westinghouse hematite decommissioning project - final status … · 2017. 9. 19. · ivan h vania,...

ANALYTICAL REPORT

Job Number: 160-19949-1

Job Description: HDP RFP-CBA-022 (21 DAY TAT)

For:Westinghouse Electric Company LLC

3300 State Road PFestus, MO 63028

Attention: Mr. Martin Swanson

_____________________________________________

Approved for release.Rhonda E RidenhowerManager of Project Management11/21/2016 2:02 PM

Designee forIvan H Vania, Project Manager II

13715 Rider Trail North, Earth City, MO, 63045(314)298-8566

[email protected]/21/2016

The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. Pursuant toNELAP, this report shall not be reproduced, except in full, without the written approval of the laboratory. This report isconfidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should bedirected to the TestAmerica Project Manager.

Louisiana Lab Certification ID (Non-Potable, Solid/Haz. Material): 106151Florida Lab Certification ID (Drinking Water): E87689.

TestAmerica Laboratories, Inc.TestAmerica St. Louis 13715 Rider Trail North, Earth City, MO 63045Tel (314) 298-8566 Fax (314) 298-8757 www.testamericainc.com

11/21/2016Page 1 of 150

mailto:[email protected]://www.testamericainc.comhttp://

Table of ContentsCover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

Method 8260C Low Level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41Method 8260C Low Level QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42Method 8260C Low Level Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56

Method 8260C Low Level ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56Method 8260C Low Level CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101

Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115Method 8260C Low Level Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115Method 8260C Low Level Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125

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Table of ContentsMethod 8260C Low Level LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132

Method 8260C Low Level Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146

Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 148Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150

11/21/2016Page 3 of 150

Definitions/GlossaryTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC

Project/Site: HDP RFP-CBA-022 (21 DAY TAT)

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica St. Louis

11/21/2016Page 4 of 150

CASE NARRATIVE

Client: Westinghouse Electric Company LLC

Project: HDP RFP-CBA-022 (21 DAY TAT)

Report Number: 160-19949-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.”

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPTThe samples were received on 11/10/2016; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 1.8 C.

VOLATILE ORGANIC COMPOUNDS (GC/MS)Sample PW-2 (160-19949-1) was analyzed for Volatile Organic Compounds (GC/MS) in accordance with EPA SW-846 Method 8260C. The samples were analyzed on 11/15/2016.

Batch 279202The following compounds did not meet the minimum relative response factor limits in the continuing calibration verification (CCV) associated with batch 279202: Acetone, 2- Butanone, n- Butanol, 4- Methyl- 2- pentanone, 2- Hexanone and 1,1,2,2- Tetrachloroethane. A low level CCV was analyzed at the reporting limit (1ug/L) and the affected analytes were detected. Target analytes recovering above the reporting limit will be qualified and reported. (CCVIS 160-279202/5)

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate (MS/MSD) associated with batch 279202. A LCS/LCSD were performed to demonstrate accuracy and replicate precision.PW-2 (160-19949-1)

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

11/21/2016Page 5 of 150

Client Sample ResultsTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


Lab Sample ID: 160-19949-1Client Sample ID: PW-2Matrix: WaterDate Collected: 11/08/16 15:50

Date Received: 11/10/16 11:05

Method: 8260C - Volatile Organic Compounds (GC/MS)RL MDL

1,1,1-Trichloroethane ND 1.0 0.17 ug/L 11/15/16 12:55 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

1.0 0.10 ug/L 11/15/16 12:55 11,1,2,2-Tetrachloroethane ND

1.0 0.13 ug/L 11/15/16 12:55 11,1,2-Trichloroethane ND

1.0 0.10 ug/L 11/15/16 12:55 11,1-Dichloroethene ND

1.0 0.070 ug/L 11/15/16 12:55 11,1-Dichloroethane ND

1.0 0.10 ug/L 11/15/16 12:55 11,2,4-Trichlorobenzene ND

1.0 0.41 ug/L 11/15/16 12:55 11,2-Dibromo-3-Chloropropane ND

1.0 0.22 ug/L 11/15/16 12:55 11,2-Dichloroethane ND

2.0 0.14 ug/L 11/15/16 12:55 11,2-Dichloroethene, Total ND

1.0 0.10 ug/L 11/15/16 12:55 11,2-Dichloropropane ND

5.0 0.47 ug/L 11/15/16 12:55 12-Butanone ND

5.0 0.25 ug/L 11/15/16 12:55 12-Hexanone ND

5.0 0.22 ug/L 11/15/16 12:55 14-Methyl-2-pentanone ND

2.0 0.55 ug/L 11/15/16 12:55 1Acetone ND

1.0 0.10 ug/L 11/15/16 12:55 1Benzene ND

1.0 0.17 ug/L 11/15/16 12:55 1Bromoform ND

2.0 0.25 ug/L 11/15/16 12:55 1Methyl bromide ND

1.0 0.10 ug/L 11/15/16 12:55 1Carbon disulfide ND

1.0 0.18 ug/L 11/15/16 12:55 1Carbon tetrachloride ND

1.0 0.11 ug/L 11/15/16 12:55 1Chlorobenzene ND

1.0 0.14 ug/L 11/15/16 12:55 1Chlorodibromomethane ND

2.0 0.16 ug/L 11/15/16 12:55 1Chloroethane ND

1.0 0.10 ug/L 11/15/16 12:55 1Chloroform ND

2.0 0.10 ug/L 11/15/16 12:55 1Chloromethane ND

1.0 0.10 ug/L 11/15/16 12:55 1cis-1,2-Dichloroethene ND

1.0 0.16 ug/L 11/15/16 12:55 1cis-1,3-Dichloropropene ND

1.0 0.14 ug/L 11/15/16 12:55 1Bromodichloromethane ND

1.0 0.12 ug/L 11/15/16 12:55 1Ethylbenzene ND

1.0 0.13 ug/L 11/15/16 12:55 11,2-Dibromoethane ND

1.0 0.27 ug/L 11/15/16 12:55 1Methylene Chloride ND

50 12 ug/L 11/15/16 12:55 1n-Butanol ND

1.0 0.13 ug/L 11/15/16 12:55 1Styrene ND

1.0 0.18 ug/L 11/15/16 12:55 1Tetrachloroethene ND

1.0 0.14 ug/L 11/15/16 12:55 1Toluene ND

1.0 0.10 ug/L 11/15/16 12:55 1trans-1,2-Dichloroethene ND

1.0 0.10 ug/L 11/15/16 12:55 1trans-1,3-Dichloropropene ND

1.0 0.25 ug/L 11/15/16 12:55 1Trichloroethene ND

2.0 0.18 ug/L 11/15/16 12:55 1Vinyl acetate ND

2.0 0.19 ug/L 11/15/16 12:55 1Vinyl chloride ND

3.0 0.27 ug/L 11/15/16 12:55 1Xylenes, Total ND

1,2-Dichloroethane-d4 (Surr) 97 75 - 129 11/15/16 12:55 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 108 11/15/16 12:55 181 - 130

Dibromofluoromethane (Surr) 100 11/15/16 12:55 181 - 124

Toluene-d8 (Surr) 107 11/15/16 12:55 187 - 128


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Surrogate SummaryTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


Method: 8260C - Volatile Organic Compounds (GC/MS)Prep Type: Total/NAMatrix: Water

Lab Sample ID Client Sample ID (75-129) (81-130) (81-124) (87-128)

12DCE BFB DBFM TOL

97 108 100 107160-19949-1

Percent Surrogate Recovery (Acceptance Limits)

PW-2

97 100 97 102LCS 160-279202/6 Lab Control Sample

97 99 96 102LCSD 160-279202/7 Lab Control Sample Dup

98 121 97 113MB 160-279202/9 Method Blank

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

DBFM = Dibromofluoromethane (Surr)

TOL = Toluene-d8 (Surr)


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QC Sample ResultsTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


Method: 8260C - Volatile Organic Compounds (GC/MS)

Client Sample ID: Method BlankLab Sample ID: MB 160-279202/9Matrix: Water Prep Type: Total/NAAnalysis Batch: 279202

RL MDL

1,1,1-Trichloroethane ND 1.0 0.17 ug/L 11/15/16 08:57 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.101.0 ug/L 11/15/16 08:57 11,1,2,2-Tetrachloroethane

ND 0.131.0 ug/L 11/15/16 08:57 11,1,2-Trichloroethane

ND 0.101.0 ug/L 11/15/16 08:57 11,1-Dichloroethene

ND 0.0701.0 ug/L 11/15/16 08:57 11,1-Dichloroethane

ND 0.101.0 ug/L 11/15/16 08:57 11,2,4-Trichlorobenzene

ND 0.411.0 ug/L 11/15/16 08:57 11,2-Dibromo-3-Chloropropane

ND 0.221.0 ug/L 11/15/16 08:57 11,2-Dichloroethane

ND 0.142.0 ug/L 11/15/16 08:57 11,2-Dichloroethene, Total

ND 0.101.0 ug/L 11/15/16 08:57 11,2-Dichloropropane

ND 0.475.0 ug/L 11/15/16 08:57 12-Butanone

ND 0.255.0 ug/L 11/15/16 08:57 12-Hexanone

ND 0.225.0 ug/L 11/15/16 08:57 14-Methyl-2-pentanone

ND 0.552.0 ug/L 11/15/16 08:57 1Acetone

ND 0.101.0 ug/L 11/15/16 08:57 1Benzene

ND 0.171.0 ug/L 11/15/16 08:57 1Bromoform

ND 0.252.0 ug/L 11/15/16 08:57 1Methyl bromide

ND 0.101.0 ug/L 11/15/16 08:57 1Carbon disulfide

ND 0.181.0 ug/L 11/15/16 08:57 1Carbon tetrachloride

ND 0.111.0 ug/L 11/15/16 08:57 1Chlorobenzene

ND 0.141.0 ug/L 11/15/16 08:57 1Chlorodibromomethane

ND 0.162.0 ug/L 11/15/16 08:57 1Chloroethane

ND 0.101.0 ug/L 11/15/16 08:57 1Chloroform

ND 0.102.0 ug/L 11/15/16 08:57 1Chloromethane

ND 0.101.0 ug/L 11/15/16 08:57 1cis-1,2-Dichloroethene

ND 0.161.0 ug/L 11/15/16 08:57 1cis-1,3-Dichloropropene

ND 0.141.0 ug/L 11/15/16 08:57 1Bromodichloromethane

ND 0.121.0 ug/L 11/15/16 08:57 1Ethylbenzene

ND 0.131.0 ug/L 11/15/16 08:57 11,2-Dibromoethane

ND 0.271.0 ug/L 11/15/16 08:57 1Methylene Chloride

ND 1250 ug/L 11/15/16 08:57 1n-Butanol

ND 0.131.0 ug/L 11/15/16 08:57 1Styrene

ND 0.181.0 ug/L 11/15/16 08:57 1Tetrachloroethene

ND 0.141.0 ug/L 11/15/16 08:57 1Toluene

ND 0.101.0 ug/L 11/15/16 08:57 1trans-1,2-Dichloroethene

ND 0.101.0 ug/L 11/15/16 08:57 1trans-1,3-Dichloropropene

ND 0.251.0 ug/L 11/15/16 08:57 1Trichloroethene

ND 0.182.0 ug/L 11/15/16 08:57 1Vinyl acetate

ND 0.192.0 ug/L 11/15/16 08:57 1Vinyl chloride

ND 0.273.0 ug/L 11/15/16 08:57 1Xylenes, Total

1,2-Dichloroethane-d4 (Surr) 98 75 - 129 11/15/16 08:57 1

MB MB

Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery

121 11/15/16 08:57 14-Bromofluorobenzene (Surr) 81 - 130

97 11/15/16 08:57 1Dibromofluoromethane (Surr) 81 - 124

113 11/15/16 08:57 1Toluene-d8 (Surr) 87 - 128


11/21/2016Page 8 of 150



Method: 8260C - Volatile Organic Compounds (GC/MS) (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 160-279202/6Matrix: Water Prep Type: Total/NAAnalysis Batch: 279202

