wash kit - nanopore · 2016-08-12 · solution a potassium ferrocyanide (cas: 14459-95-1)...

Wash Kit

Revision Date 29/04/2014

SAFETY DATA SHEET

Solution A

According to Regulation (EU) No 453/2010

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Solution A

Container size 1 mL

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Laboratory Reagent. For research purposes only.

1.3. Details of the supplier of the safety data sheet

Oxford Nanopore Technologies Ltd.Supplier

Edmund Cartwright House,

4 Robert Robinson Avenue,

Oxford Science Park,

Oxford, OX4 4GA

UK

T: +44 (0) 845 034 7900

F: +44 (0) 845 034 7901

W: www.nanoporetech.com

E: [email protected]

1.4. Emergency telephone number

+44 (0) 845 034 7900 (Mon - Fri 09:00 - 17:00 h)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical Hazards Not classified.

Human health EUH032

Environment Not classified.

Classification (1999/45/EEC) R32.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health

Warning - this preparation contains a substance not yet tested completely. Contact with acids liberates very toxic gas.

Environment

The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic

environment.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Precautionary Statements

P280 Wear protective clothing, gloves, eye and face protection.

Supplemental label information

EUH032 Contact with acids liberates very toxic gas.

2.3. Other hazards

This product does not contain any PBT or vPvB substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

121 /

Solution A

POTASSIUM FERROCYANIDE 5-10%

CAS-No.: 14459-95-1 EC No.: 237-722-2

Classification (67/548/EEC)

R52/53,R32.


EUH032

Aquatic Chronic 3 - H412

POTASSIUM FERRICYANIDE 1-5%

CAS-No.: 13746-66-2 EC No.: 237-323-3


R32.


EUH032


SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information

Warning - this preparation contains a substance not yet tested completely. Get medical advice/attention if you feel unwell.

Contact with acids liberates very toxic gas. IF exposed or concerned: Get medical advice/attention.

Inhalation

Due to the small packaging the risk of inhalation is minimal. Move into fresh air and keep at rest. Get medical attention if any discomfort

continues.

Ingestion

Get medical attention if any discomfort continues.

Skin contact

Remove contaminated clothing. Wash skin thoroughly with soap and water for several minutes. Get medical attention promptly if

symptoms occur after washing.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.

Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

No specific symptoms noted.

Ingestion

Not known. May cause discomfort if swallowed.

Skin contact


Eye contact

Spray in the eyes: May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Warning - this preparation

contains a substance not yet tested completely. Contact with acids liberates very toxic gas.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). Hydrocarbons. Hydrogen cyanide (HCN).

122 /

Solution AUnusual Fire & Explosion Hazards

No unusual fire or explosion hazards noted.

Specific hazards

Contact with acids liberates very toxic gas.

5.3. Advice for firefighters

Special Fire Fighting Procedures

Contact with acids liberates very toxic gas. Warning - this preparation contains a substance not yet tested completely. Avoid contact with

skin and eyes.

Protective equipment for fire-fighters

Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Avoid discharge to the aquatic environment.

6.3. Methods and material for containment and cleaning up

In case of spills, beware of slippery floors and surfaces. Wear necessary protective equipment. CAUTION! Contact with acids liberates

very toxic gas. Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. For waste disposal, see

section 13.

6.4. Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for more detailed information on health effects

and symptoms. For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Do not

handle broken packages without protective equipment. Avoid contact with skin and eyes. Do not eat, drink or smoke when using the

product. Wash hands thoroughly after handling. Avoid contact with acids.

7.2. Conditions for safe storage, including any incompatibilities

Protect from freezing and direct sunlight. Store at temperatures not exceeding 4°C. Store away from: Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments

No exposure limits noted for ingredient(s).

8.2. Exposure controls

Process conditions

Provide eyewash station.

Engineering measures

Provide adequate general and local exhaust ventilation.

Respiratory equipment

Respiratory protection may be required. Contact with acids liberates very toxic gas. Wear full face mask supplied with: Type: ABEK [ EN

14387:2004 ]

Hand protection

Protective gloves must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with

the gloves supplier, who can inform about the breakthrough time of the glove material.

