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ABSCISIC ACID CAS # 14375452 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. Store under nitrogen. Light sensitive. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Store at -20°C SPECIAL REQUIREMENTS Light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL

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Page 1:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

ABSCISIC ACID CAS # 14375452

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed. Store under nitrogen.Light sensitive.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Storeunder nitrogen\. Store at -20°C SPECIAL REQUIREMENTS Light sensitive.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACACIA CAS # 9000015

A Special Carcinogen E Dermal Hazard I Neurotoxin

Page 2:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 16000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3

Page 3:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACENAPHTHENE CAS # 83329

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 1.5 mm Hg @ 20 °C FLASH POINT 257 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi N Indication of Danger: Irritant. Dangerous for the environment. R: 36/37/38 50/53 Risk Statements: Irritating to eyes, respiratory system and

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skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1.25 mg/m3 DOE Ceiling Limit 7.5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACENAPHTHENEQUINONE CAS # 82860

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACENAPHTHYLENE CAS # 208968

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5677.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 251.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S):

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l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .06 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 1.25 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACES CAS # 7365824

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

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toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETALDEHYDE CAS # 75070 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G H I J K L NFPA HAZARD CODES (H,F,R,O) 3 4 2 REPRODUCTIVE RISK INDEX 2.1 ACUTE TOXICTY RISK INDEX 2.9 - LD50 661.0 mg/Kg NEUROTOXIC - RISK INDEX 1.0 INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50 20100.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Lachrymator. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Photosensitizer. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Lungs. Cardiovascular system. Liver. Central nervous system.

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SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Pulmonary edema. Effects may be delayed. Nausea. Vomiting. Headache. Blurred vision. Unconsciousness.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable Explosive VAPOR PRESSURE 756.4 mm Hg @ 20 °C FLASH POINT -40 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area Forms explosive unstable peroxides Test periodically or discard

SEGREGATION: SHELF # 3STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Oxidizing agents, Reducing agents, Acids, Nitric acid,Peroxides, Bases, Caustic soda, Amines, Ammonia, Oxygen Warning:acetaldehyde is oxidized rapidly and exothermically by air, to acetic acid,Acid anhydrides, Alcohols, Halogens, Ketones, PFIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Store at 2-8°CKeep container closed. Keep away from heat, sparks, and open flame. Storeunder nitrogen.Store under inert gas. May develop pressure. Air sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Open carefully. Avoid all contamination. Always open containers slowly toallow any excess pressure to vent. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Store under nitrogen\. Store at 2-8░CSPECIAL REQUIREMENTS Store under inert gas. May develop pressure. Airsensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F+ Xn Indication of Danger: Extremely Flammable. Harmful. R: 12 36/37 40 Risk Statements: Extremely flammable. Irritating to eyes and respiratory system. Limited evidence of a carcinogenic effect. S: 16 33 36/37 Safety Statements: Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. Wear suitable protective clothing and gloves. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 100 ppm OSHA Short Term Exposure Limit 150 ppm

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ACGIH RECOMMENDED LIMITS ACGIH Ceiling Limit 25 ppm Immediately Dangerous to Life and Health 2000 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 45 ppm DOE Ceiling Limit 270 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETALDEHYDE DIMETHYL ACETAL CAS # 534156

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 6500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 11035.1

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 1 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong acids, Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure\. Refrigerate before opening. STORAGE:Store under inert gas. Keep tightly closed. Keep away from heat, sparks, andopen flame\. SPECIAL REQUIREMENTS Store under inert gas. Refrigerate beforeopening.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 9 16 33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETALDEHYDE OXIME CAS # 107299

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible

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SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 2636 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDE CAS # 60355 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 38576.3

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S)

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Liver.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .310 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases, Strongreducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place\. SPECIALREQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 Risk Statements: Limited evidence of a carcinogenic effect. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 mg/m3 DOE Short Term Exposure Limit 75 mg/m3 DOE Ceiling Limit 500 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDEPHENYLBORONIC ACID (4-) CAS # 101251096

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Boron oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDINE HYDROCHLORIDE CAS # 124425

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOACRYLIC ACID (2-) CAS # 5429561

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE

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To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOBENZALDEHYDE (4-) CAS # 122850

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Blood effects. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Mineral acids,Phenol.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOBENZENESULFONYL CHLORIDE (4-) CAS # 121608 HAZARDOUS CHEMICALOF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W ACUTE TOXICTY RISK INDEX 2.2 - LD50 3200.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 37 Risk Statements: Harmful if swallowed. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOBENZOIC ACID (PARA-) CAS # 556081

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOCINNAMIC ACID (ALPHA-) CAS # 5469454

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CHygroscopic.Keep container closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep container closed. Store in a cool dry place. Store at 2-8░CSPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOPHENOL (2-) CAS # 614802

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 125.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 500 mg 24H Remarks: Mild irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOPHENOL (3-) CAS # 621421

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 196.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAMIDOPHENOL (4-) CAS # 103902

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . H . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2404.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear

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suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETANILIDE CAS # 103844

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 800.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .180 mm Hg @ 20 °C FLASH POINT 321.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 7.5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETAZOLAMIDE CAS # 59665

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 13871.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. EyeContact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Eyes. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Headache. Fatigue. Anorexia. Gastrointestinal disturbances. Drowsiness. To the best of our knowledge, the chemical, physical, and toxicological properties

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have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETHYDRAZIDE CAS # 1068571 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . C . . F G . . . K . NFPA HAZARD CODES (H,F,R,O) 0 1 1 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.2 - TD50 31.8 mg/Kg EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 42.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin,on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Storeunder nitrogen\. SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/38 Risk Statements: Harmful if swallowed. Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETIC ACID CAS # 64197

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg INHALATION HAZARD

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INHALATION RISK INDEX 2.2 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSUR To the best of our knowledge, the chemical,physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid VAPOR PRESSURE 11.4 mm Hg @ 20 °C

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10-35 Risk Statements: Flammable. Causes severe burns. S: 23-26-45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 35 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETIC ACID-D CAS # 1186523

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Lachrymator. Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Ingestion or inhalation of concentrated acetic acid causes damage to tissues of the respiratory and digestive tracts. Symptoms include: hematemesis, bloody diarrhea, edema and/or perforation of the esophagus and pylorus, hematuria, anuria, uremia, albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, cardiovascular collapse, shock, and death. Direct contact or exposure to high concentrations of vapor with skin or eyes can cause: erythema, blisters, tissue destruction with slow healing, skin blackening, hyperkeratosis, fissures, corneal erosion, opacification, iritis, conjunctivitis, and possible blindness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Severe, acute pancreatitis may occur after ingestion of concentrated acetic acid.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 11.4 mm Hg @ 20 °C FLASH POINT 104 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Oxidizing agents, Soluble carbonates and phosphates,Hydroxides, Oxides, Metals, Peroxides, Permanganates, Amines, Alcohols.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store underinert gas. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 35 Risk Statements: Flammable. Causes severe burns. S: 23 26 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETIC ACID-D CAS # 758123

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50

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ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Inhalation: May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Ingestion or inhalation of concentrated acetic acid causes damage to tissues of the respiratory and digestive tracts. Symptoms include: hematemesis, bloody diarrhea, edema and/or perforation of the esophagus and pylorus, hematuria, anuria, uremia, albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, cardiovascular collapse, shock, and death. Direct contact or exposure to high concentrations of vapor with skin or eyes can cause: erythema, blisters, tissue destruction with slow healing, skin blackening, hyperkeratosis, fissures, corneal erosion, opacification, iritis, conjunctivitis, and possible blindness.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 7.6 mm Hg @ 20 °C FLASH POINT 104 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Soluble carbonates andphosphates, Hydroxides, Oxides, Metals, Acid anhydrides, Peroxides,Permanganates, Amines.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not get in eyes, on skin, on clothing. Do not breathe vapor.STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in acool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 35 Risk Statements: Flammable. Causes severe burns. S: 23 26 45

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Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETIC ANHYDRIDE CAS # 108247 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G H . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W ACUTE TOXICTY RISK INDEX 3 - LD50 1780.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 4166.9

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 120.2 °F Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive

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l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Bases, Reducing agents, Finely powdered metals, Alcohols,Acids, Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.Store at 2-8°CKeep tightly closed. Keep away from heat and open flame. Store in a cool dryplace.Reacts violently with water.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place. Store at 2-8░C SPECIALREQUIREMENTS Reacts violently with water.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10-20/22-34 Risk Statements: Flammable. Harmful by inhalation and if swallowed. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Ceiling Limit 5 ppm OSHA Ceiling Limit 20 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 5 ppm ACGIH Ceiling Limit 21 ppm Immediately Dangerous to Life and Health 200 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 5 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOACETANILIDE CAS # 102012

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 1 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1600.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 325 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOACETIC ACID ETHYL ESTER CAS # 141979

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3980.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .700 mm Hg @ 20 °C FLASH POINT 185 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26

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Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ACETOACETIC ACID ETHYL

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOL CAS # 116096

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2200.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 5.6 mm Hg @ 20 °C FLASH POINT 132.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong acids, Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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Store at 2-8°CKeep container closed. Keep away from heat, sparks, and open flame.Hygroscopic. Store under inert gas. Air sensitive.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Do not breathevapor. Avoid prolonged or repeated exposure. STORAGE: Keep container closed.Keep away from heat, sparks, and open flame. Store at 2-8░C SPECIALREQUIREMENTS Hygroscopic. Store under inert gas. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 200 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETONAPHTHALENE (1'-) CAS # 941980

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1560.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible

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FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents, Strongbases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETONAPHTHONE (2'-) CAS # 93083

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1032.8 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 334.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducingagents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETONE CAS # 67641

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . H I . . L NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5800.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50 13640.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 184.0 mm Hg @ 20 °C FLASH POINT 1 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents Acetone reactsviolently with phosphorous oxychloride.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36 66 67 Risk Statements: Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness. S: 9 16 26 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 750 ppm OSHA Short Term Exposure Limit 1000 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 500 ppm ACGIH Short Term Exposure Limit 1000 ppm

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Immediately Dangerous to Life and Health 2500 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 ppm DOE Short Term Exposure Limit 200 ppm DOE Ceiling Limit 3200 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETONE-D6 CAS # 666524

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . H I . . L NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5800.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50 13640.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 184.0 mm Hg @ 20 °C FLASH POINT -2.2 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S):

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l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Materials to Avoid: BFIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water may be effective for cooling, but may not effect extinguishment.

REACTIVE PROPERTIESHANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Store in a cool dry place. Storeunder inert gas\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36 66 67 Risk Statements: Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness. S: 9 16 26 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 750 ppm OSHA Short Term Exposure Limit 1000 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 500 ppm ACGIH Short Term Exposure Limit 1000 ppm Immediately Dangerous to Life and Health 2500 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 ppm DOE Short Term Exposure Limit 200 ppm DOE Ceiling Limit 3200 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETONITRILE CAS # 75058 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . D . . G H I J K . NFPA HAZARD CODES (H,F,R,O) 2 3 0 REPRODUCTIVE RISK INDEX 1.9 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2460.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.9 - LC50 9475.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. Blood. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE The onset of symptoms is generally delayed pending conversion to cyanide. This material can produce a cyanide like effect. Always have a cyanide first-aid kit present when using this material. Adverse effects may include nausea, vomiting, diarrhea, headache, dizziness, rashes and cyanosis. Other symptoms include mental excitement or depression, drowsiness, impaired perception, incoordination, stupor, coma, and death. CONDITIONS AGGRAVATED BY EXPOSURE Acetonitrile is metabolized in the liver to water, formic acid, and hydrogen cyanide. The cyanide is further metabolized to thiocyanate.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 72.8 mm Hg @ 20 °C FLASH POINT 35.6 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents, Alkalimetals.FIRE EXTINGUISHER: For small (incipient) fires, use media such as foam,drychemical, or carbon dioxide. For large fires, use media such as foam, drychemical, carbon dioxide or water.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Handle and store under nitrogen\.

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SPECIAL REQUIREMENTS Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F-Xn Indication of Danger: Highly Flammable. Harmful. R: 11-20/21/22-36 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes. S: 16-36/37 Safety Statements: Keep away from sources of ignition - no smoking. Wear suitable protective clothing and gloves. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 40 ppm OSHA Short Term Exposure Limit 60 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 20 ppm ACGIH Short Term Exposure Limit 60 ppm Immediately Dangerous to Life and Health 25 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 ppm DOE Short Term Exposure Limit 60 ppm DOE Ceiling Limit 60 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOPHENETIDIN CAS # 62442

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1650.0 mg/Kg INHALATION RISK INDEX <1 - LC50 10509.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S)

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Blood. Kidneys. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases,Strong reducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 Risk Statements: May cause cancer. Harmful if swallowed. S: 53 45 Safety Statements: Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOPHENONE CAS # 98862 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 4 - LD50 815.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.0 - LC50 1200.0

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 1.3 mm Hg @ 20 °C FLASH POINT 168.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducingagents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 10 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

Page 46:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOXYACETAL CHLORIDE CAS # 13831317 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 160 °F Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Alcohols Reactsviolently with water.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place. Store under nitrogen\.

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Incompatible Materials: Do not allow contact with water

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 36/37 Risk Statements: Reacts violently with water. Causes burns. Irritating to eyes and respiratory system. S: 23 26 27 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOXYBENZOIC ACID (3-) CAS # 6304898

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOXYETHANOL (2-) CAS # 542596 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8250.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Nausea,headache, and vomiting. Symptoms of ethylene glycol toxicity: when ingested early symptoms mimic alcohol inebriation and are followed by nausea, vomiting, abdominal pain, weakness, muscle tenderness, respiratory failure, convulsions, cardiovascular collapse, pulmonary edema, hypocalcemic tetany, and severe metabolic

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acidosis. Without treatment, death may occur in 8 to 24 hours. Victims who survive the initial toxicity period usually develop renal failure along with brain and liver damage. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 190.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETOXYPYRIDONE (3:2,1H-) CAS # 61296148

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1700.0 mg/Kg

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause skin sensitization SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYL BENZONITRILE (4-) CAS # 1443807

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL CHLORIDE CAS # 75365 HAZARDOUS CHEMICAL OF CONCERN

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 1 W ACUTE TOXICTY RISK INDEX 2.7 - LD50 910.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.0 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 604.4 mm Hg @ 20 °C FLASH POINT 41 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place\. IncompatibleMaterials: Do not allow contact with water Special REQUIREMENTS Readilyhydrolyzed. Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F C

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Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 9 16 26 45 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0025 ppm DOE Short Term Exposure Limit .0075 ppm DOE Ceiling Limit .05 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL CYCLOHEXANE (1:1-) CAS # 932661

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 150 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

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REACTIVE PROPERTIESHANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL CYSTEINE CAS # 616911

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5050.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause bronchospasm, nausea, vomiting, stomatitis, and nasaldischarge.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Heavy metals, Heavy metal salts, Rubber, Oxygen, Oxidizingagents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL GALACTOSAMINE CAS # 14215680

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL GALACTOSAMINE (N,D-) CAS # 1811310

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL GLUCOSAMINE CAS # 7512176

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYL HISTIDINE MONOHYDRATE (ALPHA-) CAS # 39145523

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, STORAGE: Keeptightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL LYSINE CAS # 1946823

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation.

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Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL METHIONINE CAS # 1115475

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL METHIONINE (N,L-) CAS # 65827

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIES

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STORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL PIPERIDONE (1,4-) CAS # 32161061

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL THIOUREA CAS # 591082

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves,

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and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL TRYPTOPHAN CAS # 87321

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLIN User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYL TYROSINE CAS # 537553

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYLACETONATODICARBONYL RHODIUM(I) CAS # 14874829

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE May liberate 2,4-pentanedione upon decomposition. 2,4-Pentanedione has the following toxicological hazards: toxic, irritant, neurological hazard, teratogen, possible mutagen, target organ - thymus. In humans, 2,4-pentanedione is reported to cause contact dermatitis and contact urticaria. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 63 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Possible risk of harm to the unborn child. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLALANINE (N,L-) CAS # 97698

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYLAMINOPHENYL BORONIC ACID (3-) CAS # 78887395

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Boron oxides Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLBENZOIC ACID (2-) CAS # 577560

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLBENZOIC ACID (4-) CAS # 586890

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLBENZONITRILE (3-) CAS # 6136681

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLCAPROLACTAM (N-) CAS # 1888911

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1300.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 251.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLCHOLINE BROMIDE CAS # 66239

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation.