1,1,1-Trichloroethane 10.0 10.8 ug/L 108 85 - 116

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,1,2,2-Tetrachloroethane 10.0 9.11 ug/L 91 80 - 120

1,1,2-Trichloroethane 10.0 9.68 ug/L 97 80 - 120

1,1-Dichloroethene 10.0 11.0 ug/L 110 80 - 120

1,1-Dichloroethane 10.0 10.9 ug/L 109 80 - 120

1,2,4-Trichlorobenzene 10.0 9.95 ug/L 99 75 - 121

1,2-Dibromo-3-Chloropropane 10.0 9.07 ug/L 91 73 - 123

1,2-Dichloroethane 10.0 9.58 ug/L 96 80 - 115

1,2-Dichloroethene, Total 20.0 21.0 ug/L 105 80 - 120

1,2-Dichloropropane 10.0 10.7 ug/L 107 80 - 120

2-Butanone 10.0 9.11 ug/L 91 67 - 127

2-Hexanone 10.0 9.98 ug/L 100 70 - 123

4-Methyl-2-pentanone 10.0 9.64 ug/L 96 75 - 126

Acetone 10.0 9.68 ug/L 97 69 - 129

Benzene 10.0 10.9 ug/L 109 80 - 120

Bromoform 10.0 9.16 ug/L 92 80 - 120

Methyl bromide 10.0 10.5 ug/L 105 70 - 124

Carbon disulfide 10.0 11.9 ug/L 119 80 - 121

Carbon tetrachloride 10.0 10.6 ug/L 106 83 - 125

Chlorobenzene 10.0 10.5 ug/L 105 80 - 120

Chlorodibromomethane 10.0 9.09 ug/L 91 80 - 120

Chloroethane 10.0 11.2 ug/L 112 73 - 119

Chloroform 10.0 10.4 ug/L 104 80 - 120

Chloromethane 10.0 12.0 ug/L 120 72 - 124

cis-1,2-Dichloroethene 10.0 10.3 ug/L 103 80 - 120

cis-1,3-Dichloropropene 10.0 10.4 ug/L 104 80 - 120

Bromodichloromethane 10.0 9.81 ug/L 98 80 - 120

Ethylbenzene 10.0 11.5 ug/L 115 80 - 120

1,2-Dibromoethane 10.0 9.55 ug/L 96 80 - 120

Methylene Chloride 10.0 10.3 ug/L 103 80 - 120

n-Butanol 250 248 ug/L 99 62 - 128

Styrene 10.0 11.4 ug/L 114 81 - 133

Tetrachloroethene 10.0 10.6 ug/L 106 83 - 123

Toluene 10.0 11.3 ug/L 113 80 - 120

trans-1,2-Dichloroethene 10.0 10.7 ug/L 107 80 - 120

trans-1,3-Dichloropropene 10.0 10.7 ug/L 107 82 - 124

Trichloroethene 10.0 10.6 ug/L 106 80 - 120

Vinyl acetate 10.0 10.2 ug/L 102 63 - 140

Vinyl chloride 10.0 11.8 ug/L 118 77 - 122

1,2-Dichloroethane-d4 (Surr) 75 - 129

Surrogate

97

LCS LCS

Qualifier Limits%Recovery

1004-Bromofluorobenzene (Surr) 81 - 130

97Dibromofluoromethane (Surr) 81 - 124

102Toluene-d8 (Surr) 87 - 128


11/21/2016Page 9 of 150



Method: 8260C - Volatile Organic Compounds (GC/MS) (Continued)

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 160-279202/7Matrix: Water Prep Type: Total/NAAnalysis Batch: 279202

1,1,1-Trichloroethane 10.0 10.4 ug/L 104 85 - 116 3 20

Analyte

LCSD LCSD

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits LimitRPD

RPD

1,1,2,2-Tetrachloroethane 10.0 9.73 ug/L 97 80 - 120 7 20

1,1,2-Trichloroethane 10.0 10.2 ug/L 102 80 - 120 5 20

1,1-Dichloroethene 10.0 10.8 ug/L 108 80 - 120 2 20

1,1-Dichloroethane 10.0 10.4 ug/L 104 80 - 120 5 20

1,2,4-Trichlorobenzene 10.0 9.55 ug/L 95 75 - 121 4 20

1,2-Dibromo-3-Chloropropane 10.0 9.63 ug/L 96 73 - 123 6 20

1,2-Dichloroethane 10.0 9.72 ug/L 97 80 - 115 1 20

1,2-Dichloroethene, Total 20.0 20.9 ug/L 105 80 - 120 0 20

1,2-Dichloropropane 10.0 10.4 ug/L 104 80 - 120 3 20

2-Butanone 10.0 9.51 ug/L 95 67 - 127 4 20

2-Hexanone 10.0 9.52 ug/L 95 70 - 123 5 20

4-Methyl-2-pentanone 10.0 10.8 ug/L 108 75 - 126 12 20

Acetone 10.0 9.98 ug/L 100 69 - 129 3 20

Benzene 10.0 11.0 ug/L 110 80 - 120 1 20

Bromoform 10.0 9.29 ug/L 93 80 - 120 1 20

Methyl bromide 10.0 10.4 ug/L 104 70 - 124 1 20

Carbon disulfide 10.0 11.4 ug/L 114 80 - 121 4 20

Carbon tetrachloride 10.0 10.4 ug/L 104 83 - 125 1 20

Chlorobenzene 10.0 10.6 ug/L 106 80 - 120 0 20

Chlorodibromomethane 10.0 9.61 ug/L 96 80 - 120 6 20

Chloroethane 10.0 10.9 ug/L 109 73 - 119 2 20

Chloroform 10.0 9.68 ug/L 97 80 - 120 7 20

Chloromethane 10.0 11.7 ug/L 117 72 - 124 3 20

cis-1,2-Dichloroethene 10.0 10.2 ug/L 102 80 - 120 1 20

cis-1,3-Dichloropropene 10.0 10.4 ug/L 104 80 - 120 1 20

Bromodichloromethane 10.0 9.97 ug/L 100 80 - 120 2 20

Ethylbenzene 10.0 11.3 ug/L 113 80 - 120 2 20

1,2-Dibromoethane 10.0 9.97 ug/L 100 80 - 120 4 20

Methylene Chloride 10.0 9.94 ug/L 99 80 - 120 4 20

n-Butanol 250 267 ug/L 107 62 - 128 7 20

Styrene 10.0 11.6 ug/L 116 81 - 133 2 20

Tetrachloroethene 10.0 10.1 ug/L 101 83 - 123 5 20

Toluene 10.0 11.2 ug/L 112 80 - 120 0 20

trans-1,2-Dichloroethene 10.0 10.7 ug/L 107 80 - 120 1 20

trans-1,3-Dichloropropene 10.0 10.9 ug/L 109 82 - 124 2 20

Trichloroethene 10.0 10.4 ug/L 104 80 - 120 1 20

Vinyl acetate 10.0 10.8 ug/L 108 63 - 140 5 20

Vinyl chloride 10.0 11.5 ug/L 115 77 - 122 3 20

1,2-Dichloroethane-d4 (Surr) 75 - 129

Surrogate

97

LCSD LCSD

Qualifier Limits%Recovery

994-Bromofluorobenzene (Surr) 81 - 130

96Dibromofluoromethane (Surr) 81 - 124

102Toluene-d8 (Surr) 87 - 128


11/21/2016Page 10 of 150

QC Association SummaryTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


GC/MS VOA

Analysis Batch: 279202

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water 8260C160-19949-1 PW-2 Total/NA

Water 8260CMB 160-279202/9 Method Blank Total/NA

Water 8260CLCS 160-279202/6 Lab Control Sample Total/NA

Water 8260CLCSD 160-279202/7 Lab Control Sample Dup Total/NA


11/21/2016Page 11 of 150

Lab ChronicleClient: Westinghouse Electric Company LLC TestAmerica Job ID: 160-19949-1Project/Site: HDP RFP-CBA-022 (21 DAY TAT)

Client Sample ID: PW-2 Lab Sample ID: 160-19949-1Matrix: WaterDate Collected: 11/08/16 15:50

Date Received: 11/10/16 11:05

Analysis 8260C 11/15/16 12:55 ECF1 279202 TAL SL

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Laboratory References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566


11/21/2016Page 12 of 150

Certification SummaryClient: Westinghouse Electric Company LLC TestAmerica Job ID: 160-19949-1Project/Site: HDP RFP-CBA-022 (21 DAY TAT)

Laboratory: TestAmerica St. LouisUnless otherwise noted, all analytes for this laboratory were covered under each certification below.

Authority Program EPA Region Certification ID Expiration Date

Louisiana 040806NELAP 06-30-17

Analysis Method Prep Method Matrix Analyte

The following analytes are included in this report, but certification is not offered by the governing authority:

8260C Water 1,1,1-Trichloroethane

8260C Water 1,1,2,2-Tetrachloroethane


8260C Water 1,1-Dichloroethane

8260C Water 1,1-Dichloroethene

8260C Water 1,2,4-Trichlorobenzene

8260C Water 1,2-Dibromo-3-Chloropropane

8260C Water 1,2-Dibromoethane


8260C Water 1,2-Dichloroethene, Total

8260C Water 1,2-Dichloropropane

8260C Water 2-Butanone

8260C Water 2-Hexanone

8260C Water 4-Methyl-2-pentanone

8260C Water Acetone

8260C Water Benzene

8260C Water Bromodichloromethane

8260C Water Bromoform

8260C Water Carbon disulfide

8260C Water Carbon tetrachloride

8260C Water Chlorobenzene

8260C Water Chlorodibromomethane

8260C Water Chloroethane

8260C Water Chloroform

8260C Water Chloromethane

8260C Water cis-1,2-Dichloroethene

8260C Water cis-1,3-Dichloropropene

8260C Water Ethylbenzene

8260C Water Methyl bromide

8260C Water Methylene Chloride

8260C Water n-Butanol

8260C Water Styrene

8260C Water Tetrachloroethene

8260C Water Toluene

8260C Water trans-1,2-Dichloroethene

8260C Water trans-1,3-Dichloropropene

8260C Water Trichloroethene

8260C Water Vinyl acetate

8260C Water Vinyl chloride

8260C Water Xylenes, Total

Missouri State Program 7 780 06-30-17







11/21/2016Page 13 of 150


Laboratory: TestAmerica St. Louis (Continued)Unless otherwise noted, all analytes for this laboratory were covered under each certification below.


Missouri 7807State Program 06-30-17














8260C Water Acetone

8260C Water Benzene
















8260C Water Styrene


8260C Water Toluene







NRC NRC 24-24817-01 12-31-22










11/21/2016Page 14 of 150


Laboratory: TestAmerica St. Louis (Continued)Unless otherwise noted, all analytes for this laboratory were covered under each certification below.