Eye protection

Wear approved safety goggles.

123 /

Solution AOther Protection

Wear suitable protective clothing as protection against splashing or contamination.

Hygiene measures

Wash hands after handling. When using do not eat, drink or smoke. Wash contaminated clothing before reuse.

Environmental Exposure Controls


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Colourless to pale yellow.

Odour No characteristic odour.

Solubility Soluble in water.

Initial boiling point and boiling range

(°C)

~100 °C @ 760 mm Hg

Melting point (°C) ~ 0 °C @ 760 mm Hg

Relative density

Not determined.

Vapour density (air=1)

Not determined.

Vapour pressure

Not determined.

Evaporation rate

Not determined.

pH-Value, Conc. Solution

Not determined.

Viscosity

Not determined.

Decomposition temperature (°C)

Not determined.

Odour Threshold, Lower

Not determined.

Odour Threshold, Upper

Not determined.

Flash point (°C)

Not determined.

Auto Ignition Temperature (°C)

Not determined.

Flammability Limit - Lower(%)

Not determined.

Flammability Limit - Upper(%)

Not available.

Partition Coefficient

(N-Octanol/Water)

Not determined.

Explosive properties

Not considered to be explosive.

Oxidising properties

Does not meet the criteria for oxidising.

9.2. Other information

Not known.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

Reaction with: Acids.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use. Stable under the prescribed storage conditions.

124 /

Solution A

10.3. Possibility of hazardous reactions

Not known.

Hazardous Polymerisation

Will not polymerise.

10.4. Conditions to avoid

Avoid heat. Protect from freezing and direct sunlight.

10.5. Incompatible materials

Materials To Avoid


10.6. Hazardous decomposition products

Not known.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Toxicological information

Warning - this preparation contains a substance not yet tested completely.

Acute toxicity:

Acute Toxicity (Oral LD50)

No information available.

Based on available data the classification criteria are not met.

Acute Toxicity (Dermal LD50)



Acute Toxicity (Inhalation LC50)



Skin Corrosion/Irritation:


Serious eye damage/irritation:


Respiratory or skin sensitisation:

Respiratory sensitisation



Skin sensitisation



Germ cell mutagenicity:

Genotoxicity - In Vitro



Carcinogenicity:

Carcinogenicity



Reproductive Toxicity:

Reproductive Toxicity - Fertility



125 /

Solution AReproductive Toxicity - Development



Specific target organ toxicity - single exposure:

STOT - Single exposure



Specific target organ toxicity - repeated exposure:

STOT - Repeated exposure



Aspiration hazard:

Not anticipated to present an aspiration hazard based on chemical structure.

Toxicological information on ingredients.

126 /

Solution APOTASSIUM FERROCYANIDE (CAS: 14459-95-1)


CAUTION! Contact with acids liberates very toxic gas. Hydrogen cyanide (HCN).

Acute toxicity:


3613 mg/kg Rat

IUCLID data sheet.






> 1000 mg/m3 Rat 4 hours

IUCLID data sheet.

Limited information on study available. No reported deaths occurred. Based on available data the classification criteria are not met.


Dose

(Dose and duration unstated) Rabbit

IUCLID data sheet.

Not irritating. Based on available data the classification criteria are not met.


May cause temporary eye irritation. Based on available data the classification criteria are not met.





Skin sensitisation

Guinea pig maximization test (GPMT): Guinea Pig

IUCLID data sheet.

Not Sensitising. Based on available data the classification criteria are not met.



DNA damage and/or repair:

IUCLID data sheet.

Negative.


Genotoxicity - In Vivo



Carcinogenicity:

Carcinogenicity

(Dose and duration unstated) Oral Rat

IUCLID data sheet.

Is not expected to be carcinogenic, based on results of related chemicals in animal studies Based on available data the classification

criteria are not met.





Reproductive Toxicity - Development

Teratogenicity: NOAEL =<0.036 ppm Inhalation. Rat

127 /

Solution ADelivered in aerosol form, 24 hours a day for an unknown duration. Insufficient data presented and test not conducted to OECD guidelines.

IUCLID data sheet.