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TARGET ORGAN(S) OR SYSTEM(S) Vascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gasStore at -20°CHygroscopic.Keep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Store at -20░C SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLCHOLINE CHLORIDE CAS # 60311

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0

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ACUTE TOXICTY RISK INDEX 2.3 - LD50 2500.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and uppe respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Vascular system. Heart. Central nervous system. Smooth muscle. Skeletal muscle. Adrenal medulla. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Spastic paralysis

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at -20°CVery hygroscopic. Store under inert gas.Keep tightly closed. Store under nitrogen.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Storeunder nitrogen\. Store at -20░C SPECIAL REQUIREMENTS Very hygroscopic. Storeunder inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLCHOLINE IODIDE CAS # 2260506

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4838.7 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Vascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray.TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Nitrogen oxidesStore at 2-8°Hygroscopic.Keep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Store at 2-8░ SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36

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Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLCHOLINESTERASE CAS # 9000811

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESSTORAGE Store at 2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYLCYSTEAMINE (N-) CAS # 1190734

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Air sensitive. Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLENE DICARBOXYLATE CAS # 762210

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 201.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLENEDICARBOXYLIC ACID CAS # 142450

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 203.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Bases, Reducing agents, Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at

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2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLENEDICARBOXYLIC ACID MONOPOTASSIUM CAS # 928041

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 203.2 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Bases, Reducing agents, Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

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REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 23/25 27 36/37/38 Risk Statements: Toxic by inhalation and if swallowed. Very toxic in contact with skin. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLETHYLENEDIAMINE (N-) CAS # 1001532

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 1 ACUTE TOXICTY RISK INDEX 2 - LD50 5100.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible

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FLASH POINT 230 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Store under inert gas. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor spray. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLFERROCENE (1-) CAS # 1271552

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.3 - LD50 25.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Iron oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 28 Risk Statements: Very toxic if swallowed. S: 28 36/37 45 Safety Statements: After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLGLYCINE CAS # 543248

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

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toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLGUANIDINE (1-) CAS # 5699401

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLHYDROXAMIC ACID CAS # 546883

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: IDE NITROGEN OXIDES

REACTIVE PROPERTIESDURING PREPARATION OF OXIME FROM AN ALDEHYDE, AN ETHER SOLUTION OFTHEREACTION MIXTURE, CONTAINING HYDROXYLAMINE HYDROCHLORIDE DECOMPOSEDVIOLENTLYUNDER VACUUM DISTILLATION AT 80F. SOLID HYDROXYLAMINE SULFATE WILLEXPLODEWHEN HEATED TO 170C. MAY CAUSE EXPLOSIVE DECOMPOSITION OF MALEICANHYDRIDE. REACTS VIOLENTLY WITH TRIISOBUTYL ALUMINUM. MINOR AMOUNTS OF ACIDCAUSEACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT. BENZYL ALCOHOL CONTAININGACIDICCONSTITUENTS AND DISSOLVED IRON WAS FOUND TO POLYMERIZE WITH ARAPIDTEMPERATURE INCREASE WHEN HEATED IN EXCESS OF 100C.(AMINES, PYRIDINE,ANDALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENT POLYMERIZATION.)

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REACTVIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGH CONCENTRATIONS OF ACIDREACTEXPLOSIVELY WITH NICKEL NITRIDE AND HEAT. INITIATE A FAST DECOMPOSITIONOFSODIUM OZONATE. REACTS WITH THORIUM PHOSPHIDE TO RELEASESPONTANEOUSLYFLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITH TRI-ISO-BUTYLALUMINUM.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLINDOLE (3-) CAS # 703800

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESSTORAGE -

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLINDOLE CARBOXALDEHYDE (1:3-) CAS # 22948943

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

Page 87:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLMANNOSAMINE (N,D-) CAS # 7772943

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ACETYLPHENYL ISOCYANATE (3-) CAS # 23138649

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 7 26 27 37/39

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Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLPHENYL ISOCYANATE (4-) CAS # 49647203

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 7 26 27 37/39 Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLPHENYLBORONIC ACID (3-) CAS # 204841190

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLPHENYLBORONIC ACID (4-) CAS # 149104905

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLPHENYLHYDRAZINE (1,2-) CAS # 114830 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . . . . F G . . . K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.3 - TD50 26.0 mg/Kg ACUTE TOXICTY RISK INDEX 2.8 - LD50 871.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction.

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TARGET ORGAN(S) OR SYSTEM(S) Liver. Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLPIPERAZINE (1-) CAS # 13889980

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAG Suitable: Keep tightly closed. Store in a cool dry place. Storeunder nitrogen\. SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLSALICYLIC ACID CAS # 50782

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLTHIOCHOLINE CHLORIDE CAS # 6050813

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at -20°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLTHIOCHOLINE IODIDE (S-) CAS # 1866155

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen iodide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic. Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 21 36/37/38 Risk Statements: Toxic if swallowed. Harmful in contact with skin. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLTHIOGLYCOLIC ACID HYDROXYSUCCINAMIDE ESTER ( CAS # 76931936

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLTRIBENZOYL RIBOFURANOSE (10:2,3,5:ORTHO-) CAS # 6974329

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store at 2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACETYLTYROSINE ETHYL ESTER CAS # 36546506

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID ALIZARIN VIOLET N CAS # 2092559

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID BLUE 45 CAS # 2861021

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9354.8 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Sodium/sodiumoxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.5 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 250 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID FUCHSIN CAS # 3244880

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID GREEN 25 CAS # 4403901

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Sodium oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID ORANGE 74 CAS # 10127272

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID ORANGE I CAS # 523444

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 546.0 mg/Kg INHALATION RISK INDEX <1 - LC50

TOXICITY DATA

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin

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and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID PHOSPHATASE CAS # 9001778

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep container closed. Store away from heat.

REACTIVE PROPERTIESSTORAGE: Keep container closed. Store away from heat. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID RED 1 CAS # 3734676

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID VIOLET 7 CAS # 4321691

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 23160.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACID YELLOW CAS # 6359906

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACLARUBICIN CAS # 57576440

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract.

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Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. Nausea, vomiting, diarrhea. Blood effects. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.Light sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39-45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACONIC ACID CAS # 585682

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACONITIC ACID (CIS-) CAS # 585842

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: ON MONOXIDEHYDROGEN CHLORIDE

REACTIVE PROPERTIESMINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OFHEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WASFOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESSOF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS ANDPREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE.HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE ANDHEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITHTHORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTSVIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACONITIC ACID (TRANS-) CAS # 4023658

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: ON MONOXIDEHYDROGEN CHLORIDE

REACTIVE PROPERTIES

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MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OFHEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WASFOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESSOF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS ANDPREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE.HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE ANDHEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITHTHORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTSVIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRIDINE CAS # 260946

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . I . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. Nerves. Blood. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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CONDITIONS AGGRAVATED BY EXPOSUR Causes sneezing. Do not inhale.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .000500 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLIN User Exposure: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRIDINE ORANGE CAS # 10127023

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRIDINE ORANGE FREE BASE CAS # 494382

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1.25 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 40 mg/m3ACRIDINE ORANGE FREE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRIDINE ORANGE HYDROCHLORIDE CAS # 65612

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE

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To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRIFLAVINE CAS # 8048520

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1048.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Cardiovascular effects. CNS depression. Respiratory depression.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 22 37/38 41 50/53 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 39 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACROLEIN CAS # 107028 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . B C D E F G H . J . . NFPA HAZARD CODES (H,F,R,O) 4 4 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 4.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED

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ACUTE TOXICTY RISK INDEX 5 - LD50 26.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.8 - LC50 46.8

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Cardiovascular system. Lungs. Eyes. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 209.4 mm Hg @ 20 °C FLASH POINT -20.2 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents, Oxygen, Bases, Strong acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Store at 2-8°CKeep tightly closed. Keep away from heat, sparks, and open flame.Store under inert gas. May develop pressure. Open carefully. Light sensitive.Heat- and air-sensitive

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store at 2-8░C SPECIAL REQUIREMENTS Storeunder inert gas. May develop pressure. Open carefully. Light sensitive.Heat- and air-sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F T+ N Indication of Danger: Highly Flammable. Very toxic. Dangerous

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for the environment. R: 11 24/25 26 34 50 Risk Statements: Highly flammable. Toxic in contact with skin and if swallowed. Very toxic by inhalation. Causes burns. Very toxic to aquatic organisms. S: 23 26 28 36/37/39 45 61 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .1 ppm OSHA Short Term Exposure Limit .3 ppm

ACGIH RECOMMENDED LIMITS ACGIH Short Term Exposure Limit .1 ppm Immediately Dangerous to Life and Health 2 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .03 ppm DOE Short Term Exposure Limit .03 ppm DOE Ceiling Limit .1 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACROLEIN DIMETHYLACETAL CAS # 6044684

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Liquid Flammable FLASH POINT 26.6 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents, Acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.Store at 2-8°CKeep tightly closed. Keep away from heat, sparks, andopen flame. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame.Store in a cool dry place. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16-29-33-23-24/25 Safety Statements: Keep away from sources of ignition - no smoking. Do not empty into drains. Take precautionary measures against static discharges. Do not breathe vapor. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACROLIEN DIETHYL ACETAL CAS # 3054953

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 59 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 9 16 33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACROLOYLMORPHOLINE (4-) CAS # 5117124

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 588.0 mg/Kg INHALATION RISK INDEX <1 - LC50 5280.0

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Nausea. Headache. Exposure can cause:

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Polymerizing initiators, Free radical initiators,Peroxides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CLight sensitive.Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Store in a cool dry place.Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-41-43-48/22 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. S: 23-26-36/37/39 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLAMIDE CAS # 79061 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B . D E . . . I . . L NFPA HAZARD CODES (H,F,R,O) 2 1 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.1 - TD50 3.8 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 4.8 ACUTE TOXICTY RISK INDEX 4 - LD50 124.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 1500.0

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Acrylamide toxicity is manifested as a sensorimotor peripheral neuropathy. Symptoms include: drowsiness, loss of balance, confusion, memory loss, hallucinations, numbness, paresthesias (ataxia, tremor, dysarthria), and incoordination.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .380 mm Hg @ 20 °C FLASH POINT 280 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible Solvent

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Avoid contact with acid., Oxidizing agents Iron and ironsalts., Copper, Brass, Free radical initiatorsFIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45-46-20/21-25-36/38-43-48/23/24/25-62 Risk Statements: May cause cancer. May cause heritable genetic damage. Also harmful by inhalation and in contact with skin. Also toxic if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of impaired fertility. S: 53-45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .03 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 60 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLIC ACID CAS # 79107 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 2 0

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ACUTE TOXICTY RISK INDEX 4 - LD50 2590.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.0 - LC50 1643.0

ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe burns. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 114.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 10 20/21/22 35 50 Risk Statements: Flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes severe burns. Very toxic to aquatic organisms. S: 26 36/37/39 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear

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suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 10 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 46 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLONITRILE CAS # 10713 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E F G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 3 1 ACUTE TOXICTY RISK INDEX 4 - LD50 78.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50 721.2

cancer hazard ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Central nervous system. Cardiovascular system. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Symptoms of exposure may include burning sensation, coughing, wheezing,

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laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. May be partially metabolized to cyanide in the body. CNS depression. Ataxia. Symptoms may be delayed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 86.0 mm Hg @ 20 °C FLASH POINT 23 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents Copper, Copper alloys.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame\. SPECIAL REQUIREMENTS Heat and lightsensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 45 11 23/24/25 41 43 51/53 37/38 Risk Statements: May cause cancer. Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. S: 53 9 16 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLONITRILE CAS # 107131 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . . D E . G H I . K L NFPA HAZARD CODES (H,F,R,O) 4 3 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.4 - TD50 16.9 mg/Kg ACUTE TOXICTY RISK INDEX 3.8 - LD50 78.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50

cancer hazard ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Central nervous system. Cardiovascular system. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. May be partially metabolized to cyanide in the body. CNS depression. Ataxia. Symptoms may be delayed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 86.0 mm Hg @ 20 °C FLASH POINT 23 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S):

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l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Oxidizing agents Copper, Copper alloys.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame\. SPECIAL REQUIREMENTS Heat and lightsensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 45 11 23/24/25 41 43 51/53 37/38 Risk Statements: May cause cancer. Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. S: 53 9 16 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 85 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 35 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLOYL CHLORIDE CAS # 814686 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . C D . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 4 3 1 W EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 28.5

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Lachrymator. Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 57.2 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Alcohols, Oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water.TOXIC EMISSIONS WHEN BURNED: Phosgene gas Hydrogen chloride gasStore at 2-8°CKeep tightly closed. Keep away from heat, sparks, and open flame. Do notallow contact with waterLight sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame\. Incompatible Materials: Do not allowcontact with water Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F-T+ Indication of Danger: Highly Flammable. Very toxic. R: 11-14-26-34 Risk Statements: Highly flammable. Reacts violently with water.

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Very toxic by inhalation. Causes burns. S: 7/9-16-26-36/37/39-45-28 Safety Statements: Keep container tightly closed and in well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). After contact with skin, wash immediately with plenty of water.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 ppm DOE Short Term Exposure Limit .15 ppm DOE Ceiling Limit .243 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACRYLOYL CYSTAMINE (N,N',BIS-) CAS # 60984578

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTH CAS # 12279413

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Stimulates the adrenal cortex. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTIDIONE CAS # 66819

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . I J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5+ - LD50 2.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation.

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Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Kidneys. Adrenal cortex. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Dermatitis. Nausea, vomiting, diarrhea. Tremors. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .006000 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Bases, Strong oxidizing agents, Acid anhydrides, Acidchlorides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 61 28 51/53 68 Risk Statements: May cause harm to the unborn child. Also very toxic if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Also possible risks of irreversible effects. S: 53 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3

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DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit 2 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTINOMYCIN C CAS # 8052162 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B C D . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 5++ - TD50 .0 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 7.2 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes burns. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Bone marrow. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Anemia. Drowsiness. Weakness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong bases, Strong acids, Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightlyclosed\. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 46-61-26/27/28 Risk Statements: May cause heritable genetic damage. May cause harm to the unborn child. Very toxic by inhalation, in contact with skin and if swallowed. S: 53-36/37/39-45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTINOMYCIN D CAS # 50760 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B C . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 5++ - TD50 .0 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 7.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed.

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Chronic ingestion of large doses may cause gastrointestinal disturbances including nausea and diarrhea, urinary effects involving urine acidification, oxalate and uric crystallizaton in the bladder and kidney, and decreased reaction times and

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: surrounding fire conditions.

REACTIVE PROPERTIESHANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keeptightly closed. SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTIVATED CARBON CAS # 64365113

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

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FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: AIR PROMOTES THE OXIDATION OF THE SODIUM BOROHY

REACTIVE PROPERTIESEXPLOSIONS MAY OCCUR WHEN MIXED WITH: AMMONIUM NITRATE, AMMONIUMPERCHLORATE,BROMATES, CHLORATES OR IODATES OF BARIUM, CALCIUM, MAGNESIUM,POTASSIUM,SODIUM OR ZINC, CALCIUM HYPOCHLORITE, CHLORINE, CHLORINE MONOXIDE,FLUORINE,IODINE PENTOXIDE, MERCUROUS NITRATE, NITRIC ACID, ZINC NITRATE. FATTY OILSARE SPONTANEOUSLY FLAMMABLE WHEN DISTRIBUTED IN ACTIVATED CARBON.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3ACTIVATED CARBON CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACTIVATED COCOANUT CHARCOAL CAS # 7740440

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: AIR PROMOTES THE OXIDATION OF THE SODIUM BOROHY

REACTIVE PROPERTIESEXPLOSIONS MAY OCCUR WHEN MIXED WITH: AMMONIUM NITRATE, AMMONIUMPERCHLORATE,BROMATES, CHLORATES OR IODATES OF BARIUM, CALCIUM, MAGNESIUM,POTASSIUM,SODIUM OR ZINC, CALCIUM HYPOCHLORITE, CHLORINE, CHLORINE MONOXIDE,FLUORINE,IODINE PENTOXIDE, MERCUROUS NITRATE, NITRIC ACID, ZINC NITRATE. FATTY OILSARE SPONTANEOUSLY FLAMMABLE WHEN DISTRIBUTED IN ACTIVATED CARBON.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ACYLASE I CAS # 9012377

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESSTORAGE: Keep tightly closed. Store at -20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ADAMANTANAMINE (1-) CAS # 768945

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 900.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANAMINE HYDROCHLORIDE CAS # 665667

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 900.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical,physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANAMINE HYDROCHLORIDE (2-) CAS # 10523689

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

Page 144:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANECARBONYL CHLORIDE (1-) CAS # 2094726 HAZARDOUS CHEMICAL OFCONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 230 °F Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION

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Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 37 Risk Statements: Reacts violently with water. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANECARBOXYLIC ACID (1-) CAS # 828513

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in

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a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANEMETHYLAMINE (1-) CAS # 17768411

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 198 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place. Store under nitrogen.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADAMANTANOL (1-) CAS # 768956

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ADAMANTANONE (2-) CAS # 700583

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION R: 52 Risk Statements: Harmful to aquatic organisms. S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ADAMANTYL BROMOMETHYL KETONE (1-) CAS # 5122827

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ADAMANTYL UREA (N,1-) CAS # 13072690

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 432.9 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENINE CAS # 73245

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K .

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NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 227.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENINE HEMISULFATE CAS # 321302

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENINE HYDROCHLORIDE CAS # 6055727

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENOSINE CAS # 58617

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX .9 - LD50 64516.1 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause dilation of the blood vessels and an increase in contraction of some smooth muscles.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENOSINE DIPHOSPHATE SODIUM (5'-) CAS # 20398349

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation.

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mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. effect. May cause convulsions. Weakness. Ingestion can cause: Nausea, headache, and vomiting. Dizziness. Confusion. Unconsciousness. Can cause CNS depression. Methyl alcohol may be fatal or cause blindness if swallowed. Cannot be made non-poisonous.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acidanhydrides, Oxidizing agents, Alkali metals, Reducing agents, Ammonia,Peroxides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Phosphorous oxides

REACTIVE PROPERTIESHANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE:Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn R: 20/21/22 68/20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Harmful: possible risk of irreversible effects through inhalation, in contact with skin, and if swallowed. Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENOSINE MONOPHOSPHATE CAS # 18422054

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADENOSINE TRIPHOSPHATE DISODIUM (5'-) CAS # 51963612

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADIPAMIDE CAS # 628944

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 19354.8 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled.