NRC 24-24817-01NRC 12-31-22











8260C Water Acetone

8260C Water Benzene
















8260C Water Styrene


8260C Water Toluene








11/21/2016Page 15 of 150

Method SummaryTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


Method Method Description LaboratoryProtocol

SW8468260C Volatile Organic Compounds (GC/MS) TAL SL

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566


11/21/2016Page 16 of 150

Sample SummaryTestAmerica Job ID: 160-19949-1Client: Westinghouse Electric Company LLC


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

160-19949-1 PW-2 Water 11/08/16 15:50 11/10/16 11:05


11/21/2016Page 17 of 150

Lab Name: Job No.:

SDG No.:

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica St. Louis 160-19949-1

Instrument ID: Analysis Batch Number:VMSZ 277065

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTIONTIME

MANUAL INTEGRATIONDATEANALYSTREASON

IC 160-277065/5

ZICL9862.D11/01/16 21:09 GC Column: RTX-VMS40 ID: 0.18(mm)

Acrolein Split Peak fishere 11/02/16 06:465.802-Butanone Split Peak fishere 11/02/16 06:468.202-Chloroethyl vinyl ether Split Peak fishere 11/02/16 06:4610.03

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTIONTIME

MANUAL INTEGRATIONDATEANALYSTREASON

IC 160-277065/6

ZICL9863.D11/01/16 21:32 GC Column: RTX-VMS40 ID: 0.18(mm)

Ethanol Split Peak fishere 11/02/16 06:435.17

8260C

11/21/2016Page 18 of 150

REAGENT TRACEABILITY SUMMARY

Lab Name:

SDG No.:

Job No.: 160-19949-1TestAmerica St. Louis

Reagent IDExpDate Date

Prep DilutantUsed

ReagentFinalVolume

Parent Reagent

Reagent IDVolumeAdded ConcentrationAnalyte

8260_2_CLEVE_00045 2-Chloroethyl vinyl ether 25 ug/mL10 mL 100 uL11/06/16 10/30/168260 NewWkMix_00190 Methanol, Lot DP4611,2-Dichloro-1,1,2,2-tetrafluoroethane

25 ug/mL8260Custom1_00043 125 uL

n-Nonyl Aldehyde 25 ug/mLCyclohexanone 250 ug/mL8260Cyclohexa_00045 100 uLButadiene 25 ug/mL8260Gases_00180 100 uLChloroethane 25 ug/mLChloromethane 25 ug/mLDichlorodifluoromethane 25 ug/mLDichlorofluoromethane 25 ug/mLMethyl bromide 25 ug/mLTrichlorofluoromethane 25 ug/mLVinyl chloride 25 ug/mL2-Butanone 25 ug/mL8260Ketones_00045 20 uL2-Hexanone 25 ug/mL4-Methyl-2-pentanone 25 ug/mLAcetone 25 ug/mL1,1,1,2-Tetrachloroethane 25 ug/mL8260MegaMix_00045 100 uL1,1,1-Trichloroethane 25 ug/mL1,1,2,2-Tetrachloroethane 25 ug/mL1,1,2-Trichloro-1,2,2-trifluoroethane

25 ug/mL

1,1,2-Trichloroethane 25 ug/mL1,1-Dichloroethane 25 ug/mL1,1-Dichloroethene 25 ug/mL1,1-Dichloropropene 25 ug/mL1,2,3-Trichlorobenzene 25 ug/mL1,2,3-Trichloropropane 25 ug/mL1,2,4-Trichlorobenzene 25 ug/mL1,2,4-Trimethylbenzene 25 ug/mL1,2-Dibromo-3-Chloropropane 25 ug/mL1,2-Dibromoethane 25 ug/mL1,2-Dichlorobenzene 25 ug/mL1,2-Dichloroethane 25 ug/mL1,2-Dichloropropane 25 ug/mL1,3,5-Trimethylbenzene 25 ug/mL1,3-Dichlorobenzene 25 ug/mL1,3-Dichloropropane 25 ug/mL1,4-Dichlorobenzene 25 ug/mL1,4-Dioxane 500 ug/mL2,2-Dichloropropane 25 ug/mL2-Chlorotoluene 25 ug/mL2-Methyl-2-propanol 250 ug/mL3-Chloro-1-propene 25 ug/mL4-Chlorotoluene 25 ug/mL4-Isopropyltoluene 25 ug/mLAcrylonitrile 250 ug/mLBenzene 25 ug/mL

11/21/2016Page 19 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Bromobenzene 25 ug/mLBromodichloromethane 25 ug/mLBromoform 25 ug/mLCarbon disulfide 25 ug/mLCarbon tetrachloride 25 ug/mLChlorobenzene 25 ug/mLChlorobromomethane 25 ug/mLChlorodibromomethane 25 ug/mLChloroform 25 ug/mLcis-1,2-Dichloroethene 25 ug/mLcis-1,3-Dichloropropene 25 ug/mLCyclohexane 25 ug/mLDibromomethane 25 ug/mLEthyl ether 25 ug/mLEthyl methacrylate 25 ug/mLEthylbenzene 25 ug/mLHexachlorobutadiene 25 ug/mLHexane 25 ug/mLIodomethane 25 ug/mLIsobutyl alcohol 625 ug/mLIsopropylbenzene 25 ug/mLm-Xylene & p-Xylene 25 ug/mLMethyl acetate 125 ug/mLMethyl tert-butyl ether 25 ug/mLMethylcyclohexane 25 ug/mLMethylene Chloride 25 ug/mLn-Butylbenzene 25 ug/mLn-Heptane 25 ug/mLN-Propylbenzene 25 ug/mLNaphthalene 25 ug/mLo-Xylene 25 ug/mLsec-Butylbenzene 25 ug/mLStyrene 25 ug/mLtert-Butylbenzene 25 ug/mLTetrachloroethene 25 ug/mLTetrahydrofuran 50 ug/mLToluene 25 ug/mLtrans-1,2-Dichloroethene 25 ug/mLtrans-1,3-Dichloropropene 25 ug/mLtrans-1,4-Dichloro-2-butene 25 ug/mLTrichloroethene 25 ug/mLVinyl acetate 25 ug/mL8260VinAcetat_00048 50 uLAcrolein 125 ug/mLAcrolein_00039 62.5 uL1,2,3-Trimethylbenzene 25 ug/mLAdds(A) 2016_00008 100 uL1,3,5-Trichlorobenzene 25 ug/mL2-Chloro-1,3-butadiene 25 ug/mL2-Nitropropane 50 ug/mLBenzyl chloride 25 ug/mL

11/21/2016Page 20 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Isooctane 25 ug/mLIsopropyl alcohol 250 ug/mLMethacrylonitrile 250 ug/mLn-Butanol 625 ug/mLEthyl acetate 50 ug/mLAdds(B) 2016_00002 100 uLEthyl acrylate 25 ug/mLMethyl methacrylate 50 ug/mLn-Butyl acetate 25 ug/mLAcetonitrile 250 ug/mLPolar Add._00036 100 uLEthanol 1000 ug/mLIsopropyl ether 25 ug/mLPropionitrile 250 ug/mLTert-amyl methyl ether 25 ug/mLTert-butyl ethyl ether 25 ug/mL

11/16/16 (Purchased Reagent) 2-Chloroethyl vinyl ether 2500 ug/mLRestek, Lot A0115628.8260_2_CLEVE_0004511/09/16 (Purchased Reagent) 1,2-Dichloro-1,1,2,2-tetrafluo

roethane2000 ug/mLAccustandard, Lot 215101095-01.8260Custom1_00043

n-Nonyl Aldehyde 2000 ug/mL11/16/16 (Purchased Reagent) Cyclohexanone 25000 ug/mLRestek, Lot A0116621.8260Cyclohexa_0004511/06/16 (Purchased Reagent) Butadiene 2500 ug/mLRestek, Lot A0118719.8260Gases_00180

Chloroethane 2500 ug/mLChloromethane 2500 ug/mLDichlorodifluoromethane 2500 ug/mLDichlorofluoromethane 2500 ug/mLMethyl bromide 2500 ug/mLTrichlorofluoromethane 2500 ug/mLVinyl chloride 2500 ug/mL

11/16/16 (Purchased Reagent) 2-Butanone 12500 ug/mLRestek, Lot A0115554.8260Ketones_000452-Hexanone 12500 ug/mL4-Methyl-2-pentanone 12500 ug/mLAcetone 12500 ug/mL

11/16/16 (Purchased Reagent) 1,1,1,2-Tetrachloroethane 2500 ug/mLRestek, Lot A0118177.8260MegaMix_000451,1,1-Trichloroethane 2500 ug/mL1,1,2,2-Tetrachloroethane 2500 ug/mL1,1,2-Trichloro-1,2,2-trifluoroethane

2500 ug/mL

1,1,2-Trichloroethane 2500 ug/mL1,1-Dichloroethane 2500 ug/mL1,1-Dichloroethene 2500 ug/mL1,1-Dichloropropene 2500 ug/mL1,2,3-Trichlorobenzene 2500 ug/mL1,2,3-Trichloropropane 2500 ug/mL1,2,4-Trichlorobenzene 2500 ug/mL1,2,4-Trimethylbenzene 2500 ug/mL1,2-Dibromo-3-Chloropropane 2500 ug/mL1,2-Dibromoethane 2500 ug/mL1,2-Dichlorobenzene 2500 ug/mL1,2-Dichloroethane 2500 ug/mL

11/21/2016Page 21 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


1,2-Dichloropropane 2500 ug/mL1,3,5-Trimethylbenzene 2500 ug/mL1,3-Dichlorobenzene 2500 ug/mL1,3-Dichloropropane 2500 ug/mL1,4-Dichlorobenzene 2500 ug/mL1,4-Dioxane 50000 ug/mL2,2-Dichloropropane 2500 ug/mL2-Chlorotoluene 2500 ug/mL2-Methyl-2-propanol 25000 ug/mL3-Chloro-1-propene 2500 ug/mL4-Chlorotoluene 2500 ug/mL4-Isopropyltoluene 2500 ug/mLAcrylonitrile 25000 ug/mLBenzene 2500 ug/mLBromobenzene 2500 ug/mLBromodichloromethane 2500 ug/mLBromoform 2500 ug/mLCarbon disulfide 2500 ug/mLCarbon tetrachloride 2500 ug/mLChlorobenzene 2500 ug/mLChlorobromomethane 2500 ug/mLChlorodibromomethane 2500 ug/mLChloroform 2500 ug/mLcis-1,2-Dichloroethene 2500 ug/mLcis-1,3-Dichloropropene 2500 ug/mLCyclohexane 2500 ug/mLDibromomethane 2500 ug/mLEthyl ether 2500 ug/mLEthyl methacrylate 2500 ug/mLEthylbenzene 2500 ug/mLHexachlorobutadiene 2500 ug/mLHexane 2500 ug/mLIodomethane 2500 ug/mLIsobutyl alcohol 62500 ug/mLIsopropylbenzene 2500 ug/mLm-Xylene & p-Xylene 2500 ug/mLMethyl acetate 12500 ug/mLMethyl tert-butyl ether 2500 ug/mLMethylcyclohexane 2500 ug/mLMethylene Chloride 2500 ug/mLn-Butylbenzene 2500 ug/mLn-Heptane 2500 ug/mLN-Propylbenzene 2500 ug/mLNaphthalene 2500 ug/mLo-Xylene 2500 ug/mLsec-Butylbenzene 2500 ug/mLStyrene 2500 ug/mLtert-Butylbenzene 2500 ug/mL

11/21/2016Page 22 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Tetrachloroethene 2500 ug/mLTetrahydrofuran 5000 ug/mLToluene 2500 ug/mLtrans-1,2-Dichloroethene 2500 ug/mLtrans-1,3-Dichloropropene 2500 ug/mLtrans-1,4-Dichloro-2-butene 2500 ug/mLTrichloroethene 2500 ug/mL

11/23/16 (Purchased Reagent) Vinyl acetate 5000 ug/mLRestek, Lot A0120164.8260VinAcetat_0004811/30/16 (Purchased Reagent) Acrolein 20000 ug/mLRestek, Lot A0121394.Acrolein_0003911/30/16 (Purchased Reagent) 1,2,3-Trimethylbenzene 2500 ug/mLRestek, Lot A0116133.Adds(A) 2016_00008