Data lacking.




Not classified as a specific target organ toxicant after a single exposure.




Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard:

Viscosity

Not applicable.


128 /

Solution APOTASSIUM FERRICYANIDE (CAS: 13746-66-2)



Acute toxicity:


2970 mg/kg Mouse

Supplier Safety Data Sheet









Data lacking. Based on available data the classification criteria are not met.







Skin sensitisation










Carcinogenicity:

Carcinogenicity


















129 /

Solution A

Aspiration hazard:

Viscosity

Not applicable.


SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or

frequent spills can have a harmful or damaging effect on the environment.

12.1. Toxicity

Acute Fish Toxicity

Not considered toxic to fish.

Ecological information on ingredients.

POTASSIUM FERROCYANIDE (CAS: 14459-95-1)

Acute Toxicity - Fish

LC50 96 hours 19 mg/l Poecilia reticulata (Guppy)

IUCLID data sheet.

LC50 96 hours > 100 mg/l Pimephales promelas (Fat-head Minnow)

IUCLID data sheet.

Acute Toxicity - Aquatic Invertebrates

EC50 96 hours 32 mg/l Daphnia magna

IUCLID data sheet.

Acute Toxicity - Microorganisms

NOEC ~ 47 mg/l Activated sludge

IUCLID data sheet.

POTASSIUM FERRICYANIDE (CAS: 13746-66-2)


LC50 96 hours 869 mg/l Onchorhynchus mykiss (Rainbow trout)





12.2. Persistence and degradability

Degradability

There are no data on the degradability of this product.



Degradability

Not Applicable - Inorganic chemical.

IUCLID data sheet.

Decomposition products: Hydrogen cyanide (HCN). Iron salts.


Degradability


12.3. Bioaccumulative potential

Bioaccumulative potential

No data available on bioaccumulation.

Partition coefficient

Not determined.

1210 /

Solution AEcological information on ingredients.







12.4. Mobility in soil

Mobility:

The product is soluble in water.



Mobility:

Soluble in water.


Mobility:

Soluble in water.

12.5. Results of PBT and vPvB assessment




Not Classified as PBT/vPvB by current EU criteria.



12.6. Other adverse effects

None known.



None known.


None known.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

When handling waste, consideration should be made to the safety precautions applying to handling of the product. Contact with acids

liberates very toxic gas. Residues and empty containers should be taken care of as hazardous waste according to local and national

provisions.

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,

ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Transport Labels

No transport warning sign required.

1211 /

Solution A

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40.

EU Legislation

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and

packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC)

No 1907/2006 with amendments. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006

concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals

Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94

as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including

amendments.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

General information

Only trained personnel should use this material.

Revision Comments

This is first issue.


Risk Phrases In Full

Contact with acids liberates very toxic gas.R32

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52/53

Hazard Statements In Full

Contact with acids liberates very toxic gas.EUH032

Harmful to aquatic life with long lasting effects.H412

1212 /


SAFETY DATA SHEET

Solution B

According to Regulation (EU) No 453/2010

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Solution B

Container size 1 mL

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Laboratory Reagent. For research purposes only.

1.3. Details of the supplier of the safety data sheet

Oxford Nanopore Technologies Ltd.Supplier

Edmund Cartwright House,

4 Robert Robinson Avenue,

Oxford Science Park,

Oxford, OX4 4GA

UK

T: +44 (0) 845 034 7900

F: +44 (0) 845 034 7901

W: www.nanoporetech.com

E: [email protected]

1.4. Emergency telephone number

+44 (0) 845 034 7900 (Mon - Fri 09:00 - 17:00 h)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture


Physical and Chemical Hazards Not classified.

Human health EUH032

Environment Not classified.

Classification (1999/45/EEC) R32.


Human health

Warning - this preparation contains a substance not yet tested completely. Contact with acids liberates very toxic gas.

Environment

The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic

environment.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Precautionary Statements

P280 Wear protective clothing, gloves, eye and face protection.

Supplemental label information

EUH032 Contact with acids liberates very toxic gas.