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Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADIPIC ACID CAS # 124049

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5050.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .130 mm Hg @ 20 °C FLASH POINT 385 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADIPIC DIHYDRAZIDE CAS # 1071938

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADIPOYL CHLORIDE CAS # 111502 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 233.6 °F Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC CORROSIVE

INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Phosgene gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Moisture sensitive. Store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADONITOL CAS # 488813

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADRENALIN CAS # 51434

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranesand upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Heart. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Laboratory experiments in animals have shown fetotoxic results.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cooldry place\. SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .25 mg/m3 DOE Ceiling Limit .25 mg/m3

Page 164:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ADRENOCORTICOTROPIC HORMONE CAS # 9061272

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Stimulates the adrenal cortex. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40

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Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AGAR CAS # 9002180

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Moisture sensitive.

US DEPARTMENT OF ENERGY TEEL'S

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DOE Occupational Exposure Limit 500 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AGAROSE CAS # 68652905

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AGAROSE CAS # 9012366

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE CAS # 338692

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (BETA-) CAS # 107959

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (BOC,BETA-) CAS # 3303842

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

S PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (BOC-) CAS # 15761383

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°C

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Keep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (DL-) CAS # 302727

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: de and nitrogen oxides HAZARDOUS POLYMERIZATION Hazardous Polym

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi

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Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (FMOC,BETA-) CAS # 35737101

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin

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and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (FMOC,L-) CAS # 35661393

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightlyclosed\. Store at 2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

Page 174:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE (L-) CAS # 56417

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE HYDROXYSUCCINIMIDE ESTER (BOC,L-) CAS # 3392050

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

S PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE METHYL ESTER HYDROCHLORIDE (BETA-) CAS # 3196734

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

S PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALANINE METHYL ESTER HYDROCHLORIDE (L-) CAS # 2491205

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION

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S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBAMYCIN CAS # 1476535

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 129.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Liver. Kidneys. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Flammable

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIES User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. Do not use if skin is cutor scratched. Wash thoroughly after handling. Suitable: Keep tightlyclosed. Keep away from heat, sparks, and open flame. Store underinert gas. Hygroscopic.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. Risk Statements: May cause sensitization by skin contact. S: 36 Safety Statements: Wear suitable protective clothing. Indication of Danger: Irritant. Risk Statements: May cause sensitization by skin contact. Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBENDAZOLE CAS # 54965218

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2400.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBUMIN CAS # 70024907

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Potentially biohazardous material.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: B Indication of Danger: Biohazard.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBUMIN CAS # 9048468

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

US DEPARTMENT OF ENERGY TEEL'S

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DOE Occupational Exposure Limit 150 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBUMIN (EGG WHITE) CAS # 9006502

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBUMIN (EGG) CAS # 9006591

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 24000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALBUMIN BOVINE CAS # 2329362

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALCIAN BLUE 8GK CAS # 75881231

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas Copper oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALCIAN BLUE 8GX CAS # 33864992

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALCOHOL DEHYDROGENASE CAS # 9031725

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at -20°CHygroscopic.Keep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C SPECIAL REQUIREMENTS Hygroscopic.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALDOLASE CAS # 9024526

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfireconditions.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Storeaway from heat.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALDRIN CAS # 309002 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B C . E . . . I . . . NFPA HAZARD CODES (H,F,R,O) 4 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.1 - TD50 4.1 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 39.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Reproductive system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Headache. Tremors. Incoordination. Dizziness. Cyanosis. Seizures. Unconsciousness.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 24/25 40 48/24/25 50/53

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Risk Statements: Toxic in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22 36/37 45 60 61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 10 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALDRIN CAS # 309012 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 4 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 39.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Reproductive system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Headache. Tremors.

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Incoordination. Dizziness. Cyanosis. Seizures. Unconsciousness.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 24/25 40 48/24/25 50/53 Risk Statements: Toxic in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22 36/37 45 60 61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALGINIC ACID AMMONIUM-CALCIUM CAS # 9005316

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALGINIC ACID SODIUM CAS # 9005383

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

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toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN CAS # 72480

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5+ - LD50 4.5 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.25 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 25 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN BLUE BLACK B CAS # 1324216

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN RED S CAS # 130223

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN YELLOW 2 G CAS # 584429 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin EyeContact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sodium oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN YELLOW R CAS # 2243767 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALIZARIN YELLOW R SODIUM CAS # 1718349 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALKALI BLUE 6B CAS # 1324761

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALKALINE PHOSPHATASE CAS # 9001789

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALLANTOIN CAS # 97596

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLOC ETHYLENEDIAMINE (N-) CAS # 223741660

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLOXAN MONOHYDRATE CAS # 2244113

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Pancreas. SIGNS AND SYMPTOMS OF EXPOSURE Alloxan has been used to produce diabetes in animals by selective necrosis of the pancreatic islet beta-cells. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. Open carefully. STORAGE: Keep tightly closed\. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLOXAN TETRAHYDRATE CAS # 50715

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5210.0 mg/Kg INHALATION RISK INDEX <1 - LC50

TOXICITY DATA

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°C

REACTIVE PROPERTIESSTORAGE Store at 2-8°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLOXAN TETRAHYDRATE CAS # 6010919

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous

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membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Pancreas. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8°C SPECIAL REQUIREMENTS May develop pressure. Open carefully.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL ACETATE CAS # 591877

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 130.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 4086.5

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs.

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SIGNS AND SYMPTOMS OF EXPOSURE Damage to the lungs.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 51.8 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Oxidizing agents, Bases, Peroxides.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water may be effective for cooling, but may not effect extinguishment

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 11 21 23/25 36 Risk Statements: Highly flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes. S: 16 26 36 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 10 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL ALCOHOL CAS # 107186 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E F G H I J K L NFPA HAZARD CODES (H,F,R,O) 4 3 0 ACUTE TOXICTY RISK INDEX 4 - LD50 64.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 3.7 - LC50 1000.0

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) Lungs. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 19.0 mm Hg @ 20 °C FLASH POINT 72 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE

INCOMPATIBILITIES:Alkali metals, Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIES

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HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place. Handle andstore under nitrogen\. SPECIAL REQUIREMENTS Handle and store under inertgas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 10 23/24/25 36/37/38 50 Risk Statements: Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms. S: 36/37/39 38 45 61 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm OSHA Short Term Exposure Limit 4 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .5 ppm Immediately Dangerous to Life and Health 20 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 2.1 ppm DOE Ceiling Limit 4.2 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL BROMIDE CAS # 106956

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 120.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 4110.0

ROUTE OF EXPOSURE

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skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 30.2 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 11 23/25 34 50 Risk Statements: Highly flammable. Toxic by inhalation and if swallowed. Causes burns. Very toxic to aquatic organisms. S: 16 26 36/37/39 45 60 61 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable

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protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 ppm DOE Short Term Exposure Limit 12.5 ppm DOE Ceiling Limit 75 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL CHLORIDE CAS # 107051 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G H . J K . NFPA HAZARD CODES (H,F,R,O) 3 4 0 REPRODUCTIVE RISK INDEX 2.8 ACUTE TOXICTY RISK INDEX 2.8 - LD50 700.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.8 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Lachrymator. Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Dyspnea. Respiratory depression. Tremors. Somnolence.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 295.2 mm Hg @ 20 °C FLASH POINT -25.6 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

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SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Boron trifluoride, Sulfuric acid, Nitric acid, Strongoxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gasStore at 2-8°CKeep tightly closed. Incompatible Materials: Acids Bases Metals

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\.Incompatible Materials: Acids Bases Metals Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xn N Indication of Danger: Highly Flammable. Harmful. Dangerous for the environment. R: 11 20/21/22 36/37/38 40 48/20 68 50 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of irreversible effects. Very toxic to aquatic organisms. S: 16 25 26 36/37 46 61 Safety Statements: Keep away from sources of ignition - no smoking. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 250 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 ppm DOE Short Term Exposure Limit 3 ppm DOE Ceiling Limit 40 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALLYL CHLOROACETATE CAS # 2916145

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 142 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in acool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL CHLOROFORMATE CAS # 2937500

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 5 - LD50 244.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.0 - LC50 7.2

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 189.7 mm Hg @ 20 °C FLASH POINT 87.8 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Amines, Alcohols, Strong bases, Acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.TOXIC EMISSIONS WHEN BURNED: Phosgene gasHydrogen chloride gasStore at 2-8°CKeep tightly closed. Keep away from heat, sparks, and open flame.Vent periodically.

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store at 2-8░C SPECIAL REQUIREMENTS Vent periodically.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 10-22-26-34 Risk Statements: Flammable. Harmful if swallowed. Very toxic by inhalation. Causes burns. S: 26-28-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .01 ppm DOE Short Term Exposure Limit .03 ppm DOE Ceiling Limit .15 ppm Immediately Dangerous to Life and Health .15 ppmALLYL CHLOROFORMATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL CYANIDE CAS # 109751

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 115.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.4 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 14.0 mm Hg @ 20 °C FLASH POINT 75.2 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Oxidizing agents, Strong acids, Strong bases, Strongreducing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water may be effective for cooling, but may not effect extinguishment.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 21 23/25 36/38 Risk Statements: Flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL ISOCYANATE CAS # 1476239

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 178.0 mg/Kg INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged contact can cause: Nausea, dizziness, and headache. Lung irritation, chest pain, and edema which may be fatal. Repeated exposure may cause asthma. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 109.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids, Strongoxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder.Store at 2-8°CMay develop pressure. Open carefully.Keep tightly closed. Keep away from heat and open flame.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store at 2-8░C SPECIAL REQUIREMENTS May developpressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL ISOTHIOCYANATE CAS # 57067

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . I J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 112.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Vesicant. Causes blisters on contact with skin. Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 114.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids Strongoxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Hydrogen cyanide Sulfuroxides

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS May develop pressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 24/25 42/43 34 Risk Statements: Flammable. Toxic in contact with skin and i swallowed.May cause sensitization by inhalation and skin contact. Causes burns. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 25 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .35 ppm DOE Short Term Exposure Limit 1 ppm DOE Ceiling Limit 2.5 ppm Immediately Dangerous to Life and Health 12.5 ppmALLYL ISOTHIOCYANATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL PHENYL SULFIDE CAS # 5296640

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure.STORAGE: Keep container closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21 S: 23 36/37/39 Safety Statements: Do not breathe vapor. Wear suitable protective clothing, gloves, and eye/face protection. Indication of Danger: Harmful. Risk Statements: Harmful by inhalation and in contact with skin. Safety Statements: Do not breathe vapor. Wear suitable

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL THIOUREA (1,2-) CAS # 109579

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 200.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract.

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Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYL TRIBUTYLTIN (N-) CAS # 24850337

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 217.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Tin/tin oxidesStore at 2-8°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 21 25 36/38 48/23/25 50/53 Risk Statements: Harmful in contact with skin. Toxic if swallowed. Irritating to eyes and skin. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 35 36/37/39 45 60 61 Safety Statements: This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLAMINE CAS # 107119

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G . . J K . NFPA HAZARD CODES (H,F,R,O) 4 4 1 ACUTE TOXICTY RISK INDEX 3.7 - LD50 102.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.3 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 211.5 mm Hg @ 20 °C FLASH POINT -20.2 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Acids, Oxidizing agents, Chlorine, Hypochlorites,Halogens, Chemically active metals.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame\. SPECIAL REQUIREMENTS Store under inertgas.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 11 23/24/25 51/53 Risk Statements: Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 9 16 24/25 45 61 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .125 ppm DOE Short Term Exposure Limit .42 ppm DOE Ceiling Limit 3.3 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLCHLOROBISDIPROPYLPHENYLIMIDAZOLYLIDENE PALLAD CAS # 478980039

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLDIMETHYLAMINE (N-) CAS # 2155944

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 3 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 891.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: Harmful if inhaled. Ingestion: May be harmful if swallowed. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT -4 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 20 34 Risk Statements: Highly flammable. Harmful by inhalation. Causes burns. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 1000 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLHYDROXYLAMINE HYDROCHLORIDE (ORTHO-) CAS # 38945210

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

S PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLIMIDAZOLE (1-) CAS # 31410012

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing,

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wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 219.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLMAGNESIUM CHLORIDE CAS # 2622051 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 3 2 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable Explosive FLASH POINT 1.4 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area Forms explosive unstable peroxides Test periodically or discard Reacts violently with water

SEGREGATION: SHELF # 3STORAGE GROUP(S): b - Pyrophoric/Water Reactive k - Explosive/Unstable l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Acids, Alcohols, Oxidizing agents, Water.FIRE EXTINGUISHER: Dry chemical powder. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Carbon monoxide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive.

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R: 11-14/15-34 Risk Statements: Highly flammable. Reacts violently with water, liberating extremely flammable gases. Causes burns. S: 7/8-16-26-36/37/39-43-45 Safety Statements: Keep container tightly closed and dry. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLMETHYLAMINE (N-) CAS # 627372

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 17.6 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible Solvent

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WASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed. Keep away from heat, sparks, and open flame. Store undernitrogen.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store under nitrogen. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLOXYBENZALDEHYE (4-) CAS # 40663681

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid prolonged orrepeated exposure. Do not breathe vapor. STORAGE: Keep tightly closed\.SPECIAL REQUIREMENTS Air sensitive. Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43 Risk Statements: May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALLYLTRICHLOROSILANE CAS # 107379 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous

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membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 10.0 mm Hg @ 20 °C FLASH POINT 64.4 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Silicon oxide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Handle and store under nitrogen\.Incompatible Materials: Do not allow contact with water

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 16 26 33 36/37/39 43 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry chemical. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALLYLTRIMETHYLSILANE CAS # 762721

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 60.8 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Silicon oxideStore at 2-8°CKeep container closed. Keep away from heat, sparks, and open flame.

REACTIVE PROPERTIESHANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no

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smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALPHAZURINE A CAS # 3486304

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Use protective clothing, gloves, and mask. Do not breathe dust.Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeatedexposure. STORAGE: Keep tightly closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALUM CARMINE CAS # 000032

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUM CARMINE CAS # 32

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINA CAS # 1344281

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bones. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. Damage to the lungs. Prolonged exposure can cause: IRRITATION DATA Eyes Rabbit Remarks: No irritation effect skin Rabbit Remarks: No irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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VAPOR PRESSURE .010000 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Ethylene oxide, Halocarbons, Oxygen difluoride, Sodiumnitrate, Vinyl acetate, Strong acids, Strong bases, Chlorine trifluoride.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Very hygroscopic.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 15 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINA CAS # 701236

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bones. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. Damage to the lungs.

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Prolonged exposure can cause: IRRITATION DATA Eyes Rabbit Remarks: No irritation effect skin Rabbit Remarks: No irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Ethylene oxide, Halocarbons, Oxygen difluoride, Sodiumnitrate, Vinyl acetate, Strong acids, Strong bases, Chlorine trifluoride.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Very hygroscopic.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINON CAS # 569584

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation.

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TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0004 mg/m3 DOE Short Term Exposure Limit .001 mg/m3 DOE Ceiling Limit .0075 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM CAS # 7429905 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 2 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C Reacts violently in air

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Acids, Acid chlorides, Halogens, Oxidizing agents.FIRE EXTINGUISHER: Dry chemical powder.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame. Store in a cool dry place. Storeunder nitrogen.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 15 17 Risk Statements: Contact with water liberates extremely flammable gases. Spontaneously flammable in air. S: 7/8 43 Safety Statements: Keep container tightly closed and dry. In case of fire, use special powder for metal fire. Never use water.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM ACETATE BASIC CAS # 142030

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALUMINUM AMMONIUM SULFATE DODECAHYDRATE CAS # 7784261

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Sulfur oxides Aluminum oxide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ALUMINUM CHLORIDE ANHYDROUS CAS # 7446700 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . B . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 1 W HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.7 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3450.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Damage to the lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Damage to the lungs. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Prolonged exposure can cause: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .200 mm Hg @ 20 °C Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Mixtures of nitrobenzene and aluminum chloride arethermally unstable and may lead to explosive decomposition due to amulti-step decomposition reaction occurring above 90 degree C, whichself-accelerates with high exothermicity producing azo-FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire

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conditions. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Aluminum oxideHazardousDecomposition Products Formed Upon Contact with Water: Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Store under inert gas. Vent periodically. May developpressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 7/8-28-45 Safety Statements: Keep container tightly closed and dry. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 9.88 mg/m3 DOE Short Term Exposure Limit 9.88 mg/m3 DOE Ceiling Limit 60 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM CHLORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM CHLORIDE HEXAHYDRATE CAS # 7784136 HAZARDOUS CHEMICAL OFCONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 1 W ACUTE TOXICTY RISK INDEX 2.2 - LD50 3450.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful

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if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Damage to the lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Damage to the lungs. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Prolonged exposure can cause: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .200 mm Hg @ 20 °C Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Mixtures of nitrobenzene and aluminum chloride arethermally unstable and may lead to explosive decomposition due to amulti-step decomposition reaction occurring above 90 degree C, whichself-accelerates with high exothermicity producing azo-FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfireconditions. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Aluminum oxideHazardousDecomposition Products Formed Upon Contact with Water: Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Store under inert gas. Vent periodically. May developpressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 7/8-28-45 Safety Statements: Keep container tightly closed and dry. After

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contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 17.9 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM CHLORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM HYDROXIDE CAS # 21645512

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating tomucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Constipation.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids, Reacts violently with chlorinated rubber whenheated.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 4.5 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3ALUMINUM HYDROXIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM IODIDE CAS # 7784238 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . K L NFPA HAZARD CODES (H,F,R,O) 0 0 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in

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sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused acrossthe placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .110 mm Hg @ 20 °C Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Water.FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfireconditions.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Hydrogen iodide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Light sensitive. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 40 42/43 Risk Statements: Reacts violently with water. Causes burns. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. S: 22 26 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM ISOPROPOXIDE CAS # 555317

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11300.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Flammable FLASH POINT 61 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathingdust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed.Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisturesensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 8 16 Safety Statements: Keep container dry. Keep away from sources of ignition - no smoking.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15.1 mg/m3 DOE Short Term Exposure Limit 45.4 mg/m3

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DOE Ceiling Limit 75.7 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM ISOPROPOXIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM NITRATE CAS # 7784272

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 2.1 - LD50 3671.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals, Strongacids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Aluminum oxide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom combustible materials, heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION

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Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 27.8 mg/m3 DOE Short Term Exposure Limit 27.8 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM NITRATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM POTASSIUM SULFATE CAS # 7784249

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong oxidizing agents, Bases, Steel, Aluminum, Copper,Zinc.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Aluminum oxide

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 35.2 mg/m3 DOE Short Term Exposure Limit 105 mg/m3 DOE Ceiling Limit 176 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM POTASSIUM

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM POTASSIUM SULFATE SESQUIHYDRATE CAS # 10043671

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 19.1 mg/m3 DOE Short Term Exposure Limit 57.4 mg/m3 DOE Ceiling Limit 95.7 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3ALUMINUM POTASSIUM

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM SULFATE CAS # 10043013

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 1.4 - LD50 20022.6 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.7 mg/m3 DOE Short Term Exposure Limit 38 mg/m3 DOE Ceiling Limit 63.4 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM SULFATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM SULFATE HYDRATE CAS # 17927650

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract.