1,3,5-Trichlorobenzene 2500 ug/mL2-Chloro-1,3-butadiene 2500 ug/mL2-Nitropropane 5000 ug/mLBenzyl chloride 2500 ug/mLIsooctane 2500 ug/mLIsopropyl alcohol 25000 ug/mLMethacrylonitrile 25000 ug/mLn-Butanol 62500 ug/mL

11/30/16 (Purchased Reagent) Ethyl acetate 5000 ug/mLRestek, Lot A0116077.Adds(B) 2016_00002Ethyl acrylate 2500 ug/mLMethyl methacrylate 5000 ug/mLn-Butyl acetate 2500 ug/mL

11/16/16 (Purchased Reagent) Acetonitrile 25000 ug/mLRestek, Lot A0114666.Polar Add._00036Ethanol 100000 ug/mLIsopropyl ether 2500 ug/mLPropionitrile 25000 ug/mLTert-amyl methyl ether 2500 ug/mLTert-butyl ethyl ether 2500 ug/mL

8260Gases_00182 Chloroethane 25 ug/mL10 mL 100 uL11/20/16 11/13/168260 NewWkMix_00192 Methanol, Lot DP461Chloromethane 25 ug/mLMethyl bromide 25 ug/mLVinyl chloride 25 ug/mL2-Butanone 25 ug/mL8260Ketones_00046 20 uL2-Hexanone 25 ug/mL4-Methyl-2-pentanone 25 ug/mLAcetone 25 ug/mL1,1,1-Trichloroethane 25 ug/mL8260MegaMix_00046 100 uL1,1,2,2-Tetrachloroethane 25 ug/mL1,1,2-Trichloroethane 25 ug/mL1,1-Dichloroethane 25 ug/mL1,1-Dichloroethene 25 ug/mL1,2,4-Trichlorobenzene 25 ug/mL1,2-Dibromo-3-Chloropropane 25 ug/mL1,2-Dibromoethane 25 ug/mL1,2-Dichloroethane 25 ug/mL1,2-Dichloropropane 25 ug/mLBenzene 25 ug/mL

11/21/2016Page 23 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Bromodichloromethane 25 ug/mLBromoform 25 ug/mLCarbon disulfide 25 ug/mLCarbon tetrachloride 25 ug/mLChlorobenzene 25 ug/mLChlorodibromomethane 25 ug/mLChloroform 25 ug/mLcis-1,2-Dichloroethene 25 ug/mLcis-1,3-Dichloropropene 25 ug/mLEthylbenzene 25 ug/mLMethylene Chloride 25 ug/mLStyrene 25 ug/mLTetrachloroethene 25 ug/mLToluene 25 ug/mLtrans-1,2-Dichloroethene 25 ug/mLtrans-1,3-Dichloropropene 25 ug/mLTrichloroethene 25 ug/mLVinyl acetate 25 ug/mL8260VinAcetat_00048 50 uL

Adds(A) 2016_00008 100 uL n-Butanol 625 ug/mL11/20/16 (Purchased Reagent) Chloroethane 2500 ug/mLRestek, Lot A0118719.8260Gases_00182

Chloromethane 2500 ug/mLMethyl bromide 2500 ug/mLVinyl chloride 2500 ug/mL


12/13/16 (Purchased Reagent) 1,1,1-Trichloroethane 2500 ug/mLRestek, Lot A0118177.8260MegaMix_000461,1,2,2-Tetrachloroethane 2500 ug/mL1,1,2-Trichloroethane 2500 ug/mL1,1-Dichloroethane 2500 ug/mL1,1-Dichloroethene 2500 ug/mL1,2,4-Trichlorobenzene 2500 ug/mL1,2-Dibromo-3-Chloropropane 2500 ug/mL1,2-Dibromoethane 2500 ug/mL1,2-Dichloroethane 2500 ug/mL1,2-Dichloropropane 2500 ug/mLBenzene 2500 ug/mLBromodichloromethane 2500 ug/mLBromoform 2500 ug/mLCarbon disulfide 2500 ug/mLCarbon tetrachloride 2500 ug/mLChlorobenzene 2500 ug/mLChlorodibromomethane 2500 ug/mLChloroform 2500 ug/mLcis-1,2-Dichloroethene 2500 ug/mLcis-1,3-Dichloropropene 2500 ug/mLEthylbenzene 2500 ug/mL

11/21/2016Page 24 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Methylene Chloride 2500 ug/mLStyrene 2500 ug/mLTetrachloroethene 2500 ug/mLToluene 2500 ug/mLtrans-1,2-Dichloroethene 2500 ug/mLtrans-1,3-Dichloropropene 2500 ug/mLTrichloroethene 2500 ug/mL

11/23/16 (Purchased Reagent) Vinyl acetate 5000 ug/mLRestek, Lot A0120164.8260VinAcetat_0004811/30/16 (Purchased Reagent) n-Butanol 62500 ug/mLRestek, Lot A0116133.Adds(A) 2016_00008

8260_Surr_00040 1,2-Dichloroethane-d4 (Surr) 25 ug/mL25 mL 250 uL11/04/16 10/04/168260 Surr 25_00066 Methanol, Lot DP3034-Bromofluorobenzene (Surr) 25 ug/mLDibromofluoromethane (Surr) 25 ug/mLToluene-d8 (Surr) 25 ug/mL

11/04/16 (Purchased Reagent) 1,2-Dichloroethane-d4 (Surr) 2500 ug/mLRestek, Lot A0115812.8260_Surr_000404-Bromofluorobenzene (Surr) 2500 ug/mLDibromofluoromethane (Surr) 2500 ug/mLToluene-d8 (Surr) 2500 ug/mL

8260_Surr_00041 1,2-Dichloroethane-d4 (Surr) 25 ug/mL25 mL 250 uL12/01/16 11/01/168260 Surr 25_00067 Methanol, Lot DP4614-Bromofluorobenzene (Surr) 25 ug/mLDibromofluoromethane (Surr) 25 ug/mLToluene-d8 (Surr) 25 ug/mL

12/01/16 (Purchased Reagent) 1,2-Dichloroethane-d4 (Surr) 2500 ug/mLRestek, Lot A0115812.8260_Surr_000414-Bromofluorobenzene (Surr) 2500 ug/mLDibromofluoromethane (Surr) 2500 ug/mLToluene-d8 (Surr) 2500 ug/mL

11/04/16 (Purchased Reagent) 1,2-Dichloroethane-d4 (Surr) 2500 ug/mLRestek, Lot A01158128260_Surr_000404-Bromofluorobenzene (Surr) 2500 ug/mLDibromofluoromethane (Surr) 2500 ug/mLToluene-d8 (Surr) 2500 ug/mL

8260_2_CLEVE_00045 2-Chloroethyl vinyl ether 125 ug/mL1 mL 50 uL11/06/16 10/30/168260NewHiWrk_00168 Methanol, Lot DP4611,2-Dichloro-1,1,2,2-tetrafluoroethane

125 ug/mL8260Custom1_00043 62.5 uL

n-Nonyl Aldehyde 125 ug/mLCyclohexanone 1250 ug/mL8260Cyclohexa_00045 50 uLButadiene 125 ug/mL8260Gases_00180 50 uLChloroethane 125 ug/mLChloromethane 125 ug/mLDichlorodifluoromethane 125 ug/mLDichlorofluoromethane 125 ug/mLMethyl bromide 125 ug/mLTrichlorofluoromethane 125 ug/mLVinyl chloride 125 ug/mL2-Butanone 125 ug/mL8260Ketones_00045 10 uL2-Hexanone 125 ug/mL4-Methyl-2-pentanone 125 ug/mLAcetone 125 ug/mL1,1,1,2-Tetrachloroethane 125 ug/mL8260MegaMix_00045 50 uL

11/21/2016Page 25 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


1,1,1-Trichloroethane 125 ug/mL1,1,2,2-Tetrachloroethane 125 ug/mL1,1,2-Trichloro-1,2,2-trifluoroethane

125 ug/mL

1,1,2-Trichloroethane 125 ug/mL1,1-Dichloroethane 125 ug/mL1,1-Dichloroethene 125 ug/mL1,1-Dichloropropene 125 ug/mL1,2,3-Trichlorobenzene 125 ug/mL1,2,3-Trichloropropane 125 ug/mL1,2,4-Trichlorobenzene 125 ug/mL1,2,4-Trimethylbenzene 125 ug/mL1,2-Dibromo-3-Chloropropane 125 ug/mL1,2-Dibromoethane 125 ug/mL1,2-Dichlorobenzene 125 ug/mL1,2-Dichloroethane 125 ug/mL1,2-Dichloropropane 125 ug/mL1,3,5-Trimethylbenzene 125 ug/mL1,3-Dichlorobenzene 125 ug/mL1,3-Dichloropropane 125 ug/mL1,4-Dichlorobenzene 125 ug/mL1,4-Dioxane 2500 ug/mL2,2-Dichloropropane 125 ug/mL2-Chlorotoluene 125 ug/mL2-Methyl-2-propanol 1250 ug/mL3-Chloro-1-propene 125 ug/mL4-Chlorotoluene 125 ug/mL4-Isopropyltoluene 125 ug/mLAcrylonitrile 1250 ug/mLBenzene 125 ug/mLBromobenzene 125 ug/mLBromodichloromethane 125 ug/mLBromoform 125 ug/mLCarbon disulfide 125 ug/mLCarbon tetrachloride 125 ug/mLChlorobenzene 125 ug/mLChlorobromomethane 125 ug/mLChlorodibromomethane 125 ug/mLChloroform 125 ug/mLcis-1,2-Dichloroethene 125 ug/mLcis-1,3-Dichloropropene 125 ug/mLCyclohexane 125 ug/mLDibromomethane 125 ug/mLEthyl ether 125 ug/mLEthyl methacrylate 125 ug/mLEthylbenzene 125 ug/mLHexachlorobutadiene 125 ug/mLHexane 125 ug/mL

11/21/2016Page 26 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Iodomethane 125 ug/mLIsobutyl alcohol 3125 ug/mLIsopropylbenzene 125 ug/mLm-Xylene & p-Xylene 125 ug/mLMethyl acetate 625 ug/mLMethyl tert-butyl ether 125 ug/mLMethylcyclohexane 125 ug/mLMethylene Chloride 125 ug/mLn-Butylbenzene 125 ug/mLn-Heptane 125 ug/mLN-Propylbenzene 125 ug/mLNaphthalene 125 ug/mLo-Xylene 125 ug/mLsec-Butylbenzene 125 ug/mLStyrene 125 ug/mLtert-Butylbenzene 125 ug/mLTetrachloroethene 125 ug/mLTetrahydrofuran 250 ug/mLToluene 125 ug/mLtrans-1,2-Dichloroethene 125 ug/mLtrans-1,3-Dichloropropene 125 ug/mLtrans-1,4-Dichloro-2-butene 125 ug/mLTrichloroethene 125 ug/mLVinyl acetate 125 ug/mL8260VinAcetat_00048 25 uLAcrolein 625 ug/mLAcrolein_00039 31.25 uL1,2,3-Trimethylbenzene 125 ug/mLAdds(A) 2016_00008 50 uL1,3,5-Trichlorobenzene 125 ug/mL2-Chloro-1,3-butadiene 125 ug/mL2-Nitropropane 250 ug/mLBenzyl chloride 125 ug/mLIsooctane 125 ug/mLIsopropyl alcohol 1250 ug/mLMethacrylonitrile 1250 ug/mLn-Butanol 3125 ug/mLEthyl acetate 250 ug/mLAdds(B) 2016_00002 50 uLEthyl acrylate 125 ug/mLMethyl methacrylate 250 ug/mLn-Butyl acetate 125 ug/mLAcetonitrile 1250 ug/mLPolar Add._00036 50 uLEthanol 5000 ug/mLIsopropyl ether 125 ug/mLPropionitrile 1250 ug/mLTert-amyl methyl ether 125 ug/mLTert-butyl ethyl ether 125 ug/mL