2.3. Other hazards


SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

121 /

Solution B

POTASSIUM FERROCYANIDE 5-10%

CAS-No.: 14459-95-1 EC No.: 237-722-2


R52/53,R32.


EUH032

Aquatic Chronic 3 - H412

POTASSIUM FERRICYANIDE 1-5%

CAS-No.: 13746-66-2 EC No.: 237-323-3


R32.


EUH032


SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information

Warning - this preparation contains a substance not yet tested completely. Get medical advice/attention if you feel unwell.

Contact with acids liberates very toxic gas. IF exposed or concerned: Get medical advice/attention.

Inhalation

Due to the small packaging the risk of inhalation is minimal. Move into fresh air and keep at rest. Get medical attention if any discomfort

continues.

Ingestion

Get medical attention if any discomfort continues.

Skin contact

Remove contaminated clothing. Wash skin thoroughly with soap and water for several minutes. Get medical attention promptly if

symptoms occur after washing.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.

Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation


Ingestion

Not known. May cause discomfort if swallowed.

Skin contact


Eye contact

Spray in the eyes: May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Warning - this preparation

contains a substance not yet tested completely. Contact with acids liberates very toxic gas.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). Hydrocarbons. Hydrogen cyanide (HCN).

122 /

Solution BUnusual Fire & Explosion Hazards

No unusual fire or explosion hazards noted.

Specific hazards


5.3. Advice for firefighters

Special Fire Fighting Procedures

Contact with acids liberates very toxic gas. Warning - this preparation contains a substance not yet tested completely. Avoid contact with

skin and eyes.

Protective equipment for fire-fighters

Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


6.3. Methods and material for containment and cleaning up

In case of spills, beware of slippery floors and surfaces. Wear necessary protective equipment. CAUTION! Contact with acids liberates

very toxic gas. Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. For waste disposal, see

section 13.

6.4. Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for more detailed information on health effects

and symptoms. For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Do not

handle broken packages without protective equipment. Avoid contact with skin and eyes. Do not eat, drink or smoke when using the

product. Wash hands thoroughly after handling. Avoid contact with acids.

7.2. Conditions for safe storage, including any incompatibilities

Protect from freezing and direct sunlight. Store at temperatures not exceeding 4°C. Store away from: Acids.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments

No exposure limits noted for ingredient(s).

8.2. Exposure controls

Process conditions

Provide eyewash station.

Engineering measures

Provide adequate general and local exhaust ventilation.

Respiratory equipment

Respiratory protection may be required. Contact with acids liberates very toxic gas. Wear full face mask supplied with: Type: ABEK [ EN

14387:2004 ]

Hand protection

Protective gloves must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with

the gloves supplier, who can inform about the breakthrough time of the glove material.

Eye protection

Wear approved safety goggles.

123 /

Solution BOther Protection

Wear suitable protective clothing as protection against splashing or contamination.

Hygiene measures

Wash hands after handling. When using do not eat, drink or smoke. Wash contaminated clothing before reuse.

Environmental Exposure Controls


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Colourless to pale yellow.

Odour No characteristic odour.

Solubility Soluble in water.

Initial boiling point and boiling range

(°C)

~100 °C @ 760 mm Hg

Melting point (°C) ~0 °C @ 760 mmHg

Relative density

Not determined.

Vapour density (air=1)

Not determined.

Vapour pressure

Not determined.

Evaporation rate

Not determined.

pH-Value, Conc. Solution

Not determined.

Viscosity

Not determined.

Decomposition temperature (°C)

Not determined.

Odour Threshold, Lower

Not determined.

Odour Threshold, Upper

Not determined.

Flash point (°C)

Not available.

Auto Ignition Temperature (°C)

Not determined.

Flammability Limit - Lower(%)

Not determined.

Flammability Limit - Upper(%)

Not determined.

Partition Coefficient

(N-Octanol/Water)

Not determined.

Explosive properties

Not considered to be explosive.

Oxidising properties

Does not meet the criteria for oxidising.

9.2. Other information

Not known.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

Reaction with: Acids.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use. Stable under the prescribed storage conditions.

124 /

Solution B

10.3. Possibility of hazardous reactions

Not known.

Hazardous Polymerisation

Will not polymerise.