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Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ALUMINUM SULFATE OCTADECAHYDRATE CAS # 7784318

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMARANTH CAS # 915673

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSUR skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation.

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Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36/37/39 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERJET 1200(H) CAS # 39389203

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides

REACTIVE PROPERTIESHANDLIN User Exposure: Do not breathe vapor. Avoid contact with eyes, skin,and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightlyclosed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERJET 4200-CL CAS # 60177391

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Alkylbenzenes vinylbenzenesnaphthalene benzaldehydes and phenol may also form

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. Dry ion exchange resins expand whenwetted, which may cause column to shatter. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMBERJET 4200-CL CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE CAS # 78922040

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: IDE SULFUR OXIDES

REACTIVE PROPERTIESTHE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY IONEXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPEREACTIONS WHEN MIXED WITH ION EXCHANGE RESINS.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE CG-120 CAS # 37360751

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ACUTE EFFECTS CAUSES EYE IRRITATION. MAY BE HARMFUL IF INHALED. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. WATER

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SPRAY.TOXIC EMISSIONS WHEN BURNED: ACIDS STRONG OXIDIZING AG

REACTIVE PROPERTIES-

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE IR-120 CAS # 63182081

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: IDE SULFUR OXIDES

REACTIVE PROPERTIESTHE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY IONEXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPEREACTIONS WHEN MIXED WITH ION EXCHANGE RESINS.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE IR-120 CAS # 9002237

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: IDE SULFUR OXIDES

REACTIVE PROPERTIESTHE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY IONEXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPEREACTIONS WHEN MIXED WITH ION EXCHANGE RESINS.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMBERLITE IR-120 CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE IRA-400 CAS # 122560638

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMBERLITE IRA-400

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE IRC-50 CAS # 9002293

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE MB-150 CAS # 100915966

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin.

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Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMBERLITE MB-150 CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE MB-3 CAS # 100915977

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. WATER SPRAY.TOXIC EMISSIONS WHEN BURNED: WITH: ACIDS STRONG OXIDIZING AGENTS HA

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE XAD 1180 CAS # 9003694

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.

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FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMBERLITE XAD 1180

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE XAD-4 CAS # 37380420

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE XAD-7 CAS # 37380431

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMBERLITE XAD-7 CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE XE-305 CAS # 9003536

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3AMBERLITE XE-305 CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLITE# IRA-68 CAS # 9056591

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray.

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TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Acrylate monomer anddivinylbenzene may also be formed

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. Dry ion exchange resins expand whenwetted, which may cause column to shatter. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLYST A-21 CAS # 9049938

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Amines

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMBERLYST A-26 CAS # 39339850

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMILORIDE HYDROCHLORIDE HYDRATE CAS # 2016888

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 36.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Hyperkalaemia, nausea, vomiting, abdominal pain, diarrhea or constipation, paraesthesia, thirst, dizziness, skin rash, pruritus, weakness, muscle cramps, and minor psychiatric or visual changes.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36 45 Safety Statements: Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINE-TERMINATED MAGNETIC PARTICLES CAS # 105808728

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed\. Store at2-8°C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINO ACID OXIDASE CAS # 9000899

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of toxic exposure include hypotension, reduced circulating plasma volume, shock, hemorrhage, edema, and myonecrosis. CONDITIONS AGGRAVATED BY EXPOSURE May be fatal if enters bloodstream.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Inhibited by ammonium ions, benzoate, iodoacetate, andoctyl alcohol.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 26/27/28 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. S: 36/37/39-45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINO ACID OXIDASE (D-) CAS # 9000888

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfireconditions.

REACTIVE PROPERTIES User Exposure: Avoid contact with eyes, skin, and clothing. Avoidinhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightlyclosed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINO DIFLUOROBENZONITRILE (4:2,5-) CAS # 112279615

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.9 - LD50 64.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINO-TEMPO (4-) CAS # 14691884

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOACETANILIDE (4'-) CAS # 122805

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36 42/43 Risk Statements: Irritating to eyes. May cause sensitization by inhalation and skin contact. S: 22 26 36/37 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOACETONITRILE BISULFATE CAS # 151633

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOACETONITRILE HYDROCHLORIDE CAS # 6011149

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong reducing agents, Strong oxidizing agents, Strongbases, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Carbon monoxide andnitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22-36/37/38

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Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOACETOPHENONE (4'-) CAS # 99923

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 381.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents, Strong reducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOACETOPHENONE (META-) CAS # 99036

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 995.9 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents, Strong reducing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 43 Risk Statements: Harmful if swallowed. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOANTHRAQUINONE (1-) CAS # 82451

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Chloroformates, Acid anhydrides,Acid chlorides, Acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOANTIPYRINE (4-) CAS # 83078

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1700.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, AcidFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic. Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZAMIDE (4-) CAS # 2835689

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if inhaled or swallowed. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 36/38 Risk Statements: Harmful by inhalation and if swallowed. Irritating to eyes and skin. S: 38 Safety Statements: In case of insufficient ventilation, wear suitable respiratory equipment.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZAMIDINE DIHYDROCHLORIDE (4-) CAS # 2498502

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZENEMETHANOL (2-) CAS # 5344901

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZENESULFONIC ACID (3-) CAS # 121471

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12300.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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IRRITATION DATA Eyes Rabbit 500 mg 24H Remarks: Mild irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 23 28 Safety Statements: Do not breathe fumes. After contact with skin, wash immediately with plenty of soap-suds.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZO COUMARIN (6:3,4-) CAS # 83527995

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID (3-) CAS # 99058

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 20322.6 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIALREQUIREMENTS Light sensitive. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID (4-) CAS # 150130

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 6000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.

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SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .000280 mm Hg @ 20 °C

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38-43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOBENZOIC ACID (4-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID (BOC,2-) CAS # 68790385

Page 292:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID (BOC,3-) CAS # 111331829

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID (BOC,4-) CAS # 66493398

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

Page 294:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID ETHYL ESTER METHANESULFONATE (3- CAS # 886862

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin.

Page 295:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOIC ACID POTASSIUM (PARA-) CAS # 138841

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes irritation. May be harmful by inhalation, ingestion, or skin absorption. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZONITRILE (3-) CAS # 2237301

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 878.7 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid Ccombustible FLASH POINT 233.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 43 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZONITRILE (4-) CAS # 873745

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 283.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.

Page 298:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin whichin sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acid anhydrides, Chloroformates, Strong oxidizing agents,Acid chlorides, Acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOPHENONE (4-) CAS # 1137413

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED

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ACUTE TOXICTY RISK INDEX 4.4 - LD50 18.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOTHIAZOLE (2-) CAS # 136958

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

Page 300:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

HAZARD INDEX . . . . . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 3 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZOTRIFLUORIDE (PARA-) CAS # 455141

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 128.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). Prolonged exposure can cause: Nausea, dizziness, and headache. Narcotic effect. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 188 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZYL ALCOHOL (4-) CAS # 623041

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CAir sensitive.Keep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C SPECIAL REQUIREMENTS Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZYLAMINE (2-) CAS # 4403694

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acids.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. Incompatible Materials: Absorbscarbon dioxide from air. Avoid contact with acid.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION

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Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBENZYLAMINE (4-) CAS # 4403718

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible Solvent

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBIPHENYL (2-) CAS # 90415

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2340.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid Ccombustible FLASH POINT 307.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid all contact. STORAGE: Keep tightlyclosed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 40 52/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 61 Safety Statements: Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBIPHENYL (4-BIPHENYLAMINE) (4-) CAS # 92671 HAZARDOUS CHEMICAL OFCONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . . . E . . . . . K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.9 - TD50 .6 mg/Kg ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

cancer suspect agent

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. Skin. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 Risk Statements: May cause cancer. Also harmful if swallowed. S: 53 45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMINOBIPHENYL

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOMETHYLPYRIMIDINOL (2:5:4-) CAS # 6307353

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides,Acid anhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMONITROPYRIDINE (2:5:3-) CAS # 6945682

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOPYRIDINE (2:3-) CAS # 13534991

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse

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immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOPYRIDINE (2:5-) CAS # 1072975

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 297.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. ADDITIONAL INFORMATION The preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship (QSAR) modeling.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOPYRIDINE (2:6-) CAS # 19798813

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOPYRIDINE (3:6-) CAS # 13534979

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBROMOPYRIDINE (4:2-) CAS # 7598358

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 37/38 41 43 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBUTYRIC ACID (4-) CAS # 56122

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1 - LD50 47296.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBUTYRIC ACID (BOC,4-) CAS # 57294389

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOBUTYRIC ACID (DL,3-) CAS # 2835827

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCAPROIC ACID (6-) CAS # 60322

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1 - LD50 46129.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure may cause itching, erythema, skin rash, diuresis,

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heartburn, nausea and diarrhea. Blood effects. Other symptoms include orthostatic hypotension and bradycardia. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCHLORONITROPYRIDINE (2:5:3-) CAS # 5409392

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper

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respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCHLOROPHENOL (2:4-) CAS # 95852

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 690.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: Severe irritation or burns. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Prolonged contact can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOCHLOROPHENOL (2:5-) CAS # 28443507

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOCHLOROPYRAZINE (2:6-) CAS # 33332284

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 399.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes blisters on contact with skin. Causes skin irritation. skin Absorption: Skin absorption may occur. May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 37/38 41 43 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 28 36/37/39 Safety Statements: In case of contact with eyes, rinse

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immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCHLOROPYRIDINE (3:2-) CAS # 6298197

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides,Acid anhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at 2-8°CKeep container closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing.STORAGE: Keep container closed. Store in a cool dry place. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCHLOROPYRIMIDINE (2:5-) CAS # 5428897

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 275.8 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. Sensitization: Sensitizer. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 43 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCINNAMIC ACID HYDROCHLORIDE (PARA-) CAS # 54057953

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCRESOL (META,2-) CAS # 2835974

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCRESOL (META,6-) CAS # 2835985

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCROTONIC ACID (TRANS,4-) CAS # 38090538

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCYANOPYRIDINE (2:5-) CAS # 4214737

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCYANOPYRIDINE (5:2-) CAS # 55338733

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOCYCLOPROPANE CARBOXYLIC ACID (1:1-) CAS # 22059218

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

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toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINODIETHYLAMINOPENTANE (2:5-) CAS # 140807

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 155 °F

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SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINODIMETHYL PHENOL (4:2,5-) CAS # 3096717

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and ifswallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINODIMETHYLPHENOL HYDROCHLORIDE (4,2,3-) CAS # 619603

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS TOXIC FUMES OF: CARBON MO

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINODIPHENYLAMINE (2-) CAS # 534850

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. Oral Rat 450 mg/kg LD50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orTOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE:Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn R: 20/22 38 Risk Statements: Harmful by inhalation and if swallowed. Irritating to skin. S: 22 24

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL BENZENESULFONYL FLOURIDE HYDROCHLORIDE CAS # 30827997

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE A protease inhibitor.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong bases, Strong oxidizing agents.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas HydrogenfluorideStore at 2-8°CKeep tightly closed. Store under argon.Moisture sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Storeunder argon\. Store at 2-8░C SPECIAL REQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL HYDROGEN SULFATE (2-) CAS # 926396

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3548.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE

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To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitableprotective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL PIPERAZINE CAS # 140318

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2140.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns.

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Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0500 mm Hg @ 20 °C FLASH POINT 197.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21/22 34 43 52/53 Risk Statements: Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.5 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3

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DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOETHYL PIPERAZINE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL PIPERIDINE (1,2-) CAS # 27578605

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 136.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL PROPANEDIAMINE CAS # 13531527

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 205 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: CORROSIVE

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INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents,Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL PYRROLIDINE (1,2-) CAS # 7154736

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical,

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and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 116.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Air and moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 34 Risk Statements: Flammable. Causes burns. S: 16 26 27 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYL VINYL ETHER (2-) CAS # 7336290

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 84.2 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place\. SPECIALREQUIREMENTS May develop pressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 34 36/37 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to eyes and respiratory system. S: 16 26 33 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLAMINO NITROPYRIDINE (2,2:5-) CAS # 29602399

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Damage to the eyes. Nausea, dizziness, and headache. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLAMINOETHANOL (2-) CAS # 111411

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . L NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 291.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents Avoid contact with acid. Copper, Copperalloys, Zinc, Galvanized ironFIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 43 Risk Statements: Causes burns. May cause sensitization by skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse

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immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLCARBAZOLE CAS # 132321

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.5 - LD50 144.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Liver. Kidneys. Bladder. Brain. Heart. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLMETHYL CARBAMIC ACID BUTYL ESTER (N,2:N: CAS # 121492066

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Store under inert gas. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLMORPHOLINE (4,2-) CAS # 2038031

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . G . . . . L NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1850.0 mg/Kg INHALATION RISK INDEX 1.5 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction.

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SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .700 mm Hg @ 20 °C FLASH POINT 186.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 43 Risk Statements: Harmful if swallowed. Causes burns. May cause sensitization by skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOETHYLPYRIDINE (2,2-) CAS # 2706561

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 212 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents,Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep container closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOFLUOROPYRIDINE (2:5-) CAS # 21717964

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen fluoride

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOGLUTETHIMIDE CAS # 125848 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 240.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Adrenal cortex. Thyroid. Blood. CONDITIONS AGGRAVATED BY EXPOSURE Aminoglutethimide blocks the synthesis of adrenal steroid hormones and the physiological conversion of androgens to estrogens.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOGUANIDINE HEMISULFATE CAS # 996190 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOGUANIDINO PROPIONIC ACID HYDROCHLORIDE (L,2, CAS # 1482991

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOHYDRAZINOMERCAPTOTRIAZOLE CAS # 1750125

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam\. Protective Equipment: Wear self-contained breathingapparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits tTOXIC EMISSIONS WHEN BURNED: ZARDOUS POLYMERIZATIONStore at -20°C

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE Store at -20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOHYDROXYPYRAZOLE (3:5-) CAS # 6126223

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOHYDROXYPYRIDINE (2:3-) CAS # 16867031

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 570.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acidanhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOIMIDAZOLE SULFATE (2-) CAS # 1450937

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear

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suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOINDANOL (CIS,1:2-) CAS # 136030007

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Acids, Bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38

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Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOINDAZOLE (5-) CAS # 19335116

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 645.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Cyanosis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOINDAZOLE (6-) CAS # 6967120

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3448.3 mg/Kg INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS TOXIC FUMES OF: CARBON MO

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOINDOLE (4-) CAS # 5192234

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOIODOBENZOIC ACID (2:5-) CAS # 5326476

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodideStore at 2-8°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOIODOBENZONOTRILE (4:3-) CAS # 33348344

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36

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Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOIODOPYRIDINE (2:5-) CAS # 20511120

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant.

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R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOISOBUTYRIC ACID (2-) CAS # 62577

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOISOINDOLE HYDROCHLORIDE (3,1-) CAS # 76644741

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Remarks: Moderate irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOISOXAZOLE (3-) CAS # 1750421

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOLEVULINIC ACID HYDROCHLORIDE (5-) CAS # 5451092

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8°C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMERCAPTOTHIADIAZOLE CAS # 2349679

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHOXYISOXAZOLE (3:5-) CAS # 1072679

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 2 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Explosive

SEGREGATION: SHELF # 3STORAGE GROUP(S): k - Explosive/UnstableWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHOXYPROPANE (2:1-) CAS # 37143547

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Female reproductive system. Eyes. Bone marrow. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Blood effects. Narcotic effect. Nausea, dizziness, and headache.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 48 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible Solvent

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WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Acid anhydrides, Acid chlorides, Strong acids, Strongoxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-22-34-52/53 Risk Statements: Highly flammable. Harmful if swallowed. Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 9-26-36/37/39-45-61 Safety Statements: Keep container in a well-ventilated place. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-T Indication of Danger: Highly Flammable. Toxic. R: 45-46-11-34 Risk Statements: May cause cancer. May cause heritable genetic damage. Highly flammable. Causes burns. S: 53-26-36/37/39-45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL BENZENESULFONAMIDE HYDROCHLORIDE HYDRA CAS # 138374

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 25800.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause pain or burning sensation at the site of contact. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL BENZOIC ACID (4-) CAS # 56917

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL BENZONITRILE (4:3-) CAS # 78881217

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful.