11/16/16 (Purchased Reagent) 2-Chloroethyl vinyl ether 2500 ug/mLRestek, Lot A0115628.8260_2_CLEVE_0004511/09/16 (Purchased Reagent) 1,2-Dichloro-1,1,2,2-tetrafluo

roethane2000 ug/mLAccustandard, Lot 215101095-01.8260Custom1_00043

n-Nonyl Aldehyde 2000 ug/mL

11/21/2016Page 27 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


11/16/16 (Purchased Reagent) Cyclohexanone 25000 ug/mLRestek, Lot A0116621.8260Cyclohexa_0004511/06/16 (Purchased Reagent) Butadiene 2500 ug/mLRestek, Lot A0118719.8260Gases_00180

Chloroethane 2500 ug/mLChloromethane 2500 ug/mLDichlorodifluoromethane 2500 ug/mLDichlorofluoromethane 2500 ug/mLMethyl bromide 2500 ug/mLTrichlorofluoromethane 2500 ug/mLVinyl chloride 2500 ug/mL


11/16/16 (Purchased Reagent) 1,1,1,2-Tetrachloroethane 2500 ug/mLRestek, Lot A0118177.8260MegaMix_000451,1,1-Trichloroethane 2500 ug/mL1,1,2,2-Tetrachloroethane 2500 ug/mL1,1,2-Trichloro-1,2,2-trifluoroethane

2500 ug/mL

1,1,2-Trichloroethane 2500 ug/mL1,1-Dichloroethane 2500 ug/mL1,1-Dichloroethene 2500 ug/mL1,1-Dichloropropene 2500 ug/mL1,2,3-Trichlorobenzene 2500 ug/mL1,2,3-Trichloropropane 2500 ug/mL1,2,4-Trichlorobenzene 2500 ug/mL1,2,4-Trimethylbenzene 2500 ug/mL1,2-Dibromo-3-Chloropropane 2500 ug/mL1,2-Dibromoethane 2500 ug/mL1,2-Dichlorobenzene 2500 ug/mL1,2-Dichloroethane 2500 ug/mL1,2-Dichloropropane 2500 ug/mL1,3,5-Trimethylbenzene 2500 ug/mL1,3-Dichlorobenzene 2500 ug/mL1,3-Dichloropropane 2500 ug/mL1,4-Dichlorobenzene 2500 ug/mL1,4-Dioxane 50000 ug/mL2,2-Dichloropropane 2500 ug/mL2-Chlorotoluene 2500 ug/mL2-Methyl-2-propanol 25000 ug/mL3-Chloro-1-propene 2500 ug/mL4-Chlorotoluene 2500 ug/mL4-Isopropyltoluene 2500 ug/mLAcrylonitrile 25000 ug/mLBenzene 2500 ug/mLBromobenzene 2500 ug/mLBromodichloromethane 2500 ug/mLBromoform 2500 ug/mLCarbon disulfide 2500 ug/mL

11/21/2016Page 28 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Carbon tetrachloride 2500 ug/mLChlorobenzene 2500 ug/mLChlorobromomethane 2500 ug/mLChlorodibromomethane 2500 ug/mLChloroform 2500 ug/mLcis-1,2-Dichloroethene 2500 ug/mLcis-1,3-Dichloropropene 2500 ug/mLCyclohexane 2500 ug/mLDibromomethane 2500 ug/mLEthyl ether 2500 ug/mLEthyl methacrylate 2500 ug/mLEthylbenzene 2500 ug/mLHexachlorobutadiene 2500 ug/mLHexane 2500 ug/mLIodomethane 2500 ug/mLIsobutyl alcohol 62500 ug/mLIsopropylbenzene 2500 ug/mLm-Xylene & p-Xylene 2500 ug/mLMethyl acetate 12500 ug/mLMethyl tert-butyl ether 2500 ug/mLMethylcyclohexane 2500 ug/mLMethylene Chloride 2500 ug/mLn-Butylbenzene 2500 ug/mLn-Heptane 2500 ug/mLN-Propylbenzene 2500 ug/mLNaphthalene 2500 ug/mLo-Xylene 2500 ug/mLsec-Butylbenzene 2500 ug/mLStyrene 2500 ug/mLtert-Butylbenzene 2500 ug/mLTetrachloroethene 2500 ug/mLTetrahydrofuran 5000 ug/mLToluene 2500 ug/mLtrans-1,2-Dichloroethene 2500 ug/mLtrans-1,3-Dichloropropene 2500 ug/mLtrans-1,4-Dichloro-2-butene 2500 ug/mLTrichloroethene 2500 ug/mL

11/23/16 (Purchased Reagent) Vinyl acetate 5000 ug/mLRestek, Lot A0120164.8260VinAcetat_0004811/30/16 (Purchased Reagent) Acrolein 20000 ug/mLRestek, Lot A0121394.Acrolein_0003911/30/16 (Purchased Reagent) 1,2,3-Trimethylbenzene 2500 ug/mLRestek, Lot A0116133.Adds(A) 2016_00008

1,3,5-Trichlorobenzene 2500 ug/mL2-Chloro-1,3-butadiene 2500 ug/mL2-Nitropropane 5000 ug/mLBenzyl chloride 2500 ug/mLIsooctane 2500 ug/mLIsopropyl alcohol 25000 ug/mLMethacrylonitrile 25000 ug/mLn-Butanol 62500 ug/mL

11/21/2016Page 29 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


11/30/16 (Purchased Reagent) Ethyl acetate 5000 ug/mLRestek, Lot A0116077.Adds(B) 2016_00002Ethyl acrylate 2500 ug/mLMethyl methacrylate 5000 ug/mLn-Butyl acetate 2500 ug/mL

11/16/16 (Purchased Reagent) Acetonitrile 25000 ug/mLRestek, Lot A0114666.Polar Add._00036Ethanol 100000 ug/mLIsopropyl ether 2500 ug/mLPropionitrile 25000 ug/mLTert-amyl methyl ether 2500 ug/mLTert-butyl ethyl ether 2500 ug/mL

8260GasesSS_00181 Chloroethane 25 ug/mL5 mL 50 uL11/06/16 10/30/168260NewICVMix_00181 Methanol, Lot DP461Chloromethane 25 ug/mLMethyl bromide 25 ug/mLVinyl chloride 25 ug/mL2-Butanone 25 ug/mL8260KetonesSS_00044 10 uL2-Hexanone 25 ug/mL4-Methyl-2-pentanone 25 ug/mLAcetone 25 ug/mL1,1,1-Trichloroethane 25 ug/mL8260MegaMixSS_00044 50 uL1,1,2,2-Tetrachloroethane 25 ug/mL1,1,2-Trichloroethane 25 ug/mL1,1-Dichloroethane 25 ug/mL1,1-Dichloroethene 25 ug/mL1,2,4-Trichlorobenzene 25 ug/mL1,2-Dibromo-3-Chloropropane 25 ug/mL1,2-Dibromoethane 25 ug/mL1,2-Dichloroethane 25 ug/mL1,2-Dichloropropane 25 ug/mLBenzene 25 ug/mLBromodichloromethane 25 ug/mLBromoform 25 ug/mLCarbon disulfide 25 ug/mLCarbon tetrachloride 25 ug/mLChlorobenzene 25 ug/mLChlorodibromomethane 25 ug/mLChloroform 25 ug/mLcis-1,2-Dichloroethene 25 ug/mLcis-1,3-Dichloropropene 25 ug/mLEthylbenzene 25 ug/mLMethylene Chloride 25 ug/mLStyrene 25 ug/mLTetrachloroethene 25 ug/mLToluene 25 ug/mLtrans-1,2-Dichloroethene 25 ug/mLtrans-1,3-Dichloropropene 25 ug/mLTrichloroethene 25 ug/mLVinyl acetate 25 ug/mL8260VinAcetSS_00047 25 uL

11/21/2016Page 30 of 150


Lab Name:

SDG No.:



Prep DilutantUsed

ReagentFinalVolume

Parent Reagent


Add(A)SS 2016_00010 50 uL n-Butanol 625 ug/mL11/06/16 (Purchased Reagent) Chloroethane 2500 ug/mLRestek, Lot A0115484.8260GasesSS_00181

Chloromethane 2500 ug/mLMethyl bromide 2500 ug/mLVinyl chloride 2500 ug/mL

11/16/16 (Purchased Reagent) 2-Butanone 12500 ug/mLRestek, Lot A0118013.8260KetonesSS_000442-Hexanone 12500 ug/mL4-Methyl-2-pentanone 12500 ug/mLAcetone 12500 ug/mL

11/16/16 (Purchased Reagent) 1,1,1-Trichloroethane 2500 ug/mLRestek, Lot A0120604.8260MegaMixSS_000441,1,2,2-Tetrachloroethane 2500 ug/mL1,1,2-Trichloroethane 2500 ug/mL1,1-Dichloroethane 2500 ug/mL1,1-Dichloroethene 2500 ug/mL1,2,4-Trichlorobenzene 2500 ug/mL1,2-Dibromo-3-Chloropropane 2500 ug/mL1,2-Dibromoethane 2500 ug/mL1,2-Dichloroethane 2500 ug/mL1,2-Dichloropropane 2500 ug/mLBenzene 2500 ug/mLBromodichloromethane 2500 ug/mLBromoform 2500 ug/mLCarbon disulfide 2500 ug/mLCarbon tetrachloride 2500 ug/mLChlorobenzene 2500 ug/mLChlorodibromomethane 2500 ug/mLChloroform 2500 ug/mLcis-1,2-Dichloroethene 2500 ug/mLcis-1,3-Dichloropropene 2500 ug/mLEthylbenzene 2500 ug/mLMethylene Chloride 2500 ug/mLStyrene 2500 ug/mLTetrachloroethene 2500 ug/mLToluene 2500 ug/mLtrans-1,2-Dichloroethene 2500 ug/mLtrans-1,3-Dichloropropene 2500 ug/mLTrichloroethene 2500 ug/mL

11/30/16 (Purchased Reagent) Vinyl acetate 5000 ug/mLRestek, Lot A0120342.8260VinAcetSS_0004711/30/16 (Purchased Reagent) n-Butanol 62500 ug/mLRestek, Lot A0116135.Add(A)SS 2016_00010

8260 IS(2014)_00033 1,4-Dichlorobenzene-d4 25 ug/mL25 mL 250 uL11/23/16 10/23/16I.S. Working_00139 Methanol, Lot DP303Chlorobenzene-d5 25 ug/mLFluorobenzene 25 ug/mL

11/23/16 (Purchased Reagent) 1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0117358.8260 IS(2014)_00033Chlorobenzene-d5 2500 ug/mLFluorobenzene 2500 ug/mL

11/21/2016Page 31 of 150

Reagent

8260 IS(2014)_00033

11/21/2016Page 32 of 150

11/21/2016Page 33 of 150

~ .... RESTEK" CERTIFIED REFERENCE MATERIAL 110 Benner Circle

Bellefonte, PA 16823-8812 Tei: (800)356·1688 Fax: (814)353-1309

www.restek.com

Catalog No. : 30241

Certificate of Analysis

FOR LWOR.\TORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed.

Lot No.: AO 117358

Description : 8260A Internal Standard Mix

8260A Internal Standard Mix 2,500 µg/rnl, P&T Methanol. 1mUarnpul ~e:c, 'D ::/'-~-1,,£. .Jbc}-' Container Size : 2 ml

Expiration Date : Februacy 28, 2021

- Compound Fiuoroben.zene CAS# 462·06·6 (LotBCBK8l7lV) Purity 99?4.

