Program University of New Hampshire Wild For Innovation Friday, March 5, 2010

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On March 5th, 2010 the UNH Wildcats, Whittemore School of Business, New Hampshire Division of Economic Development and Public Service of New Hampshire hosted a unique afternoon workshop at UNH aimed at building teams, developing effective leaders and stimulating innovation. The "Wild for Innovation" workshop was developed specifically for New Hampshire business leaders and their teams, and included presentations like this one, on nanotechnology research at UNH and science in support of next-gen consumer products, by Glen Miller.

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Page 1: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Nanotechnology at UNH: Innovative Science In Support of Next

Generation Consumer Products

Glen P. Miller Department of Chemistry and Materials Science Program

University of New Hampshire

Wild For InnovationFriday, March 5, 2010

Page 2: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

S

S

I

polymer

Active Layer(PCBM + P3HT)

Al

Solar light

I

polymer

Active Layer(PCBM + P3HT)

Al

Solar light

Application Road Map

NanoelementsThrust I

Acenes

Funct.Fullerenes

Funct. CNTs& Graphene

Nanocups &Nanorings

OFETs, OLEDs

Organic Photovoltaics

Nanotemplates

FlexibleElectronics

Polymer composites,

EMI Shielding

Interconnects

Structural & Electronic Mat’s

Cyclacenes & Uniform SWNTs

Page 3: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

An Example: Carbon Nanotube Memory Chip

2

ON state

OFF state

In principle… In reality…

Related Applications: SWNT Switches, Sensors, Transistor Arrays

Page 4: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Q: How Can We Achieve Addressable Sites Based on 1 CNT (required to make highest

density memory chips)

A: Chemical Functionalization

Page 5: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Initial Result: Hydrogenation of C60 Buckminsterfullerene

Work Performed at UNH for Collaborators at Northrup Grumman

Page 6: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Northrup Grumman Wanted a Faster, Scalable Process

Innovation: Use Microwave Reactor Reduce Total Reaction Time to 5 minutes

Page 7: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Before Hydrogenation After Hydrogenation

Innovation: Apply Same Chemistry to SWNTs Highly Dispersed Species

Page 8: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

30 Seconds 5 Minutes

1 Hour 2 Days

Functionalized SWNTs Stay Well Dispersed Without Added Surfactant

H-SWNTs

H-SWNTs

H-SWNTs

H-SWNTs

SWNTs SWNTs

SWNTs SWNTs

Page 9: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Carbon Nanotube Memory Chip2

ON state

OFF state

In principle… In reality…

Related Applications: SWNT Switches, Sensors, Transistor Arrays

Page 10: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

Carbon nanotubes assembled from solution

Nanomanufacturing with Templates

Page 11: Wild for Innovation: Nanotechnology at UNH - Innovative Science In Support of Next Generation Consumer Products

S

S

I

polymer

Active Layer(PCBM + P3HT)

Al

Solar light

I

polymer

Active Layer(PCBM + P3HT)

Al

Solar light

Application Road Map

NanoelementsThrust I

Acenes

Funct.Fullerenes

Funct. CNTs& Graphene

Nanocups &Nanorings

OFETs, OLEDs

Organic Photovoltaics

Nanotemplates

FlexibleElectronics

Polymer composites,

EMI Shielding

Interconnects

Structural & Electronic Mat’s

Cyclacenes & Uniform SWNTs