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R: 20/21 43 Risk Statements: Harmful by inhalation and in contact with skin. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL BUTANE (R,2-) CAS # 34701332

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 531.0 mg/Kg INHALATION RISK INDEX <1 - LC50 5200.0

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 70 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 22 34 Risk Statements: Highly flammable. Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL BUTANE (S,2-) CAS # 22526461

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing,

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wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 70 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 20/21/22 35 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes severe burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL ISOXAZOLE (5:3-) CAS # 14678025

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL PROPANEDIOL CAS # 115695

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 17000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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VAPOR PRESSURE .002837 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Aluminum, Copper, Brass, Strongacids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL PROPANOL CAS # 124685

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2900.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation.nhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .800 mm Hg @ 20 °C FLASH POINT 154.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents, Strong acids Copper, Copper alloys,Brass, Aluminum.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxidesStore at -20°CStore under inert gas. Air sensitive.Keep tightly closed. Keep away from heat and open flame. Store in a cool dryplace. Store under nitr

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place. Store under nitrogen\.Store at -20░C SPECIAL REQUIREMENTS Store under inert gas. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 52/53

METHODS FOR CLEANING UP Absorb on sand or vermiculite and place in closed containers for disposal. Ventilate area and wash spill site after material pickup is complete.Section 7 - Handling and StorageHANDLING User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. Section 8 - Exposure Controls / PPEENGINEERING CONTROLS Mechanical exhaust required. Safety shower and eye bath. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Government approved respirator. Hand: Compatible chemical-resistant gloves.

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Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling.Section 9 - Physical/Chemical PropertiesAppearance Physical State: Liquid Property Value At Temperature or Pressure Molecular Weight 671.1 AMUpH N/ABP/BP Range 178 ░C 760 mmHgMP/MP Range -52 ░CFreezing Point N/AVapor Pressure 1.3 mmHg 25 ░CVapor Density 23.3 g/lSaturated Vapor Conc. N/ASG/Density 1.89 g/cm3Bulk Density N/AOdor Threshold N/AVolatile% N/AVOC Content N/AWater Content N/ASolvent Content N/AEvaporation Rate N/AViscosity N/ASurface Tension N/APartition Coefficient N/ADecomposition Temp. N/AFlash Point N/AExplosion Limits N/AFlammability N/AAutoignition Temp N/ARefractive Index 1.3Optical Rotation N/AMiscellaneous Data N/ASolubility N/A N/A = not availableSection 10 - Stability and ReactivitySTABILITY Stable: Stable. Materials to Avoid: Finely powdered metals, Alkali metals. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Hydrogen fluoride, May also form perfluoroisobutylene. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occurSection 11 - Toxicological InformationROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation.

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Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DATA Oral Rat > 10000 mg/kg LD50 Intravenous Mouse 12 GM/KG LD50Section 12 - Ecological InformationNo data available.Section 13 - Disposal ConsiderationsAPPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations.Section 14 - Transport InformationDOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport.Section 15 - Regulatory InformationEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .03 mg/m3 DOE Short Term Exposure Limit .075 mg/m3 DOE Ceiling Limit .6 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOMETHYL PROPANOL

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

Page 387:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYL PYRIDINE (2-) CAS # 3731519

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 694.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 210.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive.

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R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLAMINOMETHYL BENZENE (1:N,BOC,4-) CAS # 108468004

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLANLINE (4:1,N,BOC-) CAS # 94838558

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLBENZIMIDAZOLE (2:1-) CAS # 1622577

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLBENZIMIDAZOLE DIHYDROCHLORIDE HYDRATE ( CAS # 5993919

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLBENZOIC ACID HYDROCHLORIDE (3-) CAS # 876039

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLCYCLOHEXANOL HYDROCHLORIDE (1:1-) CAS # 19968855

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

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REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.STORAGE: Keep container closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMETHYLISOTHIAZOLE HYDROCHLORIDE (5:3-) CAS # 52547009

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOMETHYLPYRIDINE (4-) CAS # 3731531

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 219.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOMORPHOLINE (4-) CAS # 4319497

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3225.8 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 137 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and

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if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHALENE (1-) CAS # 134327 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 680.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Harmful if swallowed. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 314.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, STORAGE: Keep

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tightly closed\. SPECIAL REQUIREMENTS Air and light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Indication of Danger: Harmful. Dangerous for the environment. R: 22 51/53 Risk Statements: Harmful if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic S: 24 61 Safety Statements: Avoid contact with skin. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 350 mg/m3AMINONAPHTHALENE (1-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHALENE CARBONITRILE (4:1-) CAS # 58728646

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHOL HYDROCHLORIDE (1,2-) CAS # 1198272

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cooldry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. S: 26 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHOL HYDROCHLORIDE (4,1) CAS # 5959568

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHOL SULFONIC ACID (1,2,4-) CAS # 116632

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides,Acid anhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONAPHTHOLSULFONIC ACID (6,1,3-) CAS # 87025

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Chemical pneumonitis. Pulmonary edema. Effects may be delayed. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonaryedema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONICOTINIC ACID METHYL ESTER (6-) CAS # 36052241

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2100.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic

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reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROBENZOIC ACID (2:5-) CAS # 616795

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract.

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Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROBENZONITRILE (4:3-) CAS # 6393404

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROBENZOPHENONE (4:3-) CAS # 31431193

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITRONAPTHELENE (1:4-) CAS # 776341

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROPHENOL (2:4-) CAS # 99570 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2400.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 212 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acidanhydrides, Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINONITROPHENOL (4,2-) CAS # 119346 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1470.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides, Acidanhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid all contact. Do not get in eyes, onskin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROPHENOL (4:3-) CAS # 610811

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROPYRIDINE (2:3-) CAS # 4214759

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 332.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

Page 413:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROQUINOLINE (5:6-) CAS # 35975009

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

Page 414:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONITROTOLUENE (2,4-) CAS # 99558 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .0000100 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acidanhydrides, Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES

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HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 40 52/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 45 61 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMINONITROTOLUENE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINONORBORNANE (EXO,2-) CAS # 7242924

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

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Flammable FLASH POINT 95 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame.Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPENICILLANIC ACID (6-) CAS # 551166

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption.

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SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22-36/37 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPEPTIDASE CAS # 9031941

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep container closed. Store away from heat.

REACTIVE PROPERTIESSTORAGE: Keep container closed. Store away from heat. Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENOL (2-) CAS # 95556

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 951.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract.

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Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 1.8 mm Hg @ 20 °C FLASH POINT 334.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid anhydrides, Acidchlorides, Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 68 Risk Statements: Harmful by inhalation and if swallowed. Possible risk of irreversible effects. S: 28 36/37 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOPHENOL (2-) CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENOL (3-) CAS # 591275

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 924.0 mg/Kg INHALATION RISK INDEX <1 - LC50 1162.0

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.TARGET ORGAN(S) OR SYSTEM(S) Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Exposure can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. Dangerous for theenvironment. R: 20/22 51/53 Risk Statements: Harmful by inhalation and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 61 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 3 mg/m3

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DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3AMINOPHENOL (3-) CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENOL (PARA-) CAS # 123308

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 5 - LD50 375.0 mg/Kg INHALATION RISK INDEX <1 - LC50 5.0

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 383 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 50/53 68 Risk Statements: Harmful by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of irreversible effects. S: 28 36/37 60 61 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENOL HYDROCHLORIDE (4-) CAS # 51785

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam\. Protective Equipment: Wear self-contained breathingapparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits tTOXIC EMISSIONS WHEN BURNED: XPOSURE

REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.Store under argon. Store in a SPECIAL REQUIREMENTS

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 43 36/37/38 Risk Statements: May cause sensitization by skin contact. S: 28 36 Safety Statements: After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing. Indication of Danger: Harmful. Risk Statements: May cause sensitization by skin contact. Irritating to eyes, respiratory system and skin. Safety Statements: Wear suitable protective clothing, gloves, immediately with plenty of water and seek medical advice. US Statements: Target organ(s): Blood. Kidneys.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYL BORONIC ACID (BOC,4-) CAS # 380430499

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation.

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Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Boron oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYL BORONIC ACID HYDROCHLORIDE (3-) CAS # 85006231

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Boronoxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYL BORONIC ACID MONOHYDRATE (3-) CAS # 280563635

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Boron oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYL DISULFIDE CAS # 722270

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYL ETHYLAMINE (2,4-) CAS # 13472009

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the

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larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYLACETIC ACID (4-) CAS # 1197553

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5882.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYLACETYLENE (3-) CAS # 54060309

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin.

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Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 138 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed. Keep away from heat and open flame.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHENYLMERCURIC ACETATE (PARA-) CAS # 6283245

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . D E . . . I . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Exposure to mercury compounds can cause tremors, loss of appetite, weight loss, anuria, and uremia. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Mercury/mercury oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 26/27/28 33 50/53 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13 28 36 45 60 61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and

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its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHTHALHYDRAZIDE (3-) CAS # 521313

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: appropriate foam.

REACTIVE PROPERTIESHANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keeptightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin.

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S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPHYLLIN HYDRATE CAS # 317340

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 243.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Heart. Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Adverse reactions: nausea, vomiting, diarrhea, anorexia, dyspepsia, epigastric pain, hematemesis, dizziness, vertigo, headache,light- headedness, nervousness, insomnia, hyperreflexia, fasciculations, clonic and tonic convulsions, palpitation tachycardia, extrasystoles, hypotension, circulatory failure, increased respiratory rates, urticaria.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPIPERIDINE (1-) CAS # 2213436

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 97 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acidanhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPANOL (2:1-) CAS # 2749113

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 145 °F

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SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Oxidizing agents Avoid contact with acid.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in acool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPANOL (3,1-) CAS # 156876

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2830.0 mg/Kg INHALATION RISK INDEX 1.7 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE

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Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 2.1 mm Hg @ 20 °C FLASH POINT 213.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame\. SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .015 mg/m3 DOE Short Term Exposure Limit .04 mg/m3 DOE Ceiling Limit .3 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOPROPANOL (3,1-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOPROPANOL (DL,1:2-) CAS # 78966

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 INHALATION RISK INDEX 1.7 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE***** mm Hg @ 20 °C FLASH POINT 159.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed. Keep away from heat and open flame. Store in a cool dryplace.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place\. Store at 2-8°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive.

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R: 34 Risk Statements: Causes burns. S: 23 26 36 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPYL SILICA GEL CAS # 000039

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: When heated to decomposition it may emit:HAZARDOUS EXOTHERMIC REACTIONS Hazardous Exothermic Reactions: Will not occur

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOPROPYL SILICA GEL CAS # 39

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

OTHER HEALTH HAZARDS MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPYLMORPHOLINE (4,3-) CAS # 123002

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3560.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: Readily absorbed through skin. Harmful if absorbed through skin. Inhalation: May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema.

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Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 210 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents,Chloroformates, sensitive to carbon dioxide.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21 34 Risk Statements: Harmful in contact with skin. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPYLTRIETHOXYSILANE (3-) CAS # 919302

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1780.0 mg/Kg

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SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: DO NOT USE WATER. CARBON DIOXIDE, DRY CHEMICAL POWDEROR appropriate foam.TOXIC EMISSIONS WHEN BURNED: MBUSTION OR DECOMPOSITION PRODUCTS THERMAL DE

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPROPYLTRIMETHOXYSILANE (3-) CAS # 13822565

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 197.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Silicon oxide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place. Store at 2-8░C SPECIALREQUIREMENTS Moisture sensitive.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPTERIN CAS # 54626 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . B C . . . . . . J . . NFPA HAZARD CODES (H,F,R,O) 4 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 6.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.7 - LD50 9.7 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Blood effects. To the best of our knowledge, the chemical,

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physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.Light sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 61 28 Risk Statements: May cause harm to the unborn child. Very toxic if swallowed. S: 53 28 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 25 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPYRAZINE CAS # 5049616

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 2.5 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMINOPYRIDINE (2-) CAS # 504290

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 200.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE May cause convulsions.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 197.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 21 25 36/37/38 Risk Statements: Harmful in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse

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immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 5 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPYRIDINE (3-) CAS # 462088

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 3.5 - LD50 165.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Nerves.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 190.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides,Acid anhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in

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a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 33 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPYRIMIDINE (2-) CAS # 109126

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPYRIMIDINE (4-) CAS # 591548

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid anhydrides,Acid chlorides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOPYRROLIDINE HYDROCHLORIDE (1-) CAS # 63234719

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOQUINOLINE (3-) CAS # 580176

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOQUINOLINE (6-) CAS # 580154

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOQUINOLINE (8-) CAS # 578665

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin,on clothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOSALICYLIC ACID (3-) CAS # 570230

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOSALICYLIC ACID (4-) CAS # 65496

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12903.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Liver.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place. Handle and storeunder nitrogen\. SPECIAL REQUIREMENTS Handle and store under inert gas. Lightsensitive. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOSALICYLIC ACID (5-) CAS # 89576

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2800.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.Light sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOSALICYLIC ACID SODIUM (4-) CAS # 6018195

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIALREQUIREMENTS Light sensitive. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

Page 459:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

AMINOTETRAHYDRONAPHTHALENE CAS # 2217416

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

Page 460:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTETRAMETHYL PIPERIDINE CAS # 36768624

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 906.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .200 mm Hg @ 20 °C FLASH POINT 167 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38

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Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTETRAZOLE MONOHYDRATE (5-) CAS # 4418615

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DAT Oral Rat 1,300 mg/kg LD50 Intraperitoneal Mouse 2500 MG/KG LD50 IRRITATION DATA Eyes Remarks: Moderate irritation effect

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids, Acid chlorides, Acid anhydrides, Strongoxidizing agents, Metals.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wea suitableprotective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTHIAZOL (2-) CAS # 96504

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 799.5 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed.

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SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acidanhydrides.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 43 Risk Statements: Harmful if swallowed. Irritating to eyes. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTHIOPHENOL (2-) CAS # 137075

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G . . . . L

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NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Pulmonary edema. Effects may be delayed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Coughing, chest pains, difficulty in breathing.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 174.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Chloroformates, Acid anhydrides,Acid chlorides, Acids.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store under nitrogen\. SPECIAL REQUIREMENTS Storeunder inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C-N Indication of Danger: Corrosive. Dangerous for the environment. R: 22-34-43-50/53 Risk Statements: Harmful if swallowed. Causes burns. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26-36/37/39-45-60-61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.

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In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTOLUENE SULFONIC ACID CAS # 118887

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam.TOXIC EMISSIONS WHEN BURNED: IDE NITROGEN OXIDES SULFUR OXIDES

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOTRIAZOLE (3,1,2,4-) CAS # 61825 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.7 - TD50 9.9 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED

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REPRODUCTIVE RISK INDEX 4.0 ACUTE TOXICTY RISK INDEX 5 - LD50 25000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 400.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Liver. Kidneys.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Copper Iron andiron salts.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 48/22 63 51/53 Risk Statements: Harmful: danger of serious damage to health by prolonged exposure if swallowed. Possible risk of harm to the unborn child. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13 36/37 61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .2 mg/m3

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .2 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3

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DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOTRIAZOLE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOUNDECANOIC ACID (11-) CAS # 2432997

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

Page 468:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOURACIL (6-) CAS # 873836

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4032.3 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMINOVALERIC ACID (5-) CAS # 660888

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIA CAS # 7664417 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . C D . . G H . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 44940.0

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Can cause rapid suffocation. Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Gas Ccombustible VAPOR PRESSURE 6196.1 mm Hg @ 20 °C FLASH POINT 269.6 °F

SEGREGATION: SHELF # 3STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents, Galvanized iron, Zinc, Copper,Silver/silver oxides, Cadmium/cadmium oxides, Alcohols, Acids, Halogens,Aldehydes.FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool. Movecylinder away from fire if there is no risk.TOXIC EMISSIONS WHEN BURNED: Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Use withequipment rated for cylinder pressure, and of compatible materials ofconstruction. Close valve when not in use and when empty. Make surecylinder is properly secured when in use or stored Cylinder temperature should not exceed 125░F (52░C)\. SPECIAL REQUIREMENTS Contents under

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pressure.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 10 23 34 50 Risk Statements: Flammable. Toxic by inhalation. Causes burns. Very toxic to aquatic organisms. S: 9 16 26 36/37/39 45 61 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Short Term Exposure Limit 35 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 25 ppm ACGIH Short Term Exposure Limit 35 ppm Immediately Dangerous to Life and Health 300 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 30 ppm DOE Ceiling Limit 160 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM ACETATE CAS # 631618

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be

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irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.5 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMMONIUM ACETATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM BICARBONATE CAS # 1066337

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1576.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation.