" Chlorobenzene~d5 k CAS# 3114-55-4 (Lot PR-23926) Pu~ty 99%

3 1. 4-Dichlorobenzene-d4 CAS# 3855R82R 1 (Lot PR-18488) Purity 99°;0

Solvent: P&T Methanol CAS# 67-56·1 Purity 99"!.

Pkg Amt: > 1 ~~~~~~~~~

Storage: o~c or colder 'i~oSBl-568

CERTIFIED VALUES

Grav Cone. (weightfvolu~)

2.501.8 ,uglmL

2.500.J µgimL

2.500.7 µglmL

+/-+I-+/·

+/-+i-

+/-

+/-+/-+/-

Expanded Uncertainty (95% C.L K;2}

14.5457 µglmL 140.2734 µglmL 143.5557 µglmL

14.5358 µgJmL 14{l.i 78 i µg/mL 143.4581 µg./mL

14.5393 µg/mL 140.2118 µg/mL 143.4925 µg/mL

Gravimetric Unstressed Stressed

Gravimetric UJL'itressed Stressed

Gravimetric lTnstressed Stressed

11/21/2016Page 34 of 150

Column: 105rr x O.!\Srnrn • '.':I 0;.1~ Rtx-501.2le.at1110910)

Carrier Gas: Mytlrog~n~ru:tant preuure ll.O p~i

Temp. Program: 40'C (hold 2 min.) to 2.io•t:

@ S'C/mln. (hold 5 min.)

lnj. Temp: ioo·c

Del Temp: 250'C

Det Type: ~m

~:J-p~ Jennifer L Polllno • QC Anal}'it

-

-

0 5 15 Minutes

20 25 3C

This chromatogram represents a general set of testing conditions chosen for product acceptance_ For optimal results in your lab, conditions should be ad1usted for your specific instrument, method, and application.

Date Miud: 16-feh-2016

Date Pas~: !.B·feb-2016

Balance: 1127510105

Manufaetured under R&stek's t$O 9001 :2006 Regi&tered Quality System

Certificat9 #FWI a0397

Reagent

8260_Surr_00040

11/21/2016Page 35 of 150

11/21/2016Page 36 of 150

RESTEK 110 Benner Circle

Bellefonte, PA 16823-8812 Tel: (800)356-1688 Fax: (814)353-1309

www.restek.com

Catalog No. : 567650

CERTIFIED REFERENCE MATERIAL

Certificate of Analysis

FOR LABO RA TORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte{s) listed.

Lot No.: A0115812

ISCGU.do.3.1~ ~-tll .. l'o«lo.oc:o< -~'

Description : 8260 Surrogate Standard

8260 Surrogate Standard 2,500 uglml, P&T Methanol, 5 ml/ampul ~EC,·l) ~ 1- {Jo _jt;t\-

Cf(i!OSeA- SGD

Container Size : 5mL

Expiration Date : December 31 2020

- Compound Dibromofluorometharu: CAS# 1868-53-7 (Lm 022012) Purity 99",i,

2 l.2-Dichloroefu30e-d4 CAS# 17060--07-0 (Lot l4C·l9l) Purity 99'!4

3 Toluene-µrity 99~0

Solvent: P&T Methanol CAS# 67-56-1 Purity 99~i

Pkg Amt: > 5 ml ~~~~~~~~~

Storage: o~c or colder

CERTIFIED VALUES

Grav. Cone. (weight/volume)

2.503.l µgimL

2.500.l µg!mL

2,505.0 µglmL

2.501.l ug/mL

+/-+/-+l~

+/-+/~

+/.

+/.

... ;~ ..... /~

-/. -!--1-

Expanded Uncertainty {95~o CL.; K=2)

14.5534 µg/mL

140.3482 µg/mL 143.6322 µg!mL

14.5360 .ugimL 140.1800 µgJmL 143.4600 µg!mL

14.5643 µg!mL 140.4529 µglmL 143.7393 ;1glmL

14.5418 µ.g!n1L 140.2361 µgimL 143.5174 µgimL

Gravinietric lJnstressed Stressed

(.Jravimetric Unstressed Stressed

Gravimetric Unstressed Stressed

Gravimetric Unstressed Suesserl

11/21/2016Page 37 of 150

Column: lOSm x 0.53mm'JI 3.0µ'1'1 Rt;.;·502.2 fcat.ll10910)

Carner Gas: l"lydrogen-eoostant pre~~ure 11.0 p$l.

Temp. Program: 40"C(hold 2 min.) to 240'C

@ 8'C/mh·i. (hold 5 min.I

ln). Temp: 2oo·c

Del Temp: 2so·c

Del Type: "'ID

Jennll1!r L. Polllno ·QC Analy>t

•

... I

~I c e 1J ~= 2C 25 30

Minutes

This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application.

Datt Mixed: O?-Dem

C*'1:fficate #FM 80.197

Reagent

8260Custom1_00043

11/21/2016Page 38 of 150

11/21/2016Page 39 of 150

125 Merkel Stre-01 New Haven, CT 00513 USA ~ AccuStandard~ Inc.

Tel (203)786-5290 Fax (203)786-5287

www.AccuStandard.com

CERTIFICATE OF ANALYSIS

Catalog No: S-26138 Description: Custom VOC Standard

Lot: 215101095-01 Solvent: Methanol Hazards: HIGHLY FLAMMABLE - Refer to SDS for safely info

Component

Freon 114 Non.an.al

Danger 2

CAS#

76-14-2 124-19-6

Date Certified: Jul 25, 2016 Expiration: Jul 25, 2017

Sample Size: 1 mL Components: 2

Storage Condition: Remg (0-5 °C)

lnduded on ISOllEC 17025 Scope of Accredilali011: Yes Included on ISO Guide 34 Scope of Accreditation: Yes

Purity% Prepa....t Certified Analyte Concentration• Concentratk>n2

GCIFID lmL J lmL 99.0 2013 1993

100.0 2004 2004

A productwrlh e auffix (-1A, -iB, etc. or-01, -02, etc.) on its lot number has had Its expiration dete extended and is identical to the seme lot number without the sl.lffix. 1 All weights are traceable 1hrough NIST. Test No. 822-275872~11 11 Certifled Analyte Coocentra1lon =Purity x Prepared Concentration. The Uncertainty associated with the gravimetric values reported on thi5 CEITTficate is ±0.24o/o. The CRM Uncertainty calculated fer thi.s product is ±5%. The&e values are the expanded uncerts:irrty and represent an estimated standard deviation equal to the positive .square root of !he: total variation of the uncertainty ot components. A normal dis~ribution is assumed and a coverage factor of K=2 is chosen u5ing approximately a 95% confidence leYel, Labels and certificates. follow U.S. Conventions in reporting numerical values: A comma(.) is used to separate units ol on.thousaf'ld 0t greater. A period(.} is used as a decimal place marl

11/21/2016Page 40 of 150

CERTIFICATION REPORT

1. QYalily Documenta!l!m:. This certificate is designed in accordance with ISO Guide 31 (Reference Materials ·Contents of Certificates and Labels) and ISO Guide 35 (Reference Materials - General and Statistical Principles for Certification).

2. Quallty .. S!ll!!dards:

ISO Guide 34 · General Requirements for the Competence of Reference Material Producers ANAB Certificate Number AR-1463

ISOllEC 17025 • General Reqwrements for the Competence of Testing and Calibration Laboratories ANAB Certificate Number AT-1339

ISO 9001 • Quality Management System • Requirements Eagle Registrations Certificate Number 3774

......... -AR-1463

AT-1339

3. Intended Use: The produc: covered by this certificate is designed for ca:ibraiion or for use in quality control procedures for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or identification. This product can a1so be used as a reference material to validate analytical procedures, subject to the conditions under Section 11. If dilution is required. use only Glass A glassware and diluent compatible with all certified analytes in this preparation. All solutions should be thoroughly mixed prior to use.

4. .13.!!lN Materials: Reference standards are prepared from the highest quality starting materials with defined purities. All analytes and solvents are obtained from pre-qualified vendors and then analyzed or evaluated prior to use.

5. M11nufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Glass A glassware is used in the manufacture and quality control of all standards and calibrated using an in-house procedure. Good Laboratory Practices have been used throughout the preparation of this CRM.

a. Homogen~ssessment~ Ho'Tlogeneity of the finished product is assessed by analyzing sample batches or by other methods consistent with the intended use of the product and by procedures that comply with the appropriate Quality System requirements, and ISO Guide 35.

7. $!ability Assess1rnmt The manufacturer guarantees the stability of this solution through the expiration date stated on lhe label, when handled and stored according to the conditions stated on the label. To ensure a uniform solution. mix the contents of the sealed container thoroughly prior to use. Care should be taken not to contaminate the contents of the original container.

8. An!tlytical Quality..c&rurol: Products are tested by validated analytical methods specified in the manufacturer's quality system.

9. _Uncerta.J.11ty_S.!!tistics and Confidence .. l.imJts: The uncertainty values as stated on the face of this certificate have been determined using the EURACHEM/GITAG Guide We report a combined expanded uncertainty equal to the positive square root of the total variance of the uncertainty of the components using the following formula: "m .J!u(P)l' 1 (u(m))' + (11(V)f The expanded uncertainty, UcAM assumes a normal distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level. The UcRM for organic products is ±5%, the UcRM for inorganic products is ±2°/a.

10. W.arranties: The manufacturer warrants that its products shall conform to the description of such products as provided in its catalog or on the specific product label. This warranty is exclusive, and the manufacturer makes no other warranty, express or implied, including any implied warranty of merchantability or fitness for any particular purpose.

11. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. Due to the hazardous nalllre. only :rained personnel should handle this product The company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made within thirty (30) days from date of delivery.

Method 8260C Low Level

Volatile Organic Compounds (GC/MS) by Method 8260C Low Level

11/21/2016Page 41 of 150

FORM IIGC/MS VOA SURROGATE RECOVERY

Lab Name: Job No.: 160-19949-1

SDG No.:

Matrix: Water Level: Low


GC Column (1): RTX-VMS40 ID: 0.18(mm)

#Lab Sample IDClient Sample ID # # #DBFM DCA TOL BFB

160-19949-1PW-2 100 97 107 108

MB 160-279202/9 97 98 113 121

LCS 160-279202/6 97 97 102 100

LCSD 160-279202/7

96 97 102 99

QC LIMITSDBFM = Dibromofluoromethane (Surr) 81-124DCA = 1,2-Dichloroethane-d4 (Surr) 75-129TOL = Toluene-d8 (Surr) 87-128BFB = 4-Bromofluorobenzene (Surr) 81-130

FORM II 8260C

# Column to be used to flag recovery values

11/21/2016Page 42 of 150

GC/MS VOA LAB CONTROL SAMPLE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

160-19949-1

Lab File ID: ZLCS0117.DWater

Lab ID: LCS 160-279202/6 Client ID:


REC %REC

QCLIMITSCONCENTRATION

(ug/L)

SPIKEADDED(ug/L)