10.4. Conditions to avoid

Avoid heat. Protect from freezing and direct sunlight.

10.5. Incompatible materials

Materials To Avoid


10.6. Hazardous decomposition products

Not known.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects


Warning - this preparation contains a substance not yet tested completely.

Acute toxicity:


















Skin sensitisation







Carcinogenicity:

Carcinogenicity







125 /

Solution BReproductive Toxicity - Development











Aspiration hazard:


Toxicological information on ingredients.

126 /

Solution BPOTASSIUM FERROCYANIDE (CAS: 14459-95-1)



Acute toxicity:


3613 mg/kg Rat

IUCLID data sheet.






> 1000 mg/m3 Rat 4 hours

IUCLID data sheet.

Limited information on study available. No reported deaths occurred. Based on available data the classification criteria are not met.


Dose

(Dose and duration unstated) Rabbit

IUCLID data sheet.

Not irritating. Based on available data the classification criteria are not met.


May cause temporary eye irritation. Based on available data the classification criteria are not met.





Skin sensitisation

Guinea pig maximization test (GPMT): Guinea Pig

IUCLID data sheet.

Not Sensitising. Based on available data the classification criteria are not met.



DNA damage and/or repair:

IUCLID data sheet.

Negative.





Carcinogenicity:

Carcinogenicity

(Dose and duration unstated) Oral Rat

IUCLID data sheet.

Is not expected to be carcinogenic, based on results of related chemicals in animal studies Based on available data the classification

criteria are not met.






Teratogenicity: NOAEL =<0.036 ppm Inhalation. Rat

127 /

Solution BDelivered in aerosol form, 24 hours a day for an unknown duration. Insufficient data presented and test not conducted to OECD guidelines.

IUCLID data sheet.

Data lacking.









Aspiration hazard:

Viscosity

Not applicable.


128 /

Solution BPOTASSIUM FERRICYANIDE (CAS: 13746-66-2)



Acute toxicity:


2970 mg/kg Mouse

















Skin sensitisation










Carcinogenicity:

Carcinogenicity


















129 /

Solution B

Aspiration hazard:

Viscosity

Not applicable.


SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or

frequent spills can have a harmful or damaging effect on the environment.

12.1. Toxicity

Acute Fish Toxicity

Not considered toxic to fish.




LC50 96 hours 19 mg/l Poecilia reticulata (Guppy)

IUCLID data sheet.

LC50 96 hours > 100 mg/l Pimephales promelas (Fat-head Minnow)

IUCLID data sheet.



IUCLID data sheet.

Acute Toxicity - Microorganisms

NOEC ~ 47 mg/l Activated sludge

IUCLID data sheet.



LC50 96 hours 869 mg/l Onchorhynchus mykiss (Rainbow trout)





12.2. Persistence and degradability

Degradability

There are no data on the degradability of this product.



Degradability


IUCLID data sheet.

Decomposition products: Hydrogen cyanide (HCN). Iron salts.


Degradability


12.3. Bioaccumulative potential



Partition coefficient

Not determined.

1210 /

Solution BEcological information on ingredients.







12.4. Mobility in soil

Mobility:

The product is soluble in water.



Mobility:

Soluble in water.


Mobility:

Soluble in water.

12.5. Results of PBT and vPvB assessment







12.6. Other adverse effects

None known.



None known.


None known.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

When handling waste, consideration should be made to the safety precautions applying to handling of the product. Contact with acids

liberates very toxic gas. Residues and empty containers should be taken care of as hazardous waste according to local and national

provisions.

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,

ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Transport Labels

No transport warning sign required.

1211 /

Solution B

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40.

EU Legislation

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and

packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC)

No 1907/2006 with amendments. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006

concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals

Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94

as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including

amendments.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Revision Comments

This is first issue.


Risk Phrases In Full

Contact with acids liberates very toxic gas.R32

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52/53

Hazard Statements In Full

Contact with acids liberates very toxic gas.EUH032

Harmful to aquatic life with long lasting effects.H412

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wash kit - nanopore · 2016-08-12 · solution a potassium ferrocyanide (cas: 14459-95-1)...

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