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Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE 50.3 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents, Strong acids, Nitrites, Nitrates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: AmmoniaStore at 2-8°CHeat sensitive.Keep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C SPECIAL REQUIREMENTS Heat sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMMONIUM BICARBONATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM BROMIDE CAS # 12124979

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2700.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged contact with moist skin can produce severe irritation or burns. Prolonged inhalation of dust can produce bronchitis. Ingestion of large quantities can cause irritability, confusion, tremors, acne- like skin erruptions, memory loss, headache, slurred speech, and anorexia. To the best of our knowledge, th chemical,physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .1000 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases, Heavymetals, Silver salts, Potassium.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Hydrogen bromide gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 200 mg/m3

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Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM BROMIDE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CARBONATE CAS # 10361292

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 52/53

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Risk Statements: Irritating to eyes, respiratory system and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CARBONATE CAS # 506876

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Air sensitive.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 52/53 Risk Statements: Irritating to eyes, respiratory system and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3AMMONIUM CARBONATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CERIUM(IV) NITRATE CAS # 16774213

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 2.4 - LD50 1720.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powderedmetals.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam\. Protective Equipment: Wear self-contained breathingapparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits tTOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS HAZARDOUS POLYMER

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, STORAGE: Keeptightly closed. Keep away from combustible materials, heat, sparks, andopen flame\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 39.1 mg/m3 DOE Short Term Exposure Limit 117 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM CERIUM(IV)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CHLORIDE CAS # 12125029

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . H . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1650.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin EyeContact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .120 mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriatetosurrounding fire conditions.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36 Risk Statements: Harmful if swallowed. Irritating to eyes S: 22 Safety Statements: Do not breathe dust.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM CHLORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CHROMATE CAS # 7788989 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . H . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing,laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong acids, Organic materials, Finely powdered metals.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriatetosurrounding fire conditions.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Unsuitable: Do not store near, nor allow contact with,clothing and other combustible material.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 49 8 43 50/53 Risk Statements: May cause cancer by inhalation. Contact with combustible material may cause fire. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 17 45 60 61 Safety Statements: Avoid exposure - obtain specialinstructions before use. Keep away from combustible material. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 15 mg/m3

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US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0146 mg/m3 DOE Short Term Exposure Limit .438 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 43.9 mg/m3AMMONIUM CHROMATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CITRATE CAS # 3458728

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi

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Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMMONIUM CITRATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM CITRATE DIBASIC CAS # 3012655

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 10 mg/m3AMMONIUM CITRATE DIBASIC

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM DEUTEROXIDE CAS # 13550497

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . F G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 350.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.7 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Can cause rapid suffocation. Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous

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membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Gas Ccombustible VAPOR PRESSURE 6196.0 mm Hg @ 20 °C FLASH POINT 269.6 °F

SEGREGATION: SHELF # 3STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Oxidizing agents, Galvanized iron, Zinc, Copper,Silver/silver oxides, Cadmium/cadmium oxides, Alcohols, Acids, Halogens,Aldehydes.FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool.Movecylinder away from fire if there is no risk.TOXIC EMISSIONS WHEN BURNED: Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Use withequipment rated for cylinder pressure, and of compatible materials ofconstruction. Close valve when not in use and when empty. Make surecylinder is properly secured when in use or stored Cylinder temperature should not exceed 125░F (52░C)\. SPECIAL REQUIREMENTS Contents underpressure.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 10 23 34 50 Risk Statements: Flammable. Toxic by inhalation. Causes burns. Very toxic to aquatic organisms. S: 9 16 26 36/37/39 45 61 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 ppm DOE Short Term Exposure Limit 29 ppm

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DOE Ceiling Limit 177 ppm Immediately Dangerous to Life and Health 883 ppmAMMONIUM DEUTEROXIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM DICHROMATE CAS # 7789095 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . H . J K L NFPA HAZARD CODES (H,F,R,O) 2 1 3 OX ACUTE TOXICTY RISK INDEX 4 - LD50 53.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of dichromate dusts can cause ulceration and perforation of the nasal septum. Contact with breaks in the skin can cause ulceration (chrome sores). Other symptoms of exposure include erosion and discoloration of the teeth, nephritis, epigastric pain (inflammation and ulceration of the gastrointestinal tract). Material is extremely destructive t tissue ofthe mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Stomach pains, vomiting, diarrhea. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible Explosive Shock sensitive Explosive Oxidizing Agent

SEGREGATION: SHELF # 3STORAGE GROUP(S): e - Oxidizer/Organic Peroxide k - Explosive/Unstable l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Strong reducing agents, Alcohols, Strong acids Avoidcontact with acid.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray.

REACTIVE PROPERTIESHANDLING: Avoid prolonged or repeated exposure. Do not breathe dust. Avoidcontact with eyes, skin, and clothing\. Container should be opened only by atechnically qualified person. STORAGE: Keep tightly closed. Keep away fromheat, sparks, and open flame\. SPECIAL REQUIREMENTS Do not grind or subjectto friction or shock. Isolated storage

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: E T+ N Indication of Danger: Explosive. Very toxic. Dangerous for the environment R: 45 46 60 61 2 8 21 25 26 34 42/43 48/23 50/53 Risk Statements: May cause cancer. May cause heritable genetic damage. May impair fertility. May cause harm to the unborn child. Risk of explosion by shock, friction, fire, or other sources of ignition. Contact with combustible material may cause fire. Also harmful in contact with skin. Also toxic if swallowed. Also very toxic by inhalation. Causes burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

Immediately Dangerous to Life and Health 15 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0121 mg/m3 DOE Short Term Exposure Limit .363 mg/m3 DOE Ceiling Limit 7.5 mg/m3

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Immediately Dangerous to Life and Health 36.4 mg/m3AMMONIUM DICHROMATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM DIETHYLDITHIOCARBAMATE CAS # 21124334

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C SPECIAL REQUIREMENTS Hygroscopic.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMMONIUM DIHYDROGEN PHOSPHATE CAS # 7722761

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5750.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong acids, Strong oxidizing agents.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriatetosurrounding fire conditions.

REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM DIHYDROGEN

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM FERRIC SULFATE DODECAHYDRATE CAS # 7783837

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 8.64 mg/m3 DOE Short Term Exposure Limit 25.9 mg/m3 DOE Ceiling Limit 43.2 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMMONIUM FERRIC SULFATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM FLUORIDE CAS # 12125018

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

InformationROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bones.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid prolonged or repeated exposure. Donot get in eyes, on skin, on clothing. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear

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suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.88 mg/m3 DOE Short Term Exposure Limit 4.88 mg/m3 DOE Ceiling Limit 4.88 mg/m3 Immediately Dangerous to Life and Health 12.5 mg/m3AMMONIUM FLUORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM FORMATE CAS # 540692

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3793.1 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM FORMATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM HEXAFLUOROPHOSPHATE CAS # 16941110

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and

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vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To thebest of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids.FIRE EXTINGUISHER: Dry chemical powder.TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Thermal decomposition mayproduce toxic fumes of phosphorus oxides and/orphosphine Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM HYDROGEN DIFLUORIDE CAS # 1341497

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. ACGIH CARCINOGEN LIST Rating: A4

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Hydrogen fluoride

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T C Indication of Danger: Toxic. Corrosive. R: 25 34 Risk Statements: Toxic if swallowed. Causes burns. S: 22 26 37 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.75 mg/m3 DOE Short Term Exposure Limit 3.75 mg/m3 DOE Ceiling Limit 3.75 mg/m3

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Immediately Dangerous to Life and Health 3.75 mg/m3AMMONIUM HYDROGEN

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM HYDROGEN PHOSPHATE CAS # 7783280

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Magnesium, Strong bases, Strong acids, Strong oxidizingagents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38

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Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMMONIUM HYDROGEN

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM HYDROGEN SULFATE CAS # 7803636

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicologica properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .025 mg/m3 DOE Short Term Exposure Limit .075 mg/m3 DOE Ceiling Limit .5 mg/m3 Immediately Dangerous to Life and Health 2.5 mg/m3AMMONIUM HYDROGEN

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM HYDROXIDE CAS # 1336216

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 350.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.7 - LC50 ********

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator Inhalation: Material is extremelydestructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled.

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Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid VAPOR PRESSURE 115.0 mm Hg @ 20 °C

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Copper, Copper alloys, Galvanized iron, Zinc.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.FIREFIGHTIN Protective Equipment: Wear self-contained breathing apparatusand protective clothing to prevent contact with skin and eyes. SpecificHazard(s): Emits toxic fuTOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 34 50 Risk Statements: Causes burns. Very toxic to aquatic organisms. S: 26 36/37/39 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 6 ppm DOE Ceiling Limit 40 ppm Immediately Dangerous to Life and Health 100 ppmAMMONIUM HYDROXIDE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

Page 499:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM METAVANADATE CAS # 7803556

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 4 0 0 ACUTE TOXICTY RISK INDEX 5 - LD50 58.1 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 7.8

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Headache. Tremors. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia Vanadium/vanadiumoxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic.

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R: 25 26 36/37/38 Risk Statements: Toxic if swallowed. Very toxic by inhalation. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0322 mg/m3 DOE Short Term Exposure Limit .0965 mg/m3 DOE Ceiling Limit .322 mg/m3 Immediately Dangerous to Life and Health 3.5 mg/m3AMMONIUM METAVANADATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM MOLYBDATE CAS # 13106768

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 333.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10.2 mg/m3 DOE Short Term Exposure Limit 30.7 mg/m3 DOE Ceiling Limit 51.1 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3AMMONIUM MOLYBDATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM MOLYBDATE TETRAHYDRATE CAS # 12027677

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.

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US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 8.67 mg/m3 DOE Short Term Exposure Limit 8.67 mg/m3 DOE Ceiling Limit 8.67 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM MOLYBDATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM NICKEL(II) SULFATE HEXAHYDRATE CAS # 7785208 HAZARDOUS CHEMICALOF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 399.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Ammonia Nickel/nickel oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 42/43 Risk Statements: May cause cancer. Also harmful if swallowed. May cause sensitization by inhalation and skin contact. S: 53 22 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM NITRATE CAS # 6484522

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX ACUTE TOXICTY RISK INDEX 2.3 - LD50 2217.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin EyeContact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Gastrointestinal disturbances. Blood effects. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong reducing agents, Strong acids, Finely powderedmetals.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom combustible materials, heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM NITRATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM OXALATE MONOHYDRATE CAS # 6009707

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 30 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3AMMONIUM OXALATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMMONIUM PEROXODISULFATE CAS # 7727540

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX ACUTE TOXICTY RISK INDEX 2.8 - LD50 689.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powderedmetals.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom combustible materials, heat, sparks, and open flame\. SPECIALREQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 36/37/38 42/43 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact.

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S: 22 24 26 37 Safety Statements: Do not breathe dust. Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3AMMONIUM

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM RHODANIDE CAS # 1762954

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 750.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin Eye Contact: May causeeye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Forms explosive

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mixtures with:, Lead nitrate.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen cyanideAmmonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic. Air sensitive. Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22-32-52/53 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13-61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.5 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMMONIUM RHODANIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM SULFAMATE CAS # 7773060

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4109.6 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material is irritating to mucous membranes and upper

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respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. Multiple Routes: Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Nitrogen oxides Sulfur oxidesStore at 2-8°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes. Immediately Dangerous to Life and Health 1500 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM SULFAMATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM SULFATE CAS # 7783202

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2840.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Ammonia Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 125 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM SULFATE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM SULFATE-15N CAS # 43086584

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. Multiple Routes: Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Oxidizing Agent

SEGREGATION: SHELF # 2STORAGE GROUP(S): e - Oxidizer/Organic PeroxideWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Ammonia Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM SULFIDE CAS # 12135761

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 3.8 - LD50 80.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.7 - LC50

ROUTE OF EXPOSURE

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skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Readily absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Hydrogen sulfide is recognized by its characteristic odor of "rotten eggs". The detectable, minimum perceptible odor occurs at 0.13ppm. At concentrations of 20ppm hydrogen sulfide begins acting as an irritant on the mucous membranes of the eyes and respiratory tract and increases with concentration and exposure time. The irritant action and odor of rotten eggs often provides the first warning of hydrogen sulfide exposure. Unfortunately, above 150ppm the gas exerts a paralyzing effect on the olfactory apparatus. Prolonged exposure to moderate concentrations (250ppm) may cause pulmonary edema. At concentrations over 500ppm, drowsiness, dizziness, excitement, headache, unstable gait, and other systemic symptoms occur within a few minutes. Sudden loss of consciousness without premonition, anxiety, or sense of struggle are characteristic of acute exposure at concentrations above 700ppm. At concentrations of 1000-2000ppm hydrogen sulfide is rapidly absorbed through the lung into the blood. Initially hyperpnea occurs, followed by rapid collapse and respiratory inhibition. At higher concentrations, hydrogen sulfide exerts an immediate paralyzing effect on the respiratory centers. When concentration reaches 5000ppm, imminent death almost always results. Generally speaking, imminent death due to asphyxia can happen at any time when the concentration reaches 1000ppm or more. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headac

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 450.0 mm Hg @ 20 °C FLASH POINT 68 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Copper, Zinc, Aluminum, Strong bases, Acids, Strongoxidizing agents.FIRE EXTINGUISHER: Water spray. appropriate foam. Dry chemical powder. Usewater spray to cool fire-exposed containers. Do not use carbon dioxideextinguisher on this material.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Evolves hydrogen sulfide which ispoisonous Ammonia

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame\. Incompatible Materials: Avoid contactwith acid\. SPECIAL REQUIREMENTS Avoid contact with acid.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C-N Indication of Danger: Highly Flammable. Corrosive. Dangerous for the environment. R: 11-31-34-50 Risk Statements: Highly flammable. Contact with acids liberates toxic gas. Causes burns. Very toxic to aquatic organisms. S: 26-36/37/39-45-61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.5 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 15 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM SULFITE CAS # 7783111

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION

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Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Ingestion results in irritation of the gastrointestinal tract. Large doses may cause violent colic and diarrhea, circulatory disturbances, central nervous depression, and even death. Persons with allergies and/or asthma may exhibit hypersensitiveity to sulfites. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents Avoid contact with acid., Evolveshydrogen sulfide which is poisonousFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Ammonia Hydrogen sulfide gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Handle and store under inert gas. Air sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 31 36/37/38 Risk Statements: Contact with acids liberates toxic gas. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMMONIUM SULFITE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMMONIUM TARTRATE CAS # 3164292

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMMONIUM TARTRATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM TETRAFLUOROBORATE (1-) CAS # 13826830

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Glass, Avoid all contact with strong acids and strongbases, Aluminum.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia Fluoboric acid Hydrogenfluoride Boron oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONUS CLASSIFICATION AND LABEL TEXT Indication of Danger: Irritant. Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Immediately Dangerous to Life and Health 250 mg/m

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.45 mg/m3 DOE Short Term Exposure Limit 3.45 mg/m3 DOE Ceiling Limit 6 mg/m3 Immediately Dangerous to Life and Health 20 mg/m3AMMONIUM

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM THIOSULFATE CAS # 7783188

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2890.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Magnesium, Aluminum.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Ammonia Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM THIOSULFATE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMMONIUM TRIFLUOROACETATE CAS # 3336581

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nitrogen oxides Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under argon\. SPECIAL REQUIREMENTS Store under inertgas. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear

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suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPHETAMINE SULFATE CAS # 60139

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 4 - LD50 55.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged or repeated exposure can lead to habituation or addiction. Exposure can cause: CNS stimulation. Gastrointestinal disturbances. Fatal poisoning terminates in convulsions, coma, and cerebral hemorrhages. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPHOLYTE CAS # 000042

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIES

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HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPHOLYTE CAS # 42

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

IN CASE OF FIRE, DEVELOPMENT OF TOXIC AND IRRITANT DECOMPOSITION PRODUCTS. OTHER HEALTH HAZARDS MAY BE HARMFUL. MAY CAUSE IRRITATION.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPHOTERICIN B CAS # 1397893

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. Convulsions. Chills, fever, malaise, muscle and joint pain, rash, anorexia, diarrhea, gastrointestinal cramps, hypertension, hypotension, cardiac arrhythmias, ventricular fibrillation, cardiac arrest, blurred vision, tinnitus, vertigo, anaemia and hypokalemia.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.Light and moisture sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C SPECIAL REQUIREMENTS Light and moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPICILLIN CAS # 69534

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 16129.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. There are reports of serious and sometimes fatal hypersensitiveity (anaphylactic) reactions occurring in people receiving penicillin therapy by the parenteral route although it has also occurred via oral administration. These reactions usually occur in individuals who have a history of sensitiveity to multiple allergens, asthma, hay fever or urticaria. Ingestion has resulted in nausea, vomiting, diarrhea, glossitis, stomatitis, enterocolitis, pseudomembranous coloitis. Hypersensitiveity reactions: erythematous maculopapular rashes, erythema multiforme, urticaria and exfoliative dermatis. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at 2-8°C

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Hygroscopic.Keep tightly closed. Store under argon.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Storeunder argon\. Store at 2-8░C SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42/43 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 22 26 36/37 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPICILLIN SODIUM CAS # 69523

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5314.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. There are reports of serious and sometimes fatal hypersensitiveity (anaphylactic) reactions occurring in people receiving penicillin therapy by the parenteral route although it has also occurred via oral administration. These reactions usually occur in individuals who have a history of sensitiveity to multiple allergens, asthma, hay fever or urticaria. Ingestion has resulted in nausea, vomiting,

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diarrhea, glossitis, stomatitis, enterocolitis, pseudomembranous coloitis. Hypersensitiveity reactions: erythematous maculopapular rashes, erythema multiforme, urticaria and exfoliative dermatis. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at 2-8°CKeep tightly closed.Hygroscopic.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C SPECIAL REQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42/43 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 22 26 36/37 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMPICILLIN TRIHYDRATE CAS # 7177482

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect Carcinogen

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C Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. There are reports of serious and sometimes fatal hypersensitiveity (anaphylactic) reactions occurring in people receiving penicillin therapy by the parenteral route although it has also occurred via oral administration. These reactions usually occur in individuals who have a history of sensitiveity to multiple allergens, asthma, hay fever or urticaria. Ingestion has resulted in nausea, vomiting, diarrhea, glossitis, stomatitis, enterocolitis, pseudomembranous coloitis. Hypersensitiveity reactions: erythematous maculopapular rashes, erythema multiforme, urticaria and exfoliative dermatis. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION

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Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42/43 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 22 26 36/37 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYL ACETATE CAS # 628637

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1152.6 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 102.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION R: 10 66 Risk Statements: Flammable. Repeated exposure may cause skin dryness or cracking. S: 25 23 Safety Statements: Avoid contact with eyes. Do not breathe vapor. Immediately Dangerous to Life and Health 1000 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 100 ppm DOE Short Term Exposure Limit 100 ppm DOE Ceiling Limit 100 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYL ALCOHOL CAS # 1565806

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if inhaled or swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 111.2 °F

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SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 20 Risk Statements: Flammable. Harmful by inhalation. S: 24/25 Safety Statements: Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYL ALCOHOL (TERT-) CAS # 75854

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.7 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Lachrymator. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE

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Prolonged exposure can cause: Nausea, dizziness, and headache. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 12.0 mm Hg @ 20 °C FLASH POINT 68 °F Forms ignitable mixtures in air at room temperature - Danger of remoteignition and flashback

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Materials to Avoid: S

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xn Indication of Danger: Highly Flammable. Harmful. R: 11 20 37/38 Risk Statements: Highly flammable. Harmful by inhalation. Irritating to respiratory system and skin. S: 46 Safety Statements: If swallowed, seek medical advice immediately and show this container or label.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 60 ppm DOE Short Term Exposure Limit 100 ppm DOE Ceiling Limit 100 ppm Immediately Dangerous to Life and Health 100 ppmAMYL ALCOHOL (TERT-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYL IODIDE CAS # 628171

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 109.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, andclothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat and open flame. Store in a cool dry place\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 75 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYL PROPIONATE CAS # 624544

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin.

Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

SIGNS AND SYMPTOMS OF EXPOSURE Ingestion can cause gastrointestinal disorders, nausea, and vomiting. Exposure can cause: Incoordination. Conjunctivitis. Prolonged or repeated exposure to skin causes defatting and dermatitis.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Do not breathevapor. Avoid prolonged or repeated exposure. STORAGE: Keep container closed.Keep away from heat, sparks, and open flame.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AMYLAMINE CAS # 110587

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 470.0 mg/Kg INHALATION RISK INDEX <1 - LC50 7115.9

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Flammable FLASH POINT 33.8 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: For small (incipient) fires, use media such as "alcohol"foam, dry chemical, or carbon dioxide. For large fires, apply water fromas far as possible. Use very large quantities (flooding) of water appliedas a mist or spray; solidTOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-20/21/22-34 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes burns. S: 16-26-33-36/37/39-45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 6 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLAMINE (TERT-) CAS # 594398

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Severe irritation or burns. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Prolonged contact can cause: To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

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Flammable FLASH POINT 30 °F Store in an explosion-proof refrigerator or tightly stoppered in awell-ventilated area

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizingagents Carbon dioxide.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 16 26 27 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLASE (ALPHA-) CAS # 9000855

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin.

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Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLASE (ALPHA-) CAS # 9000902

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SENSITIZATION Respiratory: May cause allergic respiratory reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42 Risk Statements: May cause sensitization by inhalation. S: 22 24 36/37 Safety Statements: Do not breathe dust. Avoid contact with skin. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLASE (BETA-) CAS # 9000913

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Respiratory: May cause allergic respiratory reaction. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°C

REACTIVE PROPERTIESSTORAGE Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42 Risk Statements: May cause sensitization by inhalation. S: 22 24 36/37 Safety Statements: Do not breathe dust. Avoid contact with skin. Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLOGLUCOSIDASE CAS # 9032080

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation.

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skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at 2-8°CKeep tightly closed. Store away from heat.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Storeaway from heat. Store at 2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLOID (BETA-) CAS # 131602534

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation.

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Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AMYLOPECTIN CAS # 9037223

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANDROSTANE (5A-) CAS # 438222

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Some steroids show carcinogenic and teratogenic activity. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANETHOLE (TRANS-) CAS # 104461

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 2 1 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2090.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 194 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame\. SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43

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Risk Statements: May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANETHOLE (TRANS-) CAS # 4180238

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 195 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43 Risk Statements: May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANGIOTENSIN I CAS # 70937972

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Angiotensin is a potent vasoconstrictor. It acts directly on the adrenal gland to stimulate the release of aldosterone, which in turn affects metabolism of electrolytes and water. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANGIOTENSIN II CAS # 68521880

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. Adrenal cortex. SIGNS AND SYMPTOMS OF EXPOSURE Angiotensin is a potent vasoconstrictor. It acts directly on the adrenal gland to stimulate the release of aldosterone, which in turn affects metabolism of electrolytes and water. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

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INCOMPATIBILITIES:Strong acids, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANHYDROERYTHRITOL (1,4-) CAS # 4358649

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANHYDROTETRACYCLINE HYDROCHLORIDE CAS # 13803651

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

Page 548:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINE CAS # 62533 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G . I J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 250.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 2500.0

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed.

SENSITIZATION skin: May cause allergic skin reaction.

TARGET ORGAN(S) OR SYSTEM(S) Blood. Bladder. Kidneys. Central nervous system.

SIGNS AND SYMPTOMS OF EXPOSURE Fatigue. Incoordination. Nausea. Vomiting. Headache. Dizziness. Symptoms may be delayed. Unconsciousness. Weakness. Confusion. Drowsiness. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Cyanosis.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .560 mm Hg @ 20 °C FLASH POINT 158 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: ZFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat and open flame. Store in a cool dry place. Store undernitrogen\. SPECIAL REQUIREMENTS Handle under inert gas. Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 23/24/25-40-41-43-48/23/24/25-68-50 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. Very toxic to aquatic organisms. S: 26-27-36/37/39-45-46-61-63 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest. to fresh air and keep at rest. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm

ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm Immediately Dangerous to Life and Health 100 ppm

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 8 ppm DOE Ceiling Limit 12 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINE BLUE CAS # 28631665

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. WATER SPRAY.TOXIC EMISSIONS WHEN BURNED: DES SULFUR OXIDES

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINE BLUE WS CAS # 8004919

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. WATER SPRAY.TOXIC EMISSIONS WHEN BURNED: DES SULFUR OXIDES

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINE HYDROCHLORIDE CAS # 142041

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E F G . . J K L NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 840.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 381.2 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 23/24/25-40-41-43-48/23/24/25-68-50

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Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. Very toxic to aquatic organisms. S: 26-27-36/37/39-45-61-63 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Referto special instructions/safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINE PHTHALATE CAS # 50930795

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G . I J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Blood. Ears. Central nervous system. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Unconsciousness. Weakness. Confusion. Drowsiness. Absorption into the body leads to the formation of methemoglobin which in

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sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Drying, cracking, or irritation of the skin. Gastrointestinal disturbances. Exposure can cause: Can cause CNS depression. Prolonged exposure can cause: Dizziness. Fatigue. Nausea. Vomiting. Cyanosis.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 104 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC

INCOMPATIBILITIES:Halogens, Strong acids Iron and iron salts., Zinc, Strongoxidizing agents, Alkali metals, BasesFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep container closed. Keep away from heat, sparks, and open flame.Light sensitive.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keepaway from heat, sparks, and open flame\. Store at 2-8°C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION R: 11-20/21/22-37/38-40-41-43-48/23/24/25-68 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system and skin. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINO NAPHTHALENESULFONIC ACID CAS # 82768

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANILINOETHANOL (2-) CAS # 122985

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2230.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .010000 mm Hg @ 20 °C FLASH POINT 307.4 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents,Chloroformates.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.STORAG Suitable: Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 24 36 Risk Statements: Toxic in contact with skin. Irritating to eyes. S: 26 36/37/39 4 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ANILINONAPHTHALENESULFONIC ACID AMMONIUM (8:1-) CAS # 28836035

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 3STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Store under inert gas. Hygroscopic. Air and light sensitive.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISALDEHYDE CAS # 123115

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0

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ACUTE TOXICTY RISK INDEX 1.1 - LD50 43000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE***** mm Hg @ 20 °C FLASH POINT 240.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Water spray\. Protective Equipment: Wear self-contained breathing apparatusand protective clothing to prevent contact with skin and eyes. SpecificHazard(s): Emits t

REACTIVE PROPERTIESHANDLING: Avoid prolonged or repeated exposure. Do not STORAGE: Keep tightlyclosed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .075 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 1.5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ANISIC ACID (ORTHO-) CAS # 579759

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ANISIC ACID (PARA-) CAS # 100094

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 1 1 ACUTE TOXICTY RISK INDEX 2.7 - LD50 887.0 mg/Kg INHALATION RISK INDEX 1.2 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .130 mm Hg @ 20 °C FLASH POINT 365 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contactwith eyes, rinse immediately with plenty of water and seek medical advice.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISIDINE (META-) CAS # 536903

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 526.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 258.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates,Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 22 36/37/38 50/53 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISIDINE (ORTHO-) CAS # 90040 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . . . I J K L NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1150.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen).

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0475 mm Hg @ 20 °C FLASH POINT 212 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store underinert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 23/24/25 68 Risk Statements: May cause cancer. Also toxic by inhalation, in contact with skin and if swallowed. Also possible risks of irreversible effects. S: 53 45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 2.5 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3ANISIDINE (ORTHO-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISIDINE (PARA-) CAS # 104949

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A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1320.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be fatal if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 251.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 45 26/27/28 33 50 Risk Statements: May cause cancer. Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative

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effects. Very toxic to aquatic organisms. S: 53 28 36/37 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 2.5 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3ANISIDINE (PARA-) CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISOLE CAS # 100663

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 4 - LD50 3700.0 mg/Kg INHALATION RISK INDEX 1.9 - LC50 936.5

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.7 mm Hg @ 20 °C FLASH POINT 109.4 °F

SEGREGATION: SHELF # 1

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STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: IGNITABLE

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION R: 10 Risk Statements: Flammable.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 12.5 mg/m3 DOE Ceiling Limit 75 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISOMYCIN CAS # 22862766

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.8 - LD50 72.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISOYL CHLORIDE (META-) CAS # 1711053

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

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investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 197.6 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keeptightly closed. Keep away from heat and open flame. Store in a cool dryplace\. SPECIAL REQUIREMENTS May develop pressure. Open carefully.Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 36/37 Risk Statements: Causes burns. Irritating to eyes and respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANISOYL CHLORIDE (PARA-) CAS # 100072 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE

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skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratorytract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid Ccombustible FLASH POINT 188.6 °F Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat and open flame. Store in a cool dry place\. Incompatible Materials:Do not allow contact with water Special REQUIREMENTS Vent periodically.May develop pressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 Risk Statements: Reacts violently with water. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitableprotective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot

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guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRACENE CAS # 120127

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 17000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. Bladder. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Possible tumor promoter. Exposure can cause: Headache. Nausea. Weakness.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .140 mm Hg @ 20 °C FLASH POINT 249.8 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Hypochlorites, Chromic acid,Fluorine.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi N Indication of Danger: Irritant. Dangerous for the environment. R: 36/37/38 50/53 Risk Statements: Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 30 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRACENE CARBOXYLIC ACID (9-) CAS # 723626

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRAFLAVIC ACID CAS # 84606

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLIN User Exposure: Do not breathe dust. Avoid contact with eyes, skin,

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and clothing. STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRALDEHYDE (9-) CAS # 642319

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRANIL CAS # 271589

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orTOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesROUTE OF EXPOSURE

REACTIVE PROPERTIESHANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keeptightly closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ANTHRANILIC ACID CAS # 118923

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 5 - LD50 5410.0 mg/Kg INHALATION RISK INDEX <1 - LC50 29.7

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 12.5 mg/m3 DOE Ceiling Limit 75 mg/m3

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Immediately Dangerous to Life and Health 500 mg/m3ANTHRANILIC ACID CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRAQUINONE CAS # 84651

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 4 - LD50 16129.0 mg/Kg INHALATION RISK INDEX <1 - LC50 1300.0

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .110 mm Hg @ 20 °C FLASH POINT 365 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIES

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HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43 Risk Statements: May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRAQUINONE CARBOXYLIC ACID (2-) CAS # 117782

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRAQUINONE DISULFONIC ACID CAS # 853350

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 500 mg 24H Remarks: Mild irritation effect

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRAQUINONE SULFONIC ACID SODIUM CAS # 131088

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 19444.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTHRONE CAS # 90448

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTI-PYRUVIC ALDEHYDE OXIME CAS # 31915829 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CSublimes at room temperature

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Handle and store under nitrogen. Unsuitable:Sublimes at room temperature Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIFOAM CAS # 43

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR

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appropriate foam.TOXIC EMISSIONS WHEN BURNED: ON MONOXIDE HAZARDOUS POLYMERIZ

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIFOAM A CAS # 000048

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi

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Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 23 26 36 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIFOAM A CAS # 48

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: PRODUCTS NOT KNOWNHAZARDOUS POLYMERIZATION

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIMONY CAS # 7440360 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7000.0 mg/Kg

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INHALATION RISK INDEX 1.2 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Heart. Respiratory system. SIGNS AND SYMPTOMS OF EXPOSURE Nausea, vomiting, diarrhea. Headache. Dizziness. CONDITIONS AGGRAVATED BY EXPOSURE Chronic effects due to antimony are alterations of the ECG, especially T-wave abnormalities, myocardial changes, pneumoconiosis, but also pneumonitis, tracheitis, laryngitis, bronchitis, pustular skin eruptions called antimony spots, and contact allergy to the metal.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents, Acids, Reaction with acids produceshighly toxic fumes of stibine (antimony hydride).FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Antimony/antimony oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Air sensitive. Moisture sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: N Indication of Danger: Dangerous for the environment. R: 51/53 Risk Statements: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 60 Safety Statements: This material and its container must be disposed of as hazardous waste.

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Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIMONY TRIOXIDE CAS # 1309644

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.2 - LD50 34600.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Materials to Avoid: S

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 Risk Statements: Limited evidence of a carcinogenic effect.

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S: 22 36/37 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .599 mg/m3 DOE Short Term Exposure Limit 1.8 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 59.9 mg/m3ANTIMONY TRIOXIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIMONY(II) FLUORIDE CAS # 7783564 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W ACUTE TOXICTY RISK INDEX 2.3 - LD50 2593.5 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 3.3 - LC50

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Blood. Kidneys. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE 200.0 mm Hg @ 20 °C Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Oxidizing agents, Acids, Perchloric acid.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water.TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Antimony/antimony oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Handle and store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/24/25 51/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 7 26 45 61 Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 50 mg/m

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .734 mg/m3 DOE Short Term Exposure Limit .734 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 73.4 mg/m3ANTIMONY(II) FLUORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIMONY(V) CHLORIDE CAS # 7647189 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W ACUTE TOXICTY RISK INDEX 5 - LD50 1115.0 mg/Kg INHALATION RISK INDEX 1.8 - LC50 192.2

ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE .870 mm Hg @ 20 °C Reacts violently with water

SEGREGATION: SHELF # 1STORAGE GROUP(S): b - Pyrophoric/Water ReactiveWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Reacts violently with water.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Do not use waterTOXIC EMISSIONS WHEN BURNED: Antimony/antimony oxides

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Store under inert gas. Keeptightly closed. Store in a cool dry place\. Incompatible Materials: Do notallow contact with water Special REQUIREMENTS Store under inert gas. Reactsviolently with water.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 34 51/53 Risk Statements: Causes burns. Toxic to aquatic organisms, may

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cause long-term adverse effects in the aquatic environment. S: 26 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advic immediately(show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.23 mg/m3 DOE Short Term Exposure Limit 3.68 mg/m3 DOE Ceiling Limit 6.14 mg/m3 Immediately Dangerous to Life and Health 123 mg/m3ANTIMONY(V) CHLORIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIMONY(V) SULFIDE CAS # 1315044 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin EyeContact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Acids, Oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Antimony/antimony oxides Hydrogen sulfide gasSulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Avoid contact with acid.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 51/53 Risk Statements: Harmful by inhalation and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 61 Safety Statements: Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 50 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .829 mg/m3 DOE Short Term Exposure Limit 2.49 mg/m3 DOE Ceiling Limit 4.15 mg/m3 Immediately Dangerous to Life and Health 82.9 mg/m3ANTIMONY(V) SULFIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTIPAIN CAS # 37682727

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ACUTE EFFECTS THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. MAY CAUSE SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. MAY CAUSE EYE IRRITATION.

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MAY BE HARMFUL IF INHALED. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. RTECS #: YV9350800 L-VALINAMIDE, N(SUP 2)-(((1-CARBOXY-2-PHENYLETHYL)AMINO)CARBONYL)-L-ARGINYL-N-(4-((AMINO IMINOMETHYL)AMINO)-1-FORMYLBUTYL)-, DIHYDROCHLORIDE ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR

REACTIVE PROPERTIES-

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ANTITRYPSIN (ALPHA,1-) CAS # 9041923

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Potentially biohazardous material. CONDITIONS AGGRAVATED BY EXPOSURE

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The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fireconditions.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: B Indication of Danger: Biohazard.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

APIGENIN CAS # 520365

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

APOFERRITIN CAS # 9013314

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

APOMORPHINE HYDROCHLORIDE CAS # 41372207

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 967.7 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed.

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SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. G.I. System. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Ingestion can cause: Abdominal pain, nausea, vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases Iron and iron salts.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store underinert gas. Light sensitive. Air-, heat-, and moisture-sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 36 Safety Statements: Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

APOTRYPTOPHANASE CAS # 9024004

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L

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NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

APROTININ CAS # 9087701

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed.