#LCS LCS

COMPOUND1,1,1-Trichloroethane 10.0 10.8 85-1161081,1,2,2-Tetrachloroethane 10.0 9.11 80-120911,1,2-Trichloroethane 10.0 9.68 80-120971,1-Dichloroethene 10.0 11.0 80-1201101,1-Dichloroethane 10.0 10.9 80-1201091,2,4-Trichlorobenzene 10.0 9.95 75-121991,2-Dibromo-3-Chloropropane 10.0 9.07 73-123911,2-Dichloroethane 10.0 9.58 80-115961,2-Dichloroethene, Total 20.0 21.0 80-1201051,2-Dichloropropane 10.0 10.7 80-1201072-Butanone 10.0 9.11 67-127912-Hexanone 10.0 9.98 70-1231004-Methyl-2-pentanone 10.0 9.64 75-12696Acetone 10.0 9.68 69-12997Benzene 10.0 10.9 80-120109Bromoform 10.0 9.16 80-12092Methyl bromide 10.0 10.5 70-124105Carbon disulfide 10.0 11.9 80-121119Carbon tetrachloride 10.0 10.6 83-125106Chlorobenzene 10.0 10.5 80-120105Chlorodibromomethane 10.0 9.09 80-12091Chloroethane 10.0 11.2 73-119112Chloroform 10.0 10.4 80-120104Chloromethane 10.0 12.0 72-124120cis-1,2-Dichloroethene 10.0 10.3 80-120103cis-1,3-Dichloropropene 10.0 10.4 80-120104Bromodichloromethane 10.0 9.81 80-12098Ethylbenzene 10.0 11.5 80-1201151,2-Dibromoethane 10.0 9.55 80-12096Methylene Chloride 10.0 10.3 80-120103n-Butanol 250 248 62-12899Styrene 10.0 11.4 81-133114Tetrachloroethene 10.0 10.6 83-123106Toluene 10.0 11.3 80-120113trans-1,2-Dichloroethene 10.0 10.7 80-120107trans-1,3-Dichloropropene 10.0 10.7 82-124107Trichloroethene 10.0 10.6 80-120106Vinyl acetate 10.0 10.2 63-140102Vinyl chloride 10.0 11.8 77-122118

FORM III 8260C

# Column to be used to flag recovery and RPD values

11/21/2016Page 43 of 150

GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

160-19949-1

Lab File ID: ZLCS0118.DWater

Lab ID: LCSD 160-279202/7 Client ID:


COMPOUND

SPIKEADDED CONCENTRATION %

REC%RPD

QC LIMITS

RPD REC (ug/L) (ug/L)#

LCSD LCSD

10.0 10.4 20 85-1161,1,1-Trichloroethane 310410.0 9.73 20 80-1201,1,2,2-Tetrachloroethane 79710.0 10.2 20 80-1201,1,2-Trichloroethane 510210.0 10.8 20 80-1201,1-Dichloroethene 210810.0 10.4 20 80-1201,1-Dichloroethane 510410.0 9.55 20 75-1211,2,4-Trichlorobenzene 49510.0 9.63 20 73-1231,2-Dibromo-3-Chloropropane 69610.0 9.72 20 80-1151,2-Dichloroethane 19720.0 20.9 20 80-1201,2-Dichloroethene, Total 010510.0 10.4 20 80-1201,2-Dichloropropane 310410.0 9.51 20 67-1272-Butanone 49510.0 9.52 20 70-1232-Hexanone 59510.0 10.8 20 75-1264-Methyl-2-pentanone 1210810.0 9.98 20 69-129Acetone 310010.0 11.0 20 80-120Benzene 111010.0 9.29 20 80-120Bromoform 19310.0 10.4 20 70-124Methyl bromide 110410.0 11.4 20 80-121Carbon disulfide 411410.0 10.4 20 83-125Carbon tetrachloride 110410.0 10.6 20 80-120Chlorobenzene 010610.0 9.61 20 80-120Chlorodibromomethane 69610.0 10.9 20 73-119Chloroethane 210910.0 9.68 20 80-120Chloroform 79710.0 11.7 20 72-124Chloromethane 311710.0 10.2 20 80-120cis-1,2-Dichloroethene 110210.0 10.4 20 80-120cis-1,3-Dichloropropene 110410.0 9.97 20 80-120Bromodichloromethane 210010.0 11.3 20 80-120Ethylbenzene 211310.0 9.97 20 80-1201,2-Dibromoethane 410010.0 9.94 20 80-120Methylene Chloride 499250 267 20 62-128n-Butanol 710710.0 11.6 20 81-133Styrene 211610.0 10.1 20 83-123Tetrachloroethene 510110.0 11.2 20 80-120Toluene 011210.0 10.7 20 80-120trans-1,2-Dichloroethene 110710.0 10.9 20 82-124trans-1,3-Dichloropropene 210910.0 10.4 20 80-120Trichloroethene 110410.0 10.8 20 63-140Vinyl acetate 510810.0 11.5 20 77-122Vinyl chloride 3115

FORM III 8260C

# Column to be used to flag recovery and RPD values

11/21/2016Page 44 of 150

FORM IVGC/MS VOA METHOD BLANK SUMMARY

Lab Name:

SDG No.:


Date Analyzed:

GC Column: ID:

Instrument ID: 11/15/2016 08:57

RTX-VMS40

YHeated Purge:(Y/N)

VMSZ

ZBLK0120.DLab File ID: Lab Sample ID: MB 160-279202/9

WaterMatrix:

0.18(mm)

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:

LAB SAMPLE IDLAB

FILE ID DATE ANALYZEDCLIENT SAMPLE ID 11/15/2016 07:46ZLCS0117.DLCS 160-279202/6 11/15/2016 08:10ZLCS0118.DLCSD 160-279202/7 11/15/2016 12:55ZSMP0130.D160-19949-1PW-2

FORM IV 8260C

11/21/2016Page 45 of 150

FORM V

BROMOFLUOROBENZENE (BFB)

Lab Name:

SDG No.:

Job No.: 160-19949-1

Lab File ID:

Instrument ID:

ZBFB9860.D

VMSZ

11/01/2016

20:15

BFB Injection Date:

BFB Injection Time:

M/E ION ABUNDANCE CRITERIA% RELATIVEABUNDANCE

Analysis Batch No.: 277065

50 15.0 - 40.0 % of mass 95 17.8 75 30.0 - 60.0 % of mass 95 52.4 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 7.2 173 Less than 2.0 % of mass 174 0.8 (0.7) 1174 50.0 - 120.00 % of mass 95 113.8 175 5.0 - 9.0 % of mass 174 8.0 (7.0) 1176 95.0 - 101.0 % of mass 174 108.8 (95.6) 1177 5.0 - 9.0 % of mass 176 8.1 (7.5) 2

1-Value is % mass 174

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:


GC/MS VOA INSTRUMENT PERFORMANCE CHECK


CLIENT SAMPLE IDLAB

FILE IDLAB SAMPLE IDDATE

ANALYZEDTIME

ANALYZED

ZICL9862.D 11/01/2016 21:09IC 160-277065/5ZICL9863.D 11/01/2016 21:32IC 160-277065/6ZICL9864.D 11/01/2016 21:56IC 160-277065/7ZICL9865.D 11/01/2016 22:20IC 160-277065/8ZICL9866.D 11/01/2016 22:43ICIS 160-277065/9ZICL9867.D 11/01/2016 23:07IC 160-277065/10ZICL9868.D 11/01/2016 23:31IC 160-277065/11ZICV9870.D 11/02/2016 00:18ICV 160-277065/13

FORM V 8260C 11/21/2016Page 46 of 150

FORM V

BROMOFLUOROBENZENE (BFB)

Lab Name:

SDG No.:

Job No.: 160-19949-1

Lab File ID:

Instrument ID:

ZBFB0114.D

VMSZ

11/15/2016

06:47

BFB Injection Date:

BFB Injection Time:

M/E ION ABUNDANCE CRITERIA% RELATIVEABUNDANCE

Analysis Batch No.: 279202

50 15.0 - 40.0 % of mass 95 18.7 75 30.0 - 60.0 % of mass 95 51.8 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.6 173 Less than 2.0 % of mass 174 0.5 (0.5) 1174 50.0 - 120.00 % of mass 95 109.0 175 5.0 - 9.0 % of mass 174 7.8 (7.2) 1176 95.0 - 101.0 % of mass 174 106.3 (97.6) 1177 5.0 - 9.0 % of mass 176 7.6 (7.2) 2


THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:


GC/MS VOA INSTRUMENT PERFORMANCE CHECK


CLIENT SAMPLE IDLAB

FILE IDLAB SAMPLE IDDATE

ANALYZEDTIME

ANALYZED

ZLCS0116.D 11/15/2016 07:22CCVIS 160-279202/5ZLCS0117.D 11/15/2016 07:46LCS 160-279202/6ZLCS0118.D 11/15/2016 08:10LCSD 160-279202/7ZBLK0120.D 11/15/2016 08:57MB 160-279202/9

PW-2 ZSMP0130.D 11/15/2016 12:55160-19949-1

FORM V 8260C 11/21/2016Page 47 of 150

GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY

Lab Name: Job No.:

SDG No.:

FORM VIII


Sample No.: ICIS 160-277065/9 Date Analyzed: 11/01/2016 22:43

Lab File ID (Standard): ZICL9866.D

Instrument ID: VMSZ GC Column: RTX-VMS40 ID: 0.18(mm)

Heated Purge: (Y/N) Y

Calibration ID: 11790

# RT # RT # # RT ##

FB CBNZd5 DCBd4

AREA AREA AREA

UPPER LIMIT

LOWER LIMIT

3416452

854113 695064

2780254

383091

1532362

8.86 11.70 13.88INITIAL CALIBRATION MID-POINT

9.36

8.36

12.20

11.20

14.38

13.38

1708226 1390127 766181

LAB SAMPLE ID CLIENT SAMPLE ID

ICV 160-277065/13 1974256 1572071 841728 8.86 11.71 13.88

FB = FluorobenzeneCBNZd5 = Chlorobenzene-d5DCBd4 = 1,4-Dichlorobenzene-d4

Area Limit = 50%-200% of internal standard areaRT Limit = ± 0.5 minutes of internal standard RT

# Column used to flag values outside QC limits

FORM VIII 8260C

11/21/2016Page 48 of 150

GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY

Lab Name: Job No.:

SDG No.:

FORM VIII


Sample No.: CCVIS 160-279202/5 Date Analyzed: 11/15/2016 07:22

Lab File ID (Standard): ZLCS0116.D

Instrument ID: VMSZ GC Column: RTX-VMS40 ID: 0.18(mm)

Heated Purge: (Y/N) Y

Calibration ID: 11790

# RT # RT # # RT ##

FB CBNZd5 DCBd4

AREA AREA AREA

UPPER LIMIT

LOWER LIMIT

3097692

774423 620626

2482502

329774

1319096

8.86 11.71 13.8912/24 HOUR STD

9.36

8.36

12.21

11.21

14.39

13.39

1548846 1241251 659548

LAB SAMPLE ID CLIENT SAMPLE ID

LCS 160-279202/6 1554655 1228425 654854 8.86 11.71 13.89

LCSD 160-279202/7 1607165 1263568 685381 8.86 11.70 13.88

MB 160-279202/9 1449543 1022079 479646 8.86 11.70 13.88

160-19949-1 PW-2 1160958 829072 383163 8.85 11.70 13.88

FB = FluorobenzeneCBNZd5 = Chlorobenzene-d5DCBd4 = 1,4-Dichlorobenzene-d4

Area Limit = 50%-200% of internal standard areaRT Limit = ± 0.5 minutes of internal standard RT

# Column used to flag values outside QC limits

FORM VIII 8260C

11/21/2016Page 49 of 150

FORM IGC/MS VOA ORGANICS ANALYSIS DATA SHEET

Client Sample ID:

Lab Name: Job No.:

PW-2

SDG No.:

160-19949-1

Lab Sample ID: 160-19949-1

Matrix: ZSMP0130.DLab File ID:

Date Collected:8260CAnalysis Method:

Water


11/08/2016 15:50

Sample wt/vol:

% Moisture:

GC Column:Soil Extract Vol.:

Dilution Factor:Soil Aliquot Vol: 1

Level: (low/med) Low

25(mL)

0.18(mm)

Date Analyzed: 11/15/2016 12:55

ID:RTX-VMS40

Analysis Batch No.: 279202 ug/LUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

1.0 0.1771-55-6 1,1,1-Trichloroethane ND

1.0 0.1079-34-5 1,1,2,2-Tetrachloroethane ND

1.0 0.1379-00-5 1,1,2-Trichloroethane ND

1.0 0.1075-35-4 1,1-Dichloroethene ND

1.0 0.07075-34-3 1,1-Dichloroethane ND

1.0 0.10120-82-1 1,2,4-Trichlorobenzene ND

1.0 0.4196-12-8 1,2-Dibromo-3-Chloropropane ND

1.0 0.22107-06-2 1,2-Dichloroethane ND

2.0 0.14540-59-0 1,2-Dichloroethene, Total ND

1.0 0.1078-87-5 1,2-Dichloropropane ND

5.0 0.4778-93-3 2-Butanone ND

5.0 0.25591-78-6 2-Hexanone ND

5.0 0.22108-10-1 4-Methyl-2-pentanone ND

2.0 0.5567-64-1 Acetone ND

1.0 0.1071-43-2 Benzene ND

1.0 0.1775-25-2 Bromoform ND

2.0 0.2574-83-9 Methyl bromide ND

1.0 0.1075-15-0 Carbon disulfide ND

1.0 0.1856-23-5 Carbon tetrachloride ND

1.0 0.11108-90-7 Chlorobenzene ND

1.0 0.14124-48-1 Chlorodibromomethane ND

2.0 0.1675-00-3 Chloroethane ND

1.0 0.1067-66-3 Chloroform ND

2.0 0.1074-87-3 Chloromethane ND

1.0 0.10156-59-2 cis-1,2-Dichloroethene ND

1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND

1.0 0.1475-27-4 Bromodichloromethane ND

1.0 0.12100-41-4 Ethylbenzene ND

1.0 0.13106-93-4 1,2-Dibromoethane ND

1.0 0.2775-09-2 Methylene Chloride ND

50 1271-36-3 n-Butanol ND

1.0 0.13100-42-5 Styrene ND

1.0 0.18127-18-4 Tetrachloroethene ND

1.0 0.14108-88-3 Toluene ND

1.0 0.10156-60-5 trans-1,2-Dichloroethene ND

1.0 0.1010061-02-6 trans-1,3-Dichloropropene ND

FORM I 8260C

11/21/2016Page 50 of 150

FORM IGC/MS VOA ORGANICS ANALYSIS DATA SHEET

Client Sample ID:

Lab Name: Job No.:

PW-2

SDG No.:

160-19949-1

Lab Sample ID: 160-19949-1

Matrix: ZSMP0130.DLab File ID:

Date Collected:8260CAnalysis Method:

Water


11/08/2016 15:50

Sample wt/vol:

% Moisture:

GC Column:Soil Extract Vol.:

Dilution Factor:Soil Aliquot Vol: 1

Level: (low/med) Low

25(mL)

0.18(mm)

Date Analyzed: 11/15/2016 12:55

ID:RTX-VMS40

Analysis Batch No.: 279202 ug/LUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

1.0 0.2579-01-6 Trichloroethene ND

2.0 0.18108-05-4 Vinyl acetate ND

2.0 0.1975-01-4 Vinyl chloride ND

3.0 0.271330-20-7 Xylenes, Total ND

%RECCAS NO. LIMITSQSURROGATE

97 75-12917060-07-0 1,2-Dichloroethane-d4 (Surr)

108 81-130460-00-4 4-Bromofluorobenzene (Surr)

100 81-1241868-53-7 Dibromofluoromethane (Surr)

107 87-1282037-26-5 Toluene-d8 (Surr)

FORM I 8260C

11/21/2016Page 51 of 150

Report Date: 15-Nov-2016 13:16:09 Chrom Revision: 2.2 14-Nov-2016 08:15:18

TestAmerica St. LouisTarget Compound Quantitation Report

Data File: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\ZSMP0130.DLims ID: 160-19949-A-1 Client ID: PW-2Sample Type: ClientInject. Date: 15-Nov-2016 12:55:30 ALS Bottle#: 16 Worklist Smp#: 19Purge Vol: 25.000 mL Dil. Factor: 1.0000 Sample Info: 160-0009064-019Misc. Info.: 160-19949-a-1Operator ID: EF Instrument ID: VMSZ

Method: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\25mL-8260-MSZ.mLimit Group: MSV-8260Last Update: 15-Nov-2016 13:16:09 Calib Date: 01-Nov-2016 23:31:30Integrator: RTE ID Type: Deconvolution IDQuant Method: Internal Standard Quant By: Initial CalibrationLast ICal File: \\ChromNA\StLouis\ChromData\VMSZ\20161101-8917.b\ZICL9868.D

Column 1 : RTX-VMS (40m) ( 0.18 mm) Det: MS SCANProcess Host: XAWRK013

First Level Reviewer: fishere Date: 15-Nov-2016 13:16:09

Compound SigRT

(min.)Adj RT(min.)

Dlt RT(min.) Q Response

OnCol Amtug/l Flags

3 Chloromethane 50 3.271 ND 4 Vinyl chloride 62 3.425 ND 6 Bromomethane 94 4.011 ND 7 Chloroethane 64 4.249 ND 12 1,1-Dichloroethene 96 5.282 ND 13 Carbon disulfide 76 5.324 ND S 16 1,2-Dichloroethene, Total 96 5.816 ND 20 Methylene Chloride 84 6.092 ND 21 Acetone 43 6.162 ND 22 trans-1,2-Dichloroethene 96 6.302 ND 30 1,1-Dichloroethane 63 7.028 ND 33 Vinyl acetate 43 7.279 ND 34 cis-1,2-Dichloroethene 96 7.615 ND 38 Chloroform 83 7.880 ND 40 Carbon tetrachloride 117 8.034 ND $ 42 Dibromofluoromethane (Surr 113 8.072 8.075 -0.003 94 260863 9.96 43 1,1,1-Trichloroethane 97 8.103 ND 44 2-Butanone (MEK) 43 8.187 ND 48 Benzene 78 8.467 ND $ 53 1,2-Dichloroethane-d4 (Sur 65 8.603 8.606 -0.003 89 191929 9.70 54 1,2-Dichloroethane 62 8.662 ND * 55 Fluorobenzene 96 8.854 8.858 -0.004 99 1160958 10.0 56 Trichloroethene 95 9.011 ND 59 n-Butanol 56 9.235 ND 62 1,2-Dichloropropane 63 9.514 ND 63 Dichlorobromomethane 83 9.556 ND 67 cis-1,3-Dichloropropene 75 10.115 ND $ 68 Toluene-d8 (Surr) 98 10.292 10.282 0.010 92 1044423 10.7 69 Toluene 92 10.338 ND 71 4-Methyl-2-pentanone (MIBK 43 10.645 ND 73 Tetrachloroethene 164 10.687 ND

11/21/2016Page 52 of 150

Report Date: 15-Nov-2016 13:16:09 Chrom Revision: 2.2 14-Nov-2016 08:15:18Data File: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\ZSMP0130.D

Compound SigRT

(min.)Adj RT(min.)

Dlt RT(min.) Q Response

OnCol Amtug/l Flags

72 trans-1,3-Dichloropropene 75 10.701 ND 75 1,1,2-Trichloroethane 83 10.855 ND 76 Chlorodibromomethane 129 11.036 ND 79 Ethylene Dibromide 107 11.274 ND 80 2-Hexanone 43 11.385 ND * 83 Chlorobenzene-d5 117 11.703 11.707 -0.004 83 829072 10.0 82 Ethylbenzene 91 11.707 ND 84 Chlorobenzene 112 11.721 ND 86 m-Xylene & p-Xylene 106 11.832 ND 88 o-Xylene 106 12.251 ND 89 Styrene 104 12.293 ND 90 Bromoform 173 12.363 ND $ 92 4-Bromofluorobenzene (Surr 95 12.820 12.824 -0.004 94 251358 10.8 95 1,1,2,2-Tetrachloroethane 83 12.978 ND * 108 1,4-Dichlorobenzene-d4 152 13.882 13.885 -0.003 93 383163 10.0 114 1,2-Dibromo-3-Chloropropan 157 15.100 ND 117 1,2,4-Trichlorobenzene 180 15.771 ND S 119 Xylenes, Total 106 16.500 ND

Reagents:8260 Surr 25_00067 Amount Added: 10.00 Units: uL Run ReagentI.S. Working_00139 Amount Added: 10.00 Units: uL Run Reagent

11/21/2016Page 53 of 150

Report Date: 15-Nov-2016 13:16:09 Chrom Revision: 2.2 14-Nov-2016 08:15:18TestAmerica St. Louis

Data File: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\ZSMP0130.DInjection Date: 15-Nov-2016 12:55:30 Instrument ID: VMSZ Operator ID: EFLims ID: 160-19949-A-1 Lab Sample ID: 160-19949-1 Worklist Smp#: 19Client ID: PW-2Purge Vol: 25.000 mL Dil. Factor: 1.0000 ALS Bottle#: 16Method: 25mL-8260-MSZ Limit Group: MSV-8260Column: RTX-VMS (40m) ( 0.18 mm)

2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0Min

0

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

Y (

X10

0000

)

ZSMP0130[MS SCAN Chro]:Total

$ D

ibro

mof

luor

omet

hane

(Sur

r)(

8.07

2)

$ 1,

2-D

ichl

oroe

than

e-d4

(Sur

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8.60

3)*

Flu

orob

enze

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8.85

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$ T

olue

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urr)

( 10.

292)

* C

hlor

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-d5(

11.

703)

$ 4-

Bro

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(Sur

r)( 1

2.82

0)

* 1,

4-D

ichl

orob

enze

ne-d

4( 1

3.88

2)

11/21/2016Page 54 of 150

Report Date: 15-Nov-2016 13:16:09 Chrom Revision: 2.2 14-Nov-2016 08:15:18

TestAmerica St. LouisRecovery Report

Data File: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\ZSMP0130.DLims ID: 160-19949-A-1 Client ID: PW-2Sample Type: ClientInject. Date: 15-Nov-2016 12:55:30 ALS Bottle#: 16 Worklist Smp#: 19Purge Vol: 25.000 mL Dil. Factor: 1.0000 Sample Info: 160-0009064-019Misc. Info.: 160-19949-a-1Operator ID: EF Instrument ID: VMSZ

Method: \\ChromNA\StLouis\ChromData\VMSZ\20161115-9064.b\25mL-8260-MSZ.mLimit Group: MSV-8260Last Update: 15-Nov-2016 13:16:09 Calib Date: 01-Nov-2016 23:31:30Integrator: RTE ID Type: Deconvolution IDQuant Method: Internal Standard Quant By: Initial CalibrationLast ICal File: \\ChromNA\StLouis\ChromData\VMSZ\20161101-8917.b\ZICL9868.D

Column 1 : RTX-VMS (40m) ( 0.18 mm) Det: MS SCANProcess Host: XAWRK013

First Level Reviewer: fishere Date: 15-Nov-2016 13:16:09

CompoundAmountAdded

AmountRecovered % Rec.

$ 42 Dibromofluoromethane (Surr) 10.0 9.96 99.61

$ 53 1,2-Dichloroethane-d4 (Surr) 10.0 9.70 97.02

$ 68 Toluene-d8 (Surr) 10.0 10.7 106.95

$ 92 4-Bromofluorobenzene (Surr) 10.0 10.8 107.89

11/21/2016Page 55 of 150

FORM VI

Lab Name: Job No.:

Calibration ID:

SDG No.:

Instrument ID: GC Column: Heated Purge: (Y/N)