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SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause nausea, vomiting, diarrhea, muscle pains, blood pressure changes, and bronchospasm. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABINOSE CAS # 20235192

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABINOSE (D-) CAS # 28697532

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriatetosurrounding fire conditions.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABINOSE (L-) CAS # 147819

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ARABINOSE (L-) CAS # 5328370

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABINOSE (L-) CAS # 87729

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

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ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABINOSE-13C (D,1-) CAS # 70849239

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE

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To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARABITOL (D-) CAS # 488824

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARACHIDONIC ACID SODIUM CAS # 6610259 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 2 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible Explosive FLASH POINT 235 °F Forms explosive unstable peroxides Test periodically or discard

SEGREGATION: SHELF # 3STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: REACTIVE

INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents.

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FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.Store at -20°CKeep tightly closed.Store under inert gas. Air and moisture sensitive.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C SPECIAL REQUIREMENTS Store under inert gas. Air and moisturesensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION R: 19 Risk Statements: May form explosive peroxides.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARALDITE 502 CAS # 25068386

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 13600.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid VAPOR PRESSURE .010000 mm Hg @ 20 °C

SEGREGATION: SHELF # 2

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STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi N Indication of Danger: Irritant. Dangerous for the environment. R: 36/38 43 51/53 Risk Statements: Irritating to eyes and skin. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 37/39 61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable gloves and eye/face protection. Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 125 mg/m3 DOE Short Term Exposure Limit 350 mg/m3 DOE Ceiling Limit 500 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGINASE CAS # 9000968

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic

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reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°C

REACTIVE PROPERTIESSTORAGE: Keep container closed. Store away from heat\. Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGININE (DL-) CAS # 7200251

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

S PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION

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EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGININE (L-) CAS # 74793

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

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US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGININE HYDROCHLORIDE (D-) CAS # 627758

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25

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Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGININE HYDROCHLORIDE (DL-) CAS # 32042436

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ARGININE KINASE CAS # 9026704

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at 2-8°C

REACTIVE PROPERTIESSTORAGE Store at 2-8░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGININE MONOHYDROCHLORIDE (L-) CAS # 1119342

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12000.0 mg/Kg

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARGON CAS # 7440371

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Can

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cause rapid suffocation. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, dizziness, and headache. CONDITIONS AGGRAVATED BY EXPOSURE At high concentrations argon functions as a simple asphyxiant by displacing air.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Gas VAPOR PRESSURE******* mm Hg @ 20 °C

SEGREGATION: SHELF # 3STORAGE GROUP(S): i - CorrosiveorNon-Toxic GasWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool. Movecylinder away from fire if there is no risk.

REACTIVE PROPERTIESHANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Cylindertemperature should not exceed 125░F (52░C)\. SPECIAL REQUIREMENTS Contents under pressure.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 38 Safety Statements: In case of insufficient ventilation, wear suitable respiratory equipment.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 65000 ppm DOE Short Term Exposure Limit 65000 ppm DOE Ceiling Limit 230000 ppm

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARSENIC(III) OXIDE CAS # 1327533

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . B C . . . . . I J . L NFPA HAZARD CODES (H,F,R,O) 3 0 0

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HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.5 - LD50 14.6 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 3.2 - LC50

cancer hazard ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Heart. Brain. Kidneys. Skin. Bone marrow. Peripheral nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to arsenic compounds can cause exfoliation and pigmentation of skin, herpes, inflammation of nerves, and nasal septum ulceration. Dry mouth, a metallic taste, drowsiness, loss of appetite, excessive salivation, nausea, vomiting and a foul, garlic-like breath. CONDITIONS AGGRAVATED BY EXPOSURE Exposure to arsenic compounds can cause burning and dryness of the oral and nasal cavities, muscle spasms, irritation of the gastrointestinal tract, nausea, vomiting and diarrhea which can progress to shock and death.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents, Metals.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Arsenic oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 45 28 34 50/53 Risk Statements: May cause cancer. Also very toxic if swallowed. Causes burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .01 mg/m3 DOE Short Term Exposure Limit .03 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 5 mg/m3ARSENIC(III) OXIDE CAS

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ARSENIC(III) SULFIDE CAS # 1303339 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D E F G . I J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 185.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

cancer hazard

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ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) skin. Lungs.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE

INCOMPATIBILITIES:Acids, Oxidizing agents, Halogens.FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriatetosurrounding fire conditions.TOXIC EMISSIONS WHEN BURNED: Arsenic oxides Sulfur oxides Hydrogen sulfidegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoidprolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cooldry place\. Incompatible Materials: Avoid contact with acid.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 50/53 Risk Statements: Toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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ARSENIC(V) OXIDE CAS # 1303282

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . C D . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 8.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

cancer hazard ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) skin. Lungs.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Arsenic oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 45 23/25 50/53 Risk Statements: May cause cancer. Also toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 60 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. This

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material and its container must be disposed of as hazardous waste. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0153 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 7.67 mg/m3 Immediately Dangerous to Life and Health 7.67 mg/m3ARSENIC(V) OXIDE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASCARITE CAS # 81133202

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

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INCOMPATIBILITIES:Strong acids.FIRE EXTINGUISHER: Dry chemical powder.

REACTIVE PROPERTIESHANDLING: Do not get in eyes, on skin, on clothing. Avoid prolonged orrepeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\.SPECIAL REQUIREMENTS Air sensitive. Hygroscopic.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .005 mg/m3 DOE Short Term Exposure Limit .5 mg/m3 DOE Ceiling Limit .5 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASCORBIC ACID (L-) CAS # 50817

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11900.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and

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toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.Light sensitive.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C SPECIAL REQUIREMENTS Light sensitive.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 60 mg/m3 DOE Short Term Exposure Limit 200 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ASCORBIC ACID (L-)

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASCORBIC ACID SODIUM (L-) CAS # 134032

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE

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To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong bases.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARAGINASE CAS # 9015683 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . B . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 1.8 - LD50 7500.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Pancreas.

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SIGNS AND SYMPTOMS OF EXPOSURE Other symptoms may include anorexia, chills, fever, weight loss, abdominal cramps, hyperglycemia, pancreatitis, bone marrow depression, a decrease in blood concentration of fibrinogen depressing the clotting mechanisms, and liver and kidney damage. Inhibits protein synthesis in various tissues of the body. Exposure can cause: Nausea, headache, and vomiting. CNS depression.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 63 Risk Statements: May cause sensitization by inhalation and skin contact. Possible risk of harm to the unborn child. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARAGINE (L-) CAS # 70473

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0

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INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Dessicate.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARTAME CAS # 22839470

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation.

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Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Warning! To persons with phenylketonuria! This material can release phenylalanine

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARTIC ACID (D-) CAS # 1783966

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARTIC ACID (DL-) CAS # 617458

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin.

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Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/ToxicWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARTIC ACID (L-) CAS # 56848

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be

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irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents, Nitricacid.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ASPARTIC ACID DIMETHYL ESTER HYDROCHLORIDE (L-) CAS # 32213959

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gasStore at -20°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ATENOLOL CAS # 29122687

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):

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g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ATP DIPHOSPHATE (5'-) CAS # 42373411

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ACUTE EFFECTS MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAN CAUSE CNS DEPRESSION. EXPOSURE CAN CAUSE: NAUSEA, HEADACHE AND VOMITING NARCOTIC EFFECT DAMAGE TO THE HEART TARGET ORGAN(S): NERVES LIVER TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2

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STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TOSURROUNDING FIRE CONDITIONS.TOXIC EMISSIONS WHEN BURNED: RODUCE TOXIC FUMES OF PHOSPHORUS OXIDES AND/ORPHOSPHINE CARBON MONOXI

REACTIVE PROPERTIES-

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ATP SODIUM CAS # 987655

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Liver. Kidneys. Heart. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Phosphorous oxides Sodium/sodium oxidesNitrogen oxides Carbon dioxideStore at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ATRAZINE CAS # 1912249

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . . . E . G . I . K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX ++ - TD50 31.7 mg/Kg REPRODUCTIVE RISK INDEX 2.9 ACUTE TOXICTY RISK INDEX 3 - LD50 672.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 43 48/22 50/53 Risk Statements: May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 60 61 Safety Statements: Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

ATROPINE SULFATE HYDRATE CAS # 5908996

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . D . . . . I . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be fatal if inhaled. Material may be irritating

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to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Heart. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Can cause CNS depression.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 26/28 Risk Statements: Very toxic by inhalation and if swallowed. S: 23 45 Safety Statements: Do not breathe fumes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AURAMINE O CAS # 2465272 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX A . . . E . . . . . K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.6 - TD50 11.0 mg/Kg ACUTE TOXICTY RISK INDEX 2.5 - LD50 1548.4 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 22 24 40 Risk Statements: Harmful if swallowed. Toxic in contact with skin. Limited evidence of a carcinogenic effect. S: 36/37 45 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.5 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 60 mg/m3

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AVA-OH (BOC,5-) CAS # 27219074

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed. Store in a cool dry place.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place. Store at 2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

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The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AVIDIN CAS # 1405692

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Symptoms of biotin deficiency. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.Store at -20°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at-20°C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25

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Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AVIDIN GALACTOSIDASE (BETA-) CAS # 000044

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE Store at -20░C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AVIDIN GALACTOSIDASE (BETA-) CAS # 44

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: NHAZARDOUS POLYMERIZATION WILL NOT OCCURStore at -20°C

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZA-18-CROWN-6 (1-) CAS # 33941150

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 OX INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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Ccombustible FLASH POINT 235 °F Oxidizing Agent

SEGREGATION: SHELF # 1STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZABICYCLONONANE CAS # 283249

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1700.0 mg/Kg INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

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FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: C FUMES OF:

REACTIVE PROPERTIESMAY CAUSE EXPLOSIVE DECOMPOSITION OF MALEIC ANHYDRIDE. REACTS VIOLENTLYWITHTRIISOBUTYL ALUMINUM.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZACYTIDINE (5-) CAS # 320672 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A B . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 5+ - TD50 .2 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 2.4 - LD50 1845.2 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bone marrow. G.I. System. Immune system. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Nausea, headache, and vomiting. Damage to the liver.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 1STORAGE GROUP(S): a - Organic Base/Flammable/ToxicWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

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TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at -20°CLight sensitive.Keep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C SPECIAL REQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZAGUANINE (8-) CAS # 134587

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4838.7 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

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SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZAINDOLE (7-) CAS # 271636

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZELAIC ACID CAS # 123999

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . F G . . . . L NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3100.0 mg/Kg INHALATION RISK INDEX 1.5 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE***** mm Hg @ 20 °C FLASH POINT 410 °F

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SEGREGATION: SHELF # 1STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: CORROSIVE

INCOMPATIBILITIES:Bases, Reducing agents, Oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Avoid prolonged or repeatedexposure. STORAGE: Keep container closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZETIDINE CARBOXYLIC ACID (L,2-) CAS # 2133348

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides

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REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store ina cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZETIDINONE (2-) CAS # 930212

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep tightly closed.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.

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Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at2-8░C

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZIDOTETRAFLUOROBENZOIC ACID SUCCINIMIDYL ESTER (4 CAS # 126695587

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.

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FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen fluorideStore at -20°CKeep tightly closed.Light sensitive.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at-20░C SPECIAL REQUIREMENTS Light sensitive.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZINOBIS ETHYLBENZOTHIAZOLIDINE SULFONATE DIAMINE CAS # 30931670

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

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REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZINOBIS ETHYLBENZTHIAZOLINE (2,2'-) CAS # 28752683

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Liquid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ORappropriate foam.TOXIC EMISSIONS WHEN BURNED: UMES OF:

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZITHROMYCIN CAS # 83905015

A Special Carcinogen E Dermal Hazard I Neurotoxin

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B Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOBENZENE CAS # 103333 HAZARDOUS CHEMICAL OF CONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX A . . . . . . . . . K . NFPA HAZARD CODES (H,F,R,O) 1 1 1

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SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.3 - TD50 24.1 mg/Kg ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Spleen. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .190 mm Hg @ 20 °C FLASH POINT 212 °F

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIALREQUIREMENTS Store under inert gas.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 45 20/22 48/22 68 50/53 Risk Statements: May cause cancer. Also harmful by inhalation and if swallowed. Also harmful: danger of serious damage to health by prolonged exposure if swallowed. Also possible risks of irreversible effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice

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immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOBIS CYANOPENTANOIC ACID (4,4':4-) CAS # 2638940

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Flammable

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CKeep container closed. Keep away from heat, sparks, and open flame.Light sensitive.

REACTIVE PROPERTIESHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathingdust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed.

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Keep away from heat, sparks, and open flame. Store at 2-8░C SPECIALREQUIREMENTS Light sensitive.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 15 16 22 24/25 36 Safety Statements: Keep away from heat. Keep away from sources of ignition - no smoking. Do not breathe dust. Avoid contact with skin and eyes. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOBIS ISOBUTYRONITRILE (2,2'-) CAS # 78671 HAZARDOUS CHEMICAL OFCONCERN

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 3 3 ACUTE TOXICTY RISK INDEX 3.7 - LD50 100.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, dizziness, and headache. Drowsiness. Unconsciousness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Explosive

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Shock sensitive Explosive

SEGREGATION: SHELF # 3STORAGE GROUP(S): k - Explosive/UnstableWASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC

INCOMPATIBILITIES:Aldehydes, Strong oxidizing agents, Alcohols, Alkalimetals, Heptane, Chemical contamination, Acetone.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Tetramethylsuccinonitrile Hydrogen cyanideStore at 2-8°CKeep tightly closed. Keep away from heat, sparks, and open flame.Self-heating runaway reaction may

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep awayfrom heat, sparks, and open flame. Unsuitable: Self-heating runawayreaction may occur above 40░ Store at 2-8░C SPECIAL REQUIREMENTS

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: E Xn Indication of Danger: Explosive. Harmful. R: 2 11 20/22 52/53 Risk Statements: Risk of explosion by shock, friction, fire, or other sources of ignition. Highly flammable. Harmful by inhalation andif swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 39 41 47 61 Safety Statements: Wear eye/face protection. In case of fire and/or explosion do not breathe fumes. Keep at temperature not exceeding 40░C Avoid release to the environment. Refer to special instructions/safety data sheets.

US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 300 mg/m3AZOBIS ISOBUTYRONITRILE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOBIS(CYCLOHEXANE CARBONITRILE (1,1'-) CAS # 2094986

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

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HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Nausea, headache, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid Flammable

SEGREGATION: SHELF # 1STORAGE GROUP(S): l - Flammable/Combustible SolventWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesStore at 2-8°CVent periodically. May develop pressure. Open carefully.

REACTIVE PROPERTIESHANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE Store at 2-8░C SPECIALREQUIREMENTS Vent periodically. May develop pressure. Open carefully.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 22 24/25 26 36 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AZOBISAMIDINOPROPANE DIHYDROCHLORIDE (2,2':2-) CAS # 2997924

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 410.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Anorexia. Headache. Dizziness. Stomach pains, vomiting, diarrhea. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong acids.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Ammonia

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 43 Risk Statements: Harmful if swallowed. May cause sensitization by skin contact. S: 24 37 Safety Statements: Avoid contact with skin. Wear suitable gloves.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOCARMINE G CAS # 25641183

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this

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information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZOCOLL CAS # 53092903

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

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AZOXYBENZENE CAS # 495487

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 620.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the liver. Damage to the kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). Exposure can cause: Damage to the liver. Damage to the kidneys.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents, Strong reducingFIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid all contact. Avoid prolonged orrepeated exposure. Do not get in eyes, on skin, on clothing. STORAGE: Keeptightly closed. Keep away from heat and open flame. Store in a cool dryplace.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 Risk Statements: Harmful by inhalation and if swallowed. S: 28 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources

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documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZULENE CAS # 275514

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S):WASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE A CAS # 531533

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro Haz

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D Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE A EOSINATE CAS # 62298435

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . .

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NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE B CAS # 531555

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICS

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PHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Materials to Avoid: SFIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE B EOSINATE CAS # 62298424

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous

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WASTE CHARACTERISTIC HAZARD:

FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.

REACTIVE PROPERTIESSTORAGE

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE C CAS # 531577

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam\. Protective Equipment: Wear self-contained breathingapparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t

REACTIVE PROPERTIESHANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, onclothing. STORAGE SPECIAL REQUIREMENTS

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION S: 22 24/25

Page 663:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE II CAS # 37247102

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Stomach pains, vomiting, diarrhea. Nausea, dizziness, and headache.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD: TOXIC

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing.Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed.

Page 664:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.

AZURE II EOSINATE CAS # 53092856

A Special Carcinogen E Dermal Hazard I NeurotoxinB Human Terato\Repro Haz F Corrosive J Suspect CarcinogenC Highly Toxic G Eye Damage K Suspect Terato\Repro HazD Inhalation Hazard H STEL L Sensitizers

HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50

ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes severe eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

PHYSICAL CHARACTERISTICSPHYSICAL STATE: Solid

SEGREGATION: SHELF # 2STORAGE GROUP(S): g - Non-Reactive/Non-HazardousWASTE CHARACTERISTIC HAZARD:

INCOMPATIBILITIES:Strong oxidizing agents.FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, orappropriate foam.TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloridegas Hydrogenbromide gas

Page 665:  · Web viewABSCISIC ACID CAS # 14375452. A Special Carcinogen E Dermal Hazard I Neurotoxin. B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen. C Highly Toxic G Eye Damage

REACTIVE PROPERTIESHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing.STORAGE: Keep tightly closed. Store in a cool dry place.

GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATIONEU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 41 Risk Statements: Risk of serious damage to eyes. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.